US3566790A - Packaged aqueous slurry type explosives - Google Patents
Packaged aqueous slurry type explosives Download PDFInfo
- Publication number
- US3566790A US3566790A US784211A US3566790DA US3566790A US 3566790 A US3566790 A US 3566790A US 784211 A US784211 A US 784211A US 3566790D A US3566790D A US 3566790DA US 3566790 A US3566790 A US 3566790A
- Authority
- US
- United States
- Prior art keywords
- mass
- container
- explosive
- release agent
- wall
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002360 explosive Substances 0.000 title claims abstract description 79
- 239000002002 slurry Substances 0.000 title claims abstract description 71
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 65
- 150000003839 salts Chemical class 0.000 claims abstract description 39
- 239000007800 oxidant agent Substances 0.000 claims abstract description 25
- 239000002562 thickening agent Substances 0.000 claims description 35
- 229920000642 polymer Polymers 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 19
- 239000004615 ingredient Substances 0.000 claims description 18
- 239000005662 Paraffin oil Substances 0.000 claims description 14
- -1 alkali metal acrylates Chemical class 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 230000008719 thickening Effects 0.000 claims description 13
- 229920002401 polyacrylamide Polymers 0.000 claims description 11
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 10
- 239000004698 Polyethylene Substances 0.000 claims description 9
- 239000003431 cross linking reagent Substances 0.000 claims description 9
- 229920003023 plastic Polymers 0.000 claims description 9
- 239000004033 plastic Substances 0.000 claims description 9
- 229920000573 polyethylene Polymers 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 8
- 230000009471 action Effects 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 239000000295 fuel oil Substances 0.000 claims description 7
- 239000000314 lubricant Substances 0.000 claims description 7
- 238000004806 packaging method and process Methods 0.000 claims description 7
- BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 claims description 7
- 229910001488 sodium perchlorate Inorganic materials 0.000 claims description 7
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- DNZWLJIKNWYXJP-UHFFFAOYSA-N butan-1-ol;propan-2-one Chemical group CC(C)=O.CCCCO DNZWLJIKNWYXJP-UHFFFAOYSA-N 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 238000004132 cross linking Methods 0.000 claims description 4
- 230000006872 improvement Effects 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003125 aqueous solvent Substances 0.000 claims description 3
- 239000012153 distilled water Substances 0.000 claims description 3
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 claims description 3
- OVARTBFNCCXQKS-UHFFFAOYSA-N propan-2-one;hydrate Chemical compound O.CC(C)=O OVARTBFNCCXQKS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 229920002545 silicone oil Polymers 0.000 claims description 3
- 230000007062 hydrolysis Effects 0.000 claims description 2
- 238000006460 hydrolysis reaction Methods 0.000 claims description 2
- 239000000446 fuel Substances 0.000 abstract description 10
- 238000005474 detonation Methods 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- 229940048053 acrylate Drugs 0.000 description 6
- 238000005422 blasting Methods 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 6
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 239000003999 initiator Substances 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- TZRXHJWUDPFEEY-UHFFFAOYSA-N Pentaerythritol Tetranitrate Chemical compound [O-][N+](=O)OCC(CO[N+]([O-])=O)(CO[N+]([O-])=O)CO[N+]([O-])=O TZRXHJWUDPFEEY-UHFFFAOYSA-N 0.000 description 4
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 4
- 150000001642 boronic acid derivatives Chemical class 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000005012 migration Effects 0.000 description 3
- 238000013508 migration Methods 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 235000010344 sodium nitrate Nutrition 0.000 description 3
- 239000004317 sodium nitrate Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical class N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 229920000926 Galactomannan Polymers 0.000 description 2
- 229920002907 Guar gum Polymers 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- AGUIVNYEYSCPNI-UHFFFAOYSA-N N-methyl-N-picrylnitramine Chemical group [O-][N+](=O)N(C)C1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O AGUIVNYEYSCPNI-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 235000019257 ammonium acetate Nutrition 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- 239000007853 buffer solution Substances 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 239000000665 guar gum Substances 0.000 description 2
