US3743536A - Nonwoven sponge fabric - Google Patents

Nonwoven sponge fabric Download PDF

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US3743536A
US3743536A US00013174A US3743536DA US3743536A US 3743536 A US3743536 A US 3743536A US 00013174 A US00013174 A US 00013174A US 3743536D A US3743536D A US 3743536DA US 3743536 A US3743536 A US 3743536A
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composition
nonwoven fabric
polyvinyl alcohol
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G Russell
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Johnson and Johnson
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    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/22—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing macromolecular materials
    • A61L15/225—Mixtures of macromolecular compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42—Use of materials characterised by their function or physical properties
    • A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425—Cellulose series
    • D04H1/4258—Regenerated cellulose series
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4266—Natural fibres not provided for in group D04H1/425
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4282—Addition polymers
    • D04H1/4291—Olefin series
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326—Condensation or reaction polymers
    • D04H1/435—Polyesters
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/02—Homopolymers or copolymers of unsaturated alcohols
    • C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2508—Coating or impregnation absorbs chemical material other than water

Definitions

  • This invention relates to absorbent products.
  • this invention relates to absorbent products which are highly absorbent and low in adhesion characteristics suitable for use as surgical sponges.
  • Surgical sponges are normally composed of several layers of gauze or more recently, one or more layers of nonwoven fabric.
  • the traditional gauze sponges are relatively expensive to manufacture, and unless modified by further treatment, have a tendency to adhere to wounds.
  • nonwoven fabrics In considering replacement for gauze sponges, nonwoven fabrics have been employed. To a large extent, they overcome the disadvantages of the prior art sponges. However, it has been found that in some cases, non-woven fabrics tend to block during steam sterilization and have a tendency to become discolored as a result of the sterilization.
  • a nonwoven absorbent product comprising at least one layer of nonwoven fabric treated with a binder composition consisting of the mixture of (a) a water soluble high molecular weight alcohol capable of insolubilizing a high molecular weight carboxylic acid, (b) a water soluble high molecular weight polycarboxylic acid, and (c) an acrylic polymer.
  • the improved properties of the products of the present invention are believed to be attributed to the novel treating composition used, whereby the treating composition imparts to the products the anti-blocking and/or nondiscoloration and similar properties.
  • the high molecular weight polycarboxylic acid and the high molecular weight alcohol components are chosen as to be complementary to each other whereby when combined, each has the elfect of producing an insolubilized composition.
  • a preferred alcohol because of its availability and inexpensiveness is polyvinyl alcohol.
  • a preferred polycarboxylic acid is polyacrylic acid.
  • other acids and alcohols having the required properties mentioned above may be employed in accordance with this invention.
  • the other component of the composition namely an acrylic polymer
  • Typical polymers include polymers of butyl acrylate, ethyl acrylate and mixtures thereof.
  • the components used in the composition of the present invention may be mixed in any suitable manner to provide the treating product.
  • the alcohol and the polycarboxylic acid components are first mixed together and subsequently the resulting mixture blended with the acrylate polymer.
  • reaction product is an esterification product which is partially reacted with the methylol groups of the cross-linking acrylate polymer.
  • various types of materials can be employed. Typical of these materials are viscose rayon of deniers below 4.5 denier; cuprammonium rayon of deniers below 4.5 denier; cellulose acetate of deniers below 4.5 denier; cotton (bleached absorbent); polyester of deniers below 4.5 denier; and polypropylene of deniers below 4.5 denier.
  • viscose rayon of deniers below 4.5 denier Typical of these materials are viscose rayon of deniers below 4.5 denier; cuprammonium rayon of deniers below 4.5 denier; cellulose acetate of deniers below 4.5 denier; cotton (bleached absorbent); polyester of deniers below 4.5 denier; and polypropylene of deniers below 4.5 denier.
  • other materials may also be employed.
