US3715232A - Shatter-resistant incandescent lamp - Google Patents

Shatter-resistant incandescent lamp Download PDF

Info

Publication number
US3715232A
US3715232A US00158712A US3715232DA US3715232A US 3715232 A US3715232 A US 3715232A US 00158712 A US00158712 A US 00158712A US 3715232D A US3715232D A US 3715232DA US 3715232 A US3715232 A US 3715232A
Authority
US
United States
Prior art keywords
coating
lamp
bulb
tacky
dust
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US00158712A
Inventor
J Robertson
E Audesse
A Tartakoff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GTE Sylvania Inc
Original Assignee
GTE Sylvania Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GTE Sylvania Inc filed Critical GTE Sylvania Inc
Application granted granted Critical
Publication of US3715232A publication Critical patent/US3715232A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01KELECTRIC INCANDESCENT LAMPS
    • H01K1/00Details
    • H01K1/28Envelopes; Vessels
    • H01K1/32Envelopes; Vessels provided with coatings on the walls; Vessels or coatings thereon characterised by the material thereof
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/3405Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of organic materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J5/00Details relating to vessels or to leading-in conductors common to two or more basic types of discharge tubes or lamps
    • H01J5/02Vessels; Containers; Shields associated therewith; Vacuum locks
    • H01J5/03Arrangements for preventing or mitigating effects of implosion of vessels or containers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/30Vessels; Containers
    • H01J61/35Vessels; Containers provided with coatings on the walls thereof; Selection of materials for the coatings

Definitions

  • the hard, non-tacky material should be heat-resistant, at least to the operating temperature of the bulb, and compatible with the tacky undercoat.
  • Dow Corning Silicone resin XR-4-3095 We have found Dow Corning Silicone resin XR-4-3095 to be very effective.
  • the resultant doubly-coated lamp has a very glossy surface, and if the undercoat is clear, will be so invisible the coating will not be noticeable, but the outside of the bulb will appear to be merely an uncoated glass envelope. Dust, dirt, grime, fingerprints, scratches and mar marks can easily be removed from the coating.
  • the glass bulb 1 has the translucent coating 2 of plastic over its outer surface, and the usual screw base 3 at one end.
  • the base 3 has the threaded metal shell 4.
  • the eyelet contact 5 and the glass piece 6 insulates the eyelet contact 5 from the metal shell while supporting it therefrom.
  • the usual lead-in wires not shown since they are inside the base, terminate in the solder drops 7, 8, which affix them to the base contacts, one lead-in wire to each contact.
  • the bulb envelope 1 carries a clear, transparent coating 9 of a tacky silicone rubber, and over that a coating 20 of a hard heat-resistant silicone material, the lamp filament 10 being visible through the coating 9 and ready for use as substantially a point source.
  • Any of the usual filament types can be used, for example, a coiled-coil of tungsten wire, held near its ends by the support and lead-in wires 11, 12, which extend through the press 13 of stem 14 in the usual manner.
  • the opening 15 in the stem is in communication with the exhaust tube 16, which is used in manufacture for evacuation and gas-filling of the bulb 1, but in the finished lamp described as sealed off within the base 3.
  • Tungsten support wire 15 extends from the press 13 to be looped around the filament 10 in the usual manner.
  • the bulb will generally be filled at slightly below atmospheric pressure with nitrogen, argon, krypton or some other gas inert with respect to the tungsten filament 10.
  • the filament 10 becomes incandescent in the usual manner when a current is passed through it. For this reason, it is generally called an incandescent or incandescible filament.
  • the bulb l is coated with a clear silicone rubber.
  • Silastic 2288 a 25 percent dispersion by weight of silicone rubber in xylene
  • the thickness of the coating can be varied with the size of the bulb.
  • a coating about 0.004 inch thick to be very effective for the A-l9 bulb that is a bulb of the shape shown in the drawing and nineteen-eighths inch in diameter, that is 2 inches, and a coating of about 0.015 inch thick to be better for the PS-30 bulb, that is the usual pear-shaped bulb about thirty-eighths inch in diameter, that is 3 inch diameter.
  • the bulb sizes are given in eighths of an inch in accordance with the usual lamp practice.
  • the bulb can be coated by dipping it in the dispersion given above, and afterward dried.
  • the bulb After the bulb is coated with the silicone rubber 9, it is air dried and desolvated, and the overcoat 20 applied, or if desired, the coating 9 can be fully cured before applying the overcoat 20.
  • the material of the overcoat 20 can be a Dow Corning Silicone resin XR-4-3095. It is used as a clear water-white liquid. At room temperature of 20 C this material takes 29 seconds to efflux through a No. 1 GE. Zahn Cup (viscosity relationship measurement). As such, this can be sprayed on the lamp, flowed on the lamp, or the lamp can be dipped into it. This material could be more viscous, but this would lead to putting on a thicker coat than necessary and increase costs. The optimum thickness for this glossy overcoat is 0.5 mil.
  • This overcoat will withstand the same temperatures that the regular undercoat will withstand namely, 400 to 450 F for extended periods (2,000 hrs.).
  • the visual appearance of the tested lamp gives a much sharper advantage to the hard overcoat it still has a clean, clear look and if some dust does settle on top, it can easily be blown or wiped off, while the plain silicone rubber coating does attract and hold dust and no amount of wiping, dusting or blowing will return it to its fresh condition.
  • An incandescent electric lamp including an enclosing envelope, a first coating of clear tacky silicone rubber over said envelope to reduce shattering of the glass on impact, and a second clear coating of a hard, heat-resistant silicone over said first coating to reduce the adherence of dust.
  • the lamp of claim 1 in which the lamp is an incandescent lamp having a globular envelope.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Vessels And Coating Films For Discharge Lamps (AREA)

