US3537879A - Method of coating magnesium metal to prevent corrosion - Google Patents
Method of coating magnesium metal to prevent corrosion Download PDFInfo
- Publication number
- US3537879A US3537879A US611539A US3537879DA US3537879A US 3537879 A US3537879 A US 3537879A US 611539 A US611539 A US 611539A US 3537879D A US3537879D A US 3537879DA US 3537879 A US3537879 A US 3537879A
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- Prior art keywords
- magnesium metal
- corrosion
- coating
- resin
- magnesium
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/10—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
- B05D3/102—Pretreatment of metallic substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
- B05D7/16—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies using synthetic lacquers or varnishes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2202/00—Metallic substrate
- B05D2202/20—Metallic substrate based on light metals
Definitions
- This invention relates to the treatment of magnesium metal and magnesium-base alloys top'rovide the same with a protective corrosion-resistant coating and, more particularly, to an improved coating composition and method of forming the coating.
- the invention provides a new and highly efiicient method for applying a hard, tough and highly flexible resinous material to articles of magnesium and magnesium-base alloys and composite metal structures containing such articles which undergo corrosive deterioration while immersed in salt water or exposed to salt splash conditions.
- the invention is based on the discovery that on cleaning the magnesium metal article with an alkaline solution, as hereinafter more fully set forth, the application to the clean surface of a resin primer obtained by adding at least 3 ounces of zinc chromate to a suitably plasticized water-insoluble, liquid phenolic resin, provides a corrosion-inhibiting film, which can be used as a final finish and which provides an excellent base for subsequent painting.
- a critical feature in the method of the present invention is the cleaning operation that precedes the application of the coating. Best results are achieved when the magnesium metal article to be coated is treated for a short time by immersion in an alkaline solution at 180 F. to 212 F.
- the invention utilizes a resin primer which consists essentially of a water-insoluble liquid phenolic resin.
- the phenolic resin can be conveniently produced by condens ing a phenol and formaldehyde in the presence of a catalyst, such as morpholine.
- the mole ratio is about .75 mole of formaldehyde per one mole of phenol.
- the reaction is catalyzed with 1% morpholine based on the weight of the phenol.
- the condensation reaction is carried out at 60 C.
- phenolic resins of the present invention are therefore plasticized with l020% polyvinyl butyral to give greater flexibility to the primer.
- the solvent employed can be any organic solvent in which the phenolic resin is soluble. Commonly employed as solvents are toluene, xylenes, denatured ethyl alcohol, isopropanol, aromatic hydrocarbon mixtures such as Solvesso, and also various aliphatic, naphthenic and aromatic naphthas.
- the phenolic resin is preferably applied to the magnesium metal article from a solvent solution as by spraying, or roller coating, or dipping, as desired.
- a solvent solution as by spraying, or roller coating, or dipping, as desired.
- the magnesium metal article may be dipped in a tank containing a 20% solution of phenolic resin in an organic solvent of the aforesaid type.
- the coating solutions may contain from about 20 to about 50% by weight of resin, based on the combined weight resin and solvent.
- the resultant coating is adapted to be advantageously cured by heating. Generally the curing cycles are conducted at temperatures on the order of about 250 F. to about 400 F. until the coating cures to a hard, infusible state and is insoluble in most of the known solvents. If desired, pigments and other such modifiers can be added to the phenolic resins in suitable amounts as is well known in the art.
- the phenolic resins can be conveniently produced by condensing a phenol with formaldehyde.
- phenols suitable for reaction with formaldehyde are the tri-functional phenols, that is phenols having at least 3 unsubstituted positions, illustrative of which are the following: phenol; meta-substituted phenols such as the alkylated phenols exemplary of which are m-cresol, methyl phenol, m-n-propyl phenol, m-isopropyl phenol, m-sec.-butyl phenol, m-tert.-butyl phenol and the like; meta-substituted alkoxy phenols such as m-methoxy phenol, m-ethoxy phenol and the like; also suitable is re sorcinol.
- Formaldehyde in any of its available forms, i.e. Formalin and para-formaldehyde can be used.
- the magnesium metal article to be coated is cleaned in an alkaline solution heated to 180 F.2l2 F. for a period of 2 minutes.
