US3617276A - Silver complex diffusion transfer process separating development nuclei and alkaline liquid - Google Patents

Silver complex diffusion transfer process separating development nuclei and alkaline liquid Download PDF

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Publication number
US3617276A
US3617276A US697005A US3617276DA US3617276A US 3617276 A US3617276 A US 3617276A US 697005 A US697005 A US 697005A US 3617276D A US3617276D A US 3617276DA US 3617276 A US3617276 A US 3617276A
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United States
Prior art keywords
light
diffusion transfer
liquid
sensitive material
nuclei
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Expired - Lifetime
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US697005A
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English (en)
Inventor
Louis Maria De Haes
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Agfa Gevaert NV
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Agfa Gevaert NV
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Priority claimed from GB5089967A external-priority patent/GB1216508A/en
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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
    • G03C8/02—Photosensitive materials characterised by the image-forming section
    • G03C8/04—Photosensitive materials characterised by the image-forming section the substances transferred by diffusion consisting of inorganic or organo-metallic compounds derived from photosensitive noble metals
    • G03C8/06—Silver salt diffusion transfer

Definitions

  • the present invention relates to a method of producing photographic images according to the silver complex diffusion transfer process.
  • a method of producing diffusion transfer images comprises'the treatment of a light-sensitive silver halide material comprising a colloid layer on top of the silver halide emulsion layer or the treatment of both the said lightwsensitive materials and a not specially pretreated sheet material used as the receiving material with a developing or activating liquid containing development nuclei or other substance(s), which promote conversion of complexed silver halide to form a visible image.
  • the light-sensitive and the receiving material are then pressed against each other and after an optimal contact time separated again, after which the receiving material shows the diffusion transfer image produced.
  • the present invention relates to a method of producing photographicimages according to the silver complex diffusion transfer process comprising the steps of imagewise exposing a light-sensitive material comprising a silver halide emulsion layer, applying a liquid containing a substance or substances (hereinafter called development nuclei and shortly even nuclei) for promoting conversion of complexed silver halide to form a visible image, to the imagewise exposed light-sensitive material and subsequently applying an aqueous alkaline liquid for carrying through the diffusion transfer image formation, keeping the light-sensitive material in contact with a receiving material in the presence of a sufficient amount of water or other liquid to allow the transfer of the produced diffusion transfer image to the receiving material to take place, and separating the light-sensitive and the receiving material from each other, whereafter the diffusion transfer image becomes visible on the receiving material.
  • development nuclei and shortly even nuclei a substance or substances
  • nuclei-containing liquid and the aqueous alkaline liquid are very stable and may be kept for a long time without substantial change of their characteristics. The risk of a reduction or even the complete annihilation of the action of the development nuclei is also avoided of course.
  • the light-sensitive material for use in carrying out the method of the present invention generally includes a suitable support sheet e.g. a paper support or a support of a synthetic polymeric material such as a support of a cellulose ester e.g. cellulose triacetate, or of polyethylene terephthalate.
  • the silver halide emulsion layer preferably is a gelatino silver halide emulsion layer. it may be applied directly or, if necessary or advantageous, by means of a suitable subbing layer to the support sheet. Any light-sensitive emulsion composition conventionally used in the art of diffusion transfer can be used.
  • the emulsion composition is not critical provided its silver salt(s) is (are) capable of being developed and of diffusing in the exposed and nonexposed areas respectively with the rapidity required in diffusion transfer processes.
  • Silver chloride emulsions are preferably used and they may contain silver bromide or silver iodine. Also silver bromide emulsions are often used, particularly when the reproduction of continuous tone originals is intended.
  • the silver bromide emulsions may comprise minor amounts of silver iodide. It is appropriate to use the emulsion in such a way that an amount of silver halide equivalent to 0.2 to 2 of silver is present per square meter of light-sensitive material.
  • the emulsion layer is at least slightly hardened.
  • the light-sensitive material for use in carrying out the method of the present invention preferably comprises a layer of a water-permeable colloid on top of the silver halide layer.
  • water'permeable colloids which may be used in the water-permeable colloid layer on top of the silver halide emulsion layer are: methylcellulose, the sodium salt of carboxymethylcellulose, hydroyethylcellulose, hydroxyethyl starch, hydroxypropyl starch, sodium alginate, tragacanth, starch, poly(vinyl alcohol), poly(acrylic acid), poly(acryl amide) poly(vinyl pyrrolidone), poly(oxethylene) and copoly(methylvinyl ether/maleic acid).
  • the thickness of the water-permeable colloid top layer is selected according to i.a. the nature of the colloid applied and the viscosity of the colloid solution used.
  • the water-permeable colloid layer on top of the silver halide emulsion layer is unhardened or but slightly hardened.
  • the light-sensitive material may contain all kinds of generally used ingredients such as sensitizers, stabilizers, hardeners, occasionally latent hardeners, softening agents, latices, pigments, wetting agents, and other coating aids.
  • a substance or substances beneficial or essential to the specific process involved i.e. a diffusion transfer process
  • developing substances are incorporated into the light-sensitive material.
  • Suitable developing substances are 3-pyrazolidinone developing substances and hydroquinone, preferably applied together.
  • a common paper sheet which was not specially treated i.e. the paper sheet is not provided with a special water-permeable colloid layer.
  • the receiving material may also have a more complex composition and comprise a suitable support sheet, e.g. a sheet of paper, film, or textile provided at the front and/or back side with at least one coating.
  • This coating may be an impermeabilizing coating formed by a film-forming waterimpermeablc synthetic polymeric substance.
  • a water-permeable coating is used, e.g. a baryta coating comprising a protein binding agent such as gelatin or casein.
  • barium sulfate As an alternative to barium sulfate, other pigments may be used such as kaolin or titanium dioxide, and instead of or in addition to protein binding agents polymerization products such as for instance copolymers of butadiene and styrene, poly(styrene), copolymers of vinyl chloride and vinylidene chloride,
