US3637446A - Manufacture of radial-filament spheres - Google Patents

Manufacture of radial-filament spheres Download PDF

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US3637446A
US3637446A US822769*A US3637446DA US3637446A US 3637446 A US3637446 A US 3637446A US 3637446D A US3637446D A US 3637446DA US 3637446 A US3637446 A US 3637446A
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strips
mandrel
hemisphere
sphere
preparing
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US822769*A
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Daniel R Elliott
Edgar Francois
Donald C Macdonald
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UNIROYAL PLASTICS COMPANY Inc WORLD HEADQUARTERS MIDDLEBURY CT 06749 A CORP OF
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Uniroyal Inc
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63BSHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B3/00Hulls characterised by their structure or component parts
    • B63B3/13Hulls built to withstand hydrostatic pressure when fully submerged, e.g. submarine hulls
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/902High modulus filament or fiber
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1002Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
    • Y10T156/1026Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina with slitting or removal of material at reshaping area prior to reshaping
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1002Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
    • Y10T156/1036Bending of one piece blank and joining edges to form article
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1052Methods of surface bonding and/or assembly therefor with cutting, punching, tearing or severing
    • Y10T156/1062Prior to assembly
    • Y10T156/1064Partial cutting [e.g., grooving or incising]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1052Methods of surface bonding and/or assembly therefor with cutting, punching, tearing or severing
    • Y10T156/1062Prior to assembly
    • Y10T156/1075Prior to assembly of plural laminae from single stock and assembling to each other or to additional lamina
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1052Methods of surface bonding and/or assembly therefor with cutting, punching, tearing or severing
    • Y10T156/1082Partial cutting bonded sandwich [e.g., grooving or incising]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1089Methods of surface bonding and/or assembly therefor of discrete laminae to single face of additional lamina

Definitions

  • This invention relates to underwater research and exploration vessels of the type disclosed and claimed in our aforesaid application and there named Radial-Filament Spheres, and in particular to methods of manufacturing such vessels.
  • Hollow vessels capable of withstanding extremely high external pressures are in great demand for oceanographic and various other types of underwater research and exploration, to serve as the load-carrying envelopes for underwater structures, as vehicles for men and/or instruments, and as buoyant elements for attachment to underwater vessels.
  • Such a vessel when made out of a solid, monolithic metal shell has wellknown superior strength characteristics and resistance to buckling under the tremendous compressive stresses to which it is subjected at great depths below the surface of the water, but metallic vessels are disadvantageous in that their strengthto-weight ratio is relatively low, while their weight-to-displacement ratio is relatively high.
  • FIG. 1 is a perspective illustration of a radial-filament sphere constructed of two identical hemispheres each built up in accordance with one aspect of the present invention
  • FIG. 2 is a fragmentary vertical section through the sphere shown in FIG. 1;
  • FIG. 4 is a similar view of the said member as modified prior to use in the actual buildup of the hemispheres
  • FIG. 5 is a plan view of the member shown in FIG. 4 and illustrates a further structural modification thereof which is effected prior to the hemisphere-building operation;
  • FIG. 6 is an elevational view of a partly built-up hemisphere which when completed is to be used in making the sphere of FIG. 1;
  • FIG. 6a is a fragmentary diagrammatic illustration of the manner of building of the hemisphere shown in FIG. 6 from the structural members of FIG. 5;
  • FIG. 8 is a perspective illustration of a radial-filament sphere constructed of two identical hemispheres each built up in accordance with another aspect of the present invention.
  • FIG. 9a is a somewhat enlarged perspective illustration of the starting structural member employed in building up the intermediate member shown in FIG. 9;
  • FIGS. 11 and 12 are schematic elevational viewsof a h emispherical mandrel and illustrate the first two steps in the method of building a radial-filament hemisphere in accordance with yet another aspect of the present invention
  • FIG. 13 is a sectional view taken along the line 13-13 in FIG. 12;
  • FIG. 14 is an elevational view of the mandrel, similar to FIG. 12, and illustrates the next step of the method according to this aspect of the present invention.
  • FIG. 15 is an elevational view of the mandrel, seen at an angle of 45 to the plane of FIG. M, and illustrates further steps of this method
  • FIGS. 16a and 16b are similar views illustrating, respectively, severed parts of the block of FIG. 16 and their reassembly into a relatively thin undirectional slab;
  • FIG. 17 is a fragmentary perspective illustration of the slab of FIG. 16b as cut transversely in the first step of a sphere-constructing method according to yet another aspect of the present invention.
  • FIG. 18 is a perspective illustration of a built-up intermediate structural member made from the cut slab shown in FIG. 17;
  • FIGS. 19, 19a and 19b are side elevational, top plan and end elevational views, respectively, of further intermediate structural members cut from the member of FIG. 18;
  • FIGS. 20 and 20a are perspective illustrations, respectively, of parts of a sphere built up from a multiplicity of the members shown in FIGS. 19 and 19b by further steps of this method.
  • B denotes a rectangularly prismatic structure, composed of a cured resin matrix having embedded therein a great number of filaments (not shown) all oriented parallel to each other in the direction of the double-headed arrow F, and subjected to balanced compressive stresses cr and 0- which are perpendicular both to each other and to the filament direction. Under such conditions, the filaments are also stressed in tension as indicated by the arrows T.
  • each such element of the shell body is composed of a unidirectional filament slab in which all the individual fibers are oriented substantially radially of the sphere and thus normal to the plane of application of the compressive stresses, the fibers in each element of the shell body will be stressed in tension as well as in lateral compression. Thus, no buckling of the filaments can occur, which obviates the requirement of a high degree of straightness in the fibers and effective lateral support by the resin. It will be readily recognized that this is precisely opposite to the situation existing in conventional filament-wound spheres, where transverse buckling of the filament windings is resisted only by the lateral support provided by the resin.
  • the critical pressure P for the buckling of a spherical shell of wall thickness t and radius r is where E is the modulus of elasticity, v is Poisson's ratio, and k is an empirically determinable numerical constant.
  • W/D which is the weight-todisplacement ratio
  • W/D which is the weight-todisplacement ratio
  • glass filaments having a modulus in the range ofabout million to 12% million p.s.i.
  • 1,009 having a modulus of about 430,000 p.s.i.
  • the fiber component of the building elements may include asbestos fibers (modulus in the range of about 24 million to 25 million p.s.i.), boron filaments (modulus in the range of about 50 million to 60 million p.s.i.), carbon filaments (modulus in the range of about million to 70 million p.s.i.), sapphire whiskers, tungsten whiskers, etc.
  • the resin component may be such epoxy resin systems as are marketed by Union Carbide Corporation under the designations ERL-2256" (modulus about 550,000 p.s.i.), "ERRA-0300 (modulus about 720,000 p.s.i.) and "EP-21l4" (modulus about 1,030,000 million p.s.i.), as well as other epoxies, and various other resins such as phenolics, melamines, and the maleic alkyd/styrene copolymer types of polyester resins, characterized by relatively low values of We have found, for example, that an element such as shown in FIG.
  • FIGS. 1 and 2 show a radial-filament hollow sphere 25 constructed of two hemispheres 25a and 25b each built up in accordance with the principles of the present invention.
  • the method here employed which we term the lune or wedge" method, uses as the starting material precured unidirectional sheet composed of a resin matrix, e.g., epoxy resin, and glass or other filaments embedded therein, the filaments extending parallel to each other and to the wide faces of the sheet.
  • the sheet is first severed into a plurality of thin strips 26 (FIG. 3), the direction of cutting being perpendicular to both the direction of the filaments and the plane of the sheet.
  • Each stripitithus has a multitude of short, closely packed filament lengths extending perpendicularly to its wider faces, as in dicated diagrammatically at 26a.
  • the thickness of the strips 26 will, of course, depend on the intended structural and strength characteristics of the sphere to be constructed.
  • Each strip 26 is then cut into the shape of a half-lune or wedgelike member 27 (FIG. 4), and a double-faced, pressuresensitive adhesive tape 28 is applied to one face of each member 27.
  • each member 27 is cut in a gridlike pattern (FIG. 5), severing it to, but not enough, the adhesive tape backing.
  • the bits 27a thus remain adhered to the backing tape, and the assembly thereby has a two-dimensional formability, i.e., the ability to bend somewhat both longitudinally and transversely.
  • FIGS. 6 and 6a The manner in which the various members 27 are built up into the form of a hemisphere 25a (or 25b) is best shown in FIGS. 6 and 6a.
  • the only equipment required for this operation is a destructible spherical mandrel 29 of the appropriate outer diameter, made conveniently of a low-melting alloy, e.g., Woods metal.
