US3341641A - Centrifugal casting process - Google Patents
Centrifugal casting process Download PDFInfo
- Publication number
- US3341641A US3341641A US315370A US31537063A US3341641A US 3341641 A US3341641 A US 3341641A US 315370 A US315370 A US 315370A US 31537063 A US31537063 A US 31537063A US 3341641 A US3341641 A US 3341641A
- Authority
- US
- United States
- Prior art keywords
- mold
- centrifugal casting
- rotation
- walls
- casting process
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 23
- 238000009750 centrifugal casting Methods 0.000 title claims description 12
- 239000000463 material Substances 0.000 claims description 41
- 239000007788 liquid Substances 0.000 claims description 9
- 239000012530 fluid Substances 0.000 claims description 3
- 239000007790 solid phase Substances 0.000 claims description 2
- 238000006073 displacement reaction Methods 0.000 description 8
- 230000001133 acceleration Effects 0.000 description 7
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000011344 liquid material Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 238000005266 casting Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- IYDYVVVAQKFGBS-UHFFFAOYSA-N 2,4,6-triphenoxy-1,3,5-triazine Chemical compound N=1C(OC=2C=CC=CC=2)=NC(OC=2C=CC=CC=2)=NC=1OC1=CC=CC=C1 IYDYVVVAQKFGBS-UHFFFAOYSA-N 0.000 description 1
- 241001605719 Appias drusilla Species 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000011952 anionic catalyst Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000037237 body shape Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000009828 non-uniform distribution Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/04—Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2077/00—Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
Definitions
- This invention relates to a centrifugal casting process, more particularly to a centrifugal casting process wherein the rotation rate of the mold is varied.
- the rotational speed of the mold is fast, mold surfaces closer to the bottom tend to be starved and remote surfaces overloaded; if it is attempted to overcome this lack of uniformity by employing a lower rotational speed, the liquid charge may remain at or near the bottom of the mold so that higher areas are starved; and if the mold surface is not a continuous smooth one, but is interrupted by angles, crevices, curvatures, or protrusions, a heavy or insufiicient material buildup occurs in these parts. Additionally, nonuniform distribution of the material on the walls of the mold cavity is often more pronounced in the case of such low-viscosity materials.
- a charge of the liquid material to be molded is inserted into a stationary or rotating mold and, subsequently, depending on Whether or not the mold is already rotating, rotation is commenced. After the mold has accomplished acceleration to the maximum r.p.m., its rate of rotation is alternately decreased and increased. In the alternative, the mold can be alternatively rotated in a clockwise and counterclockwise direction.
- the material charge-d into the mold cavity Will first have a speed less than the speed of the mold. Due to the friction between the mold and the material, the latter will accelerate until an equilibrium is established between the speed of the mold and that of the material. When the mold rotation is braked, the material, due to inertia, will continue rotating by its momentum at a speed higher than the speed of the decelerating mold, resulting in a lateral relative shearing displacement between the material and mold, the material thereby Washing the mold walls in a lateral direction.
- the mold deceleration is followed by a more gradual deceleration of the material, and the lateral slippage or displacement of the material relative to the mold diminishes in degree in time. If the mold is now accelerated again, a second lateral relative displacement between the material and the mold walls occurs due to the friction of the material against the wall, the second relative displacement being in an opposite sense as the displacement which occurred during the deceleration.
- a similar alternating relative displacement between the material and the mold walls can be accomplished in both directions when the direction of the mold rotation is reversed. As a result of these lateral relative displacements, a greater wall thickness uniformity of the material of the object thus molded, along any horizontal cross section, can be accomplished.
- the materials forming the different layers may be charged into the mold at successive stages.
- Such layers may include alternating deposited layers of materials having varying physical properties complementing each other, alternating layers of resins, fillers, pigments, etc.
- Undue material buildup in corners and crevices of the mold is avoided because only a relatively thin layer of material is deposited within one acceleration and deceleration cycle as the material shifts up and then down along the walls, and the thin layer is well distributed in such places before another layer of material is deposited thereon in a subsequent cycle.
