US3498886A - Flash distillation partitioned tower - Google Patents

Flash distillation partitioned tower Download PDF

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US3498886A
US3498886A US545197A US3498886DA US3498886A US 3498886 A US3498886 A US 3498886A US 545197 A US545197 A US 545197A US 3498886D A US3498886D A US 3498886DA US 3498886 A US3498886 A US 3498886A
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tower
liquid
columnar
brine
conduit
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US545197A
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Peter Thomas Walker
Ivan Henry Newson
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VWS Westgarth Ltd
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Weir Westgarth Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/10Treatment of water, waste water, or sewage by heating by distillation or evaporation by direct contact with a particulate solid or with a fluid, as a heat transfer medium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/14Evaporating with heated gases or vapours or liquids in contact with the liquid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/06Flash distillation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S159/00Concentrating evaporators
    • Y10S159/33Two liquids, one a heat carrier
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S203/00Distillation: processes, separatory
    • Y10S203/11Batch distillation

Definitions

  • a flash distillation process comprising the steps of heating raw feed liquid, passing the same into the lower portion of a first undivided vertical section of a tower maintained at such pressure that a mixture of vapour and liquid is formed in that section of the tower, Withdrawing liquid from the upper part of that section of such tower, effecting condensation of thevapour in a second vertical section of such tower alongside the first sectionand to which second section access by the unvapourised liquid in the first section is prevented, and removing a liquid condensate from the lower part of such second section.
  • This invention relates to flash distillation processes and apparatus, particularly but not exclusively for the desalination of brine.
  • Fash distillation is one practical method of effecting desalination of sea water in order, for example, to provide fresh water of drinking quality or suitable for agricultural use.
  • a conventional flash distillation plant the heated brine is caused to flow through a series of flashing chambers in each of which a proportion is converted into steam and is condensed within the chamber in order to provide the fresh water.
  • This condensation i nor mally effected upon condenser tubes and it can be shown from theoretical considerations that the temperature drop across these tubes must inevitably result in a loss of efficiency.
  • these condensers are cooled by brine and in consequence some form of scaling is almost inevitable within the condenser tubes, thus increasing the loss of efficiency.
  • a flash distillation process comprises the steps of heating raw feed liquid, passing the same into the lower portion of a tower maintained at such pressure that a mixture of vapour and liquid is formed in the tower, Withdrawing liquid from the upper part of such tower, effecting condensation of the vapour in a section of such tower to which section access by the unvapourished liquid is prevented, and removing a liquid condensate from the lower part of such condensation section.
  • the condensate will represent the fresh water product.
  • flash distillation plant comprising a tower divided by a wall into side-by-side sections, such wall allowing vapour to pass therethrough but preventing the passage of liquid, one such section forming a foaming section and having raw liquid inlet and outlet means at its lower and upper parts respectively, and the other such section forming a condensation section and having cooling liquid inlet means at its upper end and condensate outlet means at its lower end.
  • the cooling liquid used to effect condensation of the vapour which is steam in the case of desalination, is preferably such an oil and the liquid condensate is therefore an oil/water mixture.
  • the condensate may be passed to an oil/water separator and the product fresh water recovered.
  • the oil may be heated externally by any suitable means, e.g. process steam, and passed to a liquid/ liquid contactor to heat the raw feed liquid passing to the base of the foaming section of the tower.
  • FIGURE 1 is a diagrammatic flow sheet
  • FIGURE 2 is a detail of a wall member in the tower of FIGURE 1.
  • raw sea water enters by a conduit 1 and is passed to a tube and shell heat exchanger 2 where it is heated by waste brine entering through conduit 3 and discharged to waste through conduit 4.
