US3370940A - Iron-nickel alloys - Google Patents
Iron-nickel alloys Download PDFInfo
- Publication number
- US3370940A US3370940A US594474A US59447466A US3370940A US 3370940 A US3370940 A US 3370940A US 594474 A US594474 A US 594474A US 59447466 A US59447466 A US 59447466A US 3370940 A US3370940 A US 3370940A
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- US
- United States
- Prior art keywords
- alloys
- iron
- uranium
- nickel
- manganese
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 title description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 31
- 229910052770 Uranium Inorganic materials 0.000 description 23
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 20
- 229910045601 alloy Inorganic materials 0.000 description 19
- 239000000956 alloy Substances 0.000 description 19
- 229910052759 nickel Inorganic materials 0.000 description 15
- 239000011572 manganese Substances 0.000 description 14
- 229910052748 manganese Inorganic materials 0.000 description 12
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 9
- 238000007792 addition Methods 0.000 description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000000155 melt Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 230000035699 permeability Effects 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 238000000137 annealing Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 229910000863 Ferronickel Inorganic materials 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910001004 magnetic alloy Inorganic materials 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/007—Alloys based on nickel or cobalt with a light metal (alkali metal Li, Na, K, Rb, Cs; earth alkali metal Be, Mg, Ca, Sr, Ba, Al Ga, Ge, Ti) or B, Si, Zr, Hf, Sc, Y, lanthanides, actinides, as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
Definitions
- This invention relates to uranium-containing iron-nickel alloys.
- vacuum-melted iron-nickel alloys having a nickel content greater than or equal to 30% have excellent magnetic properties.
- Deoxidised alloys of this kind can be forged and hot-rolled without difliculty if they are prepared from very pure raw materials, but they behave differently if the raw materials used contain sulphur, as is frequently the case with commercial quality materials.
- the magnetic properties remain substantially unchanged, but the high-temperature deformability deteriorates unless a desulphurising agent is added to the alloy; unless this is done, the product cannot be forged or hot-rolled and despite its good magnetic properties it can be used only for very restricted applications.
- uranium has a great afiinity for sulphur and oxygen. In steel it forms refractory inclusions of a globular shape which are thought to be oxysulphides.
- uranium may advantageously completely or partly replace manganese in order that ironnickel alloys having a nickel content greater than or equal to 30% may be made forgeable.
- oxygen concentration not to exceed 100 ppm.
- Processing partially or completely in vacuo or in a protective or reducing gas may be of advantage to give such a low impurity content.
- a heat treatment was carried out and comprised annealing for 6 hours at a temperature of 1100 C. in hydrogen.
- the first two melts respectively contained about 0.5 and 0.3% of manganese while the third contained only traces thereof. Although the third melt was unfortunately unforgeable, it had very much better magnetic properties than the first two.
- the deformability of the ingot without a desulphurising addition is practically zero between 500 and 800 C.; above 800 C. it improves, but never reaches a satisfactory level. With an 0.3% manganese addition, the fragil- Of course the above-indicated uranium contents are 2 given by way of example and have no limiting force.
- the nickel content is preferably between 43 and 55% for the application in question but the superior magnetic quality provided by uranium instead of manganese may be obtained with all ferronickel alloys having a nickel content greater than or equal to Table IV gives examples of results obtained with melts containing various nickel contents.
- the corresponding properties were measured on 0.07 mm. thick strip rings annealed for 6 hours at 1100 C. in hydrogen with slow cooling in the furnace in the case of the alloy containing 36% of nickel; in the case of the alloy containing 78% of Ni, the tests were carried out on 0.3 mm. thickstrip rings annealed for 6 hours at 1000 C. in hydrogen with rapid cooling from 600 C.
- beneficial eiiect of uranium is found with an addition of as little as 0.02% by Weight; with regard to the top uranium concentration limit, this is dictated more by safety requirements in respect of radiation than by technological conditions. The maximum concentration would be limited to 0.5% by weight.
- Table II and the single figure refer essentially to alloys containing 48-50% Ni, these contents have no limiting force and the beneficial influence of the uranium additive covers all ferronickel alloys having a nickel content greater than or equal to 30%.
- the uranium additive is much less harmful to the magnetic properties than is the manganese additive.
- Table III shows the magnetic properties after annealing for 6 hours at 1100 C. in hydrogen for iron-nickel alloy melts containing 48 to 50% Ni processed under identical conditions and respectively containing 0.34% Mn, 0.05% U, 0.10% U and 0.25% U.
- the main object of the invention is to replace manganese by uranium in magnetic iron-nickel alloys.
- the field of application of the invention is not restricted solely to magnetic alloys but relates generally to all binary or complex iron-nickel alloys having a nickel content greater than or equal to 30%, irrespective of use (e.g., magnetic alloys, alloys having a specific expansion, alloys having special elastic or thermoelastic properties, alloys having a specific resistivity, and so on).
- complex iron-nickel alloys iron and nickel based alloys which in addition to the impurities inherent in any metallurgical product contain additions of chromium, copper, silicon, molybdenum, aluminum, calcium, or magnesium for example which, without modifying the character or structure of the alloy, contribute towards improving the physical properties thereof.