  • the building method involves laying the individual wedgelike members onto the mandrel with their respective adhesive tape backings in contact with the mandrel.
  • each such member is applied to the mandrel by initially positioning the wide end 27b parallel to the equator of the mandrel, as indicated in solid lines in FIG.
  • the assembly is vacuum-impregnated on the mandrel with an appropriate thermosetting resin, e.g., epoxy resin, to fill the respective spaces between adjoining members 27 and between adjoining bits 270, and is cured on the mandrel to complete the setting of the filling resin.
  • an appropriate thermosetting resin e.g., epoxy resin
  • the mandrel is removed, as by melting it out, and the interior of the hemisphere is cleaned, at which time the tape 28 is also removed.
  • the annular equatorial surface of the hemisphere is then cut and ground true, so it can mate with another like hemisphere.
  • Two identical hemispheres are finally equatorially joined together by means of an epoxy resin adhesive, for example that marketed by Shell Oil Company under the designation EPON-934.
  • the soassembled sphere is then again subjected to a curing operation to set the adhesive.
  • a wall thickness of 0.180 inch (the component strips being transversely cut to that thickness from a %-inch thick unidirectional sheet of epoxy-bonded glass filaments obtained from the Minnesota Mining and Manufacturing Company and available in various thicknesses) to be sufficient to provide a collapse pressure in excess of 13,000 p.s.i. at a weight-to-displacement ratio of 0.53.
  • a comparable filament-wound and internal ring-stiffened construction having a collapse pressure of 13,600 p.s.i. is found to have a weight-to-displacement ratio of 0.62, the increase of about 17 percent in weight representing a correspondingly reduced payload capability.
  • FIGS. 8 to 10 A somewhat different method, herein termed the one-third octant" method, of building a radial-filament sphere from unidirectional resin and filament sheets is illustrated in FIGS. 8 to 10.
  • the sphere 30 (FIG. 8) is constructed by joining two identical hemispheres 30a and 30b.
  • Each hemisphere is, however, made up of four quadrant sectors 31, each of which is an octant of a sphere, and each quadrant of the hemisphere is made up of three substantially identical, foursided, spherically curved segments 32 (see also FIGS. 9 and 10) the areas and contours of which can be easily calculated from m" es i HEWFEFPL;
  • a number of elongated planar strips 33 (FIG. 9a) somewhat greater than the number required for the segment 32 to be formed is assembled in side-by-side relation and clamped together against a flat surface, with the fibers oriented normal to said surface.
  • a thin sheet 34 of rubber or other flexible material capable of being formed smoothly over a doubly curved surface is then cemented to the entire exposed face of this assembly of strips.
  • the assembled strips are then cut transversely to their lines of juncture, down to but not through the flexible sheet 34, resulting in the formation of a relatively large number of small bits 33a which are cemented only to the rubber sheet but not to each other.
  • This assembly is then laid onto a spherically curved mandrel of proper radius (with the sheet 34 against the mandrel surface) and is impregnated with epoxy resin to fill the numerous essentially V-shaped cracks between the bits.
  • the segment is cleaned of the sheet backing and excess resin, and cut and trimmed to proper contours as shown in FIG. 9.
  • Three such cured segments 32 are then assembled on a hemispherical mandrel and fitted together to constitute a quadrant 31 of the hemisphere, and epoxy resin is applied to the mating or abutting surfaces of the segments and cured to complete the quadrant.
  • FIGS. 11 to 15 Yet another method of building radial-filament spheres according to the present invention is illustrated in FIGS. 11 to 15.
  • this method herein termed the strip” method, elongated strips 35 of unidirectional bits 36 are employed, each strip consisting of an endto-end arrangement of a number of such bits adhered at one face to a double-faced, pressure-sensitive adhesive tape 37 (similar to the tape 28 shown in FIGS. 2, 4 and 6).
  • the filaments are, as before, perpendicular to the tape backing.
  • the method involves first forming an equatorial region, one or more strips in width, alongthe equator of the spherical mandrel 29 (FIG. 11 the strips 35 being secured to the mandrel by the tape.
  • one or more strips 350 are laid along a great circle path across the pole of the mandrel, joining two diametrically opposite sections of the uppermost edge of the topmost equatorial strip 35 (FIGS. 12 and 13).
  • Two quarter-circle strips 35b are then laid onto the mandrel, spaced 90 from strips 35a and extending from opposite sides of polar strips 35a down to the corresponding diametrally opposed sections of the upper edge of the topmost equatorial band 35 (FIG. 14).
  • FIG. 14 two quarter-circle strips 35b are then laid onto the mandrel, spaced 90 from strips 35a and extending from opposite sides of polar strips 35a down to the corresponding diametrally opposed sections of the upper edge of the topmost equatorial band 35 (FIG. 14).
  • FIG. 14 the topmost equatorial band
  • the lowermost strip 35 will preferably extend somewhat below the equator" of the mandrel 29.
  • the cracks are filled in with epoxy resin as previously described, and the entire assembly is cured and, after removal of the mandrel and the tape, machined accurately in the equatorial plane.
  • a complete sphere is then formed, as above, by cementing two such hemispheres to each other along their equatorial edges.
  • Still another method of constructing radial-filament spheres according to the present invention employs as the starting material a block 38 of unidirectional, resin-bonded filaments (FIG. 16), of appropriate transverse dimensions, in which the filaments run lengthwise of the block.
  • the block is cut in planes transverse to the filament direction, as indicated by the lines 39, into a plurality of relatively thin strips 40 which are then laid on their sides (FIG. 16a), assembled in side-by-side relation (FIG. 16b), and cemented to one another at their abutting edges 40a to form a thin panel 41 (similar, but for the joints, to the strip 26 shown in FIG. 3).
  • the thickness of each of the strips 40 cut from the block 3% will be equal to the desired wall thickness of the ultimate spherical shell body.
  • the flat panel 41 having all filaments oriented normal to its broad faces, is then severed along oblique planes, as indicated by the lines 42 (FIG. 17), to provide a plurality of relatively narrow strips 43 of essentially trapezoidal cross section. These strips are then separated, alternate ones are inverted, and all are reassembled and cemented along their abutting faces 434 (FIG. 18), resulting in the formation of a sector 44 of a right circular cylinder (FIG. 18).
  • a sector 44 of a right circular cylinder FIG. 18
  • the cylindrically curved sector 44 having the individual fiber lengths extending perpendicularly to the inner and outer surfaces of the sector, is then severed into a plurality of strips 45 (FIGS. 19, 19a and 1912) by making suitable paired oblique planar cuts through the sector 44 in the circumferential direction thereof, as indicated by the dot-dash lines 46-46a in FIG. 18, the paired planes of cutting being so oriented as to intersect at the axis of curvature of the sector 44.
  • a sufficient number of such strips 45 is then reassembled and cemented to each other in side-by-side relation (after the removal of the waste material resulting form the cutting operation) and the cement cured to form a barrellike body 47 (FIG. 20) essentially having the shape of a spherical segment of two bases but differing therefrom slightly in that the annular edge surface 47a of each cutoff area is a zone of a cone having its apex at the center of the sphere.
  • the body 47 may be formed by first building up a plurality of intermediate members in the shape of spherical sectors (now shown) from the strips 45 and then assembling such sectors into the final configuration shown in FIG. 20.
  • a second such barrellike body or a substantial lesser part thereof e.g., a spherical sector of sufficient areal size, is assembled and cured in the same manner to provide two blanks from which two complementary polar caps 48 (only one is shown in FIG. 20a) having boundary edge surfaces 48a mated in size and orientation to the surfaces 47a of the body 47 can be derived, e.g., machined, these caps then being cemented and cured to the body 47 to complete the sphere, as indicated in phantom outline in FIG. 20.
  • a spherically curved sector built up from the strips 45 may be trimmed, cut, precision ground, etc., in any desired manner, for example to the dimensions of a one-third quadrant of a hemisphere as explained hereinbefore in connection with FIGS. 8 to 10, or it may be employed as any other portion of a spherical shell which can be bonded to suitably mated shell segments to complete the desired sphere.
  • the radial-filament configuration of the present invention is circumferentially isotropic, i.e., it is equally effective in all circumferential directions, whereas in conventional filament-wound structures a given filament provides support primarily in a single direction, which makes it approximately one-half as effective as the filaments in the structures according to the present invention.
  • the uncurred unidirectional filament and resin material which is used to make the basic building elements of the spheres, generally is relatively resin-rich (resin about 35 to 50 percent of the total volume) and thus has a maximum filament content of about 65 percent.
  • a filament content above about 65 percent and preferably in the range of about 75 to 90 percent of the total volume. This condition can be readily achieved by squeezing out some of the resin from the uncured material prior to the curing thereof. The reason is that with a higher filament content in the shell wall, the sphere can withstand higher external hydrostatic pressures.
