US3330753A - Electroplating barrel for non-conductive buoyant and near-buoyant articles - Google Patents

Electroplating barrel for non-conductive buoyant and near-buoyant articles Download PDF

Info

Publication number
US3330753A
US3330753A US351988A US35198864A US3330753A US 3330753 A US3330753 A US 3330753A US 351988 A US351988 A US 351988A US 35198864 A US35198864 A US 35198864A US 3330753 A US3330753 A US 3330753A
Authority
US
United States
Prior art keywords
barrel
buoyant
conductive
plating
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US351988A
Inventor
Ivan C Hepfer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to US351988A priority Critical patent/US3330753A/en
Application granted granted Critical
Publication of US3330753A publication Critical patent/US3330753A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/16Apparatus for electrolytic coating of small objects in bulk
    • C25D17/18Apparatus for electrolytic coating of small objects in bulk having closed containers
    • C25D17/20Horizontal barrels

Definitions

  • Electroplating of small metal objects in a rotating plating barrel immersed in a plating solution is generally relatively easy to achieve. Continuous contact of the objects in the bottom of the barrel is readily made by dangling cathodic contacts or by electrode buttons on the inner barrel peripheral Wall. Metallic objects are good conductors and tumble nicely in the bottom of the barrel as it rotates.
  • these non-conductive materials have a specific gravity less than or only slightly greater than the plating solution, e.'g., about 0.9 to 1.8 they either float on the solution, or if they sink, remain in a semi-buoyant suspended state in the agitated solution. This creates several difficultices. Firstly, the lightweight articles fail to tumble and mix properly in the rotating barrel for uniform plating, but rather tend to remain in a suspended, freely moving state. Secondly, a small area of contact between the buoyant or near buoyant parts causes poor conductivity between the parts, even though they .are provided with a thin metallized coating. Thirdly, the
  • peripheral contacts do provide more contact area, they are deficient in that they attract the major share of the current, causing little current to be attracted to the parts because of their initial poor surface conductivity. These peripheral contacts also soon build up with treed electrodeposits so that little or no current gets to the work. In fact, the plate build-up is so extensive that the small holes in the barrel walls are soon plugged. Further, in operating a barrel only partially submerged in a plating solution, the volume of parts plated must be reduced to allow for a tumbling action. This reduces the production capacity of the barrel. Further, there is a slightly greater tendency to increase the scufling action as the parts tumble outside of the plating solution.
  • buoyant non-conductive parts to be considered in the electroplating of these buoyant non-conductive parts is the distinct change of physical and electrical characteristics of the non-conductive buoyant articles after partial plating.
  • the partially plated articles increase substantially in specific gravity and sink to the bottom of the plating barrel. Further, they become much more electrically conductive. Consequently, a proper barrel must be capable of accommodating these changes to complete the plating process in a quality manner.
  • the electroplating industry is, therefore, in great need of a production plating apparatus and method for lightweight, buoyant, or near buoyant parts which are essentially non-conductive in nature.
  • an object of this invention to provide a novel method and apparatus for electroplating nonconductive articlessuch as plastic materials which have a specific gravity less than or slightly greater than the plating solution.
  • Still another object of this invention is to provide an apparatus for electroplating plastic parts that achieves excellent tumbling and mixing action, improved type of cathode contacts which result in improved contact with or between the parts to be plated, and increased contact pressure between the parts.
  • a further object of this invention is to provide an apparatus for electroplating buoyant non-conductive parts in a manner allowing the barrel to be completely immersed beneath the plating solution for maximum production rates and minimum oxidation, while still achieving uniform dependable plating of articles.
  • Still a further object of this invention is to achieve the above objects with an apparatus which can be formed from conventional plating barrel structures with a few significant but relatively inexpensive modifications and additions.
  • Further objects of this invention are to make possible efficient barrel plating: of thin metallized plastic or nonconducting materials which either float or sink in the plating solution; that does not cause damage to the thin metallized coating on the plastic parts as in conventional barrel plating where the heavy danglers often scratch off the thin metallized coating before the parts build up a substantial electrodeposit on the surface; that brings about a much faster coverage of the parts with the electrodeposit to thereby reduce rejects due to abrasion or bipolar effects, and also to thereby increase production; that enables consumable components (cathode contacts) to be readily removed and replaced when built up beyond a usable condition with electrodeposit material; that enables much larger loads to be processed compared to previous methods; that enables lower generator voltage to be used to effect complete and faster coverage as compared to conventional methods; that maintains the floating objects in intimate pressed contact with one another for optimum conductivity; that enables the barrel to be operated either totally submerged where there is less tendency of breaking electrical contact and less danger of oxidation, but also
  • FIG. 1 is a perspective view of the plating barrel shown immersed in a plating solution illustrated in phantom;
  • FIG. 2 is a perspective view of a portion of the barrel in FIG. 1, shown with one hexagonal panel that serves as the cover removed and adjacent wall portions cut away;
  • FIG. 3 is an enlarged, elevational, sectional view of the barrel in FIGS. 1 and 2;
  • FIG. 4 is an enlarged, fragmentary, perspective view of the central portion of the barrel assembly in FIGS. 1 through 3;
  • FIG. 5 is an enlarged, sectional view of one end spider hub of the barrel assembly
  • FIG. 6 is a sectional, enlarged view taken on plane VI-VI of FIG. 3;
  • FIG. 7 is a sectional, enlarged view taken on plane VII-VII of FIG. 3;
  • FIG. 8 is a sectional, elevational view of a second form of the invention.
  • FIG. 9 is a sectional, elevational view of one type of contactor structure of the apparatus in FIG. 8, taken on the plane IX-IX of FIG. 8',
  • FIG. 10 is a sectional view of a second type of contactor useful for the structure of FIG. 8;
  • FIG. 11 is a perspective, enlarged view of a central portion similar to that in FIG. 4, but slightly modified;
  • FIG. 12 is a fragmentary, enlarged, elevational, sectional view of a further modified end assembly.
  • FIG. 13 is an end elevational view of the apparatus in FIG. 3.
  • the first form of the plating assembly 10 shown includes a plating tank 12 (shown in phantom) and the barrel assembly itself 14.
  • the barrel assembly includes a barrel 16 having a pair of end plates 18 and 20 and a peripheral shell 22. It is formed of a non-conductive material such as a high temperature acrylic, polypropylene, rigid polyethylene, etc.
  • the peripheral wall sections of the barrel are perforated, containing a large number of openings of sufificient size for solution entry and drainage, but small enough to prevent article passage.
  • the barrel is supported on a nonconductive holding frame, including suspension arms 24 and 26 on opposite ends of the barrel. These suspension arms have coaxial openings which receive a pair of nonconductive axles or barrel hubs 28 and 30. These include means forming cable holders.
  • a pair of non-conductive belt pulleys 34 and 36 operably associated with a pair of drive belts 38 and 40 (FIG. 1) to rotate the barrel.
  • a pair of non-conductive locking plates 44 and 46 Slidably inserted between each of the pulleys and the end frame arms is a pair of non-conductive locking plates 44 and 46 of conventional construction, interfitting with slotted keyways in elements 28 and 30 to secure the assembly in its suspended condition.
  • Elements 28 and 30 include removable plastic end caps 50 and 52 to hold the metallic, electrically conducting pair of cables 54 and 56 into the cable holders 28 and 30. These cables extend to an external bus bar connection (not shown) out of the tank above the barrel.
