US3696851A

US3696851A - Chemical compounds and compositions

Info

Publication number: US3696851A
Application number: US6309A
Authority: US
Inventors: Donald R Randell
Original assignee: Geigy Chemical Corp
Current assignee: Novartis Corp
Priority date: 1964-02-11
Filing date: 1970-01-27
Publication date: 1972-10-10
Anticipated expiration: 1989-10-10

Abstract

Chemical compositions are composed of synthetic lubricant and antioxidant compound of the formula:

Description

United States Patent [15] 3, Randell 1 51 Oct. 10, 1972 CHEMICAL COMPOUNDS AND [56] References Cited COMPOSITIONS m 72 1 t Do ald R R (111 s k E EDSTATES PATENTS e t n or e pm 318,410 5/1885 Armstrong ..252/56 x 2,009,480 7/1935 Craig ..252/50 x [73] Asslgnee: Geigy Chemical Corporation, Ard- 2,530,769 11/1950 Hollis ..252/50X s1ey,N.Y. 2,971,912 2/1961 Elliott at al. ..252/51.5 x 3,004,916 10/1961 Ertelt ..252/50 x [22] 3,011,976 12/1961 Cyba ..252/50 x 21 App1.No.: 6,309 3,052,632 9/1962 Loeffler ..252/515 3,210,281 10/1965 Peeler ..252/50 Related pp e Data 3,282, 40 1 l/1966 Foster et a1 .,....,..,252/50 [62] Division of set. No. 753,321, April 26, 1968,

Pat. No. 3,536,706, which is a division of Ser. No. 526,401, Feb. 10, 1966, Pat. No. 3,414,618, which is a division of Ser. No. 431,709, Feb. 10, 1965, abandoned.

Foreign Application Priority Data Field of Search..252/50, 51.5, 56 S, 401, 51.5 A

Primary Examiner-Daniel E. Wyman Assistant Examiner-W. Cannon Attorney-Wenderoth, Lind & Ponack [5 7] ABSTRACT Chemical compositions are composed of synthetic lubricant and antioxidant compound of the formula:

wherein A and B are the same or different and each is an aryl group, and one of the aryl group A and B contains a tertiary alkyl substituent group having from four to 12 carbon atoms.

7 Claims, No Drawings CHEMICAL COMPOUNDS AND COMPOSITIONS This application is a division of application Ser. No. 753,321, filed April 26, 1968, now US. Pat. No. 3,536,706 dated Oct. 27, 1970, a division of application Ser. No. 526,401, filed Feb. 10, 1966, now U.S. Pat. No. 3,414,618, dated Dec. 3, 1968, which application is in turn a division of application Ser. No. 431,709, filed Feb. 10, 1965, now abandoned.

The present invention relates to synthetic lubricant compositions containing antioxidants.

It is known that dialkylated derivatives of conventional antioxidant systems such as diphenylamine and phenothiazine, and synergistic combinations thereof, may be used as antioxidants in ester-based synthetic lubricants, and that these dialkylated derivatives do not have the disadvantage of bringing about the formation of oil-insoluble products in synthetic lubricants at high temperatures, which is encountered if phenothiazine itself is used. It was found that the requirements of standard test specifications could be met by incorporating dialkylated phenothiazines and dialkylated secondary amines, thus avoiding the so-called phenothiazine dirtiness.

However, with the advent of gas turbine engines required to propel aircraft at greater speeds, has come a demand for lubricants which will function satisfactorily at still higher temperatures, at which lubricant compositions comprising the previously suggested dialkylated compounds do not pass the requirements of standard specification tests. For instance, the requirements of the Pratt and Whitney Type II oxidation-corrosion tests, carried out at 425 or 450 F. for 48 hours cannot be met by lubricants containing dialkylated derivatives of diphenylamine and phenothiazine.

It is an object of the present invention to provide improved compositions of synthetic lubricants containing improved antioxidants.

The present invention also provides a composition which comprises a synthetic lubricant susceptible to oxidative deterioration and as antioxidant; a compound of the formula:

wherein A and B are the same or different and each is an aryl group, and one of the aryl groups A and B contains a tertiary alkyl substituent group having from four to 12 carbon atoms.