Abstract

An electric lamp having a glass envelope with a tacky, shatterresistant silicone rubber coating over the envelope and a coating over that of a hard, heat resistant silicone material to resist the accumulation of dust on the tacky coating.

Description

United States Patent Audesse et al. 5] Feb. 6, 1973 [54] SHATTER-RESISTANT 3,420,694 1/1969 James l l7/94 X INCANDESCENT L 3,117,245 l/l964 Ehrreich 1.1 17/72 x 3,0l8,l87 l/l962 Boyce et al. ..ll7/72X [75 1 Inventors: Emery Audesse i Alex 3,l56,l07 11/1964 Shaffer ..117/124 1-: i gg g g 3,102,049 8/1963 Quirk ..117/124 F x [73] Assignee: GTE Sylvania Incorporated Primary Examiner-Ralph Husaclt [22] Filed: July 1, 1971 Atzorney-Norman J. OMalley et al.
211 App]. No.: 158,712 [57] ABSTRACT An electric lamp having a glass envelope with a tacky, [52] US CL n 55 ;32 :4 3; shatter-resistant silicone rubber coating over the en- 51 1111. C1. ..C03c 17/30 1 2 lv 3/04 "dope and a Coating that of a hard heat 53 Field f Search 17/124 F, E 94, 72 silicone material to resist the accumulation of dust on v the tacky coating. [56] References Cited 2 Claims, 1 Drawing Figure PATENTEDFEB 6|975 3,715,232
JOHN K. ROBERTSON EMERY G. AUDESSE ALEXANDER TARTAKOFF INVENTORS I SHATTER-RESISTANT INCANDESCENT LAMP BACKGROUND OF THE INVENTION 1. Field of the Invention This invention relates to electric lamps, and particularly to such lamps coated on the outside to prevent shattering or breakage. It is particularly adapted to lamps in bulbs of glass or the like.
2. Brief Summary Of Prior Art It had previously been suggested to coat the lamps with a silicone rubber film to hold the glass pieces together on breakage. This had been satisfactory in respect to reducing or eliminating scattering, but the film was of a soft, tacky nature and dust collected on it and adhered so firmly that it could not be removed. This darkened the bulb and reduced its light output; when used in subway systems, where the passing trains stir up an atmosphere of dust, the lamps have been found to lose 80 or 90 percent of their light output, and in fact the light output would become so low that it would seem to have been turned off.
The use of a hard, non-tacky coating instead of the tacky silicone rubber was not effective in reducing shattering.
BRIEF SUMMARY OF INVENTION However, we have discovered that if a hard, nontacky coating is used over the tacky coating, it does not interfere with the shatterproofing effect of the silicone rubber, but does provide a hard, polished-looking surface to which dust will not readily adhere, and from which any dust which does appear can be easily wiped off with a cloth or the like.
The hard, non-tacky material should be heat-resistant, at least to the operating temperature of the bulb, and compatible with the tacky undercoat. We have found Dow Corning Silicone resin XR-4-3095 to be very effective.
The resultant doubly-coated lamp has a very glossy surface, and if the undercoat is clear, will be so invisible the coating will not be noticeable, but the outside of the bulb will appear to be merely an uncoated glass envelope. Dust, dirt, grime, fingerprints, scratches and mar marks can easily be removed from the coating. The
lamp is very effective in withstanding the dusty atmosphere of a subway in a transportation system.
BRIEF DESCRIPTION OF DRAWING Other features, objects and advantages of the invention will be apparent from the following specification, taken in connection with the accompanying drawing, which shows a lamp according to the invention, partly in section.
DETAILED DESCRIPTION OF EMBODIMENTS In FIG. I, the glass bulb 1 has the translucent coating 2 of plastic over its outer surface, and the usual screw base 3 at one end. The base 3 has the threaded metal shell 4. The eyelet contact 5 and the glass piece 6 insulates the eyelet contact 5 from the metal shell while supporting it therefrom. The usual lead-in wires, not shown since they are inside the base, terminate in the solder drops 7, 8, which affix them to the base contacts, one lead-in wire to each contact.
