US3521874A - Gas diffuser unit for use in treating molten metal - Google Patents

Gas diffuser unit for use in treating molten metal Download PDF

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Publication number
US3521874A
US3521874A US638085A US3521874DA US3521874A US 3521874 A US3521874 A US 3521874A US 638085 A US638085 A US 638085A US 3521874D A US3521874D A US 3521874DA US 3521874 A US3521874 A US 3521874A
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molten metal
gas
diffuser unit
gas diffuser
treating molten
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US638085A
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Eugene L Warfield
Charles M Thompson
Gordon C Johnson
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Reynolds Metals Co
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Reynolds Metals Co
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D1/00Treatment of fused masses in the ladle or the supply runners before casting
    • B22D1/002Treatment with gases
    • B22D1/005Injection assemblies therefor
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B21/00Obtaining aluminium
    • C22B21/06Obtaining aluminium refining
    • C22B21/064Obtaining aluminium refining using inert or reactive gases
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B9/00General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
    • C22B9/05Refining by treating with gases, e.g. gas flushing also refining by means of a material generating gas in situ

Definitions

  • This invention relates to the treatment of molten metal, particularly aluminous metal, and to apparatus for introducing a fluxing gas into the molten metal in the course of such treatment.
  • a gas diffusion unit having a one-piece body of porous graphite and one or more openings to an interior hollow portion or portions thereof.
  • inlet tubes are securely attached to the one-piece body, preferably by means of threaded connections therebetween. A gas-tight system is thereby assured.
  • FIG. 1 shows a fluxing device as previously constructed
  • FIG. 2 is an end view of a porous graphite diffuser in accordance with the present invention, showing a pair of symmetrically disposed inlet tubes
  • FIG. 3 is a sectional view along line AA of FIG. 2.
  • the gas diffuser unit has a one-piece hollow graphite body 12 of controlled porosity to allow for the flow of gas therethrough.
  • inlet tubes 14 and 15 also made of graphite (and having substantially the same thermal expansion characteristic) which are attached to the body 12 by threaded connections.
  • the fluxing gas is introduced through these tubes into a hollow interior passageway 18 associated with each tube.
  • the passageways which may be cylindrical as a result of boring the graphite body from one end thereof, are symmetrically disposed with respect to the semi-circular cross-section of body 12 and are spaced from its outer surface to provide a porous graphite wall of uniform thickness.
  • Typical dimensions of such a unit are: a body of 37" length and 3 /2" radius, with bore holes of 1" diameter spaced apart about 2 /2" (center to 3,521,874 Patented July 28, 1970 ice center) and spaced inwardly to leave a wall thickness of about 1%".
  • a commercially available porous graphite found to be suitable for the body 12 is Grade No. 60 sold by Carbon Products Division of Union Carbide.
  • the present invention overcomes these problems and provides a reliable means of introducing fluxing gas into the molten metal to be treated. This is accomplished simply by immersing the unit in the molten metal, with the inlet tubes exposed for connection to a supply of gas under pressure, and forcing the gas outwardly throug the porous graphite.
  • a gas diffuser unit for introducing fluxing gas into molten metal comprising a hollow elongated graphite body of substantially semicircular transverse cross-section adapted to be immersed in the molten metal, having a porous graphite Wall and an adjoining interior chamber to receive the gas for transmission outwardly through said wall; and
  • tube means for introducing gas into the interior chamber of said body.
  • Apparatus according to claim 2 including a plurality of parallel cylindrical passageways spaced inwardly from said outer surface the same distance.
  • Apparatus according to claim 3 including one such passageway on each side of the axis of symmetry of said bod 5?
  • a gas diffuser unit for introducing fiuxing gas into molten metal comprising a hollow porous graphite body having porous walls defining at least two interior chambers to receive the gas for transmission outwardly through said walls; and tube means for introducing gas into each interior chamber of said body, said tube means and hollow body 3 4 gaging gas-tight joints therebetween, said body and FOREIGN PATENTS the portion of said tube means forming the joints 456,234 3/1950 Ita1y being adapted for immersion in the molten metal.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Steel In Its Molten State (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Description

