US3463892A - Contact supporting stud and method for making the same - Google Patents

Contact supporting stud and method for making the same Download PDF

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US3463892A
US3463892A US567337A US3463892DA US3463892A US 3463892 A US3463892 A US 3463892A US 567337 A US567337 A US 567337A US 3463892D A US3463892D A US 3463892DA US 3463892 A US3463892 A US 3463892A
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copper
alloy
vacuum
studs
zirconium
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US567337A
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Henry J Wesoloski
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Allis Chalmers Corp
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Allis Chalmers Corp
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H1/00Contacts
    • H01H1/02Contacts characterised by the material thereof
    • H01H1/0203Contacts characterised by the material thereof specially adapted for vacuum switches
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H33/00High-tension or heavy-current switches with arc-extinguishing or arc-preventing means
    • H01H33/60Switches wherein the means for extinguishing or preventing the arc do not include separate means for obtaining or increasing flow of arc-extinguishing fluid
    • H01H33/66Vacuum switches

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  • This invention relates generally to electrical circuit interrupters. More particularly, it relates to improved current carrying members for use in vacuum switches, vacuum circuit interrupters and similar devices (all hereinafter called vacuum interrupters) and to improved methods for making such members.
  • Vacuum interrupters are used in the electrical power industry, for example, to switch capacitOr banks and to interrupt power circuits in the event of fault conditions. Though compact in size, vacuum interrupters are adapted to handle relatively high voltages and currents. Vacuum interrupters comprise a sealed envelope in which a high vacuum is maintained and wherein one or more pairs of relatively movable contacts are disposed. In some types of vacuum interrupters each contact is mounted on the end of a current carrying member such as an electrically conductive elongated rod or stud. The studs are in axial alignment with each other and at least one stud is axially movable to effect contact opening and closing.
  • a cylindrical glass or metal (thin molybdenum, copper, or nickel) shield is disposed within the envelope and surrounds the contacts to prevent metal vapor and particles from being deposited on the inside of the envelope during arcing between the contacts and shorting out the tube.
  • the studs were usually made of high purity copper designated as O.F.H.C. (oxygen free high conductivity) copper which is 99.95% pure.
  • O.F.H.C. oxygen free high conductivity
  • the O.F.H.C. copper studs became fully annealed and dead soft. Consequently, great care was needed in handling the vacuum interrupters during manufacture, shipping and field use to prevent sudden jolts from bending the studs to a position where they pierced the shield, broke the envelope, or became misaligned.
  • Another object is to provide studs of the aforesaid character which are made of copper-vanadium-Zirconium allo
  • a iiOther object is to provide an improved vacuum interrupter having contact supporting studs which achieve desired mechanical and electrical properties as a result of the heat treatment to which the interrupter is subjected during manufacture.
  • Another object is to provide an improved method for making studs for vacuum interrupters.
  • the drawing shows a cross-sectional view of a type of vacuum interrupter in which the invention is advantageously employed.
  • a vacuum interrupter comprising an envelope 12 made of electrical insulating material such as glass or ceramic.
  • the interior of envelope 12 is understood to be maintained at a relatively high vacuum.
  • the vacuum interrupter further comprises a pair of relatively movable contacts 14 and 16 (shown in open position) which are made, for example, of tungsten and are mounted on a pair of studs 18 and 20, respectively.
  • stud 18 supports the stationary contact and is therefore, rigidly mounted in sealed relationship in envelope 12.
  • Stud 20 supports the movable contact and is movably mounted in sealed relationship in envelope 12 by means of a bellows 22.
  • a cylindrical shield 24 is mounted on stud 18 and extends around the contacts 14 and 16.
  • shield 24 is made of molybdenum on the order of .004 of an inch thick which tends to become brittle and fragile after being subjected to the heat treatment hereinafter described.
  • the contacts are brazed to the studs, and the bellows and shield are brazed to their respective studs as hereinafter described.
  • the studs 18 and 20 are made of copper-vanadium-zirconium alloy instead of O.F.H.C. copper as is the case in prior art devices of this type.
  • the ternary alloy comprised about 99.7+% pure copper, about .03 to .08% vanadium, and about .2% zirconium.
  • an alloy comprising other percentages of the stated materials could be employed.
  • a vacuum interrupter of the type disclosed herein.
  • the component parts of the vacuum interrupter are assembled using suitable jigs to hold the components in proper relationship.
  • Brazing material of high purity and in the form of thin sheets, rings and pellets is disposed on the assembled components at places where components are to be jointed together, i.e., at the joints between the contacts 14 and 16 and the studs 18 and 20, respectively, at the point between shield 24 and stud 18, at the joint between bellows 22 and stud 20, and at other places where brazing is required.
  • the entire assembly is then disposed in an atmosphere of pure hydrogen and raised to a temperature of about 1020 C. for about 3 to 5 minutes until the brazing material melts.
  • the assembly is then cooled so that the brazing material solidifies. Afterward, the entire assembly is pumped out to establish a high vacuum in envelope 12 and is baked-out at a temperature of about 400 to 450 C. for about 10 to 16 hours. The bake-out procedure is necessary to age the components and drive off any residual impurities. After the bake-out cycle, the envelope 12 is cooled to room temperature (which will aid in getting the vacuum to approximately 2x10 torr) and is sealed. As will be understood, all of the steps described above are carried out in a clean room environment.
  • the foregoing steps are required whether or not the studs are made of O.F.H.C. copper or of copper-vanadium-zirconium alloy.
  • the hydrogen brazing step causes the Zirconium and vanadium in the alloy to be taken into solid solution with the copper when a temperature of about 980 C. or above is reached.
  • the zirconium and vanadium are disposed throughout the copper while the basic crystalline structure of the copper remains unchanged.
  • there is imparted to the alloy an excellent resistance to softening at temperatures as high as 615 C.
  • the electrical conductivity of the alloy rises from 50% I.A.C.S.
  • O.F.H.C. copper has a yield strengthof 40,000 p.s.i. (pounds per square inch) and a softening point of 250 to 300 C.
  • the ultimate tensile strength of O.F.H.C. copper is below 32,000 p.s.i. after annealing, whereas the worst condition of the ternary alloy is 58,000 p.s.i.
  • a vacuum interrupter an envelope wherein a high vacuum is maintained, and a pair of relatively movable contact carrying studs within said envelope, at least one of said studs being made of a copper-vanadium-zirconium alloy, said alloy comprising at least 99.7+% copper, .2% zirconium, and .03 to .08% vanadium.
  • a high strength, high conductivity current carrying component comprised of an alloy containing copper, vanadium and zirconium, said alloy comprising at least 99.7+% copper, .03 to 08% vanadium and .2% zirconium.