- 229960002154 guar gum Drugs 0.000 description 2
- 235000010417 guar gum Nutrition 0.000 description 2
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000012673 precipitation polymerization Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2,2'-azo-bis-isobutyronitrile Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- WHQOKFZWSDOTQP-UHFFFAOYSA-N 2,3-dihydroxypropyl 4-aminobenzoate Chemical compound NC1=CC=C(C(=O)OCC(O)CO)C=C1 WHQOKFZWSDOTQP-UHFFFAOYSA-N 0.000 description 1
- OQUFOZNPBIIJTN-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarboxylic acid;sodium Chemical compound [Na].OC(=O)CC(O)(C(O)=O)CC(O)=O OQUFOZNPBIIJTN-UHFFFAOYSA-N 0.000 description 1
- HZTVIZREFBBQMG-UHFFFAOYSA-N 2-methyl-1,3,5-trinitrobenzene;[3-nitrooxy-2,2-bis(nitrooxymethyl)propyl] nitrate Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O.[O-][N+](=O)OCC(CO[N+]([O-])=O)(CO[N+]([O-])=O)CO[N+]([O-])=O HZTVIZREFBBQMG-UHFFFAOYSA-N 0.000 description 1
- GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical compound FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 description 1
- 239000005695 Ammonium acetate Substances 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 102100024133 Coiled-coil domain-containing protein 50 Human genes 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 101000910772 Homo sapiens Coiled-coil domain-containing protein 50 Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- MPCRDALPQLDDFX-UHFFFAOYSA-L Magnesium perchlorate Chemical compound [Mg+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O MPCRDALPQLDDFX-UHFFFAOYSA-L 0.000 description 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
- 239000000026 Pentaerythritol tetranitrate Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- HDYRYUINDGQKMC-UHFFFAOYSA-M acetyloxyaluminum;dihydrate Chemical compound O.O.CC(=O)O[Al] HDYRYUINDGQKMC-UHFFFAOYSA-M 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910001963 alkali metal nitrate Inorganic materials 0.000 description 1
- 229910001964 alkaline earth metal nitrate Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 229940009827 aluminum acetate Drugs 0.000 description 1
- 229940043376 ammonium acetate Drugs 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- WUPZNKGVDMHMBS-UHFFFAOYSA-N azane;dihydrate Chemical compound [NH4+].[NH4+].[OH-].[OH-] WUPZNKGVDMHMBS-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-M bisulphate group Chemical group S([O-])(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- WYYQVWLEPYFFLP-UHFFFAOYSA-K chromium(3+);triacetate Chemical compound [Cr+3].CC([O-])=O.CC([O-])=O.CC([O-])=O WYYQVWLEPYFFLP-UHFFFAOYSA-K 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- RHCJOJDSMWJGMV-UHFFFAOYSA-N diazanium acetate hydroxide Chemical compound [NH4+].[NH4+].[OH-].CC([O-])=O RHCJOJDSMWJGMV-UHFFFAOYSA-N 0.000 description 1
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 description 1
- HDFXRQJQZBPDLF-UHFFFAOYSA-L disodium hydrogen carbonate Chemical compound [Na+].[Na+].OC([O-])=O.OC([O-])=O HDFXRQJQZBPDLF-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229960002413 ferric citrate Drugs 0.000 description 1
- IMBKASBLAKCLEM-UHFFFAOYSA-L ferrous ammonium sulfate (anhydrous) Chemical compound [NH4+].[NH4+].[Fe+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O IMBKASBLAKCLEM-UHFFFAOYSA-L 0.000 description 1
- 229960002089 ferrous chloride Drugs 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 1
- 239000004312 hexamethylene tetramine Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- NPFOYSMITVOQOS-UHFFFAOYSA-K iron(III) citrate Chemical compound [Fe+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NPFOYSMITVOQOS-UHFFFAOYSA-K 0.000 description 1
- 229960004011 methenamine Drugs 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 229960004321 pentaerithrityl tetranitrate Drugs 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 229910001487 potassium perchlorate Inorganic materials 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940047670 sodium acrylate Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 229960004793 sucrose Drugs 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
- C06B47/14—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase comprising a solid component and an aqueous phase
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B3/00—Blasting cartridges, i.e. case and explosive
Definitions
- a packaged, and thickened, but generally pourable, inorganic oxidizer salt explosive of the aqueous slurry type is provided which contains a release agent to preclude adhesion of the mass of explosive to the inner wall of the container during gravitation of the mass therefrom.
- the agent is disposed so as to be in direct contact with said mass and the container inner wall across the mass-inner wall interface during the gravitation.