  • the heated brine leaves the exchanger 2 through a conduit 5 and is passed to a further tube and shell heat exchanger 6 where it is heated by fresh water entering through conduit 7, and leaving, as product, through conduit 8.
  • the heated brine leaves the exchanger 6 through a conduit 9 and is passed by a pump 10 to a conduit 11 and thence to a liquid/ liquid contactor 12.
  • the brine is heated to the process temperature in this contactor 12 by direct contact with heated oil and leaves through a conduit 13 which conveys it to a brine inlet at the base of a tower 14, the brine entering only the lefthand or columnar flash evaporation chamber 15 of the tower.
  • this columnar flash evaporation chamber 15 has no internal divisions but is vertically continuous throughout the height of the tower.
  • the pressure at the base of the columnar chamber 15 may be of the order of atmospheric so that the brine may be at a temperature of the order of 200 F. whilst the pressure at the top of the columnar chamber 15 may be of the order of 1 p.s.i.a. Consequently violent foaming and steam formation will take place in the columnar chamber 15 and the liquid brine remaining is removed through the top outlet conduit 3.
  • the steam generated in the columnar flash evaporation chamber 15 passes laterally through an apertured vertical partition wall 16 and into a columnar condensing chamber 17 of the tower 14, the liquid brine being prevented from passing through the Wall '16.
  • the columnar condensing chamber 17 contains a packing (not shown) and is provided with plates 18 that divide it into a succession of intercommunicating condensing stages disposed one below another down the tower.
  • the apertures in the partition wall 16 are distributed throughout the height of the tower so that vapor passes through from the columnar flash evaporation chamber 15 into all stages of the columnar condensing chamber 17 simultaneously.
  • Condensation is effected by spraying cool oil into the uppermost stage of the columnar condensing chamber 17 through a spray head 19. A mixture of fresh water and oil therefore passes down the columnar condensing chamber 17 from stage to stage and is withdrawn through a conduit 20 to be passed to an oil/Water separator 21 from which the fresh water-leaves through the conduit 7.
  • the oil leaves the separator 21 through a conduit 22 and is passed by a pump 23 to a further tube-and-shell heat exchanger 24 which is heated by steam entering and leaving through conduits 25 and 26.
  • the hot oil then goes to the liquid/liquid contactor 12 via a conduit '27 and leaves via a conduit 28 to be passed to the spray head 19.
  • each entry point for steam includes an aperture 30 and a baflle plate 31 against which the steam/ water mixture impinges.
  • the steam passes upwardly through a mesh strainer 32 which is protected by a baffle 33.
  • the brine falling from the plate 31 and strainer 32 is collected by a liquid pocket 34 and returned to the columnar flash evaporation chamber 15 through a further aperture in the wall 16.
  • vapour entry units as shown in FIGURE 2 will be provided as necessary.
  • Flash distillation plant for the desalination of sea water or brine comprising a tower, a centrally disposed partition wall within the tower extending from top to bottom thereof, a columnar flash evaporation chamber within the tower on one side only of said partition wall which columnar chamber has no internal divisions but is vertically continuous throughout the height of the tower, a raw liquid feed inlet for brine heated to about 200 F.
  • said liquidvapor separator means comprise a first set of apertures in said partition wall through which liquid-vapor mixture from the columnar flash evaporation chamber passes, compartments on the condensing chamber side of said wall receiving said liquid-vapor mixture passing through said first set of apertures and each containing a baffle plate on which the liquid-vapor mixture impinges, vapor outlets at the tops of said compartments releasing vapor only into said condensing stages, and a second set of apertures in said wall through which liquid passes back from the bottoms of said compartments into said columnar flash evap. oration chamber.
  • said spray means receives, as cooling liquid, the oil that has passed through said liquid-liquid contactor, and further comprising a separator receiving condensate-oil mixture from said condensatecooling liquid mixture outlet, a heat exchanger receiving separated oil from said separator and reheating it by heat from an external source, and conduit means recirculating the reheated oil from said heat exchanger to said contactor.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)

