US3608025A - Slitting to form filaments - Google Patents

Slitting to form filaments Download PDF

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US3608025A
US3608025A US757446A US3608025DA US3608025A US 3608025 A US3608025 A US 3608025A US 757446 A US757446 A US 757446A US 3608025D A US3608025D A US 3608025DA US 3608025 A US3608025 A US 3608025A
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filaments
film
longitudinally
dividing
laterally
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Alexander Mirsky
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/42Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments
    • D01D5/426Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments by cutting films

Definitions

  • a method of producing filaments including longitudinally dividing drawable plastics material film which has already been drawn laterally, to produce filaments, and then drawing the filaments longitudinally.
  • apparatus for producing filaments including means for drawing plastic film laterally to impart a substantial lateral stretch thereto, means for dividing said film longitudinally to provide longitudinally extended filaments,. and means for drawing said filaments longitudinally to impart a substantial longitudinal stretch thereto.
  • a filament which has been produced by the first aspect of the invention.
  • the invention it is possible to produce very fine filaments. If undrawn cast film is slit, and the filaments are then drawn, the lateral contraction of each filament is usually proportional to the square root of the drawing ratio. However, if the film has been drawn laterally before slitting, the lateral contraction of each filament is much greater, decreasing the width to thickness ratio of the filament.
  • the drawn filaments produced in accordance with this invention can be wound on to a single rotary member in the manner described in British Pat. specification No. 1,067,514 and No. l,097,138; thus a large number of filaments, suitable for preparing a warp, may be produced from the film and wound onto a single rotary member, and an even larger number of filaments may have been produced from the film in the first instance to allow some of the filaments to be cast out.
  • the filaments produced in accordance with this invention may be for instance wound onto spindles or used for other purposes as explained hereafter; filaments in accordance with the invention are for example useful in core yarns.
  • the film slit is preferably unapertured, i.e. not provided with any pattern of holes or slits, until such time as it is divided in accordance with the invention.
  • the preferred plastics materials are polypropylene, polyethylene, nylon and polyester due to their drawing characteristics.
  • the extent to which e.g. polypropylene filaments can be drawn longitudinally after slitting depends on the extent to which the polypropylene film was stretched longitudinally (if at all) before slitting.
  • fine cast polypropylene film say 60 gauge film
  • Maximum drawing ratios may vary from one film type to another depending on polymer types, extrusion techniques and stretching techniques.
  • these ratios may be between the limits of say 2:l to l4:l, before fibrillation occurs although in the case of nylon the maximum encountered is 5:l.
  • drawing ratios are such that fibrillation point is not reached in materials which can be fibrillated.
  • the preferred lateral drawing ratio is from 2:l to l4:l; above 4:] the effect of the initial lateral drawing becomes particularly noticeable.
  • a particularly useful figure of the lateral drawing ratio for polypropylene for example is about 7:1 giving good mean results for commercial operations.
  • the filaments are preferably drawn longitudinally to a drawing ratio of 4:] to 10:1 polymer type and variety, for the same reasons, though, as explained below, the film may already have been drawn longitudinally to a small extent before dividing, which would reduce the upper limit of the range of ratios.
  • the useful value for commercial operation is about 5:l or 6:l.
  • the total longitudinal drawing ratio, both before and after dividing into filaments is preferably from 4:1 to 12:2; in the longitudinal direction, the upper limit of the drawing ratio is preferably close to the fibrillation point; a preferred commercial value for the total longitudinal drawing ratio, both before and after dividing into filaments, can be about 7:! for polypropylene.
  • the total longitudinal drawing ratio, both before and after dividing into filaments may be approximately equal to the drawing ratio to which the film is drawn laterally before dividing it into filaments.
  • the drawing ratios must be chosen having regard to the plastics material used.
  • the known materials suitable for lateral prestretching are polyethylene, nylon and polyester.
  • the main uses of filaments according to the invention can be divided into groups, namely:
  • Warp yarn for weaving or warp-knitting or other fabricforming processes l. Warp yarn for weaving or warp-knitting or other fabricforming processes.
  • filaments may be used for a wide variety of purposes, amongst which may be listed shirt fabrics, tyre cords, carpet tufts and ropes.
  • Machinery for stretching plastics material film laterally need not be described in detail.
  • the machinery may be for instance for blowing film.