  • the nonwoven fabric employed in this invention be stabilized against deterioration by incorporating into the fabric during its manufacture, a suitable stabilizer known to those skilled in this art.
  • a typical stabilizer is sodium metabisulfite which may be employed in an amount of from about 0.5% to about 1.0%.
  • a further preferred feature of the present invention is the addition of a wetting agent to the fabric to increase the wetting speed.
  • a wetting agent is known to those skilled in the art and incdlude for example di-octyl sodium sulfo-succinate which is marketed under the trademark Deceresol OT or Triton GR-S.
  • the wetting agent if included may be present in an amount of from about 0.5 to about one percent by weight.
  • the nonwoven fabrics may be constructed according to known methods of this art as taught by, for example, the procedures taught in Canadian patent 653,278.
  • the nonwoven fabric is of a foraminous type pattern which resembles a gauze.
  • a foraminous type pattern which resembles a gauze.
  • Such a pattern permits freer passage of fluids and/or air through the products, enhancing the applicability for use as surgical sponges.
  • other nonwoven fabric patterns may also be employed while still achieving the desirable attributes of the present invention.
  • the amount of binder composition incorporated into the nonwoven fabrics to provide the fabric with the desirable attributes of the present invention may vary.
  • the amount of binder composition incorporated into the nonwoven fabric, calculated on the basis of a dry solids content, is desirably between 5 and 30%, with a preferred range of 10-15%. However, these figures may vary depending on the particular end product desired.
  • the binder composition may be applied by any suitable means according to conventional techniques. Such means include passing the nonwoven fabric through a bath of the binder composition or alternately, by printing techniques such as by gravure printing. In printing, the complete nonwoven fabric need not be printed, but only a certain percentage of it-e.g. 35% or less of the fabric surface.
  • a most preferred composition for use in treating the nonwoven fabrics consists of a mixture of three components, namely a cross-linking acrylic emulsionsuch as that marketed under the trademark Rhoplex-HA-8, a solution of a polyvinyl alcohol and a solution of a polyacrylic acid.
  • a cross-linking acrylic emulsion such as that marketed under the trademark Rhoplex-HA-8
  • a solution of a polyvinyl alcohol a solution of a polyacrylic acid.
  • Such compositions have been found to provide most effective results when it contains, by weight, 20 parts acrylic emulsion solids, 1.6 parts polyvinyl alcohol solids and 0.53 part polyacrylic acid solids.
  • point A designates one componentthe acrylic polymer
  • point B the polyvinyl alcohol
  • point C the acrylic acid component.
  • Points A, B and C each represent a composition consisting of 100 percent by weight of the individual components.
  • Preferred copolymers of acrylates for use in the present invention include, for example, ethyl acrylate, butyl acrylate and methylol acrylamide which are cross-linked using heat and catalysts or by heat alone.
  • the preferred range of materials for the preferred composition is designated within the shaded boundary of the triangular portion A, B and C.
  • A represents a composition containing about 93.8%, 4.7% and 1.5% by weight of acrylic polymer, polyvinyl alcohol and acrylic acid respectively.
  • the composition consists of about 48%, 42% and by weight of acrylic polymer, polyvinyl alcohol and acrylic acid.
  • the composition consists of about 48%, 34% and 18% by weight of acrylic polymer, polyvinyl alcohol and acrylic acid.
  • the surgical sponges of the present invention may include absorbent cores or consist essentially of one or more layers of nonwoven fabric folded in a desired manner. If the sponge is fabricated to include a core of absorbent material such as wood pulp fluff or mixtures of wood pulp flufi fibers, e.g. rayon fibers, such products may be prepared according to conventional proceedings. Similarly, the folding of the nonwoven fabric to provide two or more thicknesses of the material may be accomplished according to techniques known in this art.
  • the treatment of the products to impart the bonding agents to the nonwoven fabrics takes place during the manufacture of the nonwoven fabric.