The synthetic lubricant is preferably a synthetic lubricant based on one or more organic carboxylic acid esters; intended for use at an operating temperature at or above 400 F. Examples of such synthetic lubricants include lubricants based on a diester of a dibasic acid and a monohydric alcohol, for instance dioctyl sebacate or dinonyl adipate; on a triester of trimethylolpropane and a monobasic acid or mixture of monobasic acids, for instance trimethylolpropane tripelargonate or trimethylolpropane tricaprylate; on a tetraester of pentaerythritol and a monobasic acid or mixture of monobasic acids, for instance pentaerythritol tetracaprylate; or on complex esters derived from monobasic acids, dibasic acids and polyhydric alcohols; or on mixtures thereof.

Each of the aryl groups A and B may be, for example, a benzene or naphthalene nucleus otherwise unsubstituted or containing further substituents, apart from the tertiary alkyl group which forms a substituent in one of the groups A and B; if either or both of the groups A and B is a naphthalene residue, this may be an a or ,8 -naphthyl group. The tertiary alkyl group contains from four to 12 carbon atoms, and may be, for example, tertiary butyl l":l-dimethylethyl), tertiary pentyl (1':l'-dimethylpropyl), tertiary hexyl (l:l'- dimethylbutyl), tertiary octyl 1 l ':3':3"-tetramethylbutyl) or tertiary dodecyl (l:l'z3'3'z5'5-hexamethylhexyl). The tertiary alkyl substituent preferably has a tertiary carbon atom directly attached to the aryl nucleus of which the alkyl group is a substituent.

If the aryl group A or B which contains the essential tertiary alkyl substituent is an unsubstituted or sub stituted phenyl group, the tertiary alkyl group is preferably in the 4-position relative to the carbon atom of the benzene ring directly attached to the nitrogen atom of the secondary amine grouping. If the aryl group A and B which contains the tertiary alkyl substituent is an otherwise unsubstituted or substituted naphthyl group, the tertiary alkyl group is preferably attached in the same or the analogous position as the 4- substituent in a phenyl group. These preferred structures may be represented as follows, wherein R represents the tertiary alkyl group and wherein the aryl nuclei may be otherwise unsubstituted (as shown) or substituted:

aryl-NH- aryl-N H the aryl group in each instance being an unsubstituted or substituted phenyl, a-naphthyl or B-naphthyl group.

Examples of such diarylamines used as antioxidants in the composition of the present invention therefore include:

4-tertiary pentyl-diphenylamine, N-p-tertiary pentyl-phenyla-naphthylamine, N-p-tertiary pentyl-phenyl- B-naphthylamine, 4-p-( l l :3 :3- tetramethylbutyl)-diphenylamine, N-p-( l l :3:3r-tetramethylbutyl)-a-naphthylamine N-p 1 l :3:3-tetramethylbutyl)-phenyl-B naphthylamine, 4-p-( l" l ':3':3:5 ':5'-hexamethy1hexyl)-diphenylamine, N-p( l: 113:3:5:S-hexamethylhexyl)-phenyl-anaphthylamine, N-p-( 1:l:3:3:5:5:-hexamethylhexyl)-B- naphthylamine. -The mono tertiary alkyl diarylamines used as antioxidants in the composition of the present invention are produced, as hereinbefore set forth, for example, by contacting the corresponding diarylamine with a lor 2-alkylene, the total number of carbon atoms in the molecule of the alkylene being from four to 12. The reaction with the alkylene is carried out under the conditions hereinbefore disclosed and advantageously in the presence of a F riedel-Crafts catalyst, for instance in the presence of aluminum chloride.

The compositions of the invention may, if desired, also contain other constituents. For instance one or more load carrying additives, viscosity index improvers or pourpoint depressants of conventional type for lubricants may be present. If desired, a metal deactivator may also be present in the composition: for example, benzotriazole or a copper-protecting derivative of benzotriazole may be present, preferably in a concentration within the range of from 0.01 to 1 percent by weight based on the total weight of the composition.

The proportion of antioxidant present in the compositions of the invention can be varied within wide limits. The compositions of the present invention may, for instance, contain from 0.1 to percent by weight of antioxidant and preferably from 1.5 to 4 percent by weight based on the total weight of the composition.

The following Examples further illustrate the present invention. Parts by weight shown therein bear the same relation to parts by volume as do kilograms to liters.

