US3622383A - Welding electrode - Google Patents

Welding electrode Download PDF

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US3622383A
US3622383A US871515*A US3622383DA US3622383A US 3622383 A US3622383 A US 3622383A US 3622383D A US3622383D A US 3622383DA US 3622383 A US3622383 A US 3622383A
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wire
electrode
welding
soap
impregnated
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Paul E Dane
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Hobart Brothers LLC
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/40Making wire or rods for soldering or welding
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M7/00Solid or semi-solid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single solid or semi-solid substances
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02Water
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • C10M2201/082Inorganic acids or salts thereof containing nitrogen
    • C10M2201/083Inorganic acids or salts thereof containing nitrogen nitrites
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/085Phosphorus oxides, acids or salts
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087Boron oxides, acids or salts
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/02Groups 1 or 11
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/24Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/241Manufacturing joint-less pipes
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/242Hot working
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/243Cold working
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/245Soft metals, e.g. aluminum
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/246Iron or steel
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/247Stainless steel
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    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/08Solids
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    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10Semi-solids; greasy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core
    • Y10T428/294Coated or with bond, impregnation or core including metal or compound thereof [excluding glass, ceramic and asbestos]
    • Y10T428/2951Metal with weld modifying or stabilizing coating [e.g., flux, slag, producer, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/298Physical dimension

Definitions

  • a continuous feeding ferrous-welding electrode is formed by initially coating a mild steel wire with a lime solution, applying a substantially dry-soap-lubricating compound to coat the surface of the wire, drawing the wire to reduce its diameter with a portion of the sodium soap being impregnated within the surface pores of the wire, applying a liquid lubricating solution to the wire, and further drawing the wire to reduce its diameter with a portion of the lubricating solution also being impregnated into the surface pores of the wire to provide a rust and corrosion resistant electrode having improved feeding and welding characteristics.
  • the same comprise a die box containing the drawing die and which has positioned thereto a compartment or chamber for holding lubricant, and through which the wire passes before entering the drawing die.
  • lubricants such as powdered lime, grease, soap, and the like.
  • Flash coatings of metal such as copper have also been used. Such coatings when applied to wire electrodes provide a relatively thick film of the material on the wire which is easily scraped off as the coated electrode is fed through the welding nozzle and hoses. Even flash coatings of metal, e.g. copper deposited on the wire surface tend to flake off and accumulate on the working parts of the welding apparatus.
  • the electrode is wet drawn using a combination of powdered soap and liquid detergent which is forced into the surface pores of the wire.
  • Wet drawing of the wire is essential, at least during the last wire-drawing operation, to impregnate the surface of the wire with the detergent lubricant and avoid leaving a coating of the lubricant material on the wire and such as tends to scrape off during use of the wire electrode.
  • Dry-drawing employing powdered soap and the like lubricant may be utilized during intermediate wire-drawing operations, and which is followed by a final wet-drawing operation to form the finished electrode.
  • Wet drawing of the wire using powdered soap and liquid detergent in accordance with the invention leaves only an infinitesimally thin film of the lubricant impregnant on the surface of the wire.
  • the detergent lubricant is hydraulically forced or pressure worked into the pores at the surface of the wire and which is essential for achieving the improved results.
  • the invention is applicable for the treatment of limed or unlimed wire or rod electrodes.
  • Such material is treated with a soap and liquid detergent prior to power-drawing the wire through one or more dies until the electrode is of the desired diameter.
  • the detergent lubricant is impregnated into the wire surface and no appreciable coating thickness of the lubricant is left on the surface of the wire, as aforementioned.
  • an improved electrode wire is produced by the treatment of the same to impregnate the electrode surface portion with an electrically conductive lubricant and corrosion inhibitor.
  • Welding wire electrodes treated in accordance with the invention slip through the hoses and nozzles of the welding equipment easily and the electrode is protected against rusting or deterioration due to corrosion.
  • FIG. 1 illustrates in section and on an enlarged scale a wire electrode having the surface area portion impregnated with a lubricant and protective composition
  • FIG. 2 is a vertical sectional view taken through a pair of wire-drawing die boxes and illustrating how the invention may be practiced;
  • FIG. 3 is a vertical sectional view of a modified wire-drawing die box for applying the liquid detergent
  • FIG. 1 a finished electrode 10 is illustrated, having an integral surface or impregnated shell 11 comprising the detergent lubricant.
  • a wire electrode 12 passes through a die box 14 and drawing die 16.
  • the die box is provided with a chamber 18 which is filled with powdered sodium soap 20.
  • the resultant drawn wire 21 is passed through die box 24 containing liquid detergent 25 and finally through the drawing die 30, to provide a finished electrode 32.
  • FIG. 3 a spray-type die box.
  • the wire 34 is passed through a closed spray chamber 36 and sprayed with liquid detergent, which may contain dye for marking the wire as it is drawn to the desired size by the drawing die 40.
  • liquid detergent may be withdrawn from the bath 45 and sprayed on the wire just prior to its passage through the drawing die 40 to provide a finished electrode wire 48.
  • the sodium stearate functions as an adherent lubricant, and borax and sodium nitrite serve as a buffer and rust inhibitor. While the constituents of the soap composition may be varied over a range of mm 20percent depending upon the metal used in the wire electrode, that set out in example I is preferred for ferrous metal wire electrodes.
  • the liquid detergent and impregnant is composed of the following components which are mixed with water to provide a liquid composition.
  • EXAMPLE 2 Parts by Weight potassium oleate 44 Potassium linoleate 44 Corn oil fatty acid (linoleic acid) 5 Sodium biphosphate Polyalkaline glycol (sodium salt ofdietltylene glycol) EXAMPLE 3
  • an azo dye is incorporated in the liquid detergent composition of example 2 in sufficient amount to color the elec trode.
  • Croceine scarlet 3B is added to the liquid detergent c'ompositionto give it a brilliant red color.
  • Metanil Yellow is added to the detergent composition.
  • Example 1 is repeated using a blend comprising lzl parts by weight of the sodium stearate composition of example land the detergent composition of example 2 dissolved in water. Five pounds of the solids mixture is dissolved in 20 gallons of water. This mixture is applied to limed drawn wire to provide an electrode having the liquid detergent mixture impregnated in the surface. Liming of the drawn wire is conventional practice for providing the surface with calcium electrons in the economic reasons they are not generally employed.
  • the bare wire may, where desired, be drawn through an aqueous suspension of calcium hydroxide (lime water) and the lime coated wire air dried. Thereafter the coated wire is treated with sodium soap and liquid detergent in accordance with the present invention, to provide an electrode having the improved electric arc-welding characteristics.
  • composition of the surface coating herein described constitutes a preferred embodiment of the inven tion, it is to be understood that the invention is not limited to Parts by Weight sodium slearate 84.0 borax
  • said detergent consisting of the following solids composition:

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Metal Extraction Processes (AREA)
  • Nonmetallic Welding Materials (AREA)

Abstract

A continuous feeding ferrous-welding electrode is formed by initially coating a mild steel wire with a lime solution, applying a substantially dry-soap-lubricating compound to coat the surface of the wire, drawing the wire to reduce its diameter with a portion of the sodium soap being impregnated within the surface pores of the wire, applying a liquid lubricating solution to the wire, and further drawing the wire to reduce its diameter with a portion of the lubricating solution also being impregnated into the surface pores of the wire to provide a rust and corrosion resistant electrode having improved feeding and welding characteristics.

Description

United States Patent [72] Inventor Paul E. Dane Troy, Ohio [21] Appl. No. 871,515
[22] Filed Aug. 18,1969
[45] Patented Nov. 23, 1971 [73] Assignee Hobart Brothers Company Troy, Ohio Original application Dec. 8, 1966, Ser. No. 600,276, now Patent No. 3,478,552, Continuation-impart of application Ser. No. 255,528, Feb. 1, 1963, now abandoned. Dlvided and this application Aug. 18, 1969, Ser. No. 871,515
[54] WELDING ELECTRODE 1 Claim, 3 Drawing Figs.
[52] US. Cl 117/202, 148/25 51 Int. Cl ..1 ..B23k 35/36, C23f 17/00 Primary Examiner-William L. Jarvis Attorney-Marechal, Biebel, French & Bugg ABSTRACT: A continuous feeding ferrous-welding electrode is formed by initially coating a mild steel wire with a lime solution, applying a substantially dry-soap-lubricating compound to coat the surface of the wire, drawing the wire to reduce its diameter with a portion of the sodium soap being impregnated within the surface pores of the wire, applying a liquid lubricating solution to the wire, and further drawing the wire to reduce its diameter with a portion of the lubricating solution also being impregnated into the surface pores of the wire to provide a rust and corrosion resistant electrode having improved feeding and welding characteristics.
PATENTEDunv 23 I971 3.622383 INVENTOR PAUL E. DANE ATTORN WELDING ELECTRODE RELATED APPLICATIONS This application is a division of application Ser. No. 600,276, filed Dec. 8, 1966, and now Pat. No. 3,478,552 which is a continuation of application Ser. No. 255,528, filed Feb. I, 1963, now abandoned.
In conventional wire-drawing equipment the same comprise a die box containing the drawing die and which has positioned thereto a compartment or chamber for holding lubricant, and through which the wire passes before entering the drawing die. Various lubricants have been used or suggested, such as powdered lime, grease, soap, and the like. Flash coatings of metal such as copper have also been used. Such coatings when applied to wire electrodes provide a relatively thick film of the material on the wire which is easily scraped off as the coated electrode is fed through the welding nozzle and hoses. Even flash coatings of metal, e.g. copper deposited on the wire surface tend to flake off and accumulate on the working parts of the welding apparatus.
In accordance with the improved welding electrode of this invention, the electrode is wet drawn using a combination of powdered soap and liquid detergent which is forced into the surface pores of the wire. Wet drawing of the wire is essential, at least during the last wire-drawing operation, to impregnate the surface of the wire with the detergent lubricant and avoid leaving a coating of the lubricant material on the wire and such as tends to scrape off during use of the wire electrode.
Dry-drawing employing powdered soap and the like lubricant may be utilized during intermediate wire-drawing operations, and which is followed by a final wet-drawing operation to form the finished electrode. Wet drawing of the wire using powdered soap and liquid detergent in accordance with the invention leaves only an infinitesimally thin film of the lubricant impregnant on the surface of the wire. During wet drawing, the detergent lubricant is hydraulically forced or pressure worked into the pores at the surface of the wire and which is essential for achieving the improved results.
The invention is applicable for the treatment of limed or unlimed wire or rod electrodes. Such material is treated with a soap and liquid detergent prior to power-drawing the wire through one or more dies until the electrode is of the desired diameter. By wet drawing of the wire electrode the detergent lubricant is impregnated into the wire surface and no appreciable coating thickness of the lubricant is left on the surface of the wire, as aforementioned.
It is accordingly an object of the invention to provide an electrode for welding having improved properties, and which avoids the aforementioned difficulties encountered with conventionally coated electrodes.
It is a further object of the invention to provide a welding electrode having an adherent outer impregnated film of material which functions both as a lubricant and rush inhibitor and which does not increase the contact resistance of the welding electrode at the current-collecting nozzle.