  • EXAMPLE 1 A nonwoven fabric having a foraminous type pattern with a weight of approximately 200 grains per sq. yd. was treated with a composition consisting of, in weight percent The above composition was prepared by mixing the above polyvinyl alcohol solution and the acrylic acid solution in the required proportions. This mixture was then added to the emulsion of the acrylic polymer while stirring.
  • the mixture was applied by gravure printing so as to impart to the fabric, a total dry solids pick-up of about 16% by weight.
  • the treated fabric was then cut into blanks and folded to form surgical sponges.
  • the tests used in determining the discoloration are those known in the art and the value of less than 8 represents a very good product whereas a value in excess of 11 represents considerable discoloration.
  • EXAMPLE 2 Surgical sponges were produced and as are described in Example 1, but in this case, the example employed included a stabilizer in the amount of about /2 percent by weight of the composition. Again, the products were subjected to the sterilization procedures described and the results of Example 1 were repeated with this product.
  • EXAMPLE 3 Surgical sponges of the present invention were prepared based on the procedures of Example 2.
  • the sponges consisted of a sheet of nonwoven fabric having a grain weight of about 350* grains per sq. yd.
  • the nonwoven fabric was of the type marketed under the trademark Keybak.
  • the sponges were treated with the components of Example 2.
  • Two series of such sponges were prepared in which sheet material is formed in the 4" by 4", 8 ply thickness and 4" by 4" 6- ply thickness.
  • An absorbent product having improved resistance to discoloration and blocking on sterilization comprising at least one layer of nonwoven fabric, said fabric having been treated with a composition consisting of from 1.5% to 18% of a high molecular weight polycarboxylic acid, from 4.7% to 42% of a polyvinyl alcohol, and from 48% to 93.8% of a polyacrylate.
  • composition consists of, prior to treating said absorbent product, approximately 93.8%, 4.7% and 1.5% by weight of said polyacrylate, polyvinyl alcohol and polyacrylic acid respectively.
  • composition cons sts of, prior to treating said absorbent product, approximately 48%, 42%, and 10% by weight of said polyacryllate, polyvinyl alcohol, and polyacrylic acid respecive y.
  • composition cons sts of, prior to treating said absorbent product, approximately 48%, 34% and 13% by weight of said polyacrylate, polyvinyl alcohol and polyacrylic acid respecrve y.
  • An absorbent product having improved resistance to discoloration and blocking on sterilization comprising at least one layer of nonwoven fabric, said fabric having been treated with a composition consisting of a mixture of polyvinyl alcohol, polyacrylic acid and a polyacrylate consisting of the group ethyl acrylate-methylol acrylamide copolymer, butyl acrylate-methylol acrylamide copolymer, and copolymers of ethyl and butyl acrylate possessing cross-linking functionality, the amounts of the components of said composition being correlated to fall within the range of from 4.7% to 42% polyvinyl alcohol, 1.5% to 18% polyacrylic acid and 48% to 93.8% polyacrylate.
  • composition prior to treatment of said absorbent product includes 20 parts by weight of cross-linking acrylic emulsion solids, 1.6 parts by weight of polyvinyl alcohol solids and .53 part by weight of polyacrylic acid solids.
  • composition consists of, prior to treating said absorbent product, approximately 93.8%, 4.7% and 1.5% by weight of said polyacrylate, polyvinyl alcohol and polyacrylic acid respectively.
  • composition consists of, prior to treating said absorbent product, approximately 48%, 42%, and 10% by weight of said polyacrylate, polyvinyl alcohol and polyacrylic acid respectively.
  • composition consists of, prior to treating said absorbent product, approximately 48%, 34% and 13% by Weight of said polyacrylate, polyvinyl alcohol and polyacrylic acid respectively.

Abstract

AN ABSORBENT PRODUCT OF IMPROVED RESISTANCE TO DISCOLORATION AND BLOCKING ON STERILIZATION. THE PRODUCT COMPRISES A NONWOVEN FABRIC TREATED WITH A POLYCARBOXYLIC ACID. A POLYVINYL ALCOHOL AND AN ACRYLIC ACID POLYMER.