- the agent serves as a fuel for the subsequent detonation.
- This invention relates to a packaged inorganic oxidizer salt explosive of the aqueous slurry type containing an agent at the interface of the explosive mass and container inner wall to facilitate release of the explosive from the package by gravitation.
- this invention relates to packaged slurry explosives, above described, in which'the explosive is pourable and is flowable from the container without substantially any adhesion of residual slurry to the container inner wall.
- Inorganic oxidizer salt blasting compositions of the aqueous slurry type have had extensive use in the explosives industry in recent years. These compositions comprise inorganic or oxidizer salt, water, a sensitizer, and generally a thickener in a least an amount to impart sufficient consistency to the slurry to prevent settling of any of the various ingredients. Optionally these compositions contain one or more additional solid and/or liquid fuels, any of which may be water soluble.
- the degree of thickening of the above-described slurry-type explosive is regulated over a broad e range by choice, and amount, of thickener component, and the particular conditions for regulating the thickening action.
- thickeners of the polyacrylamide type pourability of the slurry can be retained over a broad range of ambient winter temperatures.
- Other thickeners include such as cereal flour, carboxymethylcellulose, galactomannans and the like, some of which, as in the case of some polyacrylamides, undergo cross linking to impart the desired degree of thickening.
- guar gum is most generally utilized in thickening cross linked form, and is readily cross linked by any of numerous well known cross linking agents.
- the slurry is either pumped directly into the borehole, or is packaged at the time of manufacture, andtransported to the blasting site where the entire package is charged into the borehole; or alternatively, the contents of the package are transferred directly from the package into the borehole.
- a packaged slurry it is advantageous that the contents be removed from the container rather than that the entire package be charged into the borehole, inasmuch as slurry freed from the container is more readily adaptable to fill the cross section of the borehole and thus afford a corresponding increase in loading density.
- the slurry is sufficiently fiowable that it can be poured from the package directly into the borehole and flow therein to fill the entire cross section of the borehole at maximum loading density.
- the degree of thickening of the slurry to be transferred from the package container is somewhat greater than the minimum required for stability of the suspension, in order to preclude loss of slurry by flow into cracks and crevices in the earth structure forming the borehole walls.
- the thickening action has been carried to such an extent that portions of the slurry, during the pouring operation, adhere to the container wall with which it has been in contact and hence that portion of the slurry mass is lost, often in a proportion up to 10 percent or more of the entire packaged mass.
- This invention is concerned with aqueous slurry explosives, above described, packaged in a container, and the resulting package being associated with an agent providing for ready release of the explosive from the container by gravitation.
- the release agent in preferred practice, also functions as a fuel for the subsequent detonation.
- a packaged inorganic oxidizer salt explosive of the aqueous slurry type which comprises a container, a mass of said explosive in said container, and a thickener in said explosive mass to prevent settling of the ingredients thereof; a lubricant-type release agent within the package of explosive to preclude adhesion of said explosive mass to the inner wall of said container during gravitation of said mass therefrom, and disposed so as to be in direct contact with said mass and with said inner container wall across the mass-inner wall interface during said gravitation.
- the consistency of the slurry-type mass is such that time for flow of the mass through an orifice of circular cross section, 2 inches in diameter, as measured by funnel test is not greater than about 2 minutes, more often in the range of from about 5 to 50 seconds.
- 2,000 cc. of slurry is poured into an aluminum funnel having the 2 inch diameter orifice.
- the timing period is begun.
- light is visible through the orifice (looking down into the funnel), timing is stopped. The time difference is designated as the flow time.
- the release agent can be disposed within the package assembly in any suitable manner, such as by direct application to the inner wall of the container prior to packaging, or by incorporation into the mass with other ingredients, during manufacture, with subsequent migration of the release agent throughout the mass to the exterior mass surface for contact with the container inner wall across the mass-wall interface. in all embodiments the release agent is present, to an extent, in the slurry mass.
- the release agent upon contact 'with the mass is absorbed, often to a limited degree into an outer peripheral mass portion; and is of course distributed throughout the mass when added directly thereto during manufacture. It is often advantageous to utilize both of the above-described procedures for disposing the release agent within the package.
- any portion, generally a topmost portion, of the container inner wall not initially .in contact with the slurry mass in the package is coated with a release agent in anticipation of its contact with the slurry during subsequent gravitation of the slurry from the container.