Percentages shown are expressed by weight unless otherwise stated.

EXAMPLE 1 A. 169.2 parts by weight of diphenylamine were heated with 140.3 parts by weight of di-isobutylene (a mixture of 75 percent of 2:4:4z-trimethylpentene-l and 25 percent of 2:4:4-trimethylpentene-2) and with 2.2 parts by weight of anhydrous aluminum chloride for hours while maintaining the temperature within the range of from 108 to 146 C.

The product was a mixture of 4- and 4:4'-tertiary octyl diphenylamines with unreacted diphenylamine. The desired 4-tertiary octyl diphenylamine was separated from the other constituents of the reaction product by fractional distillation and was recrystallized from aqueous ethanol.

The 4-tertiary octyl diphenylamine thus obtained had melting point 48 to 49 C. and boiling point 150 to 154C. at 0.22 millimeter of mercury pressure. The conversion achieved was 55 percent.

EXAMPLE 2 A. 657 parts by weight of N-phenyl-a naphthylamine were heated with 673 parts by weight of di-isobutylene (having the same composition as that used in Example 1), and 6.6 parts by weight of anhydrous aluminum chloride for 26 hours, while maintaining the temperature at 108 to 136C.

The product was N-p-tertiary octyl-phenyl-anaphthylamine, having melting point 76 to 77C. and the following elemental analysis:

Found: Calculated: (C l- N carbon 86.94% 86.96% hydrogen 8.82% 8.82% nitrogen 4.05% 4.23%

The yield was 62 percent theoretical.

EXAMPLE 3 A. The procedure described as Example 2 was carried out using 219.3 parts by weight of Nphenyl-B naphthylamine instead of the .N-phenyl-anaphthylamine, the reaction conditions being otherwise the same.

The product was N-p-tertiary octyl-phenyl-B- naphthylamine, having melting point 126 C. and the following elemental analysis:

Found: Calculated: (C H N) carbon 87.18% 86.96% hydrogen 8.84% 8.82% nitrogen 4.40% 4.23%

The yield was 53 percent theoretical.

EXAMPLE 4 On incorporating 4-tertiary octyl diphenylamine prepared as described in Example 1 into an ester-based synthetic lubricant, the product was found to be an effective antioxidant.

EXAMPLE 5 On incorporating N-p-tertiary octyl-phenyl-anaphthylamine prepared as described in Example 2 into an ester-based synthetic lubricant, the product was found to be an effective antioxidant.

EXAMPLE 6 On incorporating N-p-tertiary octyl-phenyl-flnapthylamine prepared as described in Example 3 into an ester-based synthetic lubricant, the product was found to be an effective antioxidant.

EXAMPLE 7 84.6 parts by weight of diphenylamine, 185 parts by weight of tertiary butyl chloride and 23.7 parts by weight of anhydrous aluminum chloride were reacted together as 35 C. for 3 hours and the mixture was then boiled under reflux for 24 hours. Unreacted tertiary butyl chloride was then removed by distillation; the residue was dispersed in toluene and treated with aqueous spdium hydroxide. The solvent was then evaporated off and the residue was fractionally distilled.

4-tertiary butyl diphenylamine was obtained as distillate in the fraction having boiling point range of 130 to 148 C. at 0.35 millimeter of mercury pressure. 4:4- tertiary butyl diphenylamine (having melting point 107 to 108 C) and unreacted diphenylamine were also isolated from the reaction mixture.

The 4-tertiary butyl diphenylamine obtained was purified by crystallization and recrystallization from aqueous ethanol. The product had melting point 67 to 68 C.

On incorporating 4-tertiary butyl diphenylamine into an ester-based synthetic lubricant, the product was found to be an effective antioxidant.

EXAMPLE 8 To a mixture of 219.2 parts by weight of N-phenyl-B- naphthylamine and 2.2 parts by weight of anhydrous aluminum chloride were slowly added 140.2 parts by weight of isopentene (consisting mainly of 2-methylbutene-l) over 8 hours while maintaining the temperature of the reaction mixture at to C.

N-pvtertiary pentyl-phenyLB-naphthylamine produced was isolated from the reaction product, after Found: Calculated: (C H N) carbon 87.19% 87.12% hydrogen 8.00% 8.04% nitrogen 4.83% 4.83%

On incorporating into an ester-based synthetic lubricant the product was found to be an effective antioxidant.