Description

Ju|y-3, 1973 G. o. RUSSELL 3,743,536
NONWOVEN SPONGE FABRIC Filed Feb. 20, 1970 A [00% ACRYLIC POLYMER B C lOO/o 1 100% POLYVI NYL ALCOHOL POLYACRYLIC ACID INVENTOR ATT EY United States Patent Int. 01. B321: 2770s,- D06m 15/00 US. Cl. 117-1385 15 Claims ABSTRACT OF THE DISCLOSURE An absorbent product of improved resistance to discoloration and blocking on sterilization. The product comprises a nonwoven fabric treated with a polycarboxylic acid, a polyvinyl alcohol and an acrylic acid polymer.
This invention relates to absorbent products.
More particularly, this invention relates to absorbent products which are highly absorbent and low in adhesion characteristics suitable for use as surgical sponges.
Surgical sponges are normally composed of several layers of gauze or more recently, one or more layers of nonwoven fabric. The traditional gauze sponges are relatively expensive to manufacture, and unless modified by further treatment, have a tendency to adhere to wounds.
In considering replacement for gauze sponges, nonwoven fabrics have been employed. To a large extent, they overcome the disadvantages of the prior art sponges. However, it has been found that in some cases, non-woven fabrics tend to block during steam sterilization and have a tendency to become discolored as a result of the sterilization.
With this invention, applicant has developed a novel nonwoven sponge which overcomes the disadvanages of the prior art gauze sponges, and at the same time, incorporates all of the advantages of the known nonwoven fabrics. Further, the product of the present invention has its own desirable attributes, hereinafter referred to.
According to the present invention, there is provided a nonwoven absorbent product, comprising at least one layer of nonwoven fabric treated with a binder composition consisting of the mixture of (a) a water soluble high molecular weight alcohol capable of insolubilizing a high molecular weight carboxylic acid, (b) a water soluble high molecular weight polycarboxylic acid, and (c) an acrylic polymer.
It has been found that products in accordance with this invention possess low adh'esion to wounds, are not blocked during steam sterilization, are highly adsorbent and are softer and more comfortable on a wound. Additionally, the products of the present invention are economical to produce.
The improved properties of the products of the present invention are believed to be attributed to the novel treating composition used, whereby the treating composition imparts to the products the anti-blocking and/or nondiscoloration and similar properties. The high molecular weight polycarboxylic acid and the high molecular weight alcohol components are chosen as to be complementary to each other whereby when combined, each has the elfect of producing an insolubilized composition.
A preferred alcohol, because of its availability and inexpensiveness is polyvinyl alcohol. Likewise, for the same reasons, a preferred polycarboxylic acid is polyacrylic acid. However, other acids and alcohols having the required properties mentioned above may be employed in accordance with this invention.
The other component of the composition, namely an acrylic polymer, may be any suitable polymer which has the properties, upon being mixed with the other compo- 3,743,536 Patented July 3, 1973 ice nents, of producing a non-hardenable or harsh composition. Typical polymers include polymers of butyl acrylate, ethyl acrylate and mixtures thereof.
The components used in the composition of the present invention may be mixed in any suitable manner to provide the treating product. Preferably, the alcohol and the polycarboxylic acid components are first mixed together and subsequently the resulting mixture blended with the acrylate polymer.
The specific mixture obtained by mixing the three ingredients is believed to form some sort of a reaction product but, the nature of the reaction product or its equilibrium composition in terms of reacted components is not at present fully understood. While not being bound to any particular theory, it is believed that possibly the reaction product is an esterification product which is partially reacted with the methylol groups of the cross-linking acrylate polymer.
