US3485906A - Melt spinning elastic polypropylene monofilaments - Google Patents
Melt spinning elastic polypropylene monofilaments Download PDFInfo
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- US3485906A US3485906A US664774A US3485906DA US3485906A US 3485906 A US3485906 A US 3485906A US 664774 A US664774 A US 664774A US 3485906D A US3485906D A US 3485906DA US 3485906 A US3485906 A US 3485906A
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
- F16D7/00—Slip couplings, e.g. slipping on overload, for absorbing shock
- F16D7/04—Slip couplings, e.g. slipping on overload, for absorbing shock of the ratchet type
- F16D7/06—Slip couplings, e.g. slipping on overload, for absorbing shock of the ratchet type with intermediate balls or rollers
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- Elastic monofilament of bridged polypropylene can be prepared by extruding molten polypropylene containing a small amount of azido bridging agent into a-monofilament, subjecting the said monofilament to a melt draw down of from about 3:1 to about 9.5 :l, quenching the monofilament in an inert liquid less than /2 inch from the die and then heat treating the monofilament at a temperature between about 130 C. and about 155 C.
- the said elastic monofilament has a recovery of at least 85% after elongation up to 75%
- the present invention relates to elastic monofilament of bridged stereoregular polypropylene and to a process for the production of such monofilament.
- Monofilaments of stereoregular polypropylene are well known. While some of these filaments have been described as highly elastic, useful elastic monofilaments of stereoregular polypropylene, particularly in the higher denier range, have not been forthcoming and the problem of producing useful elastic monofilaments of such material have been fraught with difliculty.
- the process in accordance with this invention comprises extruding molten stereoregular polypropylene containing from about 0.02% to about 0.08% by weight of an azido bridging agent at a temperature between about 200 C. and about 290 C. in the form of a monofilament, subjecting the extruded filament to a melt draw down of from about 3:1 to about 9.511, quenching the filament in an inert liquid at a temperature of from about 30 C. to about 110 C.
- the elastic monofilaments prepared in accordance with this invention are useful for many purposes, as for example, in the manufacture of outdoor furniture Webbing, automobile seat covers, etc.
- the criterion for measuring the elastic properties of "ice the monofilament is its ability to return to its original length when it is relaxed after being subjected to an elongating stress. This property is referred to herein as tensile recovery or more simply as recovery. It is expressed as a percentage of the imposed elongation which is lost upon removal of the elongating force. Percent recovery (r) is calculated as Percent R 'X where L. represents the distance the sample was elongated, and I. represents the portion of that elongation which is retained upon release of the elongating stress. The parameter L may also be referred to as permanent set. The percentage of permanent set is equal to 100 minus percent recovery. It should be obvious that higher values of recovery, or conversely, lower values of permanent set indicate greater elastic properties.
- the process of the invention is illustrated in the attached drawing in which 1 designates an extruder adapted to extrude molden polymer 2 through a die 3.
- the numeral 4 represents a vessel containing a quenching liquid 5, e.g., water, in which is submerged an idler roll 6.
- Numerals 7 and 8 designate nip rolls which convey the monofilament through the quenching liquid
- 9 designates a heat treatment oven containing a series of idler rolls 10.
- 11 and 12 designate an additional set of nip rolls and 13 designates a wind up station.
- the molten polymer 2 is extruded in the form of a monofilament 14 into the inert liquid 5 in the quench tank 4.
- the monofilament is drawn through the quenching tank by the nip rolls 7 and 8 which are positively driven at a rate 3 to 9.5 times the linear rate of extrusion of the filament through the die.
- This increase in the linear speed of the monofilament causes stretching of the filament in its weakest section, i.e., the molten portion between the die and the inert liquid.
- the inert liquid in the quench tank through which the monofilament is drawn is maintained at a temperature sufiicient to solidify the filament.
- a satisfactory temperature is from about 30 C. to about C.
- the quenched monofilament is drawn from the tank and fed into the heat treatment oven 9 and around the idler rolls 10. In passing through this oven the monofilament is maintained at a temperature below its softening point.
- the finished monofilament is fed onto wind up station 13 through nip rolls 11 and 12.
- melt draw down is meant the reduction in thickness of the extruded monofilament while it is still in the liquid or molten state prior to quenching.
- Melt draw down ratio expresses the relationship between the cross-sectional area of the die opening to that of the monofilament.