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Description

Aug. 26, 1969 H. J. WESOLOSKI 3,463,392
CONTACT SUPPORTING STUD AND METHOD FOR MAKING THE SAME Filed June 29, 1966 aM/D/ M/ &
5 02mm; 3. Mp 0/ 2 United States Patent US. Cl. 200-144 Claims ABSTRACT OF THE DISCLOSURE In a vacuum type electric circuit interrupter having a pair of relatively movable contact studs therein, at least one of the studs is made of an alloy comprising 99.7+% copper, .2% zirconium and .03 to .08% vanadium, which alloy has first been heated to at least 980 C. for 3 to 5 minutes and subsequently reheated to about 400 C. for to 16 hours.
This invention relates generally to electrical circuit interrupters. More particularly, it relates to improved current carrying members for use in vacuum switches, vacuum circuit interrupters and similar devices (all hereinafter called vacuum interrupters) and to improved methods for making such members.
Vacuum interrupters are used in the electrical power industry, for example, to switch capacitOr banks and to interrupt power circuits in the event of fault conditions. Though compact in size, vacuum interrupters are adapted to handle relatively high voltages and currents. Vacuum interrupters comprise a sealed envelope in which a high vacuum is maintained and wherein one or more pairs of relatively movable contacts are disposed. In some types of vacuum interrupters each contact is mounted on the end of a current carrying member such as an electrically conductive elongated rod or stud. The studs are in axial alignment with each other and at least one stud is axially movable to effect contact opening and closing. Usually, a cylindrical glass or metal (thin molybdenum, copper, or nickel) shield is disposed within the envelope and surrounds the contacts to prevent metal vapor and particles from being deposited on the inside of the envelope during arcing between the contacts and shorting out the tube.
Heretofore, the studs were usually made of high purity copper designated as O.F.H.C. (oxygen free high conductivity) copper which is 99.95% pure. However, during manufacture of a typical vacuum interrupter it was subjected to hydrogen brazing (for example, at about 1020 C. for 3 to 5 minutes) and bake-out (for example, at about 400 C. for 10 to 16 hours) and the O.F.H.C. copper studs became fully annealed and dead soft. Consequently, great care was needed in handling the vacuum interrupters during manufacture, shipping and field use to prevent sudden jolts from bending the studs to a position where they pierced the shield, broke the envelope, or became misaligned.
It is an object of the present invention to provide improved vacuum interrupters having current carrying members such as contact supporting studs made of a material which is mechanically stronger than O.F.H.C. copper and has substantially the same electrical conductivity and resistivity under similar operating temperature conditions.
Another object is to provide studs of the aforesaid character which are made of copper-vanadium-Zirconium allo A iiOther object is to provide an improved vacuum interrupter having contact supporting studs which achieve desired mechanical and electrical properties as a result of the heat treatment to which the interrupter is subjected during manufacture.
ice
Another object is to provide an improved method for making studs for vacuum interrupters.
Other objects and advantages of the invention will hereinafter appear.
The accompanying drawing illustrates a preferred embodiment of the invention but it is to be understood that the embodiment illustrated and the process disclosed in the specification are susceptible of modification with respect to details thereof without departing from the scope of the appended claims.
The drawing shows a cross-sectional view of a type of vacuum interrupter in which the invention is advantageously employed.
Referring to the drawing, there is shown a vacuum interrupter comprising an envelope 12 made of electrical insulating material such as glass or ceramic. The interior of envelope 12 is understood to be maintained at a relatively high vacuum. The vacuum interrupter further comprises a pair of relatively movable contacts 14 and 16 (shown in open position) which are made, for example, of tungsten and are mounted on a pair of studs 18 and 20, respectively. In the embodiment shown, stud 18 supports the stationary contact and is therefore, rigidly mounted in sealed relationship in envelope 12. Stud 20 supports the movable contact and is movably mounted in sealed relationship in envelope 12 by means of a bellows 22. A cylindrical shield 24 is mounted on stud 18 and extends around the contacts 14 and 16. In practice, shield 24 is made of molybdenum on the order of .004 of an inch thick which tends to become brittle and fragile after being subjected to the heat treatment hereinafter described. In practice, the contacts are brazed to the studs, and the bellows and shield are brazed to their respective studs as hereinafter described.
In accordance with the present invention the studs 18 and 20 are made of copper-vanadium-zirconium alloy instead of O.F.H.C. copper as is the case in prior art devices of this type. In a preferred embodiment the ternary alloy comprised about 99.7+% pure copper, about .03 to .08% vanadium, and about .2% zirconium. However, an alloy comprising other percentages of the stated materials could be employed.
