US3431082A - Tube furnace provided with filling bodies - Google Patents

Tube furnace provided with filling bodies Download PDF

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Publication number
US3431082A
US3431082A US47105465A US3431082A US 3431082 A US3431082 A US 3431082A US 47105465 A US47105465 A US 47105465A US 3431082 A US3431082 A US 3431082A
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United States
Prior art keywords
filling bodies
tube
filling
bodies
individual
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Expired - Lifetime
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English (en)
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Jan Sellin
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Battelle Development Corp
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Battelle Development Corp
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B37/00Component parts or details of steam boilers
    • F22B37/02Component parts or details of steam boilers applicable to more than one kind or type of steam boiler
    • F22B37/10Water tubes; Accessories therefor
    • F22B37/18Inserts, e.g. for receiving deposits from water
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J15/00Chemical processes in general for reacting gaseous media with non-particulate solids, e.g. sheet material; Apparatus specially adapted therefor
    • B01J15/005Chemical processes in general for reacting gaseous media with non-particulate solids, e.g. sheet material; Apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053Details of the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053Details of the reactor
    • B01J19/006Baffles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/30Loose or shaped packing elements, e.g. Raschig rings or Berl saddles, for pouring into the apparatus for mass or heat transfer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/30Loose or shaped packing elements, e.g. Raschig rings or Berl saddles, for pouring into the apparatus for mass or heat transfer
    • B01J19/305Supporting elements therefor, e.g. grids, perforated plates
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D17/00Regenerative heat-exchange apparatus in which a stationary intermediate heat-transfer medium or body is contacted successively by each heat-exchange medium, e.g. using granular particles
    • F28D17/005Regenerative heat-exchange apparatus in which a stationary intermediate heat-transfer medium or body is contacted successively by each heat-exchange medium, e.g. using granular particles using granular particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761Details of the reactor
    • B01J2219/00763Baffles
    • B01J2219/00765Baffles attached to the reactor wall
    • B01J2219/0077Baffles attached to the reactor wall inclined
    • B01J2219/00774Baffles attached to the reactor wall inclined in the form of cones
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30Details relating to random packing elements
    • B01J2219/302Basic shape of the elements
    • B01J2219/30207Sphere
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30Details relating to random packing elements
    • B01J2219/302Basic shape of the elements
    • B01J2219/30223Cylinder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30Details relating to random packing elements
    • B01J2219/304Composition or microstructure of the elements
    • B01J2219/30416Ceramic
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S261/00Gas and liquid contact apparatus
    • Y10S261/72Packing elements
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T137/00Fluid handling
    • Y10T137/7722Line condition change responsive valves
    • Y10T137/7736Consistency responsive