EXAMPLE 9 164.4 parts of N-phenyl-fl-naphthylamine were heated to 160 C. with 1.7 parts of anhydrous aluminum chloride for 10 minutes, cooled to 140 C. and iso-butylene gas passed into the mixture until absorption of the gas was complete. The reaction time was approximately 8 hours. The reaction mixture was taken up into toluene and washed with aqueous sodium hydroxide and then water until the washings were neutral. The toluene was distilled off in vacuo and the residue distilled. The fraction boiling point 180 to 182 C/0.3mm. was recrystallized from petroleum ether (boiling point 60 to 80C.) to provide 45 parts (representing a yield of 17.3 percent of the theoretical) of N-p-t-butyl-phenyl-B-naphthylarnine, melting point 77 to 78 C. The product had the following elemental analysis by weight:

Found: Calculated: (C l-l N) carbon 87.00% 87.10% hydrogen 7.81% 7.75% nitrogen 5.18% 5.05%

On incorporating into an ester-based synthetic lubricant, the product was found to be an effective antioxidant.

EXAMPLE l0 ln a similar manner from 164.4 parts of N-phenyl-oznaphthylamine were obtained 100 parts (representing a yield of 48.8 percent of the theoretical) of N-p-t-butylphenyl-a-naphthylamine, melting point 87.5 C. (from petroleum ether boiling point 60 to 80 C.) The product had the following elemental analysis by weight:

Found: Calculated: (C l-l N) carbon 86. 87% 87. 10% hydrogen 7.73% 7.75% nitrogen 4.94% 5.05%

EXAMPLE 1 1 219.3 parts of N-phenyl-a-naphthylamine were heated to 120 C. with 2.2 parts of anhydrous aluminum chloride, cooled to 100C. and 105.3 parts of iso-pentene (Z-methylbutene-l) added over 2.5 hours. To complete the reaction the mixture was refluxed for 3 hours. The reaction mixture was then taken up into toluene, washed with aqueous sodium hydroxide and finally with water until the washings were neutral.

Distillation of the residue after removal of the toluene provided a fraction consisting mainly of unreacted N- phenyl-a-naphthylamine but the residue on recrystallization from methanol provided 69 parts (representing a yield of 23 percent of the theoretical) of N-p-t-pentylphenyl-a-naphthylamine, melting point 71 C. The product had the following elemental analysis by weight:

Found: Calculated: (C I-1 ,14) carbon 86.93% 87.15% hydrogen 8.25% 8.01% nitrogen 4. 79% 4.84%

EXAMPLE 12 Similarly from 438.6 parts of N-phenyLB- naphthylamine were prepared 156.5 parts (representing a yield of 43.7 of the theoretical) of N-p-t-pentylphenyl-B-naphthylamine, melting point 76 C. The product had the following elemental analysis by weight:

Found: Calculated: (C H N) carbon 87.12% 87.15% hydrogen 8.25% 8.01% nitrogen 4. 79% 4.84%

EXAMPLE 13 109.5 parts of N-phenyl-a-naphthylamine and 1.1 parts of anhydrous aluminum chloride were heated together for 10 minutes at 145 C and then 63 parts of Z-methyIpentene-l (propylene dimer) added over 4.5 hours at 130 to 140 C. After this addition the crude reaction product was dissolved in toluene, washed to remove the catalyst and the residue after removal of the toluene distilled to provide 106 parts (representing a yield of percent of the theoretical) of N-p-t hexylphenyl-a-naphthylamine, boiling point 215C/lmm. The product had the following elemental analysis by weight:

Found: Calculated: (C l-l N) carbon 86.75% 87.08% hydrogen 8.63% 8.30% nitrogen 4.41% 4.62%

EXAMPLE 14 Similarly from 109.5 parts of N-phenyl-B- naphthylamine were obtained parts (representing a yield of 56.3 percent of the theoretical) of N-p-t-hexylphenyl-B-naphthylamine, melting point 51 C. The product had the following elemental anflysis by weight:

Found Calculated: (C H N) carbon 87.14% 87.08% hydrogen 8.43% 8.30% nitrogen 4.44% 4.62%

EXAMPLES l and 16 used in the comparative tests described inhibit the production of sludge but cause heavy corrosion of magnesium, as shown hereinafter.