Description

March 3, 1970 P; 'r. WALKER E L 3,493,836
FLASH msnnmnou PABTITIONED TOWER Filed April 5, 1966 SECTION 1 LOW PRESSURE FLASH SECTION 25 MAKE-JP 3- 2 7 I 6 77 FEED) 7H Fn SEA f-fi 8% WATER WASTE FRE H WATER BR/NE PRUDUC T E F/G.2. g i 32 34 WWI-ff:
United States Patent 3,498,886 FLASH DISTILLATION PARTITIONED TOWER Peter Thomas Walker, Reading, and Ivan Henry Newson, Chilton, England, assignors to Weir Westgarth Limited, Glasgow, England, a British company Filed Apr. 5, 1966, Ser. No. 545,197 Claims priority, application Great Britain, Apr. 5, 1965, 14,447/65 Int. Cl. Bold 3/06 US. Cl. 202-167 3 Claims ABSTRACT OF THE DISCLOSURE A flash distillation process comprising the steps of heating raw feed liquid, passing the same into the lower portion of a first undivided vertical section of a tower maintained at such pressure that a mixture of vapour and liquid is formed in that section of the tower, Withdrawing liquid from the upper part of that section of such tower, effecting condensation of thevapour in a second vertical section of such tower alongside the first sectionand to which second section access by the unvapourised liquid in the first section is prevented, and removing a liquid condensate from the lower part of such second section.
DESCRIPTION OF INVENTION This invention relates to flash distillation processes and apparatus, particularly but not exclusively for the desalination of brine.
Fash distillation is one practical method of effecting desalination of sea water in order, for example, to provide fresh water of drinking quality or suitable for agricultural use. In a conventional flash distillation plant the heated brine is caused to flow through a series of flashing chambers in each of which a proportion is converted into steam and is condensed within the chamber in order to provide the fresh water. This condensation i nor mally effected upon condenser tubes and it can be shown from theoretical considerations that the temperature drop across these tubes must inevitably result in a loss of efficiency. Furthermore, these condensers are cooled by brine and in consequence some form of scaling is almost inevitable within the condenser tubes, thus increasing the loss of efficiency.
It is an object of the invention to provide a new or improved flash distillation process with certain advantages over the conventional process.
According to the present invention a flash distillation process comprises the steps of heating raw feed liquid, passing the same into the lower portion of a tower maintained at such pressure that a mixture of vapour and liquid is formed in the tower, Withdrawing liquid from the upper part of such tower, effecting condensation of the vapour in a section of such tower to which section access by the unvapourished liquid is prevented, and removing a liquid condensate from the lower part of such condensation section.
In the case of a desalination process the condensate will represent the fresh water product.
According to a further aspect of the invention, there is provided flash distillation plant comprising a tower divided by a wall into side-by-side sections, such wall allowing vapour to pass therethrough but preventing the passage of liquid, one such section forming a foaming section and having raw liquid inlet and outlet means at its lower and upper parts respectively, and the other such section forming a condensation section and having cooling liquid inlet means at its upper end and condensate outlet means at its lower end.
In our co-pending patent application No. 14450/65 we have disclosed an invention which resides primarily in the use of a water-insoluble oil as a heat transfer medium in desalination processes and we prefer to make use of such an oil with the present technique. Accordingly, the cooling liquid used to effect condensation of the vapour, which is steam in the case of desalination, is preferably such an oil and the liquid condensate is therefore an oil/water mixture.
After leaving the tower the condensate may be passed to an oil/water separator and the product fresh water recovered. The oil may be heated externally by any suitable means, e.g. process steam, and passed to a liquid/ liquid contactor to heat the raw feed liquid passing to the base of the foaming section of the tower.
In order that the invention may more readily be understood, one embodiment of the same will now be described with reference to the accompanying drawings, wherein:
FIGURE 1 is a diagrammatic flow sheet, and
FIGURE 2 is a detail of a wall member in the tower of FIGURE 1.
Referring now to the drawings and to FIGURE 1 in particular, raw sea water enters by a conduit 1 and is passed to a tube and shell heat exchanger 2 where it is heated by waste brine entering through conduit 3 and discharged to waste through conduit 4. The heated brine leaves the exchanger 2 through a conduit 5 and is passed to a further tube and shell heat exchanger 6 where it is heated by fresh water entering through conduit 7, and leaving, as product, through conduit 8. The heated brine leaves the exchanger 6 through a conduit 9 and is passed by a pump 10 to a conduit 11 and thence to a liquid/ liquid contactor 12.
The brine is heated to the process temperature in this contactor 12 by direct contact with heated oil and leaves through a conduit 13 which conveys it to a brine inlet at the base of a tower 14, the brine entering only the lefthand or columnar flash evaporation chamber 15 of the tower. As can be seen in FIGURE 1, this columnar flash evaporation chamber 15 has no internal divisions but is vertically continuous throughout the height of the tower. The pressure at the base of the columnar chamber 15 may be of the order of atmospheric so that the brine may be at a temperature of the order of 200 F. whilst the pressure at the top of the columnar chamber 15 may be of the order of 1 p.s.i.a. Consequently violent foaming and steam formation will take place in the columnar chamber 15 and the liquid brine remaining is removed through the top outlet conduit 3.