Definitions

  • reaction apparatus tubes for tube furnaces provided with filling bodies.
  • a vertically arranged outer tube has an axially extending concentrically arranged inner tube whose latter outer wall is spaced from the inner wall of the outer tube. This provides for counterflow, however, there may be in place of the inner tube a rod member extending axially within the outer tube.
  • Filling bodies are supported from the inner tube or the rod.
  • carrier elements in the form of uniformly spaced apart radially extending pins are welded at one end to the outer surface of the inner tube or rod.
  • shelf-like members extending in uniform spaced apart radial direction are secured to the outer surface of the inner tube or rod.
  • the filling bodies have an aperture therethrough and they are slidably received on the pins.
  • These filling bodies may be annular with oppositely extending frustrum of a cone ends and two may be pushed onto a carrier pin.
  • the outer bodies in -a radial direction have a greater diameter so that the intervals between the individual filling bodies in the peripheral direction remain approximately equal.
  • the filling bodies are freely supported.
  • the filling bodies here may take the shape of generally cylindrical members. The filling bodies in all cases are held in position with respect to each other in a uniform predetermined arrangement whereby equal flow conditions exist at all points within the tube and the Weight of the filling bodies is carried by the respective carrier elements.
  • This invention relates to tubes for tube furnaces, provided with filling bodies.
  • Tubes which contain a so-called stationary bed of filling bodies are frequently used in chemical work.
  • the filling bodies can here frequently fulfill a plurality of functions at the same time and possess for example an absorbing, flow-guiding, heat-storing or even catalytic action.
  • numberless variants have been developed as regards their outer form and also as regards their material composition.
  • fragments, balls, tablets or rings are used as tube filling bodies.
  • the arrangement of the filling bodies can influence very substantially the course of a process and must be determined for example according to the desired speeds of through-flow, sojourn times, heat-storage values, catalyst surfaces and the like.
  • the manner of the arrangement of the filling bodies has a particular influence upon the mechanical stressing of the tube walls and any installations thereupon and upon the filling bodies themselves. If the filling bodies are introduced by free pouring, which is almost always the case in tubes with relatively small diameter, additional stresses of the tube walls occur as considerable horizontal forces are exerted upon the tube walls as a result of the heaping angle of the bulk material being poured. Moreover the lower filling bodies are considerably stressed by the weight of the upper filling bodies and cannot carry out without hindrance, movements caused by temperature differences. These difficulties naturally become greater with greater pouring heights, narrower tubes and greater more frequent temperature fluctuations. The ratio of the tube diameter to the filling body diameter also plays a substantial part here.
  • the agglomeration of the filling bodies here firstly considerably falsifies the course of the process in the reaction tube and finally can completely suppress it, if the pressure loss occurring in the caked filling body mass exceeds the acceptable amount.
  • the invention provides, for tubes provided with filling bodies, that each individual filling body is held in a predetermined position by carrier elements, which in the case of counter-current tubes are secured on the outer surface of the inner tube or in the case of single tubes are secured on an insert of rod form extending axially of the tube.
  • the carrier elements for the filling bodies are formed as metallic pins welded on the inner tube or rodshaped inserts, upon which one or more annular filling bodies can be pushed.
  • the loads to be taken up here by each individual carrier pin are so minimal that relatively thin wire pins of appropriately refractory high-grade steel can be used, without need to fear bending thereof.
  • the provision of such carrier pins is possible in a rapid and simple manner by means of modern spot-welding guns and the fitting or threading of the individual filling bodies on to the carrier pins can also take place in a relatively short time. In any case the extra expense involved therein bears no relation whatever to the advantages explained above which are obtained with the construction according to the invention.
  • the carrier elements can also be formed as support elements upon which the filling bodies rest freely, in which case then the support elements are expediently formed from a plurality of support ribs or the like, between which there remain in each case gaps for the through-flow of the reaction media.
  • the carrier elements can expediently be secured to the inner tube or rod-shaped insert with slight downward inclination, since this achieves a more stable arrangement of the filling bodies on the carrier elements.
  • the individual filling bodies can be formed with a shape widening conically towards the outer wall of the tube or in the case of the association of a plurality of filling bodies with the individual carrier elements these can be made correspondingly greater with increasing radial distance, in such manner that the interspaces between the individual filling bodies remain approximately equal in the peripheral direction.
  • FIGURE 1 is a lateral view of filling bodies secured on the inner tube of a counter-current tube unit according to the invention, the outer tube being omitted,
  • FIGURE 2 is a vertical along the line I-I in FIGURE 1 with outer tube
  • FIGURE 3 is a horizontal section through the arrangement according to FIGURES 1 and 2,
  • FIGURE 4 is a perspective view of a modified filling body embodiment with associated carrier pins.
  • FIGURE 5 is a lateral view similar to FIGURE 1, showing a modified embodiment of filling bodies and carrier elements,
  • FIGURE 6 is a section along the line 11-11 in FIG- URE 5,
  • FIGURE 7 is a lateral view similar to FIGURES 1 and 5, showing a further variant of the embodiment of filling bodies and carrier elements, and
  • FIGURE 8 is a section along the line III-III in FIG- URE 7.
  • the invention is explained with reference to a so-called counter-current tube, in which the invention can be used with particular advantage, since the inner tube of such counter-current tubes can be utilized for the securing of the carrier elements for the individual filling bodies.