- the alkaline bath kept at a pH of about 11, contains per gallon of water:
- a preferred method of applying the coating is to quench the metal, at room temperature, in a bath containing a solution of the uncured phenolic resin in an organic solvent and zinc chromate in the proportion of 3 ounces as a minimum to as high as 16 ounces per gallon of resin. This has the effect of pulling the resin into fine cracks and defects in the surface of the metal.
- the coated article is then oven dried at 300 F. for minutes. This allows the solvent to evaporate from the coating film which becomes fully set.
- One or more coats may be used.
- One coat generally suffices for atmospheric conditions, but to secure protection in salt water it is desirable to use 2 to 3 coats.
- the bars coated with the resin primer of the present invention were continuously sprayed during a test period of 1000 hours.
- identical bars provided with a conventional corrosion-resistant coating were dried and subjected to the salt spray test referred to above during test periods of 24 hours and 48 hours respectively.
- FIG. 1 is a photomicrograph showing the bar on the top coated with the resin primer of the present invention not corroded on being subjected to 5% salt spray 4 for 1000 hours, and the bar at the bottom, provided with a conventional corrosion-resistant coating, severly corroded on being subjected to the same salt spray test for 24 hours.
- FIG. 2 is a photomicrograph showing the bar on the top coated with the resin primer of the present invention not corroded on being subjected to 5% salt spray for 1000 hours, and the bar at the bottom, provided with a conventional corrosion-resistant coating, severly corroded on being subjected to the same salt spray test for 48 hours.
- the method of inhibiting corrosion of a magnesium metal article which comprises cleaning the surface of said article with an alkaline solution at F.-212 F., drying said cleaned article, and applying to the clean surface of said article a solution consisting essentially of plasticized, water-insoluble uncured liquid phenolic resin in an organic solvent containing zinc chromate in the proportion of 3 ounces by Weight as a minimum to as high as 16 ounces per gallon of resin, and drying the coated article at temperatures in the range of 250- 400 'F. to allow the solvent to evaporate therefrom and the coating to become fully set.
- phenolic resin is a condensation product of phenol and formaldehyde plasticized with 10-20% polyvinyl butyral.
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
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Description
Nov. 3, 1970 w. WILSON, JR
METHOD OF COATING MAGNESIUM METAL TO PREVEI\'T CORROSlON Filed Jan. 19. 1967 FIG. I
FIG. 2
INVENTOR W.W|L5ON,JR BY Mfid ATTORNEY United States Patent "ice U.S. Cl. 117-49 4 Claims ABSTRACT OF THE DISCLOSURE The corrosion of magnesium metal articles is prevented by applying a phenolic resin primer containing zinc chromate to the surface of the metal which, prior to the application of said resin primer, is cleaned in an alkaline bath.
BACKGROUND This invention relates to the treatment of magnesium metal and magnesium-base alloys top'rovide the same with a protective corrosion-resistant coating and, more particularly, to an improved coating composition and method of forming the coating.
Specifically, the invention provides a new and highly efiicient method for applying a hard, tough and highly flexible resinous material to articles of magnesium and magnesium-base alloys and composite metal structures containing such articles which undergo corrosive deterioration while immersed in salt water or exposed to salt splash conditions.
Known methods of protecting magnesium against corrosion include the application of organic coatings. However, the previously used coatings, although representing definite progress in the art, have not been entirely successful. All attempts to lessen corrosion of magnesium have only been satisfactory to improve the corrosion resistance without eliminating it.
There is, accordingly, a need for a more convenient method of preventing the corrosion of magnesium, whether in the atmosphere, the sea, or the earth.
The present invention meets this need. The method of practicing the invention is made clear in the ensuing description and is specifically defined in the appended claims.
SUMMARY The invention is based on the discovery that on cleaning the magnesium metal article with an alkaline solution, as hereinafter more fully set forth, the application to the clean surface of a resin primer obtained by adding at least 3 ounces of zinc chromate to a suitably plasticized water-insoluble, liquid phenolic resin, provides a corrosion-inhibiting film, which can be used as a final finish and which provides an excellent base for subsequent painting.
A critical feature in the method of the present invention is the cleaning operation that precedes the application of the coating. Best results are achieved when the magnesium metal article to be coated is treated for a short time by immersion in an alkaline solution at 180 F. to 212 F.
DETAILED DESCRIPTION The invention utilizes a resin primer which consists essentially of a water-insoluble liquid phenolic resin. The phenolic resin can be conveniently produced by condens ing a phenol and formaldehyde in the presence of a catalyst, such as morpholine. The mole ratio is about .75 mole of formaldehyde per one mole of phenol. The reaction is catalyzed with 1% morpholine based on the weight of the phenol. The condensation reaction is carried out at 60 C.