- Binary iron-nickel alloys having a nickel content at least equal to 30% by weight, 0.02 to 0.5% by weight of uranium and the remainder iron with the conventional impurities of metallurgical products.
- Iron-nickel alloys as described in claim 1 the nickel content by weight being between 43 and 55%.
Description
Feb. 27, 1968 E. JOSSO IRON-NICKEL ALLOYS Filed Nov. 15. 1966 Unite Sttes 3 Claims. (51. 75-1225 ABSTRACT (IF THE DlISQLOSURE Iron-nickel alloys having improved magnetic properties and improved forgeability are obtained by replacing manganese in the alloy by uranium. The nickel content is greater than or equal to 30% and the amount of uranium is from 0.02 to 0.5% by Weight.
This invention relates to uranium-containing iron-nickel alloys.
It is well known that vacuum-melted iron-nickel alloys having a nickel content greater than or equal to 30% have excellent magnetic properties. Deoxidised alloys of this kind can be forged and hot-rolled without difliculty if they are prepared from very pure raw materials, but they behave differently if the raw materials used contain sulphur, as is frequently the case with commercial quality materials. The magnetic properties remain substantially unchanged, but the high-temperature deformability deteriorates unless a desulphurising agent is added to the alloy; unless this is done, the product cannot be forged or hot-rolled and despite its good magnetic properties it can be used only for very restricted applications.
To overcome this difiiculty, conventional practice is to add a small quantity (for example 0.3-0.5%) of manganese to the melt in order to facilitate forging or hotrolling of the ingots.
Unfortunately, this addition of manganese, which combines with the sulphur to give a relatively stable sulphide, has an unfavourable eifect on the magnetic properties of the alloy, as Will be apparent from the following table, which relates to 0.3 mm. thick strip rings originating from three melts prepared under identical conditions with the same raw materials.
TABLE 1 atent The carbon contents shown in Table I were determined on the ingot prior to any conversion operations. These relatively high contents have the effect or" keeping the oxygen concentration of the matreials at a very low level of about 10 ppm. After rolling into thin strips and after annealing for 6 hours at 1100 C. in purified hydrogen to develop the magnetic properties, this carbon content drops to about 0.01%.
It is well known that uranium has a great afiinity for sulphur and oxygen. In steel it forms refractory inclusions of a globular shape which are thought to be oxysulphides.
Work on the use of uranium in ferrous alloys has hitherto been devoted to ordinary, alloy or stainless steels solely to improve their mechanical properties. Uranium increases the tensile strength at ambient temperature, increases quenchability and promotes structural hardening. With regard to resistance of stainless steels to corrosion, the results are as yet too incomplete for any definite conclusions to be drawn.
No coherent data is available on the influence of an additional of uranium to binary or complex iron-nickel alloys having a nickel content greater than 30%, such alloys being in widespread use because of their special physical properties (their magnetic, expansion, electrical, mechanical and thermomechanical properties in particular).
Tests have shown the advantage of uranium over mag- It has been foundand this is one of the features of the invention-that uranium may advantageously completely or partly replace manganese in order that ironnickel alloys having a nickel content greater than or equal to 30% may be made forgeable.
This improvement of forgeability is obtained by the use of uranium as desulphurising agent and contrary to previous tests it is advantageous to introduce it into material which has previously been satisfactorily deoxidiscd in order to prevent some of the uranium from being neutralised in the form of an oxide.
It is therefore advantageous for the oxygen concentration not to exceed 100 ppm. Processing partially or completely in vacuo or in a protective or reducing gas may be of advantage to give such a low impurity content.
Reference No. Chemical analysis of ingot, percent Permezzhility a 5 milloersteds 1 (with manganese)- S =0.0088, 3, 560
O =0.00 C =O.l31,
2 (with manganese)- S =0.008 4, 170
3 (without manganese). S =0.0090, 9, 440
Maximum Coercivity, permeability 0e.
A heat treatment was carried out and comprised annealing for 6 hours at a temperature of 1100 C. in hydrogen. The first two melts respectively contained about 0.5 and 0.3% of manganese while the third contained only traces thereof. Although the third melt was unfortunately unforgeable, it had very much better magnetic properties than the first two.
TABLE IL-CHEMICAL ANALYSES (PERCENTAGES, UNLESS OTHERWISE INDICATED) Reference C Si Mn S P N i O 2 N Addition (up (p-p- 0.03 0.0090 0.008 48.98 10 19 None.
( 0.34 0.0089 0.005 49.50 5 7 Mn:0.34. 0.09 0.0078 0.005 48.98 6 6 U:0.05. 0.0073 0.007 49.15 U:0.10. 0.0067 0.007 49.20 U:0.25.
l Traces.
