US3584008A - Phosphoramidates of cyclic amidines - Google Patents
Phosphoramidates of cyclic amidines Download PDFInfo
- Publication number
- US3584008A US3584008A US665288A US3584008DA US3584008A US 3584008 A US3584008 A US 3584008A US 665288 A US665288 A US 665288A US 3584008D A US3584008D A US 3584008DA US 3584008 A US3584008 A US 3584008A
- Authority
- US
- United States
- Prior art keywords
- acids
- acid
- corrosion
- oil
- mole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- -1 cyclic amidines Chemical class 0.000 title description 56
- 150000008298 phosphoramidates Chemical class 0.000 title description 2
- 238000005260 corrosion Methods 0.000 abstract description 35
- 230000007797 corrosion Effects 0.000 abstract description 35
- 239000003112 inhibitor Substances 0.000 abstract description 29
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 11
- 239000001301 oxygen Substances 0.000 abstract description 11
- 229910052760 oxygen Inorganic materials 0.000 abstract description 11
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 10
- 150000001408 amides Chemical class 0.000 abstract description 10
- 229910052717 sulfur Inorganic materials 0.000 abstract description 10
- 239000011593 sulfur Substances 0.000 abstract description 10
- 150000001409 amidines Chemical class 0.000 abstract description 9
- 150000001875 compounds Chemical class 0.000 abstract description 9
- 150000003016 phosphoric acids Chemical class 0.000 abstract description 7
- 239000001257 hydrogen Substances 0.000 abstract description 6
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 6
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 abstract description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 5
- VSWICNJIUPRZIK-UHFFFAOYSA-N 2-piperideine Chemical compound C1CNC=CC1 VSWICNJIUPRZIK-UHFFFAOYSA-N 0.000 abstract description 2
- 239000002253 acid Substances 0.000 description 59
- 150000007513 acids Chemical class 0.000 description 40
- 239000000203 mixture Substances 0.000 description 34
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 30
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 24
- 238000006243 chemical reaction Methods 0.000 description 21
- 239000003153 chemical reaction reagent Substances 0.000 description 21
- 239000003921 oil Substances 0.000 description 19
- 239000012530 fluid Substances 0.000 description 17
- 235000019198 oils Nutrition 0.000 description 17
- 238000000034 method Methods 0.000 description 15
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 13
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 11
- 239000000839 emulsion Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 125000004432 carbon atom Chemical group C* 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 150000008039 phosphoramides Chemical class 0.000 description 9
- 235000011007 phosphoric acid Nutrition 0.000 description 9
- 150000003254 radicals Chemical class 0.000 description 9
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 8
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- 239000000194 fatty acid Substances 0.000 description 8
- 229930195729 fatty acid Natural products 0.000 description 8
- 150000004665 fatty acids Chemical class 0.000 description 8
- 230000000865 phosphorylative effect Effects 0.000 description 8
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 7
- 239000003350 kerosene Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 6
- 150000002462 imidazolines Chemical class 0.000 description 6
- 230000002401 inhibitory effect Effects 0.000 description 6
- 229920006395 saturated elastomer Polymers 0.000 description 6
- 150000005326 tetrahydropyrimidines Chemical class 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- 150000008064 anhydrides Chemical class 0.000 description 5
- 235000010233 benzoic acid Nutrition 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- HUVYLRHAZAEUHY-UHFFFAOYSA-N 2-(4,5-dihydroimidazol-1-yl)ethanamine Chemical compound NCCN1CCN=C1 HUVYLRHAZAEUHY-UHFFFAOYSA-N 0.000 description 4
- 239000005711 Benzoic acid Substances 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 125000002947 alkylene group Chemical group 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 239000010426 asphalt Substances 0.000 description 4
- 239000012267 brine Substances 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- 229920000768 polyamine Polymers 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- 230000005764 inhibitory process Effects 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 3
- 239000003129 oil well Substances 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 235000005985 organic acids Nutrition 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- CYQAYERJWZKYML-UHFFFAOYSA-N phosphorus pentasulfide Chemical compound S1P(S2)(=S)SP3(=S)SP1(=S)SP2(=S)S3 CYQAYERJWZKYML-UHFFFAOYSA-N 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
- YWWVWXASSLXJHU-AATRIKPKSA-N (9E)-tetradecenoic acid Chemical compound CCCC\C=C\CCCCCCCC(O)=O YWWVWXASSLXJHU-AATRIKPKSA-N 0.000 description 2
- LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 description 2
- MKJHXLKVZNDNDB-UHFFFAOYSA-N 2-phenyloctadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(C(O)=O)C1=CC=CC=C1 MKJHXLKVZNDNDB-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 125000003158 alcohol group Chemical group 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- NZNMSOFKMUBTKW-UHFFFAOYSA-N cyclohexanecarboxylic acid Chemical compound OC(=O)C1CCCCC1 NZNMSOFKMUBTKW-UHFFFAOYSA-N 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- WVPKAWVFTPWPDB-UHFFFAOYSA-M dichlorophosphinate Chemical compound [O-]P(Cl)(Cl)=O WVPKAWVFTPWPDB-UHFFFAOYSA-M 0.000 description 2
- LGTLXDJOAJDFLR-UHFFFAOYSA-N diethyl chlorophosphate Chemical compound CCOP(Cl)(=O)OCC LGTLXDJOAJDFLR-UHFFFAOYSA-N 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- ICAIHSUWWZJGHD-UHFFFAOYSA-N dotriacontanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O ICAIHSUWWZJGHD-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 230000002070 germicidal effect Effects 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- XMHIUKTWLZUKEX-UHFFFAOYSA-N hexacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O XMHIUKTWLZUKEX-UHFFFAOYSA-N 0.000 description 2
- 150000002440 hydroxy compounds Chemical class 0.000 description 2
- CBFCDTFDPHXCNY-UHFFFAOYSA-N icosane Chemical compound CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 125000005608 naphthenic acid group Chemical group 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 2
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 2
- PTMHPRAIXMAOOB-UHFFFAOYSA-N phosphoramidic acid Chemical compound NP(O)(O)=O PTMHPRAIXMAOOB-UHFFFAOYSA-N 0.000 description 2
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- 239000000376 reactant Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
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- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- CUXYLFPMQMFGPL-UHFFFAOYSA-N (9Z,11E,13E)-9,11,13-Octadecatrienoic acid Natural products CCCCC=CC=CC=CCCCCCCCC(O)=O CUXYLFPMQMFGPL-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- JDFOIACPOPEQLS-UHFFFAOYSA-N 1,2,2,3-tetramethylcyclopentane-1-carboxylic acid Chemical compound CC1CCC(C)(C(O)=O)C1(C)C JDFOIACPOPEQLS-UHFFFAOYSA-N 0.000 description 1
- OTPDWCMLUKMQNO-UHFFFAOYSA-N 1,2,3,4-tetrahydropyrimidine Chemical compound C1NCC=CN1 OTPDWCMLUKMQNO-UHFFFAOYSA-N 0.000 description 1
- SAICLZQEEAYNKM-UHFFFAOYSA-N 1-ethyl-4,5-dihydroimidazol-2-amine Chemical compound CCN1CCN=C1N SAICLZQEEAYNKM-UHFFFAOYSA-N 0.000 description 1
- PGJFZEZVGMGXJZ-ZAJAATJQSA-N 10,12,14-octadecatrienoic acid Chemical compound CCC\C=C\C=C\C=C\CCCCCCCCC(O)=O PGJFZEZVGMGXJZ-ZAJAATJQSA-N 0.000 description 1
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- ROVGZAWFACYCSP-MQBLHHJJSA-N [2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-MQBLHHJJSA-N 0.000 description 1
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- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000005237 alkyleneamino group Chemical group 0.000 description 1
- CUXYLFPMQMFGPL-SUTYWZMXSA-N all-trans-octadeca-9,11,13-trienoic acid Chemical compound CCCC\C=C\C=C\C=C\CCCCCCCC(O)=O CUXYLFPMQMFGPL-SUTYWZMXSA-N 0.000 description 1
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- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
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- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
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- 125000003739 carbamimidoyl group Chemical group C(N)(=N)* 0.000 description 1
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- XKZKQTCECFWKBN-SREVYHEPSA-N cis-4-decenoic acid Chemical compound CCCCC\C=C/CCC(O)=O XKZKQTCECFWKBN-SREVYHEPSA-N 0.000 description 1
- SECPZKHBENQXJG-UHFFFAOYSA-N cis-palmitoleic acid Natural products CCCCCCC=CCCCCCCCC(O)=O SECPZKHBENQXJG-UHFFFAOYSA-N 0.000 description 1
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- GEHPRJRWZDWFBJ-UHFFFAOYSA-N heptadec-2-enoic acid Chemical class CCCCCCCCCCCCCCC=CC(O)=O GEHPRJRWZDWFBJ-UHFFFAOYSA-N 0.000 description 1
- YURNCBVQZBJDAJ-UHFFFAOYSA-N heptenoic acid group Chemical class C(C=CCCCC)(=O)O YURNCBVQZBJDAJ-UHFFFAOYSA-N 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- ZVRMGCSSSYZGSM-UHFFFAOYSA-N hexadec-2-enoic acid Chemical class CCCCCCCCCCCCCC=CC(O)=O ZVRMGCSSSYZGSM-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 150000002531 isophthalic acids Chemical class 0.000 description 1
- 239000012182 japan wax Substances 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
