US3749559A - Piston rings with coating impregnated with antifriction agent - Google Patents

Abstract

A PISTON RING HAVING A BEARING FACE COATED WITH A HARD POROUS METAL OR METAL ALLOY HAVING ITS PORES IMPREGNATED WITH A SOLID ANTIFRICTION AGENT SUCH AS GRAPHITE. THE POROUS METAL OR METAL ALLOY HAS AN OPEN POROSITY RANGING FROM ABOUT 7 TO ABOUT 30% BY VOLUME OF THE OUTER SURFACE OF THE COATED BEARING FACE, AND THE PORE OPENINGS RANGE FROM ABOUT 0.2 MICRON TO ABOUT 10 MICRONS, THEREBY BEING LARGE ENOUGH TO DISCHARGE THE ANTIFRICTION AGENT TO THE CYLINDER SURFACE FOR LONG PERIODS OF TIME AFTER THE ANTIFRICITION COATING WEARS OFF OF THE BEARING FACE AND THHE METAL OR METAL ALLOY RIDES ON THE CYLINDER WALL. AT THE SAME TIME THE PORES ARE SUFFICIENTLY SMALL TO PREVENT ACCUMULATION AND TRAPPING OR DEBRIS SUCH AS MIGHT BE FORMED DURING THE BREAK-IN PERIOD OF OPERATION OF THE ENGINE. PREFERRED HARD POROUS METAL AND METAL ALLOY COATINGS ARE MOLYBDENUM, MOLYBDENUM ALLOYS AND TUNGSTEN CARBIDE ALLOYS.

D R A W I N G

Description

PISTON RINGS WITH COATING IMPREGNATED WITH ANTIFRICTION AGENT Original Filed Oct. 20, 1969 3 SheetS-Sheet 1 INVENTOR ATTYS.

H. F. PRASSE Jul al, 1973 3 Sheets-Sheet 2 Original Filed Oct. 20, 1969 0 1 x l a w 0 a w WW m D w P 5 5 I w M a I W I l 5 I 0 1 w y m I. 0 0 0 m 0 m a w w 2 0 QfimGk NQMQ m w w w w a w 0 IN VENTOR.

July 31, 1973 H. F. PRASSE 3,749,559

PISTON RINGS WITH COATING IMPREGNATED WITH ANTIFRIC'IION AGENT 3 Sheets-Sheet 5 Original Filed Oct. 20, 1969 IN VEN TOR.

zfi'szeef FP Q2952? 3 749 559 PISTON RINGS WITH COATING IMPREGNATED WITH ANTIFRICTION AGENT Herbert F. Prasse, Town and Country, Mo., assignor to Ramsey Corporation, St. Louis, Mo.

Original application Oct. 20, 1969, Ser. No. 867,632, now Patent No. 3,617,349. Divided and this application June 29, 1971, Ser. No. 157,930

Int. Cl. F02f 5/00 U.S. Cl. 29-191.2 11 Claims ABSTRACT OF THE DISCLOSURE A piston ring having a bearing face coated with a hard porous metal or metal alloy having its pores impregnated with a solid antifriction agent such as graphite. The porous metal or metal alloy has an open porosity ranging from about 7 to about 30% by volume of the outer surface of the coated bearing face, and the pore openings range from about 0.2 micron to about 10 microns, thereby being large enough to discharge the antifriction agent to the cylinder surface for long periods of time after the antifriction coating wears off of the bearing face and the metal or metal alloy rides on the cylinder wall. At the same time the pores are sufficiently small to prevent accumulation and trapping or debris such as might be formed during the break-in period of operation of the engine. Preferred hard porous metal and metal alloy coatings are molybdenum, molybdenum alloys and tungsten carbide alloys.

RELATED APPLICATION This application is a division of my copending U.S. application entitled Method of Making Anti-Friction Piston Rings, Ser. No. 867,632 filed Oct. 20, 1969 (now Pat. No. 3,617,349, dated Jan. 2, 1971).

BACKGROUND OF THE INVENTION Field of the invention This invention relates to the packing ring or piston ring art and to the provision of bearing faces on piston rings. The invention particularly deals with coatings on piston rings which exhibit exceptional antifriction characterstics, particularly valuable in the start-up operating period of internal combustion engines.

