US3668053A

US3668053A - Article for preventing edge defect in compression stretched acrylic sheet

Info

Publication number: US3668053A
Application number: US48691A
Authority: US
Inventors: Ronald L Ayres
Original assignee: Fortin Plastics Inc
Current assignee: Fortin Plastics Inc
Priority date: 1968-09-09
Filing date: 1970-05-25
Publication date: 1972-06-06
Anticipated expiration: 1989-06-06

Abstract

An article for preventing edge defects in compression-stretched acrylic sheets comprising providing the circumferential end surfaces of an acrylic blank to be stretched with a groove substantially continuous therewith, the depth of the groove being greater than 5 percent and, preferably, being greater than about 10 percent of the initial thickness of the acrylic blank. The groove may have various configurations, e.g., V- and U-shaped configurations. Preferably, the center line of the groove lies in the plane bisecting the blank in the thickness direction.

Description

United States Patent 1 a June 6, 1972 Ayres [54] ARTICLE FOR PREVENTING EDGE DEFECT IN-COMPRESSION STRETCHED ACRYLIC SHEET [72] Inventor: Ronald L. Ayres, Saugus, Calif.

[73] Assignee: For-tin Plastics, Inc., Saugus, Calif. '22 Filed: May 25, 1970 21 App]. No.: 48,691

Related US. Application Data [62] Division of Ser. No. 758,395, Sept. 9, 1968, Pat. No.

[52]- U.s.c|.. ...l6l/1l8,l6l/ll7,161/149 [51] lnt.Cl. ..B32b3/02,B32b-3/30 Y 58 FieldofSearch ..161/44,ll7,118,l24, 149,

[56] References Cited UNITED STATES PATENTS 2,201,669 5/1940 Kraft ..l6l/l49 X 3,262,136 7/1966 Sevcik.... .....l6l/ll8 X Primary Examiner-William A. Powell Attorney-Fulwider, Patton, Rieber, Lee & Utecht [57] ABSTRACT 4 Claim, 1 1 Drawing Figures stretched acrylic part.

" CROSS-REFERENCES TQRELATED APPLICATION This application is a divisional application of US. Pat. application-Ser. No. 758,395, filed Sept. 9, 1968, now US. Pat. No. 3,562,383. a I

- 1 BACKGROUND OF THE INVENTION This invention relates to'stretching of acrylic sheets and, more particularly, to the prevention of edge defects in stretched acrylic sheets.

Because of its strength, formability, and light transmission characteristics, acylic material has a variety of uses and particularly has been used to form'windows and canopies for-aircraft. Manufacture of the acrylic part often involves a stretching step in which the acrylic material is heated and stretched to enhance its physical characteristics and/or to provide the acrylic part with a required curvature. Heretofore, stretching of acrylic blanks has been accomplished by either pulling-the edges of the acrylic blanks in opposing directions such as is describedin US. Pat. No. Re. 24,978 of Bottoms et al., ,or of j'cornpression stretching acrylic blanks as described in us. Pat. application Ser. No.69 1 ,294 ofTerry D. Fortin, filed on Dec. 18,1967, now abandoned. Regardless of the way-in which the acrylic blanks are stretched, stresses are set up in the edges of the acrylic blanks which cause cracking and subsequent loss of material around the edges of the acrylic blanks. Additionally, such edge cracks can propogate throughout the stretched sheet, thereby resulting in a near total loss of the acrylic part.

To reduce losses from acrylic blanks stretched by the tension method described in the above-mentioned Bottoms patent, the edges of the acrylic blanks have been cooled relative to the remainder of the acrylic blank-as the acrylic blank is stretched. This method has reduced the material lost when stretching by .this "method. However, other stresses are produced in the stretched acrylic sheet due to the temperature differential between the edge and interior sections of the To the best of the knowledge of the instant inventor, no methods have been previously used to prevent edge losses when stretching acrylic blanks by the compression method described in the aforementioned Fortin application.