  • some machine direction (longitudinal) stretch is inevitable, though any longitudinal stretching or drawing should in general be kept as small as possible prior to dividing.
  • British Pat. specification No. l,067,5l4 describes some arrangement for slitting plastics material film. However, the arrangement which is now preferred is described below.
  • FIG. 1 is a schematic side view of apparatus in accordance with the invention.
  • FIG. 2 is a section through the cutter arrangement, on a larger scale than that of FIG. 1, taken along the line II-II of Figure 3;
  • FIG. 3 is a view in the direction III shown in Figure 2, parts being shown in section.
  • FIG. 1 laterally drawn plastics material film l is drawn off a roll 2 and is passed over a banana roller 3 in order to remove any creases from the plastic film 1.
  • Banana rollers are known, and are formed of a deformable substance such as rubber and mounted on a fixed axle which in this case is bowed upwards so that the periphery of the roller has an upwards bow.
  • the film is slit by a cutter arrangement 4 (described in more detail below, the reference to FIGS. 2 and 3) and is held against the cutters by small backing rolls 5.
  • the filaments 6, all lying in one plane pass round a set of godet rolls 7, under a heater 8, and around a further set of godet rolls 9 which draw the heated filaments to a predetermined longitudinal drawing ratio.
  • the drawn filaments then pass through a parallel run comb l0 (which maintains the parallelity of the filaments between the cutter arrangement 4 and the comb 10), a diverging comb ll to diverge the filaments to any desired extent, or a converging comb l2 to converge the filaments and a variable traverse comb l3, prior to being wound onto a rotary member 14 such as a warp beam.
  • the rotary member I4 is mounted on swinging arms 15 and bears by gravity on a rubber-covered driving roller 16 which drives the rotary member l4 at a substantially constant peripheral velocity.
  • the variable traverse comb 13 can be used to build up a package on the rotary member l4 which has conical ends, to prevent the end windings slipping; alternatively, the traverse of the comb l3 is gradually shortened as winding proceeds to build a number of pineapple cores.
  • British Pat. applications No. 45589/66 and 6I82/67 give details of ancillary equipment that may be used in association with the plant.
  • the cutters of the cutter arrangement 4 are safety razor blades 16 which are clamped in position.
  • ordinary commercial safety razor blades are broken down the middle, along the line l7, and the ends of the blades are broken off at right angles to this line 17 in order to give sharp points at each corner of the blade. By providing these sharp points, no difficulties are met with on start-up.
  • the film On start-up, the film is threaded through to the rotary member 14, and the points of the blades are then inserted into the film to start slitting.
  • the blades 16 are split in half in order to facilitate insertion into the clamping arrangement. It will be noted that by reversing the blades, four different cutting edges can be used for each blade.
  • the blades 16 are clamped in position by annular spacers 18 through which is threaded a spindle 19; the spindle 19 carries a mounting bush 20 and a lock nut and washer arrangement 21.
  • the blades are slowly reciprocated up and down using an eccentric and slide arrangement, for instance with a period of 20 to 40 seconds.
  • a slide member 22 is fixed to the bush 20, and the bush 20 is in turn keyed or pinned to the rod 19; the slide member 22 slides in a slideway 23 shown dotted in FIG. 2, and in this way keeps the edges of the blade 16 at an attitude of about 45 to the film 1.
  • An eccentric 24 is connected to the bush 20 by a connecting rod 25 in order to provide the reciprocating movement of the blade 16.
  • Suitable parameters for the apparatus are as follows:
  • the maximum number of filaments depends on machine width, slitting width, and number of film layers slit simultaneously. Thus for a 2,000 mm. machine fed with double layer film and employing a cutting head with a cutter pitch of 1 mm, the maximum number of filaments would be about 4000, allowing marginal waste for the edge tapes.
  • Warp lengths 2,000 to 40,000 meters.
  • Example 1 illustrates the invention whereas Example 2 does not.
  • cast polypropylene film is given a lateral stretch of 600 percent (7:1 drawing ratio) and a longitudinal stretch of 40 percent (1.4:l drawing ratio), the resulting stretched film weighing gms. per square meter.
  • the stretched film is then slit to give a large number of filaments l.l mm. wide.
  • the slit filaments are then given longitudinal stretch of 400 percent (5:l drawing ratio).
  • the resulting filaments have a denier of 41 and a width of about 0.25 mm.
  • Example 2 Cast polypropylene film weighing 75 gms. per square meter was slit to provide H mm. wide filaments. The filaments were given a longitudinal stretch of 500 percent (6:1 drawing ratio). The resulting filaments had a denier of 36 but a width of about 0.6 mm.
  • a method of producing plastic filaments comprising drawing plastic film laterally to impart a substantial lateral stretch thereto,
  • plastic is polypropylene, polyethylene, nylon or polyester.
  • Apparatus for producing filaments including means for drawing plastic film laterally to impart a substantial lateral stretch thereto,

