US3699973A - Film covering for apertured smoking product wrapper - Google Patents

Film covering for apertured smoking product wrapper Download PDF

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Publication number
US3699973A
US3699973A US3699973DA US3699973A US 3699973 A US3699973 A US 3699973A US 3699973D A US3699973D A US 3699973DA US 3699973 A US3699973 A US 3699973A
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Prior art keywords
film
wrapper
apertures
cigarette
degradation
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Ronald A Tamol
Leo F Meyer
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Philip Morris USA Inc
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Philip Morris USA Inc
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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/02Cigars; Cigarettes with special covers

Abstract

The disclosure relates to a film covering for a smoking product wrapper, such as a cigarette wrapper. The wrapper is either porous, or is deliberately perforated with vents or apertures. These openings or vents are covered with a polymeric film that has been submitted to a degradation operation. The degradation is electrically produced, for example, by irradiation. The degradation expedites the removal of film over the apertures by smoke components so that air is permitted to dilute the smoke during the later stages of smoking.

Description

United States Patent Tamol et al.

[ Oct. 24, 1972 [54] FILM COVERING FOR APERTURED SMOKING PRODUCT WRAPPER [72] Inventors: Ronald A. Tamol; Leo F. Meyer,

21] Appl. No.2 160,083

[52] US. Cl. ..l31/15 B', 131/9 [51] Int. Cl. ..A24d 1/02, D2lh 5/16 [58] Field of Search ..13l/l7, 2, 9,15, 8,'l40144 [56] References Cited UNITED STATES PATENTS 3,473,535 10/1969 Stahly ..l3l/l5 B 3,526,904 9/1970 Tamol..... 131/15 B Primary Examiner-Melvin D. Rein Attorney-Elmer R. Helferich et al.

[57] ABSTRACT The disclosure relates to a film covering for a smoking I product wrapper, such as a cigarette wrapper. The

wrapper is either porous, or is deliberately perforated with vents or apertures. These openings or vents are covered with a polymeric film that has been submitted to a degradation operation. The degradation is electrically produced, for example, by irradiation. The degradation expedites the removal of film over the apertures by smoke components so that air is permitted to dilute the smoke during the later stages of smoking.

6 Claims, No Drawings FILM COVERING FOR APERTURED SMOKING PRODUCT WRAPPER BACKGROUND OF THE INVENTION It has been known that the amount of smoke delivered to the smoker of a cigarette can be lowered, without increasing the resistance-to-draw of the cigarette, by increasing the proportion of air which is drawn in with the smoke behind the burning coal. It is also known that additional air can be provided with the smoke by using a very porous paper as the wrapper for the tobacco or by making perforations. in the paper. In this way a greater proportion of the combustion products are dissipated to the atmosphere in the intervals between puffing. Cigarettes have also been made wherein ventilation holes have been included in the paper or in the overtipping surrounding the filter plug of a filter cigarette. In addition, various methods have been described for the smoker to select the degree of ventilation before smoking.

None of the above-described methods have been completely satisfactory, however. Cigarettes which have been ventilated to any significant degree have been characterized by many smokers as being thin, tastelessb or not satisfying.

Among the various proposals made to provide a degree of ventilation may be mentioned a patent to Swain, U.S. Pat. No. 2,754,828 disclosing the use of covered apertures in a non-combustible cigarette sheet, the covering over the apertures being combustible and thus providing for heat-opening of the apertures during the burning of the tobacco. The essential purpose of this patent is to supplysufficient air through the apertures to support combustion when they are opened by the heat of burning tobacco.

A patent to Figge, US, Pat. No. 2,992,647, also teaches the use of a perforated or vented cigarette wrapper, with the apertures being closed with a sealing material selected to melt or sublime at low temperatures but actually a short distance in advance of the burning area, the patentees purpose and objective being to lower the combustion temperature of the burning cigarette with air intake through the apertures upon the approach of the hot coal to the vent holes. Figge, therefore, selected sealants that would melt or sublime close to the burning area, mentioning polyethylene or cellulose sealant compounds, that is said to dissipate at 50 to 100 C. but also mentions monosodium phosphate mono-hydrate that probably decomposes at about 200 C. p

More recently, patents dealing with film covered apertured cigarette wrappers issued as Tamol U.S. Pat.