- Melt draw down is commonly employed in the production of films and fibers from thermoplastic polymers for several reasons. For example, the melt draw down permits the use of a larger size die than can he used otherwise. This permits greater precision in die manufacture and results in correspondingly greater denier uniformity in the extruded monofilaments.
- the die opening used in the process of this invention will be from about 15 mils to about 50 mils resulting in monofilaments of from about 200 denier to about 1,200 denier.
- melt draw down is found to be vital to the formation of elastic filaments and as indicated above, the monofilament must be subjected to a draw down of at least about 3:1 in the molten state as it leaves the die.
- melt drawing the filament it is necessary to confine the drawing to a relatively small distance. If the draw down takes place over any sizeable distance, the resultant filament exhibits an unacceptable amount of denier variation.
- quench the filament to the solid state within a relatively short distance of the die. Since the filament will draw preferentially in the molten areas rapid quenching tends to isolate the draw area. To obtain the optimum in denier uniformity the monofilamentmust be quenched within /2 inch of the die.
- the quenching of the monofilament is effected by immersing the filament in a bath of cooling liquid, e.g., water, maintained at a temperature of from about 30 C. to about 110 C.
- a bath of cooling liquid e.g., water
- the monofilament which is formed by the extrusion, melt draw down and quenching operations discussed above has very little elasticity as it is taken from the quench bath.
- the elasticity is fully developed by heat treatment at a temperature in the range of from about 130 C. to about 155 C. for a minimum time of about 30 seconds. This can be accomplished very effectively on a continuous basis, as, for example, by the use of a heat treatment oven containing idler rolls through which the monofilament passes after leaving the quench bath. Obviously the more idler rolls the longer the period of time in the heat treatment oven.
- the azido bridging agents used in the process of this invention are exemplified by the sulfonazides and the azidoformates.
- the sulfonazides have the general formula R(SO N where R is an organic radical inert to reaction with polypropylene and x is an integer greater than 1.
- Exemplary sulfonazides are 1,5-pentane bis(sulfonazide), 1,10-decane bis(sulfonazide), 1,3-benzene bis(sulfonazide), 1- octyl-2,4-6-benzene tris (sulfonazide), 4,4-diphenylmethane bis(sulfonazide) 4,4-diphenyl ether bis(sulfonazide), 4,4 bis octadecyl biphenyl-3,5,3',5'-tetra(sulfonazide) 1,4-cyclohexane dimethyl -bis(sulfonazide), 4,4-diphenyl disulfide bis(sulfonazide), l,6-bis
- the azidoformates have the general structural formula:
- R is an organic radical inert to reaction with polypropylene and x is an integer from 2 to about 8.
- the azidoformates used are the alkylene azidoformates such as tetramethylene-bis-(azidoformate), pentamethylene-bis(azidoformate); the cyclic alkylene azidoformates such as 1,4-cyclohexanedimethyl-bis-(azidoformate); the aralkylene azidoformates such as cc,oz'pxylylene-bis(azidoformate); the aromatic azidoformates such as 2,2-isopropylidene-bis(p,p'-phenyl azidoformate); the azidoformate ethers such as 2,2-oxydiethyl-bis(azido formate), 2,2'-oxydipropyl-bis(azidoformate), 2,2'-ethylenedioxydiethyl-bis(
- azidoformate thioethers such as 2,2'-thiodiethyl-bis (azidoformate), 4,4-thiodibutyl-bis (azidoformate); etc. It will, of course, be obvious to those skilled in the art that still other azidoformates containing functional groups, which are inert to reaction with polypropylene, such as halogen, carboxyl groups, carbonyl groups, etc., are included in the above definition.
- a critical amount of bridging agent by present, i.e., the amount must be sufiicient to increase the melt viscosity of the polymer but insufficient to alter its solubility in perchlorethylene at C.
- This amount of bridging agent is provided by the addition of from about 0.02% to about 0.08% by weight of azido compound. When the amount of azido compound materially exceeds this range the polymer is insolubilized, cannot be extruded and does not exhibit the desired elastic properties. When the amount is below the range, little or no benefit is realized.
- the bridging reaction is initiated by heat.
- the temperature required depends somewhat on the particular azido compound employed but, in general, will be from about 100 C. to about 250 C. This is readily provided by control of the extruder temperature.
