US3341509A - Polymerization of polyolefins - Google Patents
Polymerization of polyolefins Download PDFInfo
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- US3341509A US3341509A US511287A US51128765A US3341509A US 3341509 A US3341509 A US 3341509A US 511287 A US511287 A US 511287A US 51128765 A US51128765 A US 51128765A US 3341509 A US3341509 A US 3341509A
- Authority
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- United States
- Prior art keywords
- polymer
- polyolefin
- curing
- lithium
- cure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000098 polyolefin Polymers 0.000 title claims description 21
- 238000006116 polymerization reaction Methods 0.000 title description 6
- 229920000642 polymer Polymers 0.000 claims description 20
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 229910052783 alkali metal Inorganic materials 0.000 claims description 15
- 150000001340 alkali metals Chemical class 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 2
- 229910000102 alkali metal hydride Inorganic materials 0.000 claims 1
- 150000008046 alkali metal hydrides Chemical class 0.000 claims 1
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical class [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 claims 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 9
- 229910052744 lithium Inorganic materials 0.000 description 8
- 239000011800 void material Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 4
- 150000004678 hydrides Chemical class 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 239000003380 propellant Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910010082 LiAlH Inorganic materials 0.000 description 2
- -1 LiH Chemical class 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 150000002642 lithium compounds Chemical class 0.000 description 2
- 229910000103 lithium hydride Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052987 metal hydride Inorganic materials 0.000 description 2
- 150000004681 metal hydrides Chemical class 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 150000002902 organometallic compounds Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920001195 polyisoprene Polymers 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- KCMZYCFSSYXEQR-UHFFFAOYSA-N CCCC[K] Chemical compound CCCC[K] KCMZYCFSSYXEQR-UHFFFAOYSA-N 0.000 description 1
- IRDQNLLVRXMERV-UHFFFAOYSA-N CCCC[Na] Chemical compound CCCC[Na] IRDQNLLVRXMERV-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920002121 Hydroxyl-terminated polybutadiene Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000010533 azeotropic distillation Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000012280 lithium aluminium hydride Substances 0.000 description 1
- SIAPCJWMELPYOE-UHFFFAOYSA-N lithium hydride Chemical compound [LiH] SIAPCJWMELPYOE-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
- C08C19/34—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with oxygen or oxygen-containing groups
- C08C19/38—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with oxygen or oxygen-containing groups with hydroxy radicals
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B45/00—Compositions or products which are defined by structure or arrangement of component of product
- C06B45/04—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive
- C06B45/06—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive the solid solution or matrix containing an organic component
- C06B45/10—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive the solid solution or matrix containing an organic component the organic component containing a resin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S260/00—Chemistry of carbon compounds
- Y10S260/31—Ionic cross-link
Definitions
- This invention relates to the polymerization of polyolefins and more particularly to a process whereby polymerization of fully polymerized polyolefins can be reinitiated by the addition thereto of a curing agent comprised of alkali metals or alkali metal compounds.
- a curing agent comprised of alkali metals or alkali metal compounds.
- the grain In the fabrication of solid rocket propellant grains the grain generally consists of a polymeric binder and various high energy additives such as active metals or metal hydrides.
- various curing agents used to cure the binder into its tough, rubbery form are highly reactive with the active metal and active metal hydrides and interreact therewith producing gas pockets and other voids within the cured polymer structure. It is, however, essential that the final grain be free from any such voids so that the burning rates can be constant and that the grain has maximum strength.
- the process of this invention can produce a tough rubbery polymer from'an initially completely polymerized liquid resin without the addition of any of the reactive curing agents previously required and produces a void-free polymer fuel matrix having the necessary characteristics of strength and controlled burning rate.
- 'It is, accordingly, the primary object of this invention to provide a process for reinitiating polymerization in liquid polyolefin polymers chain propagation of which has previously been completed.
- polyolefin polymers with terminal OH groups can be cured merely by the addition of alkali metals, their hydrides or organometallic cOmpOunds thereto followed by curing at predetermined temperature for various periods of time.
- the temperature and time of cure are interrelated and the cure time required decreases as the temperature of cure is increased.
- cures may be obtained at 70 F., but such cures require times in the order of several days, whereas at temperatures of about 100 F., cure occurs in about 18 hours.
- Suitable curing agents include the alkali metals such as metallic lithium.
- Suitable polyolefin compounds include both nited States Patent Patented Sept. 12, 1967 Suitable polybutadienes included BD-R15 and BDR45 available from Sinclair Petrochemicals and suitable polyisoprenes include AVII-20 manufactured by Texas Bu tadiene.