The following steps are followed in the manufacture of a vacuum interrupter of the type disclosed herein. First, the component parts of the vacuum interrupter are assembled using suitable jigs to hold the components in proper relationship. Brazing material of high purity and in the form of thin sheets, rings and pellets is disposed on the assembled components at places where components are to be jointed together, i.e., at the joints between the contacts 14 and 16 and the studs 18 and 20, respectively, at the point between shield 24 and stud 18, at the joint between bellows 22 and stud 20, and at other places where brazing is required. The entire assembly is then disposed in an atmosphere of pure hydrogen and raised to a temperature of about 1020 C. for about 3 to 5 minutes until the brazing material melts. The assembly is then cooled so that the brazing material solidifies. Afterward, the entire assembly is pumped out to establish a high vacuum in envelope 12 and is baked-out at a temperature of about 400 to 450 C. for about 10 to 16 hours. The bake-out procedure is necessary to age the components and drive off any residual impurities. After the bake-out cycle, the envelope 12 is cooled to room temperature (which will aid in getting the vacuum to approximately 2x10 torr) and is sealed. As will be understood, all of the steps described above are carried out in a clean room environment.
The foregoing steps are required whether or not the studs are made of O.F.H.C. copper or of copper-vanadium-zirconium alloy. However, when the cold worked alloy is used the hydrogen brazing step causes the Zirconium and vanadium in the alloy to be taken into solid solution with the copper when a temperature of about 980 C. or above is reached. Thus, the zirconium and vanadium are disposed throughout the copper while the basic crystalline structure of the copper remains unchanged. As a consequence, there is imparted to the alloy an excellent resistance to softening at temperatures as high as 615 C. When the alloy is subsequently subjected to vacuum bake-out the electrical conductivity of the alloy rises from 50% I.A.C.S. (International Annealed Copper Standard) to about 92%. Thus, the steps which are required when using O.F.H.C. copper and result in full annealing and softening thereof have the effect on the alloy of increasing its mechanical strength and raising its electrical conductivity to desirable levels.
It should be noted that O.F.H.C. copper has a yield strengthof 40,000 p.s.i. (pounds per square inch) and a softening point of 250 to 300 C. The addition of 2% zirconium alone raises its yield strength to 55,000 p.s.i. and its softening point to about 580 C. The addition of .03 to .08% vanadium to the copper-zirconium alloy raises the yield strength to 62,000 p.s.i. and the softening point to about 615 C. The ultimate tensile strength of O.F.H.C. copper is below 32,000 p.s.i. after annealing, whereas the worst condition of the ternary alloy is 58,000 p.s.i.
While the invention disclosed herein is depicted as applied to one of several types of vacuum interrupters, it will be apparent to those skilled in the art that it is applicable to other types of vacuum interrupters and other types of devices. Furthermore, while the alloy is disclosed herein as the material of which the studs are made, it is apparent that the alloy could be used for other electrical current carrying components Within vacuum interrupters or other devices which are subjected to the aforedescribed heat treatment during manufacture.
The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:
1. In a vacuum interrupter, an envelope wherein a high vacuum is maintained, and a pair of relatively movable contact carrying studs within said envelope, at least one of said studs being made of a copper-vanadium-zirconium alloy, said alloy comprising at least 99.7+% copper, .2% zirconium, and .03 to .08% vanadium.
2. A vacuum interrupter according to claim 1 wherein saidalloy has been heat treated so that it is mechanically stronger than O.F.H.C. copper and has an electrical conductivity which is about 92% of O.F.H.C. copper.
3. A vacuum interrupter according to claim 2 wherein said alloy has been first heated to at least 980 C. for 3 to 5 minutes and subsequently reheated to about 400 C. for 10 to 16 hours.
4. As an electrical contact, a high strength, high conductivity current carrying component comprised of an alloy containing copper, vanadium and zirconium, said alloy comprising at least 99.7+% copper, .03 to 08% vanadium and .2% zirconium.
5. An electrical contact according to claim 4 wherein said alloy has been raised to a temperature of at least 980 C. for a length of time sufiicient to raise its yield strength to about 62,000 p.s.i. and to raise its electrical conductivity to about 92% I.A.C.S.
References Cited UNITED STATES PATENTS 1,248,621 12/1917 Cooper. 1,350,317 8/1920 Kingsbury. 1,563,573 12/ 1925 Hybinette. 1,633,258 6/1927 Laise. 2,171,697 9/1939 Hansel et al.
FOREIGN PATENTS 947,152 1/1964 Great Britain.
ROBERT S. MACON, Primary Examiner U.S. C1. X.R. 200-166
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3700842A (en) * 1971-11-23 1972-10-24 Allis Chalmers Vacuum interrupter contacts and method for making the same
WO1982001960A1 (en) * 1980-11-28 1982-06-10 Rodionov Valery V Method of preparation of contacts and electrodes of vacuum electric apparatuses

