US3666452A - High-strength low-alloy steels - Google Patents

Abstract

FULLY KILLED HIGH-STRENGTH LOW-ALLOY STEELS CONSISTING ESSENTIALLY OF .12% TO .20% CARBON, 1.10% TO 1.65% MANGANESE, .05% TO .20% VANADIUM, .005% TO .025, NITROGEN,.04% MAXIMUM PHOSPHORUS,.025% MAXIMUM SULFUR,.60% MAXIMUM SILICON AND BALANCE IRON ARE CHAR ACTERIZED IN A HOT-ROLLED FINISHED CONDITION BY YIELD STRENGTHS IN EXCESS OF 80,000 P.S.I., ULTIMATE TENSILE STRENGTHS IN EXCESS OF 95,000 P.S.I., DUCTILITIES AS MEASURED BY PERCENT ELONGATION (2INCHES) IN EXCESS OF 18% AND GOOD TOUGHNESS. THE STEELS ARE HOT-ROLLED FINISHED IN THE TEMPERATURE RANGE 1550* F. TO 1650*F., COOLED AT A RATE WITHIN THE RANGE 20* F. TO 135* F. PER SECOND AND COLLECTED BY COILING OR PILING WITH A TEMPERATURE RANGE OF 1025* F. TO 1175* F. THE STEELS MODIFIED BY THE INCORPORATION OF .01% TO .10% OF A RARE EARTH ARE FURTHER CHARACTERIZED BY IMPROVED FORMABILITY.

Description

United States Patent US. Cl. 75-123 E 6 Claims ABSTRACT OF THE DISCLOSURE lFully killed high-strength low-alloy steels consisting essentially of .12% to .20% carbon, 1.10% to 1.65% manganese, .05% to 20% vanadium, .005% to .025% nitrogen, .04% maximum phosphorus, .025% maximum sulfur, .60% maximum silicon and balance iron are characterized in a hot-rolled finished condition by yield strengths in excess of 80,000 p.s.i., ultimate tensile strengths in excess of 95,000 p.s.i., ductilities as measured by percent elongation (2 inches) in excess of 18% and good toughness. The steels are hot-rolled finished in the temperature range 1550 F. to 1650 F., cooled at a rate within the range 20 F. to 135 F. per second and collected by coiling or piling within a temperature range of 1025 F. to 1175 F. The steels modified by the incorporation of .0l% to .10% of a rare earth are further characterized by improved formability.

This invention relates to high-strength low-alloy steels and their method of manufacture.

3,666,452 Patented May 30, 1972 ICC vention is to provide such steels characterized in a hotrolled finished condition by a yield strength in excess of 80,000 p.s.i., an ultimate tensile strength in excess of 95,000 p.s.i., ductility as measured by percent elongation (2 inches) in excess of 18% and superior toughness. Still another object of the present invention is to provide such steels which can be bent without cracking about an inside radius which is equal or less than the thickness of the steel.

These and other objects and advantages of the present invention will become apparent from the following detailed description thereof.

The steels of the present invention are fully killed and have the following preferred chemistry: carbon, .12% to .20%; manganese, 1.10% to 1.65%; vanadium, .05% to .20%; nitrogen, .005 to .025%; phosphorus, .04% maximum; sulfur, .025% maximum; silicon, .60% maximum; rare earth, 0 to .10%; iron, balance.

The steels, to possess the desired characteristics and properties of a yield strength in excess of 80,000 p.s.i., an ultimate tensile strength in excess of 95,000 p.s.i., ductility as measured by percent elongation (2 inches) in excess of 18% and superior toughness, are hot-rolled finished in the temperature range 1550 F. to 1650 F., and collected as by coiling or piling within a temperature range of 1025 F. to 1175 F. For the typical length of a modern hot-mill run-out table and conventional rolling speeds, the steel must be cooled at a rate within the range of 20 F. to 135 F. per second to maintain the finishing and coiling temperature specified.

The significance of processing the steels within a finishing temperature range of 1550 F. to 1650 F. and a coil ing temperature of 1025 *F. to 1175 F. is demonstrated in Table I.

TABLE I Flnlshing Coiling Ultimate Percent Chemlstry(weight percent) tempertemper- Yield tensile elon- Thermal ature, ature, strength strength gation HeatNo. 0 Mn Si V Al N P S practice F. F. (p.s.i.) (p.s.i.) (2) 797138 .15 1.30 .45 .10 .0 1101 001211133; 1;;28 1 133 58588 39'283 3.2-; Low 1,600 11000 901500 1191000 11:0 803769 .13 1.88 4 A124 .015 1108 {Wit;h1n 1,050 1,100 ,600 104,00 25.0

To achieve commercial acceptance, a high-strength lowalloy steel in addition to having high strength should also have good formability, toughness, weldability and fatigue resistance. We have developed low-alloy steels which through a unique combination of chemistry and processing parameters possess these properties to an extent and in a balance not heertofore available in hot-rolled finished material. It has been necessary to heat treat hot-rolled lowalloy steels to obtain the properties possessed by the steels of the invention in a hot-rolled state.