Description of the prior art One of the most critical times for the operation of the cylinder-piston assembly of an internal combustion engine is during its initial operation or break-in period. During this preliminary engine operation there are a number of physical and perhaps chemical changes of the running surfaces of the piston rings and cylinder barrels. After this period of time usually, say about 1000 miles, the properties of the surfaces of the piston rings and cylinder bore have been altered which should then result in optimum performance characteristics. It is during this initial period of time that a piston ring including both compresson and oil control rings should exhibit maximumu antifriction or scuff resistance properties.

To achieve close fit with piston rings cylinder bores are normally honed or polished. However, it has been found that this operation does present a drawback in that the graphite pockets in the cylinder normally leading to the surfaces have been closed. Therefore, the nat- United States Patent O "ice ural antifriction property of the cylinder has been substantialy lessened.

To overcome the above, it has been proposed that the bearing face of a piston ring be coated with a dry film lubricant such as graphite. However, the surface. coating is quickly obliterated after a relatively short period of engine operation, and the desired antifriction property lost. Chances for scufling are then materially greatened.

It would therefore be a substantial advance in the art if a piston ring were discovered which had a hard wearing surface and yet exhibited the desired antifriction property, particularly during the time of engine break-in but also beyond that point.

SUMMARY OF THE INVENTION The present invention provides hard-faced piston rings which also exhibit long term antifriction properties of ite. The concept of impregnation is particularly important in order to provide a long lasting period of lubrication, particularly during the initial period of engine break-in. A mere lubricant coating of the metal coated bearing face is ineffectual by reason of its being used up prior to the termination of the break-in period.

The piston rings of this invention are preferably made according to the method of my aforesaid Pat. No. 3,617,- 349. This method includes the steps of coating the bear ing face of a piston ring with a hard porous metal or metal alloy. The coated ring is then heated to drive the air from the pores of the coating. The still hot piston ring is then contacted with an antifriction agent which is dissolved or dispersed in a liquid solvent acting as a carrier. Upon contact of the ring the antifriction agent is drawn into the pores of the coating and remains therein as an impregnant of the coating. Meanwhile, the liquid carrier contacting the hot surface of the piston ring is volatilized from the ring.

It is therefore the object of the invention to provide an improved piston ring.

A more specific object of the invention is to provide a piston ring having its bearing face treated such that it exhibits both long wear in use, and as well demonstrates excellent lubricity, particularly during the engine breakin period, therefore substantially lessening cylinder scuffing leading to engine failure.

A still further object of the invention is to provide the above antifriction ring whereby engine torque can be materially reduced when compared to like use of prior art coated piston rings. 7

Other objects, features and advantages ofithe invention will be readily apparent from the following description of certain preferred embodiments thereof, taken in conjunction with the accompanying drawings, although variations and modifications may be effected without departing from the spirit and scope of the novel concepts of the disclosure, and in which:

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a photomicrograph of the surface of a cylinder after honing prior to operation;

FIG. 2 is a photomicrograph of a cylinder surface after a period of operation;

FIG. 3 is a graph relating engine speed to friction horsepower with a piston ring of the invention compared to a prior art piston ring;

FIG. 4 is a graph comparing static break-away torque utilizing a piston ring of the invention compared to prior art piston rings;

FIG. 5 is a side elevational view, with parts in crosssection, of an engine piston and cylinder assembly, wherein the piston has ring grooves equipped with compression and oil control rings, each having a bearing face engaging the cylinder which is composed of an 'm situ formed plasma jet applied coating;

FIG. 6 is an enlarged fragmentary crosssectional view of the top compression ring in the piston of FIG. 5;

FIG. 7 is a view similar to FIG. 6, illustrating the second compression ring in the piston of FIG. 5;

FIG. 8 is a view similar to FIG. 6 but illustrating the oil control ring in the third ring groove of the piston of FIG. 5;

FIG. 9 is a view similar to FIG. 6, but illustrating the oil control ring in the fourth ring groove of the piston of FIG. 5; and

FIG. 10 is an elevat-ional view of an arbor of piston rings being plasma jet coated.

DESCRIPTION OF THE PREFERRED EMBODIMENTS As noted above, the piston rings of the invention are those having a bearing face coated with a hard porous metal or metal alloy. impregnated in the pores of the metal is an antifriction agent.

