US3660142A - Method of making a photographic base material - Google Patents
Method of making a photographic base material Download PDFInfo
- Publication number
- US3660142A US3660142A US44872A US3660142DA US3660142A US 3660142 A US3660142 A US 3660142A US 44872 A US44872 A US 44872A US 3660142D A US3660142D A US 3660142DA US 3660142 A US3660142 A US 3660142A
- Authority
- US
- United States
- Prior art keywords
- base material
- polyethylene
- making
- photographic base
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/91—Photosensitive materials characterised by the base or auxiliary layers characterised by subbing layers or subbing means
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/795—Photosensitive materials characterised by the base or auxiliary layers the base being of macromolecular substances
Definitions
- the principal object of this invention is to improve the wettability of a photographic base material, such as polyethylene film or polyethylene laminated paper, by undercoating solutions and light-sensitive emulsions.
- British Pat. No. 971,058 discloses that the contact angle of water to the polyethylene surface is reduced by electron radiation.
- the reductionof the contact angle which can be obtained by this vmethod is limited and it is very difficult to reduce the contact angle to less than 50.
- cmooo x (I) in which R is a hydrocarbon group, preferably an alkyl group of eight to 22 carbon atoms, R is hydrogen or a lower alkyl group, M is an organic amino group or a metal, p and q are integers, preferably from one to five, x is preferably from one to three, y is preferably one, or, when M is a metal, x and y are numbers determined by its valence, followed by the preparation of a base material having a surface comprising this mixture, such as a film or laminated paper, and subjecting such surface to a corona discharge treatment.
- alkyl amino groups such as diethylamino and butylamino
- alkanolamino groups such as diethanolamino and propanolamino and the like.
- metals represented by R in the above formula there may be mentioned such metals as calcium, magnesium, aluminum, tin, zinc, iron, copper, lead, barium and the like.
- the above mentioned material (I) has the effect of improving the wettability of polyethylene, the addition of larger amounts of such compounds to polyethylene tends to result in a deterioration of the adhesiveness of the polyethylene to light-sensitive emulsion or undercoating layers. Therefore, the amount thereof to be added is limited.
- Material in accordance with the foregoing structural formula (I) can be synthesized by reacting a higher alkylamine with ethylene oxide of propylene oxide, reacting the product with monochloroacetic acid or its sodium salt and subjecting the resulting reaction product to neutralization with an organic amine, or to double decomposition, to thus obtain the corresponding salt.
- the following reaction schema illustrates this process.
- any of these compounds may be blended in polyethylene in accordance with this invention.
- a very small amount of these compounds is sufficient to achieve the object of the invention.
- Preferred amounts to be incorporated are 0.3 to 0.5% by weight based on the weight of the polyethylene.
- a polyethylene laminated paper it has been found that the addition of more than l% by weight results in gradual deterioration in the adhesiveness between the polyethylene and the paper, although wetting by an emulsion or undercoating agent coated thereon is improved.
- the advantages of this invention can be realized, however, even at proportions exceeding 1%, to some extent. Moreover, the lower limit may be extended, for example, to about 0.1%.
- Addition of the compound may, as occasion demands, be carried out after it is dispersed or dissolved in a high boiling organic solvent.
- the compound, after being added to the polyethylene, is kneaded therewith in an extruder such as those used in film making or film applying.
- the photographic base material of the present invention is a base material, the surface of which, at least, comprises polyethylene containing the foregoing compound.
- polyethylene containing the foregoing compound examples may be mentioned polyethylene film and polyethylene-coated paper, cloth, wood and metal.
- this base material is subjected to a corona discharge, whereby the wettability of the polyethylene surface by light-sensitive emulsions and aqueous undercoating solutions is improved.
- EXAMPLE 1 0.3 Part by weight of material A, represented by the formula was mixed with 100 parts of polyethylene resin pellets manufactured by Nippon Unicar Co., Ltd. (NUC-8008, having a density [ASTM-D-l505-60T] of 0.918 and amelt index [ASTM D-l23857T] of 5.0) and extruded and applied at LII 30C. to a raw base paper of 180 g/m so as to provide a film thickness of about 30 microns, by the use of a T-die extruder.