I SUMMARY OF THE INVENTION Themethod of this invention comprises providing the circumferential end surfaces of acrylic blanks with a substantially continuous groove therein. The depth of the groove is at least about 5 percent and, preferably, is greater than about percent of the initial thickness of the acrylic blank. The groove may have a variety of configurations such as, for example, V- and U-shaped configurations and the centerline of the groove may be offset from the center-line of the circumferential end surfaces. However, it is preferable to position the groove so that its center-line corresponds with the center-line of the circumferential end surfaces.

The grooving of acrylic blanks as described is relatively easy to accomplish and the machining producing the groove ap-' parently sets up no noticeable stresses in the edge of the acrylic blanks. In'spite of its simplicity and ease of accomplishment,

the method of this invention has been extremely successful in substantially eliminating lossesfrom the edges of compression stretched acrylic sheets.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 3 is a partial perspective viewv of a compressionstretched acrylic sheet stretched from the acrylic blank of FIG. 1;

FIG. 4 is a partial sectional view of the unstretched acrylic blank of FIG. 1 taken along the lines 4-4 of FIG. 1;

FIG. 4a is a sectional view of the stretched acrylic blank of FIG. 3 taken along the lines 4a 4dof FIG. 3;

FIG. 5 is a sectional view of an acrylic blank provided with another form of circumferential-groove of this invention but different in shape from the groove of FIG. 4;

FIG. 5a is a sectional view of that portion of the acrylic blank shown in FIG. 5 after being compression-stretched;

FIGS. 6, 7 and 8 are sectional views of unstretched acrylic blanks having variously shaped and positioned circumferential end grooves of this invention; and. v FIG. 9 is a partial elevational view ofa stretched acrylic sheet showing edge roll" produced' from compression stretching. I

DESCRIPTION OF THE PREFERRED EMBODIMENT The method of this 'inventioncomprises' providing the 'circumferential end surfaces of acrylic blanks with a groove which is substantially continuous therewith. The depth of the groove is at least about 5 percent and, preferably is at least aboutlO percent of the initial thickness of the acrylic blank. Various configurations, e.g., V- and U-shaped and rectangular configurations, may be used. Preferably, thecenter line of the groove lies along the center line of the acrylicjblank taken in the thickness direction. I

Acrylic blanks having the aforedescribed. groovemay be heated and compression stretched as described in the US. application Ser. No. 691,294 ofTerry-D. Fortin, filed Dec. 18, 1967 (hereafter referred. to as said Fortin application"). When acrylic blanks are grooved stretched in this manner, the resultant stretched acrylic sheetsexhibit substantially no edge defects. Therefore, the loss of acrylic material is substantially eliminated. In acrylic blanks which are not provided with the groove of this invention, the edges of the acrylic blanks, after'being stretched by the method described in said Fortin application, often are highly stressed resulting in weakened or cracked edges (FIG. 2).

Acrylic blanks'stretched according to said Fortin application'. are heated to their soflening' temperature range and, thereafter, compressed to cause the acrylic material to flow or squeeze radially outwardly to form a stretched acrylic sheet of reduced thickness. It is believed thatthe undesirable edge defects. result from the partially molten edges of the acrylic blanks rolling" non-uniformly outwardly from the central portion of the acrylic blanks. This "frolling" of the outer edges apparently takes place at a rate faster than the radially outward movement of the remainder of the acrylic blank. This difi'erential rate of movement is believed to be the cause of the stresses and cracks which are introduced into the edges of the stretched acrylic sheet. The success of the groove of this invention in preventing fracturing of the edges of compression stretched acrylic sheet is believed due to the restraining of this "edge roll" due to a change in edge forces which is, in some manner, derived from the aforedescribed circumferential grooving. That is, it is hypothesized that the initial compression forces exerted on the groove exceed the non-uniform outward forces which tend to create edge roll, thereby restraining outward flow of the edge material so that its outward flow is substantially equal to the outward 'flow of the remainder of the acrylic blank as the blank is stretched.