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- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000012184 mineral wax Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- LSHROXHEILXKHM-UHFFFAOYSA-N n'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine Chemical compound NCCNCCNCCNCCNCCN LSHROXHEILXKHM-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- SDVVLIIVFBKBMG-UHFFFAOYSA-N penta-2,4-dienoic acid Chemical class OC(=O)C=CC=C SDVVLIIVFBKBMG-UHFFFAOYSA-N 0.000 description 1
- HOGWBMWOBRRKCD-UHFFFAOYSA-N pentadec-2-enoic acid Chemical class CCCCCCCCCCCCC=CC(O)=O HOGWBMWOBRRKCD-UHFFFAOYSA-N 0.000 description 1
- YIYBQIKDCADOSF-UHFFFAOYSA-N pentenoic acid group Chemical class C(C=CCC)(=O)O YIYBQIKDCADOSF-UHFFFAOYSA-N 0.000 description 1
- 229950000688 phenothiazine Drugs 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- PTMHPRAIXMAOOB-UHFFFAOYSA-L phosphoramidate Chemical compound NP([O-])([O-])=O PTMHPRAIXMAOOB-UHFFFAOYSA-L 0.000 description 1
- 125000001863 phosphorothioyl group Chemical group *P(*)(*)=S 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- LFGREXWGYUGZLY-UHFFFAOYSA-N phosphoryl Chemical group [P]=O LFGREXWGYUGZLY-UHFFFAOYSA-N 0.000 description 1
- 230000026731 phosphorylation Effects 0.000 description 1
- 238000006366 phosphorylation reaction Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004999 plastisol Substances 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 229940015367 pyrethrum Drugs 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000006798 ring closing metathesis reaction Methods 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical class OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000019512 sardine Nutrition 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 239000012177 spermaceti Substances 0.000 description 1
- 229940084106 spermaceti Drugs 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 150000003504 terephthalic acids Chemical class 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- QZZGJDVWLFXDLK-UHFFFAOYSA-N tetracosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCC(O)=O QZZGJDVWLFXDLK-UHFFFAOYSA-N 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 150000003582 thiophosphoric acids Chemical class 0.000 description 1
- UIERETOOQGIECD-ONEGZZNKSA-N tiglic acid group Chemical group C(\C(\C)=C\C)(=O)O UIERETOOQGIECD-ONEGZZNKSA-N 0.000 description 1
- DPUOLQHDNGRHBS-MDZDMXLPSA-N trans-Brassidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-MDZDMXLPSA-N 0.000 description 1
- XXHDAWYDNSXJQM-ONEGZZNKSA-N trans-hex-3-enoic acid Chemical compound CC\C=C\CC(O)=O XXHDAWYDNSXJQM-ONEGZZNKSA-N 0.000 description 1
- 229960001124 trientine Drugs 0.000 description 1
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical class CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000010698 whale oil Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/06—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D233/06—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
- C07D233/08—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms with alkyl radicals, containing more than four carbon atoms, directly attached to ring carbon atoms
- C07D233/10—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms with alkyl radicals, containing more than four carbon atoms, directly attached to ring carbon atoms with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D233/06—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
- C07D233/08—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms with alkyl radicals, containing more than four carbon atoms, directly attached to ring carbon atoms
- C07D233/12—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms with alkyl radicals, containing more than four carbon atoms, directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D233/16—Radicals substituted by nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
- C07F9/6503—Five-membered rings
- C07F9/6506—Five-membered rings having the nitrogen atoms in positions 1 and 3
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/167—Phosphorus-containing compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S507/00—Earth boring, well treating, and oil field chemistry
- Y10S507/939—Corrosion inhibitor
Definitions
- This invention relates to amides of cyclic amidines and phosphoric acids. More particularly this invention relates to amides of the formula where is a cyclic amidine containing radical, for example imidazoline, and tetrahydropyrimidine; X is oxygen and/or sulfur; R is hydrogen or an alcohol moiety; A is alkylene; n is I-3; and p is 0-10. This invention also relates to uses for these amides, including their use as corrosion inhibitors.
- R comprises, for example, a saturated or unsaturated aliphatic radical, a cycloaliphatic radical, an aryl radical, an aralkyl radical, an alkaryl radical, an alkoxy- 3,584,008 Patented June 8, 1971 alkyl radical, an aryloxyxalkyl radical, and the like; and
- A is an alkylene group; for example, ethylene and propylene radicals, such as
- the cyclic amidine phosphoramidates are prepared by reacting phosphorylating reagents such as phosphoric acids and thiophosphoric acids and derivatives of these such as anhydrides, partial anhydrides and halides, with the desired molar ratio of amino containing cyclic amidines for example of the formula i )p where p is 0-10.
- the products are characterized by having at least one P-N bond.
- the corrosion inhibiting aspect of this invention relates to a method for inhibiting corrosion of ferrous metals by hydrocarbon fluids containing water and corrosive materials such as H 8, CO inorganic acids, organic acids, etc., combinations of these materials with each other, combinations of each of said corrosive materials with oxygen, and combinations of said materials with each other and oxygen, which comprises adding to said fluids at least five parts per million of the above cyclic amidine phosphoramidates, said compounds being sufiiciently soluble in the hydrocarbon fluid to inhibit corrosion.
- corrosive materials such as H 8, CO inorganic acids, organic acids, etc.
- cyclic amidines is employed in its usual sense to indicate ring compounds in which there are present either 5 members or 6 members, and having 2 nitrogen atoms separated by a single carbon atom supplemented by either two additional carbon atoms or three additional carbon atoms completing the ring. All the carbon atoms may be substituted.
- the nitrogen atom of the ring involving two monovalent linkages (the 1-position) is substituted with an amino-containing group capable of reacting with the phosphate precursor to form the amides of this invention.
- This amino containing side group may be represented by -(XNR'),,H wherein X is alkylene and R is hydrogen or alkyl, but preferably hydrogen, and n is a whole number, for example, 0-10 or higher, but preferably 0-3.
- cyclic amidines are further characterized as being imidazolines and tetrahydropyrimidines unsubstituted in l-position or substituted in the 1-position with alkylene-amino or polyalkylene-amino group in which the two-position carbon of the ring is generally bonded to a hydrocarbon radical or comparable radical derived from an acid, such as a low molal fatty acid, a high molal fatty acid, or comparable acids, polycarboxy acids, and the like.
- Equally suitable for use in preparing compounds of my invention and for the preparation of tetrahydropyrimidines substituted in the 2-position are the polyamines containing at least one primary amino group and at least one secondary amino group, or another primary amino group separated from the first primary amino group by three carbon atoms instead of being separated by only two carbons as with imidazolines.
- This reaction as in the case of the imidazolines is generally carried out by heating the reactants to a temperature at which two moles of Water are evolved for each carboxylic group and ring closure is eiiected.
- German Pat. No. 700,731, dated Dec. 18, 1940, to Edmund Waldmann and August Chwala German Pat. No. 701,322, dated Jan. 14, 1941, to Karl Kiescher, Ernst Erech and Willi Klarer, and US. Pat. No. 2,194,419, dated Mar. 19, 1940, to August Chwala.
- Substituted imidazolines and tetrahydropyrimidines are obtained from a variety of acids beginning with the onecarbon acid (formic) through and including higher fatty acids or the equivalent having for example 32 carbon atoms.
- Modified fatty acids also can be employed as, for example, phenyl stearic acid or the like.
- Cyclic acids may be employed, including naphthenic acids.
- a variety of other acids including benzoic acid, substituted benzoic acid, salicyclic acid, and the like, have been employed to furnish the residue ll RC- from the acid RCOOH in which the C of the residue ll RC- is part of the ring.
- the fatty acids employed, for example, may be saturated or unsaturated. Branched long chain fatty acids may be employed. See J. Am. Chem. Soc. 74, 2523 (1952). This applies also to the lower molecular weight acids as well.
- sources of such acids may be mentioned straight chain and branched chain, saturated and unsaturated, aliphatic, cycloaliphatic, aromatic, hydroaromatic, aralkyl acids, etc.
- saturated aliphatic monocarboxylic acids comprise: acetic, propionic, butyric, valeric, caproic, heptanoic, caprylic, nonanoic, capric, undecanoic, lauric, tridecanoic, myriatic, pentadecanoic, palmitic, heptadecanoic, stearic, nonadecanoic, eicosanoic, heneicosanoic, docosanoic, tricosanoic, tetracosanoic, pentacosanoic, cerotic, heptacosanoic, montanic, nonacosanoic, melissic and the like.
