US3509401A

US3509401A - Encapsulated electroluminescent device

Info

Publication number: US3509401A
Application number: US663062A
Authority: US
Inventors: James A Callely Jr; Wallace T Macdonald
Original assignee: Sylvania Electric Products Inc
Current assignee: GTE Sylvania Inc
Priority date: 1967-08-24
Filing date: 1967-08-24
Publication date: 1970-04-28
Anticipated expiration: 1987-04-28

Description

April 28, 1970 J. A. CALLEY, JR ET Al. 3,509,401

ENCAPSULATED ELECTROLUMINESCENT DEVICE Filed Aug'. 24. 1967 3 JAMES A. CALLE LY JR.

l5 WALLACE T. MacDoNALD FIG. 3 mvENToRs lsu-m ATTORNEY United States Patent O 3,509,401 ENCAPSULATED ELECTROLUMINESCENT DEVICE James A. Callely, Jr., and Wallace T. MacDonald, Beverly, Mass., assignors to Sylvania Electric Products Inc., a corporation of Delaware Filed Aug. 24, 1967, Ser. No. 663,062 Int. 'Cl. H01j 1/62, 63/04 U.S. Cl. 313-108 5 Claims ABSTRACT OF THE DISCLOSURE BACKGROUND OF THE INVENTION Field of the invention This invention pertains to electroluminescent devices wherein a phosphor is disposed between two electrodes and emits light when a suitable diterence of potential, generally of a varying nature, is applied between the electrodes. The invention particularly relates to improvements in the electrical connection and hermetic encapsulation of exible electroluminescent lamps.

Description of the prior art Electroluminescent lamps are generally classified as either rigid or flexible. The rigid lamps usually have at least one electrode made of sheet metal thicker than about 0.020 inch and have the phosphor generally embedded in a dielectric of glass and ceramic. An example of such a lamp is shown in U.S. Patent 3,153,167, issued Oct. 13, 1964 to Rulon et al. In flexible lamps, the dielectric is usually a resin or plastic and, when one of the electrodes is fabricated from sheet metal, the metal is less than about 0.020 inch thick, for ilexibility. An example is shown in U.S. Patent 3,161,797, issued Dec. 15, 1964 to Butler et al.

For many applications, such as outdoor use, it is desirable to encapsulate or hermetically seal the lamp in an envelope to prevent humidity penetration, which can deteriorate the luminescent appearance and emission. When a llexible lamp is hermetically sealed in a plastic envelope, the lead-in conductors generally protrude from the edges of the device, as shown in 3,161,797, supra, or in U.S. Patent 3,197,664, issued July 27, 1965 to Sentementes et al. The reason for this type of construction is that a reliable electrical connection between the liat lead-in conductor and the flat electrode can be readily established. Also, the at lead-in conductors, which protrude through the edge of the plastic envelope, are eminently suitable for satisfactory hermetic encapsulation.

However, in an increasing number of applications of llexible hermetically-sealed electroluminescent lamps, it is desirable to have the lead-in conductors substantially perpendicular t the surface of the lamp. This type of construction reduces the amount of space necessary to mount the lamp and simplies the electrical connection to an external power source; for example, the lead-in conductors can be short rigid terminals which can be plugged into a socket.

3,509,401 Patented Apr. 28, 1970 SUMMARY 0F THE INVENTION We have invented a flexible electroluminescent lamp which has improved electrical contacts for better reliability and has improved hermetic encapsulation for increased resistance to the elects of humidity. A feature of the invention is that electrical terminals protruding perpendicularly from one surface of the lamp permit the lamp to be plugged into a suitable socket. The terminals are held securely by plastic anges which are fused to the encapsulating envelope, thereby effectively hermetically sealing the terminals and preventing humidity penetration into the lamp. Electrical contact from the electrode to the terminal is improved by the use of a resilient electrically conductive rubber insert, maintained under compression by the encapsulating plastic. Thus, flexing or slight bending of the terminals does not interrupt the electrical connection from the terminal to the electrode.

BRIEF DESCRIPTION OF THE DRAWING FIGURE 1 is a perspective view, partly in section, of a lamp in accordance with this invention.

FIGURE 2 is a cross-sectional view, along the line 2-2, of the lamp of FIGURE 1, showing one terminal and flange prior to insertion.

FIGURE 3 is an enlarged elevational view of an electrical terminal of the lamp.