Synthetic ester-based lubricant compositions were 5 prepared into which were incorporated a mono-tertiary EXAMPLES 17 to 19 alk 1 di lamine corn und of th res nt invention y e e Synthetic ester-based lubricant compositions were and sub ected to an oxidation-corrosion test. The base fluid in each of th I sts t th 1 I produced and sub ected to the Pratt & Whitney Type t l t d t was s l oxidation-corrosion test. The base fluid was pen- :323: 3 8 2; a ours taerythritol tetracaprylate and each test was carried out 2 ry at t 8 rate tel-s P for 48 hours at 425F. with dry air at the rate of 5 liters f" m t e Preseflce 0 two Steel. specfmfans hfivmg per hour and in the presence of specimens of magnesi- A inlcghouttlsgde djlargeter and 5/ 16th inch 1ns1de dlameum alloy, aluminum alloy, copper silver and steel ted at Speclficanon 3 To each lubricant sample had been added to propor- To each lPbncam Sample hadfieen added tions of a diarylamine type additive and ben'zotriazole cent by weight of a mono-ternary alkyl-substituted asstated'mTable 1 compound accordance iii/1th the ifrlvefltiofl, based T'ie results of the tests are given to Table 11 which inthe total Welght of the lubricant composition cludes comparisons where no additive or an additive The result of the tests are given 11'] Table In this other than a monoalkylated compound of the present table the final acld Value 15 expressed as mllllgl'ams of invention was present. In the table, the acid value inpotassium hydroxide per gram; the sludge is expressed crease is expressed as milligrams of potassium hydroxas mllllgrams; and the gh Change Of the Steel ide per gram; the sludge is expressed in milligrams; and specimens is expressed as milligrams per square centhe weight change of the specimens as milligrams per timeter. included in the table are the results of comsquare centimeter.

TABLE 11 Percent VlS' cosity increase Acid Weight change of specimens Percent at value Example Additive additive 100 F. increase Sludge Mg alloy Al alloy Cu Ag Steel None 243.2 11.5 21.3 19.s0 +0.03 +0.05 +0.03 +0.03 Phenothiazine. 2.0 30.2 5.8 370.5 +0.14 +0.07 -0.22 +0.18 +0.08 Iminodibenzyl... 5.0 12.0 2.0 294.5 +0.14 +0.00 -0.30 +0.10 n11 Diphenylamine 2.0 35.4 3.8 80.2 -4.15 m1 0.59 +0. 01 ml N-phenyl-a-naphthylamine- 2.0 26.5 3.4 60.9 +0.03 +0.07 1.57 +0.03 +0.04 N-phenyl-B-naphthylamine 2.0 23.9 3.3 20.0 +0.03 nil 0.83 +0.08 +0.06 3:7-di-tertiary octylphenothiazine plus benzo- 4 o triazole 5 i 40.0 5. 01 3.0 -0.41 0. 01 0.02 0.03 0.01 2:8-di-tertiary octyliminodibenzyl plus benzotn z e d5 27.0 3.2 5.8 -3.79 nil -1.09 0.04 0.04 4:4-d1-tertiary octyldiphenylamine plus benzotriazole 5 35.5 3.8 2.2 -3.s3 0.01 +0.44 +0.04 +0.01 1? 4-tertiary octyldiphenylamlne plus benzotriazole..{ 31.5 3.0 3.0 -0.20 0.02 0. 15 0. at +0.01 18 N-p-tertiary octylphenyl-a-naphthylamine plus 3 0 benzotnazole 2 29.0 2.5 1.0 nil nil 0. 10 nil 0.01 19 N-p-tertiary octylphenyl-fl-naphthylamine plus benzotriazole... 27.6 2.0 0.8 0.05 0. 01 0. 16 0. 01 0. 01

parative tests carried out under the same conditions but EXAMPLES 20 to 26 with no additive and with compounds as additives which are other than those of the present invention.