  • the invention is obviously however also usable for simple tubes, in which case it is necessary to use a special insert of rod or tube form for the securing of the carrier elements, in place of the inner tube which is present in counter-current tubes.
  • FIGURES 1-3 show an especially advantageous form of embodiment of the invention, in which metallic carrier pins 3 are secured on the inner tube 2 of a counter-current tube unit in regular geometric arrangement so that regular interspaces are produced between annular filling bodies 4 pushed on to the carirer pins 3.
  • two annular filling bodies 4 are pushed on to each carrier pin 3, the outer filling bodies in the radial direction having a greater diameter so that the intervals between the individual filling bodies in the peripheral direction remain approximately equal.
  • further filling bodies or only one filling body on each carrier pin depending upon the size of the annular gap between inner tube 2 and outer tube 1.
  • the individual filling bodies can be made to widen conically towards the outer wall, in order to achieve a still better space utilization and still more regular flow conditions through constant interspaces between the individual filling bodies'in the peripheral direction.
  • the arrangement of the individual filling bodies 4a in accordance with the invention permits the selection of special shapings thereof which increase the effect of the filling bodies, without any danger of these filling bodies being destroyed by reason of their radial or axial bores or the like. Even profiled carrier pins 3a are usable.
  • FIGURES 5 to 8 are similar in principle to the embodiment according to FIGURES 1 to 4.
  • the filling bodies 4b and 4c are merely made spherical or cylindrical in place of the annular filling bodies 4 in the embodiment according to FIGURES 1 to 4, and rest on correspondingly formed support elements 3b and 30 respectively secured on the inner tube 2.
  • Naturally further modifications of the forms of the utilized filling bodies and of the carrier elements carrying these are also possible. It is essential only that each individual filling body is held in a predetermined position by the nature of its support and receives adequate space for movements caused by temperature, and that the outer tube jacket remains unloaded, so that it is not additionally stressed by the filling bodies.
  • the invention even permits utilization of filling body materials which have a chemically or physically attacking effect upon the tube material.
  • protective caps of neutral material on the outer ends of the carrier elements.
  • highly delicate tube materials for example ceramics or quartz, for certain special purposes.
  • the use of such materials becomes possible for the first time, since they are poorly capable of withstanding the stresses as described above which ocour on free pouring of filling bodies.
  • Reaction apparatus comprising in combination,
  • Apparatus according to claim 1 wherein the axially extending support means within the tube is an inner generally concentric tube.
  • the filling bodies have an aperture therethrough and a plurality of the filling bodies are allocated to the individual metallic pins, said filling bodies possessing correspondingly larger dimensions with increasing radial distance, so that the interspaces between the individual filling bodies remain approximately equal in the peripheral direction.
  • the carrier elements are metallic pins having one end Welded to said rod and the filling bodies have apertures therethrough through which the pins extend.
  • Apparatus according to claim 10 wherein the filling bodies have an aperture therethrough and a plurality of the filling bodies are allocated to the individual metallic pins, said filling bodies possessing correspondingly larger dimensions with increasing radial distance, so that the interspaces between the individual filling bodies remain approximately equal in the peripheral direction.
  • Apparatus according to claim 14 wherein a plurality of the filling bodies are allocated to the individual shelflike members, said filling bodies possessing correspondingly larger dimensions with increasing radial distance, so that the interspaces between the individual filling bodies remain approximately equal in the peripheral direction.
  • Reaction apparatus in which filling bodies are regularly arranged by carrier elements, characterized in that each single filling body is held by a carrier element with sufiicient space for expansion in all directions in a predetermined position within an outer tube arranged generally vertically and having an axially extending support means spaced therewithin, said carrier elements being attached and supported at one end thereof on said axially extending support means within the tube in position with respect to each other in a uniform predetermined arrangement whereby equal flow conditions exist at all points within the tube and the weight of the filling bodies is directly carried by the respective carrier elements.
  • Apparatus according to claim 18 wherein the individual filling bodies have a shape widening conically towards the surrounding tube wall.
  • Apparatus according to claim 18 wherein a plurality of filling bodies are allocated to the individual carrier elements, said bodies possessing correspondingly larger dimensions with increasing radial distance, so that the interspaces between the individual filling bodies remain approximately equal in the peripheral direction.
  • Apparauts according to claim 18 wherein the axially extending support means within the tube is an inner generally concentric tube.
  • Apparatus according to claim 24 wherein the car- 5 3,280,907 10/1966 Hoffman 165185 rier elements are metallic pins welded to the rod and the 3,154,386 10/1964 Lefren 23 277 filllling bodies gave apertures therethrough through which FOREIGN PATENTS e Pmscxten 116 547 2/1943 Australia 27. Apparatus accordmg to clalm 24 wherein the car- 783,521 9/1957 Great Britain.
  • rier elements are shelf-like members having an end sup- 10 ported by said rod and the filling bodies rest freely JAMESH TAYMAN JR Primary Examiner thereon.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
US47105465 1964-11-05 1965-07-12 Tube furnace provided with filling bodies Expired - Lifetime US3431082A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DES94051A DE1259850B (de) 1964-11-05 1964-11-05 Reaktionsapparat mit Fuellkoerpern