- the proportion of release agent, in the package assembly based on the finished slurry explosive mass is generally from about 0.1 to 1.0 weight percent.
- the proportion of release agent, in the package assembly based on the finished slurry explosive mass is generally from about 0.1 to 1.0 weight percent.
- it is often added in an amount from about 0.1 to 1.0 weight percent of the total slurry; and when the release agent is directly applied to the inner wall of the container for the package slurry, from about to 500 grams of release agent per 100 pounds of slurry mass is added.
- the container can advantageously be fabricated from a thin gauge metal, and from solid polymeric materials, such as polyethylene, polypropylene and the like.
- Exemplary release agents in accordance with the invention are saturated hydrocarbon oils, such as a paraffin oil, siliconetype oils, fuel oils and the like.
- the release agent is one which also serves as a fuel for the subsequent detonation, of which paraffin oil and fuel oil are now preferred.
- the release agent is a paraffin oil
- the container for the package is formed from polyethylene, and although the paraffin oil can be applied as the release agent, either to the polyethylene container wall or incorporated into the mass, it is advantageously applied utilizing both routes, i.e. it is applied directly to the inner wall of the container and is also added directly to the slurry during its manufacture.
- the slurrytype explosive composition mass independently of the relatively small proportion of absorbed, or residual, release agent therein, generally contains on a weight basis from 0.2 to 5 percent of the thickener component, from 8 to 25 percent water, from 20 to 75 percent inorganic oxidizer salt and from 3 to 50 percent sensitizer.
- the proportion of release agent absorbed by the explosive mass i.e. absorbed from the container inner wall after direct application of the release agent thereto, or present as residue following addition of the release agent to the slurry during slurry manufacture and migration of same to the container wall, is generally in the order of from about 0.05 to 0.2 weight percent.
- the inorganic oxidizer salt component in preferred practice, is generally ammonium nitrate or sodium perchlorate or both, often together with sodium nitrate.
- suitable inorganic oxidizer salts that can be used alone or with any one or more of the above inorganic oxidizer salts, are other alkali metal and alkaline earth metal nitrates and perchlorates (including ammonium) as for example magnesium nitrate, calcium nitrate, potassium nitrate, barium nitrate, ammonium perchlorate, potassium perchlorate, calcium perchlorate and magnesium perchlorate.
- ammonium nitrate and sodium perchlorate constitute the inorganic salt 7 component, they are utilized in any suitable relative proportions. Often, when either, or both, of ammonium nitrate and sodium perchlorate, is utilized with sodium nitrate, each is utilized in a weight ratio the sodium nitrate within the range of from about 1:1 to 10:1.
- Particle size and type of the oxidizer salt ingredient are not generally critical.
- ammonium nitrate can consist of prills such as used in fertilizers, and which are substantially all on 20 mesh, or it can be granular and in that form, very from coarse to fine.
- Other oxidizer salt ingredients are generally of comparable particle size.
- any or all of the oxidizer salt component can be added to the formulation in aqueous solution.
- any suitable thickener component for the slurry explosive mass can be utilized as for example a polyacrylamide-type thickener, carboxymethylcellulose, methyl cellulose, watersoluble starches, cereal flour, and galactomannans such as guar gum.
- a polyacrylamide-type thickener carboxymethylcellulose, methyl cellulose, watersoluble starches, cereal flour, and galactomannans such as guar gum.
- the proportion of thickener in the slurry composition is within the range of from about 0.2 to weight percent and more often from about 0.3 to 2 percent, the nowpreferred polyacrylamide thickener component, described hereinbelow, being generally present in a proportion of from about 0.4 to 1.5 weight percent.
- Now-preferred thickener components of the slurry mass are those two component polyacrylamide-type thickeners disclosed and ciaimed in my parent application, above referred to.
- the nowpreferred thickener component is a combination of polymers I and II in a polymer I to polymer 11 weight ratio within the range of :1 to 1:1.