The deformability of the ingot without a desulphurising addition is practically zero between 500 and 800 C.; above 800 C. it improves, but never reaches a satisfactory level. With an 0.3% manganese addition, the fragil- Of course the above-indicated uranium contents are 2 given by way of example and have no limiting force. The
Here again the compositions are given by way of example and have no limiting, force. The nickel content is preferably between 43 and 55% for the application in question but the superior magnetic quality provided by uranium instead of manganese may be obtained with all ferronickel alloys having a nickel content greater than or equal to Table IV gives examples of results obtained with melts containing various nickel contents. The corresponding properties were measured on 0.07 mm. thick strip rings annealed for 6 hours at 1100 C. in hydrogen with slow cooling in the furnace in the case of the alloy containing 36% of nickel; in the case of the alloy containing 78% of Ni, the tests were carried out on 0.3 mm. thickstrip rings annealed for 6 hours at 1000 C. in hydrogen with rapid cooling from 600 C.
TABLE IV S-content Mn-content U-contont Permeability Maximum Coercivity, Type of alloy by weight by weight by weight at 5 moe. permeability Oersteds Percent Percent Percent Fe-Ni alloy containing 36% of Ni 0. 01 0.8 2, 100 9,000 0.20
Fe-Ni alloy containing 78%0! Ni 0. 007 0. 48 8, 000 62, 000 0. 09
beneficial eiiect of uranium is found with an addition of as little as 0.02% by Weight; with regard to the top uranium concentration limit, this is dictated more by safety requirements in respect of radiation than by technological conditions. The maximum concentration would be limited to 0.5% by weight. Similarly, although Table II and the single figure refer essentially to alloys containing 48-50% Ni, these contents have no limiting force and the beneficial influence of the uranium additive covers all ferronickel alloys having a nickel content greater than or equal to 30%.
It has also been found-and this is another feature of the inventionthat for equal forgeability, the uranium additive is much less harmful to the magnetic properties than is the manganese additive. This is clear from Table III, which shows the magnetic properties after annealing for 6 hours at 1100 C. in hydrogen for iron-nickel alloy melts containing 48 to 50% Ni processed under identical conditions and respectively containing 0.34% Mn, 0.05% U, 0.10% U and 0.25% U.
TABLE III Magnetic properties Reference Addition Permability Maximum Coercivit-y,
at 5 milli- Permeability 0e.
oersteds The main object of the invention is to replace manganese by uranium in magnetic iron-nickel alloys. However, since the improved foreability provided by uranium is valid irrespective of the use for which the material is intended, the field of application of the invention is not restricted solely to magnetic alloys but relates generally to all binary or complex iron-nickel alloys having a nickel content greater than or equal to 30%, irrespective of use (e.g., magnetic alloys, alloys having a specific expansion, alloys having special elastic or thermoelastic properties, alloys having a specific resistivity, and so on). By complex iron-nickel alloys is meant iron and nickel based alloys which in addition to the impurities inherent in any metallurgical product contain additions of chromium, copper, silicon, molybdenum, aluminum, calcium, or magnesium for example which, without modifying the character or structure of the alloy, contribute towards improving the physical properties thereof.
I claim:
1. Binary iron-nickel alloys, having a nickel content at least equal to 30% by weight, 0.02 to 0.5% by weight of uranium and the remainder iron with the conventional impurities of metallurgical products.
2. Iron-nickel alloys as described in claim 1, containing less than p.p.m. of oxygen.
3. Iron-nickel alloys as described in claim 1, the nickel content by weight being between 43 and 55%.
References Cited UNITED STATES PATENTS 9/1964 Douglas et a1. 75122.5 9/1966 Weber 75-122.5 X
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR40297A FR1465578A (en) | 1965-11-30 | 1965-11-30 | Iron-nickel alloys |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3370940A true US3370940A (en) | 1968-02-27 |
Family
ID=8593829
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US594474A Expired - Lifetime US3370940A (en) | 1965-11-30 | 1966-11-15 | Iron-nickel alloys |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US3370940A (en) |
| DE (1) | DE1533382B1 (en) |
| FR (1) | FR1465578A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4929275A (en) * | 1989-05-30 | 1990-05-29 | Sps Technologies, Inc. | Magnetic alloy compositions and permanent magnets |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3148978A (en) * | 1960-02-02 | 1964-09-15 | Atomic Energy Authority Uk | Alloys |
| US3221559A (en) * | 1963-09-16 | 1965-12-07 | Harbison Walker Refractories | Immersion sampler |
-
1965
- 1965-11-30 FR FR40297A patent/FR1465578A/en not_active Expired
-
1966
- 1966-11-11 DE DE19661533382 patent/DE1533382B1/en active Pending
- 1966-11-15 US US594474A patent/US3370940A/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3148978A (en) * | 1960-02-02 | 1964-09-15 | Atomic Energy Authority Uk | Alloys |
| US3221559A (en) * | 1963-09-16 | 1965-12-07 | Harbison Walker Refractories | Immersion sampler |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4929275A (en) * | 1989-05-30 | 1990-05-29 | Sps Technologies, Inc. | Magnetic alloy compositions and permanent magnets |
| WO1990014911A1 (en) * | 1989-05-30 | 1990-12-13 | Sps Technologies, Inc. | Magnetic alloy compositions and permanent magnets |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1533382B1 (en) | 1970-12-17 |
| FR1465578A (en) | 1967-01-13 |
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