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

Producing filaments by drawing plastic film laterally, slitting the film into filaments and drawing the filaments longitudinally.

Description

United States Patent SLlTTlNG TO FORM FILAMENTS 10 Claims, 3 Drawing Figs.
US. Cl 264/103, 264/147, 264/160, 264/290, 18/1 Int. Cl B29c 17/02, B29c 17/14 Field of Search 264/ 147,
210, 160,103; 18/1 FB, 1 FS References Cited UNITED STATES PATENTS Annesser Ryan Berggren FOREIGN PATENTS Great Britain Great Britain Primary Examiner-Robert F. White Assistant Examiner-Allen M. Sokal Attorney-Holman & Stein ABSTRACT: Producing filaments by drawing plastic film laterally, slitting the film into filaments and drawing the filaments longitudinally.
SLITTING TO FORM FILAMENTS It is known to produce filaments by slitting or otherwise dividing plastics material sheet.
In British Pat. specification No. l,067,5l4, there is described a process in which drawable plastics material sheet is divided into filaments which are then drawn to decrease their denier. British Pat. specification No. l,097,l38 describes a modification of such a process.
According to a first aspect of the present invention, there is provided a method of producing filaments, including longitudinally dividing drawable plastics material film which has already been drawn laterally, to produce filaments, and then drawing the filaments longitudinally.
According to a second aspect of the present invention, there is provided apparatus for producing filaments, including means for drawing plastic film laterally to impart a substantial lateral stretch thereto, means for dividing said film longitudinally to provide longitudinally extended filaments,. and means for drawing said filaments longitudinally to impart a substantial longitudinal stretch thereto.
According to a third aspect of the present invention, there is provided a filament which has been produced by the first aspect of the invention.
Using the invention, it is possible to produce very fine filaments. If undrawn cast film is slit, and the filaments are then drawn, the lateral contraction of each filament is usually proportional to the square root of the drawing ratio. However, if the film has been drawn laterally before slitting, the lateral contraction of each filament is much greater, decreasing the width to thickness ratio of the filament.
The drawn filaments produced in accordance with this invention can be wound on to a single rotary member in the manner described in British Pat. specification No. 1,067,514 and No. l,097,138; thus a large number of filaments, suitable for preparing a warp, may be produced from the film and wound onto a single rotary member, and an even larger number of filaments may have been produced from the film in the first instance to allow some of the filaments to be cast out. Alternatively, the filaments produced in accordance with this invention may be for instance wound onto spindles or used for other purposes as explained hereafter; filaments in accordance with the invention are for example useful in core yarns.
The film slit is preferably unapertured, i.e. not provided with any pattern of holes or slits, until such time as it is divided in accordance with the invention.
The preferred plastics materials are polypropylene, polyethylene, nylon and polyester due to their drawing characteristics. The extent to which e.g. polypropylene filaments can be drawn longitudinally after slitting depends on the extent to which the polypropylene film was stretched longitudinally (if at all) before slitting. For instance, fine cast polypropylene film (say 60 gauge film) may be drawn longitudinally a little before it is chilled on a chill roll, causing a certain amount of polymer orientation. Maximum drawing ratios may vary from one film type to another depending on polymer types, extrusion techniques and stretching techniques. In the case of polypropylene, for example, these ratios may be between the limits of say 2:l to l4:l, before fibrillation occurs although in the case of nylon the maximum encountered is 5:l. In this context, drawing ratios are such that fibrillation point is not reached in materials which can be fibrillated.
In general, the preferred lateral drawing ratio is from 2:l to l4:l; above 4:] the effect of the initial lateral drawing becomes particularly noticeable. A particularly useful figure of the lateral drawing ratio for polypropylene for example is about 7:1 giving good mean results for commercial operations.
The filaments are preferably drawn longitudinally to a drawing ratio of 4:] to 10:1 polymer type and variety, for the same reasons, though, as explained below, the film may already have been drawn longitudinally to a small extent before dividing, which would reduce the upper limit of the range of ratios. The useful value for commercial operation is about 5:l or 6:l.
The total longitudinal drawing ratio, both before and after dividing into filaments, is preferably from 4:1 to 12:2; in the longitudinal direction, the upper limit of the drawing ratio is preferably close to the fibrillation point; a preferred commercial value for the total longitudinal drawing ratio, both before and after dividing into filaments, can be about 7:! for polypropylene. In general, the total longitudinal drawing ratio, both before and after dividing into filaments, may be approximately equal to the drawing ratio to which the film is drawn laterally before dividing it into filaments.