Juiy 28, 1970 3,521,874
GAS DIFFUSER UNIT FOR usE in TREATING MOLTEN METAL Filed May 12. 1967' E. L. WARFIgL ErAL,
2 Sheets-Sheet 1 CARBONPLATE I (PRIOR ART} CEMENTED JOINTS GRAPHDTE TUBES 0|||||||| llllulllllllllllllllllullllllllnIll-Ill.l|.||l llllulllllllll|l||||-lu|l nlllllllu lllu llllSlZl-lll llllllll llllllllallllllilllllilllllllllllllllllllllllllllulll ll lullill" INVENTOR UGENE LWARHELD E CHARLES M. THOMPSON sonoom CJOHNSON BY v ATTORNEY July 28, 1970 E. L. WARFIELD ErAL 3,521,874
NVENTOR EUGENE LWARFIE CHARLES MTHOMPSON GORDON CJOHNSON Y BY E Z TORNEY v United States Patent US. Cl. 266--41 6 Claims ABSTRACT OF THE DISCLOSURE Apparatus for and method of treating molten metal by introducing gas into the molten metal through the wall of a porous graphite body immersed therein.
This invention relates to the treatment of molten metal, particularly aluminous metal, and to apparatus for introducing a fluxing gas into the molten metal in the course of such treatment.
In the treatment of molten aluminum, it has been known to use a plurality of porous carbon plates cemented together to form a diffuser element for introducing an inert gas. The use of such elements has not been entirely satisfactory, however, due to leakage at the joints between plates. In addition, there was a tendency for molten metal to seep into such joints and plug the inlet tubes.
In accordance with the present invention, there is provided a gas diffusion unit having a one-piece body of porous graphite and one or more openings to an interior hollow portion or portions thereof. In order to avoid any joints through which leakage of the gas might take place, inlet tubes are securely attached to the one-piece body, preferably by means of threaded connections therebetween. A gas-tight system is thereby assured.
In the accompanying drawings: FIG. 1 shows a fluxing device as previously constructed; FIG. 2 is an end view of a porous graphite diffuser in accordance with the present invention, showing a pair of symmetrically disposed inlet tubes; and FIG. 3 is a sectional view along line AA of FIG. 2.
Referring next to FIGS. 2 and 3 of the drawings, the gas diffuser unit has a one-piece hollow graphite body 12 of controlled porosity to allow for the flow of gas therethrough. As shown, there are preferably two inlet tubes 14 and 15 also made of graphite (and having substantially the same thermal expansion characteristic) which are attached to the body 12 by threaded connections. The fluxing gas is introduced through these tubes into a hollow interior passageway 18 associated with each tube.
It will be noted that the passageways, which may be cylindrical as a result of boring the graphite body from one end thereof, are symmetrically disposed with respect to the semi-circular cross-section of body 12 and are spaced from its outer surface to provide a porous graphite wall of uniform thickness. Typical dimensions of such a unit are: a body of 37" length and 3 /2" radius, with bore holes of 1" diameter spaced apart about 2 /2" (center to 3,521,874 Patented July 28, 1970 ice center) and spaced inwardly to leave a wall thickness of about 1%". A commercially available porous graphite found to be suitable for the body 12 is Grade No. 60 sold by Carbon Products Division of Union Carbide.
In contrast, as shown in FIG. 1, the construction previously used for this purpose had several carbon plates 20 cemented together, with gas inlet connections made from half-round tube sections 22 cemented onto adjacent faces of the plates. Not only was there a problem of leakage between plates, but the joints between the tubes and plates made it even more likely that excessive leakage would occur. In fact, it was regularly observed that molten metal seeped into the joints and soon plugged the inlet tubes. A further complication was that graphite tubes employed with the carbon plates resulted in a 3:1 difference in coefficient of thermal expansion, which made the maintenance of a gas-tight joint virtually hopeless.
The present invention overcomes these problems and provides a reliable means of introducing fluxing gas into the molten metal to be treated. This is accomplished simply by immersing the unit in the molten metal, with the inlet tubes exposed for connection to a supply of gas under pressure, and forcing the gas outwardly throug the porous graphite.
While the present preferred embodiment of the invention and its method of use in treating molten metal have been described and illustrated, the invention may be otherwise variously embodied and practiced within the scope of thefollowing claims.
What is claimed is:
1. A gas diffuser unit for introducing fluxing gas into molten metal, comprising a hollow elongated graphite body of substantially semicircular transverse cross-section adapted to be immersed in the molten metal, having a porous graphite Wall and an adjoining interior chamber to receive the gas for transmission outwardly through said wall; and
tube means for introducing gas into the interior chamber of said body.
2. Apparatus according to claim 1, in which said body has an interior cylindrical passageway extending parallel to its semicircular outer surface.
3. Apparatus according to claim 2, including a plurality of parallel cylindrical passageways spaced inwardly from said outer surface the same distance.
4. Apparatus according to claim 3, including one such passageway on each side of the axis of symmetry of said bod 5? Apparatus according to claim 1, in which a graphite tube is joined to said hollow body by a threaded connection, said tube and body having substantially the same thermal expansion characteristic.
6. A gas diffuser unit for introducing fiuxing gas into molten metal, comprising a hollow porous graphite body having porous walls defining at least two interior chambers to receive the gas for transmission outwardly through said walls; and tube means for introducing gas into each interior chamber of said body, said tube means and hollow body 3 4 gaging gas-tight joints therebetween, said body and FOREIGN PATENTS the portion of said tube means forming the joints 456,234 3/1950 Ita1y being adapted for immersion in the molten metal.
References Cited UNITED STATES PATENTS 1,386,390 12/1964 France.
OTHER REFERENCES National Carbon and Graphite and Karbate Products, Catalog Section 8-5005, August 1951, published by Avery et a1. 26 National Carbon 00., 30 E. 42nd St., New York, N.Y., Ruhenbeck et a1 75-59 pp. 13 and 17 relied on.
Spire 7559 1 Le y et a1. 75 59 J. SPENCER OVERHOLSER, Primary Examiner Ruttiger et V. K. RISING, Assistant Examiner snelling- Y US. Cl. X.R.
Richardson. 15
US638085A 1967-05-12 1967-05-12 Gas diffuser unit for use in treating molten metal Expired - Lifetime US3521874A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3758081A (en) * 1970-04-02 1973-09-11 Rhone Progil Quench chamber for hot gases
EP0006453A1 (en) * 1978-06-22 1980-01-09 Messer Griesheim Gmbh Process for increasing the lifetime of flush gas lances with porous lance heads made of graphite and inertion cage used therefor
US4741515A (en) * 1986-10-20 1988-05-03 Bethlehem Steel Corporation Apparatus for introducing gas into a metallurgical vessel
EP0333586A1 (en) * 1988-03-15 1989-09-20 Alusuisse-Lonza France Apparatus for removing gaseous and solid impurities from a molten product contained in a vessel