  • the cables usually of copper, are bent at right angles to extend into the pair of barrel hub assemblies on the rotational axis of the barrel.
  • the inner ends 54' and 56 of these conducting cables have metallic, conductive sleeves 60 and 62 sweated thereon.
  • the sleeves usually of stainless steel, form a sliding fit inside the annular axially elongated metallic spider hubs 64 and 66 of the assembly.
  • a pair of plugs or caps 68 and 70 are fitted in the inner ends of the hubs to cover the ends of the sleeves and cables.
  • the copper cables 54 and 56 are coated over their length up to the hubs with rubber or equivalent electrical insulating jackets 76 and 78 to prevent plating thereon.
  • each of the hubs and rigidly attached thereto as by welding is a plurality of radial spoke sleeves 90.
  • Each of these sleeves (FIG. 7) has a hollow outer radial end.
  • Correspondingly aligned sleeves on opposite hubs receive the depending pair of legs of a U-shaped copper contactor rod 94.
  • the entire hub assembly including the exposed surfaces of the hubs 64 and 66, the end plugs 68 and 70, the radial finger holders and 90', are all coated with a thin layer of electrically insulating jacket 67 (FIG, 5) such as an unplasticized vinyl chloride resin.
  • a pair of annular resilient seals 96 and 98 are inserted into holders 28 and 30 immediately behind hubs 64 and 66.
  • the U-shaped contactor rods are slidably inserted into the finger holders 90 and frictionally retained.
  • the main rotational drive for the inner assembly with the barrel is achieved by one or more dogs 106 (FIG. 2) attached to the end plates of the drum between plastic holding elements 90 and 90.
  • dogs 106 FIG. 2
  • the screw will shear and act as a safety shear pin. This prevents damage to the cathode assembly in case of a bind.
  • the hubs are electrically connected to the DC. power source by the rotating spindle assembly to the cables.
  • the cable conductors are connected to the source, and more specifically to the cathode terminal of the DC. generator or rectifier with a variable voltage of about 6-15 volts.
  • the contractor bars or rods are, therefore, cathodes in the plating solution.
  • the electrical current flows from the anodes in the plating tank (not shown) outside of the barrel through the plating solution to the articles to be plated and then from them to the bars.
  • the electrical insulation material around the hub assemblies prevents plate build up or chemical attack of these parts.
  • the contact rods can be constructed of stainless steel in many plating applications, with the rod being about A inch in diameter. When deposits build up on the rods they can be stripped in nitric acid for example. In the case of copper plating, however, it is advantageous to make the rods out of copper. Then when the rods build up with copper plating, they are removed and used as anodes in the plating bath.
  • the cathode contactor rods are placed somewhat near the outside wall of the barrel rather than the center. This shortens the distance that the electrical current has to travel from article to article to reach the cathode contactor rod. Thus, the electrical resistance is lowered and less voltage need be used. Less arcing and a faster covering of the parts with the electrodeposit will occur. If the contacting rods are placed too near the outside periphery of the barrel, it has been found that much of the current will be attracted to the rods and very little to the parts. On the other hand, if the contactors are placed too far towards the center of the barrel, the resistance of the electrical path increases and requires a higher plating voltage initially. This results in increased arcing and slower coverage, and also results in pronounced bipolar effects. Arciug will also cause burning which creates a pitted condition in the plate.
  • This invention has means for adjusting the radial length of the cathode rods to optimum conditions, by removing one U-shaped set of rods and inserting another. Consequently, the particular distance of the rods from the center of the assembly and from the periphery can be exactly adjusted to suit the particular buoyancy or specific gravity of the parts, the particular configuration and size of the parts, the loading of the barrel, the degree of immersion of the barrel in the plating solution, and any other variable factors which are normally encountered.
  • the number of contact rods employed can vary.
  • the criterion is the circumferential area to be accommodated, or, i.e., the arcuate distances between the contact bars.
  • the number of contacts is usually chosen to be equal to the number of sides of the barrel. Normally, a hexagonal shaped barrel is preferable for optimum tumbling conditions. Consequently, six rods are preferred.
  • peripheral supplemental contacts as in FIG. 11, or alternatively to use more contact bars.
  • In a 16-inch barrel it is advisable to use 12 contacts.
  • the barrel can be made of other different configurations and can accommodate diiferent numbers of the elongated, axially extending, generally parallel rods.
  • central cylindrical tube assembly 110 which controls the location of the plastic parts between the barrel axis and its periphery.
  • the central positioner tube assembly 110 is formed of a pair of hollow, semi-cylindrical elements 112 and 114 (FIG. 7) of plastic, non-conducting and non-reactive ma terials such as a rigid vinyl polymer, or a polypropylene. These have their ends overlapping the two hubs 64 and 66, and secured thereto on a plurality of bosses 114 (FIGS. 3 and 4) by screws. The sleeves are also secured together in their central portions by a plurality of intermediate plastic discs 116, using screws 118 (FIGS. 4 and 6).
  • the hollow interior of this tube includes drains to the outside, such drains being formed by a great number of peripheral openings 120 in the tube, and by slight spacing 122 between the two sections 112 and 114. Consequently, the plating solution is free to move into and out of this tube assembly as necessary, while the articles to be plated cannot pass.
  • the tube can vary in diameter according to the size of the plating barrel, it having been found that a 3-inch diameter tube performs excellent results in a 10-inch diameter plating barrel, as does a 6-inch diameter tube for a 16-inch barrel. The exact size has been found to be dependent upon article size, configuration, and density, as Well as the type of plating, barrel configuration, barrel load, and others. For small loads of articles, it has been found that a large plastic cylinder should be used.
  • the plastic tube maintains the parts out of the center of the barrel and forces them to the outside periphery where they are kept in contact with the novel cathode rods.
  • Still another function of the plastic cylinder is to distribute the load of parts more uniformly throughout the length of the plating barrel for a more uniform plate coverage. In other words, it prevents bunching and/or free floating. Its main function, however is to locate the plastic parts in the vicinity of the contactor rods, which in turn are located between the center of the periphery of the barrel.
  • the second barrel may be desirable to transfer articles to a second barrel of similar construction after the parts have been completely covered with sufficient plate to give good electrical conductivity in the first barrel.
  • the second barrel will have the contactor rods placed closer to or adjacent the plastic cylinder. In the second barrel, the rods build up with plate at a slower rate because they are more deeply covered with the mass of rolling parts, with more plate, therefore, being applied to the parts.
  • Optimum location for the bafile is intermediate the edges of each flat peripheral polygonal segment, with the radially outwardly extending contactor rods being staggered therewith to project toward the apices of the polygonal sides (FIG. 13).
  • These paddles cause generally sinuous movement of the objects, and further tend to hold the objects beneath the plating solution if the barrel is only partially submerged. They provide better agitation and mixing of both the parts and the solution during the plating operation. This results in more uniform plate distribution from part to part in the load, and faster plating rate due to the fact that the increased agitation allows the use of higher current densities without burning (formation of rough or treed deposits at high current density).
  • the so-called paddles are especially advantageous when plating with large diameter barrels with the cathode contacts close to the plastic center to reduce the rate of build-up of the contacts.
  • the invention will work without these paddles. It has certain definite advantages under certain conditions.
