US3410765A - Sonic distillation process and apparatus - Google Patents

Sonic distillation process and apparatus Download PDF

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US3410765A
US3410765A US575680A US57568066A US3410765A US 3410765 A US3410765 A US 3410765A US 575680 A US575680 A US 575680A US 57568066 A US57568066 A US 57568066A US 3410765 A US3410765 A US 3410765A
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oscillator
sonic
liquid
mass
vapor
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US575680A
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Albert G Bodine
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Priority to GB32639/67A priority patent/GB1189513A/en
Priority to DE19671619687 priority patent/DE1619687A1/en
Priority to ES344521A priority patent/ES344521A1/en
Priority to IL28573A priority patent/IL28573A/en
Priority to ES358111A priority patent/ES358111A1/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01BBOILING; BOILING APPARATUS ; EVAPORATION; EVAPORATION APPARATUS
    • B01B1/00Boiling; Boiling apparatus for physical or chemical purposes ; Evaporation in general
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/006Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping by vibration
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N25/00Investigating or analyzing materials by the use of thermal means
    • G01N25/14Investigating or analyzing materials by the use of thermal means by using distillation, extraction, sublimation, condensation, freezing, or crystallisation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S159/00Concentrating evaporators
    • Y10S159/90Concentrating evaporators using vibratory force
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S203/00Distillation: processes, separatory
    • Y10S203/11Batch distillation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S366/00Agitating
    • Y10S366/60Bodine vibrator