  • the principles of the present invention can also be implemented by using the original material of unreduced resin content, it being understood that the critical pressure rating of a sphere so produced will be somewhat lower than that of a sphere having a reduced resin content and thus an increased fiber content.
  • a radial-filament sphere 3 inches in diameter by the method of FIGS. 11 to 15 described herein, from fiberglassepoxy prepreg tape having a resin of modulus 430,000 p.s.i. and glass of modulus 12,400,000 million p.s.i. (supplied by Minnesota Mining and Manufacturing Company under the designation l009-26S).
  • the volume fraction of filaments present in the sphere was 77 percent, and the sphere had a weight-to-displacement ratio (W/D) of 0.50. In actual tests, this sphere sustained an external hydrostatic pressure of 25,000 p.s.i. without failure.
  • the method of constructing a radial-filament, spherically curved, hollow shell-type body comprising the steps of preparing a plurality of sheetlike members of a unidirectional fiber-reinforced resin in each of which members all the individual fiber lengths are oriented substantially normal to the broad faces of that member, building said body by assembling a plurality of said members in laterally adjacent relation and in a spherically curved configuration so as to dispose said fiber lengths substantially radially of said body, filling all cracks and spaces between said assembled members with a material comprising a thermosetting resin to complete said body, and treating said body to cure any still uncured resin part thereof.
  • the method of constructing a radial-filament, spherically curved, hollow shell-type body comprising the steps of preparing a plurality of flat sheetlike members of a cured, unidirectional fiber-reinforced resin in each of which members all the individual fiber lengths are oriented substantially normal to the broad faces of that member, building said body by assembling a plurality of said members in laterally adjacent relation and in a spherically curved configuration so as to dispose said fiber lengths substantially radially of said body, filling all cracks and spaces between said assembled members with a material comprising a thermosetting resin to complete said body, and curing the resin filling.
  • the method of constructing a hollow radial-filament sphere comprising the steps preparing a plurality of flat, wedgelike strips of precured, high-modulus, unidirectional fiber-reinforced thermosetting resin wherein all the individual fiber lengths are oriented substantially normal to the broad faces of said strips, applying a double-faced pressure-sensitive adhesive tape to one face of each strip, cutting a grid of mutually perpendicular longitudinal and transverse incisions into and through each strip to said tape from the other face of said strip so that the severed bits remain attached to said tape, assembling said severed strips on a spherically curved mandrel so that the wide end of each strip overlies the equatorial line of the mandrel and that the narrow ends of said strips meet at the pole of the mandrel, thereby defining a hemisphere having all the fibers oriented substantially radially, said adhesive tapes serving to retain said strips in position on said mandrel, and said incisions enabling said strips to curve in
  • the method of constructing a hollow radial-filament sphere comprising the steps of preparing a plurality of flat small blocks of a precured, unidirectional high-modulus fiberreinforced thermosetting resin, all the individual fiber lengths in each block being oriented substantially normal to the opposite plane faces thereof, applying a respective double-faced, pressure-sensitive adhesive tape to one face of each of a plurality of elongated series of said blocks to define a plurality of strips, assembling said strips into the shape of a hemisphere on a spherically curved mandrel y first applying at least one strip to the mandrel as an equatorial band, then at least one strip over the pole of the mandrel from one end to the diametrically opposite edge of said equatorial hand, then at least one strip on each side of said edge-to-edge band transverse to the latter and extending from the opposite sides thereof to the equatorial hand, then angularly oriented strips within each of the a
  • the method of constructing a hollow radial-filament sphere comprising the steps of preparing a flat sheet of a precured, unidirectional high modulus fiber-reinforced thermosetting resin, all the individual fiber lengths in said sheet being oriented substantially normal to the opposite planefaces thereof, making a plurality of side-by-side transverse cuts in said sheet, with adjacent cuts being alternatively oriented in equiangular converging and diverging relation to each other, thereby to define a plurality of rectilinear strips of trapezoidal cross section, inverting alternate ones of said strips in situ and recementing all the strips to define a cylindrically curved sector, making a plurality of pairs of side-by-side cuts in said sector at axially spaced locations therein, with each pair of such cuts being made on respective equally but oppositely oblique planes oriented to intersect at the axis of said sector along a line perpendicular to said axis, thereby to define a plurality of curved strips having equally inward

Abstract

Making a shell-type body of spherical curvature by various methods which include the butt edge bonding in a spherical configuration of segments of resin/reinforced by short length high-modulus filaments extending substantially normal to the inner and outer surfaces of the segments and preferably through the entire segment thickness whereby the filaments are disposed generally radially with respect to the curvature of the body. Complete spheres of this construction are particularly suited for deep submergence work under high-external hydrostatic pressures, being characterized by a low weight to displacement ratio and a high-compressive strength to weight ratio. The full nature and extent of the invention is discernable only by reference to the entire disclosure.

Description

TJnited States atent Elliott et al.
[ 1 .lan.2,1972
[ 41 MANUFACTURE OF RADIAL- FILAMENT SPHERES [72] Inventors: Daniel R. Elliott, Ridgewood; lEdgar Francois, Wayne; Donald C. MacDonald, Ridgewood, all of NJ.
Related [1.8. Application Data [62] Division of Ser. No. 522,675, Jan. 24, 1966, Pat. No.
[52] U.S.Cl ..156/69,156/182,156/211, 156/217, 156/257, 156/264,156/268, 156/292, 156/297, 156/304 3,042,562 7/1962 Peterson ..l56/257 X 1,027,571 5/1912 Siegwart ..156/297 X 2,510,213 6/1950 Ekstedt et a1. .....l56/2l1 X 2,762,739 9/1956 Weiss ..156/292 X 2,949,953 8/1960 Maio et a1 ..156/297 X 2,998,637 9/1961 Wallis ..l56/211 X 3,117,902 1/1968 Holsheimer ..156/217 Primary ExaminerCar1 D. Quarforth Assistant ExaminerE. A. Miller AttorneyNorbert P. Holler [5 7] ABSTRACT Making a shell-type body of spherical curvature by various methods which include the butt edge bonding in a spherical configuration of segments of resin/reinforced by short length high-modulus filaments extending substantially normal to the inner and outer surfaces of the segments and preferably through the entire segment thickness whereby the filaments are disposed generally radially with respect to the curvature of the body. Complete spheres of this construction are particularly suited for deep submergence work under high-extemal hydrostatic pressures, being characterized by a low weight to displacement ratio and a high-compressive strength to weight ratio. The full nature and extent of the invention is discemable only by reference to the entire disclosure.
6 Claims, 27 Drawing Figures PATENTED M25 1232 SHEET 1 OF 4 0 8 Z RT A a a E mwwwm W4 0 0 pm I a c Em M w% v! B PATENTFU M25 @372 SHEET 3 BF 4 JUL numnmnmu/ mmmnmmm 15w ZNVENTORJ T 22% flaw? ;7-Z56 y OO/VAZO LXMacflOA/AZO 0 lllllllllllllllll'HlllllllillllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllI W sued Jan. 20, 1970.
This invention relates to underwater research and exploration vessels of the type disclosed and claimed in our aforesaid application and there named Radial-Filament Spheres, and in particular to methods of manufacturing such vessels.
Hollow vessels capable of withstanding extremely high external pressures are in great demand for oceanographic and various other types of underwater research and exploration, to serve as the load-carrying envelopes for underwater structures, as vehicles for men and/or instruments, and as buoyant elements for attachment to underwater vessels. Such a vessel when made out of a solid, monolithic metal shell has wellknown superior strength characteristics and resistance to buckling under the tremendous compressive stresses to which it is subjected at great depths below the surface of the water, but metallic vessels are disadvantageous in that their strengthto-weight ratio is relatively low, while their weight-to-displacement ratio is relatively high.
It is an important object of the present invention to provide novel methods of manufacturing radial-filament spheres which are capable of withstanding high external pressures and which are possessed of relatively high ratios of compressive strength to weight and of elastic stability to weight, and of a relatively low ratio of weight to displacement.
It is another object of the present invention to provide methods of making resin and fiber shell-type bodies of spherical curvature which are characterized by the fact that all the fibers in each such body are oriented substantially radially thereof and which can be assembled from structural elements made of unidirectional filament-reinforced resin.