- Examples of ethylenic unsaturated aliphatic acids comprise: angelic, tiglic, the pentenoic acids, the hexenoic acids, for example, hydrosorbic acid, the heptenoic acids, the octenoic acids, the nonenoic acids, the decenoic acids, for example, obtusilic acid, the undecanoic acids, the dodecenoic acids, for example, lauroleic, linderic, etc., the tridecenoic acids, the tetradecenoic acids, for example, myristoleic acid, the pentadecenoic acids, the hexadecenoic acids, for example, palmitoleic acid, the heptadecenoic acids, the octodecenoic acids, for example, petrosilenic acid, oleic acid, elaidic acid, the nonadecenoic acids, for example, the eicosenoic acids, the docoseno
- dienoic acids comprise the pentadienoic acids, the hexadienoic acids, for example, sorbic acid, the octadienoic acids, for example, linoleic, and the like.
- trienoic acids comprise the octadecatrienoic acids, for example, linolenic acid, eleostearic acid, pseudo-eleostearic acid, and the like.
- cyclic aliphatic carboxylic acids comprise those found in petroleum called naphthenic acids, hydrocarpic and chaulmoogric acids, bicyclopentane carboxylic acids, cyclohexanecarboxylic acid, campholic acid, fencholic acids, and the like.
- aromatic monocarboxylic acids comprise benzoic acid, substituted benzoic acids, for example, the toluic acids, the xyleneoic acids, alkoxy benzoic acid,
- phenyl benzoic acid naphthalene carboxylic acid, and the like.
- Fatty and similar acids include those derived from various waxes, such as beeswax, spermaceti, montan wax, japan wax, coccerin and carnauba wax.
- Such acids include carnaubic acid, cerotic acid, lacceric acid, montanic acid, psyllastearic acid, etc.
- Suitable acids include phenylstearic acid, benzoylnonylic acid, cetyloxybutyric acid, cetyloxyacetic acid, chlorstearic acid, etc.
- polycarboxylic acids comprise those of the aliphatic series, for example, oxalic, malonic, glutaric, adipic, pimelic, suberic, azelaic, sebacic, nonanedicarboxylic acid, decanedicarboxylic acids, undecanedicarboxylic acids, and the like.
- unsaturated aliphatic polycarboxylic acids comprise mesocenic, citraconic, glutonic, itaconic, muconic, acenitic acids, and the like.
- aromatic polycarboxylic acids comprise isophthalic acids, terephthalic acids, substituted derivatives thereof (e.g. alkyl, chloro, alkoxy, etc. deriva tives), biphenyldicarboxylic acid, diphenylether dicarboxylic acids, diphenylsulfone dicarboxylic acids and the like.
- Higher aromatic polycarboxylic acids containing more than two carboxylic groups comprise hemimellitic, trimellitic, trimesic, mellophanic, prehnitic, pyromellitic acids, mellitic acid, and the like.
- polycarboxylic acids comprise the dimeric, trimeric and poly acids, for example, diricinoleic acid, triricinoleic acid, polyricinoleic acid, and the like.
- Other polycarboxylic acids comprise those containing ether groups, for example, diglycollic acid. Mixtures of the above acids can be advantageously employed.
- acid precursors such as esters, acid chlorides, glycerides, etc. can be employed in place of the free acid.
- cyclic amidines within the scope of this invention include compounds of the formulae:
- the desired products are obtained by reacting an amino-containing cyclic amidine with a phosphorylating reagent which is a derivative of phosphoric acid.
- a phosphorylating reagent which is a derivative of phosphoric acid.
- R is H, alkyl (e.g. methyl, ethyl, propyl, hexyl, 2-ethyl hexyl, lauryl, etc.), cycloalkyl (e.g. cyclopentyl, cyclohexyl), aryl (phenyl, tolyl, anisyl) or heterocyclic (furfuryl, etc.).
- the simplest phosphorylating reagent which can be used is ortho-phosphoric acid, but this requires vigorous conditions to bring about reaction leading to side reaction.
- the products from this reagent are mixtures containing some monophosphoramidates,
- Reagents which are generally preferred as phosphorylating reagents are anhydrides, partial anhydrides and halides (including phosphoryl and thiophosphoryl trihalides, dialkyl or arylphosphorohalidates,
- phosphorus pentoxide is a powerful phosphorylating re agent which on reaction with an amino-containing amidine yields a mixture of phosphoramides It is often preferred to react the phosphorus pentoxide partially with the amino-containing amidine and then with a hydroxy compound such as a simple alcohol (e.g. ethanol, propanol). In this case a mixture containing phosphoramidate ester is obtained containing the following structures:
- Phosphorus pentasulfide is similarly a powerful phosphorylating reagent which with amino-containing amidines gives similar products to those obtained from phosphorus pentoxide in which some or all of the oxygens attached to posphorus are replaced by sulfur.
- Polyphosphoric acid is a reagent which is intermediate in phosphorylating power between ortho phosphoric acid and phosphorus pentoxide (it is in fact a partial anhydride). This reagent can be reacted alone with aminocontaining cyclic-amidines or in combination with hydroxy compounds to give products similar to those described for the phosphorus pentoxide.
- phosphorylating reagents which are used to prepare the products of this invention are halides of phosphoric acid.
- phosphoryl halide phosphoryl halide
- phosphorochloridates phosphorochloridates
- a phosphorodichloridate can be reacted with an amino-containing cyclic amidine to give a phosphoramidate as follows:
- the hydrogen chloride produced in these reactions is normally taken up by the amidine ring as the reaction proceeds. However, in some cases it may be desirable to add a base to remove the acid as it is formed.
- a tertiary amine such as pyridine may be used or an alkali metal oxide or carbonate such as calcium oxide or carbonate.
- EXAMPLE 2 To a stirred suspension of phosphorus pentoxide (52 g.; 0.4 mole) in toluene (130 ml.) was added the aminoethyl imidazoline of Example 1 (75 g.; 0.2 mole) dissolved in toluene (45 ml.) dropwise during 40 minutes. The mixture was then heated at 100-110 for 1% hours during which time most of the solid phosphorus pentoxide disappeared. After cooling to 40 2-ethyl hexanol (130 g.; 1 mole) was added over a period of 1% hours. During the addition the temperature rose to 60. The reaction was completed by heating at 110-120" for three hours. The product is a mixture of phosphoramides, the main constituents of which can be represented by the formulae:
- EXAMPLE 3 This example follows the procedure of Example 2 except that Z-ethyl hexanol is replaced by Alfol 810 (144 g.; 1 mole).
- Alfol 810 is a commercial mixture of C to C l-alkanol of average molecular weight 144.
- the product is likewise a mixture of phosphoramides.
- EXAMPLE 4 To a stirred suspension of phosphorus pentasulfide (72.5 g.; 0.33 mole) in toluene (130 ml.) was added the aminoethyl imidazoline of Example 1 (61 g.; 0.16 mole) dissolved in toluene (45 ml.) during 1% hours. The mixture was heated at 100110 for 1 /2 hours and then allowed to cool to 50. Ethanol (37.5 g.; 0.82 mole) was added dropwise during 1% hours at 50-60 and then heated at 105-110" for two hours to complete the reaction.
- the product is mainly a mixture of sulfur containing phosphoramides which can be represented by the formulae:
- EXAMPLE 5 This example is similar to Example 4 except that ethanol is replaced by an equimolar amount of 2-ethyl hexanol.
- the product is similarly mainly a mixture of sulfur containing phosphoramides of the following formulae:
- EXAMPLE 6 To a stirred suspension of phosphorus pentoxide (52 g.; 0.4 mole) in toluene (130 ml.) was added the aminoethyl imidazoline of Example 1 g.; 0.2 mole) during 30 minutes. The mixture was then heated at 110 for 1% hours. After cooling to 40 Alfol 810 oxyethylated with two weights of ethylene oxide (430 g.; 1 mole) was added dropwise at 40-55 in one hour. The reaction was completed by heating at -120 for three hours.
- the product comprises mainly of a mixture of phosphoramides of the following formulae:
- Tretamine #2 is a commercial polyamine mixture containing diethylene triamine, triethylene tetramine, tetraethylene pentamine and pentaethylene hexamine as major components.
- this phase of the invention relates to the inhibition of corrosion in the petroleum industry with specific reference to producing wells, pipe lines, refineries, tank storage, etc.
- this aspect of the invention relates to inhibiting corrosion caused by hydrogen sulfide, carbon dioxide, inorganic acids, organic acids, combinations of each with oxygen, and with each other and oxygen. More particularly, it relates to treating wells to mitigate metal corrosion and associated difficulties.
- demulsifiers may be added. This is important not only to avoid the troublesome emulsions and gels themselves, but also to improve corrosion inhibition.
- the explanation of less effective corrosion inhibition in the presence of emulsions apparently is that the inhibitor is somewhat surface-active. That is, it is concentrated at interfacial surfaces. Since this surface is great in an emulsion, most of the inhibitor will be concentrated in these interfaces and little will remain in the body of the oil for deposition on the metal surfaces.
- oil-inwater type emulsions often occur naturally. In such wells the inhibitors, herein described tending to form water-inoil type emulsions, often decrease the emulsion problems naturally present.
- the herein described products tend to eliminate emulsion problems which sometimes appear when some of the present day inhibitors are used in oil wells or refinery processing.
- the method of carrying out my process is relatively simple in principle.