The piston ring may be first coated with the metal or metal alloy in any conventional manner, although, it is greatly preferred that the piston rings be coated utilizing a plasma jet spray technique, as will be discussed in more detail hereinafter. The coating itself may be derived from a number of metal or metal alloys with the only requirement being that it have sufficient porosity to absorb a substantial amount of the antifriction agent. Base coatings which may be utilized hereinclude such coatings as molybdenum, molybdenum alloys, tungsten carbide alloys, chromium carbide alloys, alumina-titania, zirconium oxide, etc. For best results the porous metal or metal alloy should have an open porosity ranging from about 7% to about 30% by volume of the outer surface of the thuscoated bearing face. More often, the porosity ranges from about 7% to about 20%. Again, the pore opening should be sufiiciently large to allow sufiicient inclusion of the antifriction agent. Normally the pore openings range from about 0.2 micron to about 10 microns. Preferred coatings include molybdenum, molybdenum alloys, and tungsten carbide alloys.

As mentioned above, the initial or base coatings are preferably applied by resort to a plasma jet spray procedure wherein the coating is formed in situ on the hearing face of the ring. The coating is usually applied by resort to a powder containing the various metals or metal alloys as powder ingredients.

A typical coating will be formed from a powder containing tungsten carbide and other metals as follows:

25 to 55% by weight tungsten carbide 4 to 8% by weight cobalt 25 to 45% by weight nickel 3 to 7% by Weight chromium 0 to '7 by weight aluminum 0 to 3% by weight boron Balance-substantially iron.

The tungsten carbide content of the above powder may be admixed with or replaced by other carbides such as the carbides of metals or metalloids from the group including titanium, tantalum, columbium, molybdenum,

vanadium, chromium, zirconium, hafnium, silicon, and boron.

A specific tungsten carbide powder is a mixture of the following compositions:

Other and preferred coatings are molybdenum-derived coatings, either molybdenum itself or a molybdenum alloy. One molybdenum powder has the following composition:

65% to 90% by weight molybdenum 7% to 25% by weight nickel 1% to 6% by Weight chromium 0.3% to 1.5% by weight boron 0.2% to 1.5% by weight silicon Balance-iron with small amounts of carbon and cobalt.

A preferred molybdenum powder has the following range of elements:

65% to 90% by weight of molybdenum 7% to 24.5% by weight of nickel 1.6% to 5.8% by weight of chromium 0.4% to 1.3% by weight of boron 0.3% to 1.4% by weight of silicon Balanceiron with small amounts of carbon and cobalt.

One specifically preferred powder mixture has the following composition:

75% by Weight molybdenum 17.5% by weight nickel 4.12% by weight chromium 0.94% by weight boron 1.00% by weight silicon Balance-iron with small amounts of carbon and cobalt.

Another preferred powder has the following range of elements:

65 to 90% by weight of molybdenum 3.5 to 12% by weight of nickel 3 to 10% by weight of chromium 1.5 to 5% by weight of tungsten 1 to 3% by weight of cobalt 0.8 to 3% by weight of iron 0.2 to 1% by Weight of carbon Balancesilicon and manganese.

One specific powder mixture falling within the above range has the following composition:

% by weight molybdenum 7% by weight nickel 6% by weight chromium 3% by Weight tungsten 2% by weight cobalt 0.8% by weight iron 0.4% by weight carbon Balance-silicon and manganese.

A still further preferred powder mixture has the following range of elements:

65 to by weight of molybdenum 6.5 to 25% by weight of nickel 1.3 to 7% by weight of chromium 0.3 to 1.7% by weight of silicon 0.2 to 1.7 by weight of boron 0.3 to 1.7% by weight of iron 0.1 to 0.4% by weight of cobalt Balance-carbon and manganese.

Another specific powder mixture falling within the just-enumerated range of elements has the following composition:

80% by weight molybdenum 14.6% by weight nickel 2.8% by weight chromium 0.8% by weight silicon 0.6% by weight boron 0.7% by weight iron 0.2% by weight cobalt Balancecarbon and manganese.

After the piston ring has been properly coated with a porous type of coating, it is then impregnated with an antifriction agent. This is carried out by first heating the coated piston ring to say 300400 F. to drive the air from the pores of the coating. Immediately thereafter while the ring is still hot it is contacted with a solution or dispersion of the antifriction agent. The antifriction agent is then drawn into the pores of the coating, remaining there as an impregnant, while the liquid carrier is evaporated upon contacting the hot piston ring.

The actual contact step of ring and antifriction agent may be carried out via a variety of techniques such as spraying the antifriction agent on the hot ring or immersing the ring in a solution or dispersion containing the antifriction agent.