In the manufacture of the nonwoven fabric, various types of materials can be employed. Typical of these materials are viscose rayon of deniers below 4.5 denier; cuprammonium rayon of deniers below 4.5 denier; cellulose acetate of deniers below 4.5 denier; cotton (bleached absorbent); polyester of deniers below 4.5 denier; and polypropylene of deniers below 4.5 denier. However, it will be understood by those skilled in the art that other materials may also be employed.
It is preferred, but not essential, that the nonwoven fabric employed in this invention be stabilized against deterioration by incorporating into the fabric during its manufacture, a suitable stabilizer known to those skilled in this art. A typical stabilizer is sodium metabisulfite which may be employed in an amount of from about 0.5% to about 1.0%.
A further preferred feature of the present invention, although also not essential, is the addition of a wetting agent to the fabric to increase the wetting speed. Such wetting agents are known to those skilled in the art and incdlude for example di-octyl sodium sulfo-succinate which is marketed under the trademark Deceresol OT or Triton GR-S. The wetting agent if included may be present in an amount of from about 0.5 to about one percent by weight.
The nonwoven fabrics may be constructed according to known methods of this art as taught by, for example, the procedures taught in Canadian patent 653,278.
Preferably, the nonwoven fabric is of a foraminous type pattern which resembles a gauze. Such a pattern permits freer passage of fluids and/or air through the products, enhancing the applicability for use as surgical sponges. However, other nonwoven fabric patterns may also be employed while still achieving the desirable attributes of the present invention.
The amount of binder composition incorporated into the nonwoven fabrics to provide the fabric with the desirable attributes of the present invention may vary. The amount of binder composition incorporated into the nonwoven fabric, calculated on the basis of a dry solids content, is desirably between 5 and 30%, with a preferred range of 10-15%. However, these figures may vary depending on the particular end product desired.
The binder composition may be applied by any suitable means according to conventional techniques. Such means include passing the nonwoven fabric through a bath of the binder composition or alternately, by printing techniques such as by gravure printing. In printing, the complete nonwoven fabric need not be printed, but only a certain percentage of it-e.g. 35% or less of the fabric surface.
A most preferred composition for use in treating the nonwoven fabrics consists of a mixture of three components, namely a cross-linking acrylic emulsionsuch as that marketed under the trademark Rhoplex-HA-8, a solution of a polyvinyl alcohol and a solution of a polyacrylic acid. Such compositions have been found to provide most effective results when it contains, by weight, 20 parts acrylic emulsion solids, 1.6 parts polyvinyl alcohol solids and 0.53 part polyacrylic acid solids.
Referring now to the attached drawing, which represents graphically a preferred range of the three component preferred composition of the present invention, point A designates one componentthe acrylic polymer, point B the polyvinyl alcohol and point C the acrylic acid component. Points A, B and C each represent a composition consisting of 100 percent by weight of the individual components.
Preferred copolymers of acrylates for use in the present invention include, for example, ethyl acrylate, butyl acrylate and methylol acrylamide which are cross-linked using heat and catalysts or by heat alone.
The preferred range of materials for the preferred composition is designated within the shaded boundary of the triangular portion A, B and C. Within this area, A represents a composition containing about 93.8%, 4.7% and 1.5% by weight of acrylic polymer, polyvinyl alcohol and acrylic acid respectively. At point B, the composition consists of about 48%, 42% and by weight of acrylic polymer, polyvinyl alcohol and acrylic acid. At point C, the composition consists of about 48%, 34% and 18% by weight of acrylic polymer, polyvinyl alcohol and acrylic acid.
The surgical sponges of the present invention may include absorbent cores or consist essentially of one or more layers of nonwoven fabric folded in a desired manner. If the sponge is fabricated to include a core of absorbent material such as wood pulp fluff or mixtures of wood pulp flufi fibers, e.g. rayon fibers, such products may be prepared according to conventional proceedings. Similarly, the folding of the nonwoven fabric to provide two or more thicknesses of the material may be accomplished according to techniques known in this art.