Nos. 3,511,247 and 3,526,904. The earlier patent teaches the use of a white cellular thermoplastic resin having microscopic voids throughout covering the apertures. The patent indicates that such a film permits improved opening of the holes by heat and at a much greater distance from the coal in the cigarette, and in addition, the white opacity changes to permit the smoker to see the vent holes being opened. The later patent stresses the use of a water-soluble polymeric material covering the apertures and designed to'be opened by smoke components, mainly the moisture in the smoke, when the cigarette is burned. Here also the psychological effect is mentioned in seeing the vent holes opened during the smoking of the cigarette. How

ever, with respect to both of these disclosures, the holes would'not always open or opened ineffectively under conditions of use. To approach the desired objectives in Tamol, a critical feature was to select the proper film thickness for the particular wrapper thickness and the tobacco used and to avoid any variations of the polymer film to insure the holes would open in the prescribed manner. I

The present invention is an improvement over these prior disclosures in that while a polymeric film'is used to cover the apertures of cigarette wrappers which eventually is opened to admit air after a period of smoking, the film is specifically treated and modified in its structure after it is applied to the wrapper, giving it characteristics that substantially expedite and insure the'removal of the film'by the smoke action, regardless of the film thickness or the type of wrapper or the tobacco used. I

SUMMARY OF THE INVENTION The present invention relates to a smoking product, and more particularly to a cigarette or other smoking article utilizing a combustible wrapper. The wrapper is normally porous or specifically provided with apertures, these being covered by a degradable polymeric film. Degradation of the film produces partial chain scission thereby hastening and facilitating the removal of the film over the apertures by smoke components when the tobacco is smoked. The degradation of the film is carried out by electrical irradiation or equivalent energy treatment, for example, using ultrasonic energy, which effects a degradation of the polymeric film.

DESCRIPTION OF THE INVENTION The present invention relates to an apertured wrapper for a tobacco product such as a cigarette, and more particularly to a specifically treated film used to cover the wrapper and the pores or apertures therein.

It is an object of the present invention to obtain a controlled dilution of the smoke of a cigarette or the like with air admitted through apertures opened by the smoke of the burning tobacco. v

It is a further object of the present invention to provide a film coating over wrapper apertures so designed as to permit its easy removal by smoke components as well as byheat of the coal.

It is a still further object of the invention to make possible a reduction in the delivery per puff after early puffs and also in total delivery.

These and other objectives will become evident in the following description of the invention.

The objects of the present invention may be realized by treating a cigarette wrapper or other combustible tobacco wrapper having spaced openings or apertures with a synthetic polymeric material capable of forming a thin but continuous film over the wrapper when dry. After the film has solidified, the apertured wrapper with the film overlay is then submitted to a degradation operation to cause at least partial chain scission of the polymeric film. The resulting degraded film is then capable of quick breakdown by smoke components during the smoking operation, thereby providing the necessary openings for ventilation and smoke dilution at the time it is most desired.

Any polymeric or resinous material capable of forming a continuous, thin, degradable film on a tobacco wrapper and that does not produce toxic components when the wrapper is burned in smoking may be used. A preferred material is one having the necessary characteristic of being able to form a continuous film without breaks when spread thin, that is, when spread on the wrapper to a thickness from 5 to 15 microns.

Polymeric substances that may be used for this purpose are polyalkylene oxides, i.e., polyethylene or where x is an integer of about 1,600 to about 120,000, preferably representing an integer of about 3,400 to about 13,600. The polymer may be prepared by known methods, forv example, as described in U. S. Pat. No. 3,526,904. A particularly suitable polymeric material is sold by Carbide and Carbon Chemicals Corp. under the trade name Polyox. Resin grades are usually assigned with grades N-80, and N-750 and N-3000 representing the particular molecular weights of the resin, name- 1y, materials of 150,000 mol. wt., and 300,000 mol. wt., and 600,000 mol. wt., respectively, being preferred.

The above mentioned polymers may be used by themselves or may be modified with plasticizers, emulsifiers, or non-ionic surfactants or other additives to improve the coating action or the type of coating, or merely for ease in applying the polymer coating to the wrapper. One type of modified polymeric resin that is preferred is the above-described Polyox polyethylene oxide having a molecular weight in the general range mentioned above to which has been added from 2 to percent by weight of a nonylphenoxy polyethylene oxide of 800 to 2,000 molecular weight as a non-ionic surfactant or plasticizer. Compositions of this nature are sold under the trade name Tergitol by Carbide and Carbon Chemicals Co.