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US3431082A true US3431082A (en) 1969-03-04

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US47105465 Expired - Lifetime US3431082A (en) 1964-11-05 1965-07-12 Tube furnace provided with filling bodies

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US (1) US3431082A (nl)
AT (1) AT254828B (nl)
BE (1) BE663901A (nl)
CH (1) CH447123A (nl)
DE (1) DE1259850B (nl)
GB (1) GB1088517A (nl)
NL (1) NL145150B (nl)
SE (1) SE327971B (nl)

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3617227A (en) * 1969-05-05 1971-11-02 Midland Ross Corp Apparatus for catalytic reforming
US3790350A (en) * 1971-12-22 1974-02-05 Universal Oil Prod Co Apparatus for catalytic conversion of fluids
US4209466A (en) * 1973-07-10 1980-06-24 Basf Aktiengesellschaft Manufacture of formaldehyde
US4832837A (en) * 1987-04-13 1989-05-23 Frederick Loren D Apparatus for augmenting separation of oil and water
US6258900B1 (en) 1998-07-16 2001-07-10 Crystaphase International, Inc Filtration and flow distribution method for chemical reactors
US6291603B1 (en) 1997-07-18 2001-09-18 Crystaphase International, Inc. Filtration and flow distribution method for chemical reactors using reticulated ceramics with uniform pore distributions
US20020139510A1 (en) * 2001-03-30 2002-10-03 Ecti And Fukuda Metal Foil & Powder Co., Ltd Sheet-type regenerative heat exchanger and manufacturing method thereof, and regenerator and refrigerator using the same
US20040116751A1 (en) * 2002-12-12 2004-06-17 Brian Carvill Process for the synthesis of bisphenol
US20040192862A1 (en) * 2003-03-25 2004-09-30 Glover John N. Filtration, flow distribution and catalytic method for process streams
US20040225085A1 (en) * 2003-03-25 2004-11-11 Glover John N. Decontamination of process streams
US20050004406A1 (en) * 2003-07-01 2005-01-06 Brian Carvill Process for the synthesis of bisphenol
US20080181054A1 (en) * 2007-01-29 2008-07-31 Anemos Company Ltd. Fluid mixer
US20090145502A1 (en) * 2005-10-24 2009-06-11 Danfoss A/S Flow system and a micro fluidic system comprising a flow system
US8062521B2 (en) 1998-05-29 2011-11-22 Crystaphase Products, Inc. Filtering medium and method for contacting solids-containing feeds for chemical reactors
US20120048259A1 (en) * 2010-08-26 2012-03-01 Wagner & Co., Solartechnik GmbH Solar installation
US20150211805A1 (en) * 2014-01-29 2015-07-30 Kunshan Jue-Chung Electronics Co., Ltd. Thermostat module
US10054140B2 (en) 2016-02-12 2018-08-21 Crystaphase Products, Inc. Use of treating elements to facilitate flow in vessels
US10500581B1 (en) 2003-03-25 2019-12-10 Crystaphase International, Inc. Separation method and assembly for process streams in component separation units
US10744426B2 (en) 2015-12-31 2020-08-18 Crystaphase Products, Inc. Structured elements and methods of use
US11052363B1 (en) 2019-12-20 2021-07-06 Crystaphase Products, Inc. Resaturation of gas into a liquid feedstream
US11752477B2 (en) 2020-09-09 2023-09-12 Crystaphase Products, Inc. Process vessel entry zones