Accordingly, an object of the present invention is to provide low-alloy steels having high strength in combination with excellent formability, toughness, weldability and fatigue resistance. Another object of the present in- Material from Heat No. 797138 subjected to a high thermal practice, i.e., finished at a temperature above 1650 F. and coiled at a temperature above 1l7'5 F. exhibited a yield strength and ultimate tensile strength below that exhibited by material from the same heat finished and coiled Within the specified range. Material from Heat No. 803769 finished at a temperature within the specified range but coiled at a temperature below 1175 F, while possessing a high yield strength and ultimate tensile strength, exhibited low ductility as measured by percent elongation (2 inches). Material from the same heat processed completely within the temperature ranges of the invention demonstrated markedly superior ductility.

The importance of maintaining the steel chemistry within that set out above is shown in Table H.

TABLE II Finish- N. s1 v Al N P s Fi FZ (p.s.i.) (p.s.i.) 2") 33% :53 18%? 1393 1833 i323 1:168 $91288 33% .53 .07 .10 .021 .007 .012 1,650 1,120 98,600 1101000 2015 The heats of Table II were all processed within the specified temperature ranges of the invention. Heat No. 4347 contained only .004% nitrogen and had a yield strength and ultimate tensile strength substantially below 4 The use of rare earths result in the formation of substantially spherically-shaped inclusions which retain their spherical shape in the hot-rolled product. The improved formability of such steels is shown in Table IV.

TABLE IV Impact properties ductile brittle transter- Mini- Chemistry (weight percent) Shelf temper- 1113mm ener ature end Heat No. Gage C Mn Si S P V Al N Ce Test direction (it-lbs F.) radius 806558 "0.250" .17 1.11 .40 .017 .008 .093 .053 .010 .{ggggggggg 985297 0.250" .11 1.34 .41 .008 .005 .13 .017 .022 .014 {gggg igg g g}, fig

1 Without cracking transverse sample.

the desired strength levels. Heat No. 4391-1 contained vanadium below the minimum of .05% specified above and also had a yield strength and ultimate tensile strength significantly below the desired level. Heat No. 43233 contained vanadium in an amount near the upper limit employed by the steels of the invention and demonstrated a yield strength and ultimate tensile strength significantly above the specified minimum of 80,000 p.s.i. At the same time, the ductility of the steel, as measured by percent elongation (2 inches), was 26.5.

The effect of the thermal processing parameters on the impact properties of the steels is also significant. This 30 can be seen from Table III.

lfhe improved bending properties of Heat No. 806558 which contained a rare earth (cerium) is demonstrated by the fact that steels from that heat could be bent about an inside radius of a minimum of /4 of their thickness without cracking, whereas steels from Heat No. 985297 which did not contain any rare earth could only be bent about a minimum inside radius of 2 /2 times their thickness before cracking. Crack lengths less than 0.10 inch 'were discounted. The table further shows that the rare earths contribute to improved toughness as measured by the shelf energy.

While a carbon content within the range of .12% to .20% is preferred, lower or higher carbon contents are TABLE III Impact properties Transition Energy Fiuishtemperature, absorbed ing Coiling F. at room Chemistry (weight percent) tempertemper temperature, ature, 50% 10ft.- ature Heat No. Mn P 5 Al Si V N F. F. Test direction shear lbs. (ft.-lbs.)

197500 .11 1.50 .001 .012 .07 .50 .10 .021 1,050 750 {ggggtgggik g3 8? 806558 .10 1.05 .001 .011 .045 .00 .089 .021 1,000 1,000 {figfiififlf}: 33 3;; i2 804982 .11 1.10 .000 .011 .31 .050 .072 .118 1,040 1,120 {gggggggg g 19g 1 Room temperature.