- the amount of alkali metal required can vary from a minimum of about 2 percent by weight of the mixture to a maximum of approximately 60 percent. Above about 60 percent, the cure still occurs, but some of the solids are rejected from the curing mixture and the strength of the cured polymer tends to decrease due to the imperfections formed in the cured polymer. If materials other than alkali metal are used, such as, for example, lithium hydride, lithium aluminum hydride or butyl lithium, a larger amount of material is required than when using metallic lithium. Since it is the alkali metal that is the effective curing agent, if the above materials are used instead of metals per se, the alkali metal component of the materials must react with the polymer and this metal component is the agent that effects the cure.
- the minimum weight necessary for the use of the lithium compounds is equal to the equivalent weight of the material necessary to produce at least about 2 percent of reactive lithium in the mixture.
- the alkali metals and their compounds according to this invention are very reactive, it is necessary to carry out the mixing in an inert atmosphere.
- Commercially available argon has been found satisfactory since its dew point is sufficiently low so that the curing agent will act as a getter for the remaining water and form an inert filler in the solid polymer.
- the procedure followed in preparing these compounds is to Weigh out the desired amount of curing agent into a mixing Vessel maintained under an inert atmosphere, add the liquid polyolefin and mix the two in an inert atmosphere. The polyolefin is then cast into the desired form, still under an inert atmosphere.
- the curing agents used are preferably finely divided and although larger diameter particles may be used, it is preferable that 90 percent of the particles be under 20 microns in diameter.
- liquid hydroxyl terminated polyolefin polymer which comprises adding to said polymer a curing agent selected from the group consisting of alkali metals, alkali metal TABLE 1 Lithium, Hydride, F.) (Hrs) No. percent percent by Liquid Polymer, percent by Wt. Cure Cure Remarks by Wt. Wt. Temp. Time 1 93.2 81 BD-R-15, 4.72 Mineral 140 18 Very pliable; void free.
- a curing agent selected from the group consisting of alkali metals, alkali metal TABLE 1 Lithium, Hydride, F.) (Hrs) No. percent percent by Liquid Polymer, percent by Wt. Cure Cure Remarks by Wt. Wt. Temp. Time 1 93.2 81 BD-R-15, 4.72 Mineral 140 18 Very pliable; void free.
- the alkali metal is shipped in a mineral oil or other material, it may be desirable to filter the metal in a dry box and wash with pentane to prepare it for use in this process. Also, some of the liquid polyolefins contain water which, in suchcases, must be removed by conventional techniques such as azeotropic distillation.
- the above method of preparing the polymer is particularly useful with respect to the formulation of a propellant grain.
- the tough, rubbery cured polymer formed herein can also be used in other applications.
- the article to be coated could be sprayed or dipcoated with the mixture of the polyolefin and lithium and then the coated article cured for the desired period of time to provide a tough, rubbery stronglyadherent coating thereon.
- the lithium would be kept to a minimum and could be utilized in coating cans or other containers, for example.
- polyolefin is selected from the group consisting of hydroxyl terminated polybutadiene and hydroxyl terminated polyisoprene.
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dispersion Chemistry (AREA)
- Molecular Biology (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
3,341,509 POLYMERIZATION F POLYOLEFINS Peter L. Stang, Ewingville, N.J., assignor to United Aircraft Corporation, East Hartford, Conn., a corporation of Delaware No Drawing. Filed Nov. 24, 1965, Ser. No. 511,287 5 Claims. (Cl. 26094.2)
This invention relates to the polymerization of polyolefins and more particularly to a process whereby polymerization of fully polymerized polyolefins can be reinitiated by the addition thereto of a curing agent comprised of alkali metals or alkali metal compounds. This application is a continuation-in-part of my co-pending, co-assigned patent application S.N. 270,322 filed Apr. 3, 1963.
In the fabrication of solid rocket propellant grains the grain generally consists of a polymeric binder and various high energy additives such as active metals or metal hydrides. Unfortunately, it is known that the various curing agents used to cure the binder into its tough, rubbery form are highly reactive with the active metal and active metal hydrides and interreact therewith producing gas pockets and other voids within the cured polymer structure. It is, however, essential that the final grain be free from any such voids so that the burning rates can be constant and that the grain has maximum strength. The process of this invention can produce a tough rubbery polymer from'an initially completely polymerized liquid resin without the addition of any of the reactive curing agents previously required and produces a void-free polymer fuel matrix having the necessary characteristics of strength and controlled burning rate.
While this invention has particular utility in the field of rocket propellants, it also has broader utility in the general field of polymerization where it is desirable to produce a cured polymeric material.
'It is, accordingly, the primary object of this invention to provide a process for reinitiating polymerization in liquid polyolefin polymers chain propagation of which has previously been completed.
It is another object of this invention to provide a novel class of curing agents for hydroxy-terminated polyolefins.