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2848086C2 (de) * 1978-11-06 1986-11-06 Kernforschungsanlage Jülich GmbH, 5170 Jülich Röhrenreaktor für katalytische Prozesse

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GB783521A (en) * 1954-04-29 1957-09-25 Power Jets Res & Dev Ltd Heat-transfer wall structures
US3154386A (en) * 1960-10-11 1964-10-27 Hercules Powder Co Ltd Apparatus for pyrolysis of hydrocarbons
US3280907A (en) * 1964-09-01 1966-10-25 Hoffman Sidney Energy transfer device
US3283028A (en) * 1961-10-31 1966-11-01 Mobil Oil Corp Thermal conversion process and apparatus therefor

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DE822085C (de) * 1950-04-30 1951-11-22 Stickstoffduenger Ag F Vorrichtung zur gleichmaessigen Verteilung von Fluessigkeiten in Fuellkoerpersaeulen

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB783521A (en) * 1954-04-29 1957-09-25 Power Jets Res & Dev Ltd Heat-transfer wall structures
US3154386A (en) * 1960-10-11 1964-10-27 Hercules Powder Co Ltd Apparatus for pyrolysis of hydrocarbons
US3283028A (en) * 1961-10-31 1966-11-01 Mobil Oil Corp Thermal conversion process and apparatus therefor
US3280907A (en) * 1964-09-01 1966-10-25 Hoffman Sidney Energy transfer device