  • the cathode contacts When the cathode contacts are placed closer to the periphery of the barrel, they provide agitation to both the solution and the parts. As explained before, as soon as parts have been electroplated with sulficient copper or other electroplate in order to give them good conductivity, it is advisable to transfer them to a plating barrel with the contacts close to the plastic center in order to prevent the rapid build-up of the cathode contacts.
  • a thin electrically conductive coating To prepare the plastic parts for plating, they must first be coated with a thin electrically conductive coating. This can be done by coating with a metal using one of several methods, including vacuum metallizing, cathodesputtering, silvering reduction methods, metal spraying, metal cladding, or chemical reduction methods known as as electroless plating.
  • the articles are of course deglazed by blasting, tumbling, or chemical etching. The article surfaces are cleaned. They are sensitized chemically as with stannous chloride, and then activated by -a chemical reagent such as palladium chloride.
  • a metal, such as copper or nickel is then applied by a chemical reduction method.
  • the coating is generally in the range of 0.00001 to .00005 inch thick before the electroplating occurs.
  • the coated parts are then placed in the novel barrel by removing one of the hexagonal sides, for example, which is secured in place by any suitable clamping means such as those conventionally used to hold this side to the periphery of the barrel. Since this forms no part of the invention, is conventional and well known, it is not specifically shown.
  • the barrel is immersed in the plating solution. It is rotated at a rate of rotation of from 1 to revolutions per minute, depending upon the type of plating, size of parts and so forth. Electrical current is applied through cables 54 and 56 to sleeves 60 and 62 hubs 64 and 66. It therefore, is conducted out radial tube holders 90 to contactor rods 94.
  • the parts will usually float to the top of the barrel, if they have a specific gravity less than the specific gravity of the plating solution.
  • the contactor cathode rods therefore, make contact mostly in the upper part of the submerged barrel.
  • the barrel is normally filled about full with the parts, but it cannot be loaded so completely that the parts cannot tumble.
  • the rotation of the contactor rods with the barrel causes the parts to tumble even though they are lightweight and tend to float apart from each other and to remain in the top of the barrel. It will be understood that the main plating problem occurs initially when the parts are of substantially lighter specific gravity.
  • the elongated contactor rods 94 are tied together by wrapping around them a plurality of adjacent, binding, metallic holding elements 130. These may be formed simply of a wire wrapped around the periphery at spaced axial locations. Alternatively, the elements may be of a heavier construction.
  • the quality of products achieved with this apparatus in FIG. 11 is very similar to that of the apparatus in the first figures, but the contactor bars are more sturdy. Also, contact area and action are increased by the peripherally wrapped wires.
  • FIGS. 8, 9 and 10 Modification It has been found that some types of articles can be successfully plated utilizing the less preferred modified structure shown in FIGS. 8, 9 and 10.
  • the same central tube assembly is employed in barrel assembly 14, and the same end structures are employed, except that electrical conduction means extends clear through the barrel on its axis.
  • the two separate cables 54 and 56 are sweated into the two ends of a continuous sleeve 60a.
  • the surrounding hub support 64a also extends the length of the barrel over the sleeve. It includes a plurality of radially extending supports 90a over its length.
  • Various type legs can be used with this type of hub.
  • a plurality of radially and peripheral extending contact elements are employed, such as those illustrated in FIGS. 9 and 10. These are mounted in the plurality of support sleeves 90a.
  • the contactor elements include peripherally extending segments generally arcuate in configuration (FIG. 10) and have radial leg segments which fit in sleeves la. The elements cooperatively form a circular portion in one plane normal to the axis of rotation. Alternatively, each singular element can form a continuous circular portion 152 (FIG. 9).
  • Attached radial legs 154 inserted in sleeves 90a form electrical contact and physical mounting.
  • FIG. 12 An improved end hub assembly. This was devised to lengthen the life of the rotating barrel assembly by overcoming the potential galling problem of the hub on the sleeve over the cable in the previous forms of the invention.
  • the general peripheral barrel structure is similar, including a perforated shell 222 and a pair of end plates 220. It is supported on a holding frame with suspension arms 224, and driven by pulleys 234.
  • the cable holder 230 is on the barrel axis, having a circular inner end 231 in opening 233 of the end plate 220. Locking plates 244 are inserted between arm 224 and pulley 234 to secure the assembly.
  • the hub 266 is not basically a sleeve, however, but rather a solid metal rod having its inner end inside the plastic barrel and its outer end protruding into an annular, coaxial passage 245 in cable holder 230.
  • This passage has a narrow diameter neck slightly larger than the rod, and a larger diameter interior extending axially to plastic cap 25.2.
  • the power inlet cable 256 extends into the cable holder behind the cap and is integral with a cylindrical metal bearing cap 259 having an annular sleeve portion extending axially toward the barrel and around the outer end of the rod to make electrical contact therewith.
  • Plastic cap 252 when attached, compresses conductive bearing cap 259 to cause its inner annular end to compress O-ring 2&8 against the shoulder of the constricted portion of passage 245.
  • This preferably coupled with a rubber gasket 271 around rod 266 and against the inner axial face of cable holder 23G, effectively seals off the sliding bearing surfaces from the barrel interior.
  • a silicone grease is packed between rod 266 and bearing cap 259. Electrical conduction is therefore made from cable 256 to hearing cap 259, to rod 266, to radial sleeve 9 299, to cathode rods 294 for plating.
  • the end discs 214 for spacer tube meansw210 fit around hub rod 266.
  • the inner ends of hub rods 266 as well as sleeves 290 are coated with an insulating jacket 267.
  • the elements may be positively driven to rotate with the barrel, or may be free to rotate, or remain stationary, while the barrel rotates.
  • An electroplating barrel assembly for non-conductive lightweight buoyant and near buoyant articles, comprising: a non-conductive barrel having a perforated shell and a pair of end walls; a pair of hubs in said end walls for rotatably mounting said barrel on a central axis, including means for receiving electrical conductor means therein to make contact therefrom; a plurality of metallic contactor elements along the length of said barrel, elec trically operably associated with said hubs, having the major active contact surface portions spaced radially intermediate said shell and said axis to create article tumbling electrical contact means; and an elongated, central, hollow, perforated, non-conductive spacer means between said ends, along said ax s, spaced radially in- Wardly of said major active surface portions of said elements, and defining an open space therein, preventing articles from moving to the radial center of the shell.
  • An electroplating barre. assembly for non-conductive lightweight buoyant and near buoyant articles comprising: a non-conductive barrel having a perforated shell and a pair of end walls; a pair of non-conductive supports in said end walls for rotatably mounting said barrel on a central axis and including means for receiving electrical conductor means therein to make contact therefrom; metallic spider hub means around said conductor means and including radial support fingers; a plurality of metallic contactor elements along the length of said barrel, supported by said fingers, and electrically associated with said spider hub means, and having the major active contact surface portions spaced radially intermediate said shell and said axis to create article tumbling and electrical contact means; said spider hub means and conductor means being protected from chemical attack and electrical exposure; said contactor means comprising a plurality of circumferentially spaced metal rods extending axially of said barrel; said rods being generally U-shaped and having parallel opposite legs extending radially and being removably attached to sleeves on said hubs; an elongated non-conductive