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1248621A (en) * 1917-10-08 1917-12-04 Electro Metals Products Company Metal alloy.
US1350317A (en) * 1919-11-20 1920-08-24 Edward J Kingsbury Alloy for electric welding
US1563573A (en) * 1923-06-11 1925-12-01 Hybinette Noak Victor Heat-resisting alloy and structure, etc.
US1633258A (en) * 1925-10-08 1927-06-21 Clemens A Laise Refractory metal alloy of high density and high melting point and method of making the same
US2171697A (en) * 1939-03-09 1939-09-05 Mallory & Co Inc P R Alloy
GB947152A (en) * 1959-04-30 1964-01-22 English Electric Co Ltd Improvements in or relating to high-vacuum circuit interupter

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1248621A (en) * 1917-10-08 1917-12-04 Electro Metals Products Company Metal alloy.
US1350317A (en) * 1919-11-20 1920-08-24 Edward J Kingsbury Alloy for electric welding
US1563573A (en) * 1923-06-11 1925-12-01 Hybinette Noak Victor Heat-resisting alloy and structure, etc.
US1633258A (en) * 1925-10-08 1927-06-21 Clemens A Laise Refractory metal alloy of high density and high melting point and method of making the same
US2171697A (en) * 1939-03-09 1939-09-05 Mallory & Co Inc P R Alloy
GB947152A (en) * 1959-04-30 1964-01-22 English Electric Co Ltd Improvements in or relating to high-vacuum circuit interupter

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3700842A (en) * 1971-11-23 1972-10-24 Allis Chalmers Vacuum interrupter contacts and method for making the same
WO1982001960A1 (en) * 1980-11-28 1982-06-10 Rodionov Valery V Method of preparation of contacts and electrodes of vacuum electric apparatuses

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