The drawing ratios must be chosen having regard to the plastics material used. Apart from polypropylene, the known materials suitable for lateral prestretching are polyethylene, nylon and polyester.
The invention can give the following advantages:
1. High linear wind-on speed, whether for a single rotary member or for individual spindles.
2. Fine yarn; yarn widths of down to 016 millimeter and 30 denier have been produced.
3. Yarns suitable for weaving, knitting core spinning and crimping; tensile strengths of 6.0 gm./denier and more are obtainable for polypropylene for example. Generally the finer the yarn the higher the maximum tensile strength obtainable.
The main uses of filaments according to the invention can be divided into groups, namely:
l. Warp yarn for weaving or warp-knitting or other fabricforming processes.
2. Mono or multifilament yarns for subsequent uptwisting, crimping, core yarn spinning, doubling with other yarns, and may other applications for which conventional yarns are used in fabric forming including pile yarns.
Thus the filaments may be used for a wide variety of purposes, amongst which may be listed shirt fabrics, tyre cords, carpet tufts and ropes.
Machinery for stretching plastics material film laterally need not be described in detail. The machinery may be for instance for blowing film. In some cases, some machine direction (longitudinal) stretch is inevitable, though any longitudinal stretching or drawing should in general be kept as small as possible prior to dividing.
British Pat. specification No. l,067,5l4 describes some arrangement for slitting plastics material film. However, the arrangement which is now preferred is described below.
The invention will be further described, by the way of example, with reference to the accompanying drawings, in which:
FIG. 1 is a schematic side view of apparatus in accordance with the invention;
FIG. 2 is a section through the cutter arrangement, on a larger scale than that of FIG. 1, taken along the line II-II of Figure 3; and
FIG. 3 is a view in the direction III shown in Figure 2, parts being shown in section.
The apparatus is shown in operation. In FIG. 1, laterally drawn plastics material film l is drawn off a roll 2 and is passed over a banana roller 3 in order to remove any creases from the plastic film 1. Banana rollers are known, and are formed of a deformable substance such as rubber and mounted on a fixed axle which in this case is bowed upwards so that the periphery of the roller has an upwards bow. After passing over the banana roller 3, the film is slit by a cutter arrangement 4 (described in more detail below, the reference to FIGS. 2 and 3) and is held against the cutters by small backing rolls 5. After being slit, the filaments 6, all lying in one plane, pass round a set of godet rolls 7, under a heater 8, and around a further set of godet rolls 9 which draw the heated filaments to a predetermined longitudinal drawing ratio. The drawn filaments then pass through a parallel run comb l0 (which maintains the parallelity of the filaments between the cutter arrangement 4 and the comb 10), a diverging comb ll to diverge the filaments to any desired extent, or a converging comb l2 to converge the filaments and a variable traverse comb l3, prior to being wound onto a rotary member 14 such as a warp beam. The rotary member I4 is mounted on swinging arms 15 and bears by gravity on a rubber-covered driving roller 16 which drives the rotary member l4 at a substantially constant peripheral velocity. The variable traverse comb 13 can be used to build up a package on the rotary member l4 which has conical ends, to prevent the end windings slipping; alternatively, the traverse of the comb l3 is gradually shortened as winding proceeds to build a number of pineapple cores.
As mentioned above, machinery for laterally stretching plastic film need not be described in detail. Nonetheless, the roll 2 of laterally stretched film could be replaced by suitable machinery for stretching unorientated film laterally.
British Pat. applications No. 45589/66 and 6I82/67 give details of ancillary equipment that may be used in association with the plant.
As shown in FIG. 22, the cutters of the cutter arrangement 4 are safety razor blades 16 which are clamped in position. In order to provide the blades 16, ordinary commercial safety razor blades are broken down the middle, along the line l7, and the ends of the blades are broken off at right angles to this line 17 in order to give sharp points at each corner of the blade. By providing these sharp points, no difficulties are met with on start-up.
On start-up, the film is threaded through to the rotary member 14, and the points of the blades are then inserted into the film to start slitting.
The blades 16 are split in half in order to facilitate insertion into the clamping arrangement. It will be noted that by reversing the blades, four different cutting edges can be used for each blade.