- a laminated paper was prepared using the polyethylene free from material A. The contact angle with water was measured for both the samples, before and after being subjected to corona discharge treatment.
- the corona discharge treatment was carried out at a discharge power of 35 W, 70 W and 180 W by means of a discharge apparatus made by Lepel Highfrequency Laboratories, Inc. while moving polyethylene laminated paper of 30 cm in width at a rate of 10 m/min through an air gap of 0.8 mm.
- EXAMPLE 2 (CHzCHzOhlI CHILD-N (G1I2ClIzO)21I O [I GU20 O O 3 were mixed, respectively, with parts of high density polyethylene resin pellets manufactured by Showa Denko Co., Ltd. (Sholex 6050, having a density [ASTM-Dl505-6OT] 0.960 and a melt index [ASTM-D-l238-57T] of 5.0) and then formed into films of about 0.1 mm in thickness by the use of a T-die type extruder of 65 mm. Similarly, a material B- free film was prepared for comparison.
- the contact angle was measured for the resulting samples, before and after being subjected to discharge treatment at W by the same apparatus as that of Example 1, to obtain the results tabulated below.
- Sample No discharge Discharge treatment treatment No materialB l5g/1O mm 53 g/lO mm 0.15 part of material B (to 100 parts of polyethylene) 14 66 0.3 part of material B (to 100 parts of polyethylene) 5 l no adhesion
- the photographic light-sensitive emulsion employed above was prepared from a mixture of 70 g of gelatin,-62 g of a silver halide (65 mol.% AgCl, 35 mol %'AgBr) having an average particle size of 0.1 micron and sufficient water to make 1000 cc.
- the method of preparing the emulsion was conventional and included sensitization with sulphur and a gold salt and the incorporation of saponin as a wetting agent and formaldehyde as a hardening agent, as is well known in the art.
- the pH of the prepared emulsion was 6.0.
- a method of making a photographic base material comprising subjecting to corona discharge treatment a base material, the surface of which comprises polyethylene containing a compound represented by the general formula,
- R is a hydrocarbon group of eight to 22 carbon atoms
- R is hydrogen or a lower alkyl group
- M is an organic amino group or a metal
- p and q are integers
- x and y are numbers and, where M is a metal, numbers determined by its valence.
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paper (AREA)
- Medicinal Preparation (AREA)
Abstract
l, numbers determined by its valence.
Description
O Umted States Patent 1151 3,660,142 Kasugai et al. [4 May 2, 1972 [54] METHOD OF MAKING A v p [56] References Cited PHO' IOGRAPHIC BASE MATERIAL UNITED STATES PATENTS [721 lnvemml Kasugai Shizuoka; 3,061,882 11 1962 Wolinski ..204/168 x Kanagawa, both of Japan 3,448,128 6 1969 Marumo et al..... .260/501.13 x 73 Assignee; Fuji photo Ffl Co Ltd. Ashigara 3,555,079 l/i97l Marumo et al. ..260/501.13
Kamigun, Kanagawa, Japan Primary ExaminerAlfred L. Leavitt [22] Had: June 9, 1970 Asxistant Examiner-J. H. Newsome [21] A No,; 44,872 Atr0rneySughrue, Rothwell, Mion, Zinn and Macpeak 57 ABSTRACT [30] Folign Application Priority Data 1 Improving the wettability of photographic base material by in- June 9, 1969 Japan ..44/45271 corporating therein a Small amount Ufa compound having the 1521 US. Cl ..117/93.1 c1), 117/155 UA, 117/161 UF, formula I 204 168, 264 22, 260/501.13, 260/534 M CHR [51] Int. Cl ..B44d l/44 RN [58] Field 61 Search ..117 93.1c1), 155 [1A, 161 UP; 110
204/168; 264/22; 260/534 M, 501.13 on CO0 9 Claims, N0 Drawings METHOD OF MAKING A PHOTOGRAPHIC BASE MATERIAL BACKGROUND OF THE INVENTION 1. Field of the Invention This invention relates to a method of making a photographic base material.