- the corrosion preventive reagent is dissolved in the liquid corrosive medium in small amounts and is thus kept in contact with the metal surface to be protected.
- the corrosion inhibitor may be applied first to the metal surface, either as is, or as a solution in some carrier liquid or paste. Continuous application, as in the corrosive solution, is the preferred method however.
- the present process finds particular utility in the protection of metal equipment of oil and gas wells, especially those containing or producing an acidic constituent such as H 5, organic acids, 0 and the like.
- the reagent either undiluted or dissolved in a suitable solvent, is fed down the annulus of the well between the casing and producing tubing where it becomes commingled with the fluid in the well and is pumped or flowed from the well with these fluids, thus contacting the inner wall of the casing, the outer and inner wall of tubing, and the inner surface of all wellhead fittings, connections and flow lines handling the corrosive fluid.
- the inhibitor composition is a liquid
- it is conventionally fed into the well annulus by means of a motor driven chemical injector pump, or it may be pumped periodically (e.g., once every day or two) into the annulus by means of a so-called boll weevil device or similar arrangement.
- the inhibitor is a solid
- it may be dropped into the well as a solid lump or stick, it may be blown in as a powder with gas, or it may be washed in with a small stream of the well fluids or other liquid.
- oil and gas wells are completed in such manner that there is no opening between the annulus and the bottom of the tubing or pump. This results, for example, when the tubing is surrounded at some point by a packing held by the casing or earth formation below the casing.
- the reagent may be introduced into the tubing through a pressure equalizing vessel after stopping the flow of fluids. After being so treated, the Well should be left closed in for a period of time sufiicient to permit the reagent to drop to the bottom of the well.
- the corrosion inhibitor is usually employed as a solution in a suitable solvent, such as mineral oil, methylethyl ketone, xylene, kerosene, or even water.
- a suitable solvent such as mineral oil, methylethyl ketone, xylene, kerosene, or even water.
- solvent will depend much upon the exact reagent being used and its solubility characteristics. It is also generally desirable to employ a solvent which will yield a solution of low freezing point, so as to obviate the necessity of heating the solution and injection equipment during winter use.
- solid sticks or plugs of inhibitor are especially convenient. These may be prepared by blending the inhibitor with a mineral wax, asphalt or resin in a proportion sufficient to give a moderately hard and high-melting solid which can be handled and fed into the well conveniently.
- the amount of corrosion preventive agent required in our process varies with the corrosiveness of the system, but where a continuous or semi-continuous treating procedure is carried out as described above, the addition of reagent in the proportion of from 5 parts per million to 1000 parts per million or more parts of corrosive fluid will generally provide protection.
- corrosion inhibitors particularly in the form of a solution by means of a metering pump or the like, is common practice.
- the particular corrosion inhibitors herein described are applied in the same manner as other corrosion inhibitors intended for use for the same purpose.
- a suitable solvent such as mineral oil, methyl ethyl ketone, xylene, kerosene, high boiling aromatic solvent, or even water.
- CORROSION TESTS The test procedure includes measurement of the corrosive action of the fluids inhibited by the compositions herein described upon sand-blasted SAE-l020 steel coupons under conditions approximating those found in an actual producing well, and the comparison thereof with results obtained by subjecting identical test coupons to the corrosive action of the identical fluids containing no inhibitor.
- R corrosion rate of uninhibited fluids
- R corrosion rate of inhibited fluids
- Film life is then determined by replacing fluids in each bottle with 300 ml. brine and ml. kerosene saturated with hydrogen sulfide as before but no inhibitor.
- compositions of this invention give excellent protection in presence of inhibitor and particularly give long film life when subjected to the above test.
- Anti-static treatment for hotel rugs, hospital floors, automobile upholstery, plastic and wax polishes, wool oils, lubricants for synthetic fibers.
- Building materials water repellant treatment for plaster, concrete, cement, roofing materials, air entrainment, floor sealers, linoleum.
- Cosmetics formulation of anti-perspirants, deodorants, sun screens, hair preparations.
- De-emulsifying in antibiotic extraction, breaking crude oiland water-gas for emulsions.
- Detergents metal cleaning emulsions, lens cleaners, floor oils, dry cleaning detergents, radiator flushes, cesspool acid, boiler scale solvents, germicidal corrosion-inhibited acid detergents for dairies, enamel equipment, toilet bowls.
- Metals rust preventive oils, cutting oils, water displacing compounds, pickling inhibitor, solvent degreasing.
- Paints for improved adhesion of primers, preventing water spotting in lacquers, antiskinning, pigment flushing, grinding and dispersing, anti-feathering in inks.
- Petroleum germicide in flood Water treatment, deemulsifying fuel oil additives, anti-strip agent in asphalt emulsions and cutbacks.
- Textiles in rubberizing, textile oils, dyeing assistants, softening agents.
- Miscellaneous bentonite-amine complexes, metalamine complexes, preparation of pentachorphenates. quaternaries, plastisols, and rodent repellents.
- X is oxygen or sulfur
- CH3 (IJH3 (31-13 R is 1) hydrogen, (2) saturated aliphatic hydrocarbon of 1 to 31 carbon atoms, (3) unsaturated aliphatic hydrocarbon, without any acetylenic unsaturation, of 2 to 31 carbon atoms, (4) cycloaliphatic hydrocarbon of 6 to 31 carbon atoms, (5) phenyl heptadecyl, (6) o-hydroxyphenyl, (7) 2-hydroxy-3- methyl phenyl, (8) p-tert-butyl phenyl, (9) p-hydroxyphenyl, (10) the non-acid moiety of hydroxy naphthenic acid, (11) phenyl, (12) 2-hydroxy-3- methoxyphenyl, or (13) mixtures thereof,
- p 1-10
- R is (1), (2) alkyl of 1 to 12 carbon atoms, (3) cyclo pentyl, (4) cyclohexyl, (5) phenyl, (6) tolyl, (7) anisyl, (8) furfuryl, or (9) R being a mixture of hydrocarbon radicals from a mixture of C to C l-alkanol of average molecular 'weight of 144.
- NATALIE TROUSOF Primary Examiner U.S. CL. X.R.
Abstract
AMIDES OF CYCLIC AMIDINES AND PHOSPHORIC ACIDS INCLUDING BOTH OXYGEN, SULFUR, AND OXYGEN-SULFUR-CONTAINING PHOSPHORIC ACIDS, AS ILLUSTRATED BY AMIDES OF THE FORMULA
X=P(-(NH-A)P-A0)N(-X-R'')(3-N)
WHERE $ IS A CYCLIC AMIDINE-CONTAINING RADICAL, FOR EXAMPLE IMIDAZOLINE AND TETRAHYDROPYRIDINE, X IS OXYGEN AND/OR SULFUR; R'' IS HYDROGEN OR AN ALCOHOL MOIETY; A IS ALKYLENE, N IS 1-3 AND P IS 0-10. THESE COMPOUNDS, AMONG OTHER USES ARE EMPLOYED AS CORROSION INHIBITORS.
X=P(-(NH-A)P-A0)N(-X-R'')(3-N)
WHERE $ IS A CYCLIC AMIDINE-CONTAINING RADICAL, FOR EXAMPLE IMIDAZOLINE AND TETRAHYDROPYRIDINE, X IS OXYGEN AND/OR SULFUR; R'' IS HYDROGEN OR AN ALCOHOL MOIETY; A IS ALKYLENE, N IS 1-3 AND P IS 0-10. THESE COMPOUNDS, AMONG OTHER USES ARE EMPLOYED AS CORROSION INHIBITORS.
Description
United States Patent US. Cl. 260309.6 5 Claims ABSTRACT OF THE DISCLOSURE Amides of cyclic amidines and phosphoric acids including both oxygen, sulfur, and oxygen-sulfur-containing phosphoric acids, as illustrated by amides of the fOImula A N p nP )3 n where is a cyclic amidine-containing radical, for example imidazoline and tetrahydropyridine, X is oxygen and/or sulfur; R is hydrogen or an alcohol moiety; A is alkylene, n is 13 and p is -10. These compounds, among other uses are employed as corrosion inhibitors.
This invention relates to amides of cyclic amidines and phosphoric acids. More particularly this invention relates to amides of the formula where is a cyclic amidine containing radical, for example imidazoline, and tetrahydropyrimidine; X is oxygen and/or sulfur; R is hydrogen or an alcohol moiety; A is alkylene; n is I-3; and p is 0-10. This invention also relates to uses for these amides, including their use as corrosion inhibitors.
More specifically, in the above formula contains either imidazoline or tetrahydropyrimidine radicals, for example, the following radicals are the residual radicals derived from the carboxylic acids:
0 ll R-C where R comprises, for example, a saturated or unsaturated aliphatic radical, a cycloaliphatic radical, an aryl radical, an aralkyl radical, an alkaryl radical, an alkoxy- 3,584,008 Patented June 8, 1971 alkyl radical, an aryloxyxalkyl radical, and the like; and A is an alkylene group; for example, ethylene and propylene radicals, such as In general the cyclic amidine phosphoramidates are prepared by reacting phosphorylating reagents such as phosphoric acids and thiophosphoric acids and derivatives of these such as anhydrides, partial anhydrides and halides, with the desired molar ratio of amino containing cyclic amidines for example of the formula i )p where p is 0-10. The products are characterized by having at least one P-N bond.