The results in Table 1 demonstrate the ability of the monoalkylated compounds to provide protection to the lubricant oil without the production of oil insolubles Synthetic ester-based lubricant compositions were produced and subjected to the Pratt & Whitney Type ll oxidation-corrosion test. The base fluid was a complex ester of sebacic acid, caprylic acid and trimethylol propane, the complex ester being described and TABLE 1 Percent viscosity increase Final Weight change Percent at acid of steel Example Additive additive 100 F. value Sludge specimens None 31.7 9.0 16 +0.08 +0.07 Phenotbiazine.... 1. 0 l2. 9 3. 7 617 +0. 11 +0. 16 Imlnodibenzyl. 1. 0 4. 4 3. 5 +0. 22 +0. 19 Diphenylamine 1. 0 9. 5 4. 4 343 +0.08 +0.28 Di-tertiary octylphenothiazine 2.0 1 9 8.0 11 +0. 63 +0. 71 N-Phenyl-a-naphthylamine. 1.0 9. 2 4. 5 274 +0. 07 +0. l2 4:4'-tertiary octyldiphenylamine. 2. 0 l9. 4 6. 7 10 +0.65 +0. 15.. N-p-tertiary octylphenylflnaphthylamine 1. 5 17. 0 4. 1 10 +0. 19 +0. 20 16.... N-p-tertiary octylphenybB-naphthylamine 1. 5 8. 8 2.4 1 +0.03 +0. 01

1 Moderate.

9 l claimed in British Pat. No. 971,901. Each test was car- Having thus disclosed the invention, what is claimed ried out for 48 hours at 425F. with dry air at the rate of is: liters per hour and in the presence of specimens of 1. A composition which comprises a synthetic lubrimagnesium alloy, aluminum alloy, copper, silver and cant based on one or more organic carboxylic acid Steel 5 esters intended for use at an operating temperature at To each lubricant sample had been added to proporor above 400 F, and, as antioxidant, a mono tertiary tions of a diarylamine type additive and benzotriazole alkyl substituted compound of the formula as stated in Table IV.

The results of the tests are shown in Table IV which includes comparisons where no additive or an additive other than a monoalkylated compound of the present invention was present. in the table, the acid value inwherein R represents tertiary alkyl of from four to 12 crease is expressed as milligrams of potassium hydroxcarbon atoms and B represents a-naphthyl or ,8-

ide per gram; the sludge is expressed in milligrams; and naphthyl. the weight change of the specimens as milligrams per 2. Acomposition according to claim 1, said composisquare centimeter. tion al so contain i ig benzotn'azole as metal deactivator. TABLE IV Percent Viscosity increase Acid Weight change oi specimens Percent at value Example Additive additive 100 F. increase Sludge Mg alloy Al alloy Cu Ag Steel None 113.0 7.3 10.777 51. 27 +0.05 -0.08 +0.07 0. 14 Phenothiazine-- 2.0 134. 0 2.9 850 +0.02 +0.02 -0.38 +0. 02 +0.09 Diphenylamine 2.0 209.0 2.4 280 0. 02 0. 03 1. 02 1. 01 0. 02 ivig-di-ttzrtiarsl octyl diphenylamine plus 3.0 57.0 2. 2 34 6. 90 -0. 04 0. 62 -0.08 -0. O2

enzo r azo e. .5 Ngp-terttieiry liutyi phenyl-a-naphthylemine plus 2.2 17.3 3.1 3.4 +0. 05 +0.06 0. 07 +0.06 nil enzo r azo e. 0.

21 Nip-tertiary tlwentyl phenyl-a-naphthylamine plus 21.4 1.0 27.7 0. 10 0. 07 0. 15 0. 06 -0.07

e l-Z0 I 8Z0 6. 22 NiJp-terttiary lliexyl phenyl-a-nephthylamlne plus (I: 23.0 0.9 0.6 +0.02 nil 0.09 nil +0. 03

enzo r azo e.

23 Ngp-terttiairy ltllexyl phenyl-a-naphthylemlne plus 20. 7 0.4 4.3 0. 01 nil -0.08 -0. 01 +0. 01

enzo r azo e.

4 Niap-terttielry butyl phenyl-B-naphthylamine plus g 17. 7 0.4 0. 5 +0.05 +0.08 +0.08 +0.07 +0.07

81120 1 all) e.

25 NiJp-terttiary lJentyl phenyl-fl-naphthylamine plus g 18.2 0.5 1.0 +0.01 nil +0.01 0.03 +0.01

enzo r azo e.