2. Description of the Prior Art The principal object of this invention is to improve the wettability of a photographic base material, such as polyethylene film or polyethylene laminated paper, by undercoating solutions and light-sensitive emulsions.
Since polyethylene possesses very low polarity and wettability by water, as is well known, the use of polyethylene film or polyethylene-coated paper as photographic base materials encounters the disadvantages that light-sensitive emulsions or undercoating solutions cannot be coated uniformly, since sufficient adhesion of the light-sensitive emulsion or undercoating layers to the polyethylene surface cannot be obtained.
For the purpose of overcoming these disadvantages, British Pat. No. 971,058 discloses that the contact angle of water to the polyethylene surface is reduced by electron radiation. The reductionof the contact angle which can be obtained by this vmethod, however, is limited and it is very difficult to reduce the contact angle to less than 50.
SUMMARY OF THE INVENTION cmooo x (I) in which R is a hydrocarbon group, preferably an alkyl group of eight to 22 carbon atoms, R is hydrogen or a lower alkyl group, M is an organic amino group or a metal, p and q are integers, preferably from one to five, x is preferably from one to three, y is preferably one, or, when M is a metal, x and y are numbers determined by its valence, followed by the preparation of a base material having a surface comprising this mixture, such as a film or laminated paper, and subjecting such surface to a corona discharge treatment.
As organic amino groups represented by R in the above formula, there may be mentioned alkyl amino groups, such as diethylamino and butylamino, alkanolamino groups, such as diethanolamino and propanolamino and the like.
As metals represented by R in the above formula, there may be mentioned such metals as calcium, magnesium, aluminum, tin, zinc, iron, copper, lead, barium and the like.
Although the above mentioned material (I) has the effect of improving the wettability of polyethylene, the addition of larger amounts of such compounds to polyethylene tends to result in a deterioration of the adhesiveness of the polyethylene to light-sensitive emulsion or undercoating layers. Therefore, the amount thereof to be added is limited.
In accordance with the method of the present invention, however, it is possible to improve effectively the wettability of the surface of a polyethylene film or polyethylene laminated paper by light-sensitive emulsions without lessening the adhesiveness thereto.
Material in accordance with the foregoing structural formula (I) can be synthesized by reacting a higher alkylamine with ethylene oxide of propylene oxide, reacting the product with monochloroacetic acid or its sodium salt and subjecting the resulting reaction product to neutralization with an organic amine, or to double decomposition, to thus obtain the corresponding salt. The following reaction schema illustrates this process.
olholmmu RNH2 nCIIz-Cli2 RN- (CHzCIIzOMII 5 (CH2CH20)DH (CHzCIDOmI'I RN OlCHzCOOlI v RN+ (CIIzCHzO)qH \CIIZCIIQOXIII CHzCOO- 1O (CHzCIIzOHlH RN+ NH(CH1CH2OH)2 (CHzCHzO)qII CIIzCOO- (CIIzCHz0)pll RN'\ Cmcmomu H CIi'zCOONIIKCILUCH UH)2 2o /(CH2CHzO)pH RN\ 138012 (cmommqrt OH HzCOONa (CHzCHzOWH R-N Ba l (CI-IzCII20)qII OII CHzCOO' 2 Examples of the synthesis of compounds in accordance with formula (I) are are as follows:
SYNTHESIS EXAMPLE 1 amine was reacted with ethylene oxide and then with sodium monochloroacetate. The product was then double-decomposed with barium chloride.
Following the procedures of Synthesis Example 1, stearyl amine was reacted with ethylene oxide and then with sodium monochloroacetate. The product was then double-decomposed with barium chloride to obtain the following compound.
(CIlzCIlzO)pII CIBIIH7N*(CII2CIIZO)QII Ba (1 I=4) on c1120 0 0 z 7 SYNTHESIS EXAMPLE '4 Following the procedures of Synthesis Example 1, stearyl amine was reacted with ethylene oxide and then with sodium monochloroacetate. The product was then double-decomposed with calcium chloride to obtain the following compound.