The method of this invention will now be more particularly described with reference to the figures. In FIG. 1, the numeral 10 designates an as-cast acrylic blank which has a circumferential end surface 11. The term acrylic blank" will be employed herein, and in the claims, to denote unstretched acrylic material. The end surface 11 of the blank 10 is provided with a continuous groove 12. Some improvement in the edges of compression-stretched acrylic sheet may be produced re- 7 gardless of the shape and size of the groove 12 in the acrylic which no circumferential grooves were formed. By com- ,parison, acrylic sheets stretched'from blanks having circumferentialend grooves of depth greater than about 10 percent of the blank thickness, substantially-always exhibit no edge defects-.'.. Y

As used herein, the term edge defects" refers to a random,

uneven stressing, cracking and/or breaking of the edges of stretched sheets as shown, byway of example, in FIG. 2. Such edge ,defects can result in substantial loss of acrylic material. While the shallow circumferential grooves which may be present around the edges of acrylic material after it has been stretched by the herein-described method, such as shown in FIG. 3, and constitutes a loss of material, such loss is only a minor fraction of that due to uneven stresses and other edge cracking. This loss is minimal because the shallow grooves extend a uniform distance into the material and are not accompanied by cracking, stressing, etc., which would necessitate the removal of good material in order to remove stressed or cracked sections as in the case with stretched sheets exhibiting edge defects. i

- A section 13 of an acrylic sheetoriginally having a shape and edge groove 12 such as is shown in FIG. I, is shown in FIG. 3 after being compression-stretched. In addition to havinga reduced thickness as compared with the blank 10 of FIG.

1, the stretched sheet 13 has a much smaller edge groove 14.

The smaller groove 14 is produced by the filling'in of the original groove 12 as the acrylic blank 10 is compressionstretched. The latter is further shown by comparing the grooves 12 of FIGS. 4 and with the grooves 14 of FIGS. 4a and 5a, respectively. As will be seeri from this comparison, the stretched sheets 13 of FIGS. 4a and 5a have substantially smaller grooves14 than the acrylic blanks of FIGS. 4 and 5.

It has also beenfound that the most advantageous results are obtained when the grooves in the circumferential end surfaces of the blanks are symmetrical about the plane passing through the center-line of such surfaces as shown in FIGS. 4, 5

and 6..-That is, optimum results are produced when the maximum depth of .the grooves is located at the center-line of the circumferential surfaces and the center-line of the groove corresponds to the center-line of the circumferential surfaces.

With thisoptimumpositioning of the grooves in the blanks, the material whichhas to be removed from the edge of the stretched sheetto remove any shallow grooves remaining after compression is minimized, as compared with an asymmetrical groove as shown in F 168.7 and 8.

The shape of the groove does not appear to be critical. Grooves of various cross-sectional shapes, e.g., V-shaped, U- shaped, circular and rectangular, (FIGS. 4, 5 and 6) have been successfully employed. Additionally, the mouth of the groove may be as wide as, or narrower than, the width of the circumferential end surfaces, as shown in FIGS. 5 and 8. The groove is substantially coextensive with the length of the circumferential end surface (FIG. 1) since edge defects may be introduced into the stretched sheetat any point along the. end

surface if there is no grooving at that point.

v In actual stretching operations, it is preferable to provide a test blank with a groove having a particular depth (greater than 10 percent of the thickness of the blank) and, thereafter, to compression stretch the test blank to the'desired stretched size.'By examining the depth of the groove in the stretched part, it canjbe determined whether to use, shallower or deeper grooves in the production blanks. For example, if a relatively deep groove remains in the stretched sheet, a shallower groove than initially present in the test blank can be formed or cut'in the production blanks so that edge losses from the stretched part will be further minimizedp Cracking and stressing of theedges is generally preceded by edgeroll" as shown in FIG. 9. Thus, if edge roll is present along the edges of a stretched acrylic sheet, a border-line conwhich will be substantially eliminated in the stretched acrylic sheet. That is, optimally the depth of the acrylic blank groove is selected so that the flow of material during compression stretching substantially fills the groove. Such groove selection, of course, minimizes or eliminates any losses of material from the stretched sheet. I