- the polymer containing the critical amount of azido compound is extruded at a temperature higher than the temperature required to initiate the reaction so that the reaction occurs during the extrusion.
- the azido bridging agent can be incorporated into the polypropylene by any of the commonly used methods of admixing additives with a polymer. Exemplary methods are deposition on the polymer flake from a solvent, admixing on a heated mill such as a Banbury mixer, dry blending, dissolving both the polymer and agent in a mutual solvent and then evaporating the solvent, etc.
- Permanent Set was determined in the examples by extending the monofilament to the specified elongation, holding it in the extended state for 10 minutes, releasing it, and allowing it to relax for 5 minutes. Permanent Set is calculated is the precentage of the imposed elongation which is retained after relaxation for 5 minutes. All parts in the following examples are by weight unless otherwise specified.
- EXAMPLES 1-3 Particles of stereoregular polypropylene having a reduced specific viscosity of 2.45 (determined in a 0.1% solution in decahydronaphthalene at C.) and stabilized against light and heat were wetted with a solution in acetone of 1,10-decane bis(sulfonazide). The solution was sufiiciently concentrated to deposit 0.03% of disulfonazide on the surface of the polymer flake when the solvent was evaporated. The thus treated flake was melted in a compounding extruder and extruded at a temperature of 250 C. at various rates of speed which were adjusted to give different deniers through a 4 hole 30 mil diameter spinneret die.
- the monofilaments were drawn away from the die at a rate of 272 feet per minute, resulting in different draw down ratios and different deniers as shown in the table below.
- the monofilaments were quenched in a water bath at 50 C. located inch from the extrusion die, wound on a bobbin and then placed in a forced draft oven at C. for 15 minutes.
- a second batch of the stereoregular polypropylene flake was treated as above and extruded into monofilaments under the same conditions as above except no bis(sulfonazide) was added.
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Description
em. 23, 1969 c. OPPENLANDER 3,435,906
MELT SPINNING ELASTIC POLYPROPYLENE MONOFILAMENTS Filed Aug. 31, 1967 FIG.
GEORGE C. OPPENLANDER INVENTOR.
AGENT nited States Patent 3,485,906 MELT SPINNING ELASTIC POLYPROPYLENE MONOFILAMENTS George C. Oppenlander, Embreeville, Pa., assignor to Hercules Incorporated, Wilmington, Del., a corporation of Delaware Filed Aug. 31, 1967, Ser. No. 664,774 The portion of the term of the patent subsequent to May 7, 1985, has been disclaimed Int. Cl. D01d /10; D01f 1/02 US. Cl. 264-178 4 Claims ABSTRACT OF THE DISCLOSURE Elastic monofilament of bridged polypropylene can be prepared by extruding molten polypropylene containing a small amount of azido bridging agent into a-monofilament, subjecting the said monofilament to a melt draw down of from about 3:1 to about 9.5 :l, quenching the monofilament in an inert liquid less than /2 inch from the die and then heat treating the monofilament at a temperature between about 130 C. and about 155 C. The said elastic monofilament has a recovery of at least 85% after elongation up to 75% The present invention relates to elastic monofilament of bridged stereoregular polypropylene and to a process for the production of such monofilament.
It is known to produce so called stretch yarns of synthetic polymers where stretchability is a result of the physical structure of the yarn rather than inherent elasticity of the synthetic polymers, examples being crimped and highly twisted yarns. Truly elastic monofilaments of synthetic polymers, that is, monofilaments possessing the ability to be stretched repeatedly and regain substantially the original length due to the inherent elasticity of the material from which they are made, are much more rare.
Monofilaments of stereoregular polypropylene are well known. While some of these filaments have been described as highly elastic, useful elastic monofilaments of stereoregular polypropylene, particularly in the higher denier range, have not been forthcoming and the problem of producing useful elastic monofilaments of such material have been fraught with difliculty.
Now, in accordance with this invention, it has been found that elastic monofilaments of stereoregular polypropylene can be prepared if certain critical process steps are followed. Specifically the process in accordance with this invention comprises extruding molten stereoregular polypropylene containing from about 0.02% to about 0.08% by weight of an azido bridging agent at a temperature between about 200 C. and about 290 C. in the form of a monofilament, subjecting the extruded filament to a melt draw down of from about 3:1 to about 9.511, quenching the filament in an inert liquid at a temperature of from about 30 C. to about 110 C. less than /2 inch, preferably within about A; to about inch from the die, and heat treating the solidified monofilament at a temperature between about 130 C. and about 155 C. The elastic monofilaments prepared in accordance with this invention are useful for many purposes, as for example, in the manufacture of outdoor furniture Webbing, automobile seat covers, etc.