Description

y 1957 c. HEPFER 3,330,753
ELECTROPLATING BARREL FOR NON-CONDUCTIVE BUOYANT AND NEAR-BUOYANT ARTICLES Filed March 16, 1964 4 Sheets-Sheet l Y /1/4A/ c g? July 11, 1967 l. c. HEPFER 3,330,753
ELECTROPLATING BARREL FOR NON-CONDUCTIVE BUOYANT AND NEAR-BUOYANT ARTICLES Filed March 16, 1964 4 Sheets-Sheet 2 INVENTOR /l/4/V C. HEP/ EE BY QM y 1. 61 l. c. HpFER 3 330,753
ELECTROPLATING BARREL FOR NON-CONDUCTIVE BUOYANT AND NEAR-BUOYANT ARTICLES Filed March 16, 1964 4 Sheets-Sheen 5 INVENTOR. lV/M/ 6'v HEPF BY/QQZW/ July 11. 1967 c, HEPFER 3,330,753
AND
ELECTROPLATING BARREL FOR NONCONDUCTIVE BUOYANT NEAR-BUOYANT ARTICLES Filed March 16, 1964 4 Sheets-Sheet 4 is? z 27/ I IN VEN TOR. ll/A/V Cf HEP/"E United States Patent 3,330,753 ELECTRGPLATIN G BARREL FOR NON-CON- DUCTIVE BUGYANT AND NEAR-BUOYANT ARTICLES Ivan C. Hepfer, 4587 W. Shore Drive, Caledonia, Mich. 49316 Filed Mar. 16, 1964, Ser. No. 351,988 2 Claims. (Cl. 204--213) This invention relates to electroplating, and more particularly to electroplating on non-conductive articlm such as plastic, especially with a specific gravity either slightly greater than the specific gravity of the plating solution, or less than that of the plating solution.
Electroplating of small metal objects in a rotating plating barrel immersed in a plating solution is generally relatively easy to achieve. Continuous contact of the objects in the bottom of the barrel is readily made by dangling cathodic contacts or by electrode buttons on the inner barrel peripheral Wall. Metallic objects are good conductors and tumble nicely in the bottom of the barrel as it rotates.
Recently, it has become desirable to electroplate metallic layers on non-conductive articles, such as those formed of plastic or resin based materials. Electroplating of small items such as knobs, screws, buttons and thousands of other like articles presents a considerable problem. The different physical and electrical characteristics cause conventional barrel plating techniques to be inadequate.
More specifically, since these non-conductive materials have a specific gravity less than or only slightly greater than the plating solution, e.'g., about 0.9 to 1.8 they either float on the solution, or if they sink, remain in a semi-buoyant suspended state in the agitated solution. This creates several difficultices. Firstly, the lightweight articles fail to tumble and mix properly in the rotating barrel for uniform plating, but rather tend to remain in a suspended, freely moving state. Secondly, a small area of contact between the buoyant or near buoyant parts causes poor conductivity between the parts, even though they .are provided with a thin metallized coating. Thirdly, the
parts tend to float apart in their suspended or floating state, making only random contact with each other. Fourthly, the contact pressure between the lightweight suspended parts is extremely small, thereby further decreasing the electrical conductivity between them. Fifthly, the very thin initial metallic coating previously applied to the nonconductive articles is really not a good conductive surface, so that contact area and contact pressure must be very good to achieve quality plating. Sixthly, the lightweight parts do not sink against the normal barrel contacts, but remain suspended either in or above the solution. Seventhly, even when the articles do make contact with conventional barrel contacts, plate deposition is slow and accompanied by a scuffing off the plate during the relatively long process of completely covering the metallized surface with a continuous electroplated coating. In view of these factors and others, the mass plating of lightweight, plastic parts by barrel techniques is only practiced to a limited extent presently, and is plagued with production problems.
Currently, therefore, efforts are being made to barrel plate lightweight non-conductive plastic parts by filling the barrel almost full of parts, and then rotating the barrel partially out of the plating solution. The common heavy flexible danglers presently used to make cathodic contact to the work have a tendency to scuif off the thin rnetallized coatings on the plastic parts. Also, they do not make adequate electrical contact with a sufiicient number of the plastic parts within the barrel at all times. Consequently the parts are slow in covering with the 'electrodeposit. The poor contact made, together with the 3,330,753 Patented July 11, 1967 poor surface conductivity of the metallized parts, cause electrical arcing and bipolar efiects between the parts. The above factors cause a high percentage of rejected parts due to both bare spots and pitted or burned spots.
When using contacts on the barrel periphery (commonly termed contact buttons) the barrel must still be operated partially out of the plating solution. Although peripheral contacts do provide more contact area, they are deficient in that they attract the major share of the current, causing little current to be attracted to the parts because of their initial poor surface conductivity. These peripheral contacts also soon build up with treed electrodeposits so that little or no current gets to the work. In fact, the plate build-up is so extensive that the small holes in the barrel walls are soon plugged. Further, in operating a barrel only partially submerged in a plating solution, the volume of parts plated must be reduced to allow for a tumbling action. This reduces the production capacity of the barrel. Further, there is a slightly greater tendency to increase the scufling action as the parts tumble outside of the plating solution.
It would be far preferable to have the barrel completely submerged in the plating solution to prevent oxidation of the parts during plating and to achieve maximum production rates, but this above process would not work in such an instance.
Additional eflorts have been made to plate these troublesome articles by moving the contacts from the barrel periphery to the center axis of the barrel. When this is done, however, the electroplating process is characterized by arcing or burning of the electroplate, producing a pitted condition on the articles. Further, bipolar eifects occur, causing stripping of plate off certain areas of the articles, and excessive build-up of plate on diametrically opposite areas.
Also, to be considered in the electroplating of these buoyant non-conductive parts is the distinct change of physical and electrical characteristics of the non-conductive buoyant articles after partial plating. The partially plated articles increase substantially in specific gravity and sink to the bottom of the plating barrel. Further, they become much more electrically conductive. Consequently, a proper barrel must be capable of accommodating these changes to complete the plating process in a quality manner.
The electroplating industry is, therefore, in great need of a production plating apparatus and method for lightweight, buoyant, or near buoyant parts which are essentially non-conductive in nature.
It is therefore, an object of this invention to provide a novel method and apparatus for electroplating nonconductive articlessuch as plastic materials which have a specific gravity less than or slightly greater than the plating solution.
It is another object of this invention to provide an electroplating apparatus capable of efiiciently and effectively providing an electroplate layer of high quality on the metallized non-conductive buoyant or near buoyant articles without pitting, bipolar effects, scuffing off of plate, or oxidation of parts.
Still another object of this invention is to provide an apparatus for electroplating plastic parts that achieves excellent tumbling and mixing action, improved type of cathode contacts which result in improved contact with or between the parts to be plated, and increased contact pressure between the parts.
A further object of this invention is to provide an apparatus for electroplating buoyant non-conductive parts in a manner allowing the barrel to be completely immersed beneath the plating solution for maximum production rates and minimum oxidation, while still achieving uniform dependable plating of articles.
Still a further object of this invention is to achieve the above objects with an apparatus which can be formed from conventional plating barrel structures with a few significant but relatively inexpensive modifications and additions.