Definitions

  • This invention relates generally to sonic methods and means for speeding up certain thermodynamic processes involving equilibrium between two phases, such as between the liquid and vapor phases in a distillation process, e.g., as in a desalinization plant.
  • thermodynamic process consists in effect of the summation of a huge number of minute local transient processes or interactions of differing sizes, activities, or masses and/or consequences occurring simultaneously, and behaves or operates as a whole on a statistical basis in accordance with the average of such relatively minute or elemental local transient processes.
  • the philosophy underlying the present invention is that, by certain sonic methods and apparatus which I have contrived, the more favorable of the elemental transients participating in the process as a whole can be seized upon, so to speak, and availed of during their transitory exitence, to accomplish a favorable statistical shift from the normal average in the process as a whole, so as to improve the net output from the process.
  • minor transient thermodynamic fluctuations of nature favorable to the process are availed of while they persist, and the result is a favorable shift in the statistical average performance of the process.
  • the process of boiling is a complicated one whose basic characteristic is an evolution of vapor bubbles within the liquid at a certain boiling temperature, and the rise and escape of these bubbles at the liquid surface.
  • the process involves many variable determinants. Assuming water as the boiling medium, it is most commonly neither pure, nor uniform.
  • the boiling temperature may be considerably above 212 F. because of inclusions or impurities. It also varies with pressure, as is known. Surface tension somewhat elevates boiling temperature above what it would otherwise be.
  • the sonic field also apparently has the effect of reducing surface tension at the liquid surface, and therefore actually reducing the boiling temperature. ⁇
  • the sonic system of the invention also tends to agglomerate minute quantities of air and other gases trapped between liquid molecules, and these gases, thus gathered into larger particles, can then rise and leave as bubbles, further activating the boiling process.
  • the invention employs application of a sonic wave field to the liquid to be boiled.
  • This radiator and the special later-described resonant sonic driving means behind it operate automatically in -a manner to accommodate certain continuously varying conditions in the liquid during boiling.
  • These varying conditions are of two kinds: The first is resistive, or power consuming, and corresponds with resistance in an electrical system, or friction or other energy dissipation in a mechanical system.
  • the second is reactive, or nonpower consuming, corresponding, by analogy to electrical alternating current systems, to the algebraic difference between inductive reactance and capacitance reactance, and by analogy to ordinary mechanical vibration systems, to the algebraic difference between mass reactance and elastic compliance reactance.
  • the liquid boiling medium represents a large resistive or energyconsuming load factor presented to the sonic wave source, being composed of the resistance of the liquid body to oscillation by the sonic wave and the energy dissipation involved, plus the larger energy dissipation involved in the evolution of vapor bubbles and the resulting general agitation caused by their creation and their movement through the liquid body.
  • Cavitation is apparently also an energy dissipating phenomenon, and there may be other ways in which energy is dissipated. Now, these energy dissipating factors are comparatively irregular, sporadic, and may take place somewhat in bursts.
  • the resistive load in sonically stimulated or activated boiling is a variable one.
  • the resonant acoustic circuit comprises, first, a sonic wave generator or oscillator of a special orbital-mass type, which, in conjunction with a resonator, which is the component of the circuit, has the desired automatic accommodation to the impedance variations of the load.
  • My orbital-mass vibration generators or oscillators may take various mechanical forms, one of the simplest and best of which involves a roller mass rolling around in a bearing, so that the mass generates a centrifugal force which is reactively opposed by the bearing.
  • the bearing is in a housing, which in response to the centrifugal force so generated, exerts a periodic inertial force on whatever may support it or be coupled thereto. Examples of suitable forms of such orbital-mass generators are disclosed in my Patents Nos. 2,960,314 and 3,217,551.
  • the resonant acoustic circuit comprises next, as mentioned above, a vibratory resonator, and this member is acoustically coupled to the housing of the orbital-mass oscillator.
  • This resonator terminates in the aforementioned vibratory wave radiator, which is in turn acoustically coupled to the liquid body to be boiled, which comprises, as already mentioned, the variable impedance load.
  • the oscillator is equipped with a driving means or power source, generally in the nature of a motor of some sort, either electrical, pneumatic, internal combustion engine, or any other found suitable.
  • this driving motor for the oscillator be powered so as to tend to operate at the resonant frequency of the acoustic circuit, and by having the driving motor tend normally to drive the oscillator at a frequency just under that for peak resonance, a number of additional important advantages are gained, particularly when using a driving motor which has a characteristic of inverse speed responsiveness to loading torque imposed upon it by the oscillator and the balance of the acoustic system. These advantages will be spoken of more particularly hereinafter.
  • the driving motor, oscillator, resonator, and the variable impedance load constituted by the boiling body of liquid make up a discrete acoustic circuit.
  • the impedance of the resonantly vibratory resonator, or of any vibratory portion of the acoustic circuit is a complex quantity proportional to the ratio of force to vibratory velocity at any point along the resonator, or in the acoustic circuit as a whole.
  • the impedance of the load depends upon the vector resultant of the reactances and resistances of the load. This impedance, and the optimum phase angle, power factor and frequency for desired resonant performance, with maximum power delivery to the load, depends upon the magnitudes of these parameters at any particular instant, and can and do vary from instant to instant.
  • the orbital-mass oscillator accommodates automatically and instantaneously in response to these variations in impedance, including change of phase angle of its orbiting mass relative to the motion of the vibrating resonator, with accompanying change of power factor, and/or frequency, assuring thereby effete and sustained delivery of large sonic energy to the load, under which conditions the boiling process is most powerfully sonically activated.
  • the orbital-mass oscillator adjusts its output frequency to maintain resonance with changes in impedance of the circuit.
  • the system automatically adjusts its frequency to itself in optimum resonant operation by virtue of a resonant frequency lockin characteristic of the orbital-mass generator.
  • the orbital-mass oscillator and its drive motor are dimensioned and designed so that, with the drive effort properly adjusted, the oscillator will tend to lock in for operation at a frequency just on the low side of that for peak resonance.
  • the oscillator then automatically changes its frequency and also its phase angle and therefore its power factor to correspond with changes in both the resistive and reactive components of load impedance comprised of the boiling body of liquid as the boiling process proceeds and as sporadic variations in activity take place throughout the liquid from instant to instant.
  • the drive effort can readily be adjusted so that the system locks in, as already mentioned, at just below the resonant frequency of the circuit, inclusive of the load. An excellent frequency stability is thereby established.
  • libe orbital-mass oscillator as described, coupled to a resonator, particularly an elastically vibratory equivalently half-wavelength standing wave system terminated by a high-impedance wave radiator, with the latter sonically coupled to the liquid body, affords a very powerful vibratory system.
  • a resonator particularly an elastically vibratory equivalently half-wavelength standing wave system terminated by a high-impedance wave radiator, with the latter sonically coupled to the liquid body, affords a very powerful vibratory system.
  • Such a system moreover, can be readily designed with sufficient elastic compliance reactance to counteract the mass reactance of the relatively heavy resonator member and oscillator housing at the resonant operating frequency, and thus virtually cancel out forcewasting mass blocking effects.
  • the elastic compliance reactance in such a system can readily be made sufliciently large to afford resonant magnification of vibratory amplitudes in the system, and to provide also a large energy storage property (often designated Q).
  • the system also has a surprising frequency stabilizing feedback effect from the resonator to the oscillator, provided that the oscillator be designed to deliver a cyclic impulse properly related to the reactance and resistance of the resonator and of the load, s-o that the oscillator and resonator tend to maintain a frequency just below that for peak resonance, as explained above, and provided further that I drive the oscillator of this cornbination with a characteristic of inverse speed responsiveness to load.
  • the oscillator then both locks in at such frequency, and automatically adjusts its phase angle to the load resistance.
  • the frequency adjusts to the load reactance.
  • a further feature of the invention is the use of a sonic wave generating system, preferably again of the orbitalmass oscillator type, for establishing a standing sound wave in the vapor space within the boiler.
  • the sonic standing wave so developed results in agglomeration or gathering together of vapor molecules for effective condensation thereof.
  • the agglomeration effect is owing to migration of vapor molecules to nodal regions of the standing wave established within the vapor space. Minute water droplets also migrate to the nodal regions of the standing wave, and these agglomerate or coalesce to fall out like rain.
  • the advantage of the orbital-mass oscillator and resonator system is that it can accommodate, in a manner analogous to that described hereinabove in regard to the boiling phase of the process, for changes in the total vapor load, and for the condensation rate, by the type of performance hereinabove described by which the orbital-mass system accommodates for both reactive and resistive components of total impedance in the load.
  • a further preferred and advantageous feature of the particular form of the invention here chosen for illustrative purposes is the use of sonic oscillators, again preferably of the orbital-mass resonance type because of the peculiar advantages thereof hereinabove mentioned, in connection with the condensation tubes of the boiler through which the brine input flows on its way to the heat exchanger.
  • the sonic action so applied t-o the condensation tubes has a number of effects, one of which is that as vapor is condensed against the outside of the tube, the sonic vibration quickly throws this condensed liquid free so that it can drop into a collection tray. This then instantly exposes the pipe for condensation of further vapor, affording a high performance rate. A much higher performance for a given amount of pipe surface area is thus attained.
  • the standing wave in the vapor space around the condensation pipes greatly increases the rate of condensation by virtue of migration and agglomeration of the larger vapor molecule groups.
  • a sonic resonant system comprising an elastically vibratory resonator member in combination with an orbiting-mass oscillator or vibration generator is employed in my invention.
  • This combination has many unique and desirable features.
  • this orbitingmass oscillator has the ability to adjust its input power and phase to the resonant system so as to accommodate changes in the work load, including changes in either or both the reactive impedance and the resistive impedance. This is a very desirable feature in that the oscillator hangs on to the load even as the load changes.
  • this unique advantage of the orbiting-mass oscillator accrues from the combination thereof with the acoustic resonant circuit, so as to comprise a complete acoustic system.
  • the orbiting-mass oscillator is matched up to the resonant part of its system, and the combined system is matched up to the acoustic load, or the job to be accomplished.
  • the combined system has a unique performance which is exhibited in the form of a greater effectiveness and particularly greater persistence in a sustained sonic action as the work process proceeds or goes through phases and changes of conditions.
  • the orbiting-mass oscillator in this matched-up arrangement, is able to hang on to the load and continue to develop power as the sonic energy absorbing environment changes with the variations in sonic energy absorption by the load.
  • the orbiting-mass oscillator automatically changes its phase angle, and therefore its power factor, with these changes in the resistive impedance of the load.
  • a further important characteristic which tends to make the orbiting-mass oscillator 4hang on to the load and continue the development of effective power, is that it also accommodates for changes in the reactive impedance of the acoustic environment while the work process continues. For example, if the load tends to add either inductance or capacitance to the sonic system, then the orbiting-mass oscillator will accommodate accordingly. Very often this is accommodated by an automatic shift in frequency of operation of the orbiting-mass oscillator by virtue of an automatic feedback of torque to the energy source which drives the orbiting-mass oscillator. In other words, if the reactive impedance of the load changes this automatically causes a shift in the resonant response of the resonant circuit portion of the complete sonic system. This in turn causes a shift in the frequency of the orbitingmass oscillator for a given torque load provided by the power source which drives the orbiting-mass oscillator.
  • the sonic oscillator is especially beneficial to couple the sonic oscillator at a low-impedance (high velocity vibration) region, for optimum power input, and then have high impedance (high force vibration) at the work point.
  • the sonic circuit is then functioning additionally as a transformer, or acoustic lever, to optimize the effectiveness of both the oscillator region and the work delivering region.
  • FIG. 1 is a schematic layout of a system in accordance with the invention, parts being shown in elevation and parts in section;
  • FIG. 2 is a partly broken away view of a typical simple oscillator of the orbital-mass type.
  • the numeral 10 designates generally a combined boiler and condensation tank, the tank having, as shown, end walls 11 and 12, a top wall 13, a bottom wall 14, a side wall 1S, and another side wall opposite to wall 15, not shown.
  • the walls of this tank are of steel, and in the illustrative embodiment the upper wall 13 in particular is elastically vibratory in a standing wave pattern, as to be described, while the end walls 11 and 12 are quite stiff so as to fairly firmly support the end edges of the vibratory top wall 13.
  • the tube or tubes 17 lead via pipeline 19 to a header 2G at the end of a heat exchanger 22, the latter having an external casing 23, conventional tube sheets 24, heat exchanger tubes 25, and an outlet header 26, to which is coupled heated brine outlet pipe 30.
  • a heating uid is introduced to the space around the tubes 25 via an inlet 31 and leaves via an outlet 32.
  • the heated brine pipe 30 opens into the lower end or liquid space of boiler and condenser tank 10, supplying the heated water or brine to the latter, forming a liquid body 33.
  • a pipe line 34 withdraws brine from the lower portion of tank 10, and rises to a level, as shown, to establish the liquid level in the tank ttl.
  • a tray 3S adapted to collect water particles thrown off the tube 17, and this tray is mounted on and discharges through a pipe 4i) lcading out of tank l@ as clearly shown ⁇
  • a sonic circuit means comprised of an orbital-mass vibration generator or oscillator 42, and an elastically vihratory resonator generally designated by the numeral 44.