The criterion for measuring the elastic properties of "ice the monofilament is its ability to return to its original length when it is relaxed after being subjected to an elongating stress. This property is referred to herein as tensile recovery or more simply as recovery. It is expressed as a percentage of the imposed elongation which is lost upon removal of the elongating force. Percent recovery (r) is calculated as Percent R 'X where L. represents the distance the sample was elongated, and I. represents the portion of that elongation which is retained upon release of the elongating stress. The parameter L may also be referred to as permanent set. The percentage of permanent set is equal to 100 minus percent recovery. It should be obvious that higher values of recovery, or conversely, lower values of permanent set indicate greater elastic properties.
The process of the invention is illustrated in the attached drawing in which 1 designates an extruder adapted to extrude molden polymer 2 through a die 3. The numeral 4 represents a vessel containing a quenching liquid 5, e.g., water, in which is submerged an idler roll 6. Numerals 7 and 8 designate nip rolls which convey the monofilament through the quenching liquid, 9 designates a heat treatment oven containing a series of idler rolls 10. 11 and 12 designate an additional set of nip rolls and 13 designates a wind up station.
In operating according to the drawing, the molten polymer 2 is extruded in the form of a monofilament 14 into the inert liquid 5 in the quench tank 4. The monofilament is drawn through the quenching tank by the nip rolls 7 and 8 which are positively driven at a rate 3 to 9.5 times the linear rate of extrusion of the filament through the die. This increase in the linear speed of the monofilament causes stretching of the filament in its weakest section, i.e., the molten portion between the die and the inert liquid. The inert liquid in the quench tank through which the monofilament is drawn is maintained at a temperature sufiicient to solidify the filament. A satisfactory temperature is from about 30 C. to about C. The quenched monofilament is drawn from the tank and fed into the heat treatment oven 9 and around the idler rolls 10. In passing through this oven the monofilament is maintained at a temperature below its softening point. The finished monofilament is fed onto wind up station 13 through nip rolls 11 and 12.
The extruded monofilament is subjected to a melt draw of at least 200% or stated otherwise a melt draw down of at least 3:1. By melt draw down is meant the reduction in thickness of the extruded monofilament while it is still in the liquid or molten state prior to quenching. Melt draw down ratio expresses the relationship between the cross-sectional area of the die opening to that of the monofilament. Melt draw down is commonly employed in the production of films and fibers from thermoplastic polymers for several reasons. For example, the melt draw down permits the use of a larger size die than can he used otherwise. This permits greater precision in die manufacture and results in correspondingly greater denier uniformity in the extruded monofilaments. Most preferably the die opening used in the process of this invention will be from about 15 mils to about 50 mils resulting in monofilaments of from about 200 denier to about 1,200 denier.
In the process of this invention the use of melt draw down is found to be vital to the formation of elastic filaments and as indicated above, the monofilament must be subjected to a draw down of at least about 3:1 in the molten state as it leaves the die. When melt drawing the filament it is necessary to confine the drawing to a relatively small distance. If the draw down takes place over any sizeable distance, the resultant filament exhibits an unacceptable amount of denier variation. To assure that the drawing is thus confined, it is necessary to quench the filament to the solid state within a relatively short distance of the die. Since the filament will draw preferentially in the molten areas rapid quenching tends to isolate the draw area. To obtain the optimum in denier uniformity the monofilamentmust be quenched within /2 inch of the die.
The quenching of the monofilament is effected by immersing the filament in a bath of cooling liquid, e.g., water, maintained at a temperature of from about 30 C. to about 110 C.
The monofilament which is formed by the extrusion, melt draw down and quenching operations discussed above has very little elasticity as it is taken from the quench bath. The elasticity is fully developed by heat treatment at a temperature in the range of from about 130 C. to about 155 C. for a minimum time of about 30 seconds. This can be accomplished very effectively on a continuous basis, as, for example, by the use of a heat treatment oven containing idler rolls through which the monofilament passes after leaving the quench bath. Obviously the more idler rolls the longer the period of time in the heat treatment oven. The heat treatment can also be accomplished by simply forming a roll of monofilament and then placing the roll in a heated oven for the desired length of time. After the heat treatment the =monofilaments of bridged polypropylene are capable of at least 85% recovery after elongation up to about 75%.