The steam generated in the columnar flash evaporation chamber 15 passes laterally through an apertured vertical partition wall 16 and into a columnar condensing chamber 17 of the tower 14, the liquid brine being prevented from passing through the Wall '16. The columnar condensing chamber 17 contains a packing (not shown) and is provided with plates 18 that divide it into a succession of intercommunicating condensing stages disposed one below another down the tower. The apertures in the partition wall 16 are distributed throughout the height of the tower so that vapor passes through from the columnar flash evaporation chamber 15 into all stages of the columnar condensing chamber 17 simultaneously. Condensation is effected by spraying cool oil into the uppermost stage of the columnar condensing chamber 17 through a spray head 19. A mixture of fresh water and oil therefore passes down the columnar condensing chamber 17 from stage to stage and is withdrawn through a conduit 20 to be passed to an oil/Water separator 21 from which the fresh water-leaves through the conduit 7.
The oil leaves the separator 21 through a conduit 22 and is passed by a pump 23 to a further tube-and-shell heat exchanger 24 which is heated by steam entering and leaving through conduits 25 and 26. The hot oil then goes to the liquid/liquid contactor 12 via a conduit '27 and leaves via a conduit 28 to be passed to the spray head 19.
Clearly the flow sheet is diagrammatic and savings may be effected in known ways, e.g. by recirculation.
The construction of the wall 16 is illustrated in FIG- URE 2, and it will be seen that each entry point for steam includes an aperture 30 and a baflle plate 31 against which the steam/ water mixture impinges. The steam passes upwardly through a mesh strainer 32 which is protected by a baffle 33. The brine falling from the plate 31 and strainer 32 is collected by a liquid pocket 34 and returned to the columnar flash evaporation chamber 15 through a further aperture in the wall 16. As many vapour entry units as shown in FIGURE 2 will be provided as necessary.
It will be apparent that advantages reside in the arrangement described in that the throat and weir construction of normal flash chambers is avoided, whilst direct brine heating and steam cooling avoid the use of heat exchanger tubes.
We claim:
1. Flash distillation plant for the desalination of sea water or brine comprising a tower, a centrally disposed partition wall within the tower extending from top to bottom thereof, a columnar flash evaporation chamber within the tower on one side only of said partition wall which columnar chamber has no internal divisions but is vertically continuous throughout the height of the tower, a raw liquid feed inlet for brine heated to about 200 F. which is introduced at the bottom of said columnar flash evaporation chamber, the pressure within said columnar flash evaporation chamber decreasing progressively up the tower from said inlet to said outlet whereby the brine is flashed into steam, a columnar condensing chamber within the tower on the opposite side of said partition wall and likewise extending from top to bottom of the tower but divided into a succession of intercommunicating condensing stages disposed one below another down the tower, liquid-vapor separator means associated with said partition wall comprising apertures distributed throughout the height of the partition wall in said tower said separator means allowing said steam to pass laterally through from the columnar flash evaporation chamber into all the stages of the columnar condensing chamber simultaneously but preventing liquid from entering said condensing stages, cooling liquid inlet spray 4m means at the top of said columnar condensing chamber admitting a spray of cooling liquid comprising water-insoluble oil to the uppermost of said condensing stages, and
a condensate cooling liquid mixture outlet means at the bottom of said condensing chamber for withdrawing condensate-cooling liquid mixture from the lowermost of said condensing stages. I
2. Plant according to claim 1, wherein said liquidvapor separator means comprise a first set of apertures in said partition wall through which liquid-vapor mixture from the columnar flash evaporation chamber passes, compartments on the condensing chamber side of said wall receiving said liquid-vapor mixture passing through said first set of apertures and each containing a baffle plate on which the liquid-vapor mixture impinges, vapor outlets at the tops of said compartments releasing vapor only into said condensing stages, and a second set of apertures in said wall through which liquid passes back from the bottoms of said compartments into said columnar flash evap. oration chamber. I l
.3. Plant according to claim 1, wherein said spray means receives, as cooling liquid, the oil that has passed through said liquid-liquid contactor, and further comprising a separator receiving condensate-oil mixture from said condensatecooling liquid mixture outlet, a heat exchanger receiving separated oil from said separator and reheating it by heat from an external source, and conduit means recirculating the reheated oil from said heat exchanger to said contactor.
References Cited UNITED STATES PATENTS 2,976,224 3/1961 Gilliland 20310 3,165,452 1/1965 Williams 2031 1 3,181,600 5/1965 Woodward et a1.
3,219,554 11/1965 Woodward 202-173 3,232,847 2/1966 Hoif 203-11 3,236,747 2/1966 Margilofl 20311 3,298,932 1/1967 Bauer 203-11 3,312,601 4/1967 Wilson et al. 20311 3,057,786 10/1962 Waddill.
WILB'UR L. BASCOMB, JR., Primary Examiner F. E. DRUMMOND, Assistant Examiner US. Cl. X.R. 202177, 185, 186, 197; 20311, 88,
US545197A 1965-04-05 1966-04-05 Flash distillation partitioned tower Expired - Lifetime US3498886A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3674652A (en) * 1969-08-14 1972-07-04 Aluminum Co Of America Method of water purification
US3970512A (en) * 1971-08-09 1976-07-20 Ismail Zulfugarovich Makinsky Falling film evaporator
DE2526499A1 (en) * 1975-06-13 1976-12-23 Linde Ag METHOD FOR TRANSFERRING HEAT FROM THE AMBIENT AIR TO A WORK EQUIPMENT
EP2322260A3 (en) * 2009-11-16 2011-08-31 H2O GmbH Separating assembly and method