  • Daniel ABSTRACT Silver complex diffusion transfer reproduction process in which a liquid containing development nuclei and an aqueous alkaline liquid for diffusion transfer image formation are applied separately and in sequential order to a lightsensitive material carrying a silver halide emulsion layer after which the latter material is contacted while still moist with an image-receiving material.
  • the photographic developing agent for the silver halide emulsion is provided via one or both of the light-sensitive and image-receiving materials so that the alkaline liquid can be free of such agent.
  • the light-sensitive material carries a water-permeable hydrophilic colloid layer superimposed upon the emulsion layer.
  • the development nuclei are dispersed in the carried liquid therefor which contains only an amount of hydrophilic colloid sufficient for maintaining the nuclei in dispersion.
  • the aqueous alkaline liquid may be applied to the receiving material, after which the latter material may be brought in contact with the imagewise exposed light-sensitive material wetted with the nuclei-containing liquid. At this moment the development of the exposed silver halide emulsion layer and the diffusion transfer image formation start.
  • the receiving material preferably is provided with a hydrophilic colloid layer, whereby the receiving material holds more easily a sufficient amount of the aqueous alkaline liquid for carrying through the whole method.
  • the light-sensitive material is still wet from the application of the developing nuclei, at the very moment of applying the aqueous liquid, since the whole process is often considerably accelerated thereby.
  • the aqueous alkaline processing liquid is applied directly to the light-sensitive material.
  • the total processing time may be reduced considerably and at the same time drier diffusion transfer copies are obtained, because the receiving material need not be wetted previously and can be pressed in dry condition against the light-sensitive material.
  • the content of these pods is spread in such a manner that first the nuclei are applied to the lightsensitive material and only afterwards the aqueous alkaline liquid for carrying through the diffusion transfer image formation.
  • the aqueous alkaline liquid the same techniques can be followed as those described above for the application of the nuclei-containing liquid.
  • a diffusion transfer image may also be obtained by first applying the alkaline liquid and only thereafter the development nuclei.
  • the development of the imagewise exposed light-sensitive silver halide emulsion layer and the diffusion of undeveloped and complexed silver halide are going on already.
  • the first diffusing complexed silver halide has the opportunity of diffusing laterally, thus resulting in an unsharp image having a fogged background.
  • the contact between the light-sensitive and the receiving material is effected in the presence of a sufiicient amount of water or other liquid to allow the transfer of the diffusion transfer image produced on top of the light-sensitive material to the receiving material to take place.
  • a sufiicient amount of water or other liquid comes from the wetting with the nuclei-containing liquid and/or the aqueous alkaline liquid.
  • the keeping in contact mostly occurs by means of pressure rollers, between which both the light-sensitive and the receiving material are conducted.
  • the receiving material may supply the aqueous alkaline processing liquid to the light-sensitive material during the contacting stage as explained above.
  • the nuclei-containing liquid and the aqueous alkaline processing liquid may also be supplied at the contacting stage and even later by rupture of a pod or pods containing same and by uniform distribution of the contents of this pod or these pods on the surface to be processed.
  • the light-sensitive and the image-receiving material are separated.
  • the separation of the light-sensitive material from the image-receiving material can be performed manually or by mechanical means specially designed therefor, e.g. the separating means described in the United Kingdom Pat. Specifications 1,060,572, 1,077,355, in the French Pat. Specification 1,473,494 and in the U.S. Pat. Specifications 3,297,317.
  • a thin diffusion transfer image-containing stratum is transferred during the separation stage from the light-sensitive material to the receiving material.
  • the drying of the receiving material after separation can be accelerated, if necessary or desirable, by applying heat or by means of a blower occasionally blowing hot air.
  • a suitable apparatus for complete processing is provided with an exposure station (the exposure may occur by transmission or reflectographically e.g. in contact and reflectographically or episcopically and reflectographically), a station for application of the nuclei-containing liquid to the light-sensitive material and a station-for the subsequent application of the aqueous alkaline processing liquid to the light-sensitive material, occasionally a unit for removing the excess of liquid, pressure rollers for bringing the light-sensitive material in contact with a preferably dry receiving material, and a unit for separating the light-sensitive material from the receiving material after production of diffusion transfer image.
  • the apparatus there may also be provided a transport mechanism, guidemembers, licking rollers, heating means, a blower, etc.
  • the light-sensitive material with which there was already produced a first diffusion transfer copy, again and preferably in approximately identical conditions for the production of a second, a third, etc. diffusion transfer copy.
  • a light-sensitive material having a hydrophilic colloid layer on top of the silver halide emulsion layer.
  • EXAMPLE 1 A common paper sheet weighing g. per sq. m. was coated with a gelatin silver chloride emulsion layer in such a way that per sq. m. 1.4 of hydroquinone, 0.4 g. of l-phenyl-3- pyrazolidinone, and an amount of silver chloride equivalent to 0.8 g. of silver nitrate were present.
  • the silver chloride emulsion layer was coated with a top layer of hydroxyethyl starch containing 0.64 g. of l-phenyl-3- pyrazolidinone per sq. m.
  • the lighusensitive material thus prepared was imagewise exposed reflectographically while in contact with an original. Subsequently the light-sensitive material was wetted at a rate of 4.5 cm./sec. by means of a licking roller with the following nuclei-containing liquid:
  • aqueous solution of colloidal silver (trade name:
  • the light-sensitive material was then wetted immediately at the same rate of 4.5 cm./sec. by means of licking roller with the following aqueous alkaline liquid for carrying through the diffusion transfer image formation:
  • EXAMPLE 2 A light-sensitive material as described in example 1 was imagewise exposed reflectographically while in contact with an original. Subsequently the material was conducted through the following nuclei-containing liquid in a common apparatus for producing images according to the silver complex diffusion transfer process at a rate of4.5 cm. per sec:
  • the light-sensitive material was then conducted immediately through a common apparatus for producing images according to the silver complex diffusion transfer process at a rate of 4.5 cm. per sec., to wet both materials with an aqueous alkaline processing liquid as described in example 1.
  • each material containing a developing substance also includes a preservative for such developing substance.