The process of the invention is carried out by dispersing or solubilizing the polymeric material in an inert organic liquid or solvent for the polymer with or without additives and the solution or dispersion is then applied to the perforated wrapper material by any known coating procedure capable of producing an even continuous coating or thin layer on a relatively thin wrapper base. One coating method is by knifecoating the coating solution on to the perforated wrapper. Another method utilizes-roller coating. The wrapper itself is preferably the usual thin cigarette paper having pores similar in size and number as described in Tamol, U.S. Pat. No. 3,526,904 or Figge,

U.S. Pat. No. 2,993,647 to which reference had previously been made. However, cigarette wrappers having about 150-200 pores per inch with pore sizes of about 0.005 to about 0.01 inch produce effective results.

After the coating is applied over the perforated wrapper, it is dried either under atmospheric condigamma ray generator, or an ultraviolet energy source,

i.e., a, mercury vapor or quartz ultraviolet lamp. Degradation may also be carried out utilizing mechanical energy by means of an ultrasonic generator. Actually, any device may be used that is capable of generating radiant or mechanical energy of an intensity sufficient to degrade the polymeric film. The most preferred method of degradation by irradiation, however, is the use of an electrical discharge produced by a Van de Graaff generator. With this apparatus, the

amount of exposure can be controlled to give a desireddegree of degradation which will leave the film intact but removable by smoke at a rate determined by the exposure.

ln utilizing the Van de Graaff generator, the perforated wrapper having a film of about 5 to 15 microns thick is exposed to electronic discharge, the generator being operated to produce an irradiation dosage range of about 0.02 to 1.0 megarad per gram weight, and preferably from 0.1 to 1.0 megarads per gram weight of film.

The effect produced by the described irradiation procedure is believed to result in chain scission of at least a portion of the polymeric film thereby facilitating the breakdown of the film and the opening of the apertures when the tobacco is smoked as to provide a nearly level total particulate matter (TPM) delivery throughout the smoking period.

The following example is illustrative.

EXAMPLE 1 A 10 g. portion of Polyox N-750 polyethylene oxide (molecular weight 300,000) was dispersed in 30 ml. of petroleum naptha and ml. of ethylene chloride was added together with 0.5 g. of Tergital NP-40 non-ionic surfactant (Carbide and Carbon Chemicals Co.) and the mixture was rolled overnight to complete the solution. This solution was knife-coated on cigarette paperperforated with 0.010 X 0.014 inch holes, 154 per inch of length, and dried, forming a film of about 10 to 12 microns thick.

The coated paper was exposed to varying dosages (see Table I) of high energy electrons from a Van de Graaff generator. Cigarettes with 20 mm. cellulose acetate filters, 65mm. rods were made from these wrappers and a commercial filler, and cigarettes for controls were made correspondingly with unperforated wrapper which had been irradiated at the same levels.

The results of smoking these cigarettes by machine with measurement of TPM delivery puff-by-puff are shown in Table l. The method used was that described by Wartman, Coghill, and Harlow, Analytical Chem. 31, pp. 1705-1709 (1958) and the machine used for measuring TPM puff-by-puff is that disclosed by W. F Mutter in the US. Pat. No. 3,433,054, granted Mar. 18, 1969.

It is judged that 0.1 megarad dosage of the coated 5 oxide polymer has a molecular weight of about 150,000

to about 600,000.

3. The product of claim 1, in which the polymeric film has a thickness of about 5 to 15 microns.

4. The process comprising coating a cigarette perforated wrapper is sufficient to facilitate opening of wrapper or the like having spaced apertures therein holes to provide a nearly level TPM delivery throughout thesmoking, as compared to an unirradiated wrapper shown in the last column. It will also be noted from the Table that there was increasing degradation with increasing irradiation dose. lr'radiation at 1.0 megarad resulted in delivery at a very low level throughout. This level of irradiation would be indicated for thicker films or films of higher molecular with a polyethylene oxide film of 5 to microns thick, drying said film to form a thin, continuous coating over the wrapper and apertures, drying said coating and then submitting said coated wrapper to the electrical 15 discharge of a Van de Graaff generator to cause 5. The process of claim 4, in which'the film is exposed to an irradiation dosage range of 0.02 to 1.0

weight mes xedsr ra iiueishtifi m...