- the rate of deceleration or acceleration is limited by the possibility that at higher rates the liquid material may tend to splash or form waves, and if this occurs at a point where the liquid starts to solidfy or polymerize, the irregularities may be frozen into the final molded body shape. This limiting rate has to be determined individually case of very fluid.
- the rotational speeds employed will greatly vary from one material and mold shape to another, but in the materials, such as anionically polymthe rotational speed usually always in view of its viscosity,
- Example An aluminum vessel 11 inches in diameter and 7 inches deep and having a flat bottom joined by a gentle curve to the slightly tapered, almost cylindrical sidewall was mounted in an electric oven as a mold for rotation about. its axis.
- the mold vessel was covered and sealed except for a 1-inch hole in the center for purging the mold cavity with an inert gas and for introducing liquid resin therethrough.
- the mold was preheated to 175 C. and the cavity purged with dry nitrogen.
- the invention is disclosed by way of an example and, depending on production requirements and material characteristics, a number of and 0.63 g. triphenoXy-s-triazine as polym-' modifications may be employed. Different materials and different production rates would require different processing temperatures and durations, while some materials, such as thermoplasticresins may also require cooling during the process. Depending on the viscosity characteristics of the material to be molded, a variety of acceler-ation and deceleration rates as well as rotation times may beused.
- the process of the invention is not limited to centrifuging only about a vertical mold axis, the process is also applicable to the centrifugal casting of articles in which the walls above the bottom plane converge inward at any point. In this case the rotational axis of the mold has to be inclined from the vertical at some point during In view of the foregoing, the scope the rotational cycle. of the invention is to claims.
- An improved centrifugal casting process which comprises charging a mold with a mixture, consisting the mixture at 100 C. was i polymerization promotor followed by essentially of caprolactam, an anionic catalyst and a the repeated cycle of rotating the mold about its vertical axis to a about 500' r.p.m., quickly braking the rotation within -a periodof about .5 seconds when it attains the desired rotational speed and permitting the mold to'remain at least for about 10 seconds prior to repeating the cycle.
Description
Patented Sept. 12, 1967 3,341,641 CENTRIFUGAL CASTING PROCESS Charles D. Spencer, Morris County, N.J., assignor to Allied Chemical Corporation, New York, N.Y., a corporation of New York No Drawing. Filed Oct. 10, 1963, Ser. No. 315,370 Claims. (Cl. 26472) This invention relates to a centrifugal casting process, more particularly to a centrifugal casting process wherein the rotation rate of the mold is varied.
When a liquid material is charged in a rotatable mold and the upright mold is subsequently set to rotation about its vertical axis, the liquid material will move upward along the walls of the mold, due to the resulting centrifugal force, as far as the walls do not converge inwards towards the axis. The outer surface of the resulting liquid rotational shape conforms to the walls of the mold cavity, while the interior, exposed surface of the liquid tends to assume a more or less paraboloidal shape, the shape depending on the rotational velocity and the surface tension of the liquid. This does not present problems as long as the Walls of the mold cavity are also of a paraboloidal or near-paraboloidal shape. However, if one intends to form uniform wall thickness items of a shape markedly deviating from a paraboloid, such as a straightwalled funnel or a cylinder, the control and the uniformity of the wall thickness becomes increasingly difiicult, or
even impossible.
Another factor in the difficulty of accomplishing uniform wall thicknesses of centrifugally cast articles, in general, results from a nonuniform wetting of the mold walls by the material due to a great variety of possible reasons. This problem becomes especially aggravated when one attempts to centrifugally form articles from materials having a very low viscosity in the casting stage, such as in situ polymerized polyamide resins, i.e. resins polymerized in the mold during the centrifugal forming process. These resins polymerize and set up within a given time; therefore, the complete deposition thereof on the mold Walls and in the desired distribution has to be accomplished within that time, otherwise the nondeposited material will set up as one or more solidified puddle or puddles, respectively,
If the rotational speed of the mold is fast, mold surfaces closer to the bottom tend to be starved and remote surfaces overloaded; if it is attempted to overcome this lack of uniformity by employing a lower rotational speed, the liquid charge may remain at or near the bottom of the mold so that higher areas are starved; and if the mold surface is not a continuous smooth one, but is interrupted by angles, crevices, curvatures, or protrusions, a heavy or insufiicient material buildup occurs in these parts. Additionally, nonuniform distribution of the material on the walls of the mold cavity is often more pronounced in the case of such low-viscosity materials.