  • the resonator 44 may be embodied in various forms, but in the case here instanced, comprises a downwardly extending and downwardly tapering elastic stem or bar 45, having at the top an annularly enlarged vibratory head or piston 46, preferably faced at the top with a layer of rubber-like material such as polyurethane or silicon rubber, in order to increase the coupling coe'icient from the piston 46 to the liquid.
  • the piston 46 lits closely within the annular wall 48 of a pan or shroud 49 which is mounted in the lower tank wall 14, and fastened thereto as indicated. The close spacing presents a high impedance in the liquid annulus between the piston and shroud, so as to minimize loss of energy down past the piston.
  • Stem 45 protrudes downwardly through the bottom wall of the pan 49 by way of an opening 50, and the resonator 44 is supported by its annularly enlarged head 46 by means of a pneumatic vibration isolator tube 52 of rubber-like material, encircling stem 45 above the bottom of the pan and supportingly engaging the upper extent of the stem 45 and the underside of head 46, for example as clearly illustrated in FIG. 1.
  • the pneumatic tube 52 is inflated so as to support vibratory action of the resonator, and act also as a seal against the bottom wall of the pan. It engages the stem at a node of the vibratory system, and, being protected from leakage of sonic energy between the piston and shroud, is not subjected to very substantial pressure fluctuations and consequent energy loss from the piston.
  • the tube 52 functions as a shunt compliance, or decoupler, to prevent wave generation and high impedance blocking effects on the underside.
  • the orbital-mass oscillator 42 at the lower terminal of stem 45 may be, for example, any suitable one of a number of those shown in my aforesaid Patents Nos. 2,960,314 and 3,217,551.
  • the oscillator will be referred to in more particular hereinafter, and for the time being it will merely be mentioned that its function is to deliver against the lower end of stem 45 a periodic cyclic force or force component oriented along thc direction line of the stem.
  • the stem 45 taken together with the enlarged head is designed to vibrate elastically along the longitudinal direction line of the stem in the classic manner of a half-wavelength elastic bar undergoing resonant elastic vibration in the longitudinal mode, i.e, according to a half-wavelength longitudinal resonant standing wave pattern.
  • a longitudinal resonant half-wavelength standing wave pattern involves a node, a region of minimized vibration amplitude, at the midpoint, and antinodes, or regions of maximized vibration amplitude, at the two extremities.
  • Each half length of the bar alternately elastically contracts and expands, and
  • the present device comprised of the stem 45 and the piston or head 46, is, very broadly speaking, an equivalent for the classic uniform half-wavelength longitudinally vibratory bar, but a very material improvement thereupon.
  • the structure has, as in the case of the classic half-wavelength bar, a nodal point, here designated at N, and velocity antinodes V at the extremities. In the specific embodiment of FIG. l, one extremity will be seen to be within the lower end oscillator 42, and the other at the top of the piston 46.
  • the structure vibrates along the vertical longitudinal axis with the portion above the node N always traveling in phase opposition to the portion of the structure below the node N.
  • the distance from node N to the lower velocity antinode V may be somewhat greater than a half wavelength, notwithstanding the lumped mass effect of the oscillator because of the tapered and thus considerably slenderized form of the stern 45.
  • the portion of the structure above the node N which will be seen to be constituted partly of an upper portion of the stem 4S together with the entirety of the head or piston 46, is considerably shorter than a half wavelength because of the very great concentration of mass.
  • the upper face or end of the piston 46 then vibrates with high impedance, or in other words, with great force but through small displacement distance and at small velocity amplitude.
  • the lower extremity of the stem 45 by contrast, vibrates with substantially lower impedance, and therefore with less force amplitude and greater displacement and velocity amplitude.
  • the upper high impedance end of the piston 46 then has the necessary high impedance for effective acoustic coupling to the liquid. As mentioned hereinabove, some improvement in the coupling coeflicient is attainable by use of the rubber-like facing on the piston.
  • the configuration of the downwardly tapering stem 45 joining the enlarged piston 46 at the top to the oscillator at the bottom is in elfect an acoustic lever or transformer, matching a lower impendance oscillator 42 at the lower end to a relatively high impedance radiator 46 at the top.
  • the system is thus an acoustic transformer, giving optimized impedance for the separate special functions at the terminations.
  • the large lumped masses tend towards shortening of the distances from the node to the upper and lower antinodes, whereas the downward tapering or slenderizing of the bar 45 increases the elastic compliance in this part of the device, and progressively reduces the impendance downwardly along the stem.
  • the mass and elasticity reactances 9 of the vibratory resonator are thus, by a balance of these parameters, brought towards equalization with one another at the resonant frequency, with the very desirable consequence of reduction or elimination of oscillator force otherwise consumed in the vibration of the masses.
  • FIG. 2 I have shown a partially broken away view of a simple and illustrative orbital-mass type oscillator 42. It comprises simply a housing 53 on the lower endof stem 45, with a cylindrical bearing surface 54 therein for a cylindrical orbital-mass rotor 55, the diameter of the rotor 55 being somewhat less than that of the race 54, for example as illustrated in FIG. 2, and the rotor 55 being adapted to travel in an orbital path guided by the bearing surface 54.
  • the rotor 55 is driven in this orbital path by air under pressure introduced tangentially into the chamber defined by bearing surface 54 via a tapering nozzle 56 fed with air under pressure through a hose or pipe 57, the latter leading from a suitable source of air under pressure.
  • a port such as 58.
  • controllable means not shown, for regulating the ow of pressure air to the oscillator.
  • the pressurized air introduced into the oscillator is thus controlled to cause the rotor 55 to gyrate or follow its orbital path around the raceway 54 at a frequency corresponding to the resonant frequency of the liquid-loaded resonator 44, or just below the peak of such resonance, as explained hereinabove.
  • the driving means for the oscillator thus in this case comprises a fluid pressure system, affording considerable slip between the introduced air and the rotor 52, so that the oscillator has the desirable characteristic of slip in the air stream, producing a substantial inverse speed responsiveness to the load portion of the acoustic circuit.
  • the heat exchanger 22 of the system is preferably equipped with a sonic wave generation system and resonator of the nature just described, utilizing a resonator 44a exactly like resonator 44, an oscillator 42a exactly like oscillator 42, with the piston portion 46a of the oscillator 42a this time accommodated in a pan 60 hung from the bottom wall of the heat exchanger tank with a lar-ge port 62 alording unobstructed communication between the interior of the pan and the heat exchanger tank.
  • the piston 46a radiates sound waves upwardly into heating liquid of the heat exchanger, with the effect of scrubbing away heat-insulated boundary layers on the surfaces of the heat exchanger tubes 25, and thus improving heat transfer.
  • the system as so far described then operates as follows: Brine is circulated inwardly through the brine tubes 17 running through the vapor space of the boiler and condenser tank 10. This brine then ows via line 19 to the heat exchanger, through the tubes thereof, which are surrounded by a heating fluid circulated between an inlet 31 and an outlet 32. The brine is thereby heated to a temperature typically of the order of 250 F., and thence introduced, via pipe 30, into the lower end of the tank 10. Oscillator 42 is then driven, and the orbitally traveling cylindrical rotor 55 then exerts on the oscillator housing 53 a force vector which rotates about the central axis of the bearing 54 at some frequency determined by the pressure and flow of air into the chamber of the oscillator.
  • the piston member 46 radiates strong sonic vibrations into the liquid body 33. These sonic vibrations can be radiated into the liquid body 33 at large, or, with increased advantage, so as to establish standing wave patterns in the liquid. In the rst case, compressional waves are transmitted through the liquid body causing pressure and oscillations therein such as are characteristic of any sound wave transmission. It is also possible to set up a standing wave system, with nodes and antinodes.
  • the sound waves radiated from the top of the radiator piston 46 upon encountering the interface between the liquid body 33 and the vapor space above, are reliected back downwardly; and if the height of the liquid over the piston corresponds properly with the vibration frequency of the piston, certain known interference phenomena take place with the result that a standing wave system is established within the body of the liquid.
  • Such a system will of course have regions of maximized and minimized liquid oscillation velocities and pressure Variation-s, leading to materially increased mobility within the liquid body, and ease and speed of travel of the evolved Vapor bubbles through the body of the liquid.
  • the process of the invention instead, facilitates and speeds up the boiling process, affording increased throughput per hour, for example, within a plant of a -given scale.
  • the invention produces a condition within the boiling body of water by which the vapor of small and often transient boiling-condensation equilibrium system-s can be removed therefrom, and by which vapor molecules, as well as all vapor bubbles evolved in the boiling process, are additionally mobilized and thus rise from the body of liquid in reduced time, or with greater speed.
  • a further important feature of the invention is to create a sonic wave condition, preferably a sonic standing wave, within the tank 10 in the condensation region thereof.
  • a sonic vibration generator or oscillator again of the orbital-mass type.
  • a vibration generator is designated at 7th in the drawings, and it will be understood that the generator 70 may be of the type of FIG. 2, for example, con-taining an orbitally traveling mass roller, or may be any of the orbital-mass types referred to hereinabove.
  • the oscillator 70 is driven at a frequency to create a lateral standing wave in the top wall 13 of the tank, which possesses sufficient elasticity to develop such wave action,
  • the end walls of the tank are stiff enough to remain fairly stationary during the lateral vibratory action of the wall 13, so that with a proper frequency, a one and one-half wavelength standing wave is developed, with a pattern such as designated at si, having nodes or pseudonodes N at the end walls of the tank and at half-wavelength distances inwardly therefrom, and three intervening velocity antinodes V.
  • the top tank wall 13 elastically deects as represented by the standing wave diagram sl, producing corresponding pressure and velocity conditions in the vapor space.
  • the bottom surface of the wall 13 thus radiates sound waves downwardly into the region of the tank where condensation is to occur.
  • This wave action results in an action characterized by condensation of the vapor into minute droplets which immediately agglomerate and fall out of the vapor space like rain.
  • Such agglomeration effect is owing to migration of vapor or water molecules, or fine Water droplets, to nodal regions of the standing wave within the vapor space.
  • minute particles or droplets within the standing wave area migrate from the regions of maximum vibration displacement and velocity' amplitude to regions of minimized displacement and velocity amplitude, so that minimized work is done thereon.
  • the oscillator 70 together with the elastically vibratory tank top 13 vibrating in a resonant standing wave pattern will ⁇ be seen to be an orbitalmass oscillator and resonator system, with a variable load, the latter varying with changes in the total vapor load and in the condensation rate.
  • the advantage here is that -f this system can accommodate or self-regulate itself in response to changes in the total vapor load and for the condensation rate, in accordance with principles discussed hereinabove, responding, in this connection, to both changes in reactive and resistive impedance such as is useful in gaining an optimum performance rate.
  • a further advantageous feature of invention is the use of orbital-mass type oscillators mounted on the condenser tubes 17.
  • Such an oscillator 80 is shown mounted on one of the tubes 17 in the drawings, and is shown as placed on the tube 17 midway between the end walls 11 and 12 of the tank, i.e., at a selected Velocity antinode V.
  • the end walls of the tank again establish nodal regions, and the oscillator S is again driven so as to provide a resonant standing wave in the tube 17, such as diagrammed at sl'.
  • the oscillator 80 is again driven, through any suitable source of drive, so as to generate the resonant standing wave pattern sl in the tube 17 corresponding to that set up in the top Wall 13.
  • the wave pattern is again a'ssumed to be a lateral type, though gyratory or other modes may be used. It will of course be understood that the vapor condenses on these tubes 17 and tends to collect thereon. The wave action developed in the tubes 17 quickly throws off this condensed water so that it can drop into the collection tray 38. This exposes the tube for condensation of further vapor, and so improves the performance rate. The result is higher performance for a given amount of pipe surface area. Condensation onto the pipes 17 is also promoted by the standing waves in the vapor space which materially increase the rate of condensation by virtue of migration and agglomeration of the larger vapor molecule groups or combinations to the nodal regions of the wave where they are crowded together.
  • orbital-mass oscillators 80 may in many instances be either electric-motor driven, or shaft driven, many illustrative forms of which are shown in my aforementioned patents. These types of oscillator drive avoid any problem which might arise out of discharge of air into the tank. Air driven oscillators may, however, be successfully used provided the air discharged into the vapor space does not result in a shift in the heat balance.
  • system of the invention in its preferred, illustrative form employs, in different parts of the apparatus and for different purposes, use of sonic waves generated in liquid, solid a'nd in vapor media.
  • a sonically aided boiler comprising:
  • a boiler tank for holding a body of heated liquid to be boiled
  • a heater for preheating the liquid prior to discharge into the Aboiler tank; and a vibratory resonator coupled to said oscillators and vibrated in its resonant frequency range thereby,
  • said oscillator and resonator including a vibratory sonic wave radiator immersed in and thereby coupled to said body of liquid.
  • means for driving said oscillator including a power source having the characteristic of inverse speed responsiveness to torque load, and which is powered to drive said resonator in the range of resonance but on the low side of the frequency for the peak of resonance for said resonator.
  • said oscillator comprises an orbital-mass rotor, and a housing having a bearing engaged by and defining an orbital path for said orbital-mass rotor;
  • said oscillator comprises an equivalent half-Wavelength longitudinally elastically vibratory member of generally elongated form having velocity antinodes at its extremities and an intervening node, and having said wave radiator at one extremity thereof positioned within and thereby a'coutically coupled to said body of liquid, and having said housing of said oscillator iixed on the other extremity thereof.
  • said elastically vibratory member includes a stem, a radially enlarged piston on one extremity of said stem to form said wave radiator, and said housing of said oscillator at the other end thereof.
  • an orbital-mass oscillator coupled to said resonator and including a vibratory radiator exposed to vapor and any water droplets in said space and operable to set up in the vapor in said space a resonant sonic standing Wave;
  • an orbital-mass oscillator coupled to said resonatng condenser and operable to set up resonant standing Wave vibration thereof;