More specifically, the corrosion inhibiting aspect of this invention relates to a method for inhibiting corrosion of ferrous metals by hydrocarbon fluids containing water and corrosive materials such as H 8, CO inorganic acids, organic acids, etc., combinations of these materials with each other, combinations of each of said corrosive materials with oxygen, and combinations of said materials with each other and oxygen, which comprises adding to said fluids at least five parts per million of the above cyclic amidine phosphoramidates, said compounds being sufiiciently soluble in the hydrocarbon fluid to inhibit corrosion.
THE CYCLIC AMIDINE PRECURSOR The expression cyclic amidines is employed in its usual sense to indicate ring compounds in which there are present either 5 members or 6 members, and having 2 nitrogen atoms separated by a single carbon atom supplemented by either two additional carbon atoms or three additional carbon atoms completing the ring. All the carbon atoms may be substituted. The nitrogen atom of the ring involving two monovalent linkages (the 1-position) is substituted with an amino-containing group capable of reacting with the phosphate precursor to form the amides of this invention. This amino containing side group may be represented by -(XNR'),,H wherein X is alkylene and R is hydrogen or alkyl, but preferably hydrogen, and n is a whole number, for example, 0-10 or higher, but preferably 0-3.
These cyclic amidines are further characterized as being imidazolines and tetrahydropyrimidines unsubstituted in l-position or substituted in the 1-position with alkylene-amino or polyalkylene-amino group in which the two-position carbon of the ring is generally bonded to a hydrocarbon radical or comparable radical derived from an acid, such as a low molal fatty acid, a high molal fatty acid, or comparable acids, polycarboxy acids, and the like.
For details of the preparation of imidazolines substituted in the 2-position from amines, see the following US. Pats. No. 1,999,989, dated Apr. 30, 1935, Max Bockmuhl et al.; No. 2,155,877, dated Apr. 25, 1939, .Edmund Waldmann et al.; and No. 2,155,878, dated Apr. 25, 1939, Edmund Waldmann et a1. Also see Chem. Rev. 32, 47 (1943) and Chem. Rev. 54, 593 (1954).
Equally suitable for use in preparing compounds of my invention and for the preparation of tetrahydropyrimidines substituted in the 2-position are the polyamines containing at least one primary amino group and at least one secondary amino group, or another primary amino group separated from the first primary amino group by three carbon atoms instead of being separated by only two carbons as with imidazolines. This reaction as in the case of the imidazolines is generally carried out by heating the reactants to a temperature at which two moles of Water are evolved for each carboxylic group and ring closure is eiiected. For details of the preparation of tetrahydropyrimidines, see German Pat. No. 700,731, dated Dec. 18, 1940, to Edmund Waldmann and August Chwala; German Pat. No. 701,322, dated Jan. 14, 1941, to Karl Kiescher, Ernst Erech and Willi Klarer, and US. Pat. No. 2,194,419, dated Mar. 19, 1940, to August Chwala.
Substituted imidazolines and tetrahydropyrimidines are obtained from a variety of acids beginning with the onecarbon acid (formic) through and including higher fatty acids or the equivalent having for example 32 carbon atoms. Modified fatty acids also can be employed as, for example, phenyl stearic acid or the like. Cyclic acids may be employed, including naphthenic acids. A variety of other acids including benzoic acid, substituted benzoic acid, salicyclic acid, and the like, have been employed to furnish the residue ll RC- from the acid RCOOH in which the C of the residue ll RC- is part of the ring. The fatty acids employed, for example, may be saturated or unsaturated. Branched long chain fatty acids may be employed. See J. Am. Chem. Soc. 74, 2523 (1952). This applies also to the lower molecular weight acids as well.
Among sources of such acids may be mentioned straight chain and branched chain, saturated and unsaturated, aliphatic, cycloaliphatic, aromatic, hydroaromatic, aralkyl acids, etc.
Examples of saturated aliphatic monocarboxylic acids comprise: acetic, propionic, butyric, valeric, caproic, heptanoic, caprylic, nonanoic, capric, undecanoic, lauric, tridecanoic, myriatic, pentadecanoic, palmitic, heptadecanoic, stearic, nonadecanoic, eicosanoic, heneicosanoic, docosanoic, tricosanoic, tetracosanoic, pentacosanoic, cerotic, heptacosanoic, montanic, nonacosanoic, melissic and the like.
Examples of ethylenic unsaturated aliphatic acids comprise: angelic, tiglic, the pentenoic acids, the hexenoic acids, for example, hydrosorbic acid, the heptenoic acids, the octenoic acids, the nonenoic acids, the decenoic acids, for example, obtusilic acid, the undecanoic acids, the dodecenoic acids, for example, lauroleic, linderic, etc., the tridecenoic acids, the tetradecenoic acids, for example, myristoleic acid, the pentadecenoic acids, the hexadecenoic acids, for example, palmitoleic acid, the heptadecenoic acids, the octodecenoic acids, for example, petrosilenic acid, oleic acid, elaidic acid, the nonadecenoic acids, for example, the eicosenoic acids, the docosenoic acids, for example, erucic acid, brassidic acid, cetoleic acid, the tetracosenic acids, and the like.
Examples of dienoic acids comprise the pentadienoic acids, the hexadienoic acids, for example, sorbic acid, the octadienoic acids, for example, linoleic, and the like.
Examples of the trienoic acids comprise the octadecatrienoic acids, for example, linolenic acid, eleostearic acid, pseudo-eleostearic acid, and the like.
Examples of the cyclic aliphatic carboxylic acids comprise those found in petroleum called naphthenic acids, hydrocarpic and chaulmoogric acids, bicyclopentane carboxylic acids, cyclohexanecarboxylic acid, campholic acid, fencholic acids, and the like.
Examples of aromatic monocarboxylic acids comprise benzoic acid, substituted benzoic acids, for example, the toluic acids, the xyleneoic acids, alkoxy benzoic acid,
phenyl benzoic acid, naphthalene carboxylic acid, and the like.
Mixed higher fatty acids derived from animal or vegetable sources, for example, lard, cocoanut oil rapeseed oil, sesame oil, palm kernel oil, palm oil, olive oil, corn oil, cottonseed oil, sardine oil, tallow, soyabean oil, peanut oil, castor oil, seal oils, whale oil, shark oil, and other fish oils, teaseed oil, partially or completely hydrogenated animal and vegetable oils are advantageously employed. Fatty and similar acids include those derived from various waxes, such as beeswax, spermaceti, montan wax, japan wax, coccerin and carnauba wax. Such acids include carnaubic acid, cerotic acid, lacceric acid, montanic acid, psyllastearic acid, etc. One may also employ higher molecular Weight carboxylic acids derived by oxidation and other methods, such as from paraffin wax, petroleum and similar hydrocarbons; resinic and hydroaromatic acids, such as hexahydrobenzoic acid, hydrogenated naphthoic, hydrogenated carboxy diphenyl, naphthenic, and abietic acid; aralkyl and aromatic acids, such as Twitchell fatty acids, naphthoic acid, carboxydiphenyl pyridine carboxylic acid, blown oils, blown oil fatty acids and the like.
Other suitable acids include phenylstearic acid, benzoylnonylic acid, cetyloxybutyric acid, cetyloxyacetic acid, chlorstearic acid, etc.
Examples of the polycarboxylic acids comprise those of the aliphatic series, for example, oxalic, malonic, glutaric, adipic, pimelic, suberic, azelaic, sebacic, nonanedicarboxylic acid, decanedicarboxylic acids, undecanedicarboxylic acids, and the like.
Examples of unsaturated aliphatic polycarboxylic acids comprise mesocenic, citraconic, glutonic, itaconic, muconic, acenitic acids, and the like.
Examples of the aromatic polycarboxylic acids comprise isophthalic acids, terephthalic acids, substituted derivatives thereof (e.g. alkyl, chloro, alkoxy, etc. deriva tives), biphenyldicarboxylic acid, diphenylether dicarboxylic acids, diphenylsulfone dicarboxylic acids and the like.
Higher aromatic polycarboxylic acids containing more than two carboxylic groups comprise hemimellitic, trimellitic, trimesic, mellophanic, prehnitic, pyromellitic acids, mellitic acid, and the like.
Other polycarboxylic acids comprise the dimeric, trimeric and poly acids, for example, diricinoleic acid, triricinoleic acid, polyricinoleic acid, and the like. Other polycarboxylic acids comprise those containing ether groups, for example, diglycollic acid. Mixtures of the above acids can be advantageously employed.
In addition, acid precursors such as esters, acid chlorides, glycerides, etc. can be employed in place of the free acid.
Thus, cyclic amidines within the scope of this invention include compounds of the formulae:
(GB-.911 i D 1-10, but preferably 1-3, and (CB is, for example, tuted amidines in Table 1, appear in Table 2 immediately a divalent radical of the formula: following.