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5230780A (en) * 1989-12-08 1993-07-27 Eltech Systems Corporation Electrolyzing halogen-containing solution in a membrane cell
GB2337210A (en) 1998-05-14 1999-11-17 Aqua Pure Ventures Inc Mechanical vapour recompression separation process

Citations (9)

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US2976224A (en) * 1958-01-22 1961-03-21 Exxon Research Engineering Co Vaporization by molten material
US3057786A (en) * 1959-04-27 1962-10-09 Phillips Petroleum Co Foam eliminating feed distributor
US3165452A (en) * 1959-06-15 1965-01-12 Submerged Comb Inc Submerged combustion and flash evaporation system and process
US3181600A (en) * 1961-01-24 1965-05-04 Fmc Corp Liquid to liquid heat exchange
US3219554A (en) * 1962-11-07 1965-11-23 Fmc Corp Flash distillation apparatus with direct contact heat exchange
US3232847A (en) * 1961-09-11 1966-02-01 Hoff Chemical Corp Distillation process employing direct contact heating and condensation
US3236747A (en) * 1962-02-21 1966-02-22 Halcon International Inc Process for separating volatile material from a liquid mixture by a series of vaporization stages
US3298932A (en) * 1962-04-25 1967-01-17 Lummus Co Distillation of a solute-solvent mixture in successively reduced pressure stages while in direct contact and concurrent flow with a heat transfer medium
US3312601A (en) * 1964-07-21 1967-04-04 Allis Chalmers Mfg Co Water immiscible liquid condenser in multistage flash distillation

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2976224A (en) * 1958-01-22 1961-03-21 Exxon Research Engineering Co Vaporization by molten material
US3057786A (en) * 1959-04-27 1962-10-09 Phillips Petroleum Co Foam eliminating feed distributor
US3165452A (en) * 1959-06-15 1965-01-12 Submerged Comb Inc Submerged combustion and flash evaporation system and process
US3181600A (en) * 1961-01-24 1965-05-04 Fmc Corp Liquid to liquid heat exchange
US3232847A (en) * 1961-09-11 1966-02-01 Hoff Chemical Corp Distillation process employing direct contact heating and condensation
US3236747A (en) * 1962-02-21 1966-02-22 Halcon International Inc Process for separating volatile material from a liquid mixture by a series of vaporization stages
US3298932A (en) * 1962-04-25 1967-01-17 Lummus Co Distillation of a solute-solvent mixture in successively reduced pressure stages while in direct contact and concurrent flow with a heat transfer medium
US3219554A (en) * 1962-11-07 1965-11-23 Fmc Corp Flash distillation apparatus with direct contact heat exchange
US3312601A (en) * 1964-07-21 1967-04-04 Allis Chalmers Mfg Co Water immiscible liquid condenser in multistage flash distillation

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3674652A (en) * 1969-08-14 1972-07-04 Aluminum Co Of America Method of water purification
US3970512A (en) * 1971-08-09 1976-07-20 Ismail Zulfugarovich Makinsky Falling film evaporator
DE2526499A1 (en) * 1975-06-13 1976-12-23 Linde Ag METHOD FOR TRANSFERRING HEAT FROM THE AMBIENT AIR TO A WORK EQUIPMENT
EP2322260A3 (en) * 2009-11-16 2011-08-31 H2O GmbH Separating assembly and method

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NL6604522A (en) 1966-10-06

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