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Photosensitive Polymer And Photoresist Processing (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
US697005A 1967-01-11 1968-01-11 Silver complex diffusion transfer process separating development nuclei and alkaline liquid Expired - Lifetime US3617276A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB5089967A GB1216508A (en) 1967-01-11 1967-01-11 Silver complex diffusion transfer process
GB5764267 1967-01-11

Publications (1)

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US3617276A true US3617276A (en) 1971-11-02

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US (1) US3617276A (is")
BE (1) BE709194A (is")
FR (1) FR1550777A (is")
NL (1) NL6800432A (is")

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2992102A (en) * 1955-03-29 1961-07-11 Polaroid Corp Photographic processes and products
US3030207A (en) * 1952-07-17 1962-04-17 Polaroid Corp Photographic processes
GB1001558A (en) * 1961-04-13 1965-08-18 Gevaert Photo Prod Nv Photographic diffusion transfer copying processes
US3223525A (en) * 1959-07-22 1965-12-14 Philips Corp Method of manufacturing, by photographic means, external, electrically conductive noble-metal patterns on non-metallic, electrically non-conductive, macromolecular supports and products obtained by these methods
US3396018A (en) * 1963-05-17 1968-08-06 Eastman Kodak Co Diffusion transfer system

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3030207A (en) * 1952-07-17 1962-04-17 Polaroid Corp Photographic processes
US2992102A (en) * 1955-03-29 1961-07-11 Polaroid Corp Photographic processes and products
US3223525A (en) * 1959-07-22 1965-12-14 Philips Corp Method of manufacturing, by photographic means, external, electrically conductive noble-metal patterns on non-metallic, electrically non-conductive, macromolecular supports and products obtained by these methods
GB1001558A (en) * 1961-04-13 1965-08-18 Gevaert Photo Prod Nv Photographic diffusion transfer copying processes
US3396018A (en) * 1963-05-17 1968-08-06 Eastman Kodak Co Diffusion transfer system

Also Published As

Publication number Publication date
NL6800432A (is") 1968-03-25
BE709194A (is") 1968-07-11
FR1550777A (is") 1968-12-20

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