The blades 16 are clamped in position by annular spacers 18 through which is threaded a spindle 19; the spindle 19 carries a mounting bush 20 and a lock nut and washer arrangement 21.
in order to spread the wear along the length of each blade l6, the blades are slowly reciprocated up and down using an eccentric and slide arrangement, for instance with a period of 20 to 40 seconds. To this end, a slide member 22 is fixed to the bush 20, and the bush 20 is in turn keyed or pinned to the rod 19; the slide member 22 slides in a slideway 23 shown dotted in FIG. 2, and in this way keeps the edges of the blade 16 at an attitude of about 45 to the film 1. An eccentric 24 is connected to the bush 20 by a connecting rod 25 in order to provide the reciprocating movement of the blade 16.
Suitable parameters for the apparatus are as follows:
1. Width at roll 2; 1100-2000 mm.
2. Width at rotary member 14; :50 percent of width at roll 2.
3. Drawing ratios, i.e. longitudinal and and lateral stretch in film in roll 2 and drawing ratio between the godet rolls 7, 9; discussed above.
4. Speed of filaments at rotary member 14; 220-440 in. per minute depending one type and variety of polymer.
5. Slitting width (distance between edges of adjacent blades 16); 0.8 mm. to 3 mm. or more.
6. Resultant width of filament at rotary member 14; 0.l6 mm. upwards or even less.
7. The maximum number of filaments depends on machine width, slitting width, and number of film layers slit simultaneously. Thus for a 2,000 mm. machine fed with double layer film and employing a cutting head with a cutter pitch of 1 mm, the maximum number of filaments would be about 4000, allowing marginal waste for the edge tapes.
8. Film gauges; 12 to 120 micron.
9. Warp lengths; 2,000 to 40,000 meters.
10. Barrel diameter of rotary member 14; 300 mm.
These parameters are only given by way of example. The apparatus illustrated could be used with different parameters.
The methods described in the following examples could be carried out on the apparatus shown, but Example 1 illustrates the invention whereas Example 2 does not.
xample 1 In accordance with the invention, cast polypropylene film is given a lateral stretch of 600 percent (7:1 drawing ratio) and a longitudinal stretch of 40 percent (1.4:l drawing ratio), the resulting stretched film weighing gms. per square meter. The stretched film is then slit to give a large number of filaments l.l mm. wide. The slit filaments are then given longitudinal stretch of 400 percent (5:l drawing ratio). The resulting filaments have a denier of 41 and a width of about 0.25 mm.
Example 2 Cast polypropylene film weighing 75 gms. per square meter was slit to provide H mm. wide filaments. The filaments were given a longitudinal stretch of 500 percent (6:1 drawing ratio). The resulting filaments had a denier of 36 but a width of about 0.6 mm.
It can be seen from a comparison of Examples 1 and 2 that the filaments produced in accordance with the invention will have much finer appearance than those of Example 2, being more nearly square in cross section.
I claim:
1. A method of producing plastic filaments, comprising drawing plastic film laterally to impart a substantial lateral stretch thereto,
dividing said film longitudinally to provide a plurality of iongitudinally extending filaments, and
drawing said filaments longitudinally to impart a substantial longitudinal stretch thereto whilst achieving a substantially exaggerated lateral contraction thereof.
2. A method as claimed in claim 1, wherein said plastic is polypropylene, polyethylene, nylon or polyester.
3. A method as claimed in claim 1, wherein said film is drawn laterally to a drawing ratio of from 2:1 to 14: l.
4. A method as claimed in claim 1, wherein said film is polypropylene and is drawn laterally to a drawing ratio of about 7: l.
5. A method as claimed in claim 1, wherein said filaments are d rawn longitudinally to a drawing ratio of from 2: l to l4:l
6. A method as claimed in claim 1, wherein the total iongitudinal drawing ratio, both before and after dividing into filaments, is from 4:1 to 12:1.
7. A method as claimed in claim 1, wherein the total longitudinal drawing ratio, both before and after dividing into filaments, is approximately equal to the drawing ratio to which the film is drawn laterally before dividing it into filaments.
8. A method as claimed in claim 1, wherein a large number of said filaments are produced from said film by said dividing and are wound onto one or more rotary members after said longitudinal drawing, to form warp or yarn packages side by side on the or each rotary member.
9. Apparatus for producing filaments, including means for drawing plastic film laterally to impart a substantial lateral stretch thereto,
means for dividing said film longitudinally to provide a plurality of longitudinally extending filaments, and
means for drawing said filaments longitudinally to impart a substantial longitudinal stretch thereto whilst achieving a substantially exaggerated lateral contraction thereof.
l0. Apparatus as claimed in claim 9, and further comprising means for mounting one or more rotary members for winding on a large number of said longitudinally stretched filaments.