The bulb envelope 1 carries a clear, transparent coating 9 of a tacky silicone rubber, and over that a coating 20 of a hard heat-resistant silicone material, the lamp filament 10 being visible through the coating 9 and ready for use as substantially a point source. Any of the usual filament types can be used, for example, a coiled-coil of tungsten wire, held near its ends by the support and lead-in wires 11, 12, which extend through the press 13 of stem 14 in the usual manner. The opening 15 in the stem is in communication with the exhaust tube 16, which is used in manufacture for evacuation and gas-filling of the bulb 1, but in the finished lamp described as sealed off within the base 3. Tungsten support wire 15 extends from the press 13 to be looped around the filament 10 in the usual manner. The bulb will generally be filled at slightly below atmospheric pressure with nitrogen, argon, krypton or some other gas inert with respect to the tungsten filament 10.
The filament 10 becomes incandescent in the usual manner when a current is passed through it. For this reason, it is generally called an incandescent or incandescible filament.
The bulb l is coated with a clear silicone rubber. We have found the material marketed by Dow Corning Corporation, Midland, Michigan, as Silastic 2288, a 25 percent dispersion by weight of silicone rubber in xylene, to be quite effective. The thickness of the coating can be varied with the size of the bulb. We have found a coating about 0.004 inch thick to be very effective for the A-l9 bulb, that is a bulb of the shape shown in the drawing and nineteen-eighths inch in diameter, that is 2 inches, and a coating of about 0.015 inch thick to be better for the PS-30 bulb, that is the usual pear-shaped bulb about thirty-eighths inch in diameter, that is 3 inch diameter. The bulb sizes are given in eighths of an inch in accordance with the usual lamp practice.
The bulb can be coated by dipping it in the dispersion given above, and afterward dried.
After the bulb is coated with the silicone rubber 9, it is air dried and desolvated, and the overcoat 20 applied, or if desired, the coating 9 can be fully cured before applying the overcoat 20.
The material of the overcoat 20 can be a Dow Corning Silicone resin XR-4-3095. It is used as a clear water-white liquid. At room temperature of 20 C this material takes 29 seconds to efflux through a No. 1 GE. Zahn Cup (viscosity relationship measurement). As such, this can be sprayed on the lamp, flowed on the lamp, or the lamp can be dipped into it. This material could be more viscous, but this would lead to putting on a thicker coat than necessary and increase costs. The optimum thickness for this glossy overcoat is 0.5 mil.
Then, after a 3 5 minute air dry and desolvation of the overcoat, we can pass the lamp with both coats through the curing oven (30minutes at temperature to C) after which, the lamp is tested by lighting it and packed.
This overcoat will withstand the same temperatures that the regular undercoat will withstand namely, 400 to 450 F for extended periods (2,000 hrs.).
Tested in a fairly clean environment, we see the fol- 2. Hard overcoated lamps show a 1.27 percent loss in light output.
The difference is much greater in a dusty atmosphere such as a subway, that is, the lamps with the silicone coating show a much greater loss in light output than the 3.78 percent in the above test.
The visual appearance of the tested lamp gives a much sharper advantage to the hard overcoat it still has a clean, clear look and if some dust does settle on top, it can easily be blown or wiped off, while the plain silicone rubber coating does attract and hold dust and no amount of wiping, dusting or blowing will return it to its fresh condition.
Other modifications will be apparent to a worker skilled in the art from the foregoing description, without departing from the spirit and scope of the invention, which is intended to be limited only by the claims.
What we claim is:
1. An incandescent electric lamp including an enclosing envelope, a first coating of clear tacky silicone rubber over said envelope to reduce shattering of the glass on impact, and a second clear coating of a hard, heat-resistant silicone over said first coating to reduce the adherence of dust.
2. The lamp of claim 1, in which the lamp is an incandescent lamp having a globular envelope.