Further objects of this invention are to make possible efficient barrel plating: of thin metallized plastic or nonconducting materials which either float or sink in the plating solution; that does not cause damage to the thin metallized coating on the plastic parts as in conventional barrel plating where the heavy danglers often scratch off the thin metallized coating before the parts build up a substantial electrodeposit on the surface; that brings about a much faster coverage of the parts with the electrodeposit to thereby reduce rejects due to abrasion or bipolar effects, and also to thereby increase production; that enables consumable components (cathode contacts) to be readily removed and replaced when built up beyond a usable condition with electrodeposit material; that enables much larger loads to be processed compared to previous methods; that enables lower generator voltage to be used to effect complete and faster coverage as compared to conventional methods; that maintains the floating objects in intimate pressed contact with one another for optimum conductivity; that enables the barrel to be operated either totally submerged where there is less tendency of breaking electrical contact and less danger of oxidation, but also allowing partial submerged operation if desired; that achieves excellent mixing and tumbling with better coverage and plate distribution; that enables different sized and diiferent specific gravity non-conducting parts to be readily accommodated in the same barrel in successive plating operations; that enables the non-conducting parts which change in physical and electrical characteristics to be quality plated both at the beginning and at the end of the operation; and that enables the equipment and procedure to be constructed similar to present electroplating equipment with only modest retooling expenditures and procedures.
These and several other objects of this invention will become apparent upon studying the following specification in conjunction with the drawings in which:
FIG. 1 is a perspective view of the plating barrel shown immersed in a plating solution illustrated in phantom;
FIG. 2 is a perspective view of a portion of the barrel in FIG. 1, shown with one hexagonal panel that serves as the cover removed and adjacent wall portions cut away;
FIG. 3 is an enlarged, elevational, sectional view of the barrel in FIGS. 1 and 2;
FIG. 4 is an enlarged, fragmentary, perspective view of the central portion of the barrel assembly in FIGS. 1 through 3;
FIG. 5 is an enlarged, sectional view of one end spider hub of the barrel assembly;
FIG. 6 is a sectional, enlarged view taken on plane VI-VI of FIG. 3;
FIG. 7 is a sectional, enlarged view taken on plane VII-VII of FIG. 3;
FIG. 8 is a sectional, elevational view of a second form of the invention;
FIG. 9 is a sectional, elevational view of one type of contactor structure of the apparatus in FIG. 8, taken on the plane IX-IX of FIG. 8',
FIG. 10 is a sectional view of a second type of contactor useful for the structure of FIG. 8;
FIG. 11 is a perspective, enlarged view of a central portion similar to that in FIG. 4, but slightly modified;
FIG. 12 is a fragmentary, enlarged, elevational, sectional view of a further modified end assembly; and
FIG. 13 is an end elevational view of the apparatus in FIG. 3.
Referring now specifically to the drawings, the first form of the plating assembly 10 shown includes a plating tank 12 (shown in phantom) and the barrel assembly itself 14.
The barrel assembly includes a barrel 16 having a pair of end plates 18 and 20 and a peripheral shell 22. It is formed of a non-conductive material such as a high temperature acrylic, polypropylene, rigid polyethylene, etc. The peripheral wall sections of the barrel are perforated, containing a large number of openings of sufificient size for solution entry and drainage, but small enough to prevent article passage. The barrel is supported on a nonconductive holding frame, including suspension arms 24 and 26 on opposite ends of the barrel. These suspension arms have coaxial openings which receive a pair of nonconductive axles or barrel hubs 28 and 30. These include means forming cable holders. Mounted to ends 18 and 20 of the barrel is a pair of non-conductive belt pulleys 34 and 36 operably associated with a pair of drive belts 38 and 40 (FIG. 1) to rotate the barrel. Slidably inserted between each of the pulleys and the end frame arms is a pair of non-conductive locking plates 44 and 46 of conventional construction, interfitting with slotted keyways in elements 28 and 30 to secure the assembly in its suspended condition.
Elements 28 and 30 include removable plastic end caps 50 and 52 to hold the metallic, electrically conducting pair of cables 54 and 56 into the cable holders 28 and 30. These cables extend to an external bus bar connection (not shown) out of the tank above the barrel. The cables, usually of copper, are bent at right angles to extend into the pair of barrel hub assemblies on the rotational axis of the barrel. The inner ends 54' and 56 of these conducting cables have metallic, conductive sleeves 60 and 62 sweated thereon. The sleeves usually of stainless steel, form a sliding fit inside the annular axially elongated metallic spider hubs 64 and 66 of the assembly. A pair of plugs or caps 68 and 70 are fitted in the inner ends of the hubs to cover the ends of the sleeves and cables.
The copper cables 54 and 56 are coated over their length up to the hubs with rubber or equivalent electrical insulating jackets 76 and 78 to prevent plating thereon.
Projecting from each of the hubs and rigidly attached thereto as by welding is a plurality of radial spoke sleeves 90. Each of these sleeves (FIG. 7) has a hollow outer radial end. Correspondingly aligned sleeves on opposite hubs receive the depending pair of legs of a U-shaped copper contactor rod 94. In order to prevent the exposure of metallic conductive surfaces on the hub assemblies, the entire hub assembly including the exposed surfaces of the hubs 64 and 66, the end plugs 68 and 70, the radial finger holders and 90', are all coated with a thin layer of electrically insulating jacket 67 (FIG, 5) such as an unplasticized vinyl chloride resin.
Also, to prevent plating build up on the ends of the conducting sleeves (69 and 62) and the spider hubs (64 and 66), a pair of annular resilient seals 96 and 98 are inserted into holders 28 and 30 immediately behind hubs 64 and 66.
The U-shaped contactor rods are slidably inserted into the finger holders 90 and frictionally retained. The main rotational drive for the inner assembly with the barrel is achieved by one or more dogs 106 (FIG. 2) attached to the end plates of the drum between plastic holding elements 90 and 90. Thus, when pulleys 34 and 36 rotate the drum these dogs cause the entire hub assembly to rotate. Preferably only one dog held with one screw is used, so that, in case of a jam, the screw will shear and act as a safety shear pin. This prevents damage to the cathode assembly in case of a bind. In some instances, it may be desirable to allow the hub mechanism to be free wheeling or alternatively rotationally fixed. In this instance these dogs are not employed.
The hubs are electrically connected to the DC. power source by the rotating spindle assembly to the cables. The cable conductors are connected to the source, and more specifically to the cathode terminal of the DC. generator or rectifier with a variable voltage of about 6-15 volts. The contractor bars or rods are, therefore, cathodes in the plating solution. The electrical current flows from the anodes in the plating tank (not shown) outside of the barrel through the plating solution to the articles to be plated and then from them to the bars. The electrical insulation material around the hub assemblies prevents plate build up or chemical attack of these parts.
The contact rods can be constructed of stainless steel in many plating applications, with the rod being about A inch in diameter. When deposits build up on the rods they can be stripped in nitric acid for example. In the case of copper plating, however, it is advantageous to make the rods out of copper. Then when the rods build up with copper plating, they are removed and used as anodes in the plating bath.
The cathode contactor rods are placed somewhat near the outside wall of the barrel rather than the center. This shortens the distance that the electrical current has to travel from article to article to reach the cathode contactor rod. Thus, the electrical resistance is lowered and less voltage need be used. Less arcing and a faster covering of the parts with the electrodeposit will occur. If the contacting rods are placed too near the outside periphery of the barrel, it has been found that much of the current will be attracted to the rods and very little to the parts. On the other hand, if the contactors are placed too far towards the center of the barrel, the resistance of the electrical path increases and requires a higher plating voltage initially. This results in increased arcing and slower coverage, and also results in pronounced bipolar effects. Arciug will also cause burning which creates a pitted condition in the plate.
This invention has means for adjusting the radial length of the cathode rods to optimum conditions, by removing one U-shaped set of rods and inserting another. Consequently, the particular distance of the rods from the center of the assembly and from the periphery can be exactly adjusted to suit the particular buoyancy or specific gravity of the parts, the particular configuration and size of the parts, the loading of the barrel, the degree of immersion of the barrel in the plating solution, and any other variable factors which are normally encountered.