The antifriction agent may be chosen from a wide variety of materials including such lubricants as graphite, zinc stearate, mica, fibrous talc, magnesium oleate, calcium palmitate, barium stearate, molybdenum sulfide, aluminum sulfide, Teflon, and combinations of the above. A preferred antifriction agent is graphite.

Again, the solvent or dispersing medium for any one or more of the above antifriction agents may be chosen from a wide variety of liquids such as alcohols, benzene, toluene, xylene, aliphatics, esters, ethers, halogenated hydrocarbons, kerosene, substituted benzenes, etc. For example, a typical solvent for graphite is mineral spirits.

After the above steps have been followed the thus impregnated ring coating is ready for use. A suflicient amount of antifriction agent is present in the coating to last at least through the break-in period of the engine. The friction level is then maintained at a low level and temperature problems are avoided. Piston rings containing the dry film lubricant or antifriction agent may be employed in diesel engines and gasoline engines, giving equally good protection in both. After the initial break-in period, usually considered to be at least 1000 miles, the graphite begins to be exposed in the cylinder bore itself. Until this time the antifriction agent such as graphite from the ring is provided for proper protection.

The antifriction rings of the invention are particularly useful in low emission engines. In engines of this type which remain hot after stopping it is imperative to have a relatively high cranking speed. Thus, one needs low friction rings in order to crank the engine fast enough with current ordinary batteries.

Turning now to the drawings, FIG. 1 is a photomicrograph of the surface of a cylinder after being honed. The pockets near the surface have been closed by the honing operation. In this regard it is interesting to note that up to about 1000 miles of use the cylinder bores did not exhibit graphite pockets even at the turn-around point of the ring, which is the area of most wear. Thus, during the critical break-in period and for some time thereafter the graphite of the cylinder would not be available as an antifriction agent. It is evident then that the impregnated piston ring coatings of the invention are extremely useful during this period.

FIG. 2 is a photomicrograph showing a portion of a cylinder surface in ring travel after about 1000 hours of operation. The magnification here was again 750 times. It is evident now that graphite pockets are available at the surface of the cylinder, and the graphite available as a dry lubricant. However, as noted above, prior to about 300 hours of wear the graphite was not available due to honing of the cylinder.

FIG. 3 is a graph showing the reduced friction at various engine speeds utilizing a graphite impregnated molybdenum coated piston rings versus a non-impregnated molybdenum piston ring. In Test I, involving a molybdenum coated ring, engine speeds at various r.p.m.s are plotted against friction horsepower as a dotted line. A like plot is shown as a solid line involving a graphiteimpregnated molybdenum ring in Test II. It is clearly evident that the graphite impregnation materially reduced friction due to pressure of the antifriction agent, here 'being graphite.

FIG. 4 again shows improved engine performance using a graphite impregnated ring. Here, static break-away torque was compared with three rings. The first was a barrel face chrome compression ring designated on the graph as I. The second was a barrel face molybdenum compression ring designated as II on the graph. The third was a piston ring of the invention, here a barrel face molybdenum graphite-impregnated compression ring designated III. It is apparent from the graph of FIG. 4, that there is required a hundred percent increase in relative torque in an engine utilizing a chrome compression ring compared to a like engine wherein there is employed a graphite-impregnated molybdenum coated ring. Likewise, there is greater than a 50% increase in relative torque utilizing a molybdenum coated compression ring versus the graphite impregnated molybdenum coated compression ring of the invention. Again, the antifriction property of the rings of the invention is amply demonstrated in this work.

The remaining figures, FIGS. 5-10, illustrate typical piston rings which may be coated, coated rings thereof, and the preferred method of coating these rings by plasma jet coating techniques.

The piston and cylinder assembly 10 of FIG. 5 illustrates generally a conventional 4-ring groove internal combustion engine piston, operating in an engine cylinder. The assembly 10 includes a piston 11 and an engine cylinder 12 with a bore 13, receiving the piston 11. The piston 11 has a head 14 with a ring band 15 having four peripheral ring grooves 16, 17, 18 and 19 therearound. The top ring groove 16 has a split solid cast iron compression or fire piston ring 20 therein. The second ring groove 17 has a split solid second compression ring 21 somewhat wider than the ring 20. The third ring groove 18 carries a tWopiece oil control ring assembly 22. The fourth or bottom ring groove 19 carries a three-piece oil control ring assembly 23.