The foregoing and other objects of the present invention, as well as the characteristics and advantages thereof, will be more clearly understood from the following detailed description of preferred embodiments of the invention when read in conjunction with the accompanying drawings, in which:
FIG. 1 is a perspective illustration of a radial-filament sphere constructed of two identical hemispheres each built up in accordance with one aspect of the present invention;
FIG. 2 is a fragmentary vertical section through the sphere shown in FIG. 1;
FIG. 3 is a perspective elevational view of the starting basic structural member employed in large numbers in the manufacture of the sphere shown in FIGS. 1 and 2;
FIG. 4 is a similar view of the said member as modified prior to use in the actual buildup of the hemispheres;
FIG. 5 is a plan view of the member shown in FIG. 4 and illustrates a further structural modification thereof which is effected prior to the hemisphere-building operation;
FIG. 6 is an elevational view of a partly built-up hemisphere which when completed is to be used in making the sphere of FIG. 1;
FIG. 6a is a fragmentary diagrammatic illustration of the manner of building of the hemisphere shown in FIG. 6 from the structural members of FIG. 5;
FIG. 7 is a diagrammatic illustration of the effect of compressive stresses on a unidirectional or parallel filament member of the type employed in the practice of the present invention;
FIG. 8 is a perspective illustration of a radial-filament sphere constructed of two identical hemispheres each built up in accordance with another aspect of the present invention;
FIG. 9 is a plan view of a built-up intermediate structural member employed in building up the hemispheres used in constructing the sphere shown in FIG. 8;
FIG. 9a is a somewhat enlarged perspective illustration of the starting structural member employed in building up the intermediate member shown in FIG. 9;
FIG. 10 is a side elevational view of the said intermediate member, taken along the line 10-10 in FIG. 9;
FIGS. 11 and 12 are schematic elevational viewsof a h emispherical mandrel and illustrate the first two steps in the method of building a radial-filament hemisphere in accordance with yet another aspect of the present invention;
FIG. 13 is a sectional view taken along the line 13-13 in FIG. 12;
FIG. 14 is an elevational view of the mandrel, similar to FIG. 12, and illustrates the next step of the method according to this aspect of the present invention;
FIG. 15 is an elevational view of the mandrel, seen at an angle of 45 to the plane of FIG. M, and illustrates further steps of this method;
FIG. 16 is a perspective view of a large block of undirectional filament-reinforced resin which can be employed as the basic starting material for the construction of radial-filament spheres in accordance with the present invention;
FIGS. 16a and 16b are similar views illustrating, respectively, severed parts of the block of FIG. 16 and their reassembly into a relatively thin undirectional slab;
FIG. 17 is a fragmentary perspective illustration of the slab of FIG. 16b as cut transversely in the first step of a sphere-constructing method according to yet another aspect of the present invention;
FIG. 18 is a perspective illustration of a built-up intermediate structural member made from the cut slab shown in FIG. 17;
FIGS. 19, 19a and 19b are side elevational, top plan and end elevational views, respectively, of further intermediate structural members cut from the member of FIG. 18; and
FIGS. 20 and 20a are perspective illustrations, respectively, of parts of a sphere built up from a multiplicity of the members shown in FIGS. 19 and 19b by further steps of this method.
Generally speaking, the present invention provides methods of manufacturing radial-filament spheres the theory underlying the construction of which is based on the fact that, when a three-dimensional structure composed of a cured thermosetting resin matrix having embedded therein a multiplicity of parallel, unidirectional, high-modulus filaments is subjected to bidirectional compressive stresses normal to each other and to the filament orientation, the filaments are additionally stressed in tension. This is diagrammatically illustrated in FIG. 7 wherein B denotes a rectangularly prismatic structure, composed of a cured resin matrix having embedded therein a great number of filaments (not shown) all oriented parallel to each other in the direction of the double-headed arrow F, and subjected to balanced compressive stresses cr and 0- which are perpendicular both to each other and to the filament direction. Under such conditions, the filaments are also stressed in tension as indicated by the arrows T.
In a hollow spherical vessel subjected to external hydrostatic pressure over its entire surface, the external pressure is opposed by balanced circumferential stresses in the wall of the vessel, and any given element of such a body can thus be considered as being subjected to two perpendicular compressive stresses, both essentially parallel to the surface. The general equation for the circumferential stress in a spherical shell under external hydrostatic pressure is 1 a=Pr/ 1 2t where P is the unit pressure, r is the mean radius of the sphere, and t is the wall thickness of the shell. If, now, each such element of the shell body is composed of a unidirectional filament slab in which all the individual fibers are oriented substantially radially of the sphere and thus normal to the plane of application of the compressive stresses, the fibers in each element of the shell body will be stressed in tension as well as in lateral compression. Thus, no buckling of the filaments can occur, which obviates the requirement of a high degree of straightness in the fibers and effective lateral support by the resin. It will be readily recognized that this is precisely opposite to the situation existing in conventional filament-wound spheres, where transverse buckling of the filament windings is resisted only by the lateral support provided by the resin.
It can be shown that the critical pressure P, for the buckling of a spherical shell of wall thickness t and radius r is where E is the modulus of elasticity, v is Poisson's ratio, and k is an empirically determinable numerical constant. Deep submergence vessels are also generally characterized by a figure of merit M which is defined by the relation (3 M=W/D where W is the weight of the vessel, and D is the weight of the water displaced thereby. For a given value of the critical pressure for buckling, the quantity W/D, which is the weight-todisplacement ratio, is related to the nature of the material of which the vessel is made by the proportionality W/D-p/ where p is the density of the wall material. It will be evident that a low value for the ratio W/D represents a large payload capability for the vessel, and from equation (1) that the wall thickness 1 should be in direct proportion to the radius of the vessel, so that vessels of different sizes will have the same pressure capabilities.
From equations (2) to (4) it can be seen, therefore, that for a sphere of a given size and intended for a specified critical pressure, better performance (lower W/D) results from a higher modulus E, which permits a decreased wall thickness 1, and from a lower density p. Efi'ective implementation of the principles outlined above thus entails the use of unidirectional fiber and resin building elements having an optimally low value of ph E, a ratio which decreases as E increases, E in this case being he transverse modulus of the element (i.e., the modulus perpendicular to the filament direction). It is preferred to employ both resin and fiber components of high modulus, since both contribute to the transverse modulus of the composite element. Nevertheless, it will be understood that other factors, e.g., permissible density, weight, etc., may place limitations on the choice of resin and/or fiber for the elements.
Merely by way of example, we have found that excellent results are achieved by using glass filaments (having a modulus in the range ofabout million to 12% million p.s.i.) as the fiber component in a resin matrix composed of an epoxy resin system marketed by Minnesota Mining and Manufacturing Company under the designation 1,009" (having a modulus of about 430,000 p.s.i.). Alternatively, the fiber component of the building elements may include asbestos fibers (modulus in the range of about 24 million to 25 million p.s.i.), boron filaments (modulus in the range of about 50 million to 60 million p.s.i.), carbon filaments (modulus in the range of about million to 70 million p.s.i.), sapphire whiskers, tungsten whiskers, etc. The resin component may be such epoxy resin systems as are marketed by Union Carbide Corporation under the designations ERL-2256" (modulus about 550,000 p.s.i.), "ERRA-0300 (modulus about 720,000 p.s.i.) and "EP-21l4" (modulus about 1,030,000 million p.s.i.), as well as other epoxies, and various other resins such as phenolics, melamines, and the maleic alkyd/styrene copolymer types of polyester resins, characterized by relatively low values of We have found, for example, that an element such as shown in FIG. 7 and composed of an epoxy resin matrix (Minnesota Mining and Manufacturing Companys type l009) having embedded therein unidirectional filaments of 8" glass (77 percent of the total volume) can withstand balanced compressive stresses of 165,000 p.s.i. in each of the 0" and 0" directions.
FIGS. 1 and 2 show a radial-filament hollow sphere 25 constructed of two hemispheres 25a and 25b each built up in accordance with the principles of the present invention. The method here employed, which we term the lune or wedge" method, uses as the starting material precured unidirectional sheet composed of a resin matrix, e.g., epoxy resin, and glass or other filaments embedded therein, the filaments extending parallel to each other and to the wide faces of the sheet. The sheet is first severed into a plurality of thin strips 26 (FIG. 3), the direction of cutting being perpendicular to both the direction of the filaments and the plane of the sheet. Each stripitithus has a multitude of short, closely packed filament lengths extending perpendicularly to its wider faces, as in dicated diagrammatically at 26a. The thickness of the strips 26 will, of course, depend on the intended structural and strength characteristics of the sphere to be constructed.
Each strip 26 is then cut into the shape of a half-lune or wedgelike member 27 (FIG. 4), and a double-faced, pressuresensitive adhesive tape 28 is applied to one face of each member 27. As the final preparatory step, each member 27 is cut in a gridlike pattern (FIG. 5), severing it to, but not enough, the adhesive tape backing. The bits 27a thus remain adhered to the backing tape, and the assembly thereby has a two-dimensional formability, i.e., the ability to bend somewhat both longitudinally and transversely.