3,537,879 Patented Nov. 3, 1970 and is terminated at the point where the resulting resin is soluble in alcohol.
Heretofore, the poor flexibility characteristics of phenolic resins has limited considerably the scope of usefulness of such resins in coating applications. The phenolic resins of the present invention are therefore plasticized with l020% polyvinyl butyral to give greater flexibility to the primer.
Substantially the same result as that set forth herein can be gained by the use of other plasticizers. Some of the lower polymers of acrylic acids form salts which are relatively flexible and these classes of resins may be advantageously employed to plasticize more inflexible resins as exemplified by the hardened phenolic resins.
The condensation reaction product of a phenol and formaldehyde which, when plasticized with polyvinyl butyral, or the like, yields the phenolic resin of this invention, is conveniently dissolved in a water-immiscible solvent. The solvent employed can be any organic solvent in which the phenolic resin is soluble. Commonly employed as solvents are toluene, xylenes, denatured ethyl alcohol, isopropanol, aromatic hydrocarbon mixtures such as Solvesso, and also various aliphatic, naphthenic and aromatic naphthas.
The phenolic resin is preferably applied to the magnesium metal article from a solvent solution as by spraying, or roller coating, or dipping, as desired. Thus the magnesium metal article may be dipped in a tank containing a 20% solution of phenolic resin in an organic solvent of the aforesaid type. For purposes of this invention the coating solutions may contain from about 20 to about 50% by weight of resin, based on the combined weight resin and solvent.
The resultant coating is adapted to be advantageously cured by heating. Generally the curing cycles are conducted at temperatures on the order of about 250 F. to about 400 F. until the coating cures to a hard, infusible state and is insoluble in most of the known solvents. If desired, pigments and other such modifiers can be added to the phenolic resins in suitable amounts as is well known in the art.
As noted, the phenolic resins can be conveniently produced by condensing a phenol with formaldehyde. Among phenols suitable for reaction with formaldehyde are the tri-functional phenols, that is phenols having at least 3 unsubstituted positions, illustrative of which are the following: phenol; meta-substituted phenols such as the alkylated phenols exemplary of which are m-cresol, methyl phenol, m-n-propyl phenol, m-isopropyl phenol, m-sec.-butyl phenol, m-tert.-butyl phenol and the like; meta-substituted alkoxy phenols such as m-methoxy phenol, m-ethoxy phenol and the like; also suitable is re sorcinol.
Formaldehyde in any of its available forms, i.e. Formalin and para-formaldehyde can be used.
DETAILED DESCRIPTION OF METHOD In carrying out the invention, the magnesium metal article to be coated is cleaned in an alkaline solution heated to 180 F.2l2 F. for a period of 2 minutes. The alkaline bath, kept at a pH of about 11, contains per gallon of water:
4-8 ounces of sodium hydroxide O2 ounces of trisodium phosphate 0-2 ounces of sodium carbonate On entering the bath, hydrogen bubbles can be seen coming from the surface of the metal so that at the end of 2. minutes the metal is not only free from grease and mill scale, but has a skin left thereon formed of a magnesium hydride without any free hydrogen. The magnesium metal article is then dried, as by oven baking at 300 F. for 5 minutes which insures that all loose oxides and residual products causing corrosion are eliminated. A preferred method of applying the coating is to quench the metal, at room temperature, in a bath containing a solution of the uncured phenolic resin in an organic solvent and zinc chromate in the proportion of 3 ounces as a minimum to as high as 16 ounces per gallon of resin. This has the effect of pulling the resin into fine cracks and defects in the surface of the metal. The coated article is then oven dried at 300 F. for minutes. This allows the solvent to evaporate from the coating film which becomes fully set.
One or more coats may be used. One coat generally suffices for atmospheric conditions, but to secure protection in salt water it is desirable to use 2 to 3 coats.
When zinc chromate is combined with the phenolic resin in the manner described, there results an improved corrosion protection over the use of the phenolic resin alone. It is believed that if the magnesium metal part is scratched to the bare surface and exposed to corrosive influences, e.g. aqueous salt solution, a leeching effect is obtained whereby the zinc compounds reacts with the magnesium to prevent corrosion on the uncovered surface and creepage under the coating.