Any of these compounds may be blended in polyethylene in accordance with this invention. A very small amount of these compounds is sufficient to achieve the object of the invention. Preferred amounts to be incorporated are 0.3 to 0.5% by weight based on the weight of the polyethylene. In the case of a polyethylene laminated paper, it has been found that the addition of more than l% by weight results in gradual deterioration in the adhesiveness between the polyethylene and the paper, although wetting by an emulsion or undercoating agent coated thereon is improved. The advantages of this invention can be realized, however, even at proportions exceeding 1%, to some extent. Moreover, the lower limit may be extended, for example, to about 0.1%. Addition of the compound may, as occasion demands, be carried out after it is dispersed or dissolved in a high boiling organic solvent. The compound, after being added to the polyethylene, is kneaded therewith in an extruder such as those used in film making or film applying.
The photographic base material of the present invention is a base material, the surface of which, at least, comprises polyethylene containing the foregoing compound. As examples of such materials may be mentioned polyethylene film and polyethylene-coated paper, cloth, wood and metal. In the method of the invention, this base material is subjected to a corona discharge, whereby the wettability of the polyethylene surface by light-sensitive emulsions and aqueous undercoating solutions is improved.
The following examples are presented in order to further i1- lustrate the invention without limiting the same.
EXAMPLE 1 0.3 Part by weight of material A, represented by the formula was mixed with 100 parts of polyethylene resin pellets manufactured by Nippon Unicar Co., Ltd. (NUC-8008, having a density [ASTM-D-l505-60T] of 0.918 and amelt index [ASTM D-l23857T] of 5.0) and extruded and applied at LII 30C. to a raw base paper of 180 g/m so as to provide a film thickness of about 30 microns, by the use of a T-die extruder. For comparison, a laminated paper was prepared using the polyethylene free from material A. The contact angle with water was measured for both the samples, before and after being subjected to corona discharge treatment.
The corona discharge treatment was carried out at a discharge power of 35 W, 70 W and 180 W by means of a discharge apparatus made by Lepel Highfrequency Laboratories, Inc. while moving polyethylene laminated paper of 30 cm in width at a rate of 10 m/min through an air gap of 0.8 mm.
The contact angles of water to the surface of the laminated papers treated as above are tabulated below.
Sample No.
discharge 35 W 70 W 150 W Comparison samplepolyethylene alone 94 71 67 66 A-containing polyethylene 60 42 16 7 The measurement of the contact angle was carried out after 60 seconds by the dropping of about 0.001 cc of distilled water and using a contact angle meter of the Goniometer type, model G-l, made by Erma Optical Works Ltd.
When a 2% aqueous solution of gelatin as an undercoating solution was coated onto the foregoing samples at a rate of 25 m/min, only the samples in which the contact angle had been reduced to or less by the method of this invention exhibited good wettability.
EXAMPLE 2 (CHzCHzOhlI CHILD-N (G1I2ClIzO)21I O [I GU20 O O 3 were mixed, respectively, with parts of high density polyethylene resin pellets manufactured by Showa Denko Co., Ltd. (Sholex 6050, having a density [ASTM-Dl505-6OT] 0.960 and a melt index [ASTM-D-l238-57T] of 5.0) and then formed into films of about 0.1 mm in thickness by the use of a T-die type extruder of 65 mm.. Similarly, a material B- free film was prepared for comparison.
The contact angle was measured for the resulting samples, before and after being subjected to discharge treatment at W by the same apparatus as that of Example 1, to obtain the results tabulated below.
(to 100 parts of polyethylene) After the foregoing samples were respectively coated with a photographic light-sensitive emulsion and dried, the adhesive strengths of the emulsions to the polyethylene surfaces were measured to obtain the results tabulated below (by a Schoppers tension tester).