Description

Nov. 12, 1968 A. G. BoDlNE SONIC DISTILLATION PROCESS AND APPARATUS Filed Aug. 29, 1966 United States Patent O 3,410,765 SONIC DISTILLATION PROCESS AND APPARATUS Albert G. Bodine, Los Angeles, Calif. (7877 Woodley Ave., Van Nuys, Calif. 91406) Filed Aug. 29, 1966, Ser. No. 575,680 Claims. (Cl. 203-10) ABSTRACT 0F THE DISCLOSURE Liquid to be boiled is preheated and simultaneously exposed to sonic vibrations. The liquid is fed from the preheater to a cooler tank. Sonic vibratory energy `is generated by means of a sonic oscillator and vibratory resonator which is sonically coupled to the liquid in the boiler tank to create sonic vibrations therein.
This invention relates generally to sonic methods and means for speeding up certain thermodynamic processes involving equilibrium between two phases, such as between the liquid and vapor phases in a distillation process, e.g., as in a desalinization plant.
Such a thermodynamic process consists in effect of the summation of a huge number of minute local transient processes or interactions of differing sizes, activities, or masses and/or consequences occurring simultaneously, and behaves or operates as a whole on a statistical basis in accordance with the average of such relatively minute or elemental local transient processes. In a major aspect, the philosophy underlying the present invention is that, by certain sonic methods and apparatus which I have contrived, the more favorable of the elemental transients participating in the process as a whole can be seized upon, so to speak, and availed of during their transitory exitence, to accomplish a favorable statistical shift from the normal average in the process as a whole, so as to improve the net output from the process. Thus minor transient thermodynamic fluctuations of nature favorable to the process are availed of while they persist, and the result is a favorable shift in the statistical average performance of the process.
Speaking generally, consider the condensate output from a distillation process. Clearly, a small percentage increase in vapor evolved at a given temperature, or conversely, vapor condensed at a given temperature, can substantially improve the net output yield of condensate. It is a general object of the invention to accomplish, by special sonic means, such improvement.
The process of boiling is a complicated one whose basic characteristic is an evolution of vapor bubbles within the liquid at a certain boiling temperature, and the rise and escape of these bubbles at the liquid surface. The process involves many variable determinants. Assuming water as the boiling medium, it is most commonly neither pure, nor uniform. The boiling temperature may be considerably above 212 F. because of inclusions or impurities. It also varies with pressure, as is known. Surface tension somewhat elevates boiling temperature above what it would otherwise be. Also, apparently, there are many small localized equilibrium systems within the body of the liquid, comprised of small or minute vapor bubbles wherein vaporization may be momentarily at equilibrium with condensation, and these systems may shift so that vaporization exceeds condensation, leading to rise and release of the vapor, or so that condensation exceeds vaporization, leading to termination of the transient without net result.
Application of a high-energy sonic eld to a body of liquid undergoing the boiling phenomenon increases general mobility within the heated liquid by setting up in the liquid substantial flow oscillations. These are characterized by pressure and velocity fluctuations of considerable magnitude, which have the effect of speeding the vapor bubbles through the liquid body and to and through the liquid surface. The rate of vaporization is thus increased by the improved mobility, both by hurrying along those normally evolved vapor bubbles which would escape from the liquid body in any event, and by speeding to and through the surface the more active vvapor molecules, as well as certain small transient vapor bubbles otherwise destined for return to the liquid phase.` The average vaporization rate throughout the liquid body is thus favorably shifted.
The sonic field also apparently has the effect of reducing surface tension at the liquid surface, and therefore actually reducing the boiling temperature.`
Still further, when the high-energy sonic wave system is superimposed on the liquid, the pressure excursions of elastic vibration of the fluid body on the negative halfcycles cause cavitation in the liquid, which is of course productive of vapor bubbles. These bubbles, once formed, tend to persist rather than collapsing on the positive halfcycles of the wave, there apparently being a boundary condition at the interface which tends toward retardation of the collapse of the vapor bubbles until the next negative pressure or cavitation half-cycle again occurs. Thus these vapor bubbles tend to persist, and owing to the high mobility of the liquid body under the influence of the sonic wave eld, these vapor bubbles caused by cavitation move to the surface and escape in aid of the boiling process.
The sonic system of the invention also tends to agglomerate minute quantities of air and other gases trapped between liquid molecules, and these gases, thus gathered into larger particles, can then rise and leave as bubbles, further activating the boiling process.
From the above considerations, it will be evident that the boiling process, particularly when subjected to a sonic wave field, is inherently a sporadic process, with changes in conditions from instant to instant. The sonic system, to work really effectively, and to accomplish a large economic benefit, must adapt itself automatically, continuously and speedily to accommodate these changes in operating conditions. It is accordingly a major and most important object of the invention to provide a resonant sonic wave generating system, in combination with a boiling process, which automatically undergoes certain variations in phase angle, power factor and frequency in almost instantaneous accommodation to changes that take place in the boiling process under sonic activation, so that sonic energy application to the liquid to be boiled will be constantly maximized, the vaporization rate will be improved accordingly, and materially improved boiling efficiency thus achieved.
The invention, as indicated above, employs application of a sonic wave field to the liquid to be boiled. This involves the use of a vibratory sonic Wave radiator. This radiator and the special later-described resonant sonic driving means behind it operate automatically in -a manner to accommodate certain continuously varying conditions in the liquid during boiling. These varying conditions are of two kinds: The first is resistive, or power consuming, and corresponds with resistance in an electrical system, or friction or other energy dissipation in a mechanical system. The second is reactive, or nonpower consuming, corresponding, by analogy to electrical alternating current systems, to the algebraic difference between inductive reactance and capacitance reactance, and by analogy to ordinary mechanical vibration systems, to the algebraic difference between mass reactance and elastic compliance reactance.
These parameters will be somewhat more fully defined hereinafter. In each case, however, the reactance factors combine algebraically, and the difference of these combines vectorially with the resistance factor or component to form a resultant load impedance.
To return to the process of the invention, the liquid boiling medium represents a large resistive or energyconsuming load factor presented to the sonic wave source, being composed of the resistance of the liquid body to oscillation by the sonic wave and the energy dissipation involved, plus the larger energy dissipation involved in the evolution of vapor bubbles and the resulting general agitation caused by their creation and their movement through the liquid body. Cavitation is apparently also an energy dissipating phenomenon, and there may be other ways in which energy is dissipated. Now, these energy dissipating factors are comparatively irregular, sporadic, and may take place somewhat in bursts. Thus, the resistive load in sonically stimulated or activated boiling is a variable one.
Also involved in the sonically activated boiling process are changes in reactance, such as when there are abrupt changes in reactive coupling of the sonic wave radiator to the liquid owing to sudden boiling and release of bubbles. This change in loading reactance changes the reactive environment into which the sonic wave radiator is working. In other words, the characteristic elastic stiffness and inertia of the liquid body presents a reactance which, as seen by the radiator, varies considerably during the boiling process.
The combined resistive and reactive factors thus impose on the sonic wave radiator a load impedance of which all factors are variable, and this variable load impedance functions as a part of a discrete resonant acoustic circuit involved in the system, as will next be described.
The resonant acoustic circuit comprises, first, a sonic wave generator or oscillator of a special orbital-mass type, which, in conjunction with a resonator, which is the component of the circuit, has the desired automatic accommodation to the impedance variations of the load.
My orbital-mass vibration generators or oscillators may take various mechanical forms, one of the simplest and best of which involves a roller mass rolling around in a bearing, so that the mass generates a centrifugal force which is reactively opposed by the bearing. The bearing is in a housing, which in response to the centrifugal force so generated, exerts a periodic inertial force on whatever may support it or be coupled thereto. Examples of suitable forms of such orbital-mass generators are disclosed in my Patents Nos. 2,960,314 and 3,217,551.
The resonant acoustic circuit comprises next, as mentioned above, a vibratory resonator, and this member is acoustically coupled to the housing of the orbital-mass oscillator. This resonator terminates in the aforementioned vibratory wave radiator, which is in turn acoustically coupled to the liquid body to be boiled, which comprises, as already mentioned, the variable impedance load. The oscillator is equipped with a driving means or power source, generally in the nature of a motor of some sort, either electrical, pneumatic, internal combustion engine, or any other found suitable. It is important that this driving motor for the oscillator be powered so as to tend to operate at the resonant frequency of the acoustic circuit, and by having the driving motor tend normally to drive the oscillator at a frequency just under that for peak resonance, a number of additional important advantages are gained, particularly when using a driving motor which has a characteristic of inverse speed responsiveness to loading torque imposed upon it by the oscillator and the balance of the acoustic system. These advantages will be spoken of more particularly hereinafter. The driving motor, oscillator, resonator, and the variable impedance load constituted by the boiling body of liquid make up a discrete acoustic circuit.
Acoustically, speaking, the impedance of the resonantly vibratory resonator, or of any vibratory portion of the acoustic circuit, is a complex quantity proportional to the ratio of force to vibratory velocity at any point along the resonator, or in the acoustic circuit as a whole. As preliminarily mentioned above, the impedance of the load depends upon the vector resultant of the reactances and resistances of the load. This impedance, and the optimum phase angle, power factor and frequency for desired resonant performance, with maximum power delivery to the load, depends upon the magnitudes of these parameters at any particular instant, and can and do vary from instant to instant. The orbital-mass oscillator accommodates automatically and instantaneously in response to these variations in impedance, including change of phase angle of its orbiting mass relative to the motion of the vibrating resonator, with accompanying change of power factor, and/or frequency, assuring thereby efective and sustained delivery of large sonic energy to the load, under which conditions the boiling process is most powerfully sonically activated.