The method of the present invention has been described in some detail, and it will be evident to those skilled in the art that for some reason the combination of a clean magnesium hydrided surface with the resin primer specified herein provides a corrosion-inhibiting film having outstanding properties, including excellent paint bonding characteristics.
DESCRIPTION OF CORROSION TESTS AS SHOWN IN PHOTOMICROGRAPHS Corrosion tests were carried out on magnesium metal samples, in the form of bars. In each case, one bar was coated with the resin primer that forms the subject of the present invention and one comparison bar was provided with a conventional corrosion-resistant coating. Each coated bar was thoroughly air-dried and then subjected to a salt spray test in which a 5% solution of sodium chloride at 100 F. is continuously sprayed on the bars during certain test periods.
The bars coated with the resin primer of the present invention were continuously sprayed during a test period of 1000 hours. By way of comparison, identical bars provided with a conventional corrosion-resistant coating were dried and subjected to the salt spray test referred to above during test periods of 24 hours and 48 hours respectively.
Visual inspection of the exposed or tested bars coated with the resin primer of the present invention showed no attack of the magnesium metal. The comparison bars having the conventional corrosion-resistant coating showed severe attack of the magnesium metal.
The results of the tests are illustrated in the accompanying figures, where FIG. 1 is a photomicrograph showing the bar on the top coated with the resin primer of the present invention not corroded on being subjected to 5% salt spray 4 for 1000 hours, and the bar at the bottom, provided with a conventional corrosion-resistant coating, severly corroded on being subjected to the same salt spray test for 24 hours.
FIG. 2 is a photomicrograph showing the bar on the top coated with the resin primer of the present invention not corroded on being subjected to 5% salt spray for 1000 hours, and the bar at the bottom, provided with a conventional corrosion-resistant coating, severly corroded on being subjected to the same salt spray test for 48 hours.
The composition and method of the invention having been thus described, modifications thereof will be apparent to those skilled in the art and the invention is to be considered limited in scope only by the scope of the hereinafter appended claims.
What is claimed is:
1. The method of inhibiting corrosion of a magnesium metal article which comprises cleaning the surface of said article with an alkaline solution at F.-212 F., drying said cleaned article, and applying to the clean surface of said article a solution consisting essentially of plasticized, water-insoluble uncured liquid phenolic resin in an organic solvent containing zinc chromate in the proportion of 3 ounces by Weight as a minimum to as high as 16 ounces per gallon of resin, and drying the coated article at temperatures in the range of 250- 400 'F. to allow the solvent to evaporate therefrom and the coating to become fully set.
2. The method of claim 1 wherein the magnesium metal article is cleaned in an alkaline bath kept at a pH of 11.
3. The method of claim 1 wherein said coated article is oven dried at 300 F.
4. The method of claim 1 wherein the phenolic resin is a condensation product of phenol and formaldehyde plasticized with 10-20% polyvinyl butyral.
References Cited UNITED STATES PATENTS 2,709,664 5/ 1955 Evans 117-75 2,927,046 3/1960 Andrade 117-75 X 3,053,691 9/ 1962 Hartman 117-475 3,053,785 9/1962 Rosenbloom 117-75 X 3,251,708 5/ 1966 Schmettercr 117-75 X 3,252,215 5/1966 DeLong 117-75 X 3,312,624 4/1967 Levittown 252-156 X 2,725,310 11/1955 McBride 117-49 X 3,034,210 5/1962 DeLong 117132 3,351,675 11/1967 Gilchrist 117132 3,398,107 8/1968 Rowe 117-132 3,401,139 9/1968 Wertz 117-l32 3,443,977 5/1969 Bennetch 117132 WILLIAM 'D. MARTIN, Primary Examiner W. R. TRENOR, Assistant Examiner U.S. C1.X.R.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US61153967A | 1967-01-19 | 1967-01-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3537879A true US3537879A (en) | 1970-11-03 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US611539A Expired - Lifetime US3537879A (en) | 1967-01-19 | 1967-01-19 | Method of coating magnesium metal to prevent corrosion |