DESCRIPTION OF THE PREFERRED EMBODIMENT Referring to the drawings, electrode 1 is made of an electrically conductive material, usually sheet metal less than about 0.020 inch thick for flexibility, and preferably of aluminum. Aluminum provides a good base for the subsequent layers to be applied, is readily available in rolls for semi-continuous production and can be obtained in various thicknesses and widths with electrically clean surfaces. Dielectric 2 is an insulating layer on electrode 1 and is usually a high dielectric constant material, about 1 or 2 mils thick, which provides a good base for the light-emitting phosphor layer 3. Dielectric 2 and phosphor 3 can be the materials such as shown in previously mentioned Patent 3,197,664, that is, barium-strontium titanate dispersed in cyanoethylcellulose and copperactivated, zinc sulfide phosphor dispersed in cyanoethylcellulose, respectively. Light transmitting electrode 4 is usually made of electrically conductive glass paper or fibers, about l or 2 mils thick, and is disposed on phosphor layer 3. To prevent the possibility of electrode 4 short circuiting to electrode 1, a small margin is left around the periphery of electrode 4, as shown in FIGURE 3.

In order for

terminals

7 and 8 to protrude from the same surface of the lamp, that is, from the surface of electrode 1 as shown in FIGURE 1, it is necessary for a conductor to contact electrode 4, extend to the surface of electrode 1 and be insulated from the latter. A partially insulated flat metal ribbon 5, preferably of copper, is used for this purpose. One side of ribbon 5, excepting that portion which is in electrical contact with electrode 4, is electrically insulated by bonding a thin plastic lm 6, such as cellulose acetate or Mylar, to the ribbon. The uninsulated portion is then placed on electrode 4, or on a flat conductor thereon, and taped in place to establish electrical Contact between ribbon 5 and electrode 4. The remainder of ribbon 5 is then bent around the edges of electrode 4, phosphor 3, dielectric 2 and electrode 1 and onto the surface of electrode 1 so that insulation 6 prevents ribbon 5 from short circuiting to electrode 1. Preferably, insulation 6 also overlaps slightly on electrode 4 to further provide against a short circuit. To insure good electrical contact between ribbon S and electrode 4, the

uninsulated portion of ribbon can extend almost the entire length of electrode 4 in contact therewith. To insure satisfactory contact between ribbon 5 and terminal 7, that portion of ribbon 5 which can contact disk portion 9 of terminal 7 has an increased area, substantially circular and slightly greater than the diameter of disk 9. The greater diameter of the insulated circular portion of ribbon 5 also prevents any possibility of disk 9, when properly positioned against ribbon 5, from overlapping and short circuiting to electrode 1. Y

The entire device is then encapsulated between two

overlapping sheets

13 and 14 of thermoplastic material which flow under heat and pressure and fuse together along the margins. The material selected must be reasonably tough and stable, in addition to being light-transmitting and fairly flexible. Examples of such materials are polyethylene, polycarbonate, chlorotrifluoroethylene and polystyrene. A preferred material is polycarbonate film about or 30 mils thick. The encapsulation inhibits the penetration of water vapor into the device, which, as previously mentioned, deteriorates the lamp. It also physically protects the lamp from, for example, abrasion or accidental scratching, which might remove parts of the various layers. Additionally, in our invention, the encapsulation holds and secures

flanges

19 and 20, in addition to

terminals

7 and 8, and aids in making electrical contact, as will be explained later, to disks 9 and 10'. For even greater protection, the device may be encapsulated in two different materials, selected for their particular superior properties. As illustrated in FIGURES 2 and 3, the device can be first encapsulated in two

sheets

15 and 16 of a thermoplastic material having superior moisture vapor transmission properties, such as chlorotrifluoroethylene, and then in two

sheets

13 and 14 of a thermoplastic material such as the previously-mentioned polycarbonate, selected for its toughness and fusibility, the latter in order to provide forthe subsequent hermetic seal to

flanges

19 and 20.

Two holes 17 and 18 are then drilled through

plastic sheets

14 and 16 to expose the metallic surface of ribbon 5 and electrode 1. The holes must be drilled with care in order not to damage or drill through the metal substrates and, preferably, a flat ended drill, such as an end mill, is used. Alternatively, holes 17 and 18 may be pre-punched in sheets 114 and 16 prior to the encapsulation, but suitable removable inserts must then be positioned in the holes during the heat-sealing operation to prevent holes 17 and 18 from distorting. Holes 17 and 18 are of the proper diameter to accommodate disks 9 and 10 of

terminals

7 and 8. Also, hole 17 is centrally located on, and is of smaller diameter than, the circular end of ribbon 5.

Metal terminals

7 and 8 comprise cylindrical

hollow pins

11 and 12, which are closed at one end and centrally fastened at the opposite end to disks 9 and 10. Holes through the centers of disks 9 and 10 are in communication with the bore of

pins

11 and 12. Resilient

cylindrical inserts

21 and 22, preferably made of electrically conductive rubber, are inserted through the holes of disks 9 and 10 completely into the bore of

pins

11 and 12 up to the closed ends, with a short length protruding beyond disks 9 and 10.