The orbital-mass oscillator adjusts its output frequency to maintain resonance with changes in impedance of the circuit. Thus, in the face of changes in the effective mass and compliance presented by the load, the system automatically adjusts its frequency to itself in optimum resonant operation by virtue of a resonant frequency lockin characteristic of the orbital-mass generator. As mentioned hereinabove, in order to obtain optimal performance, the orbital-mass oscillator and its drive motor are dimensioned and designed so that, with the drive effort properly adjusted, the oscillator will tend to lock in for operation at a frequency just on the low side of that for peak resonance. The oscillator then automatically changes its frequency and also its phase angle and therefore its power factor to correspond with changes in both the resistive and reactive components of load impedance comprised of the boiling body of liquid as the boiling process proceeds and as sporadic variations in activity take place throughout the liquid from instant to instant. At the same time, assuming a drive means powered to establish operation in the range of resonance, and just below the frequency for peak resonance, and assuming also a drive means that has the characteristic of inverse speed responsiveness to load, the drive effort can readily be adjusted so that the system locks in, as already mentioned, at just below the resonant frequency of the circuit, inclusive of the load. An excellent frequency stability is thereby established.
libe orbital-mass oscillator as described, coupled to a resonator, particularly an elastically vibratory equivalently half-wavelength standing wave system terminated by a high-impedance wave radiator, with the latter sonically coupled to the liquid body, affords a very powerful vibratory system. Such a system, moreover, can be readily designed with sufficient elastic compliance reactance to counteract the mass reactance of the relatively heavy resonator member and oscillator housing at the resonant operating frequency, and thus virtually cancel out forcewasting mass blocking effects. It is further a definite advantage that the elastic compliance reactance in such a system can readily be made sufliciently large to afford resonant magnification of vibratory amplitudes in the system, and to provide also a large energy storage property (often designated Q). The system also has a surprising frequency stabilizing feedback effect from the resonator to the oscillator, provided that the oscillator be designed to deliver a cyclic impulse properly related to the reactance and resistance of the resonator and of the load, s-o that the oscillator and resonator tend to maintain a frequency just below that for peak resonance, as explained above, and provided further that I drive the oscillator of this cornbination with a characteristic of inverse speed responsiveness to load. The oscillator then both locks in at such frequency, and automatically adjusts its phase angle to the load resistance. The frequency adjusts to the load reactance. An ideal acoustic system for transmitting large sonic energy to the boiling body of water is thus afforded.
A further feature of the invention is the use of a sonic wave generating system, preferably again of the orbitalmass oscillator type, for establishing a standing sound wave in the vapor space within the boiler. The sonic standing wave so developed results in agglomeration or gathering together of vapor molecules for effective condensation thereof. The agglomeration effect is owing to migration of vapor molecules to nodal regions of the standing wave established within the vapor space. Minute water droplets also migrate to the nodal regions of the standing wave, and these agglomerate or coalesce to fall out like rain. The advantage of the orbital-mass oscillator and resonator system is that it can accommodate, in a manner analogous to that described hereinabove in regard to the boiling phase of the process, for changes in the total vapor load, and for the condensation rate, by the type of performance hereinabove described by which the orbital-mass system accommodates for both reactive and resistive components of total impedance in the load.
A further preferred and advantageous feature of the particular form of the invention here chosen for illustrative purposes is the use of sonic oscillators, again preferably of the orbital-mass resonance type because of the peculiar advantages thereof hereinabove mentioned, in connection with the condensation tubes of the boiler through which the brine input flows on its way to the heat exchanger. The sonic action so applied t-o the condensation tubes has a number of effects, one of which is that as vapor is condensed against the outside of the tube, the sonic vibration quickly throws this condensed liquid free so that it can drop into a collection tray. This then instantly exposes the pipe for condensation of further vapor, affording a high performance rate. A much higher performance for a given amount of pipe surface area is thus attained. In addition, the standing wave in the vapor space around the condensation pipes greatly increases the rate of condensation by virtue of migration and agglomeration of the larger vapor molecule groups.
Since both the condensation processes have constantly changing or transient conditions, here again the orbitalmass resonant circuit system, with its ability to accommodate for changes in both resistive and reactive components of impedance, is very beneficial to the economic effectiveness of the over-all system.
It is now important to note that the automatic accommodationcharacteristic of the sonic system of the invention to changes in resisive reactive impedance of the load results in a favorable shift in the statistical expectation of the system based upon averaging of normal (nonsonic) localized processes. It should be seen that an important contribution made by this invention is the provision of a sonic process to facilitate boiling and condensation which .accommodates almost instantaneously to the average of small localized momentary fluctuations in the process and so takes advantage of these to bring about a higher average performance rate.
To summarize certain of the acoustic concepts referred to hereinabove, a sonic resonant system comprising an elastically vibratory resonator member in combination with an orbiting-mass oscillator or vibration generator is employed in my invention, This combination has many unique and desirable features. For example, this orbitingmass oscillator has the ability to adjust its input power and phase to the resonant system so as to accommodate changes in the work load, including changes in either or both the reactive impedance and the resistive impedance. This is a very desirable feature in that the oscillator hangs on to the load even as the load changes.
It is important to note that this unique advantage of the orbiting-mass oscillator accrues from the combination thereof with the acoustic resonant circuit, so as to comprise a complete acoustic system. In other words, the orbiting-mass oscillator is matched up to the resonant part of its system, and the combined system is matched up to the acoustic load, or the job to be accomplished. One
manifestation of this proper matching is a characteristic whereby the orbiting-mass oscillator tends to lock in to the resonant frequency of the resonant part of the system.
The combined system has a unique performance which is exhibited in the form of a greater effectiveness and particularly greater persistence in a sustained sonic action as the work process proceeds or goes through phases and changes of conditions. The orbiting-mass oscillator, in this matched-up arrangement, is able to hang on to the load and continue to develop power as the sonic energy absorbing environment changes with the variations in sonic energy absorption by the load. The orbiting-mass oscillator automatically changes its phase angle, and therefore its power factor, with these changes in the resistive impedance of the load.
A further important characteristic which tends to make the orbiting-mass oscillator 4hang on to the load and continue the development of effective power, is that it also accommodates for changes in the reactive impedance of the acoustic environment while the work process continues. For example, if the load tends to add either inductance or capacitance to the sonic system, then the orbiting-mass oscillator will accommodate accordingly. Very often this is accommodated by an automatic shift in frequency of operation of the orbiting-mass oscillator by virtue of an automatic feedback of torque to the energy source which drives the orbiting-mass oscillator. In other words, if the reactive impedance of the load changes this automatically causes a shift in the resonant response of the resonant circuit portion of the complete sonic system. This in turn causes a shift in the frequency of the orbitingmass oscillator for a given torque load provided by the power source which drives the orbiting-mass oscillator.
All of the above-mentioned characteristics of the orbiting-mass oscillator are provided to a unique degree by this oscillator in combination with the resonant circuit. The kinds of acoustic environment presented to the sonic source by this invention are uniquely accommodated by the combination of the orbiting-mass oscillator and the resonant system. As will be noted, this invention involves the application of sonic power which brings forth some special problems unique to this invention, which problems are primarily a matter of delivering effective sonic energy to the particular work process involved in. this invention. The work process, as explained elsewhere herein, presents a special combination of resistive and reactive impedances. These circuit values must be properly met in order that the invention be practiced effectively.
Sometimes it is especially beneficial to couple the sonic oscillator at a low-impedance (high velocity vibration) region, for optimum power input, and then have high impedance (high force vibration) at the work point. The sonic circuit is then functioning additionally as a transformer, or acoustic lever, to optimize the effectiveness of both the oscillator region and the work delivering region.
The invention will be understood more fully by considering a somewhat diagrammatically shown illustrative form of the invention, reference for this purpose being had to the accompanying drawings, in which:
FIG. 1 is a schematic layout of a system in accordance with the invention, parts being shown in elevation and parts in section; and
FIG. 2 is a partly broken away view of a typical simple oscillator of the orbital-mass type.
In FIG. l of these drawings, the numeral 10 designates generally a combined boiler and condensation tank, the tank having, as shown, end walls 11 and 12, a top wall 13, a bottom wall 14, a side wall 1S, and another side wall opposite to wall 15, not shown. The walls of this tank are of steel, and in the illustrative embodiment the upper wall 13 in particular is elastically vibratory in a standing wave pattern, as to be described, while the end walls 11 and 12 are quite stiff so as to fairly firmly support the end edges of the vibratory top wall 13.
Running longitudinally through the upper portion of tank 10, and thus through - walls 11 and 12 and the vapor Space 16 in the tank, are a plurality of water or brine tubes 17, only one of which is here shown, which serve also as condensation tubes, as will appear. The tube or tubes 17 lead via pipeline 19 to a header 2G at the end of a heat exchanger 22, the latter having an external casing 23, conventional tube sheets 24, heat exchanger tubes 25, and an outlet header 26, to which is coupled heated brine outlet pipe 30. A heating uid is introduced to the space around the tubes 25 via an inlet 31 and leaves via an outlet 32. The heated brine pipe 30 opens into the lower end or liquid space of boiler and condenser tank 10, supplying the heated water or brine to the latter, forming a liquid body 33. A pipe line 34 withdraws brine from the lower portion of tank 10, and rises to a level, as shown, to establish the liquid level in the tank ttl.