The azido bridging agents used in the process of this invention are exemplified by the sulfonazides and the azidoformates.
The sulfonazides have the general formula R(SO N where R is an organic radical inert to reaction with polypropylene and x is an integer greater than 1. Exemplary sulfonazides are 1,5-pentane bis(sulfonazide), 1,10-decane bis(sulfonazide), 1,3-benzene bis(sulfonazide), 1- octyl-2,4-6-benzene tris (sulfonazide), 4,4-diphenylmethane bis(sulfonazide) 4,4-diphenyl ether bis(sulfonazide), 4,4 bis octadecyl biphenyl-3,5,3',5'-tetra(sulfonazide) 1,4-cyclohexane dimethyl -bis(sulfonazide), 4,4-diphenyl disulfide bis(sulfonazide), l,6-bis(4-sulfonazidophenyl) hexane, 2,7-naphthalene bis(sulfonazide), etc. Other sulfonazides may be used, for instance those having functional groups on the Organic hydrocarbon such as halogen, carboxyl groups, carbonyl groups, etc., so long as such groups are inert to reaction with polypropylene.
The azidoformates have the general structural formula:
where R is an organic radical inert to reaction with polypropylene and x is an integer from 2 to about 8. Exemplary of the azidoformates used are the alkylene azidoformates such as tetramethylene-bis-(azidoformate), pentamethylene-bis(azidoformate); the cyclic alkylene azidoformates such as 1,4-cyclohexanedimethyl-bis-(azidoformate); the aralkylene azidoformates such as cc,oz'pxylylene-bis(azidoformate); the aromatic azidoformates such as 2,2-isopropylidene-bis(p,p'-phenyl azidoformate); the azidoformate ethers such as 2,2-oxydiethyl-bis(azido formate), 2,2'-oxydipropyl-bis(azidoformate), 2,2'-ethylenedioxydiethyl-bis(azidoformate), the tetraazidoformate of pentaerythritolpropylene oxide adduct having the general formula:
the azidoformate thioethers such as 2,2'-thiodiethyl-bis (azidoformate), 4,4-thiodibutyl-bis (azidoformate); etc. It will, of course, be obvious to those skilled in the art that still other azidoformates containing functional groups, which are inert to reaction with polypropylene, such as halogen, carboxyl groups, carbonyl groups, etc., are included in the above definition.
It is known to bridge polypropylene by the use of azido compounds such as the aforesaid sulfonazides. The bridged polymers are completely soluble in the usual solvents for polypropylene, extrude smoothly with reduced sag and have greater hardness, strength, and stiffness and higher density.
In order to improve the elastic properties of the monofilaments of this invention it is necessary that a critical amount of bridging agent by present, i.e., the amount must be sufiicient to increase the melt viscosity of the polymer but insufficient to alter its solubility in perchlorethylene at C. This amount of bridging agent is provided by the addition of from about 0.02% to about 0.08% by weight of azido compound. When the amount of azido compound materially exceeds this range the polymer is insolubilized, cannot be extruded and does not exhibit the desired elastic properties. When the amount is below the range, little or no benefit is realized.
The bridging reaction is initiated by heat. The temperature required depends somewhat on the particular azido compound employed but, in general, will be from about 100 C. to about 250 C. This is readily provided by control of the extruder temperature. In other words, the polymer containing the critical amount of azido compound is extruded at a temperature higher than the temperature required to initiate the reaction so that the reaction occurs during the extrusion.
The azido bridging agent can be incorporated into the polypropylene by any of the commonly used methods of admixing additives with a polymer. Exemplary methods are deposition on the polymer flake from a solvent, admixing on a heated mill such as a Banbury mixer, dry blending, dissolving both the polymer and agent in a mutual solvent and then evaporating the solvent, etc.
The general nature of the invention having been set forth the following examples serve to illustrate the invention. It is to be understood that the invention is in no way limited to the examples since it can be carried out by the use of various modifications and changes within the scope of the invention as herein set forth and described. Permanent Set was determined in the examples by extending the monofilament to the specified elongation, holding it in the extended state for 10 minutes, releasing it, and allowing it to relax for 5 minutes. Permanent Set is calculated is the precentage of the imposed elongation which is retained after relaxation for 5 minutes. All parts in the following examples are by weight unless otherwise specified.