In accordance with the present invention, an improved electrode wire is produced by the treatment of the same to impregnate the electrode surface portion with an electrically conductive lubricant and corrosion inhibitor. Welding wire electrodes treated in accordance with the invention slip through the hoses and nozzles of the welding equipment easily and the electrode is protected against rusting or deterioration due to corrosion.
Further objects and advantages of the invention will hereinafter be apparent, and for the purpose of illustration, an embodiment of the invention is shown in the accompanying drawing in which FIG. 1 illustrates in section and on an enlarged scale a wire electrode having the surface area portion impregnated with a lubricant and protective composition;
FIG. 2 is a vertical sectional view taken through a pair of wire-drawing die boxes and illustrating how the invention may be practiced;
FIG. 3 is a vertical sectional view of a modified wire-drawing die box for applying the liquid detergent;
Referring to the drawings, in FIG. 1 a finished electrode 10 is illustrated, having an integral surface or impregnated shell 11 comprising the detergent lubricant.
In the embodiment illustrated in FIG. 2, a wire electrode 12 passes through a die box 14 and drawing die 16. The die box is provided with a chamber 18 which is filled with powdered sodium soap 20. Following drawing die 16, the resultant drawn wire 21 is passed through die box 24 containing liquid detergent 25 and finally through the drawing die 30, to provide a finished electrode 32.
As a modification of the liquid die box arrangement shown in FIG. 2, there is illustrated in FIG. 3 a spray-type die box. In this modification the wire 34 is passed through a closed spray chamber 36 and sprayed with liquid detergent, which may contain dye for marking the wire as it is drawn to the desired size by the drawing die 40. Utilizing a pump 41 and conduit arrangement with spray nozzles 43, the liquid detergent may be withdrawn from the bath 45 and sprayed on the wire just prior to its passage through the drawing die 40 to provide a finished electrode wire 48.
Preferred embodiments of the invention, but not limitative thereof, are exemplified in the examples as follows EXAMPLE 1 Parts by Weight Sodium stearate 84.0 Borax 10.0 Sodium nitrite 5.5 Moisture 0.5
The sodium stearate functions as an adherent lubricant, and borax and sodium nitrite serve as a buffer and rust inhibitor. While the constituents of the soap composition may be varied over a range of mm 20percent depending upon the metal used in the wire electrode, that set out in example I is preferred for ferrous metal wire electrodes.
The liquid detergent and impregnant is composed of the following components which are mixed with water to provide a liquid composition.
EXAMPLE 2 Parts by Weight potassium oleate 44 Potassium linoleate 44 Corn oil fatty acid (linoleic acid) 5 Sodium biphosphate Polyalkaline glycol (sodium salt ofdietltylene glycol) EXAMPLE 3 As a modification, and where it is desired to color the electrode, an azo dye is incorporated in the liquid detergent composition of example 2 in sufficient amount to color the elec trode. To produce a red colored electrode Croceine scarlet 3B is added to the liquid detergent c'ompositionto give it a brilliant red color. To provide a yellow-colored electrode, Metanil Yellow is added to the detergent composition.
EXAMPLE 4 Example 1 is repeated using a blend comprising lzl parts by weight of the sodium stearate composition of example land the detergent composition of example 2 dissolved in water. Five pounds of the solids mixture is dissolved in 20 gallons of water. This mixture is applied to limed drawn wire to provide an electrode having the liquid detergent mixture impregnated in the surface. Liming of the drawn wire is conventional practice for providing the surface with calcium electrons in the economic reasons they are not generally employed. The bare wire may, where desired, be drawn through an aqueous suspension of calcium hydroxide (lime water) and the lime coated wire air dried. Thereafter the coated wire is treated with sodium soap and liquid detergent in accordance with the present invention, to provide an electrode having the improved electric arc-welding characteristics.
While the composition of the surface coating herein described constitutes a preferred embodiment of the inven tion, it is to be understood that the invention is not limited to Parts by Weight sodium slearate 84.0 borax |0,0 sodium nitrite 5.5 moisture 0.5
said detergent consisting of the following solids composition:
potassium oleate 44 potassium linoleate 44 corn oil fatty acid 5 sulfonated naphthalene 5 sodium biphosphate l polyalkaline glycol l.
US871515*A 1966-12-08 1969-08-18 Welding electrode Expired - Lifetime US3622383A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4113524A (en) * 1977-02-24 1978-09-12 Rca Corporation Method of assembling components on printed circuit boards
FR2429642A1 (en) * 1978-06-28 1980-01-25 Kauppi Markku
EP0685293A1 (en) * 1994-05-06 1995-12-06 KABUSHIKI KAISHA KOBE SEIKO SHO also known as Kobe Steel Ltd. Flux-cored wire and solid wire for arc welding
US6337144B1 (en) * 1997-11-11 2002-01-08 Kabushiki Kaisha Kobe Seiko Sho Wire for welding
US20050045699A1 (en) * 2003-08-26 2005-03-03 Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) Method of producing solid wire for welding