In attempts to overcome the above-mentioned difiiculties, complicated centrifugal casting machines have been constructed to impart a compound centrifugal motion to the mold and the liquid charge therein, such as proposed, for instance, in United States Patent No. 2,961,703. Various attempts made heretofore resulted only in a partial alleviation of the problems.
It is an object of the invention to provide an improved centrifugal casting method eliminating the above-mentioned drawbacks of the prior art methods.
According to the improved centrifugal casting process of the invention, a charge of the liquid material to be molded is inserted into a stationary or rotating mold and, subsequently, depending on Whether or not the mold is already rotating, rotation is commenced. After the mold has accomplished acceleration to the maximum r.p.m., its rate of rotation is alternately decreased and increased. In the alternative, the mold can be alternatively rotated in a clockwise and counterclockwise direction.
As a result of the alternating acceleration and deceleration of the mold, or the alternative method, whereby the acceleration and deceleration are coupled with a directional change, the material charge-d into the mold cavity Will first have a speed less than the speed of the mold. Due to the friction between the mold and the material, the latter will accelerate until an equilibrium is established between the speed of the mold and that of the material. When the mold rotation is braked, the material, due to inertia, will continue rotating by its momentum at a speed higher than the speed of the decelerating mold, resulting in a lateral relative shearing displacement between the material and mold, the material thereby Washing the mold walls in a lateral direction. The mold deceleration is followed by a more gradual deceleration of the material, and the lateral slippage or displacement of the material relative to the mold diminishes in degree in time. If the mold is now accelerated again, a second lateral relative displacement between the material and the mold walls occurs due to the friction of the material against the wall, the second relative displacement being in an opposite sense as the displacement which occurred during the deceleration. A similar alternating relative displacement between the material and the mold walls can be accomplished in both directions when the direction of the mold rotation is reversed. As a result of these lateral relative displacements, a greater wall thickness uniformity of the material of the object thus molded, along any horizontal cross section, can be accomplished. Due to the alternating accelerations and decelera-tions and the attendant increases and decreases in the centrifugal force acting on the material, it will, in addition to the lateral displacements referred to above, also move up and down along the mold cavity, and thereby repeatedly wash the mold Walls to permit the forming of items, the inner cross-sectional shape of which markedly deviates from a paraboloid. In addition, a better and more uniform layup or mold-wall coverage with the material will also result.
In the prior art continuous rotation centrifuging techniques, slight variations in material characteristics and temperature required a constant readjusting and close control of the material temperature and mold rotation. By employing the alternating rotational process of this invention, the strict control requirements necessitated by the prior art methods may be relaxed.
If the item to be molded is desired to be formed with stratified walls, wherein successive layers of different materials form the composite wall cross-section, the materials forming the different layers may be charged into the mold at successive stages. Such layers may include alternating deposited layers of materials having varying physical properties complementing each other, alternating layers of resins, fillers, pigments, etc.
Undue material buildup in corners and crevices of the mold is avoided because only a relatively thin layer of material is deposited within one acceleration and deceleration cycle as the material shifts up and then down along the walls, and the thin layer is well distributed in such places before another layer of material is deposited thereon in a subsequent cycle.
The rate of deceleration or acceleration is limited by the possibility that at higher rates the liquid material may tend to splash or form waves, and if this occurs at a point where the liquid starts to solidfy or polymerize, the irregularities may be frozen into the final molded body shape. This limiting rate has to be determined individually case of very fluid.
for the particular material used, surface tension and mold shape.
The rotational speeds employed will greatly vary from one material and mold shape to another, but in the materials, such as anionically polymthe rotational speed usually always in view of its viscosity,
erized caprolactam, exceeds 50 r.p.m.
In the following, by way of example, an embodiment of the process, of the inventionis given, as applied to centrifugal polymerization of liquid lactams while casting objects thereof, thel-a-ctams generally having a viscosity of about 10 centipoises in the monomer state; however, it is to be understood that the process of the invention is also applicableto the .centrifugal casting of other materials which have different viscosities, The minor adjustments of the processing parameters for any given material may be determined by routine experimentation.
