US3695041A - Two-stage hydrazine rocket motor - Google Patents
Two-stage hydrazine rocket motor Download PDFInfo
- Publication number
- US3695041A US3695041A US35858A US3695041DA US3695041A US 3695041 A US3695041 A US 3695041A US 35858 A US35858 A US 35858A US 3695041D A US3695041D A US 3695041DA US 3695041 A US3695041 A US 3695041A
- Authority
- US
- United States
- Prior art keywords
- reaction chamber
- wall
- primary
- reactant
- liner
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 title claims abstract description 64
- 238000006243 chemical reaction Methods 0.000 claims abstract description 35
- 238000010517 secondary reaction Methods 0.000 claims abstract description 24
- 239000007800 oxidant agent Substances 0.000 claims abstract description 17
- 239000002826 coolant Substances 0.000 claims abstract description 16
- 239000000376 reactant Substances 0.000 claims description 15
- 239000003054 catalyst Substances 0.000 claims description 5
- 238000011144 upstream manufacturing Methods 0.000 claims description 4
- 238000000354 decomposition reaction Methods 0.000 abstract description 10
- 239000000047 product Substances 0.000 description 17
- 239000007789 gas Substances 0.000 description 12
- 239000003380 propellant Substances 0.000 description 10
- WFPZPJSADLPSON-UHFFFAOYSA-N dinitrogen tetraoxide Chemical compound [O-][N+](=O)[N+]([O-])=O WFPZPJSADLPSON-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- RHUYHJGZWVXEHW-UHFFFAOYSA-N 1,1-Dimethyhydrazine Chemical compound CN(C)N RHUYHJGZWVXEHW-UHFFFAOYSA-N 0.000 description 1
- WKGVMWWXCVKKCK-UHFFFAOYSA-N 1,1-dimethylhydrazine;hydrazine Chemical compound NN.CN(C)N WKGVMWWXCVKKCK-UHFFFAOYSA-N 0.000 description 1
- 241000606545 Biplex Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02K—JET-PROPULSION PLANTS
- F02K9/00—Rocket-engine plants, i.e. plants carrying both fuel and oxidant therefor; Control thereof
- F02K9/08—Rocket-engine plants, i.e. plants carrying both fuel and oxidant therefor; Control thereof using solid propellants
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
- C06B47/02—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase the components comprising a binary propellant
- C06B47/08—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase the components comprising a binary propellant a component containing hydrazine or a hydrazine derivative
Definitions
- a the decomposition products flow directly to the n zlean ed Field Of Search a major portion of the decomposed hydrazine in 60/260 266 the central portion of the secondary reaction chamber downstream of the primary reaction chamber.
- the [56] References and remaining decomposed hydrazine is directed as a UNITED STATES PATENTS buffer layer along the inner surface of the secondary reaction chambers outer wall, to serve as a coolant.
- This invention relates to gas generators such as in rocket propulsion systems, and more particularly to a two-stage propulsion system which uses the reacted products of a monopropellant first stage as both a propellant and a coolant for a bipropellant second stage.
- hydrazine-substitutes produce lower specific impulse than hydrazine.
- hydrazine is already being more widely used as a monopropellant for attitude control and gas pressurization systems and therefore it is highly desirable to avoid using a hydrazine-substitute so as to eliminate the need for a third storage facility aboard the space vehicle.
- the thrust chamber walls and nozzle in order to be protected must either be manufactured of heat resisting materials, lined with ceramic materials or the like, cooled by passing a coolant through or over them, or combinations or these.
- This invention pertains to a two-stage rocket motor which employs a primary reaction chamber in which hydrazine is catalytically decomposed, and a secondary reaction chamber in which the hydrazine products of decomposition may be reacted with an oxidizer.
- the products of hydrazine decomposition may be used alone to provide low energy propulsion and reacted with the oxidizer to provide high energy propulsion. Also, during the secondary reaction some of the products of hydrazine decomposition are advantageously used as a film coolant for the side wall of the secondary reaction chamber.
- FIG. 1 is a view partially in side elevation and partially in longitudinal section of a two-stage rocket motor employing the principles of the invention
- FIG. 2 is a transverse sectional view taken substantially along line 2-2 of FIG. 1, with a portion of the oxidizer injector cut away;
- FIG. 3 is a fragmentary view, also partially in side elevation and partially in longitudinal section, of a modified form of two-stage rocket motor.
- the illustrated embodiment comprises an outer tubular wall 12 of stainless steel or the like defining an internal space which is divided axially into a first stage or primary reaction chamber 14 and a second stage or secondary reaction chamber 16.