The treatment of the products to impart the bonding agents to the nonwoven fabrics takes place during the manufacture of the nonwoven fabric.
The following examples will demonstrate preferred embodiments of the present invention.
EXAMPLE 1 A nonwoven fabric having a foraminous type pattern with a weight of approximately 200 grains per sq. yd. was treated with a composition consisting of, in weight percent The above composition was prepared by mixing the above polyvinyl alcohol solution and the acrylic acid solution in the required proportions. This mixture was then added to the emulsion of the acrylic polymer while stirring.
To treat the fabric, the mixture was applied by gravure printing so as to impart to the fabric, a total dry solids pick-up of about 16% by weight.
The treated fabric was then cut into blanks and folded to form surgical sponges.
Samples of the surgical sponges were then subjected to steam sterilization using saturated steam at a temperature of 225 F. for a period of twenty minutes. After twenty minutes the samples were measured and studied for blocking and discoloration. It was found that there was substantially no blocking and, the sponges had a +b value which was less than 8. As compared to samples which were prepared using different bonding agents of the prior art, and which were subjected to steam sterilization, it was found that such prior art samples were blocked and, had a +b Value in excess of 11.
The tests used in determining the discoloration are those known in the art and the value of less than 8 represents a very good product whereas a value in excess of 11 represents considerable discoloration.
It will therefore be seen that applicants products exhibited improved and superior results compared to the prior art.
EXAMPLE 2 Surgical sponges were produced and as are described in Example 1, but in this case, the example employed included a stabilizer in the amount of about /2 percent by weight of the composition. Again, the products were subjected to the sterilization procedures described and the results of Example 1 were repeated with this product.
EXAMPLE 3 Surgical sponges of the present invention were prepared based on the procedures of Example 2. The sponges consisted of a sheet of nonwoven fabric having a grain weight of about 350* grains per sq. yd. The nonwoven fabric was of the type marketed under the trademark Keybak. The sponges were treated with the components of Example 2. Two series of such sponges were prepared in which sheet material is formed in the 4" by 4", 8 ply thickness and 4" by 4" 6- ply thickness.
Conventional gauzes sponges were also prepared which consisted of several layers of gauze folded to form 4 by 4 inch size products.
The two series of products according to the present invention, and the conventional gauze sponges, were then used in a plurality of repetitive tests to determine their adherence to wounds. As a result of these tests, it was found that wound adherence by the products of the present invention was substantially non-existent, whereas with the conventional gauze sponges, there was evidence of wound adherence in almost all cases.
The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:
1. An absorbent product having improved resistance to discoloration and blocking on sterilization comprising at least one layer of nonwoven fabric, said fabric having been treated with a composition consisting of from 1.5% to 18% of a high molecular weight polycarboxylic acid, from 4.7% to 42% of a polyvinyl alcohol, and from 48% to 93.8% of a polyacrylate.
2. The product of claim 1 wherein said nonwoven fabric includes a stabilizer to prevent deterioration.
3. The product of claim 1 wherein said nonwoven fabric includes a wetting agent.
4. The product of claim 3, wherein said composition consists of, prior to treating said absorbent product, approximately 93.8%, 4.7% and 1.5% by weight of said polyacrylate, polyvinyl alcohol and polyacrylic acid respectively.
5. The product of claim 3, wherein said composition cons sts of, prior to treating said absorbent product, approximately 48%, 42%, and 10% by weight of said polyacryllate, polyvinyl alcohol, and polyacrylic acid respecive y.
'6. The product of claim 3, wherein said composition cons sts of, prior to treating said absorbent product, approximately 48%, 34% and 13% by weight of said polyacrylate, polyvinyl alcohol and polyacrylic acid respecrve y.