Following'the choice'of a satisfactory. groove depth, the production acrylic blanks are provided with edge groove by any method, e.g., sawing, which will not critically stress the blank. The blanks are then ready to be compression stretched. Compression stretching of the grooved blanks may be performed by any desired technique. However, it is presently preferably to employ the compression stretching method described in said Fortin application, the description of which is incorporated herein by reference to said F ortin application. Examples of the article and process of this invention follow:

EXAMPLE 1 An as-cast Plexiglas 55 blank'(manufactured by Rohm & Haas) having initial dimensions of 6 in. X ,6 in. X 0.751. in. thick was provided with a circumferential groove having a configuration substantially as shown in FIG. 8. The maximum depth of the groove'was 0.125 inches, or'about 16 percent of the initial acrylic blank thickness. This blank was coated with Mold-Wiz F-57 lubricant (Teflon colloidal dispersion manufactured by Axel Plastics Research Lab., Inc.) and placed between a pair of polished glass'plates, and isothermally heated to a temperature of 295 F. I

The blank was thereafter compressed as a thickness reduction rate of about 0.10inches per minute to produce a stretched acrylic sheet measuring 9.5in. x 9.5 in. x 0.270 in. thick. Thereafter, the temperature of the acrylic sheet was reduced at a rate of l3 F. per minute to'a temperature below aboutll0F. r

No cracks developed in the stretched acrylic sheet and no edge roll was observed. Additionally, the size of the groove in the blank was substantially reduced.

5 EXAMPLE z 4 same conditions as described in Example I to a stretched.

acrylic sheet having dimensionsof 9 in. X 9 in. X 0.350 in. thick. I y

No cracks or edge roll were observed in the stretched acrylic sheet and thedepth of theoriginal groove in the acrylic blank was substantially eliminated in the stretched sheet.

EXAMPLE 3 An acrylic blank formed from the same material and having the same dimensions as that described in Example 2 was provided with a V-shaped groove similar to that used in Example 2 except that the maximum depth of the groove was 0.046 inches or about 6 percent of the'acrylic blank thickness. This blank was stretched under the same conditions as employed in Example 2 to a stretched acrylic sheet having dimensionsof 9.5 in. X 9.5 in. X 0.300 in. thick.

No cracks were observed in the edges of the stretched acrylic sheet. However, some edge roll was noticed along the edges of the sheetand, from experience, this indicated a borderline condition.

EXAMPLE 4 EXAMPLE 5 An acrylic blank of Plexiglas 55 having dimensions of 12.5 in. X 12.5 in. X 0.780 in. was provided with a continuous circumferential groove similar to that shown in FIG. 7 and having a maximum depth of about 0.375 inches (about 50 percent of the initial blank thickness). This blank was compression stretched by the method of Example 1 to a stretched acrylic sheet having dimensions of 22.2 in. X 22.2 in. X 0.233 in.

No cracks or edge roll were observed along the edges of the stretched acrylic sheet.

EXAMPLE 6 An as-cast acrylic blank of Plexiglas 55 having dimensions of 12.5 in. X 12.5 in. X 0.735 in. was provided with a continuous circumferential V-shaped groove as shown in FIG. 4 and having a maximum depth of about 0.312 inches (about 40 percent of the initial blank thickness). This acrylic blank was stretched by the method of Example 1 to a stretched acrylic sheet having dimensions of 21 in. X 22 in. X 0.235 in.

No cracks or edge roll were observed around the edges of the stretched acrylic sheet.

As will be apparent from the foregoing, modifications in the present invention may be made by those skilled in the art without departing from the spirit of the invention. Therefore. this invention is to be limited only by the scope of the claims which follow.

I claim:

1. An acrylic blank defined by an upper and a lower surface and by a circumferential end surface and having an initial thickness, said circumferential end surface having a circumferential groove therein having a depth at least about 5 percent of said initial thickness of said blank.

2. The acrylic blank of claim 1 wherein said circumferential groove is substantially coextensive with said circumferential end surface.

3. The acrylic blank of claim 1 wherein said depth of said groove is at least about 10 percent of said initial thickness of said blank.

4. The acrylic blank of claim 1 wherein said groove is symmetrical about a plane through the center-line of said circumferential end surfaces.