Below the tubes 17 in the tank 10 is a tray 3S adapted to collect water particles thrown off the tube 17, and this tray is mounted on and discharges through a pipe 4i) lcading out of tank l@ as clearly shown` Mounted in the bottom portion of tank l@ is a sonic circuit means comprised of an orbital-mass vibration generator or oscillator 42, and an elastically vihratory resonator generally designated by the numeral 44. The resonator 44 may be embodied in various forms, but in the case here instanced, comprises a downwardly extending and downwardly tapering elastic stem or bar 45, having at the top an annularly enlarged vibratory head or piston 46, preferably faced at the top with a layer of rubber-like material such as polyurethane or silicon rubber, in order to increase the coupling coe'icient from the piston 46 to the liquid. The piston 46 lits closely within the annular wall 48 of a pan or shroud 49 which is mounted in the lower tank wall 14, and fastened thereto as indicated. The close spacing presents a high impedance in the liquid annulus between the piston and shroud, so as to minimize loss of energy down past the piston. Stem 45 protrudes downwardly through the bottom wall of the pan 49 by way of an opening 50, and the resonator 44 is supported by its annularly enlarged head 46 by means of a pneumatic vibration isolator tube 52 of rubber-like material, encircling stem 45 above the bottom of the pan and supportingly engaging the upper extent of the stem 45 and the underside of head 46, for example as clearly illustrated in FIG. 1. The pneumatic tube 52 is inflated so as to support vibratory action of the resonator, and act also as a seal against the bottom wall of the pan. It engages the stem at a node of the vibratory system, and, being protected from leakage of sonic energy between the piston and shroud, is not subjected to very substantial pressure fluctuations and consequent energy loss from the piston. Moreover, the tube 52 functions as a shunt compliance, or decoupler, to prevent wave generation and high impedance blocking effects on the underside.
The orbital-mass oscillator 42 at the lower terminal of stem 45 may be, for example, any suitable one of a number of those shown in my aforesaid Patents Nos. 2,960,314 and 3,217,551. The oscillator will be referred to in more particular hereinafter, and for the time being it will merely be mentioned that its function is to deliver against the lower end of stem 45 a periodic cyclic force or force component oriented along thc direction line of the stem. The stem 45 taken together with the enlarged head is designed to vibrate elastically along the longitudinal direction line of the stem in the classic manner of a half-wavelength elastic bar undergoing resonant elastic vibration in the longitudinal mode, i.e, according to a half-wavelength longitudinal resonant standing wave pattern. Assuming a bar of uniform cross-section, a longitudinal resonant half-wavelength standing wave pattern involves a node, a region of minimized vibration amplitude, at the midpoint, and antinodes, or regions of maximized vibration amplitude, at the two extremities. Each half length of the bar alternately elastically contracts and expands, and
the amount of such movement increases progressively from the midpoint to each end of such a bar, as is well known. As is also well known, these vibrations of the two half lengths of the bar take place in opposition to one another, so as to remain in balance with one another. The present device, comprised of the stem 45 and the piston or head 46, is, very broadly speaking, an equivalent for the classic uniform half-wavelength longitudinally vibratory bar, but a very material improvement thereupon. The structure has, as in the case of the classic half-wavelength bar, a nodal point, here designated at N, and velocity antinodes V at the extremities. In the specific embodiment of FIG. l, one extremity will be seen to be within the lower end oscillator 42, and the other at the top of the piston 46. The structure vibrates along the vertical longitudinal axis with the portion above the node N always traveling in phase opposition to the portion of the structure below the node N. With the specific configuration here given in this illustrative embodiment of resonator, the distance from node N to the lower velocity antinode V may be somewhat greater than a half wavelength, notwithstanding the lumped mass effect of the oscillator because of the tapered and thus considerably slenderized form of the stern 45. The portion of the structure above the node N, on the other hand, which will be seen to be constituted partly of an upper portion of the stem 4S together with the entirety of the head or piston 46, is considerably shorter than a half wavelength because of the very great concentration of mass. The upper face or end of the piston 46 then vibrates with high impedance, or in other words, with great force but through small displacement distance and at small velocity amplitude. The lower extremity of the stem 45, by contrast, vibrates with substantially lower impedance, and therefore with less force amplitude and greater displacement and velocity amplitude. The upper high impedance end of the piston 46 then has the necessary high impedance for effective acoustic coupling to the liquid. As mentioned hereinabove, some improvement in the coupling coeflicient is attainable by use of the rubber-like facing on the piston. On the other hand, a lower impedance condition has been provided at the lower end of the stem, permitting use of an orbital-mass oscillator 42 having an output impedance somewhat less than would otherwise be required, Assuming an oscillator 42 driven at the resonant frequency for the resonator 44, a longitudinal resonant standing wave will then be set up in the structure as diagrammed at st in FlG. l, wherein the horizontal distance between the two lines of the diagram represents the vibration ampltiude of the resonator 44 at corresponding points along the latter. It should of course be understood that, as described in full particular in the introductory portion of the specification, very great advantage is derived from so designing and driving the oscillator that it tends to operate at a frequency just under the peak of resonance.
It should be mentioned that the configuration of the downwardly tapering stem 45 joining the enlarged piston 46 at the top to the oscillator at the bottom is in elfect an acoustic lever or transformer, matching a lower impendance oscillator 42 at the lower end to a relatively high impedance radiator 46 at the top. The system is thus an acoustic transformer, giving optimized impedance for the separate special functions at the terminations. Also, attention may be called to the fact that the relatively short distance from the node N to the upper antinode V is owing to the large concentration of mass within the head 46 or piston, and that by the same token, the oscillator 42 at the lower end represents some concentration of mass such as will raise the lower velocity antinode V somewhat. The large lumped masses tend towards shortening of the distances from the node to the upper and lower antinodes, whereas the downward tapering or slenderizing of the bar 45 increases the elastic compliance in this part of the device, and progressively reduces the impendance downwardly along the stem. The mass and elasticity reactances 9 of the vibratory resonator are thus, by a balance of these parameters, brought towards equalization with one another at the resonant frequency, with the very desirable consequence of reduction or elimination of oscillator force otherwise consumed in the vibration of the masses.
In FIG. 2 I have shown a partially broken away view of a simple and illustrative orbital-mass type oscillator 42. It comprises simply a housing 53 on the lower endof stem 45, with a cylindrical bearing surface 54 therein for a cylindrical orbital-mass rotor 55, the diameter of the rotor 55 being somewhat less than that of the race 54, for example as illustrated in FIG. 2, and the rotor 55 being adapted to travel in an orbital path guided by the bearing surface 54. The rotor 55 is driven in this orbital path by air under pressure introduced tangentially into the chamber defined by bearing surface 54 via a tapering nozzle 56 fed with air under pressure through a hose or pipe 57, the latter leading from a suitable source of air under pressure. Spent air escapes from the oscillator housing via a port such as 58. There is normally included some controllable means, not shown, for regulating the ow of pressure air to the oscillator. The pressurized air introduced into the oscillator is thus controlled to cause the rotor 55 to gyrate or follow its orbital path around the raceway 54 at a frequency corresponding to the resonant frequency of the liquid-loaded resonator 44, or just below the peak of such resonance, as explained hereinabove. The driving means for the oscillator thus in this case comprises a fluid pressure system, affording considerable slip between the introduced air and the rotor 52, so that the oscillator has the desirable characteristic of slip in the air stream, producing a substantial inverse speed responsiveness to the load portion of the acoustic circuit.
The heat exchanger 22 of the system is preferably equipped with a sonic wave generation system and resonator of the nature just described, utilizing a resonator 44a exactly like resonator 44, an oscillator 42a exactly like oscillator 42, with the piston portion 46a of the oscillator 42a this time accommodated in a pan 60 hung from the bottom wall of the heat exchanger tank with a lar-ge port 62 alording unobstructed communication between the interior of the pan and the heat exchanger tank. The piston 46a radiates sound waves upwardly into heating liquid of the heat exchanger, with the effect of scrubbing away heat-insulated boundary layers on the surfaces of the heat exchanger tubes 25, and thus improving heat transfer.
The system as so far described then operates as follows: Brine is circulated inwardly through the brine tubes 17 running through the vapor space of the boiler and condenser tank 10. This brine then ows via line 19 to the heat exchanger, through the tubes thereof, which are surrounded by a heating fluid circulated between an inlet 31 and an outlet 32. The brine is thereby heated to a temperature typically of the order of 250 F., and thence introduced, via pipe 30, into the lower end of the tank 10. Oscillator 42 is then driven, and the orbitally traveling cylindrical rotor 55 then exerts on the oscillator housing 53 a force vector which rotates about the central axis of the bearing 54 at some frequency determined by the pressure and flow of air into the chamber of the oscillator. Only the vertical component of the rotating force vector so developed is useful, and this component is augmented and amplified by vertical vibration amplification of the resonant stem 45 as the rotor 55 of the oscillator 42 comes up to resonant frequency with increasing air ow to the oscillator. The system can be readily controlled to produce the desired resonant frequency operation, the manifestations of resonance being unmistakably evident, and it being a very simple matter to control the air How to establish the operating frequency as desired, below the peak of resonance.
With the above conditions established, the piston member 46 radiates strong sonic vibrations into the liquid body 33. These sonic vibrations can be radiated into the liquid body 33 at large, or, with increased advantage, so as to establish standing wave patterns in the liquid. In the rst case, compressional waves are transmitted through the liquid body causing pressure and oscillations therein such as are characteristic of any sound wave transmission. It is also possible to set up a standing wave system, with nodes and antinodes. For example, the sound waves radiated from the top of the radiator piston 46, upon encountering the interface between the liquid body 33 and the vapor space above, are reliected back downwardly; and if the height of the liquid over the piston corresponds properly with the vibration frequency of the piston, certain known interference phenomena take place with the result that a standing wave system is established within the body of the liquid. Such a system will of course have regions of maximized and minimized liquid oscillation velocities and pressure Variation-s, leading to materially increased mobility within the liquid body, and ease and speed of travel of the evolved Vapor bubbles through the body of the liquid.