- Wall 12 is provided with a peripheral flange 18 to which is secured a rocket nozzle 20, also of stainless steel or the like, which may be of conventional design.
- a conduit 22 leads from a source of liquid hydrazine to a multiported injector incorporated into the upstream wall 26 of the primary reaction chamber.
- a plurality of conduits 24 extend from a source of an oxidizer, such as nitrogen tetroxide, to and then axially through the primary reaction chamber 14.
- the first stage reaction chamber 14 is divided into two parts by a perforated screen or plate 28.
- the upstream part contains fine catalyst particles and the downstream part contains coarser catalyst particles.
- Reaction chamber 14 has a perforated downstream wall 32.
- a screen 30 is located inside of wall 32 for retaining the catalyst particles within chamber 14.
- Wall 32 is provided with a plurality of central openings 31, a plurality of intermediate openings 33, and a plurality of outer openings 34.
- the outer openings 34 are directed to discharge adjacent an inner surface portion of wall 12.
- the second stage reaction chamber 16 may include an annular liner 36 (e.g., of a refractory material) which is spaced radially inwardly of outer wall 12, so as to leave an annular space between the liner 36 and the outer wall 12. In other embodiments (not shown) this liner may be omitted.
- annular liner 36 e.g., of a refractory material
- An annular oxidizer injector 37 is centrally positioned within the second stage reaction chamber, and is connected to the conduits 24 leading from the supply of liquid oxidizer.
- the outlet ports 39 of injector 37 are shown to discharge radially outwardly into the annular zone surrounding injector 37, for mixing contact in such zone with hydrazine decomposition products.
- the outlet ports 39 would be directed generally axially.
- liquid hydrazine is delivered into the first stage reaction chamber 14 and decomposes therein, forming hot gaseous nitrogen, hydrogen and ammonia, the temperature of which is about of l,600 F.
- the main portion of these gases passes through the openings 31, 33 in wall 32.
- all of the decomposed hydrazine flows directly to the nozzle 20.
- the gases exiting the openings 33 are mixed with the oxidizer (e.g., nitrogen tetroxide (N 0,) which is introduced through the injector 37.
- N 0, nitrogen tetroxide
- the second stage reaction between the hydrazine gases and the oxidizer results in an increase in the chamber gas temperature to approximately 5,000 F depending upon the oxidizer used.
- the decomposed but relative cool (viz. about 1,600 F) hydrazine which flows through openings 34 in wall 32 into the space between the liner 36 and the wall 12 insulates the outer wall 12 and the nozzle 20 from the high temperature in the central zone.
- the pressure drop of the gases within chamber 14 exerts a force which tends to buckle wall 32 outwardly.
- the conduits 24 are anchored at their ends so that they can provide support for wall 32.
- the basic structural configuration is the same as that shown in FIG. 1.
- the oxidizer is directed through a conduit 24a which passes laterally through the outer chamber wall 12 and the liner 36, into an injector 37 spaced downstream of wall 32, and from injector 37 spaced downstream of wall 32, and from injector 37 into the secondary reaction chamber.
- the start transient and combustion characteristics are inherently smoother due to the fact that only atomization and vaporization of the oxidizer are required for combustion to occur. This feature eliminates the problem of destructive ignition transients due to the accumulation of unburned or partially reacted fuel constituents.
- the relatively cool decomposition products (approximately l,600 F) can be effectively used. for cooling the thrust chamber and thrust and total impulse levels. With valve modulation a greater throttling range with greater reliability can be obtained. 4. Due to the unique chamber and nozzle cooling capability, and the relatively simple injector elements, it is anticipated that low cost rocket engines in a wide range of thrusts can be tkveloped. 5.