It is another object of this invention to provide a method for producing a tough rubbery polymer from a liquid polyolefin polymer.
These andother objects of the invention Will be readily apparent from the following description.
It has been found that polyolefin polymers with terminal OH groups can be cured merely by the addition of alkali metals, their hydrides or organometallic cOmpOunds thereto followed by curing at predetermined temperature for various periods of time. The temperature and time of cure are interrelated and the cure time required decreases as the temperature of cure is increased. Thus, although there is no criticality in the temperatures chosen, they should be selected so that the cure is completed within a reasonable and practical time. For example, cures may be obtained at 70 F., but such cures require times in the order of several days, whereas at temperatures of about 100 F., cure occurs in about 18 hours. Suitable curing agents include the alkali metals such as metallic lithium. sodium, and potassium, their hydrides such as LiH, LiAlH NaH, KH and their organometallic compounds such as butyl lithium and butyl sodium and butyl potassium. This list is not all inclusive and, for example, other materials including the heavier alkali metals and their compounds can be used. The essential characteristic being that the curing agent employed when added to the polyolefin will produce reactive alkali metal in the mixture. It has been found that lithium and lithium compounds are the preferred curing agents. Suitable polyolefin compounds include both nited States Patent Patented Sept. 12, 1967 Suitable polybutadienes included BD-R15 and BDR45 available from Sinclair Petrochemicals and suitable polyisoprenes include AVII-20 manufactured by Texas Bu tadiene.
The amount of alkali metal required can vary from a minimum of about 2 percent by weight of the mixture to a maximum of approximately 60 percent. Above about 60 percent, the cure still occurs, but some of the solids are rejected from the curing mixture and the strength of the cured polymer tends to decrease due to the imperfections formed in the cured polymer. If materials other than alkali metal are used, such as, for example, lithium hydride, lithium aluminum hydride or butyl lithium, a larger amount of material is required than when using metallic lithium. Since it is the alkali metal that is the effective curing agent, if the above materials are used instead of metals per se, the alkali metal component of the materials must react with the polymer and this metal component is the agent that effects the cure. The minimum weight necessary for the use of the lithium compounds is equal to the equivalent weight of the material necessary to produce at least about 2 percent of reactive lithium in the mixture.
The exact mechanism of cure has not been completely established but from a consideration of the time involved and the evolution of hydrogen that is noted after mixing,
a condensation reaction rather than a free radical mechanism is suggested.
While not being limited thereto, the following reaction mechanisms appear consistent with existing observations:
Since the alkali metals and their compounds according to this invention are very reactive, it is necessary to carry out the mixing in an inert atmosphere. Commercially available argon has been found satisfactory since its dew point is sufficiently low so that the curing agent will act as a getter for the remaining water and form an inert filler in the solid polymer. Generally, the procedure followed in preparing these compounds is to Weigh out the desired amount of curing agent into a mixing Vessel maintained under an inert atmosphere, add the liquid polyolefin and mix the two in an inert atmosphere. The polyolefin is then cast into the desired form, still under an inert atmosphere. It is preferable to maintain the inert atmosphere at all steps, but once the solids have been wetted by the polyolefin, they are relatively safe to handle in ambient atmospheres since only a negligible amount of oxidation appears to take place at the surface of the mixture. The curing agents used are preferably finely divided and although larger diameter particles may be used, it is preferable that 90 percent of the particles be under 20 microns in diameter.
liquid hydroxyl terminated polyolefin polymer, which comprises adding to said polymer a curing agent selected from the group consisting of alkali metals, alkali metal TABLE 1 Lithium, Hydride, F.) (Hrs) No. percent percent by Liquid Polymer, percent by Wt. Cure Cure Remarks by Wt. Wt. Temp. Time 1 93.2 81 BD-R-15, 4.72 Mineral 140 18 Very pliable; void free.
1 2 18 Soft and pliable. 3 18 D0. 4 18 Tough, void free. 5 18 Do. 6 do 18 Do. 7 6.72 LiAlH 7; ISqoft; and pliable.
. 7 o cure. 8 00 mm 7g gough and pliable; void free.
- 7 0 cure. 9 00 10'00 72 Tough and pliable; void free. 10 None 5000 18 Tough and pliable; void free. 11... 10.00 90.00 AVII 18 Tough and rubbery. 12 5. 55 81.050l BD-R-14, 1 95 Mineral 140 18 Very pliable; void free.
13. 60.00 40.00 AVII-ZO 140 18 Tough and rubbery.
In cases where the alkali metal is shipped in a mineral oil or other material, it may be desirable to filter the metal in a dry box and wash with pentane to prepare it for use in this process. Also, some of the liquid polyolefins contain water which, in suchcases, must be removed by conventional techniques such as azeotropic distillation.