TABLE I Cigarette v Number 1 Control Number 2 Control Number 3 Control Number 4 Control Coating. PerL. 750, N0npert., Perf., 750, Nonperf., Perf., 750, Nonperf., Perri, 750, Nonperf., Number 5, 5% Terg. none 5% Terg. none 5% Terg. none 5% Terg. none Peri, 750, 5% Terg.

Irradiation dosage, megarad 0. 1 0. 1 0.3 0.3 0. 6 0.6 1. 0 1. 0 None TPM Pufi:

Number 1 .3 2 1. 0 1. 0 0. 6 1. 4 0.05 1. 0 1.1 Number 2.-- 1.7 1.6 1.3 1.6 0.9 1.8 0.2 1.5 1.2 Number3 1. 9 1. 7 1. 5 1.7 0.9 1. 9 0.2 1.5 1.8 Number 4 1. 8 1. 9 1. 4 1. 9 1. 0 2. 0 0. 3 1. 7 2. 0 Number 5 1.6 2. 1 1. 1 2. 2 0.9 2. 3 0. 3 2. 0 2. 0 Number 6..- 1. 5 2. 3 0. 9 2. 3 0. 5 2. 4 0. 2 2. 1 1. 9 Number 7 1. 8 5 1 2. 3 0. 6 2. 7 0. 1 2. 3 2, 0 Number 3 1. 8 2. 7 1. 2 2. 6 0. 7 3. 2 0.3 2. 7 2.1 Number 9- 2.0 3.8 1.2 3.1 0.9 3.3 0.5 2.9 2.4 Number 10 .3 .4 3.0 1.2 0.6 3.2 2,5

*Coatlng750 denotes Polyox N-750 grade material with molecular weight-300,000.

Tergitol-Tergitol NP-40.

The invention that is claimed is: 1. A cigarette wrapper or the like comprising a com- 6. The process of claim {Ya which the film is degraded by irradiation in a dosage range from about bustile material having spaced apertures thereinand a 0.1 to 1.0 megarad per gram weight of film.

Claims (5)

  1. 2. The product of claim 1, in which the polyethylene oxide polymer has a molecular weight of about 150,000 to about 600,000.
  2. 3. The product of claim 1, in which the polymeric film has a thickness of about 5 to 15 microns.
  3. 4. The process comprising coating a cigarette wrapper or the like having spaced apertures therein with a polyethylene oxide film of 5 to 15 microns thick, dryiNg said film to form a thin, continuous coating over the wrapper and apertures, drying said coating and then submitting said coated wrapper to the electrical discharge of a Van de Graaff generator to cause degradation of the polymeric film.
  4. 5. The process of claim 4, in which the film is exposed to an irradiation dosage range of 0.02 to 1.0 megarads per gram weight of film.
  5. 6. The process of claim 4, in which the film is degraded by irradiation in a dosage range from about 0.1 to 1.0 megarad per gram weight of film.
US3699973D 1971-07-06 1971-07-06 Film covering for apertured smoking product wrapper Expired - Lifetime US3699973A (en)