Claims (9)

1. A method of producing plastic filaments, comprising drawing plastic film laterally to impart a substantial lateral stretch thereto, dividing said film longitudinally to provide a plurality of longitudinally extending filaments, and drawing said filaments longitudinally to impart a substantial longitudinal stretch thereto whilst achieving a substantially exaggerated lateral contraction thereof.
2. A method as claimed in claim 1, wherein said plastic is polypropylene, polyethylene, nylon or polyester.
3. A method as claimed in claim 1, wherein said film is drawn laterally to a drawing ratio of from 2:1 to 14:1.
4. A method as claimed in claim 1, wherein said film is polypropylene and is drawn laterally to a drawing ratio of about 7:1.
5. A method as claimed in claim 1, wherein said filaments are drawn longitudinally to a drawing ratio of from 2:1 to l4:1.
6. A method as claimed in claim 1, wherein the total longitudinal drawing ratio, both before and after dividing into filaments, is from 4:1 to 12:1.
7. A method as claimed in claim 1, wherein the total longitudinal drawing ratio, both before and after dividing into filaments, is approximately equal to the drawing ratio to which the film is drawn laterally before dividing it into filaments.
8. A method as claimed in claim 1, wherein a large number of said filaments are produced from said film by said dividing and are wound onto one or more rotary members after said longitudinal drawing, to form warp or yarn packages side by side on the or each rotary member.
9. Apparatus for producing filaments, including means for drawing plastic film laterally to impart a substantial lateral stretch thereto, means for dividing said film longitudinally to provide a plurality of longitudinally extending filaments, and means for drawing said filaments longitudinally to impart a substantial longitudinal stretch thereto whilst achieving a substantially exaggerated lateral contraction thereof. l0. Apparatus as claimed in claim 9, and further comprising means for mounting one or more rotary members for winding on a large number of said longitudinally stretched filaments.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4060999A (en) * 1974-11-05 1977-12-06 Enterprise Incorporated Method and apparatus for forming yarn elements and producing products therefrom
US4415517A (en) * 1981-07-31 1983-11-15 Manville Service Corporation Method and apparatus for shaping fiber mats
US5366804A (en) * 1993-03-31 1994-11-22 Basf Corporation Composite fiber and microfibers made therefrom

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4060999A (en) * 1974-11-05 1977-12-06 Enterprise Incorporated Method and apparatus for forming yarn elements and producing products therefrom
US4415517A (en) * 1981-07-31 1983-11-15 Manville Service Corporation Method and apparatus for shaping fiber mats
US5366804A (en) * 1993-03-31 1994-11-22 Basf Corporation Composite fiber and microfibers made therefrom

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