Example An aluminum vessel 11 inches in diameter and 7 inches deep and having a flat bottom joined by a gentle curve to the slightly tapered, almost cylindrical sidewall was mounted in an electric oven as a mold for rotation about. its axis. The mold vessel was covered and sealed except for a 1-inch hole in the center for purging the mold cavity with an inert gas and for introducing liquid resin therethrough. The mold Was preheated to 175 C. and the cavity purged with dry nitrogen.
With the mold rotating at 500 r.p.m., 250 g. of a mix ture consisting of 247 g. caprolactam, 2% g. lithium caproylimi-de, erization catalyst and promotor at 100 C. was charged through the filler. opening. Materialsof this type are described in greater detail, for instance, in Belgian Patent No. 623,840. During the handling and pouring, the mixture was blanketed vwith dry nitrogen to prevent its exposure to atmospheric moisture and oxygen.
As soonas the mixture was fully charged into the mold, the mold rotation was braked from the original 500 r.p.m. to a full stop in 5 seconds. After a -secondrest the mold'was accelerated again in 5 seconds to 500 r.p.m. by a torque motor driving the mold through a belt. As soon as the mold reached the full speed, it was again decelerated, and this 20-second cycle was repeated for. a period of 5 minutes.
A second 250 g. charge of then poured into the mold rotating at 500 r.p.m. and the above 5-minute acceleration-deceleration cycling was repeated. After the mold was stopped, it was maintained 7 at 175 C. for minutes. The resulting saucepan-shaped item had excellent circumferential wall thickness uniformity; the vertical wall thickness distribution was also satisfactory; The two successive charges gave a cross-section that appeared as if only one charge had been made.
It is to be understood that the invention is disclosed by way of an example and, depending on production requirements and material characteristics, a number of and 0.63 g. triphenoXy-s-triazine as polym-' modifications may be employed. Different materials and different production rates would require different processing temperatures and durations, while some materials, such as thermoplasticresins may also require cooling during the process. Depending on the viscosity characteristics of the material to be molded, a variety of acceler-ation and deceleration rates as well as rotation times may beused. The process of the invention is not limited to centrifuging only about a vertical mold axis, the process is also applicable to the centrifugal casting of articles in which the walls above the bottom plane converge inward at any point. In this case the rotational axis of the mold has to be inclined from the vertical at some point during In view of the foregoing, the scope the rotational cycle. of the invention is to claims.
I claim: 1. In a centrifugal casting process wherein a mold is charged with a materialto a molded, and the material is converted therein froma fluid liquidv to a solid phase,
be interpreted from the appended the improvement which comprises a repeated cycle of j rotating said mold about its vertical 'aXis to.a desired rotational speed of at least 50 r.p.m. and quickly braking said rotating moldwhen it attains said desired rotational speed, each cycle comprising about 10 seconds of rotation in which, the mold is not followed by about 10 seconds rotated.
2. The process of claim 1 wherein the direction of rotation is reversed about each braking.
3. The process of claim 1 wherein the desired speed of rotation-is in the range from 50 to about 500 r.p.m.
4. An improved centrifugal casting process which comprises charging a mold with a mixture, consisting the mixture at 100 C. was i polymerization promotor followed by essentially of caprolactam, an anionic catalyst and a the repeated cycle of rotating the mold about its vertical axis to a about 500' r.p.m., quickly braking the rotation within -a periodof about .5 seconds when it attains the desired rotational speed and permitting the mold to'remain at least for about 10 seconds prior to repeating the cycle.