TABLE 2 CH3 -CHCH-, -CH2(|'JH-CH2 CH3 CH: CH: N N-R' \C/ etc. 1'1
The following tables present examples of amino cyclic amidines which can be employed in the present invention.
Ex. RCOOH source of RC R No particular advantage has been found in using other polyamines in which some other divalent radical, such as b Formic omcmcrrmm appears. For this reason examples in Table I are limited B8- to derivatives of the three most readily available poly- 2 amines above indicated.
Hydroxybutyrle Methyloctadecanoic Suitable products derived from the three amines pre- TABLE 1 viously noted are described in Table 3, following: N N-R' 1 R TABLE 3 EX. RCOOHsourceof RC R l I b! I 1a Formic CHzGHzNHz R N N-R' 2a Propionic, Same as above. W 3a- Isovaleric. Do. C 4a-.-. Stearic Do. 5a Melissic Do.
Do. Do. Ex. HOOC-R-COOH go. No. source of CRC R 0. Do. Dilinoleie CH CH NH; CHzCHzNHCHzCIhNHz Adipie... Same as above; Same as above. Suberic- Do. 0. Sebacic Do. Do. 5c Nonodecane diear- Do. 15a..- Cerotic. Do. boxylic. 16a p-tert-Butyl benzoic... Do. 60. Diglycolic Do 17a. p-Hydroxybenzoie Do. 7c- Ethylene bis(glyco Do. 18a Salicylic Do. 80. Methylene disalicylie... Do. 19a. Hydroxy naphthenic Do. 9c- Stearyl malonic Do. 20a Benzoic Do. 00... Phthallc Do. 21a..- Formic CH2OH2NHCH2CH2NI'ICH2CIT2NII2 11c- Succtnic- OHzCHzNHCHzCHgNHg 22a Methyloetadecanoie-.. Same as above. 120... Glutaric Same as above. 23a Capric Do. 130. Pimelic- Do. 24a Stearim... Do. 140... Azelaic Do. 25a. Phenylstearic. Do. 150. Eicosane dlcarboxylic- Do. 26a Oresotinic Do. 160... Dilinoleic Do. 27a. Linoleic. Do. 170. Isophthalic- Do. 28a Salicylic Do. 80-.- Diglycolic D0. 29a 2-hydroxy-3-methoxy- Do. 19c Lauryl malonic Do. benzoie. 20c- Methylene disalicylic Do. 30a.-. Naphthenic Do. 210. Dilinoleic OH CH NHCH Q 22c- Suceinio- Same as above. 230... Suberie Do. 24e Pimel' Do. 250. Nonodecane dicar- Do. boxylie.
26c.-. Diglycolie Do.- 270. Methylene disalicylic Do. 280... Stearyl malonle Do. 290. Stearyl succinic Do. 300... Terephthallc Do.
The only polyamine available on a large scale for the manufacture of tetrahydropyrimidines is 3,3-iminobispropylamine. This product can be converted into the tetraamine or pentamine by appropriate reaction with a suitable imine or by reaction with acrylonitrile, followed by the usual steps of converting the intermediate into the In the use of dicarboxy acids, the bulk of the examples amine. Tetrahydropyrimidines comparable to the substiwere obtained from 3,3-iminobispropylamine. These com- TABLE 4 HOOCR-COOH Ex. No. source of CRC R 1d Maleic CHzCHzCHzNHz Suecinie. Same as above.
4d- Adipie Do. 5d Subene D0. 66 Sebacrc Do. 7d Pimelic Do. 8d Azelaic Do. 9d- N ouodecane diearbox Do. 10d Eicosane dicarboxylic Do. 11d Diglyeolie Do. 12d. Ethylene bisglycolic Do. 13d Methylene disalieylie Do. 14d Dilinoleic Do. 15d Stearyl malomo. D0. 16d Lauryl suecinie Do. 17d Isotetradeeyl suc Do. 18d Phthalic Do. 19d Isophthalic- Do. 20d Terephthalic. Do. 21d Glutaeonic Do.
THE PHOSPHORIC ACID MOIETY The desired products are obtained by reacting an amino-containing cyclic amidine with a phosphorylating reagent which is a derivative of phosphoric acid. The rereactions. The exact reagent of choice will depend on X=S and/ or O is a cyclic amidine R is H, alkyl (e.g. methyl, ethyl, propyl, hexyl, 2-ethyl hexyl, lauryl, etc.), cycloalkyl (e.g. cyclopentyl, cyclohexyl), aryl (phenyl, tolyl, anisyl) or heterocyclic (furfuryl, etc.).
The simplest phosphorylating reagent which can be used is ortho-phosphoric acid, but this requires vigorous conditions to bring about reaction leading to side reaction. The products from this reagent are mixtures containing some monophosphoramidates,
O 2)2-a ]p-' (0 )a Reagents which are generally preferred as phosphorylating reagents are anhydrides, partial anhydrides and halides (including phosphoryl and thiophosphoryl trihalides, dialkyl or arylphosphorohalidates,
(R o) zi 01 and alkyl or aryl phosphorodihalidates,
(ROhl 012) of phosphoric acid. These reagents require much milder conditions than ortho phosphoric acid itself since they are highly reactive and furthermore give much better yields of the required products by elimination of side reactions. The exact reagent of choice will depende on the individual amino-containing amidine to be reacted and on the structure of the desired product. For example phosphorus pentoxide is a powerful phosphorylating re agent which on reaction with an amino-containing amidine yields a mixture of phosphoramides It is often preferred to react the phosphorus pentoxide partially with the amino-containing amidine and then with a hydroxy compound such as a simple alcohol (e.g. ethanol, propanol). In this case a mixture containing phosphoramidate ester is obtained containing the following structures:
Phosphorus pentasulfide is similarly a powerful phosphorylating reagent which with amino-containing amidines gives similar products to those obtained from phosphorus pentoxide in which some or all of the oxygens attached to posphorus are replaced by sulfur.
Polyphosphoric acid is a reagent which is intermediate in phosphorylating power between ortho phosphoric acid and phosphorus pentoxide (it is in fact a partial anhydride). This reagent can be reacted alone with aminocontaining cyclic-amidines or in combination with hydroxy compounds to give products similar to those described for the phosphorus pentoxide.
Another important group of phosphorylating reagents which are used to prepare the products of this invention are halides of phosphoric acid. Among these are phosphoryl halide, POX (where X=Br, Cl), phosphorochloridates,
ll (ROMP-Cl (where R is alkyl, cycloalkyl, aryl, heterocyclic), phosphorodichloridates t ROPClz (where R is as defined above). For example, a phosphorodichloridate can be reacted with an amino-containing cyclic amidine to give a phosphoramidate as follows:
'(GH2)23NH2 h C1 0 (CH2)z-:NHl (OR)z HCI A phosphorodichloridate would give a similar reaction:
The hydrogen chloride produced in these reactions is normally taken up by the amidine ring as the reaction proceeds. However, in some cases it may be desirable to add a base to remove the acid as it is formed. For example, a tertiary amine such as pyridine may be used or an alkali metal oxide or carbonate such as calcium oxide or carbonate.
Other methods of phosphorylation are known and can be found described in Structure and Mechanism in Organo-Phosphorus Chemistry, pp. 250-288 by R. F. Hudson, Academic Press, 1965, and also in Newer Methods of Preparative Organic Chemistry, vol. III, Ed. W. Foerst, pp. 319-356, Academic Press, 1964.
The following examples are presented for purposes of illustration and not of limitation.
EXAMPLE '1 and was collected. Heating was continued at 170185 for a further 2 /2 hours at which time the reaction was complete. The product was mainly a 1-18 amino ethyl 2- imidazoline represented in the following formula R is Crofatol P residue.
EXAMPLE 2 To a stirred suspension of phosphorus pentoxide (52 g.; 0.4 mole) in toluene (130 ml.) was added the aminoethyl imidazoline of Example 1 (75 g.; 0.2 mole) dissolved in toluene (45 ml.) dropwise during 40 minutes. The mixture was then heated at 100-110 for 1% hours during which time most of the solid phosphorus pentoxide disappeared. After cooling to 40 2-ethyl hexanol (130 g.; 1 mole) was added over a period of 1% hours. During the addition the temperature rose to 60. The reaction was completed by heating at 110-120" for three hours. The product is a mixture of phosphoramides, the main constituents of which can be represented by the formulae:
EXAMPLE 3 This example follows the procedure of Example 2 except that Z-ethyl hexanol is replaced by Alfol 810 (144 g.; 1 mole). Alfol 810 is a commercial mixture of C to C l-alkanol of average molecular weight 144. The product is likewise a mixture of phosphoramides.