The number of contact rods employed can vary. The criterion is the circumferential area to be accommodated, or, i.e., the arcuate distances between the contact bars. For example, on a -inch barrel, the number of contacts is usually chosen to be equal to the number of sides of the barrel. Normally, a hexagonal shaped barrel is preferable for optimum tumbling conditions. Consequently, six rods are preferred. In a 14-inch barrel on the other hand, it is advisable to use peripheral supplemental contacts as in FIG. 11, or alternatively to use more contact bars. In a 16-inch barrel, it is advisable to use 12 contacts. The barrel can be made of other different configurations and can accommodate diiferent numbers of the elongated, axially extending, generally parallel rods.
Another important feature of this invention, in addition to this contactor rod assembly intermediate the center and periphery of the barrel, is the central cylindrical tube assembly 110 which controls the location of the plastic parts between the barrel axis and its periphery.
The central positioner tube assembly 110 is formed of a pair of hollow, semi-cylindrical elements 112 and 114 (FIG. 7) of plastic, non-conducting and non-reactive ma terials such as a rigid vinyl polymer, or a polypropylene. These have their ends overlapping the two hubs 64 and 66, and secured thereto on a plurality of bosses 114 (FIGS. 3 and 4) by screws. The sleeves are also secured together in their central portions by a plurality of intermediate plastic discs 116, using screws 118 (FIGS. 4 and 6). The hollow interior of this tube includes drains to the outside, such drains being formed by a great number of peripheral openings 120 in the tube, and by slight spacing 122 between the two sections 112 and 114. Consequently, the plating solution is free to move into and out of this tube assembly as necessary, while the articles to be plated cannot pass.
This coaxial elongated spacer in the center of the barrel keeps the plastic articles being plated pressed together toward the periphery so that much better electrical contact is maintained between the parts. The tube can vary in diameter according to the size of the plating barrel, it having been found that a 3-inch diameter tube performs excellent results in a 10-inch diameter plating barrel, as does a 6-inch diameter tube for a 16-inch barrel. The exact size has been found to be dependent upon article size, configuration, and density, as Well as the type of plating, barrel configuration, barrel load, and others. For small loads of articles, it has been found that a large plastic cylinder should be used. The plastic tube maintains the parts out of the center of the barrel and forces them to the outside periphery where they are kept in contact with the novel cathode rods.
Still another function of the plastic cylinder is to distribute the load of parts more uniformly throughout the length of the plating barrel for a more uniform plate coverage. In other words, it prevents bunching and/or free floating. Its main function, however is to locate the plastic parts in the vicinity of the contactor rods, which in turn are located between the center of the periphery of the barrel.
The combination of these components has been found to be extremely effective for rapid, efiicient, high quality plating of buoyant or near buoyant non-conductive parts. The particular configuration of this tube need not be cylindrical since other shapes such as triangular, square, hexagonal and so forth may be employed. A cylindrical spacer has been found to be the most economical and performs in excellent fashion.
In some instances, it may be desirable to transfer articles to a second barrel of similar construction after the parts have been completely covered with sufficient plate to give good electrical conductivity in the first barrel. The second barrel, for example, will have the contactor rods placed closer to or adjacent the plastic cylinder. In the second barrel, the rods build up with plate at a slower rate because they are more deeply covered with the mass of rolling parts, with more plate, therefore, being applied to the parts.
Extensive experimentation has shown the advisability of utilizing radial baflle plates or paddles when the cathodic contactor rods are placed close to the central spacer. This is especially helpful in larger diameter plating barrels. For example in a 16-inch diameter barrel, paddles 17 (FIGS. 3 and 13) extending the length of barrel and projecting radially inwardly to a width of 1 inch to 2 /2 inches exert a definite beneficial influence on the plating action. These baffles are of plastic material integral with or secured to the inner periphery of the barrel. Optimum location for the bafile is intermediate the edges of each flat peripheral polygonal segment, with the radially outwardly extending contactor rods being staggered therewith to project toward the apices of the polygonal sides (FIG. 13). These paddles cause generally sinuous movement of the objects, and further tend to hold the objects beneath the plating solution if the barrel is only partially submerged. They provide better agitation and mixing of both the parts and the solution during the plating operation. This results in more uniform plate distribution from part to part in the load, and faster plating rate due to the fact that the increased agitation allows the use of higher current densities without burning (formation of rough or treed deposits at high current density). The so-called paddles are especially advantageous when plating with large diameter barrels with the cathode contacts close to the plastic center to reduce the rate of build-up of the contacts.
It should be noted that the invention will work without these paddles. It has certain definite advantages under certain conditions. When the cathode contacts are placed closer to the periphery of the barrel, they provide agitation to both the solution and the parts. As explained before, as soon as parts have been electroplated with sulficient copper or other electroplate in order to give them good conductivity, it is advisable to transfer them to a plating barrel with the contacts close to the plastic center in order to prevent the rapid build-up of the cathode contacts.
Operation To prepare the plastic parts for plating, they must first be coated with a thin electrically conductive coating. This can be done by coating with a metal using one of several methods, including vacuum metallizing, cathodesputtering, silvering reduction methods, metal spraying, metal cladding, or chemical reduction methods known as as electroless plating. The articles are of course deglazed by blasting, tumbling, or chemical etching. The article surfaces are cleaned. They are sensitized chemically as with stannous chloride, and then activated by -a chemical reagent such as palladium chloride. A metal, such as copper or nickel, is then applied by a chemical reduction method. The coating is generally in the range of 0.00001 to .00005 inch thick before the electroplating occurs.
The coated parts are then placed in the novel barrel by removing one of the hexagonal sides, for example, which is secured in place by any suitable clamping means such as those conventionally used to hold this side to the periphery of the barrel. Since this forms no part of the invention, is conventional and well known, it is not specifically shown. The barrel is immersed in the plating solution. It is rotated at a rate of rotation of from 1 to revolutions per minute, depending upon the type of plating, size of parts and so forth. Electrical current is applied through cables 54 and 56 to sleeves 60 and 62 hubs 64 and 66. It therefore, is conducted out radial tube holders 90 to contactor rods 94.
At first the parts will usually float to the top of the barrel, if they have a specific gravity less than the specific gravity of the plating solution. The contactor cathode rods, therefore, make contact mostly in the upper part of the submerged barrel. As the plate builds up to increase the specific gravity to an amount where the parts tend to sink, the contactors make optimum contact mostly in the bottom portions of the barrel. The barrel is normally filled about full with the parts, but it cannot be loaded so completely that the parts cannot tumble. The rotation of the contactor rods with the barrel causes the parts to tumble even though they are lightweight and tend to float apart from each other and to remain in the top of the barrel. It will be understood that the main plating problem occurs initially when the parts are of substantially lighter specific gravity. These parts tumble over and around the elongated contactor rods and remain in intimate contact with one another as forced radially out to the vicinity of the rods by the central spacer tube. It has been found with extensive experimentation and use of the invention that the adjustable contactor rods and the center plastic spacing tube enable plastic parts to be plated with an excellent quality uniform plate with surprisingly few rejects.