- the polymer 1 is a partially hydrolyzed acrylamide polymer having a degree of hydrolysis such that 15 to 40 percent of the monomeric units therein have been converted to the hydrolyzed form, and the polymer having a molecular weight such that a 1 percent solution of the polymer in distilled water will have a viscosity in the range of 1,500 to 7,000 centipoises at 25 C.; and said polymer [1 being a cross linked product formed by copolymerizing acrylamide with at least one acrylate of the group consisting of ammonium an alkali metal acrylates, in an acrylamide to total acrylate weight ratio within the range of 40:1 to 2:1 in an aqueous solvent medium containing from 30 to 65 weight percent water and selected from the group s consisting of water-tertiary butanol, water-acetone, and water-tertiary butanol-acetone, at a temperature of 0 to 60 C., and cross linking the resulting copolymer as an ingredient of
- the polymeric 1 ingredient above described is that set forth in U.S. Pat. No. 3,341,383, and in preferred practice contains from about to 35 percent of the monomeric units therein converted to the hydrolyzed form, often in the order of about 22 percent together with a polymer viscosity of about 4,000 centipoises.
- polymeric ll copolymer ingredient above described, is disclosed in most of the monomeric unit proportions contemplated in practice of this invention in the copending application of Harrison et al. Ser. No. 594,500, filed Nov. 15, 1966; and in preferred practice has an acrylamide to total acrylate weight ratio not exceeding 20:1 and often within the range of about 6:1 to 12:1, a weight ratio of about 9:1 being advantageously employed in many instances.
- the polymeric l1 ingredient, a copolymer is prepared by only one known process, i.e., which will produce the polymer II ingredient having the properties applicable in the present invention.
- This process is referred to as a precipitation polymerization and comprises polymerizing a solution of acrylamide and acrylate monomers in aqueous tertiary butanol, aqueous acetone or aqueous tertiary butanol-acetone in the substantial absence of air while agitating the solution to give a copolymer product that can be isolated by filtration, the aqueous tertiary butanol and aqueous acetone being solvents for the monomers but nonsolvents for the copolymer product.
- the solvent for the monomers must be aqueous tertiary butanol, aqueous acetone, or aqueous tertiary butanol-acetone i.e., mixtures of water with tertiary butanol or acetone alone or with both).
- the concentrations of water in said mixtures must be 30 to 65 percent, preferably 45 to 60 percent, by weight of said mixtures.
- the polymerization reaction temperature must be 0 C. to 60 C., preferably 0 C. to 40 C.
- the polymerization may be carried out either in the presence or absence of a polymerization catalyst (initiator), but preferably a polymerization initiator will be used. Both the types and amounts of free radical initiator applicable are well known in this art. Peroxygen compounds arequite suitable, including, e.g., ammonium persulfate, potassium persulfate and hydrogen peroxide. Other free radical initiators include, e.g., a, a-azo-bis-isobutyronitrile.
- the peroxygen initiators may be used alone or in combination with activators (also well known in this art) including, e.g., sodium bisulfite, sodium thiosulfate, tetramethylethylenediamine, thiourea and and ferrous chloride, said combination forming a redox system.
- activators also well known in this art
- the amount of initiator usually will not exceed 0.5 percent, preferably is 0.05 to 0.2 percent, 0.05 percent being specifically preferred by weight of the combined weight of monomers.
- the precipitation polymerization is carried out in the presence of a salt dissolved in the polymerization reaction mixture.
- a salt or a buffer system comprising one or more salts in combination with another material to complete the buffer system, recovery of the copolymer product is substantially facilitated.
- These salts and buffer systems include, e.g.
- the amount of salt which may be used is about 0.1 to 2.0 percent, preferably about 0.2 to 0.7 percent, by weight of the reaction mixture. If the amount of salt exceeds about 2.0 percent, usually there is a tendency for the granules of the polymeric product to agglomerate in the polymerization reaction mixture.
- the manner of adding the salt and the point at which it is added are not critical.
- polyvalent metal salt cross linking agents for the formation of the polymer [1 ingredient are alum, chromium acetate and ferric citrate. Trivalent metal salt cross linking agents are generally preferred.
- polyacrylamide type thickeners particularly applicable in the packaged aqueous slurries, in practice of the invention, are well known in the art, as for example those described in several US. Pats. viz., US. Pat. Nos. 3,097,120; 3,097,121; 3,321,344; 3,341,383 and 3,355,336.
- the slurry mass of the package assembly of the invention is in most instances insensitive to detonating action of a commercial No. 8 blasting cap but detonatable by convention booster charges of PETN (pentaerythritol tetranitrate), RDX (cyclotrimethylenetrinitramine), Pentolite (PETN- TNT), tetryl, Composition B (RDX-TNT), and the like.