7. The product of claim 1, wherein there is included a stabilizer which is sodium metabisulfitc.
8. An absorbent product having improved resistance to discoloration and blocking on sterilization comprising at least one layer of nonwoven fabric, said fabric having been treated with a composition consisting of a mixture of polyvinyl alcohol, polyacrylic acid and a polyacrylate consisting of the group ethyl acrylate-methylol acrylamide copolymer, butyl acrylate-methylol acrylamide copolymer, and copolymers of ethyl and butyl acrylate possessing cross-linking functionality, the amounts of the components of said composition being correlated to fall within the range of from 4.7% to 42% polyvinyl alcohol, 1.5% to 18% polyacrylic acid and 48% to 93.8% polyacrylate.
9. The product of claim 8 wherein said nonwoven fabric includes a stabilizer to prevent deterioration.
10. The product of claim 1, wherein there is included a stabilizer which is sodium metabisulfite.
11. The product of claim 8, wherein said nonwoven fabric includes a wetting agent.
12. The product of claim 8, wherein said composition prior to treatment of said absorbent product, includes 20 parts by weight of cross-linking acrylic emulsion solids, 1.6 parts by weight of polyvinyl alcohol solids and .53 part by weight of polyacrylic acid solids.
13. The product of claim 11, wherein said composition consists of, prior to treating said absorbent product, approximately 93.8%, 4.7% and 1.5% by weight of said polyacrylate, polyvinyl alcohol and polyacrylic acid respectively.
14. The product of claim 11, wherein the composition consists of, prior to treating said absorbent product, approximately 48%, 42%, and 10% by weight of said polyacrylate, polyvinyl alcohol and polyacrylic acid respectively.
15. The product of claim 11, wherein said composition consists of, prior to treating said absorbent product, approximately 48%, 34% and 13% by Weight of said polyacrylate, polyvinyl alcohol and polyacrylic acid respectively.
References Cited UNITED STATES PATENTS 3,253,715 5/1966 Painter ct al 1l7140 A 2,773,050 12/1956 Caldwell 260l 3,518,041 6/1970 Brelich l17l40 A 3,666,640 5/1972 Lofton et al. 8l15.6
WILLIAM D. MARTIN, Primary Examiner W. H. SCHMIDT, Assistant Examiner US. Cl. X.-R.
117138.8 E, F, A, 143 A; l28296; 26090l
US00013174A 1969-02-25 1970-02-20 Nonwoven sponge fabric Expired - Lifetime US3743536A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3900631A (en) * 1973-10-24 1975-08-19 Du Pont Flexible nonwoven sheets for use against splashing liquids
US5171307A (en) * 1990-06-11 1992-12-15 Sanning Frank B Irrigation solution collection device
US5552479A (en) * 1993-01-27 1996-09-03 Kureha Kagaku Kogyo K. K. Gas barrier film and production process thereof
FR2930159A1 (en) * 2008-04-17 2009-10-23 Clean Concepts Soc Par Actions Absorbent cloth for absorbing human or animal physiological liquid, comprises a mixture of paste and cross-linked polyacrylate confined in a warp of non-woven fabric, a biocide, and a perfume or an odor destroyer

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8811776D0 (en) * 1988-05-18 1988-06-22 Smith & Nephew Ass Dressings

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3900631A (en) * 1973-10-24 1975-08-19 Du Pont Flexible nonwoven sheets for use against splashing liquids
US5171307A (en) * 1990-06-11 1992-12-15 Sanning Frank B Irrigation solution collection device
US5552479A (en) * 1993-01-27 1996-09-03 Kureha Kagaku Kogyo K. K. Gas barrier film and production process thereof
FR2930159A1 (en) * 2008-04-17 2009-10-23 Clean Concepts Soc Par Actions Absorbent cloth for absorbing human or animal physiological liquid, comprises a mixture of paste and cross-linked polyacrylate confined in a warp of non-woven fabric, a biocide, and a perfume or an odor destroyer

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NL7002688A (en) 1970-08-27
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BR7017007D0 (en) 1973-03-07
JPS4823983B1 (en) 1973-07-18
IT944540B (en) 1973-04-20

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