Circular flanges

19 and 20, made of the same material as

sheets

13 and 14, are then positioned on

terminals

7 and 8. Axial holes through

flanges

19 and 20 are of the proper size to provide a tight fit when the

pins

11 and 12 are inserted therethrough. The length of

flanges

19 and 20 is shorter than the length of the

pins

11 and 12 so that the latter protrude when

flanges

19 and 20 are flush against disks 9 and 10.

Flanges

19 and 20 are of greater diameter than holes 17 and 18 in order to overlap sheet 14 and to provide a satisfactory hermetic seal when subsequently fused therewith.

Terminals

7 and 8 with

flanges

11 and 12 thereon, are then centrally positioned in holes 17 and 1S and the er1- tire device is placed into a suitable press, which is designed to exert heat and pressure on

pins

11 and 12,

flanges

19 and 20 and the underlying and immediately adjacent area of sheet 14. During sealing, the protruding ends of rubber inserts 21 and 22 are compressed between ribbon 5 and disk 9 and between electrode 1 and disk 10, respectively. After the

flanges

19 and 20 have completely fused to sheet 14 to form a hermetic seal, the finished lamp is removed from the press. The jointure of the flanges with sheet 14 maintains compression on rubber inserts 21 and 22 for substantially the life of the lamp, which provides improved electrical continuity between the terminals and electrodes when'the terminals are flexed or when the lamp undergoes vibration or shock. The design and construction of

terminals

7 and 8 also permit simple electrical connection of the lamp to an external power source merely by plugging it into a suitable socket.

In a specific example of a lamp about 3 inches square, designed for volt A.C. operation, electrode 1 was made of 5 mil thick aluminum. Dielectric 2 was 1 mil thick and was deposited on electrode 1 from a solvent dispersion of cyanoethylcellulose and powdered barium titanate. After drying, phosphor layer 3 was next deposited from a solvent dispersion of cyanoethylcellulose and powdered copper-activated Zinc sulphide to a dry film thickness of 2 mils. Electrode 4 comprised a commercially available micro-fiber glass paper 1 mil thick, made conductive by dipping into a solution of indium basic trifluoroacetate and stannic chloride dissolved in ethylene propyl monoethyl ether acetate, drying and then baking at an elevated temperature. It was fused to phosphor 3 by heat sealing with a thin film of nylon and, in order to prevent short circuiting to electrode 1, a small margin was left around the periphery of electrode 4.

Ribbon 5 was made of 5 mil thick copper 5732 inch wide, with an overall length of 5/8 inch and a diameter at its circular end of 5%16 inch. Except for Vs inch at its narrow end, all of one side was insulated by adhesively bonding 2 mil Mylar to the ribbon. A self-sticking adhesive coating was then applied to the Mylar. Ribbon 5 was then bent, as previously mentioned, around one end near a corner of the device, with the 1A; inch bare end in electrical contact with a strip of 5 mil copper, about 21/2 inches long and 3/32 inch wide, which was taped to the surface of, and in electrical contact with, electrode 4 near an edge.

The device was then heat sealed under pressure between

sheets

15 and 16, which were made of chlorotrifluoroethylene film, 9 mils thick, the edges of which extended 1/16 inch beyond the periphery of electrode 1. In the same manner, the device was then encapsulated between

sheets

13 and 14, made of polycarbonate film, 30 mils thick, and which extended beyond

sheets

13 and 14 about 1/16 inch. The polycarbonate film fused at a lower temperature than the chlorotrifluoroethylene, about 350 F. versus 425 F. respectively, and thus

sheets

15 and 16 were not distorted by the subsequent fusion of

sheets

13 and 14.

Holes

17 and 18, 7/32 inch in diameter, were carefully drilled through

sheets

14 and 16 with an end mill, to expose electrode 1 and the central part of the circular end ribbon 5.

Metal terminals

7 and 8 comprised disk portions 9 and 10, 0.210 inch diameter by 1/32 inch thick, centrally fastened to partially

hollow pins

11 and 12 as previously described, which were 1A inch long by 0.050 inch in diameter. Conductive rubber inserts, 21 and 22, i716 inch long by 1/32 inch diameter, were inserted into the bore of the pins through holes at the center of disks 9 and 10 so that 1/32 inch of the rubber inserts protruded beyond the face of the disks at complete insertion.

Circular flanges

19 and 20 were made of polycarbonate plastic and had a 0.050 inch diameter hole through the center which resulted in a tight tit around pins 11 and 12 when

terminals

7 and 8 were inserted on

flanges

19 and 20. The face of

flanges

19 and 20, which were flush against disks 9 and 10, had a diameter of "716 inch, thereby overlapping the disks in a heat sealing press. During heat sealing, the 176,2 inch p protruding portions of rubber inserts 21 and 22 were compressed and the 7/64 inch overlapping portionsof flanges 9 and 10 were fused to the underlying and immediately adjacent area of sheet 14. After fusion, pressure was maintained on the terminals and flanges until the polycarbonate had cooled below its Working temperature. On removal from the press, the rubber inserts are maintained in cornpression by the jointure of the flanges to encapsulating sheet 14 which is firmly sealed around the entire device. The finished lamp was then energized by plugging

pins

11 and 12 into a suitable 110 volt A.C. receptacle.