- PETN penentaerythritol tetranitrate
- RDX cyclotrimethylenetrinitramine
- Pentolite PETN- TNT
- tetryl tetryl
- Composition B Composition B
- One booster advantageously employed is a dispersion of a crystalline high explosive e.g., PETN or RDX, in a plastic carrier such as described in U.S. Pat. No. 2,965,466 and which is detonated by either a commercial blasting cap or detonating fuse.
- sensitizer materials for inorganic oxidizer salt blasting compositions of the aqueous slurry type can be utilized as such, in the compositions of the invention.
- exemplary of now preferred sensitizer components are smokeless powder as disclosed and claimed in the above said U.S. Pat. No. 3,235,425 and TNT and/or particulate aluminum as disclosed and claimed in the above said US. Pat. No. 2,930,685.
- Other suitable sensitizers include particulate aluminum, particulate magnesium-alumninum alloys, and high explosives such as PETN, tetryl, and the like.
- particulate metal fuels such as aluminum, silicon, and the like
- any suitable amount say, up to about 40 weight percent, often up to about 25 percent, but generally at least 1 percent.
- Formulations based on nonexplosive fuels are advantageously employed in the practice of the invention exemplary of which are the soluble polyalcohols such as ethylene required mixture of polymer I and II ingredients is dispersed in a nonaqueous liquid, generally ethylene glycol, and then added to a hot aqueous solution of the inorganic oxidizer salt in an amount to permit sufficient thickening to retain subsequently added ingredients, including the paraffin oil, in suspension.
- a suitable cross linking agent for the polymer II is added such as a polyvalent metal salt.
- the cross linking agent is often advantageously the last added ingredient, it can be added at any time during formation of the explosive slurry.
- the resulting slurry mixture is then packaged in a bag formed from polyethylene generally of the high-density type and of wall thickness of from about 4 to 15 mils.
- the inner wall of the bag is coated with paraffin oil prior to the packaging step to supplement release activity of the paraffin oil added during manufacture.
- the invention is further illustrated with reference to the following examples each of which shows a formulation made up in accordance with procedure described herein involving use of the polyacrylamide thickener system of polymers 1 and II, and then promptly packaged in bags of 18 inch length formed from 6 mil 6.25 inches diameter layflat polyethylene (highdensity type) tubing.
- the resulting packaged explosive, in each instance, was stored for 24 hours after which each bag was opened at the top, inverted, and the slurry content permitted to gravitate therefrom until all slurry, that would gravitate, was removed therefrom.
- the thickener (basis entire formulation) was formed from 0.8 percent polymer I and 0.2 percent polymer II as described herein; the polymer II was a eopolymer of acrylamide and sodium aerylate in an acrylamide: sodium acrylate Weight ratio of 9:1.
- the cross-linking agent for pol for Examples l-l incl. and Examples 5-8 incl.
- the cross-li 3 Funnel test Approximately 2 liters of slurry is po is opened to permit flow, the timeing is started. Whe
- ymer II was 0.00; and 0.006 wt. percent ferrous ammonium sulfate, resp. nking agent in Example 9 was 0.002 weight percent basic aluminum acetate.
- glycol and carbohydrates such as cane sugar.
- Nonsoluble fuels such as ground coal, powdered sulfur, fuel oil and other hydrocarbons are also useful when suitably dispersed.
- the amount of fuel present in the formulation is selected so as to provide an overall oxygen balance of 0 or less.
- the invention is, in preferred practice, applied to pourable slurry type explosives in which sodium perchlorate is at least 75 percent of the inorganic oxidizer salt component and the thickener is of the above described polyacrylamide type, preferably the polymer l-polymer ll thickener component described hereinabove.
- Such pourable slurry compositions, in which sodium perchlorate is at least 75 percent of the total inorganic oxidizer salt are disclosed and claimed in my copending application Sr. No. 784,210 filed Dec. 16, 1968.
- Any suitable procedure can be utilized in the manufacture, and packaging, of aqueous slurry explosives of the invention.
- One such procedure is directed to preparation of slurry compositions containing the above described combination of polymers I and II as the thickener component, and a paraffin oil as the release agent.
- the thickener component containing the above described combination of polymers I and II as the thickener component, and a paraffin oil as the release agent.