Since the rods used as the contactor material are quite flexible and bendable, it has been found advisable in many instances to tie these together in some manner to prevent them from being deformed excessively during operation. Also, it has been found that if the means for tying these together is electrically conductive, the plating can often be improved further. Therefore, referring to FIG. 11, the elongated contactor rods 94 are tied together by wrapping around them a plurality of adjacent, binding, metallic holding elements 130. These may be formed simply of a wire wrapped around the periphery at spaced axial locations. Alternatively, the elements may be of a heavier construction. The quality of products achieved with this apparatus in FIG. 11 is very similar to that of the apparatus in the first figures, but the contactor bars are more sturdy. Also, contact area and action are increased by the peripherally wrapped wires.
8 Modification It has been found that some types of articles can be successfully plated utilizing the less preferred modified structure shown in FIGS. 8, 9 and 10. In this structure, the same central tube assembly is employed in barrel assembly 14, and the same end structures are employed, except that electrical conduction means extends clear through the barrel on its axis. The two separate cables 54 and 56 are sweated into the two ends of a continuous sleeve 60a. The surrounding hub support 64a also extends the length of the barrel over the sleeve. It includes a plurality of radially extending supports 90a over its length. Various type legs can be used with this type of hub. Specifically, instead of the U-shaped, axially elongated contact bars, a plurality of radially and peripheral extending contact elements, each in one transverse plane, are employed, such as those illustrated in FIGS. 9 and 10. These are mounted in the plurality of support sleeves 90a. The contactor elements include peripherally extending segments generally arcuate in configuration (FIG. 10) and have radial leg segments which fit in sleeves la. The elements cooperatively form a circular portion in one plane normal to the axis of rotation. Alternatively, each singular element can form a continuous circular portion 152 (FIG. 9). Attached radial legs 154 inserted in sleeves 90a form electrical contact and physical mounting. These elements therefore, have a peripheral electrical contact area intermediate the central tube assembly 110, and the periphery of the barrel. This combination does not achieve optimum tumbling action as the previous forms of the invention do in FIGS. 1 through 6 and 11. Consequently, for some types of articles, this form is satisfactory, but the first forms of the invention are greatly preferred. In a few instances, it is even possible to employ simple radial spokes without the peripheral segments, i.e., spokes 154 without ring 152. However, the electrical contact as well as the physical tumbling characteristics are inferior. Consequently, this is employable in only select circumstances.
Modified hub assembly In FIG. 12 is disclosed an improved end hub assembly. This was devised to lengthen the life of the rotating barrel assembly by overcoming the potential galling problem of the hub on the sleeve over the cable in the previous forms of the invention. The general peripheral barrel structure is similar, including a perforated shell 222 and a pair of end plates 220. It is supported on a holding frame with suspension arms 224, and driven by pulleys 234.
The cable holder 230 is on the barrel axis, having a circular inner end 231 in opening 233 of the end plate 220. Locking plates 244 are inserted between arm 224 and pulley 234 to secure the assembly.
The hub 266 is not basically a sleeve, however, but rather a solid metal rod having its inner end inside the plastic barrel and its outer end protruding into an annular, coaxial passage 245 in cable holder 230. This passage has a narrow diameter neck slightly larger than the rod, and a larger diameter interior extending axially to plastic cap 25.2. The power inlet cable 256 extends into the cable holder behind the cap and is integral with a cylindrical metal bearing cap 259 having an annular sleeve portion extending axially toward the barrel and around the outer end of the rod to make electrical contact therewith.
Plastic cap 252, when attached, compresses conductive bearing cap 259 to cause its inner annular end to compress O-ring 2&8 against the shoulder of the constricted portion of passage 245. This, preferably coupled with a rubber gasket 271 around rod 266 and against the inner axial face of cable holder 23G, effectively seals off the sliding bearing surfaces from the barrel interior. Preferably a silicone grease is packed between rod 266 and bearing cap 259. Electrical conduction is therefore made from cable 256 to hearing cap 259, to rod 266, to radial sleeve 9 299, to cathode rods 294 for plating. The end discs 214 for spacer tube meansw210 fit around hub rod 266. The inner ends of hub rods 266 as well as sleeves 290 are coated with an insulating jacket 267.
In these last forms of the invention, the elements may be positively driven to rotate with the barrel, or may be free to rotate, or remain stationary, while the barrel rotates.
It is conceivable that those skilled in this field will see other advantages than those specifically recited herein. Also, various minor structural modifications could conceivably be made in the particular preferred form of the invention and in the less preferred forms of the invention to suit a particular type of barrel, type of plating, size or configuration of articles, size of batch to be plated, buoyancy of articles or other such factors, yet without departing from the inventive concept taught. Therefore, this invention is not to be limited to the specific preferred forms of the invention illustrated, but only by the scope of the claims attached hereto.
Iclaim:
1. An electroplating barrel assembly for non-conductive lightweight buoyant and near buoyant articles, comprising: a non-conductive barrel having a perforated shell and a pair of end walls; a pair of hubs in said end walls for rotatably mounting said barrel on a central axis, including means for receiving electrical conductor means therein to make contact therefrom; a plurality of metallic contactor elements along the length of said barrel, elec trically operably associated with said hubs, having the major active contact surface portions spaced radially intermediate said shell and said axis to create article tumbling electrical contact means; and an elongated, central, hollow, perforated, non-conductive spacer means between said ends, along said ax s, spaced radially in- Wardly of said major active surface portions of said elements, and defining an open space therein, preventing articles from moving to the radial center of the shell.
2. An electroplating barre. assembly for non-conductive lightweight buoyant and near buoyant articles, comprising: a non-conductive barrel having a perforated shell and a pair of end walls; a pair of non-conductive supports in said end walls for rotatably mounting said barrel on a central axis and including means for receiving electrical conductor means therein to make contact therefrom; metallic spider hub means around said conductor means and including radial support fingers; a plurality of metallic contactor elements along the length of said barrel, supported by said fingers, and electrically associated with said spider hub means, and having the major active contact surface portions spaced radially intermediate said shell and said axis to create article tumbling and electrical contact means; said spider hub means and conductor means being protected from chemical attack and electrical exposure; said contactor means comprising a plurality of circumferentially spaced metal rods extending axially of said barrel; said rods being generally U-shaped and having parallel opposite legs extending radially and being removably attached to sleeves on said hubs; an elongated non-conductive spacer means between said end walls along said axis, spaced radially inwardly of said major active contact surface portions of said elements, preventing articles from moving to the radial center of the shell; said spacer means comprising a hollow perforated tube defining an open space therein.
References Cited UNITED STATES PATENTS 1,509,534 9/1924 Todd 204213 2,673,076 3/1954 Colclesser 204213 3,183,177 5/1965 DeSante et a1. 204-213 FOREIGN PATENTS 2,159 1900 Great Britain.
JOHN H. MACK, Primary Examiner.
V. VAN SISE, Assistant Examiner.