Cited By (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3617227A (en) * 1969-05-05 1971-11-02 Midland Ross Corp Apparatus for catalytic reforming
US3790350A (en) * 1971-12-22 1974-02-05 Universal Oil Prod Co Apparatus for catalytic conversion of fluids
US4209466A (en) * 1973-07-10 1980-06-24 Basf Aktiengesellschaft Manufacture of formaldehyde
US4832837A (en) * 1987-04-13 1989-05-23 Frederick Loren D Apparatus for augmenting separation of oil and water
US6291603B1 (en) 1997-07-18 2001-09-18 Crystaphase International, Inc. Filtration and flow distribution method for chemical reactors using reticulated ceramics with uniform pore distributions
US8062521B2 (en) 1998-05-29 2011-11-22 Crystaphase Products, Inc. Filtering medium and method for contacting solids-containing feeds for chemical reactors
US6258900B1 (en) 1998-07-16 2001-07-10 Crystaphase International, Inc Filtration and flow distribution method for chemical reactors
US20020139510A1 (en) * 2001-03-30 2002-10-03 Ecti And Fukuda Metal Foil & Powder Co., Ltd Sheet-type regenerative heat exchanger and manufacturing method thereof, and regenerator and refrigerator using the same
US7112702B2 (en) 2002-12-12 2006-09-26 General Electric Company Process for the synthesis of bisphenol
US20040116751A1 (en) * 2002-12-12 2004-06-17 Brian Carvill Process for the synthesis of bisphenol
US20040192862A1 (en) * 2003-03-25 2004-09-30 Glover John N. Filtration, flow distribution and catalytic method for process streams
US10500581B1 (en) 2003-03-25 2019-12-10 Crystaphase International, Inc. Separation method and assembly for process streams in component separation units
US10525456B2 (en) 2003-03-25 2020-01-07 Crystaphase International, Inc. Separation method and assembly for process streams in component separation units
US7265189B2 (en) 2003-03-25 2007-09-04 Crystaphase Products, Inc. Filtration, flow distribution and catalytic method for process streams
US7393510B2 (en) 2003-03-25 2008-07-01 Crystaphase International, Inc. Decontamination of process streams
US10543483B2 (en) 2003-03-25 2020-01-28 Crystaphase International, Inc. Separation method and assembly for process streams in component separation units
US20040225085A1 (en) * 2003-03-25 2004-11-11 Glover John N. Decontamination of process streams
US20050004406A1 (en) * 2003-07-01 2005-01-06 Brian Carvill Process for the synthesis of bisphenol
US7132575B2 (en) 2003-07-01 2006-11-07 General Electric Company Process for the synthesis of bisphenol
US20090145502A1 (en) * 2005-10-24 2009-06-11 Danfoss A/S Flow system and a micro fluidic system comprising a flow system
US20080181054A1 (en) * 2007-01-29 2008-07-31 Anemos Company Ltd. Fluid mixer
US20120048259A1 (en) * 2010-08-26 2012-03-01 Wagner & Co., Solartechnik GmbH Solar installation
US20150211805A1 (en) * 2014-01-29 2015-07-30 Kunshan Jue-Chung Electronics Co., Ltd. Thermostat module
US10744426B2 (en) 2015-12-31 2020-08-18 Crystaphase Products, Inc. Structured elements and methods of use
US11000785B2 (en) 2015-12-31 2021-05-11 Crystaphase Products, Inc. Structured elements and methods of use
US10876553B2 (en) 2016-02-12 2020-12-29 Crystaphase Products, Inc. Use of treating elements to facilitate flow in vessels
US10655654B2 (en) 2016-02-12 2020-05-19 Crystaphase Products, Inc. Use of treating elements to facilitate flow in vessels
US10662986B2 (en) 2016-02-12 2020-05-26 Crystaphase Products, Inc. Use of treating elements to facilitate flow in vessels
US10738806B2 (en) 2016-02-12 2020-08-11 Crystaphase Products, Inc. Use of treating elements to facilitate flow in vessels
US10557486B2 (en) 2016-02-12 2020-02-11 Crystaphase Products, Inc. Use of treating elements to facilitate flow in vessels
US10161428B2 (en) 2016-02-12 2018-12-25 Crystaphase Products, Inc. Use of treating elements to facilitate flow in vessels
US10920807B2 (en) 2016-02-12 2021-02-16 Crystaphase Products, Inc. Use of treating elements to facilitate flow in vessels
US10054140B2 (en) 2016-02-12 2018-08-21 Crystaphase Products, Inc. Use of treating elements to facilitate flow in vessels
US11156240B2 (en) 2016-02-12 2021-10-26 Crystaphase Products, Inc. Use of treating elements to facilitate flow in vessels
US11754100B2 (en) 2016-02-12 2023-09-12 Crystaphase Products, Inc. Use of treating elements to facilitate flow in vessels
US11052363B1 (en) 2019-12-20 2021-07-06 Crystaphase Products, Inc. Resaturation of gas into a liquid feedstream
US11731095B2 (en) 2019-12-20 2023-08-22 Crystaphase Products, Inc. Resaturation of gas into a liquid feedstream
US11752477B2 (en) 2020-09-09 2023-09-12 Crystaphase Products, Inc. Process vessel entry zones

Also Published As

Publication number Publication date
DE1259850B (de) 1968-02-01
AT254828B (de) 1967-06-12
SE327971B (nl) 1970-09-07
GB1088517A (en) 1967-10-25
NL6505931A (nl) 1966-05-06
CH447123A (de) 1967-11-30
NL145150B (nl) 1975-03-17
BE663901A (nl) 1965-09-01

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