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Cited By (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4648413A (en) * 1984-03-07 1987-03-10 Saintsing Barry L Adjustable-delivery cigarette
EP0231664A1 (en) * 1986-01-07 1987-08-12 Gallaher Limited Smoking rod wrappers and compositions for their production
WO1988001478A1 (en) * 1986-08-27 1988-03-10 Gallaher Limited Smoking rod wrapper and compositions for their production
US4924888A (en) * 1987-05-15 1990-05-15 R. J. Reynolds Tobacco Company Smoking article
US4942888A (en) * 1989-01-18 1990-07-24 R. J. Reynolds Tobacco Company Cigarette
US5060675A (en) * 1990-02-06 1991-10-29 R. J. Reynolds Tobacco Company Cigarette and paper wrapper therefor
US5074321A (en) * 1989-09-29 1991-12-24 R. J. Reynolds Tobacco Company Cigarette
US5092353A (en) * 1989-01-18 1992-03-03 R. J. Reynolds Tobacco Company Cigarette
US5101839A (en) * 1990-08-15 1992-04-07 R. J. Reynolds Tobacco Company Cigarette and smokable filler material therefor
US5105836A (en) * 1989-09-29 1992-04-21 R. J. Reynolds Tobacco Company Cigarette and smokable filler material therefor
US5129408A (en) * 1990-08-15 1992-07-14 R. J. Reynolds Tobacco Company Cigarette and smokable filler material therefor
US5396911A (en) * 1990-08-15 1995-03-14 R. J. Reynolds Tobacco Company Substrate material for smoking articles
US5415186A (en) * 1990-08-15 1995-05-16 R. J. Reynolds Tobacco Company Substrates material for smoking articles
WO2003015543A1 (en) * 2001-08-13 2003-02-27 Miquel Y Costas & Miquel, S.A. Method of preparing paper for self-extinguishing cigarettes
US20030089377A1 (en) * 2001-11-15 2003-05-15 Mohammad Hajaligol Cigarette paper having heat-degradable filler particles, and cigarette comprising a cigarette paper wrapper having heat-degradable filler particles
US20030131860A1 (en) * 2001-08-14 2003-07-17 Ashcraft Charles Ray Wrapping materials for smoking articles
US20030136420A1 (en) * 2002-01-23 2003-07-24 Schweitzer-Mauduit International, Inc. Smoking articles with reduced ignition proclivity characteristics
US6725867B2 (en) 2000-11-13 2004-04-27 Schweitzer-Mauduit International, Inc. Process for producing smoking articles with reduced ignition proclivity characteristics and products made according to same
US20040099280A1 (en) * 2002-11-25 2004-05-27 Stokes Cynthia Stewart Wrapping materials for smoking articles
US20040099279A1 (en) * 2002-11-25 2004-05-27 Chapman Paul Stuart Wrapping materials for smoking articles
US20050005947A1 (en) * 2003-07-11 2005-01-13 Schweitzer-Mauduit International, Inc. Smoking articles having reduced carbon monoxide delivery
US20050016556A1 (en) * 2001-08-14 2005-01-27 Ashcraft Charles Ray Wrapping materials for smoking articles
US20090120450A1 (en) * 2007-07-03 2009-05-14 Schweitzer-Mauduit International, Inc. Smoking Articles Having Reduced Ignition Proclivity Characteristics
US20090223529A1 (en) * 2008-02-22 2009-09-10 Schweitzer-Mauduit International, Inc. Treated Areas on a Wrapper For Reducing the Ignition Proclivity Characteristics of a Smoking Article
US8151806B2 (en) 2005-02-07 2012-04-10 Schweitzer-Mauduit International, Inc. Smoking articles having reduced analyte levels and process for making same
US8701682B2 (en) 2009-07-30 2014-04-22 Philip Morris Usa Inc. Banded paper, smoking article and method
US8707967B2 (en) 2006-03-31 2014-04-29 Philip Morris Usa Inc. Banded papers, smoking articles and methods
US8869805B2 (en) 2006-06-01 2014-10-28 Schweitzer-Mauduit International, Inc. Free air burning smoking articles with reduced ignition proclivity characteristics
US9149068B2 (en) 2012-10-11 2015-10-06 Schweitzer-Mauduit International, Inc. Wrapper having reduced ignition proclivity characteristics
US9302522B2 (en) 2010-12-13 2016-04-05 Altria Client Services Llc Process of preparing printing solution and making patterned cigarette wrappers
US9668516B2 (en) 2012-05-16 2017-06-06 Altria Client Services Llc Banded cigarette wrapper with opened-area bands