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1884713A (en) * 1930-04-25 1932-10-25 Lincoln Electric Co Method of and apparatus for coating wire
US1936693A (en) * 1930-01-21 1933-11-28 Smith Corp A O Weldrod for arc welding
US2840890A (en) * 1952-03-19 1958-07-01 Armco Steel Corp Wire coating

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1936693A (en) * 1930-01-21 1933-11-28 Smith Corp A O Weldrod for arc welding
US1884713A (en) * 1930-04-25 1932-10-25 Lincoln Electric Co Method of and apparatus for coating wire
US2840890A (en) * 1952-03-19 1958-07-01 Armco Steel Corp Wire coating

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4113524A (en) * 1977-02-24 1978-09-12 Rca Corporation Method of assembling components on printed circuit boards
FR2429642A1 (en) * 1978-06-28 1980-01-25 Kauppi Markku
EP0685293A1 (en) * 1994-05-06 1995-12-06 KABUSHIKI KAISHA KOBE SEIKO SHO also known as Kobe Steel Ltd. Flux-cored wire and solid wire for arc welding
US5550348A (en) * 1994-05-06 1996-08-27 Kabushiki Kaisha Kobe Seiko Sho Flux-cored wire and solid wire for arc welding
US5672287A (en) * 1994-05-06 1997-09-30 Kabushiki Kaisha Kobe Seiko Sho Flux-cored wire and solid wire for ARC welding
US6337144B1 (en) * 1997-11-11 2002-01-08 Kabushiki Kaisha Kobe Seiko Sho Wire for welding
US20020037420A1 (en) * 1997-11-11 2002-03-28 Kabushiki Kaisha Kobe Seiko Sho Wire for welding
US6841246B2 (en) 1997-11-11 2005-01-11 Kabushiki Kaisha Kobe Seiko Sho Wire for welding
US20050045699A1 (en) * 2003-08-26 2005-03-03 Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) Method of producing solid wire for welding
US7485829B2 (en) * 2003-08-26 2009-02-03 Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) Method of producing solid wire for welding

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