EXAMPLE 4 To a stirred suspension of phosphorus pentasulfide (72.5 g.; 0.33 mole) in toluene (130 ml.) was added the aminoethyl imidazoline of Example 1 (61 g.; 0.16 mole) dissolved in toluene (45 ml.) during 1% hours. The mixture was heated at 100110 for 1 /2 hours and then allowed to cool to 50. Ethanol (37.5 g.; 0.82 mole) was added dropwise during 1% hours at 50-60 and then heated at 105-110" for two hours to complete the reaction. The product is mainly a mixture of sulfur containing phosphoramides which can be represented by the formulae:
EXAMPLE 5 This example is similar to Example 4 except that ethanol is replaced by an equimolar amount of 2-ethyl hexanol. The product is similarly mainly a mixture of sulfur containing phosphoramides of the following formulae:
EXAMPLE 6 To a stirred suspension of phosphorus pentoxide (52 g.; 0.4 mole) in toluene (130 ml.) was added the aminoethyl imidazoline of Example 1 g.; 0.2 mole) during 30 minutes. The mixture was then heated at 110 for 1% hours. After cooling to 40 Alfol 810 oxyethylated with two weights of ethylene oxide (430 g.; 1 mole) was added dropwise at 40-55 in one hour. The reaction was completed by heating at -120 for three hours. The product comprises mainly of a mixture of phosphoramides of the following formulae:
( owmomomrv R R'=A1fol 810 (C -C EXAMPLE 7 To a stirred suspension of phosphorus pentoxide (26 g.; 0.2 mole) in toluene (130 ml.) was added the amino-ethyl imidazoline of Example 1 (37.5 g.; 0.1 mole) dissolved in toluene (45 ml.) during 15 minutes. The mixture was heated under reflux (110) for one hour and allowed to cool to 35. To this was added 1-(2-hydroxy-ethyl) 2- imidazoline (from Crofatol P and hydroxyethyl ethylene diamine) (189 g.; 0.5 mole) dissolved in toluene (50 ml.) during 20 minutes. The reaction was completed by heating at -120 for two hours. The product consists mainly (if a mixture of phosphoramides of the following formu ae:
EXAMPLE 8 Crofatol P (590 g.; 2 mole) was mixed with Tretamine #2 (460 g.; 2 equivalents) and heated to 170 for one hour in a reaction flask fitted with still head and condenser for distillation. (Tretamine #2 is a commercial polyamine mixture containing diethylene triamine, triethylene tetramine, tetraethylene pentamine and pentaethylene hexamine as major components.)
This time a vacuum of 50 mm. was applied and heating continued at 170-180" for five hours during which time water was distilled from reaction vessel. At this time the reaction was virtually complete as determined by infrared measurement and the product is mainly a mixture of imidazolines of the following formula containing some amide.
GET-CH2 N N-(CHzOHzNII) 1-611 EXAMPLE 9 To a stirred suspension of phosphorus pentoxide (52 g.; 0.4 mole) in toluene (130 ml.) was added the aminoalkyl imidazoline of Example 8 (195.6 g.; 0.2 mole) in toluene (45 ml.) during 25 minutes. The mixture was heated under reflux for one hour and cooled to 30 before adding ethanol (46 g.; 1 mole) dropwise in 20 minutes. The mixture was then heated at 105-110 for 2% hours to complete the reaction. The product is mainly a mixture of phosphoramides which can be represented by the formulae:
l l t This preparation follows the method of Example 9 except that the ethanol is replaced by an equivalent amount of 2-ethyl hexanol. The product therefore, consists mainly of the phosphoramides shown in the formulae of Example 9 except that the ethyl group is now 2-ethyl hexyl for this example.
EXAMPLE 11 To the imidazoline of Example 8 (97.8 g.; 0.1 mole) dis solved in kerosene 140 ml.) was added diethyl phosphorochloridate (17.4 g.; 0.1 mole) dropwise in 15 minutes. The mixture was then heated at 75-85 for 2 /2 hours to bring the reaction to completion. The product of this reaction is mainly a phosphoramide of the following formula:
EXAMPLE 12 To the imidazoline of Example 8 (97.8 g.; 0.1 mole) dissolved in kerosene (140 ml.) was added bis(2-ethylhexyl) phosphorochloridate (34.1 g.; 0.1 mole) in 20 12 minutes. After heating for two hours at the reaction was complete. The product is mainly the phosphoramide of the following formula:
I i N N-(CHzCHzNHh-BP(OCaHu);
EXAMPLE 13 R is Crofatol P residue.
Reactions with the product of Example 13 are summarized as follows:
Imidaz- Method N0. oline Reactants followed 14.. Ex. 13..... Phosphorus pentoxide 2 ethyl hexanol.. Ex. 2. 15.... Ex. 13..... Phosphorus pentoxide Alfol 810 Ex. 16.... Ex. 13..... Diethyl phosphorochloridate Ex. 11.
W (02115) 2 P C1 17- Ex. 13.... Phosphorus pentasulfide Alfol 810 Ex. 4.
The above products are analogous to those formed with cyclic amidines having amino side chains except that the amide group is tied directly to a ring nitrogen that is:
where X=oxygen or sulfur.
USE AS CORROSION INHIBITOR More specifically, this phase of the invention relates to the inhibition of corrosion in the petroleum industry with specific reference to producing wells, pipe lines, refineries, tank storage, etc.
The use of a corrosion inhibiting agent in the oil industry and other industries, and particularly for the protection of ferrous metals, is well known. For example, see US. Pats. Nos. 2,736,658, dated Feb. 28, 1954, to Pfohl et al., and 2,756,211, dated July 24, 1956, to Jones, and 2,727,003, dated Dec. 13, 1955, to Hughes.
More specifically then, and particularly from the standpoint of oil production, this aspect of the invention relates to inhibiting corrosion caused by hydrogen sulfide, carbon dioxide, inorganic acids, organic acids, combinations of each with oxygen, and with each other and oxygen. More particularly, it relates to treating wells to mitigate metal corrosion and associated difficulties.
It should also be pointed out that the corrosiveness of oil well brines will vary from well to well, and the proportion of corrosion inhibiting agent added to the well fluids should also be varied from well to well. Thus, in some wells it may be possible to effectively control corrosion by the addition of as little as 5 ppm. of my new compositions to the well fluids, whereas in other wells, it may be necessary to add 200 ppm. or more.
In using my improved compositions for protecting oil well tubing, casing and other equipment which comes in contact with the corrosive oil-brine production, I find that excellent results may be obtained by injecting an appropriate quantity of a selected composition into a producing well so that it may mingle with the oil-brine mixture and come into contact with the casing, tubing, pumps and other producing equipment. I may, for example, introduce the inhibiting composition into the top of the casing, thus causing it to flow down into the well and thence back through the tubing, etc. In general, I have found that this procedure sufiices to inhibit corrosion throughout the entire system of production, and collection, even including field tankage.
In case serious emulsion or gel problems are encountered, demulsifiers may be added. This is important not only to avoid the troublesome emulsions and gels themselves, but also to improve corrosion inhibition. The explanation of less effective corrosion inhibition in the presence of emulsions apparently is that the inhibitor is somewhat surface-active. That is, it is concentrated at interfacial surfaces. Since this surface is great in an emulsion, most of the inhibitor will be concentrated in these interfaces and little will remain in the body of the oil for deposition on the metal surfaces. In many wells, oil-inwater type emulsions often occur naturally. In such wells the inhibitors, herein described tending to form water-inoil type emulsions, often decrease the emulsion problems naturally present. Thus, in addition to being effective corrosion inhibitors, the herein described products tend to eliminate emulsion problems which sometimes appear when some of the present day inhibitors are used in oil wells or refinery processing.
The method of carrying out my process is relatively simple in principle. The corrosion preventive reagent is dissolved in the liquid corrosive medium in small amounts and is thus kept in contact with the metal surface to be protected. Alternatively, the corrosion inhibitor may be applied first to the metal surface, either as is, or as a solution in some carrier liquid or paste. Continuous application, as in the corrosive solution, is the preferred method however.
The present process finds particular utility in the protection of metal equipment of oil and gas wells, especially those containing or producing an acidic constituent such as H 5, organic acids, 0 and the like. For the protection of such wells, the reagent, either undiluted or dissolved in a suitable solvent, is fed down the annulus of the well between the casing and producing tubing where it becomes commingled with the fluid in the well and is pumped or flowed from the well with these fluids, thus contacting the inner wall of the casing, the outer and inner wall of tubing, and the inner surface of all wellhead fittings, connections and flow lines handling the corrosive fluid.
Where the inhibitor composition is a liquid, it is conventionally fed into the well annulus by means of a motor driven chemical injector pump, or it may be pumped periodically (e.g., once every day or two) into the annulus by means of a so-called boll weevil device or similar arrangement. Where the inhibitor is a solid, it may be dropped into the well as a solid lump or stick, it may be blown in as a powder with gas, or it may be washed in with a small stream of the well fluids or other liquid. Where there is gas pressure on the casing, it is necessary, of course, to employ any of these treating methods through a pressure equalizing chamber equipped to allow introduction of reagent into the chamber equalization of pressure between chamber and casing, and travel of reagent from chamber to well casing.
Occasionally, oil and gas wells are completed in such manner that there is no opening between the annulus and the bottom of the tubing or pump. This results, for example, when the tubing is surrounded at some point by a packing held by the casing or earth formation below the casing. In such wells the reagent may be introduced into the tubing through a pressure equalizing vessel after stopping the flow of fluids. After being so treated, the Well should be left closed in for a period of time sufiicient to permit the reagent to drop to the bottom of the well.