Cited By (62)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4648413A (en) * 1984-03-07 1987-03-10 Saintsing Barry L Adjustable-delivery cigarette
EP0231664A1 (en) * 1986-01-07 1987-08-12 Gallaher Limited Smoking rod wrappers and compositions for their production
WO1988001478A1 (en) * 1986-08-27 1988-03-10 Gallaher Limited Smoking rod wrapper and compositions for their production
US4889145A (en) * 1986-08-27 1989-12-26 Gallagher Limited Smoking rod wrapper and compositions for their production
US4924888A (en) * 1987-05-15 1990-05-15 R. J. Reynolds Tobacco Company Smoking article
US5092353A (en) * 1989-01-18 1992-03-03 R. J. Reynolds Tobacco Company Cigarette
US4942888A (en) * 1989-01-18 1990-07-24 R. J. Reynolds Tobacco Company Cigarette
US5105836A (en) * 1989-09-29 1992-04-21 R. J. Reynolds Tobacco Company Cigarette and smokable filler material therefor
US5074321A (en) * 1989-09-29 1991-12-24 R. J. Reynolds Tobacco Company Cigarette
US5060675A (en) * 1990-02-06 1991-10-29 R. J. Reynolds Tobacco Company Cigarette and paper wrapper therefor
US5101839A (en) * 1990-08-15 1992-04-07 R. J. Reynolds Tobacco Company Cigarette and smokable filler material therefor
US5129408A (en) * 1990-08-15 1992-07-14 R. J. Reynolds Tobacco Company Cigarette and smokable filler material therefor
US5396911A (en) * 1990-08-15 1995-03-14 R. J. Reynolds Tobacco Company Substrate material for smoking articles
US5415186A (en) * 1990-08-15 1995-05-16 R. J. Reynolds Tobacco Company Substrates material for smoking articles
US5598868A (en) * 1990-08-15 1997-02-04 R. J. Reynolds Tobacco Company Cigarette and smokable filler material therefor material for use in smoking articles
US6725867B2 (en) 2000-11-13 2004-04-27 Schweitzer-Mauduit International, Inc. Process for producing smoking articles with reduced ignition proclivity characteristics and products made according to same
US20040182407A1 (en) * 2000-11-13 2004-09-23 Peterson Richard M. Process for producing smoking articles with reduced ignition proclivity characteristics and products made according to same
US10258078B2 (en) 2000-11-13 2019-04-16 Schweitzer-Mauduit International, Inc. Process for producing smoking articles with reduced ignition proclivity characteristics and products made according to same
WO2003015543A1 (en) * 2001-08-13 2003-02-27 Miquel Y Costas & Miquel, S.A. Method of preparing paper for self-extinguishing cigarettes
US20050241659A1 (en) * 2001-08-14 2005-11-03 R.J. Reynolds Tobacco Company Wrapping materials for smoking articles
US7677256B2 (en) 2001-08-14 2010-03-16 R.J. Reynolds Tobacco Company Wrapping materials for smoking articles
US7237559B2 (en) 2001-08-14 2007-07-03 R.J. Reynolds Tobacco Company Wrapping materials for smoking articles
US20060011207A1 (en) * 2001-08-14 2006-01-19 R.J. Reynolds Tobacco Company Wrapping materials for smoking articles
US20030131860A1 (en) * 2001-08-14 2003-07-17 Ashcraft Charles Ray Wrapping materials for smoking articles
US20060005847A1 (en) * 2001-08-14 2006-01-12 R.J. Reynolds Tobacco Company Wrapping materials for smoking articles
US6929013B2 (en) 2001-08-14 2005-08-16 R. J. Reynolds Tobacco Company Wrapping materials for smoking articles
US20050016556A1 (en) * 2001-08-14 2005-01-27 Ashcraft Charles Ray Wrapping materials for smoking articles
US20050241660A1 (en) * 2001-08-14 2005-11-03 R.J. Reynolds Tobacco Company Wrapping materials for smoking articles
US20030089377A1 (en) * 2001-11-15 2003-05-15 Mohammad Hajaligol Cigarette paper having heat-degradable filler particles, and cigarette comprising a cigarette paper wrapper having heat-degradable filler particles
US6817365B2 (en) 2001-11-15 2004-11-16 Philip Morris Usa Inc. Cigarette paper having heat-degradable filler particles, and cigarette comprising a cigarette paper wrapper having heat-degradable filler particles
US10028525B2 (en) 2002-01-23 2018-07-24 Schweitzer-Mauduit International, Inc. Smoking articles with reduced ignition proclivity characteristics