The manner in which the various members 27 are built up into the form of a hemisphere 25a (or 25b) is best shown in FIGS. 6 and 6a. The only equipment required for this operation is a destructible spherical mandrel 29 of the appropriate outer diameter, made conveniently of a low-melting alloy, e.g., Woods metal. As is clearly apparent, the building method involves laying the individual wedgelike members onto the mandrel with their respective adhesive tape backings in contact with the mandrel. Thus, each such member is applied to the mandrel by initially positioning the wide end 27b parallel to the equator of the mandrel, as indicated in solid lines in FIG. 6a, and then bending the wedgelike strip over into its final, curved, mandrel-conforming position, as indicated in broken lines in FIG. 60, so that the apex 27c of the member or strip 27 essentially reaches the pole of the mandrel. It should be understood that in actual practice it will be preferable to use half-lunes or wedgelike members 27 of such sizes that when they are adhered to the mandrel, their wider ends 27b are located slightly below the mandrel "equator," for a reason which will become clear as the description proceeds.
After this building operation has been completed, the assembly is vacuum-impregnated on the mandrel with an appropriate thermosetting resin, e.g., epoxy resin, to fill the respective spaces between adjoining members 27 and between adjoining bits 270, and is cured on the mandrel to complete the setting of the filling resin. Thereafter, the mandrel is removed, as by melting it out, and the interior of the hemisphere is cleaned, at which time the tape 28 is also removed. The annular equatorial surface of the hemisphere is then cut and ground true, so it can mate with another like hemisphere. Two identical hemispheres are finally equatorially joined together by means of an epoxy resin adhesive, for example that marketed by Shell Oil Company under the designation EPON-934. The soassembled sphere is then again subjected to a curing operation to set the adhesive.
For a radial-filament sphere of this type, having a 3-inch inner diameter, we have found a wall thickness of 0.180 inch (the component strips being transversely cut to that thickness from a %-inch thick unidirectional sheet of epoxy-bonded glass filaments obtained from the Minnesota Mining and Manufacturing Company and available in various thicknesses) to be sufficient to provide a collapse pressure in excess of 13,000 p.s.i. at a weight-to-displacement ratio of 0.53. A comparable filament-wound and internal ring-stiffened construction having a collapse pressure of 13,600 p.s.i. is found to have a weight-to-displacement ratio of 0.62, the increase of about 17 percent in weight representing a correspondingly reduced payload capability.
A somewhat different method, herein termed the one-third octant" method, of building a radial-filament sphere from unidirectional resin and filament sheets is illustrated in FIGS. 8 to 10. As before, the sphere 30 (FIG. 8) is constructed by joining two identical hemispheres 30a and 30b. Each hemisphere is, however, made up of four quadrant sectors 31, each of which is an octant of a sphere, and each quadrant of the hemisphere is made up of three substantially identical, foursided, spherically curved segments 32 (see also FIGS. 9 and 10) the areas and contours of which can be easily calculated from m" es i HEWFEFPL;
As the first step of the hemisphere-building method according to this aspect of the present invention, a number of elongated planar strips 33 (FIG. 9a) somewhat greater than the number required for the segment 32 to be formed is assembled in side-by-side relation and clamped together against a flat surface, with the fibers oriented normal to said surface. A thin sheet 34 of rubber or other flexible material capable of being formed smoothly over a doubly curved surface is then cemented to the entire exposed face of this assembly of strips. The assembled strips are then cut transversely to their lines of juncture, down to but not through the flexible sheet 34, resulting in the formation of a relatively large number of small bits 33a which are cemented only to the rubber sheet but not to each other. This assembly is then laid onto a spherically curved mandrel of proper radius (with the sheet 34 against the mandrel surface) and is impregnated with epoxy resin to fill the numerous essentially V-shaped cracks between the bits. After the resin filling is cured, the segment is cleaned of the sheet backing and excess resin, and cut and trimmed to proper contours as shown in FIG. 9. Three such cured segments 32 are then assembled on a hemispherical mandrel and fitted together to constitute a quadrant 31 of the hemisphere, and epoxy resin is applied to the mating or abutting surfaces of the segments and cured to complete the quadrant. Four such quadrants, properly trimmed, are assembled on a spherical mandrel, and epoxy resin is applied to their mating surfaces and cured, to complete the hemisphere (30a or 30b). Two such hemispheres are thereafter equatorially joined as before by an epoxy resin bond to complete the sphere.
Yet another method of building radial-filament spheres according to the present invention is illustrated in FIGS. 11 to 15. In this method, herein termed the strip" method, elongated strips 35 of unidirectional bits 36 are employed, each strip consisting of an endto-end arrangement of a number of such bits adhered at one face to a double-faced, pressure-sensitive adhesive tape 37 (similar to the tape 28 shown in FIGS. 2, 4 and 6). The filaments are, as before, perpendicular to the tape backing. The method involves first forming an equatorial region, one or more strips in width, alongthe equator of the spherical mandrel 29 (FIG. 11 the strips 35 being secured to the mandrel by the tape. Thereafter, one or more strips 350 are laid along a great circle path across the pole of the mandrel, joining two diametrically opposite sections of the uppermost edge of the topmost equatorial strip 35 (FIGS. 12 and 13). Two quarter-circle strips 35b are then laid onto the mandrel, spaced 90 from strips 35a and extending from opposite sides of polar strips 35a down to the corresponding diametrally opposed sections of the upper edge of the topmost equatorial band 35 (FIG. 14). At this stage, therefore, there are still open four spherically triangular sections of the hemisphere. These are then filled in progressively by applying further strips 350 etc., (FIG. 15) cut to suitable shape where they meet corners of the respective triangles. It is again noted that in actual practice the lowermost strip 35 will preferably extend somewhat below the equator" of the mandrel 29. After the hemisphere has been completed in this manner, the cracks are filled in with epoxy resin as previously described, and the entire assembly is cured and, after removal of the mandrel and the tape, machined accurately in the equatorial plane. A complete sphere is then formed, as above, by cementing two such hemispheres to each other along their equatorial edges.
Still another method of constructing radial-filament spheres according to the present invention, herein designated the barrel" method, employs as the starting material a block 38 of unidirectional, resin-bonded filaments (FIG. 16), of appropriate transverse dimensions, in which the filaments run lengthwise of the block. The block is cut in planes transverse to the filament direction, as indicated by the lines 39, into a plurality of relatively thin strips 40 which are then laid on their sides (FIG. 16a), assembled in side-by-side relation (FIG. 16b), and cemented to one another at their abutting edges 40a to form a thin panel 41 (similar, but for the joints, to the strip 26 shown in FIG. 3). It will be understood that the thickness of each of the strips 40 cut from the block 3% will be equal to the desired wall thickness of the ultimate spherical shell body.
The flat panel 41, having all filaments oriented normal to its broad faces, is then severed along oblique planes, as indicated by the lines 42 (FIG. 17), to provide a plurality of relatively narrow strips 43 of essentially trapezoidal cross section. These strips are then separated, alternate ones are inverted, and all are reassembled and cemented along their abutting faces 434 (FIG. 18), resulting in the formation of a sector 44 of a right circular cylinder (FIG. 18). Merely by way of example, for the member 44 enough strips 43 are employed to form a 90 sector. (It should be understood that the elements 43 are drawn to a greatly enlarged scale in FIGS. 17 and 18 and that actually many more than five strips will be required to make up such a sector 44.) The cylindrically curved sector 44, having the individual fiber lengths extending perpendicularly to the inner and outer surfaces of the sector, is then severed into a plurality of strips 45 (FIGS. 19, 19a and 1912) by making suitable paired oblique planar cuts through the sector 44 in the circumferential direction thereof, as indicated by the dot-dash lines 46-46a in FIG. 18, the paired planes of cutting being so oriented as to intersect at the axis of curvature of the sector 44.
A sufficient number of such strips 45 is then reassembled and cemented to each other in side-by-side relation (after the removal of the waste material resulting form the cutting operation) and the cement cured to form a barrellike body 47 (FIG. 20) essentially having the shape of a spherical segment of two bases but differing therefrom slightly in that the annular edge surface 47a of each cutoff area is a zone of a cone having its apex at the center of the sphere. It will be clear, of course, that the body 47 may be formed by first building up a plurality of intermediate members in the shape of spherical sectors (now shown) from the strips 45 and then assembling such sectors into the final configuration shown in FIG. 20. By virtue of the initial formation of a 90 cylindrical sector 44, therefore, the body 47 extends 45 from either side of the equator" of the sphere, but this can obviously be varied as desired. Finally, a second such barrellike body or a substantial lesser part thereof, e.g., a spherical sector of sufficient areal size, is assembled and cured in the same manner to provide two blanks from which two complementary polar caps 48 (only one is shown in FIG. 20a) having boundary edge surfaces 48a mated in size and orientation to the surfaces 47a of the body 47 can be derived, e.g., machined, these caps then being cemented and cured to the body 47 to complete the sphere, as indicated in phantom outline in FIG. 20.