For injection into the well annulus, the corrosion inhibitor is usually employed as a solution in a suitable solvent, such as mineral oil, methylethyl ketone, xylene, kerosene, or even water. The selection of solvent will depend much upon the exact reagent being used and its solubility characteristics. It is also generally desirable to employ a solvent which will yield a solution of low freezing point, so as to obviate the necessity of heating the solution and injection equipment during winter use.
For treating wells with packed-off tubing, the use of solid sticks or plugs of inhibitor is especially convenient. These may be prepared by blending the inhibitor with a mineral wax, asphalt or resin in a proportion sufficient to give a moderately hard and high-melting solid which can be handled and fed into the well conveniently.
The amount of corrosion preventive agent required in our process varies with the corrosiveness of the system, but where a continuous or semi-continuous treating procedure is carried out as described above, the addition of reagent in the proportion of from 5 parts per million to 1000 parts per million or more parts of corrosive fluid will generally provide protection.
As pointed out previously, the addition of corrosion inhibitors, particularly in the form of a solution by means of a metering pump or the like, is common practice. The particular corrosion inhibitors herein described are applied in the same manner as other corrosion inhibitors intended for use for the same purpose. For sake of brevity, one may use the corrosion inhibitor in solution form by dissolving it in a suitable solvent such as mineral oil, methyl ethyl ketone, xylene, kerosene, high boiling aromatic solvent, or even water.
The following examples are presented to illustrate the superiority of the instant compounds as corrosion inhibitors.
CORROSION TESTS The test procedure includes measurement of the corrosive action of the fluids inhibited by the compositions herein described upon sand-blasted SAE-l020 steel coupons under conditions approximating those found in an actual producing well, and the comparison thereof with results obtained by subjecting identical test coupons to the corrosive action of the identical fluids containing no inhibitor.
In the present tests clean pint bottles are charged with 300 ml. of a synthetic brine, which contains 42 g. of sodium chloride, 14 g. calcium chloride, 1 g. of sodium sulfate and 17 g. of magnesium chloride per liter, and 140 ml. of kerosene both saturated with hydrogen-sulfide and a predetermined amount of inhibitor is then added. In all cases the inhibitor concentration is based on the total volume of fluid. Bottle caps holding three coupons are then placed tightly on the bottles. The bottles are then placed on a wheel contained in an oven and rotated for 4 hours at -95 F. Corrosion rates are then measured using the three coupons in each bottle as electrodes in conjunction with instrument for measurement of instantaneous corrosion rates. Percent protection is calculated from RI X].00%
where R is corrosion rate of uninhibited fluids R is corrosion rate of inhibited fluids Film life is then determined by replacing fluids in each bottle with 300 ml. brine and ml. kerosene saturated with hydrogen sulfide as before but no inhibitor.
Heating and rotation is continued in the oven at 9095 F. and corrosion rates measured at various times. The inhibitor film on the coupons gradually is lost in this stage of the test and is followed by an increase in corrosion rate. Once the protection falls below 85% the film is considered unsatisfactory and this marks the end of filmlife. It can be appreciated that the longer the film life the more useful the inhibitor. The compositions of this invention give excellent protection in presence of inhibitor and particularly give long film life when subjected to the above test.
The data contained in the following table clearly demonstrate the superior quality of the phosphoramidates of the cyclic amidines compared with the related unphosphorylated cyclic amidines.
TABLE Composition Concen- Percent Film of Example tration, proteclife, Number p.p.m. tion hrs. Comments 100 99 1-4 Unphosphorylated amidine. 50 100 5 Phosphorylated derivative. 75 100 17 Do. 150 100 65 D0. 100 100 17 D0. 50 100 4 D0. 100 99 4 Unphosphorylated amidino. 100 100 17 Phosphorylated derivative. 100 100 17 D0.
OTHER USES These products are effective not only as corrosion inhibitors but can be used for a number of other purposes. For instance, they can be used as asphalt additives to increase the adhesiveness of the asphalt to the mineral aggregates. In the form of water soluble salts, they are useful as bactericides in the secondary recovery of oil.
In addition, the compounds of this invention have the following uses:
Agriculture: kerosene, phenothiazine, pyrethrum sprays, fungicides, herbicidal oils.
Anti-static treatment: for hotel rugs, hospital floors, automobile upholstery, plastic and wax polishes, wool oils, lubricants for synthetic fibers.
Building materials: water repellant treatment for plaster, concrete, cement, roofing materials, air entrainment, floor sealers, linoleum.
Cosmetics: formulation of anti-perspirants, deodorants, sun screens, hair preparations.
De-emulsifying: in antibiotic extraction, breaking crude oiland water-gas for emulsions.
Detergents: metal cleaning emulsions, lens cleaners, floor oils, dry cleaning detergents, radiator flushes, cesspool acid, boiler scale solvents, germicidal corrosion-inhibited acid detergents for dairies, enamel equipment, toilet bowls.
Leather: fat liquoring oils, pickling, acid degreasing, dye fixative.
Metals: rust preventive oils, cutting oils, water displacing compounds, pickling inhibitor, solvent degreasing.
Paints: for improved adhesion of primers, preventing water spotting in lacquers, antiskinning, pigment flushing, grinding and dispersing, anti-feathering in inks.
Petroleum: germicide in flood Water treatment, deemulsifying fuel oil additives, anti-strip agent in asphalt emulsions and cutbacks.
Textiles: in rubberizing, textile oils, dyeing assistants, softening agents.
Miscellaneous: bentonite-amine complexes, metalamine complexes, preparation of pentachorphenates. quaternaries, plastisols, and rodent repellents.
Having thus described my invention what I claim as new and desire to obtain by Letters Patent is:
1. Cyclic amidine-containing amides of the formula wherein:
X is oxygen or sulfur,
CH3 (IJH3 (31-13 R is 1) hydrogen, (2) saturated aliphatic hydrocarbon of 1 to 31 carbon atoms, (3) unsaturated aliphatic hydrocarbon, without any acetylenic unsaturation, of 2 to 31 carbon atoms, (4) cycloaliphatic hydrocarbon of 6 to 31 carbon atoms, (5) phenyl heptadecyl, (6) o-hydroxyphenyl, (7) 2-hydroxy-3- methyl phenyl, (8) p-tert-butyl phenyl, (9) p-hydroxyphenyl, (10) the non-acid moiety of hydroxy naphthenic acid, (11) phenyl, (12) 2-hydroxy-3- methoxyphenyl, or (13) mixtures thereof,
p is 1-10, and
R is (1), (2) alkyl of 1 to 12 carbon atoms, (3) cyclo pentyl, (4) cyclohexyl, (5) phenyl, (6) tolyl, (7) anisyl, (8) furfuryl, or (9) R being a mixture of hydrocarbon radicals from a mixture of C to C l-alkanol of average molecular 'weight of 144.
HHHH
CITY-CH2 H 0 OR o I R References Cited UNITED STATES PATENTS 3,150,149 9/1964 Uhlenbroek et a1. 260309 3,116,249 12/1963 Ratner et al 260309.6
FOREIGN PATENTS 1,211,099 10/ 1959 France 260-3097 1,273,603 9/1961 France 260-309 1,418,688 10/1965 France 260309.6
OTHER REFERENCES Ratner et al., II Chem. Abst., vol. 60, column 11829 (1964).
NATALIE TROUSOF, Primary Examiner U.S. CL. X.R.
89 l.1P; 7l92; 1062, 14, 279, 281N; 117-1355, 139,139.5CQ;2528.55E, 8.8, 8.57
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4216334A (en) * | 1979-02-01 | 1980-08-05 | Mobil Oil Corporation | Imidazoline salts of acid phosphonates |
US4388213A (en) * | 1982-02-26 | 1983-06-14 | Basf Aktiengesellschaft | Cyclic amidine based corrosion inhibitors which inhibit corrosion caused by CO2 and H2 S |
EP0568254A2 (en) * | 1992-04-29 | 1993-11-03 | Huntsman Corporation | Method for preparing 1,2-substituted imidazoline compositions |
US6077460A (en) * | 1996-07-17 | 2000-06-20 | Basf Aktiengesellschaft | Corrosion inhibition |
-
1967
- 1967-09-05 US US665288A patent/US3584008A/en not_active Expired - Lifetime
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4216334A (en) * | 1979-02-01 | 1980-08-05 | Mobil Oil Corporation | Imidazoline salts of acid phosphonates |
US4388213A (en) * | 1982-02-26 | 1983-06-14 | Basf Aktiengesellschaft | Cyclic amidine based corrosion inhibitors which inhibit corrosion caused by CO2 and H2 S |
EP0568254A2 (en) * | 1992-04-29 | 1993-11-03 | Huntsman Corporation | Method for preparing 1,2-substituted imidazoline compositions |
EP0568254A3 (en) * | 1992-04-29 | 1994-06-08 | Texaco Chemical | Method for preparing 1,2-substituted imidazoline compositions |
US6077460A (en) * | 1996-07-17 | 2000-06-20 | Basf Aktiengesellschaft | Corrosion inhibition |
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