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| Country | Link |
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| US (1) | US3537879A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4544688A (en) * | 1984-05-29 | 1985-10-01 | Union Carbide Corp. | Metal-containing phenolic coating compositions |
| EP0219976A1 (en) * | 1985-09-18 | 1987-04-29 | Nippon Paint Co., Ltd. | A primer composition for a metallic material and a coating method using the same |
Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2709664A (en) * | 1950-10-13 | 1955-05-31 | Master Mechanics Co | Process for forming chemical resistant synthetic resin coatings on metal and product thereof |
| US2725310A (en) * | 1951-11-23 | 1955-11-29 | Westinghouse Electric Corp | Rust inhibitive finishes for ferrous metals |
| US2927046A (en) * | 1958-11-20 | 1960-03-01 | Parker Rust Proof Co | Coated metals and solutions and process for making the same |
| US3034210A (en) * | 1959-09-03 | 1962-05-15 | Dow Chemical Co | Inhibition of corrosion of magnesium |
| US3053691A (en) * | 1958-01-29 | 1962-09-11 | Allied Res Products Inc | Protective coating |
| US3053785A (en) * | 1958-02-18 | 1962-09-11 | Rosenbloom Devorah | Aqueous alkaline solution comprising vinyl acetate copolymer, a chromate and water-soluble volatile base |
| US3251708A (en) * | 1962-06-01 | 1966-05-17 | Inland Steel Co | Coating with a polyamide-epoxy resin |
| US3252215A (en) * | 1961-12-06 | 1966-05-24 | Dow Chemical Co | Method of coating a magnesium metal article |
| US3312624A (en) * | 1962-05-18 | 1967-04-04 | Rohm & Haas | Stable alkali soluble surfactants |
| US3351675A (en) * | 1966-01-10 | 1967-11-07 | Ford Motor Co | Resinous coating materials |
| US3398107A (en) * | 1965-10-28 | 1968-08-20 | Exxon Research Engineering Co | Modified xylene-formaldehyde resins |
| US3401139A (en) * | 1962-12-24 | 1968-09-10 | Union Carbide Corp | Flexible phenolic baking resins prepared by reacting a polyhydric phenol ether, phenol and an organic solution of formaldehyde |
| US3443977A (en) * | 1967-11-13 | 1969-05-13 | Pfizer & Co C | Anticorrosion pigments |
-
1967
- 1967-01-19 US US611539A patent/US3537879A/en not_active Expired - Lifetime
Patent Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2709664A (en) * | 1950-10-13 | 1955-05-31 | Master Mechanics Co | Process for forming chemical resistant synthetic resin coatings on metal and product thereof |
| US2725310A (en) * | 1951-11-23 | 1955-11-29 | Westinghouse Electric Corp | Rust inhibitive finishes for ferrous metals |
| US3053691A (en) * | 1958-01-29 | 1962-09-11 | Allied Res Products Inc | Protective coating |
| US3053785A (en) * | 1958-02-18 | 1962-09-11 | Rosenbloom Devorah | Aqueous alkaline solution comprising vinyl acetate copolymer, a chromate and water-soluble volatile base |
| US2927046A (en) * | 1958-11-20 | 1960-03-01 | Parker Rust Proof Co | Coated metals and solutions and process for making the same |
| US3034210A (en) * | 1959-09-03 | 1962-05-15 | Dow Chemical Co | Inhibition of corrosion of magnesium |
| US3252215A (en) * | 1961-12-06 | 1966-05-24 | Dow Chemical Co | Method of coating a magnesium metal article |
| US3312624A (en) * | 1962-05-18 | 1967-04-04 | Rohm & Haas | Stable alkali soluble surfactants |
| US3251708A (en) * | 1962-06-01 | 1966-05-17 | Inland Steel Co | Coating with a polyamide-epoxy resin |
| US3401139A (en) * | 1962-12-24 | 1968-09-10 | Union Carbide Corp | Flexible phenolic baking resins prepared by reacting a polyhydric phenol ether, phenol and an organic solution of formaldehyde |
| US3398107A (en) * | 1965-10-28 | 1968-08-20 | Exxon Research Engineering Co | Modified xylene-formaldehyde resins |
| US3351675A (en) * | 1966-01-10 | 1967-11-07 | Ford Motor Co | Resinous coating materials |
| US3443977A (en) * | 1967-11-13 | 1969-05-13 | Pfizer & Co C | Anticorrosion pigments |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4544688A (en) * | 1984-05-29 | 1985-10-01 | Union Carbide Corp. | Metal-containing phenolic coating compositions |
| EP0219976A1 (en) * | 1985-09-18 | 1987-04-29 | Nippon Paint Co., Ltd. | A primer composition for a metallic material and a coating method using the same |
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