It was explained in complete detail within the introductory portion of the specification how such sonic activation increases and facilitates the process of boiling. No claim of course is made that water is boiled with a lower heat of vaporization. The process of the invention, instead, facilitates and speeds up the boiling process, affording increased throughput per hour, for example, within a plant of a -given scale. As mentioned hereinabove, the invention produces a condition within the boiling body of water by which the vapor of small and often transient boiling-condensation equilibrium system-s can be removed therefrom, and by which vapor molecules, as well as all vapor bubbles evolved in the boiling process, are additionally mobilized and thus rise from the body of liquid in reduced time, or with greater speed. A favorable shift is thereby obtained whereby the evolved vapor is released, not with lesser heat of vapor-ization, but at an accelerated rate. Also, with a high-amplitude sonic wave, cavitation is produced on the negative high cycles, and the increased mobilization of the resulting vapor bubbles permits these bubbles to be released before they again collapse. It was explained above how these bubbles tend to persist longer than a negative half-cycle of the wave, and under the sonic mobilization condition of the invention, they are sustained long enough to escape, and thus coact with the normal boiling process to improve the rate of vaporization of the liquid. The system also reduces surface tension, and thus permits boiling and release of Vapor from the surface of the liquid at a lower temperature.
A further important feature of the invention is to create a sonic wave condition, preferably a sonic standing wave, within the tank 10 in the condensation region thereof.
In accordance with the preferred practice of the invention, I mount on the top wall 13 of tank 10, typically and in this case midway of the length. dimension of the tank, a sonic vibration generator or oscillator, again of the orbital-mass type. Such a vibration generator is designated at 7th in the drawings, and it will be understood that the generator 70 may be of the type of FIG. 2, for example, con-taining an orbitally traveling mass roller, or may be any of the orbital-mass types referred to hereinabove. The oscillator 70 is driven at a frequency to create a lateral standing wave in the top wall 13 of the tank, which possesses sufficient elasticity to develop such wave action, In the present case, the end walls of the tank are stiff enough to remain fairly stationary during the lateral vibratory action of the wall 13, so that with a proper frequency, a one and one-half wavelength standing wave is developed, with a pattern such as designated at si, having nodes or pseudonodes N at the end walls of the tank and at half-wavelength distances inwardly therefrom, and three intervening velocity antinodes V. It will be understood that 'the top tank wall 13 elastically deects as represented by the standing wave diagram sl, producing corresponding pressure and velocity conditions in the vapor space. The bottom surface of the wall 13 thus radiates sound waves downwardly into the region of the tank where condensation is to occur. This wave action results in an action characterized by condensation of the vapor into minute droplets which immediately agglomerate and fall out of the vapor space like rain. Such agglomeration effect is owing to migration of vapor or water molecules, or fine Water droplets, to nodal regions of the standing wave within the vapor space. By the principle of least work, such minute particles or droplets within the standing wave area migrate from the regions of maximum vibration displacement and velocity' amplitude to regions of minimized displacement and velocity amplitude, so that minimized work is done thereon.
It will be recognized that the oscillator 70 together with the elastically vibratory tank top 13 vibrating in a resonant standing wave pattern will `be seen to be an orbitalmass oscillator and resonator system, with a variable load, the latter varying with changes in the total vapor load and in the condensation rate. The advantage here is that -f this system can accommodate or self-regulate itself in response to changes in the total vapor load and for the condensation rate, in accordance with principles discussed hereinabove, responding, in this connection, to both changes in reactive and resistive impedance such as is useful in gaining an optimum performance rate.
A further advantageous feature of invention is the use of orbital-mass type oscillators mounted on the condenser tubes 17. Such an oscillator 80 is shown mounted on one of the tubes 17 in the drawings, and is shown as placed on the tube 17 midway between the end walls 11 and 12 of the tank, i.e., at a selected Velocity antinode V. The end walls of the tank again establish nodal regions, and the oscillator S is again driven so as to provide a resonant standing wave in the tube 17, such as diagrammed at sl'. The oscillator 80 is again driven, through any suitable source of drive, so as to generate the resonant standing wave pattern sl in the tube 17 corresponding to that set up in the top Wall 13. The wave pattern is again a'ssumed to be a lateral type, though gyratory or other modes may be used. It will of course be understood that the vapor condenses on these tubes 17 and tends to collect thereon. The wave action developed in the tubes 17 quickly throws off this condensed water so that it can drop into the collection tray 38. This exposes the tube for condensation of further vapor, and so improves the performance rate. The result is higher performance for a given amount of pipe surface area. Condensation onto the pipes 17 is also promoted by the standing waves in the vapor space which materially increase the rate of condensation by virtue of migration and agglomeration of the larger vapor molecule groups or combinations to the nodal regions of the wave where they are crowded together.
Referring again to the orbital-mass oscillators 80, these may in many instances be either electric-motor driven, or shaft driven, many illustrative forms of which are shown in my aforementioned patents. These types of oscillator drive avoid any problem which might arise out of discharge of air into the tank. Air driven oscillators may, however, be successfully used provided the air discharged into the vapor space does not result in a shift in the heat balance.
It is noted that the system of the invention in its preferred, illustrative form employs, in different parts of the apparatus and for different purposes, use of sonic waves generated in liquid, solid a'nd in vapor media.
Since both of the sonic systems involved in the condensation and collection process have transient or constantly changing conditions, here again the orbital-mass oscillator and resonator combination, with its ability to accommodate for or adjust to changes in both resistive and reactive impedance, is very beneficial to the economic performance of the over-all system. Not only is the boiling process benefited by the favorable shift in statistical average performance by the described accommodation or response characteristic of the sonic system, but also the condensation system is similarly benefited. The economic performance of a given condensation and evaporation plant, with the addition of the sonic wave improvements of the present invention, is thus significantly improved.
It will be understood that the particular embodiment of the invention here chosen for illustrative purposes is merely for illustration and not to be taken as limitative on the invention, particularly in its lbroader aspects, since numerous changes in design, structure, and arrangement may be made in the equipment without departing from the spirit and scope of the appended claims.
I claim:
1. The process of facilitating a boiling process, that comprises:
providing a body of liquid to be boiled in a boiler tank;
heating said liquid in a preheater preceding the boiler tank and exposing the liquid to sonic vibrations; generating vibrations by driving an orbital-mass rotor repeatedly in an orbital path around the surface of a bearing; coupling said bearing to a resonator, whereby to transmit said vibrations to said resonator, and adjusting said vibrations to the resonant frequency range of said resonator; and acoustically coupling said oscillator and resonator to said liquid in said boiler tank, so as to create sonic vibrations in said liquid.
2. The subject matter of claim 1, including also:
driving said orbital-mass rotor with a drive eiort that is inversely responsive to torque load on said bearing, and at a frequency which is in the range of resonance but on the low side of that for peak resonance amplitude.
3. The subject matter of claim 1, including causing cavitation in the liquid body by said sonic Vibrations by establishing a sonic pressure wave therein, at an amplitude sufficient to cause the negative pressure half-cycles of the wave to drop to the vaporization pressure of the liquid.
`4. A sonically aided boiler comprising:
a boiler tank for holding a body of heated liquid to be boiled;
an orbital-mass oscillator;
a heater for preheating the liquid prior to discharge into the Aboiler tank; and a vibratory resonator coupled to said oscillators and vibrated in its resonant frequency range thereby,
said oscillator and resonator including a vibratory sonic wave radiator immersed in and thereby coupled to said body of liquid.
5. The subject matter of claim 4, including means for driving said oscillator including a power source having the characteristic of inverse speed responsiveness to torque load, and which is powered to drive said resonator in the range of resonance but on the low side of the frequency for the peak of resonance for said resonator.
6. The subject matter of claim 4, wherein said oscillator comprises an orbital-mass rotor, and a housing having a bearing engaged by and defining an orbital path for said orbital-mass rotor; and
said oscillator comprises an equivalent half-Wavelength longitudinally elastically vibratory member of generally elongated form having velocity antinodes at its extremities and an intervening node, and having said wave radiator at one extremity thereof positioned within and thereby a'coutically coupled to said body of liquid, and having said housing of said oscillator iixed on the other extremity thereof.
7. The subject matter of claim 6, wherein said elastically vibratory member includes a stem, a radially enlarged piston on one extremity of said stem to form said wave radiator, and said housing of said oscillator at the other end thereof.
8. The subject matter of claim 4, including also an 13 elastically vibratory resonator in proximity to the vapor space in said tank above the liquid body therein;
an orbital-mass oscillator coupled to said resonator and including a vibratory radiator exposed to vapor and any water droplets in said space and operable to set up in the vapor in said space a resonant sonic standing Wave; and
means located in said tank for collecting liquid condensed from vapor in said vapor space.
9. The subject matter of claim 4, including also a cooled, elastically vibratory, resonating condenser in the vapor space in said tank above the liquid body therein;
an orbital-mass oscillator coupled to said resonatng condenser and operable to set up resonant standing Wave vibration thereof; and
5 denser comprises a cool Water tube extending within said vapor space.
References Cited UNITED STATES PATENTS 3,295,837 1/1967 BOdine 259*1 3,151,958 10/1964 Bodine 259-1 X NORMAN YUDKOFF, Primary Examiner. J. SOFER, Assistant Examiner.
US575680A 1966-08-29 1966-08-29 Sonic distillation process and apparatus Expired - Lifetime US3410765A (en)