US8863757B2 (en) 2002-01-23 2014-10-21 Schweitzer-Mauduit International, Inc. Smoking articles with reduced ignition proclivity characteristics
US6779530B2 (en) 2002-01-23 2004-08-24 Schweitzer-Mauduit International, Inc. Smoking articles with reduced ignition proclivity characteristics
US20030136420A1 (en) * 2002-01-23 2003-07-24 Schweitzer-Mauduit International, Inc. Smoking articles with reduced ignition proclivity characteristics
US20060124146A1 (en) * 2002-11-25 2006-06-15 R.J. Reynolds Tobacco Company Wrapping materials for smoking articles
US20040099279A1 (en) * 2002-11-25 2004-05-27 Chapman Paul Stuart Wrapping materials for smoking articles
US6997190B2 (en) 2002-11-25 2006-02-14 R.J. Reynolds Tobacco Company Wrapping materials for smoking articles
US6976493B2 (en) 2002-11-25 2005-12-20 R.J. Reynolds Tobacco Company Wrapping materials for smoking articles
US20040099280A1 (en) * 2002-11-25 2004-05-27 Stokes Cynthia Stewart Wrapping materials for smoking articles
US20090283104A1 (en) * 2003-07-11 2009-11-19 Hampl Jr Vladimir Smoking Articles Having Reduced Carbon Monoxide Delivery
US8353301B2 (en) 2003-07-11 2013-01-15 Schweitzer-Mauduit International, Inc. Smoking articles having reduced carbon monoxide delivery
US8443812B2 (en) 2003-07-11 2013-05-21 Schweitzer-Mauduit International, Inc. Smoking articles having reduced carbon monoxide delivery
US20050005947A1 (en) * 2003-07-11 2005-01-13 Schweitzer-Mauduit International, Inc. Smoking articles having reduced carbon monoxide delivery
US8151806B2 (en) 2005-02-07 2012-04-10 Schweitzer-Mauduit International, Inc. Smoking articles having reduced analyte levels and process for making same
US8905043B2 (en) 2006-03-31 2014-12-09 Philip Morris Usa Inc. Banded papers, smoking articles and methods
US8707967B2 (en) 2006-03-31 2014-04-29 Philip Morris Usa Inc. Banded papers, smoking articles and methods
US9161570B2 (en) 2006-03-31 2015-10-20 Philip Morris Usa Inc. Banded papers, smoking articles and methods
US8939156B2 (en) 2006-03-31 2015-01-27 Philip Morris Usa Inc. Banded papers, smoking articles and methods
US8844540B2 (en) 2006-03-31 2014-09-30 Philip Morris Usa Inc. Banded papers, smoking articles and methods
US10028524B2 (en) 2006-03-31 2018-07-24 Philip Morris Usa Inc. Banded papers, smoking articles and methods
US8925556B2 (en) 2006-03-31 2015-01-06 Philip Morris Usa Inc. Banded papers, smoking articles and methods
US8733370B2 (en) 2006-03-31 2014-05-27 Philip Morris Usa Inc. Banded papers, smoking articles and methods
US8833377B2 (en) 2006-03-31 2014-09-16 Philip Morris Usa Inc. Banded papers, smoking articles and methods
US8869805B2 (en) 2006-06-01 2014-10-28 Schweitzer-Mauduit International, Inc. Free air burning smoking articles with reduced ignition proclivity characteristics
US20090120450A1 (en) * 2007-07-03 2009-05-14 Schweitzer-Mauduit International, Inc. Smoking Articles Having Reduced Ignition Proclivity Characteristics
US20090223529A1 (en) * 2008-02-22 2009-09-10 Schweitzer-Mauduit International, Inc. Treated Areas on a Wrapper For Reducing the Ignition Proclivity Characteristics of a Smoking Article
US8646464B2 (en) 2008-02-22 2014-02-11 Schweitzer-Mauduit International, Inc. Treated areas on a wrapper for reducing the ignition proclivity characteristics of a smoking article
US8701682B2 (en) 2009-07-30 2014-04-22 Philip Morris Usa Inc. Banded paper, smoking article and method
US9302522B2 (en) 2010-12-13 2016-04-05 Altria Client Services Llc Process of preparing printing solution and making patterned cigarette wrappers
US9668516B2 (en) 2012-05-16 2017-06-06 Altria Client Services Llc Banded cigarette wrapper with opened-area bands
US9247769B2 (en) 2012-10-11 2016-02-02 Schweitzer-Mauduit International, Inc. Wrapper having reduced ignition proclivity characteristics
US9149068B2 (en) 2012-10-11 2015-10-06 Schweitzer-Mauduit International, Inc. Wrapper having reduced ignition proclivity characteristics

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