26 Np-tertlary hexyl phenyl-[i-naphthylamine plus 3.0 23.8 1.1 2.8 +0. 03 +0.05 +0. 05 +0.06 +0. 01

benzotriazole. 0. 5

The results in Table IV demonstrate the efiectiveness of the monoelkylated diarylamine coumpounds an (1 their superior properties over related comwe eetsaeeqal ylete V.

EXAMPLES 2'] 89.128. 3. A composition according to claim 1, wherein the Synthetic ester-based lubricant compositions were synthetic lubricant is di-2-ethylhexyl sebacate.

produced and subjected to the MIL-L-7808E oxida- 4O 4. A composition according to claim 1, wherein the tion corrosion test. The base fluid was di-Z-ethylhexyl synthetic lubricant is trimethylolpropane tripelarsebacate and each test was carried out for 72 hours at gonate.

375F. with dry air at the rate of 5 liters per hour and in 5. A composition according to claim 1, wherein the the presence of specimens of magnesium alloy, alusynthetic lubricant is pentaerythritol tetracaprylate. minum alloy, copper, silver and steel. 6. A composition according to claim 1, wherein the To each lubricant sample had been added the prosynthetic lubricant is complex ester derived from triportions of a diarylamine type additive as stated in methylolpropane,caprylic acid and sebacic acid.

Table V. 7. A composition according to claim 1, wherein the The results of the tests are given in Table V which inmono tertiary alkyl substituted compound is a member cludes comparisons where no additive or an additive selected from the group consisting of other than a monoalkylated compound of the present N-p-tertiary pentyl-phenyl-a-naphthylamine,

invention was present. in the table, the acid value in- N-per i ry pen yl-phenyl-B-naphthyl mine,

crease is expressed as milligrams of potassium hydrox- N-a-tertiary hexyl-phenyl-a-naphthylamine,

ide per gram; the sludge is expressed in milligrams; and N-a-tertiary hexyl-phenyl-B-naphthylamine,

the weight change of the specimens as milligrams per. N-p-(l:l:3:3-tetramethylbutyl)-phenyl-asquare centimeter. naphthylamme,

TABLEV Percent viscosity increase Acid Weight change of specimens Percent at value Example Additive additive 100 F. increase Sludge Mg alloy Al alloy Cu Ag Steel 142.8 24.4 228 -37.89 +0.04 1.38 +0.03 +0.02 0.8 12.5 +0.01 +0.01 +0.01 +0.03 +0.05 5.8 3.2 7 nil +0.01 4.92 -0.l3 +0.02 10.3 4.2 -0.04 0.06 -5.74 0.02 0.06 4.2 1.5 0.17 0.02 -0.l2 0.04 0 05 3.2 0.9 0.7 -0.01 0.05 O.10 0.02 0.01

The results in Table V demonstrate the eflectiveness of the monoalkylated diarylamine compounds and their superior properties over related compounds not monoalkylat

Claims

2. A composition according to claim 1, said composition also containing benzotriazole as metal deactivator.
3. A composition according to claim 1, wherein the synthetic lubricant is di-2-ethylhexyl sebacate.
4. A composition according to claim 1, wherein the synthetic lubricant is trimethylolpropane tripelargonate.
5. A composition according to claim 1, wherein the synthetic lubricant is pentaerythritol tetracaprylate.
6. A composition according to claim 1, wherein the synthetic lubricant is complex ester derived from tri-methylolpropane, caprylic acid and sebacic acid.
7. A composition according to claim 1, wherein the mono tertiary alkyl substituted compound is a member selected from the group consisting of N-p-tertiary pentyl-phenyl- Alpha -naphthylamine, N-p-tertiary pentyl-phenyl- Beta -naphthylamine, N- Alpha -tertiary hexyl-phenyl- Alpha -naphthylamine, N- Alpha -tertiary hexyl-phenyl- Beta -naphthylamine, N-p-(1:1:3:3-tetramethylbutyl)-phenyl- Alpha -naphthylamine, N-p-(1:1:3:3-tetramethylbutyl)-phenyl- Beta -naphthylamine, N-p-(1:1:3:3:5:5-hexamethylhexyl)-phenyl- Alpha -naphthylamine and N-p-(1:1:3:3:5:5-hexamethylhexyl)-phenyl- Beta -naphthylamine.