Alternatively, a spherically curved sector (not shown) built up from the strips 45 may be trimmed, cut, precision ground, etc., in any desired manner, for example to the dimensions of a one-third quadrant of a hemisphere as explained hereinbefore in connection with FIGS. 8 to 10, or it may be employed as any other portion of a spherical shell which can be bonded to suitably mated shell segments to complete the desired sphere.
Despite differences in the various above-described methods of construction, all spheres built up in accordance with the principles of the present invention will perform substantially equally well under identical environmental conditions, subject to the qualification that the presence of the resin-filled V- joints or spaces between adjoining elements in the spheres produced by the lune, one-third octant" and strip methods of construction dilutes slightly the effective modulus of the shell and thus effects a corresponding decrease in its critical pressure It will be apparent, however, that such V- spaces may be filed with tapered pieces of unidirectional fiberreinforced resin cut from the same material as the other elements, which pieces would be cemented in place with the fiber lengths therein also oriented substantially radially of the sphere, whereby the aforesaid slight decrease in the effective modulus and critical pressure could be avoided. In the barrel method, of course, no such considerations arise since the building elements 43 and 45 are cut obliquely so that the abutting faces meet without substantial cracks or spaces therebetween. In any event, the effectiveness of all these spheres in sustaining extremely high external pressures stems directly from the radial orientation of the filaments which provides, under conditions of balanced biaxial stress, strength and elastic stability far beyond those of conventional filamentwound constructions. Stated in other words, the radial-filament configuration of the present invention is circumferentially isotropic, i.e., it is equally effective in all circumferential directions, whereas in conventional filament-wound structures a given filament provides support primarily in a single direction, which makes it approximately one-half as effective as the filaments in the structures according to the present invention.
It should also be noted that the uncurred unidirectional filament and resin material, which is used to make the basic building elements of the spheres, generally is relatively resin-rich (resin about 35 to 50 percent of the total volume) and thus has a maximum filament content of about 65 percent. We have found it advantageous, however, to use a filament content above about 65 percent and preferably in the range of about 75 to 90 percent of the total volume. This condition can be readily achieved by squeezing out some of the resin from the uncured material prior to the curing thereof. The reason is that with a higher filament content in the shell wall, the sphere can withstand higher external hydrostatic pressures. Nevertheless, the principles of the present invention can also be implemented by using the original material of unreduced resin content, it being understood that the critical pressure rating of a sphere so produced will be somewhat lower than that of a sphere having a reduced resin content and thus an increased fiber content.
As an example of the present invention, we have constructed a radial-filament sphere 3 inches in diameter, by the method of FIGS. 11 to 15 described herein, from fiberglassepoxy prepreg tape having a resin of modulus 430,000 p.s.i. and glass of modulus 12,400,000 million p.s.i. (supplied by Minnesota Mining and Manufacturing Company under the designation l009-26S). The volume fraction of filaments present in the sphere was 77 percent, and the sphere had a weight-to-displacement ratio (W/D) of 0.50. In actual tests, this sphere sustained an external hydrostatic pressure of 25,000 p.s.i. without failure.
Still further advantages of the radial-filament spheres or shell bodies constructed by the methods of the present invention are set forth in our aforesaid application, and reference may be had to said application for details.
It is to be understood that the foregoing description is for purposes of illustration only, and that the structural and procedural features and relationships as well as the types, ranges and proportions of component materials disclosed herein are merely representative and are susceptible to various changes and modifications none of which entails a departure from the spirit and scope of the present invention as defined in the hereto appended claims.
Having thus described our invention, what we claim and desire to protect by Letters Patent is:
l. The method of constructing a radial-filament, spherically curved, hollow shell-type body, comprising the steps of preparing a plurality of sheetlike members of a unidirectional fiber-reinforced resin in each of which members all the individual fiber lengths are oriented substantially normal to the broad faces of that member, building said body by assembling a plurality of said members in laterally adjacent relation and in a spherically curved configuration so as to dispose said fiber lengths substantially radially of said body, filling all cracks and spaces between said assembled members with a material comprising a thermosetting resin to complete said body, and treating said body to cure any still uncured resin part thereof.
2. The method of constructing a radial-filament, spherically curved, hollow shell-type body, comprising the steps of preparing a plurality of flat sheetlike members of a cured, unidirectional fiber-reinforced resin in each of which members all the individual fiber lengths are oriented substantially normal to the broad faces of that member, building said body by assembling a plurality of said members in laterally adjacent relation and in a spherically curved configuration so as to dispose said fiber lengths substantially radially of said body, filling all cracks and spaces between said assembled members with a material comprising a thermosetting resin to complete said body, and curing the resin filling.
3. The method of constructing a hollow radial-filament sphere, comprising the steps preparing a plurality of flat, wedgelike strips of precured, high-modulus, unidirectional fiber-reinforced thermosetting resin wherein all the individual fiber lengths are oriented substantially normal to the broad faces of said strips, applying a double-faced pressure-sensitive adhesive tape to one face of each strip, cutting a grid of mutually perpendicular longitudinal and transverse incisions into and through each strip to said tape from the other face of said strip so that the severed bits remain attached to said tape, assembling said severed strips on a spherically curved mandrel so that the wide end of each strip overlies the equatorial line of the mandrel and that the narrow ends of said strips meet at the pole of the mandrel, thereby defining a hemisphere having all the fibers oriented substantially radially, said adhesive tapes serving to retain said strips in position on said mandrel, and said incisions enabling said strips to curve in conformity with the curvature of the mandrel surface, impregnating said assembly of strips with a thermosetting resin to fill all incisions and cracks between adjoining bits, curing the resin filling, preparing a second identical hemisphere a bonding the two hemispheres to each other at their open equatorial edges to complete the sphere.
4. The method of constructing a hollow radial-filament sphere, comprising the steps of preparing a plurality of flat small slabs of a precured, unidirectional high-modulus fiberreinforced thermosetting resin, all the individual fiber lengths in each slab being oriented substantially normal to the opposite plane faces thereof, assembling a plurality of said slabs into a plane structure and clamping said slabs to each other, the number of such slabs exceeding somewhat the number required for a one-third quadrant segment of a hemisphere, cementing a sheet of flexible material to one face of said as sembly, cutting through said slabs from their free faces down to but not through said flexible sheet, thereby providing a multiplicity of small bits adhered to said sheet but not to each other, fitting said assembly onto a spherically curved surface with said flexible sheet engaging the latter, filling the gaps between adjacent bits with a thermosetting resin and curing the latter, trimming the spherically curved assembly to the size of a one-third quadrant segment of a hemisphere, preparing a plurality of additional identical one-third quadrant segments sufficient in number to make up a hemisphere, assembling said segments by threes on a spherically curved mandrel an cementing each set of three segments to each other at their abutting edge faces to form a respective quadrant, assembling said quadrants by fours on said mandrel so that the wide end of each quadrant overlies the equatorial line of the mandrel and that the narrow ends of said quadrants meet at the pole of the mandrel, thereby defining a hemisphere having all the fibers oriented substantially radially, said flexible sheet engaging said mandrel, impregnating said assembly of quadrants with a thermosetting resin to fill all cracks between segments and quadrants, curing the resin filling, preparing a second identical hemisphere and bonding the two hemispheres to each other at their open equatorial edges to complete the sphere.
5. The method of constructing a hollow radial-filament sphere, comprising the steps of preparing a plurality of flat small blocks of a precured, unidirectional high-modulus fiberreinforced thermosetting resin, all the individual fiber lengths in each block being oriented substantially normal to the opposite plane faces thereof, applying a respective double-faced, pressure-sensitive adhesive tape to one face of each of a plurality of elongated series of said blocks to define a plurality of strips, assembling said strips into the shape of a hemisphere on a spherically curved mandrel y first applying at least one strip to the mandrel as an equatorial band, then at least one strip over the pole of the mandrel from one end to the diametrically opposite edge of said equatorial hand, then at least one strip on each side of said edge-to-edge band transverse to the latter and extending from the opposite sides thereof to the equatorial hand, then angularly oriented strips within each of the spherical triangles previously defined by said bands until the triangles are completely filled, thereby defining a hemisphere having all the fibers oriented substantially radially, said adhesive tapes serving to retain said strips in position on said mandrel, impregnating said assembly of strips with a thermosetting resin to fill all cracks between adjoining blocks and strips, curing the resin filling, preparing a second identical hemisphere, and bonding the two hemispheres to each other at their open equatorial edges to complete the sphere.