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US575680A US3410765A (en) 1966-08-29 1966-08-29 Sonic distillation process and apparatus
GB32639/67A GB1189513A (en) 1966-08-29 1967-07-14 Sonic Distillation Process and Apparatus
DE19671619687 DE1619687A1 (en) 1966-08-29 1967-07-21 Method for carrying out the distillation with rapid vibrations and a device for this
ES344521A ES344521A1 (en) 1966-08-29 1967-08-28 Sonic distillation process and apparatus
IL28573A IL28573A (en) 1966-08-29 1967-08-28 Sonic distillation process and apparatus
ES358111A ES358111A1 (en) 1966-08-29 1968-09-13 Sonic distillation process and apparatus

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Cited By (15)

* Cited by examiner, † Cited by third party
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US3509730A (en) * 1966-10-24 1970-05-05 Westinghouse Electric Corp Pressure modulated bubble stirring apparatus for freezing solute out of solution
US3625484A (en) * 1969-06-16 1971-12-07 Albert G Bodine Monopole elastomeric resonator
US3625486A (en) * 1969-06-16 1971-12-07 Albert G Bodine Multiple-pillar elastomeric resonator
US3672643A (en) * 1969-06-02 1972-06-27 Albert G Bodine Elastomeric piston
US3743523A (en) * 1971-08-04 1973-07-03 A Bodine Method for the sonic treating of food material
US3789617A (en) * 1972-01-13 1974-02-05 Thermocycle Inc Thermodynamic system
US5152605A (en) * 1991-01-22 1992-10-06 Ushio Co., Ltd. Apparatus for making cooled concrete
US5326164A (en) * 1993-10-28 1994-07-05 Logan James R Fluid mixing device
US5391262A (en) * 1990-04-23 1995-02-21 Wilkerson, Jr.; William Solar still vibrator
US5653852A (en) * 1995-11-08 1997-08-05 Meng; Ching Ping Distilling device
US20050260554A1 (en) * 2004-05-24 2005-11-24 Gaalswyk Mark K Ethanol production system
WO2007139524A1 (en) * 2006-05-30 2007-12-06 Mustafa Faleh Vibrating & electromagnetic evaporation
WO2013040523A1 (en) * 2011-09-15 2013-03-21 Scarborough Walter Cold distillation apparatus and treatment method
US20130315025A1 (en) * 2011-05-03 2013-11-28 Andrej Getalov Method of ultrasonic cavitation treatment of liquid media and the objects placed therein
US10232329B2 (en) * 2009-06-22 2019-03-19 Panasonic Intellectual Property Management Co., Ltd. Generating method and generator for generating mist or fine-bubble by using surface acoustic wave

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GB2152204B (en) * 1983-12-30 1988-02-24 Smidth & Co As F L Heat exchanger

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3151958A (en) * 1957-08-26 1964-10-06 Albert G Bodine Pressurized degasification of crude oil by sonic wave action
US3295837A (en) * 1964-10-08 1967-01-03 Jr Albert G Bodine Method for generating and transmitting sonic vibrations

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3151958A (en) * 1957-08-26 1964-10-06 Albert G Bodine Pressurized degasification of crude oil by sonic wave action
US3295837A (en) * 1964-10-08 1967-01-03 Jr Albert G Bodine Method for generating and transmitting sonic vibrations

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3509730A (en) * 1966-10-24 1970-05-05 Westinghouse Electric Corp Pressure modulated bubble stirring apparatus for freezing solute out of solution
US3672643A (en) * 1969-06-02 1972-06-27 Albert G Bodine Elastomeric piston
US3625484A (en) * 1969-06-16 1971-12-07 Albert G Bodine Monopole elastomeric resonator
US3625486A (en) * 1969-06-16 1971-12-07 Albert G Bodine Multiple-pillar elastomeric resonator
US3743523A (en) * 1971-08-04 1973-07-03 A Bodine Method for the sonic treating of food material
US3789617A (en) * 1972-01-13 1974-02-05 Thermocycle Inc Thermodynamic system
US5391262A (en) * 1990-04-23 1995-02-21 Wilkerson, Jr.; William Solar still vibrator
US5152605A (en) * 1991-01-22 1992-10-06 Ushio Co., Ltd. Apparatus for making cooled concrete
US5326164A (en) * 1993-10-28 1994-07-05 Logan James R Fluid mixing device
US5653852A (en) * 1995-11-08 1997-08-05 Meng; Ching Ping Distilling device
US20050260554A1 (en) * 2004-05-24 2005-11-24 Gaalswyk Mark K Ethanol production system
US8080406B2 (en) * 2004-05-24 2011-12-20 Gaalswyk Mark K Ethanol production system
WO2007139524A1 (en) * 2006-05-30 2007-12-06 Mustafa Faleh Vibrating & electromagnetic evaporation
US10232329B2 (en) * 2009-06-22 2019-03-19 Panasonic Intellectual Property Management Co., Ltd. Generating method and generator for generating mist or fine-bubble by using surface acoustic wave
US20130315025A1 (en) * 2011-05-03 2013-11-28 Andrej Getalov Method of ultrasonic cavitation treatment of liquid media and the objects placed therein
WO2013040523A1 (en) * 2011-09-15 2013-03-21 Scarborough Walter Cold distillation apparatus and treatment method

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ES344521A1 (en) 1968-12-01
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ES358111A1 (en) 1970-04-01
GB1189513A (en) 1970-04-29

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