Sample No discharge Discharge treatment treatment No materialB l5g/1O mm 53 g/lO mm 0.15 part of material B (to 100 parts of polyethylene) 14 66 0.3 part of material B (to 100 parts of polyethylene) 5 l no adhesion The photographic light-sensitive emulsion employed above was prepared from a mixture of 70 g of gelatin,-62 g of a silver halide (65 mol.% AgCl, 35 mol %'AgBr) having an average particle size of 0.1 micron and sufficient water to make 1000 cc. The method of preparing the emulsion was conventional and included sensitization with sulphur and a gold salt and the incorporation of saponin as a wetting agent and formaldehyde as a hardening agent, as is well known in the art. The pH of the prepared emulsion was 6.0.
What is claimed is: g
1. A method of making a photographic base material, comprising subjecting to corona discharge treatment a base material, the surface of which comprises polyethylene containing a compound represented by the general formula,
in which R is a hydrocarbon group of eight to 22 carbon atoms, R is hydrogen or a lower alkyl group, M is an organic amino group or a metal, p and q are integers, x and y are numbers and, where M is a metal, numbers determined by its valence. i
2. The method of making a photographic base material according to claim 1, wherein said base material is polyethylene.
3. The method of making a photographic base material according to claim 1, wherein said base material is a polyethylene coated paper.
4. The method of making a photographic base material according to claim 1, wherein said compound is one having the following formula,
5. The method of making a photographic base material according to claim 1, wherein said compound is one having the following formula,
6. The method of making a photographic base material according to claim 1, wherein said compound is one having the following formula,
7. The method of making a photographic base material according to claim 1, wherein said compound is one having the following formula,
Claims (8)
- 2. The method of making a photographic base material according to claim 1, wherein said base material is polyethylene.
- 3. The method of making a photographic base material according to claim 1, wherein said base material is a polyethylene coated paper.
- 4. The method of making a photographic base material according to claim 1, wherein said compound is one having the following formula,
- 5. The method of making a photographic base material according to claim 1, wherein said compound is one having the following formula,
- 6. The method of making a photographic base material according to claim 1, wherein said compound is one having the following formula,
- 7. The method of making a photographic base material according to claim 1, wherein said compound is one having the following formula,
- 8. The method of making a photographic base material according to claim 1, wherein the amount of said compound to be added is 0.3 to 0.5% by weight, based on the amount of said polyethylene.
- 9. The method of making a photographic base material according to claim 1, wherein the amount of said compound to be added is 0.1 to 1.0% by weight, based on the amount of said polyethylene.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP44045271A JPS4937531B1 (en) | 1969-06-09 | 1969-06-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3660142A true US3660142A (en) | 1972-05-02 |
Family
ID=12714634
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US44872A Expired - Lifetime US3660142A (en) | 1969-06-09 | 1970-06-09 | Method of making a photographic base material |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3660142A (en) |
| JP (1) | JPS4937531B1 (en) |
| DE (1) | DE2028380A1 (en) |
| FR (1) | FR2048361A5 (en) |
| GB (1) | GB1286907A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4076743A (en) * | 1976-01-10 | 1978-02-28 | Henkel Kgaa | Novel betaines, processes for the preparation thereof and recovery of underground petroleum therewith |
| US4760176A (en) * | 1985-12-20 | 1988-07-26 | Borg-Warner Chemicals, Inc. | Aminocarboxylic acid-terminated polyoxy-alkylenes and process for the preparation thereof |
| US5192656A (en) * | 1987-04-15 | 1993-03-09 | Fuji Photo Film Co., Ltd. | Silver halide color photographic light-sensitive material |
| US20030148684A1 (en) * | 2002-01-30 | 2003-08-07 | The Procter & Gamble Company | Method for hydrophilizing materials using charged particles |