As shown in FIG. 6, the top compression or fire ring 20 has a main body 24 composed of cast iron. preferably nodular gray iron, with a carbon content of about 3% percent by weight. The outer periphery 25 of this ring is covered with a hard refractory coating 26, which may be, for example, a plasma jet applied molybdenum or molybdenum alloy coating.

As shown in FIG. 7, the second compression ring 21 has a main body 27 composed of the same type of cast iron as the body 24 of the ring 20. The outer periphery 28 of the body 27 is inclined upwardly and inwardly from the bottom edge of the ring, and a peripheral groove 29 is formed around this inclined periphery. The groove 29 is filled with the coating 26.

As shown in FIG. 8, the oil control ring assembly 22 in the third ring groove 18 is composed of a one-piece flexible channel ring 30 and a sheet-metal expander ring 31, having legs extending into the channel for expanding the ring 30. The ring 30' and the expander are more fully described in Mayhew et al. Pat. 3,281,156.

The one-piece control ring 30 has a pair of axially spaced, radially projecting beads 3-2. The peripheries of these beads 32 are coated with the coating 26-.

In FIG. 9, the oil control ring assembly 23 includes a resilient spacer-expander ring 33 supporting and expanding split thin rail rings 34. The assembly 33 is of the type disclosed in Marien US. Pat. 3,133,739. The outer peripheries of the rail rings 34 are coated with the coating 26.

From the above description, it will be understood that the bearing faces of each of the compression and oil control rings 20, 21, 22 and 23 are coated with some hard facing prior to being impregnated with an antifriction agent. These bearing faces 26 ride on and sealingly engage the bore 13 of the engine cylinder 12, and the rings are compressed in the bore 13, so as to expand tightly against the bore wall, and maintain a good sealing sliding engagement therewith.

As shown in FIG. 10, the coatings 26 are applied on the rings as for example on the grooved rings 21 by stacking a plurality of the rings on an arbor 35, with the rings compressed so that their split ends will be in abutment. The arbor clamping the stack of rings in their closed, contracted position may be mounted in a lathe and the peripheries of the rings machined to form the grooves 29 therearound. The outer peripheries of the rings 21 on the arbor are then coated with the coatings 26 from a plasma jet spray gun 36. The gun 36 includes an insulated casing such as nylon 37, from which projects a rear electrode 38, the projection of which is adjustably controlled by a screw knob 39. The front face of the casing receives a front electrode 40. The casing 37 and electrode 40 are hollow and water-jacketed so that coolant may circulate therethrough from an inlet 41 to an outlet 42. Plasma jet gas is fed through an inlet 43 into the chamber provided by the casing 37 and the electrode 40 to flow around the electrode 38.

The front end of the electrode 40 provides a nozzle outlet 44 for the plasma flame and the ingredients to form the coating 26 are fed to this nozzle through a powder inlet 45, just in advance of the discharge outlet of the nozzle.

A plasma composed of ionized gas is produced by passing the plasma gas from the inlet 42 through an electric are established between the electrodes 38 and 40. This plasma gas is non-oxidizing and may be composed of nitrogen and hydrogen with argon, or helium as a carrier. The plasma flame exuding from the nozzle 44 draws the powder therewith by aspiration and subjects the powder ingredients to high temperatures to cause them to melt. The jet stream carries the melted metal into the bottom of the groove 29 of each piston ring and fills the groove.

. After the coating is deposited it is bound to the base body of the ring of the piston. The fused-in coating forms in situ in the groove of the piston ring and is bonded to the body of the ring along a fused interface or welded zone. The interface or zone is composed of materials of the coating and the material of the ring body.

During the jet spray application it is desired to maintain a temperature in the groove of the piston ring such that excessive burning and melting away of the body metal is prevented. To achieve this end result, the arbor of the rings is preferably cooled with an external blast of inert gas impinging on both sides of the jet flame. It is desirable to keep the temperatures of the rings in the arbor around 400 F. or less. It is not necessary to provide any subsequent heat treatment for the plasma jet coated rings other than allowing the rings to air cool.

The powder fed to the inlet of the plasma jet spray gun is metered preferably with the aid of an aspirating gas, vibration, mechanical gearing, etc. All the powder is completely melted and penetrates into the center cone of the plasma jet flame.

The following examples illustrates a typical method for preparing the anti-friction impregnated rings of the invention. Of course, this example is merely illustrative, and the invention is not to be limited thereto.