5. The process of claim rotation is reversed for'each succeeding cycle.
References'Cited UNITED STATES PATENTS ROBERT F. WHITE, S. I. LANDSMAN, Assistant Examin n Primary Examiner.
speed of 4 wherein the direction of
Claims (1)
1. IN A CENTRIFUGAL CASTING PROCESS WHEREIN A MOLD IS CHARGED WITH A MATERIAL TO A MOLDED, AND THE MATERIAL IS CONVERTED THEREIN FROM A FLUID LIQUID TO A SOLID PHASE, THE IMPROVEMENT WHICH COMPRISES A REPEATED CYCLE OF ROTATING SAID MOLD ABOUT ITS VERTICAL AXIS TO A DESIRED ROTATIONAL SPEED OF AT LEAST 50 R.P.M. AND QUICKLY BRAKING SAID ROTATING MOLD WHEN IT ATTAINS SAID DESIRED ROTATIONAL SPEED, EACH CYCLE COMPRISING ABOUT 10 SECONDS OF ROTATION FOLLOWED BY ABOUT 10 SECONDS IN WHICH THE MOLD IS NOT ROTATED.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US315370A US3341641A (en) | 1963-10-10 | 1963-10-10 | Centrifugal casting process |
FR990794A FR1410825A (en) | 1963-10-10 | 1964-10-08 | Centrifugal casting process and molded articles obtained by this process |
NL6411728A NL6411728A (en) | 1963-10-10 | 1964-10-08 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US315370A US3341641A (en) | 1963-10-10 | 1963-10-10 | Centrifugal casting process |
Publications (1)
Publication Number | Publication Date |
---|---|
US3341641A true US3341641A (en) | 1967-09-12 |
Family
ID=23224086
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US315370A Expired - Lifetime US3341641A (en) | 1963-10-10 | 1963-10-10 | Centrifugal casting process |
Country Status (2)
Country | Link |
---|---|
US (1) | US3341641A (en) |
NL (1) | NL6411728A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3627869A (en) * | 1967-10-06 | 1971-12-14 | Phillips Petroleum Co | Method of producing a laminated polyethylene-polypropylene article |
US5035850A (en) * | 1987-03-24 | 1991-07-30 | Teikoku Hume Pipe Co., Ltd. | Method of producing concrete composite pipe |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2325019A (en) * | 1939-03-14 | 1943-07-20 | Rubissow George Alexis | Method for molding by pulsating centrifugal force |
US2466277A (en) * | 1945-03-26 | 1949-04-05 | George A Rubissow | Method of casting |
US2629130A (en) * | 1950-05-08 | 1953-02-24 | Rempel Mfg Inc | Apparatus for producing articles as by compound rotation of articleforming means |
US2971223A (en) * | 1959-01-16 | 1961-02-14 | Grunin Louis | Process of preparing cast synthetic resin having integral sheen |
US3048896A (en) * | 1959-05-26 | 1962-08-14 | Marlo Arvid | Centrifugal rotational molding method |
US3161712A (en) * | 1961-06-12 | 1964-12-15 | Air Reduction | Rotational molding |
US3164654A (en) * | 1960-04-18 | 1965-01-05 | Allied Chem | Process for casting thermoplastic materials |
-
1963
- 1963-10-10 US US315370A patent/US3341641A/en not_active Expired - Lifetime
-
1964
- 1964-10-08 NL NL6411728A patent/NL6411728A/xx unknown
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2325019A (en) * | 1939-03-14 | 1943-07-20 | Rubissow George Alexis | Method for molding by pulsating centrifugal force |
US2466277A (en) * | 1945-03-26 | 1949-04-05 | George A Rubissow | Method of casting |
US2629130A (en) * | 1950-05-08 | 1953-02-24 | Rempel Mfg Inc | Apparatus for producing articles as by compound rotation of articleforming means |
US2971223A (en) * | 1959-01-16 | 1961-02-14 | Grunin Louis | Process of preparing cast synthetic resin having integral sheen |
US3048896A (en) * | 1959-05-26 | 1962-08-14 | Marlo Arvid | Centrifugal rotational molding method |
US3164654A (en) * | 1960-04-18 | 1965-01-05 | Allied Chem | Process for casting thermoplastic materials |
US3161712A (en) * | 1961-06-12 | 1964-12-15 | Air Reduction | Rotational molding |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3627869A (en) * | 1967-10-06 | 1971-12-14 | Phillips Petroleum Co | Method of producing a laminated polyethylene-polypropylene article |
US5035850A (en) * | 1987-03-24 | 1991-07-30 | Teikoku Hume Pipe Co., Ltd. | Method of producing concrete composite pipe |
Also Published As
Publication number | Publication date |
---|---|
NL6411728A (en) | 1965-04-12 |
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