- the invention provides the basic advantage of economy inasmuch as it provides for substantially eliminating the loss of slurry resulting from tendency of slurry portions to remain adhered to the interior of the slurry package. Further, the invention, in addition to the economic advantages, reduces the hazards involved in handling and destroying the used slurry packages which would otherwise contain portions of adhered slurry explosive.
- a packaged explosive assembly comprising a container, and a pourable mass of an inorganic oxidizer salt explosive of the aqueous slurry type contained therein, said explosive containing a thickening amount of a polyacrylamide-type thickener component, and part of said mass adhering to an inner wall of said container during gravitation of same therefrom, the improvement comprising a lubricant-type release agent within said container for precluding adhesion of portions of said mass to the inner wall of said container during said gravitation, and disposed in direct contact with said mass and with said inner container wall across the mass-inner wall interface.
- a packaged explosive of claim 3 wherein said release agent is a lubricant selected from the group consisting of a fuel oil, a paraffin oil, and a silicone oil.
- a packaged explosive of claim 8 containing from 0.4 to 1.5 weight percent of said thickener component.
- a packaged explosive of claim 9 containing sodium perchlorate as at least 75 weight percent of the total inorganic oxidizer salt.
- a packaged explosive of claim 2 said container having a portion of said release agent on said inner wall thereof prior to containing said explosive mass, and said explosive mass containing the remaining portion of said release agent, prior to being packaged in said container.
- a method for packaging a pourable mass of aqueous slurry-type inorganic oxidizer salt explosive containing a thickening amount of a polyacrylamide type thickener, in a container, and part of said mass adheres to the inner wall of said container when gravitated therefrom the improvement comprising emplacing a lubricant-type release agent within said container in direct contact with said inner wall and with said mass across the mass-inner wall interface for precluding adhesion of portions of said mass to said inner wall when said mass is gravitated from said container.
- said release agent is a lubricant selected from the group consisting of a fuel oil, a paraffin oil, and a silicon oil.
Abstract
Description
Claims (19)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US69409767A | 1967-12-28 | 1967-12-28 | |
US78421168A | 1968-12-16 | 1968-12-16 |
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US3566790A true US3566790A (en) | 1971-03-02 |
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US784211A Expired - Lifetime US3566790A (en) | 1967-12-28 | 1968-12-16 | Packaged aqueous slurry type explosives |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3690213A (en) * | 1969-09-29 | 1972-09-12 | Dow Chemical Co | Method and apparatus for delivering thickened blasting agents |
US4870884A (en) * | 1987-07-29 | 1989-10-03 | Diehl Gmbh & Co. | Incendiary projectile, method of introducing the incendiary composition into the projectile and arrangement for implementing the method |
US5233926A (en) * | 1991-06-05 | 1993-08-10 | Inco Limited | Adhesive secondary blasting cone |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3097121A (en) * | 1961-08-11 | 1963-07-09 | American Cyanamid Co | Powdered ammonium nitrate explosive containing polyacrylamide and an inorganic cross-linking agent |
US3199399A (en) * | 1963-05-17 | 1965-08-10 | Phillips Petroleum Co | Shot hole loading device |
US3303738A (en) * | 1963-10-14 | 1967-02-14 | Intermountain Res And Engineer | Method for mixing and pumping of slurry explosive |
-
1968
- 1968-12-16 US US784211A patent/US3566790A/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3097121A (en) * | 1961-08-11 | 1963-07-09 | American Cyanamid Co | Powdered ammonium nitrate explosive containing polyacrylamide and an inorganic cross-linking agent |
US3199399A (en) * | 1963-05-17 | 1965-08-10 | Phillips Petroleum Co | Shot hole loading device |
US3303738A (en) * | 1963-10-14 | 1967-02-14 | Intermountain Res And Engineer | Method for mixing and pumping of slurry explosive |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3690213A (en) * | 1969-09-29 | 1972-09-12 | Dow Chemical Co | Method and apparatus for delivering thickened blasting agents |
US4870884A (en) * | 1987-07-29 | 1989-10-03 | Diehl Gmbh & Co. | Incendiary projectile, method of introducing the incendiary composition into the projectile and arrangement for implementing the method |
US5233926A (en) * | 1991-06-05 | 1993-08-10 | Inco Limited | Adhesive secondary blasting cone |
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