- a gas generator comprising:
- a secondary reaction chamber downstream of said primary reaction chamber defined by wall mean comprising at least one tubular wall
- said secondary reaction chamber wall means includes a tubular liner separating the higher temperature reaction zone from the chamber wall coolant, said liner is spaced radially inwardly from said tubular wall, and said annular coolant stream flows between such wall and said liner in conwith the discharge products in such zone to cause a higher temperature reaction;
- the means for introducing said discharge products into said secondary reaction chamber comprises a pervious wall having first openings leading to the zone inside said liner and second openings leading to the zone surrounding said liner.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US3585870A | 1970-05-08 | 1970-05-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3695041A true US3695041A (en) | 1972-10-03 |
Family
ID=21885215
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US35858A Expired - Lifetime US3695041A (en) | 1970-05-08 | 1970-05-08 | Two-stage hydrazine rocket motor |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US3695041A (enExample) |
| DE (1) | DE2122742A1 (enExample) |
| FR (1) | FR2093469A5 (enExample) |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3871828A (en) * | 1972-10-10 | 1975-03-18 | Hughes Aircraft Co | Hydrazine gas generator |
| US3903693A (en) * | 1973-03-26 | 1975-09-09 | Anthony Fox | Rocket motor housing |
| US4069664A (en) * | 1974-01-24 | 1978-01-24 | Hughes Aircraft Company | Monopropellant thruster |
| FR2455184A1 (fr) * | 1979-04-23 | 1980-11-21 | Hughes Aircraft Co | Generateur de poussee a hydrazine et son procede de mise en oeuvre |
| US4856271A (en) * | 1987-10-01 | 1989-08-15 | Olin Corporation | Gas generator and generating method employing dual catalytic and thermal liquid propellant decomposition paths |
| US5711695A (en) * | 1995-05-01 | 1998-01-27 | Pitsco, Inc. | Gas-propelled toy with exhaust nozzle for gas cartridge |
| US20040231318A1 (en) * | 2003-05-19 | 2004-11-25 | Fisher Steven C. | Bi-propellant injector with flame-holding zone igniter |
| US6860099B1 (en) * | 2003-01-09 | 2005-03-01 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Liquid propellant tracing impingement injector |
| US20070062176A1 (en) * | 2005-12-05 | 2007-03-22 | Bendel Timothy B | Liquid propellant rocket engine with pintle injector and acoustic dampening |
| US8122703B2 (en) | 2006-04-28 | 2012-02-28 | United Technologies Corporation | Coaxial ignition assembly |
| US20130199155A1 (en) * | 2012-01-02 | 2013-08-08 | Jordin Kare | Rocket Propulsion Systems, and Related Methods |
| US20140182265A1 (en) * | 2013-01-03 | 2014-07-03 | Jordin Kare | Rocket Propulsion Systems, and Related Methods |
| US20220120240A1 (en) * | 2020-10-16 | 2022-04-21 | Sierra Nevada Corporation | Vortex thruster system including catalyst bed with screen assembly |
| US11572851B2 (en) * | 2019-06-21 | 2023-02-07 | Sierra Space Corporation | Reaction control vortex thruster system |
| US11661907B2 (en) | 2018-10-11 | 2023-05-30 | Sierra Space Corporation | Vortex hybrid rocket motor |
| US20230193857A1 (en) * | 2021-12-21 | 2023-06-22 | Firehawk Aerospace, Inc. | Catalytic decomposition reactors |
| US11879414B2 (en) | 2022-04-12 | 2024-01-23 | Sierra Space Corporation | Hybrid rocket oxidizer flow control system including regression rate sensors |
| US11952967B2 (en) | 2021-08-19 | 2024-04-09 | Sierra Space Corporation | Liquid propellant injector for vortex hybrid rocket motor |
| US11952965B2 (en) | 2019-01-30 | 2024-04-09 | Laboratoire Reaction Dynamics Inc. | Rocket engine's thrust chamber assembly |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2706887A (en) * | 1946-01-23 | 1955-04-26 | Harlow B Grow | Liquid propellant rocket motor |
| US3029602A (en) * | 1957-06-21 | 1962-04-17 | Bristol Siddeley Engines Ltd | Combustion chambers |
| US3107485A (en) * | 1959-05-27 | 1963-10-22 | Ohio Commw Eng Co | Propulsion means and method for space vehicles employing a volatile alkene and metalcarbonyl |
| US3149460A (en) * | 1960-09-28 | 1964-09-22 | Gen Electric | Reaction propulsion system |
| US3377140A (en) * | 1965-10-15 | 1968-04-09 | Specialties Dev Corp | Apparatus for catalytically decomposing hydrazine |
| US3446023A (en) * | 1966-08-05 | 1969-05-27 | United Aircraft Corp | Catalytic attitude-control rocket motor |
-
1970
- 1970-05-08 US US35858A patent/US3695041A/en not_active Expired - Lifetime