Claims (1)

1. AN ELECTROPLATING BARREL ASSEMBLY FOR NON-CONDUCTIVE LIGHWEIGHT BUOYANT AND NEAR BUOYANT ARTICLES, COMPRISING: A NON-CONDUCTIVE BARREL HAVING A PERFORATED SHELL AND A PAIR OF END WALLS; A PAIR OF HUBS IN SAID END WALLS FOR ROTABLY MOUNTING SAID BARREL ON A CENTRAL AXIS, INCLUDING MEANS FOR RECEIVING ELECTRICAL CONDUCTOR MEANS THEREIN TO MAKE CONTACT THEREFROM; A PLURALITY OF METALLIC CONTACTOR ELEMENTS ALONG THE LENGTH OF SAID BARREL, ELECTRICALLY OPERABLY ASSOCIATED WITH SAID HUBS, HAVING THE MAJOR ACTIVE CONTACT SURFACE PORTIONS SPACED RADIALLY INTERMEDIATE SAID SHELL AND SAID AXIS TO CREATE ARTICLE TUMBLING ELECTRICAL CONTACT MEANS; AND AN ELONGATED, CENTRAL, HOLLOW, PERFORATED, NON-CONDUCTIVE SPACER MEANS BETWEEN SAID ENDS, ALONG SAID AXIS, SPACED RADIALLY INWARDLY OF SAID MAJOR ACTIVE SURFACE PORTIONS OF SAID ELEMENTS, AND DEFINING AN OPEN SPACE THEREIN, PREVENTING ARTICLES FROM MOVING TO THE RADIAL CENTER OF THE SHELL.
US351988A 1964-03-16 1964-03-16 Electroplating barrel for non-conductive buoyant and near-buoyant articles Expired - Lifetime US3330753A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US351988A US3330753A (en) 1964-03-16 1964-03-16 Electroplating barrel for non-conductive buoyant and near-buoyant articles

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US351988A US3330753A (en) 1964-03-16 1964-03-16 Electroplating barrel for non-conductive buoyant and near-buoyant articles

Publications (1)

Publication Number Publication Date
US3330753A true US3330753A (en) 1967-07-11

Family

ID=23383304

Family Applications (1)

Application Number Title Priority Date Filing Date
US351988A Expired - Lifetime US3330753A (en) 1964-03-16 1964-03-16 Electroplating barrel for non-conductive buoyant and near-buoyant articles

Country Status (1)

Country Link
US (1) US3330753A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3421993A (en) * 1965-06-24 1969-01-14 Anton Lazaro Electroplating barrel
US3974057A (en) * 1971-01-13 1976-08-10 Hans Henig Electro plating barrel
US4234404A (en) * 1979-04-11 1980-11-18 The Upjohn Company Horizontal electrophoresis or isoelectric focusing apparatus
US4317707A (en) * 1980-11-03 1982-03-02 Good David L Portable electrolysis unit for recovery of silver from photographic film
US4356075A (en) * 1981-06-29 1982-10-26 Case Engineering Consulting Company Rigid dangler assembly for electroplating barrels
US4680099A (en) * 1986-04-07 1987-07-14 Raymund Singleton Electroplating apparatus

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB190002159A (en) * 1900-02-01 1900-12-15 Elizabeth Morrison Improvements in Apparatus for Electro-plating Pins and other Small Objects
US1509534A (en) * 1923-06-26 1924-09-23 Hanson & Van Winkle Company Electroplating machine
US2673076A (en) * 1950-01-17 1954-03-23 Mercil Plating Equipment Compa Rotatable work holder for electroplating apparatus
US3183177A (en) * 1962-01-12 1965-05-11 Western Electric Co Electroplating barrel with current reversal means

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB190002159A (en) * 1900-02-01 1900-12-15 Elizabeth Morrison Improvements in Apparatus for Electro-plating Pins and other Small Objects
US1509534A (en) * 1923-06-26 1924-09-23 Hanson & Van Winkle Company Electroplating machine
US2673076A (en) * 1950-01-17 1954-03-23 Mercil Plating Equipment Compa Rotatable work holder for electroplating apparatus
US3183177A (en) * 1962-01-12 1965-05-11 Western Electric Co Electroplating barrel with current reversal means

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3421993A (en) * 1965-06-24 1969-01-14 Anton Lazaro Electroplating barrel
US3421992A (en) * 1965-06-24 1969-01-14 Anton Lazaro Electroplating barrel
US3974057A (en) * 1971-01-13 1976-08-10 Hans Henig Electro plating barrel
US4234404A (en) * 1979-04-11 1980-11-18 The Upjohn Company Horizontal electrophoresis or isoelectric focusing apparatus
US4317707A (en) * 1980-11-03 1982-03-02 Good David L Portable electrolysis unit for recovery of silver from photographic film
US4356075A (en) * 1981-06-29 1982-10-26 Case Engineering Consulting Company Rigid dangler assembly for electroplating barrels
US4680099A (en) * 1986-04-07 1987-07-14 Raymund Singleton Electroplating apparatus

Similar Documents

Publication Publication Date Title
US2495695A (en) Electroplating apparatus
US3300396A (en) Electroplating techniques and anode assemblies therefor
US3330753A (en) Electroplating barrel for non-conductive buoyant and near-buoyant articles
US2272609A (en) Copper coated cooking vessel
US3649490A (en) Method for timed electrolytic processing of masses of electrically conductive metal parts
CA2045078C (en) Hydrodynamically modulated hull cell
US3394063A (en) Electrolytic stripping of copper, zinc and tin based coatings from a ferrous base using an alkaline pyrophosphate electrolyte
US3379631A (en) Electrolytic apparatus
US3272729A (en) Method of electropolishing small metal objects
US3420766A (en) Automatic electroplating and washing apparatus
US3421992A (en) Electroplating barrel
JPH0124237B2 (en)
US3974057A (en) Electro plating barrel
US3376210A (en) Process and apparatus for electroplating annular bodies
US3729389A (en) Method of electroplating discrete conductive regions
US3161578A (en) Apparatus for carrying out electrolytic treatments on the entire surface
JPS59190383A (en) Method and device for high speed partial plating
US5348637A (en) Surface treatment apparatus for workpieces
US3337442A (en) Rotatable barrel for use in electroplating of a plurality of articles
US3340174A (en) Apparatus for electroplating
US4680099A (en) Electroplating apparatus
KR20030083018A (en) Phosphate film processing method and phosphate film processing device
US4189356A (en) Method for plating copper on steel rods
US2425919A (en) Method of making metal molding material
SU537634A3 (en) Electroplating Device