Claims (1)

1. An incandescent electric lamp including an enclosing envelope, a first coating of clear tacky silicone rubber over said envelope to reduce shattering of the glass on impact, and a second clear coating of a hard, heat-resistant silicone over said first coating to reduce the adherence of dust.
US00158712A 1971-07-01 1971-07-01 Shatter-resistant incandescent lamp Expired - Lifetime US3715232A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US15871271A 1971-07-01 1971-07-01

Publications (1)

Publication Number Publication Date
US3715232A true US3715232A (en) 1973-02-06

Family

ID=22569368

Family Applications (1)

Application Number Title Priority Date Filing Date
US00158712A Expired - Lifetime US3715232A (en) 1971-07-01 1971-07-01 Shatter-resistant incandescent lamp

Country Status (4)

Country Link
US (1) US3715232A (en)
AU (1) AU4417572A (en)
CA (1) CA959916A (en)
ZA (1) ZA724522B (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3902946A (en) * 1972-09-11 1975-09-02 Gte Sylvania Inc Photoflash lamp and method of coating same
US4332329A (en) * 1977-10-25 1982-06-01 Ppg Industries, Inc. Implosion coatings
WO1984001856A1 (en) * 1982-11-08 1984-05-10 Charles K Beck Incandescent illuminating device with antifragility coating
EP0175333A2 (en) * 1984-09-17 1986-03-26 GTE Products Corporation Electric lamp including a containment coating as part thereof
US5109180A (en) * 1989-12-14 1992-04-28 Phillips Petroleum Company Apparatus providing a shatter-resistant electric lamp
EP1227512A2 (en) * 2001-01-24 2002-07-31 General Electric Company High pressure halogen filament lamp
US6501219B1 (en) 1999-07-29 2002-12-31 General Electric Company Shatter-resistant incandescent lamp, silicone coating composition, and method
EP1286190A1 (en) * 2000-04-27 2003-02-26 Tomoegawa Paper Co. Ltd. Optical connection component
US20040066653A1 (en) * 2002-10-03 2004-04-08 Star Leader Ltd Light bulbs
US20040236010A1 (en) * 2001-07-23 2004-11-25 Carter Randall Lee Stabilized polyorganosiloxane composition
US20080055898A1 (en) * 2006-08-28 2008-03-06 Dm Technology & Energy Inc. Led lamp
US20110095673A1 (en) * 2008-06-30 2011-04-28 Whitford Corporation Shatter containment coating

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3018187A (en) * 1959-03-20 1962-01-23 Westinghouse Electric Corp Method of coating a fluorescent type tube and the coated article
US3102049A (en) * 1960-03-16 1963-08-27 Sylvania Electric Prod Process of coating the exterior surface of a fluorescent lamp envelope with silicone resins
US3117245A (en) * 1961-01-03 1964-01-07 Grace W R & Co Ceramic-glazed electroluminescent lighting panel protected by siloxane-bonded linear organic polymer film
US3156107A (en) * 1961-11-21 1964-11-10 Sylvania Electric Prod Photoflash lamp and protective coating therefor
US3420694A (en) * 1966-02-01 1969-01-07 Gen Electric Plural coated transparent colored lamp and method of forming same
US3629228A (en) * 1969-12-01 1971-12-21 Dow Corning Non-corrosive siloxane vulcanizable at room temperature

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3018187A (en) * 1959-03-20 1962-01-23 Westinghouse Electric Corp Method of coating a fluorescent type tube and the coated article
US3102049A (en) * 1960-03-16 1963-08-27 Sylvania Electric Prod Process of coating the exterior surface of a fluorescent lamp envelope with silicone resins
US3117245A (en) * 1961-01-03 1964-01-07 Grace W R & Co Ceramic-glazed electroluminescent lighting panel protected by siloxane-bonded linear organic polymer film
US3156107A (en) * 1961-11-21 1964-11-10 Sylvania Electric Prod Photoflash lamp and protective coating therefor
US3420694A (en) * 1966-02-01 1969-01-07 Gen Electric Plural coated transparent colored lamp and method of forming same
US3629228A (en) * 1969-12-01 1971-12-21 Dow Corning Non-corrosive siloxane vulcanizable at room temperature