EXAMPLES 1-3 Particles of stereoregular polypropylene having a reduced specific viscosity of 2.45 (determined in a 0.1% solution in decahydronaphthalene at C.) and stabilized against light and heat were wetted with a solution in acetone of 1,10-decane bis(sulfonazide). The solution was sufiiciently concentrated to deposit 0.03% of disulfonazide on the surface of the polymer flake when the solvent was evaporated. The thus treated flake was melted in a compounding extruder and extruded at a temperature of 250 C. at various rates of speed which were adjusted to give different deniers through a 4 hole 30 mil diameter spinneret die. The monofilaments were drawn away from the die at a rate of 272 feet per minute, resulting in different draw down ratios and different deniers as shown in the table below. The monofilaments were quenched in a water bath at 50 C. located inch from the extrusion die, wound on a bobbin and then placed in a forced draft oven at C. for 15 minutes.
A second batch of the stereoregular polypropylene flake was treated as above and extruded into monofilaments under the same conditions as above except no bis(sulfonazide) was added.
The percentage permanent set of each sample is shown in Table I.
TABLE I Permanent set, elongation Example Draw Denier N 0. down 20% 75% EXAMPLES 4-6 TABLE II Permanent set,
elongation Draw Example No. down Demer 20% 75% I claim:
1. A process of forming an elastic monofilament of bridged polypropylene of at least about 200 denier cornprising extruding stereoregular polypropylene containing from about 0.02% to about 0.08% by weight of an azido bridging agent into a monofilament at a temperature of from about 200 C. to about 290 C., subjecting the molten monofilament to a melt draw down of from about 3 :1 to about 9.511, quenching the trnonofilament in an inert liquid less than /2 inch from the die and heat treating the monofilament at a temperature between about C. and about C.
2. The process of claim 1 wherein the azidio bridging agent is a bis(sulfonazide).
3. The process of claim 1 wherein the azido bridging agent is a bis(azidoformate).
4. The process of claim 1 wherein the monofilament is quenched at a temperature of from about 30 C. to about 110 C.
References Cited UNITED STATES PATENTS 3,054,652 9/1962 Heumann 264-28 3,059,991 10/ 196-2 'Munt. 3,127,915 4/ 1964 Bottomley. 3,143,584 8/1964 Roberts et al. 3,256,258 6/ 1966 Herrman. 3,323,190 6/1967 Boltniew 264-290 X 3,330,897 7/1967 Tessier 264290 X 3,377,415 4/ 1968 Oppenlander. 3,382,306 5/1968 Oppenlander 264l78 2,324,397 7/ 1943 Hull. 3,215,486 11/1965 Hada et al 874 FOREIGN PATENTS 962,231 7/ 1964 Great Britain.
229,943 10/ 1958 Australia.
456,914 5/ 1949 Canada.
JULIUS FROME, Primary Examiner I. H. WOO, Assistant Examiner US. Cl. X.R.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US66477467A | 1967-08-31 | 1967-08-31 |
Publications (1)
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US3485906A true US3485906A (en) | 1969-12-23 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US664774A Expired - Lifetime US3485906A (en) | 1967-08-31 | 1967-08-31 | Melt spinning elastic polypropylene monofilaments |
Country Status (3)
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US (1) | US3485906A (en) |
DE (1) | DE1775599A1 (en) |
GB (1) | GB1182577A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3621088A (en) * | 1968-08-09 | 1971-11-16 | Phillips Petroleum Co | High production of water-quenched filaments |
US4384098A (en) * | 1981-01-13 | 1983-05-17 | Phillips Petroleum Company | Filamentary polypropylene and method of making |
US20070063377A1 (en) * | 2005-06-17 | 2007-03-22 | Tapijtfabriek H. Desseaux N.V. | Method for the manufacture of monofilaments, as well as an artificial field |
Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2324397A (en) * | 1941-06-04 | 1943-07-13 | Du Pont | Method for production of continuous structures |