The preceding table describes various representative compositions cured according to the above described method.
The above method of preparing the polymer is particularly useful with respect to the formulation of a propellant grain. However, the tough, rubbery cured polymer formed herein can also be used in other applications. For example, if it is desired to use the cured polymer as a coating material, the article to be coated could be sprayed or dipcoated with the mixture of the polyolefin and lithium and then the coated article cured for the desired period of time to provide a tough, rubbery stronglyadherent coating thereon. In such a process the lithium would be kept to a minimum and could be utilized in coating cans or other containers, for example.
While this invention has been disclosed with respect to specific examples thereof, these examples are illustrative and should not be construed as limiting of the invention. The invention is limited only by the following claims wherein I claim:
1. A method for increasing the molecular weight of a hydrides and organo-alkali metallic compounds, said material being present in an amount sufficient to yield at least 2% of reactive alkali metal in said polymer, mixing said polymer and said material to uniformly distribute said material through said polyolefin and curing the mixture at a temperature of at least about F.
2. The process according to claim 1 wherein said polyolefin is selected from the group consisting of hydroxyl terminated polybutadiene and hydroxyl terminated polyisoprene.
3. The process of claim 1 wherein said curing agent is lithium.
4. The process of claim 1 wherein said curing agent is sodium.
5. The .process of claim 1 wherein the temperature is at least about 100 F.
References Cited UNITED STATES PATENTS 3,055,952 9/1962 Goldberg 26094.7 3,119,800 l/1964 Moss et al 260 XR 3,175,997 3/1965 Hsieh 260-94.7
JOSEPH L. SCHOFER, Primary Examiner.
BENJAMIN R. PADGETT, Examiner.
L. A. SEBASTIAN, H. I. CANTOR, F. HAMROCK,
Assistant Examiners.
Claims (1)
1. A METHOD FOR INCREASING THE MOLECULAR WEIGHT OF A LIQUID HYDROXYL TERMINATED POLYOLEFIN POLYMER, WHICH COMPRISES ADDING TO SAID POLYMER A CURING AGENT SELECTED FROM THE GROUP CONSISTING OF ALKALI METALS, ALKALI METAL HYDRIDES AND ORGANO-ALKALI METALLIC COMPOUNDS, SAID MATERIAL BEING PRESENT IN AN AMOUNT SUFFICIENT TO YIELD AT LEAST 2% THROUGH SAID POLYOLEFIN AND CURING THE MIXTURE SAID POLYMER AND SAID MATERIAL TO UNIFORMLY DISTRIBUTE SAID MATERIAL THROUGH SAID POLYOLEFIN AND CURING THE MIXTURE AT A TEMPERATURE OF AT LEAST ABOUT 70*F.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US511287A US3341509A (en) | 1965-11-24 | 1965-11-24 | Polymerization of polyolefins |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US511287A US3341509A (en) | 1965-11-24 | 1965-11-24 | Polymerization of polyolefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3341509A true US3341509A (en) | 1967-09-12 |
Family
ID=24034255
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US511287A Expired - Lifetime US3341509A (en) | 1965-11-24 | 1965-11-24 | Polymerization of polyolefins |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US3341509A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3507114A (en) * | 1967-11-27 | 1970-04-21 | Webb James E | Solid propellant liner |
| JPS5225007A (en) * | 1975-08-15 | 1977-02-24 | Boeicho Gijutsu Kenkyu Honbuch | Propellant composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3055952A (en) * | 1957-10-09 | 1962-09-25 | Du Pont | Hydroxyl-terminated polymers |
| US3119800A (en) * | 1961-04-07 | 1964-01-28 | Shell Oil Co | Method of controlling the molecular weight of polyisoprene |
| US3175997A (en) * | 1959-10-23 | 1965-03-30 | Phillips Petroleum Co | Method of preparing polymers containing hydroxy end groups |
-
1965
- 1965-11-24 US US511287A patent/US3341509A/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3055952A (en) * | 1957-10-09 | 1962-09-25 | Du Pont | Hydroxyl-terminated polymers |
| US3175997A (en) * | 1959-10-23 | 1965-03-30 | Phillips Petroleum Co | Method of preparing polymers containing hydroxy end groups |
| US3119800A (en) * | 1961-04-07 | 1964-01-28 | Shell Oil Co | Method of controlling the molecular weight of polyisoprene |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3507114A (en) * | 1967-11-27 | 1970-04-21 | Webb James E | Solid propellant liner |
| JPS5225007A (en) * | 1975-08-15 | 1977-02-24 | Boeicho Gijutsu Kenkyu Honbuch | Propellant composition |
| JPS5333649B2 (en) * | 1975-08-15 | 1978-09-16 |
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