| US6863933B2 (en) * | 2001-01-30 | 2005-03-08 | The Procter And Gamble Company | Method of hydrophilizing materials |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3061882A (en) * | 1956-06-20 | 1962-11-06 | Du Pont | Process for producing a heat-sealable printable polyethylene structure |
| US3448128A (en) * | 1966-11-28 | 1969-06-03 | Lion Fat Oil Co Ltd | Preparation of metal salts of amphoteric surface active agent |
| US3555079A (en) * | 1969-08-18 | 1971-01-12 | Lion Fat Oil Co Ltd | Preparation of amphoteric surface active agents |
-
1969
- 1969-06-09 JP JP44045271A patent/JPS4937531B1/ja active Pending
-
1970
- 1970-03-12 FR FR7008820A patent/FR2048361A5/fr not_active Expired
- 1970-04-27 GB GB02266/70A patent/GB1286907A/en not_active Expired
- 1970-06-09 US US44872A patent/US3660142A/en not_active Expired - Lifetime
- 1970-06-09 DE DE19702028380 patent/DE2028380A1/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3061882A (en) * | 1956-06-20 | 1962-11-06 | Du Pont | Process for producing a heat-sealable printable polyethylene structure |
| US3448128A (en) * | 1966-11-28 | 1969-06-03 | Lion Fat Oil Co Ltd | Preparation of metal salts of amphoteric surface active agent |
| US3555079A (en) * | 1969-08-18 | 1971-01-12 | Lion Fat Oil Co Ltd | Preparation of amphoteric surface active agents |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4076743A (en) * | 1976-01-10 | 1978-02-28 | Henkel Kgaa | Novel betaines, processes for the preparation thereof and recovery of underground petroleum therewith |
| US4760176A (en) * | 1985-12-20 | 1988-07-26 | Borg-Warner Chemicals, Inc. | Aminocarboxylic acid-terminated polyoxy-alkylenes and process for the preparation thereof |
| US5192656A (en) * | 1987-04-15 | 1993-03-09 | Fuji Photo Film Co., Ltd. | Silver halide color photographic light-sensitive material |
| US6863933B2 (en) * | 2001-01-30 | 2005-03-08 | The Procter And Gamble Company | Method of hydrophilizing materials |
| US20030148684A1 (en) * | 2002-01-30 | 2003-08-07 | The Procter & Gamble Company | Method for hydrophilizing materials using charged particles |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS4937531B1 (en) | 1974-10-09 |
| FR2048361A5 (en) | 1971-03-19 |
| GB1286907A (en) | 1972-08-31 |
| DE2028380A1 (en) | 1970-12-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4327174A (en) | Method of preparing a carrier material for photography | |
| DE69300430T2 (en) | Silver halide photographic material with new gold compound. | |
| DE2205660A1 (en) | PROCESS FOR ANTISTATIC EQUIPMENT OF A PLASTIC FILM OR OF A PLASTIC FILM | |
| US3660142A (en) | Method of making a photographic base material | |
| DE2024003A1 (en) | ||
| DE1954200A1 (en) | Photographic recording material | |
| DE1930343A1 (en) | Photographic films | |
| DE69326457T2 (en) | Silver halide photographic material with improved antistatic properties | |
| US3769022A (en) | Photosensitive silver halide emulsions comprising coating aids | |
| US3047394A (en) | Photosensitive products containing therein layers hardened by bisepoxides | |
| DE69327461T2 (en) | Silver halide photographic material with improved antistatic properties | |
| US3783003A (en) | Process for producing a resin-coated paper as a support for a photographic paper | |
| US3876430A (en) | Antistatic photographic material | |
| US3514293A (en) | Photographic surfactant compositions | |
| JPS584136A (en) | Photographic silver halide element containing antipollution agent or antipollution agent precursor | |
| DE2629843A1 (en) | GELATIN HOLDERS | |
| DE69505339T2 (en) | Processing method for a light-sensitive silver halide photographic material | |
| JPH10333267A (en) | Method for processing silver chloroiodide emulsion | |
| DE69016366T2 (en) | Process for producing an antistatic layer. | |
| DE3331805A1 (en) | PHOTOGRAPHIC, LIGHT-SENSITIVE SILVER HALOGENIDE MATERIAL | |
| DE69523012T2 (en) | Process for developing silver halide photographic material | |
| DE69225081T2 (en) | Vinyl sulfone hardener | |
| DE2163965A1 (en) | Method for curing a synthetic polymer | |
| DE69523425T2 (en) | Silver halide photographic light-sensitive material | |
| EP0023668B1 (en) | Photographic silverhalide emulsion with a stabilizer, process for its production and photographic recording material |