6. The method of constructing a hollow radial-filament sphere, comprising the steps of preparing a flat sheet of a precured, unidirectional high modulus fiber-reinforced thermosetting resin, all the individual fiber lengths in said sheet being oriented substantially normal to the opposite planefaces thereof, making a plurality of side-by-side transverse cuts in said sheet, with adjacent cuts being alternatively oriented in equiangular converging and diverging relation to each other, thereby to define a plurality of rectilinear strips of trapezoidal cross section, inverting alternate ones of said strips in situ and recementing all the strips to define a cylindrically curved sector, making a plurality of pairs of side-by-side cuts in said sector at axially spaced locations therein, with each pair of such cuts being made on respective equally but oppositely oblique planes oriented to intersect at the axis of said sector along a line perpendicular to said axis, thereby to define a plurality of curved strips having equally inwardly angled sides, assembling said curved strips in side-by-side engaging relation to each other to define a spherically curved sector and cementing the abutting sides of said curved strips to each other, trimming said spherically curved sector to desired dimensions and configuration, in like manner preparing a plurality of additional spherically curved sectors, assembling said sectors so as to define a barrel having all the fibers oriented substantially radially, cementing said assembly of sectors, cutting polar end caps from identically made barrel sectors to fit the polar openings of the barrel, and cementing said caps in place to complete the sphere.
22353?" NITED STATES" PATENT @FMCE CERTIFICATE OF I Patent No. Dated January 25, 1972 Inventor(s) Daniel Elliott et a1 It is certified that error appears in the above-identified patent and that said Letters Patent are hereby corrected as shown below:
T- Column 2, lines 12-13, for "uh-directional" read "uni-:
directiona1--; line 58, for '120" read --2t-- Column 3, line 1, delete the second sign; line 55, after "1,030,000" delete "million". Column 6, line 68, for 'i'iled" read --filled--. Column 7, line 16, for "uncurred" read --uncured--; line 38, after "12,uo0,ooo" delete "million". Column 8, line 30, for "hemisphere a read --hemisphere, and--; line 53, for "an" read --and--; line 65, a comma) should follow "hemisphere"; Column 9, line 2, for "3! read --by--; line t, for "end" read --edge-- Column 10, line 1, for "alternatively" read --alternatingly--.
Signed and sealed this 8th day of May 1973.
(SEAL) Attest:
EDWARD M.FLETCHER,JR. ROBERT GOTTSCHALK Commissioner 01' Patents Attesting Oi'ficer

Claims (5)

  1. 2. The method of constructing a radial-filament, spherically curved, hollow shell-type body, comprising the steps of preparing a plurality of flat sheetlike members of a cured, unidirectional fiber-reinforced resin in each of which members all the individual fiber lengths are oriented substantially normal to the broad faces of that member, building said body by assembling a plurality of said members in laterally adjacent relation and in a spherically curved configuration so as to dispose said fiber lengths substantially radially of said body, filling all cracks and spaces between said assembled members with a material comprising a thermosetting resin to complete said body, and curing the resin filling.
  2. 3. The method of constructing a hollow radial-filament sphere, comprising the steps preparing a plurality of flat, wedgelike strips of precured, high-modulus, unidirectional fiber-reinforced thermosetting resin wherein all the individual fiber lengths are oriented substantially normal to the broad faces of said strips, applying a double-faced pressure-sensitive adhesive tape to one face of each strip, cutting a grid of mutually perpendicular longitudinal and transverse incisions into and through each strip to said tape from the other face of said strip so that the severed bits remain attached to said tape, assembling said severed strips on a spherically curved mandrel so that the wide end of each strip overlies the equatorial line of the mandrel and that the narrow ends of said strips meet at the pole of the mandrel, thereby defining a hemisphere having all the fibers oriented substantially radially, said adhesive tapes serving to retain said strips in position on said mandrel, and said incisions enabling said strips to curve in conformity with the curvature of the mandrel surface, impregnating said assembly of strips with a thermosetting resin to fill all incisions and cracks between adjoining bits, curing the resin filling, preparing a second identical hemisphere and bonding the two hemispheres to each other at their open equatorial edges to complete the sphere.
  3. 4. The method of constructing a hollow radial-filament sphere, comprising the steps of preparing a plurality of flat small slabs of a precured, unidirectional high-modulus fiber-reinforced thermosetting resin, all the individual fiber lengths in each slab being oriented substantially normal to the opposite plane faces thereof, assembling a plurality of said slabs into a plane structure and clamping said slabs to each other, the number of such slabs exceeding somewhat the number required for a one-third quadrant segment of a hemisphere, cementing a sheet of flexible material to one face of said assembly, cutting through said slabs from their free faces down to but not through said flexible sheet, thereby providing a multiplicity of small bits adhered to said sheet but not to each other, fitting said assembly onto a spherically curved surface with said flexible sheet engaging the latter, filling the gaps between adjacent bits with a thermosetting resin and curing the latter, trimming the spherically curved assembly to the size of a one-third quadrant segment of a hemisphere, preparing a plurality of additional identical one-third quadrant segments sufficient in number to make up a hemisphere, assembling said segments by threes on a spherically curved mandrel and cementing each set of three segments to each other at their abutting edge faces to form a respective quadrant, assembling said quadrants by fours on said mandrel so that the wide end of each quadrant overlies the equatorial line of the mandrel and that the narrow ends of said quadrants meet at the pole of the mandrel, thereby definIng a hemisphere having all the fibers oriented substantially radially, said flexible sheet engaging said mandrel, impregnating said assembly of quadrants with a thermosetting resin to fill all cracks between segments and quadrants, curing the resin filling, preparing a second identical hemisphere, and bonding the two hemispheres to each other at their open equatorial edges to complete the sphere.
  4. 5. The method of constructing a hollow radial-filament sphere, comprising the steps of preparing a plurality of flat small blocks of a precured, unidirectional high-modulus fiber-reinforced thermosetting resin, all the individual fiber lengths in each block being oriented substantially normal to the opposite plane faces thereof, applying a respective double-faced, pressure-sensitive adhesive tape to one face of each of a plurality of elongated series of said blocks to define a plurality of strips, assembling said strips into the shape of a hemisphere on a spherically curved mandrel y first applying at least one strip to the mandrel as an equatorial band, then at least one strip over the pole of the mandrel from one end to the diametrically opposite edge of said equatorial band, then at least one strip on each side of said edge-to-edge band transverse to the latter and extending from the opposite sides thereof to the equatorial band, then angularly oriented strips within each of the spherical triangles previously defined by said bands until the triangles are completely filled, thereby defining a hemisphere having all the fibers oriented substantially radially, said adhesive tapes serving to retain said strips in position on said mandrel, impregnating said assembly of strips with a thermosetting resin to fill all cracks between adjoining blocks and strips, curing the resin filling, preparing a second identical hemisphere, and bonding the two hemispheres to each other at their open equatorial edges to complete the sphere.
  5. 6. The method of constructing a hollow radial-filament sphere, comprising the steps of preparing a flat sheet of a precured, unidirectional high modulus fiber-reinforced thermosetting resin, all the individual fiber lengths in said sheet being oriented substantially normal to the opposite plane faces thereof, making a plurality of side-by-side transverse cuts in said sheet, with adjacent cuts being alternatively oriented in equiangular converging and diverging relation to each other, thereby to define a plurality of rectilinear strips of trapezoidal cross section, inverting alternate ones of said strips in situ and recementing all the strips to define a cylindrically curved sector, making a plurality of pairs of side-by-side cuts in said sector at axially spaced locations therein, with each pair of such cuts being made on respective equally but oppositely oblique planes oriented to intersect at the axis of said sector along a line perpendicular to said axis, thereby to define a plurality of curved strips having equally inwardly angled sides, assembling said curved strips in side-by-side engaging relation to each other to define a spherically curved sector and cementing the abutting sides of said curved strips to each other, trimming said spherically curved sector to desired dimensions and configuration, in like manner preparing a plurality of additional spherically curved sectors, assembling said sectors so as to define a barrel having all the fibers oriented substantially radially, cementing said assembly of sectors, cutting polar end caps from identically made barrel sectors to fit the polar openings of the barrel, and cementing said caps in place to complete the sphere.