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0116818B1 (en) * 1982-12-17 1987-09-16 René Desaar Porous head for a gas injection lance

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US67350A (en) * 1867-07-30 Of glasgow
US1836196A (en) * 1928-10-24 1931-12-15 Walter O Snelling Method of treating molten materials
US2540231A (en) * 1948-08-24 1951-02-06 Republic Steel Corp Tuyere
US2871008A (en) * 1950-11-02 1959-01-27 Air Liquide Apparatus for gas flushing of molten metal
US2874038A (en) * 1955-09-19 1959-02-17 Ruhenbeck Adalbert Method of treating molten metals
US2975047A (en) * 1956-11-07 1961-03-14 Siderurgie Fse Inst Rech Process for the continuous pre-refining of molten pig iron
FR1386390A (en) * 1963-12-06 1965-01-22 Apparatus and method for facilitating and improving the manufacture of interrupted effervescence steel ingots
US3380727A (en) * 1965-01-09 1968-04-30 Hoerder Huettenunion Ag Devices for introducing gas into a metal melt

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US67350A (en) * 1867-07-30 Of glasgow
US1836196A (en) * 1928-10-24 1931-12-15 Walter O Snelling Method of treating molten materials
US2540231A (en) * 1948-08-24 1951-02-06 Republic Steel Corp Tuyere
US2871008A (en) * 1950-11-02 1959-01-27 Air Liquide Apparatus for gas flushing of molten metal
US2874038A (en) * 1955-09-19 1959-02-17 Ruhenbeck Adalbert Method of treating molten metals
US2975047A (en) * 1956-11-07 1961-03-14 Siderurgie Fse Inst Rech Process for the continuous pre-refining of molten pig iron
FR1386390A (en) * 1963-12-06 1965-01-22 Apparatus and method for facilitating and improving the manufacture of interrupted effervescence steel ingots
US3380727A (en) * 1965-01-09 1968-04-30 Hoerder Huettenunion Ag Devices for introducing gas into a metal melt

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3758081A (en) * 1970-04-02 1973-09-11 Rhone Progil Quench chamber for hot gases
EP0006453A1 (en) * 1978-06-22 1980-01-09 Messer Griesheim Gmbh Process for increasing the lifetime of flush gas lances with porous lance heads made of graphite and inertion cage used therefor
US4741515A (en) * 1986-10-20 1988-05-03 Bethlehem Steel Corporation Apparatus for introducing gas into a metallurgical vessel
EP0333586A1 (en) * 1988-03-15 1989-09-20 Alusuisse-Lonza France Apparatus for removing gaseous and solid impurities from a molten product contained in a vessel
FR2628756A1 (en) * 1988-03-15 1989-09-22 Alusuisse France Sa DEVICE FOR REMOVING IMPURITIES PRESENT IN GAS AND SOLID FORM IN A LIQUID PRODUCT CONTAINED IN A RESERVOIR

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