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3902946A (en) * 1972-09-11 1975-09-02 Gte Sylvania Inc Photoflash lamp and method of coating same
US4332329A (en) * 1977-10-25 1982-06-01 Ppg Industries, Inc. Implosion coatings
WO1984001856A1 (en) * 1982-11-08 1984-05-10 Charles K Beck Incandescent illuminating device with antifragility coating
US4459506A (en) * 1982-11-08 1984-07-10 Premier Industrial Corporation Incandescent illuminating device with antifragility coating
EP0175333A2 (en) * 1984-09-17 1986-03-26 GTE Products Corporation Electric lamp including a containment coating as part thereof
EP0175333A3 (en) * 1984-09-17 1988-10-19 GTE Products Corporation Electric lamp including a containment coating as part thereof
US5109180A (en) * 1989-12-14 1992-04-28 Phillips Petroleum Company Apparatus providing a shatter-resistant electric lamp
US6501219B1 (en) 1999-07-29 2002-12-31 General Electric Company Shatter-resistant incandescent lamp, silicone coating composition, and method
EP1286190A1 (en) * 2000-04-27 2003-02-26 Tomoegawa Paper Co. Ltd. Optical connection component
EP1286190A4 (en) * 2000-04-27 2005-04-13 Tomoegawa Paper Co Ltd Optical connection component
EP1227512A2 (en) * 2001-01-24 2002-07-31 General Electric Company High pressure halogen filament lamp
EP1227512A3 (en) * 2001-01-24 2003-01-08 General Electric Company High pressure halogen filament lamp
US20040236010A1 (en) * 2001-07-23 2004-11-25 Carter Randall Lee Stabilized polyorganosiloxane composition
US7651642B2 (en) 2001-07-23 2010-01-26 Momentive Performance Materials Inc. Stabilized polyorganosiloxane composition
US20040066653A1 (en) * 2002-10-03 2004-04-08 Star Leader Ltd Light bulbs
EP1411542A2 (en) * 2002-10-03 2004-04-21 Star Leader Limited Light bulb and method of forming it
EP1411542A3 (en) * 2002-10-03 2006-05-31 Star Leader Limited Light bulb and method of forming it
US20080055898A1 (en) * 2006-08-28 2008-03-06 Dm Technology & Energy Inc. Led lamp
US20110095673A1 (en) * 2008-06-30 2011-04-28 Whitford Corporation Shatter containment coating

Also Published As

Publication number Publication date
AU4417572A (en) 1974-01-10
ZA724522B (en) 1973-03-28
CA959916A (en) 1974-12-24

Similar Documents

Publication Publication Date Title
US3715232A (en) Shatter-resistant incandescent lamp
US3798491A (en) Rounded end halogen lamp with spiral exhaust tube and method of manufacutre
GB2161320A (en) Cathode-ray tube having antistatic silicate glare-reducing coating
US3635751A (en) Lithium silicate glare-reducing coating and method of fabrication on a glass surface
GB909621A (en) Aperture fluorescent lamp
US2810660A (en) Diffusing reflecting coating and method of preparing same
US4287231A (en) Method of spray-reflectorizing electric lamp envelopes
US4288713A (en) Lamp having opaque coating
US6538364B1 (en) Light diffusing coating for exterior bulb surfaces
US2918595A (en) Coating composition for electric lamps
EP1371084A1 (en) Cadmium-free amber automotive lamp
US2069713A (en) Electric lamp for producing short wave length radiation
US3067351A (en) Aperture fluorescent lamp
US2901646A (en) High pressure mercury vapor lamp and method
US2785327A (en) Electric discharge lamp with phosphorcoated rhodium reflector
US2840490A (en) Lamp envelope coating and method of applying
US2181291A (en) Reflector bulb lamp
US2639999A (en) Method of forming a transparent reflection reducing coating on glass and the articleresulting therefrom
CA1220505A (en) Tungsten-halogen electric lamp with permeable means closing an outer envelope
US2960414A (en) Method of providing an electric lamp envelope with a non-uniform light-diffusing coating
US2970928A (en) Light-diffusing glass articles and process of preparing same
JPH05151943A (en) Electrodeless low-voltage sodium-vapor discharge lamp
US1638369A (en) Colored incandescent-lamp bulb
US2245137A (en) Glass product and method of making the same
EP0212683B1 (en) Electric lamp