US822769*A 1966-01-24 1969-02-03 Manufacture of radial-filament spheres Expired - Lifetime US3637446A (en)

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US52267566A 1966-01-24 1966-01-24
US82276969A 1969-02-03 1969-02-03

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US3819461A (en) * 1969-08-19 1974-06-25 Stevens & Co Inc J P Unidirectional, high modulus knitted fabrics
US4248649A (en) * 1978-01-19 1981-02-03 Rolls-Royce Limited Method for producing a composite structure
US4505334A (en) * 1983-09-06 1985-03-19 Oil States Industries, Inc. Ball sealer
US4571355A (en) * 1984-11-28 1986-02-18 The Boeing Company Fiber reinforced resin composites formed of basic ply blankets
US5042751A (en) * 1987-04-06 1991-08-27 Tre Corporation Pressure vessel with a non-circular axial cross-section
US6221457B1 (en) * 1995-05-17 2001-04-24 R & R Partners Display system for curved surfaces
US20040250912A1 (en) * 2001-05-30 2004-12-16 Peer Haller Wood profile and method for the production of the same
US20110132619A1 (en) * 2009-12-08 2011-06-09 Baker Hughes Incorporated Dissolvable Tool and Method
US20110136707A1 (en) * 2002-12-08 2011-06-09 Zhiyue Xu Engineered powder compact composite material
US20110132620A1 (en) * 2009-12-08 2011-06-09 Baker Hughes Incorporated Dissolvable Tool and Method
US20110132143A1 (en) * 2002-12-08 2011-06-09 Zhiyue Xu Nanomatrix powder metal compact
US20110132612A1 (en) * 2009-12-08 2011-06-09 Baker Hughes Incorporated Telescopic Unit with Dissolvable Barrier
US20110132621A1 (en) * 2009-12-08 2011-06-09 Baker Hughes Incorporated Multi-Component Disappearing Tripping Ball and Method for Making the Same
US20110135953A1 (en) * 2009-12-08 2011-06-09 Zhiyue Xu Coated metallic powder and method of making the same
US20110214881A1 (en) * 2010-03-05 2011-09-08 Baker Hughes Incorporated Flow control arrangement and method
US8425651B2 (en) 2010-07-30 2013-04-23 Baker Hughes Incorporated Nanomatrix metal composite
US8573295B2 (en) 2010-11-16 2013-11-05 Baker Hughes Incorporated Plug and method of unplugging a seat
US8631876B2 (en) 2011-04-28 2014-01-21 Baker Hughes Incorporated Method of making and using a functionally gradient composite tool
US8776884B2 (en) 2010-08-09 2014-07-15 Baker Hughes Incorporated Formation treatment system and method
US8783365B2 (en) 2011-07-28 2014-07-22 Baker Hughes Incorporated Selective hydraulic fracturing tool and method thereof
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US9080098B2 (en) 2011-04-28 2015-07-14 Baker Hughes Incorporated Functionally gradient composite article
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US9109269B2 (en) 2011-08-30 2015-08-18 Baker Hughes Incorporated Magnesium alloy powder metal compact
US9127515B2 (en) 2010-10-27 2015-09-08 Baker Hughes Incorporated Nanomatrix carbon composite
US9133695B2 (en) 2011-09-03 2015-09-15 Baker Hughes Incorporated Degradable shaped charge and perforating gun system
US9139928B2 (en) 2011-06-17 2015-09-22 Baker Hughes Incorporated Corrodible downhole article and method of removing the article from downhole environment
US9187990B2 (en) 2011-09-03 2015-11-17 Baker Hughes Incorporated Method of using a degradable shaped charge and perforating gun system
US9227243B2 (en) 2009-12-08 2016-01-05 Baker Hughes Incorporated Method of making a powder metal compact
US9243475B2 (en) 2009-12-08 2016-01-26 Baker Hughes Incorporated Extruded powder metal compact
US9284812B2 (en) 2011-11-21 2016-03-15 Baker Hughes Incorporated System for increasing swelling efficiency
US9347119B2 (en) 2011-09-03 2016-05-24 Baker Hughes Incorporated Degradable high shock impedance material
US9605508B2 (en) 2012-05-08 2017-03-28 Baker Hughes Incorporated Disintegrable and conformable metallic seal, and method of making the same
US9643250B2 (en) 2011-07-29 2017-05-09 Baker Hughes Incorporated Method of controlling the corrosion rate of alloy particles, alloy particle with controlled corrosion rate, and articles comprising the particle
US9643144B2 (en) 2011-09-02 2017-05-09 Baker Hughes Incorporated Method to generate and disperse nanostructures in a composite material
US9707739B2 (en) 2011-07-22 2017-07-18 Baker Hughes Incorporated Intermetallic metallic composite, method of manufacture thereof and articles comprising the same
US9816339B2 (en) 2013-09-03 2017-11-14 Baker Hughes, A Ge Company, Llc Plug reception assembly and method of reducing restriction in a borehole
US9833838B2 (en) 2011-07-29 2017-12-05 Baker Hughes, A Ge Company, Llc Method of controlling the corrosion rate of alloy particles, alloy particle with controlled corrosion rate, and articles comprising the particle
US9856547B2 (en) 2011-08-30 2018-01-02 Bakers Hughes, A Ge Company, Llc Nanostructured powder metal compact
US9910026B2 (en) 2015-01-21 2018-03-06 Baker Hughes, A Ge Company, Llc High temperature tracers for downhole detection of produced water
US9926766B2 (en) 2012-01-25 2018-03-27 Baker Hughes, A Ge Company, Llc Seat for a tubular treating system
US10016810B2 (en) 2015-12-14 2018-07-10 Baker Hughes, A Ge Company, Llc Methods of manufacturing degradable tools using a galvanic carrier and tools manufactured thereof
US10221637B2 (en) 2015-08-11 2019-03-05 Baker Hughes, A Ge Company, Llc Methods of manufacturing dissolvable tools via liquid-solid state molding
USD842950S1 (en) 2014-07-01 2019-03-12 Matthew John O'Malley Soccer ball
US10240419B2 (en) 2009-12-08 2019-03-26 Baker Hughes, A Ge Company, Llc Downhole flow inhibition tool and method of unplugging a seat
US10378303B2 (en) 2015-03-05 2019-08-13 Baker Hughes, A Ge Company, Llc Downhole tool and method of forming the same
US11167343B2 (en) 2014-02-21 2021-11-09 Terves, Llc Galvanically-active in situ formed particles for controlled rate dissolving tools
US11365164B2 (en) 2014-02-21 2022-06-21 Terves, Llc Fluid activated disintegrating metal system
US11649526B2 (en) 2017-07-27 2023-05-16 Terves, Llc Degradable metal matrix composite

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US3819461A (en) * 1969-08-19 1974-06-25 Stevens & Co Inc J P Unidirectional, high modulus knitted fabrics
US4248649A (en) * 1978-01-19 1981-02-03 Rolls-Royce Limited Method for producing a composite structure
US4505334A (en) * 1983-09-06 1985-03-19 Oil States Industries, Inc. Ball sealer
US4571355A (en) * 1984-11-28 1986-02-18 The Boeing Company Fiber reinforced resin composites formed of basic ply blankets
US5042751A (en) * 1987-04-06 1991-08-27 Tre Corporation Pressure vessel with a non-circular axial cross-section
US6221457B1 (en) * 1995-05-17 2001-04-24 R & R Partners Display system for curved surfaces
US20040250912A1 (en) * 2001-05-30 2004-12-16 Peer Haller Wood profile and method for the production of the same
US9101978B2 (en) 2002-12-08 2015-08-11 Baker Hughes Incorporated Nanomatrix powder metal compact
US20110136707A1 (en) * 2002-12-08 2011-06-09 Zhiyue Xu Engineered powder compact composite material
US9109429B2 (en) 2002-12-08 2015-08-18 Baker Hughes Incorporated Engineered powder compact composite material
US20110132143A1 (en) * 2002-12-08 2011-06-09 Zhiyue Xu Nanomatrix powder metal compact
US9227243B2 (en) 2009-12-08 2016-01-05 Baker Hughes Incorporated Method of making a powder metal compact
US8528633B2 (en) * 2009-12-08 2013-09-10 Baker Hughes Incorporated Dissolvable tool and method
US20110135953A1 (en) * 2009-12-08 2011-06-09 Zhiyue Xu Coated metallic powder and method of making the same
US10240419B2 (en) 2009-12-08 2019-03-26 Baker Hughes, A Ge Company, Llc Downhole flow inhibition tool and method of unplugging a seat
US8297364B2 (en) 2009-12-08 2012-10-30 Baker Hughes Incorporated Telescopic unit with dissolvable barrier
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US20110132621A1 (en) * 2009-12-08 2011-06-09 Baker Hughes Incorporated Multi-Component Disappearing Tripping Ball and Method for Making the Same
US9243475B2 (en) 2009-12-08 2016-01-26 Baker Hughes Incorporated Extruded powder metal compact
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