The specimens for which the data of Table III was obtained comprised one-half size Charpy V-notch samples. Heat No. 797 566 was coiled at a temperature below the minimum coiling temperature of the invention, -1 025 iF., while Heat No. 806558 was both finished and coiled above the maximum temperatures of the invention. Heat No. 804-982 was finished and coiled within the temperature ranges of the invention. For specimens taken in directions both longitudinal and transverse to the rolling direction, Heat No. 804 982 had lower transition temperatures at 50% shear and ft.-lbs. than Heat No. 806558. Heat No. 804982 had lower transition temperatures at shear for both longitudinal and transverse specimens and at 10 ft.-lbs. for the transverse specimen than Heat 'No. 797566. The longitudinal specimens of the latter two heats had the same transition temperature at 10 ft.-lbs. The energy absorbed by the specimens before fracturing at room temperature (about 70 -F.) was greater in all instances for Heat No. 8049-82.

For applications where the steel is to be subjected to severe forming operations, a rare earth in the amount of a .01% to .10% is added to the steel. Examples of rare earths employed in the invention are cerium, lanthanum, praseodymium, neodymium, yttrium, scandium, or mischmetal which, of course, is a mixture of rare earths. The rare earths may be added in a pure form or in the form of a compound, such as a silicide. To insure good recovery, the rare earth is preferably added to the steel in the ingot mold or in the ladle after the steel has been killed.

acceptable depending on the manganese content. As is known, an increase in carbon is accompanied by a decrease in ductility, toughness and weldability so that where an impairment in these properties is acceptable to achieve higher strengths, higher carbon contents are employed. Similarly, while a manganese content of 1.10% to 1.65% is preferred, lower manganese contents can be used. Where corrosion resistance is of importance, copper is added to the steel to improve its atmospheric corrosion resistance.

The steels of the invention possess excellent weldability and are highly resistant to either hot or cold crack ing. Preheating or postheating of the weld area is not required. In addition, the steels of the invention are often more resistant to fatigue damage than a quenched and tempered alloy steel of the same or even higher yield strength. This is because the steels of the invention are not subjected to heat treating and therefore are virtually free of surface decarburization.

We claim:

1. A killed, low-alloy high-strength steel hot-rolled finished in the temperature range 1550 F. to 1 650" F., cooled at a rate within the range 20 F. to per second, and collected within a temperature range of 1025 F. to 1-175 F., the steel being characterized in a hot-rolled condition by a yield strength in excess of 80,000 p.s.i., an ultimate tensile strength in excess of 95,000 psi, ductility as measured by percent elongation (2 inches) in excess of 18%, and good toughness, said steel consisting essentially of at least about .12% carbon, 3. maximum of about 1.65% manganese, at least about .05% vanadium, .005% to .025% nitrogen, .04% maximum phosphorus, .025 maximum sulfur, .60% maximum silicon, .-l% to .10% of a rare earth or mixture of rare earths, balance iron.

2. The steel of claim 1 containing .12% to .20% carbon, 1.10% to 1.65% manganese and .05% to .20% vanadium.

3. A process for manufacturing a low-alloy highstrength steel characterized in the hot-rolled condition by a yield strength in excess of 80,000 psi, an ultimate tensile strength in excess in about 95,000 p.s.i., ductility as measured by percent elongation (2 inches) in excess of about 18% and good toughness, comprising, hot-rolling a steel consisting essentially of at least .12% carbon, a maximum of about 1.65% manganese, at least about .05 vanadium, .005 to .025 nitrogen, .04% maximum phosphorus, .025 maximum sulfur, .60% maximum silicon, .0l% to .10% of a rare earth or mixture of rare earths, balance iron at a finishing temperature within the range of 1550 -F. to 1650 'F., cooling the hot-rolled product at a rate within the range 20 F. to 135 F. per second and collecting the cooled material at a temperature wtihin the range 1025 F. to 1175 F.

4. The process of claim 3 wherein the steel contains .12% to .20% carbon, 1.10% to 1.65% manganese and .05% to .20% vanadium.

5. A low-alloy high-strength steel having improved bending properties and consisting essentially of at least about 112% carbon, a maximum of about 1.65% manganese, at least about .05% vanadium, .005% to .025% nitrogen, .04% maximum phosphorus, .025% maximum sulfur, .60% maximum silicon, .01% to 10% of a rare earth or mixture of rare earths, balance iron,

6. The steel of claim 5 containing .12% to .20% carbon, 1.10% to 1.65% manganese and .05% to .20% vanadium.

References Cited UNITED STATES PATENTS 3,010,822 11/1961 Altenburger et al. -123 3,102,831 9/1963 Tisdale 148-12 3,494,808 2/1970 Goda et a1. 148-12 3,539,404 11/ 1970 De Retana 148-124 FOREIGN PATENTS 1,084,231 9/1967 Great Britain 1148-12 L. DEWAYNE RUTLEDGE, Primary Examiner W. W. STALLARD, Assistant Examiner US. Cl. X.R.