CA456914A (en) * | 1949-05-24 | Canadian Industries Limited | Manufacture of artificial threads | |
US3054652A (en) * | 1957-08-28 | 1962-09-18 | Exxon Research Engineering Co | Isotactic polypropylene melt spinning process |
US3059991A (en) * | 1959-03-20 | 1962-10-23 | E B & A C Whiting Company | Method of making oriented filamentary article of isotactic polypropylene |
US3127915A (en) * | 1960-07-01 | 1964-04-07 | Phillips Petroleum Co | Synthetic knopped filaments |
GB962231A (en) * | 1967-11-13 | 1964-07-01 | Canadian Celanese Ltd | Process for the production of fibres of improved elastic recovery |
US3143584A (en) * | 1959-05-12 | 1964-08-04 | Ici Ltd | Spinning polypropylenes which have been subjected to thermal degradation promoted bythe presence of sulfur compounds |
US3215486A (en) * | 1962-04-17 | 1965-11-02 | Toyo Spinning Co Ltd | Fixation of polypropylene fibers impregnated with dyestuffs and other treating agents |
US3256258A (en) * | 1961-05-05 | 1966-06-14 | Du Pont | Fibers |
US3323190A (en) * | 1963-06-12 | 1967-06-06 | Hercules Inc | Elastic polypropylene yarn and process for its preparation |
US3330897A (en) * | 1961-02-07 | 1967-07-11 | Chemcell 1963 Ltd | Production of fibers of improved elastic recovery |
US3377415A (en) * | 1964-05-27 | 1968-04-09 | Hercules Inc | Elastic polypropylene yarn and process |
US3382306A (en) * | 1964-06-12 | 1968-05-07 | Hercules Inc | Process of forming elastic polypropylene film |
-
1967
- 1967-08-31 US US664774A patent/US3485906A/en not_active Expired - Lifetime
-
1968
- 1968-07-11 GB GB33235/68A patent/GB1182577A/en not_active Expired
- 1968-08-30 DE DE19681775599 patent/DE1775599A1/en active Pending
Patent Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA456914A (en) * | 1949-05-24 | Canadian Industries Limited | Manufacture of artificial threads | |
US2324397A (en) * | 1941-06-04 | 1943-07-13 | Du Pont | Method for production of continuous structures |
US3054652A (en) * | 1957-08-28 | 1962-09-18 | Exxon Research Engineering Co | Isotactic polypropylene melt spinning process |
US3059991A (en) * | 1959-03-20 | 1962-10-23 | E B & A C Whiting Company | Method of making oriented filamentary article of isotactic polypropylene |
US3143584A (en) * | 1959-05-12 | 1964-08-04 | Ici Ltd | Spinning polypropylenes which have been subjected to thermal degradation promoted bythe presence of sulfur compounds |
US3127915A (en) * | 1960-07-01 | 1964-04-07 | Phillips Petroleum Co | Synthetic knopped filaments |
US3330897A (en) * | 1961-02-07 | 1967-07-11 | Chemcell 1963 Ltd | Production of fibers of improved elastic recovery |
US3256258A (en) * | 1961-05-05 | 1966-06-14 | Du Pont | Fibers |
US3215486A (en) * | 1962-04-17 | 1965-11-02 | Toyo Spinning Co Ltd | Fixation of polypropylene fibers impregnated with dyestuffs and other treating agents |
US3323190A (en) * | 1963-06-12 | 1967-06-06 | Hercules Inc | Elastic polypropylene yarn and process for its preparation |
US3377415A (en) * | 1964-05-27 | 1968-04-09 | Hercules Inc | Elastic polypropylene yarn and process |
US3382306A (en) * | 1964-06-12 | 1968-05-07 | Hercules Inc | Process of forming elastic polypropylene film |
GB962231A (en) * | 1967-11-13 | 1964-07-01 | Canadian Celanese Ltd | Process for the production of fibres of improved elastic recovery |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3621088A (en) * | 1968-08-09 | 1971-11-16 | Phillips Petroleum Co | High production of water-quenched filaments |
US4384098A (en) * | 1981-01-13 | 1983-05-17 | Phillips Petroleum Company | Filamentary polypropylene and method of making |
US20070063377A1 (en) * | 2005-06-17 | 2007-03-22 | Tapijtfabriek H. Desseaux N.V. | Method for the manufacture of monofilaments, as well as an artificial field |
Also Published As
Publication number | Publication date |
---|---|
DE1775599A1 (en) | 1971-09-09 |
GB1182577A (en) | 1970-02-25 |
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