8 EXAMPLE 1 A piston ring was first prepared with a pure molybdenum coating applied via the plasma jet spray technique described above. A number of rings were prepared in this manner constituting an arbor of rings. The molybdenum coatings had pore openings ranging from about 0.2 micron to about 10 microns and an open porosity of about 20% by volume.

A dispersion of an antifriction agent comprising graphite in mineral spirits was then prepared. Specifically, a commercial preparation of a 50% solids content of graphite dispersed in a mineral spirits carrier was further diluted. One gallon of the graphite dispersion was diluted with two gallons of mineral spirits, and thoroughly agitated to insure a homogeneous mixture.

The arbor of rings was placed in a preheated oven at 350 F. for 10 minutes. After 10 minutes the arbor of rings was removed from the oven and immediately sprayed with the diluted graphite solution. The graphite upon contacting the hot rings was absorbed into the pores of the ring coatings while the mineral spirits vehicle was evaporated from the rings. The arbor was then unloaded, the rings separated and dried for 30 minutes.

It is evident that this invention provides unique antifriction piston rings. The piston rings have particular utility in lessening friction and increasing scuff resistance during the critical period of engine break-in.

I claim as my invention:

1. A piston ring having a bearing face coated with a hard porous metal or metal alloy having an open porosity at its outer surface of about 7 to about 30% by volume and a pore opening of about 0.2 to about 10 microns, and a solid antifriction agent impregnated in said pores.

2. The piston ring of claim 1 wherein said anti-friction agent is graphite.

3. The piston ring of claim 1 wherein said coating is a molybdenum coating.

4. The piston ring of claim 1 wherein said coating is a molybdenum alloy coating.

5. The piston ring of claim 1 wherein said coating is a tungsten carbide alloy coating.

6. The piston ring of claim 1 where said metal or metal alloy coating is a plasma jet applied coating.

7. The piston ring of claim 6 wherein said coating is formed in situ on the bearing face.

8. A seal for engines which comprises a metal body member with a sealing face bonded to said body member composed of a hard porous metal or metal alloy with a thin overlying coating of a solid antifriction agent that wears away during an initial break-in period of operation of the seal in an engine to expose the porous metal or metal alloy coating as the seal face, said porous metal or metal alloy coating having an open porosity at its outer surface of about 7 to about 30% by volume and a pore opening size of about 0.2 to about 10 microns which remains open after the break-in period of operation, and a solid anti-friction agent impregnated into said pores for continuing the antifriction lubrication of the sealing interface between the hard porous metal or metal alloy and the engine Wall after the antifriction coating wears off of the sealing face.

9. A piston ring having a bearing face coated with an in situ formed plasma jet spray applied coating formed from a mixture of the following composition:

20 to 55% by weight of a carbide selected from the group consisting of carbides of tungsten, titanium, tantalum, columbium, molybdenum, vanadium, chr0- mium, zirconium, hafnium, silicon and boron 4 to 8% by weight cobalt 25 to 45% by weight nickel 3 to 7% by weight chromium 0 to 7% by weight aluminum 0 to 3% by weight boron Balancesubstantially iron,

said coating having an open porosity at its outer surface of about 7 to about 30% by volume and a pore opening size of about 0.2 to about microns, and a solid antifriction agent impregnated in said pores.

10. A piston ring having a bearing face coated with an in situ formed plasma jet spray applied porous coating formed from a mixture of the following composition:

65% to 90% by weight molybdenum 7% to by weight nickel 1% to 6% by Weight chromium 0.3% to 1.5% by weight boron 0.2% to 1.5% by weight silicon Balance-iron with small amounts of carbon and cobalt, said coating having an open porosity at its outer surface of about 7 to about by volume and a pore opening size of about 0.2 to about 10 microns, and a solid antifriction agent impregnated in said pores.

11. The piston ring of claim 10 wherein the coating is formed from a powder composed of the following ingredients:

to by weight of molybdenum 3.5 to 12% by weight of nickel 10 3 to 10% by weight of chromium 1.5 to 5% by weight of tungsten 1 to 3% by weight of cobalt 0.8 to 3% by weight of iron 0.2 to 1% by weight of carbon Balance-silicon and manganese.

References Cited UNITED STATES PATENTS L. DEWAYNE RUTLEDGE, Primary Examiner M. J. ANDREWS, Assistant Examiner US. Cl. X.R.

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