Solvent fusion may be substituted for the heat sealing of the flanges to the other encapsulating layer 14 by, for example, softening the areas to be joined by the application of a suitable solvent such as methylene chloride, in the case of polycarbonate film. A similar pressure, as was applied during heat sealing, is applied and maintained until all traces of the solvent have evaporated, and the plastic has hardened again.

In the specific example mentioned, rubber inserts 21 and 22 had an electrical resistivity of 7 ohm-centimeters. However since electroluminescent lamps commonly draw a current of only a few milliamperes, the resistivity of the rubber inserts was very small compared to the resistivity of the lamp itself. Therefore, resistivities of the inserts in the order of a hundred or -a thousandL ohmcentimeters would still be satisfactory in our invention. The inserts must also be resilient enough that they will not overcome the compressive force maintained bythe jointure of flanges 9 and 10 to sheet 14. Rubber having a Shore A Hardness of 65 had sufficient resiliency for our invention. Although it is possible for the insert to be compressed sufficiently to permit contact between, say, ribbon 5 and substantially the entire face of disk 9, there can be a relaxation of the encapsulating plastic upon removal from the press, which will permit a gap of several mils to develop therebetween. If the inserts were not present in such a case, the contact might be intermittent and unreliable. In addition, if the terminal deviated slightly from the perpendicular, only one point at the periphery of disk 9 or 10 would be in contact, which might also cause an intermittent connection |whenever the terminal was slightly flexed, as could occur during insertion of the lamp into a socket. It is also possible that a particle of dirt or plastic at this one point of the peripheral contact could prevent electrical continuity.

It is also within the contemplation of this invention that the conductive rubber insert need not be cylindrical nor inserted into the bore of the terminal pin, but could be flat or any other convenient shape, and positioned entirely between the llat portions of the terminals and the adjacent electrode or conductor. In such a case, its resiliency must still be such as to not completely overcome its compression from the pressure sealingoperation.

As used in this specification, the term rubber is not confined only to the commonly accepted natural and synthetic rubbers, but has a broader definition as in Websters Dictionary: something made of o-r resembling rubber. This includes, for example, elastomeric resins and plastics or other materials having rubber-like properties of flexibility, resiliency and elasticity.

It is apparent that modifications and changes can be made within the spirit and scope of the instant invention, but it is our intention to be limited only by the appended claims.

We claim:

1. An electroluminescent lamp comprising:

two superposed electrodes, at least one of which is light transmitting;

a layer of electroluminescent phosphor interposed between said electrodes;

a llat U-shaped electrical connector insulatively disposed on the first of said electrodes, extending beyond and around the edges of said electrodes and said phosphor layer, and in electrical contact with the second of said electrodes;

two spaced apart metal terminals disposed on one surface of said lamp, each of said terminals comprising a cylindrical hollow pin closed at one end and a disc centrally attached to said pin at the other end thereof;

and an electrically conductive rubber insert disposed within each of said hollow pins, the insert in the first of said terminals being in compressive electrical engagement with the first of said electrodes, and the insert in the second of said terminals being in compressive electrical engagement with said metal connector.

2. The lamp of claim 1 comprising, in addition, a transparent plastic envelope hermetically encapsulating said lamp, said terminals protruding through said envelope.

3. The lamp of claim 2 wherein said rubber inserts are maintained in compression by said encapsulating envelope.

4. An electroluminescent lamp comprising:

two superposed electrodes, at least one of which is light transmitting;

a layer of electroluminescent phosphor interposed between said electrodes;

two spaced apart metal terminals disposed on one surface of said lamp, each of said terminals comprising a hollow cylindrical pin and a disc centrally attached thereto; l

means electrically connecting one of said terminals with one of said electrodes and the other of said terminals with the other said electrodes, said means including an electrically conductive rubber insert disposed within each of said hollow pins;

a plastic flange sealabfly disposed about each of said pins and abutting the corresponding disc;

and a transparent plastic envelope hermetically encapsulating said lamp, said envelope being sealed to said plastic flanges.

5. The lamp of claim 4 wherein said plastic envelope comprises an inner layer and an outer layer of transparent thermoplastic materials, the material of said outer layer having a lower sealing temperature than that of said inner layer, and said plastic flanges are sealed to said outer layer.

References Cited UNITED STATES PATENTS 5/1964 Knochel et al. 7/ 1967 Braeutigam et al.

U.S. Cl. X.R. 315-169