-
1971
- 1971-05-05 FR FR7116176A patent/FR2093469A5/fr not_active Expired
- 1971-05-07 DE DE19712122742 patent/DE2122742A1/de active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2706887A (en) * | 1946-01-23 | 1955-04-26 | Harlow B Grow | Liquid propellant rocket motor |
| US3029602A (en) * | 1957-06-21 | 1962-04-17 | Bristol Siddeley Engines Ltd | Combustion chambers |
| US3107485A (en) * | 1959-05-27 | 1963-10-22 | Ohio Commw Eng Co | Propulsion means and method for space vehicles employing a volatile alkene and metalcarbonyl |
| US3149460A (en) * | 1960-09-28 | 1964-09-22 | Gen Electric | Reaction propulsion system |
| US3377140A (en) * | 1965-10-15 | 1968-04-09 | Specialties Dev Corp | Apparatus for catalytically decomposing hydrazine |
| US3446023A (en) * | 1966-08-05 | 1969-05-27 | United Aircraft Corp | Catalytic attitude-control rocket motor |
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3871828A (en) * | 1972-10-10 | 1975-03-18 | Hughes Aircraft Co | Hydrazine gas generator |
| US3903693A (en) * | 1973-03-26 | 1975-09-09 | Anthony Fox | Rocket motor housing |
| US4069664A (en) * | 1974-01-24 | 1978-01-24 | Hughes Aircraft Company | Monopropellant thruster |
| FR2455184A1 (fr) * | 1979-04-23 | 1980-11-21 | Hughes Aircraft Co | Generateur de poussee a hydrazine et son procede de mise en oeuvre |
| US4324096A (en) * | 1979-04-23 | 1982-04-13 | Hughes Aircraft Company | Hydrazine thruster |
| US4856271A (en) * | 1987-10-01 | 1989-08-15 | Olin Corporation | Gas generator and generating method employing dual catalytic and thermal liquid propellant decomposition paths |
| US5711695A (en) * | 1995-05-01 | 1998-01-27 | Pitsco, Inc. | Gas-propelled toy with exhaust nozzle for gas cartridge |
| US6860099B1 (en) * | 2003-01-09 | 2005-03-01 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Liquid propellant tracing impingement injector |
| US20040231318A1 (en) * | 2003-05-19 | 2004-11-25 | Fisher Steven C. | Bi-propellant injector with flame-holding zone igniter |
| US6918243B2 (en) * | 2003-05-19 | 2005-07-19 | The Boeing Company | Bi-propellant injector with flame-holding zone igniter |
| US20070062176A1 (en) * | 2005-12-05 | 2007-03-22 | Bendel Timothy B | Liquid propellant rocket engine with pintle injector and acoustic dampening |
| US7827781B2 (en) * | 2005-12-05 | 2010-11-09 | Bendel Timothy B | Liquid propellant rocket engine with pintle injector and acoustic dampening |
| US8122703B2 (en) | 2006-04-28 | 2012-02-28 | United Technologies Corporation | Coaxial ignition assembly |
| US20130199155A1 (en) * | 2012-01-02 | 2013-08-08 | Jordin Kare | Rocket Propulsion Systems, and Related Methods |
| US20140182265A1 (en) * | 2013-01-03 | 2014-07-03 | Jordin Kare | Rocket Propulsion Systems, and Related Methods |
| US11661907B2 (en) | 2018-10-11 | 2023-05-30 | Sierra Space Corporation | Vortex hybrid rocket motor |
| US12071915B2 (en) | 2018-10-11 | 2024-08-27 | Sierra Space Corporation | Vortex hybrid rocket motor |
| US11952965B2 (en) | 2019-01-30 | 2024-04-09 | Laboratoire Reaction Dynamics Inc. | Rocket engine's thrust chamber assembly |
| US12129814B2 (en) | 2019-01-30 | 2024-10-29 | Laboratoire Reaction Dynamics Inc. | Thrust vector control for hybrid propellants rocket engine with embedded fluid injection ports |
| US12060853B2 (en) | 2019-01-30 | 2024-08-13 | Laboratoire Reaction Dynamics Inc. | Rocket engine with integrated oxidizer catalyst in manifold and injector assembly |
| US11572851B2 (en) * | 2019-06-21 | 2023-02-07 | Sierra Space Corporation | Reaction control vortex thruster system |
| US11927152B2 (en) * | 2019-06-21 | 2024-03-12 | Sierra Space Corporation | Reaction control vortex thruster system |
| US20220120240A1 (en) * | 2020-10-16 | 2022-04-21 | Sierra Nevada Corporation | Vortex thruster system including catalyst bed with screen assembly |
| US11952967B2 (en) | 2021-08-19 | 2024-04-09 | Sierra Space Corporation | Liquid propellant injector for vortex hybrid rocket motor |
| US20230193857A1 (en) * | 2021-12-21 | 2023-06-22 | Firehawk Aerospace, Inc. | Catalytic decomposition reactors |
| US12410765B2 (en) * | 2021-12-21 | 2025-09-09 | Firehawk Aerospace, Inc. | Catalytic decomposition reactors |
| US11879414B2 (en) | 2022-04-12 | 2024-01-23 | Sierra Space Corporation | Hybrid rocket oxidizer flow control system including regression rate sensors |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2093469A5 (enExample) | 1972-01-28 |
| DE2122742A1 (de) | 1971-12-02 |
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