US3330646A - Method for producing molybdenum from molybdenite - Google Patents
Method for producing molybdenum from molybdenite Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/30—Obtaining chromium, molybdenum or tungsten
- C22B34/34—Obtaining molybdenum
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/90—Carbides
- C01B32/914—Carbides of single elements
- C01B32/949—Tungsten or molybdenum carbides
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Definitions
- the present invention relates to electrolytic preparation of molybdenum carbide and recovery of metallic molybdenum from the carbide.
- the process of the invention is particularly adapted to recovery of molybdenum metal from molybdenite concentrates.
- Extra molybdenite M08 occurs in admixture with large percentages of other minerals such as quartz, feldspar, etc.
- Molybdenite concentrates containing about 90 to 95 percent molybdenite are readily obtained by conventional concentration procedures such as flotation or gravity separation.
- Recovery of molybdenum metal is conventionally accomplished by roasting the molybdenite concentrate to technical molybdic oxide. This oxide is either sublimed and collected as chemically pure M00 or dissolved in dilute ammonia, filtered and evaporated until ammonium molybdate crystallizes.
- Ammonium molybdate or molybdic oxide is reduced to molybdenum powder by hydrogen reduction at 1,050 to 1,100 C.
- the molybdenum powder is then deoxidized, either by sintering in a hydrogen atmosphere at 2,200 to 2,300 C. or by adding carbon and arc-melting in vacuum.
- Process control is quite involved due to the complex chemistry of molybdenum and the high-purity feed required for metal powder production. These methods are costly and, in addition, involve excessive fume losses of molybdenum and considerable technical difliculties to produce a metal powder of uniform quality and purity.
- the salt bath (electrolyte) that has been found to give optimum results comprises a mixture of KCl, KF and anhydrous sodium metasilicate.
- the KCl and KP salts form a relatively low melting bath and are excellent conductors of electricity, but they do not dissolve appreciable amounts of molybdenite.
- the function of sodium metasilicate is to dissolve sufficient M08 and form complex ions with the dissolved molybdenum for the satisfactory electrolytic production of Mo C.
- the carbon content of Mo C is derived, directly or indirectly, from the carbon anode used in the electrolysis. This carbon anode is preferably a graphite crucible that serves as both anode and container for the fused bath. Potassium halide salts are preferred over corresponding sodium halides because high-purity Mo C is produced under parallel electrolytic conditions.
- the initial proportions of sodium metasilicate to molybdenite should be regulated between about 1.3 to l and about 4 to 1 by weight, respectively. If insufficient solvent salt is employed, the molybdenite is not completely solubilized and resulting electrodeposit consists of synthetic MoS With increasing quantities of solvent salt in the electrolyte, the electrodeposits gradate from M08 to M0 to M0 0 to a condition where the electrodeposit dissolves as rapidly as it is formed. Electrolytic conditions for producing pure M0 0 are, however, much easier to regulate and reproduce than those for producing pure Mo metal.
- the proportions of KCl-KF-Na SiO mixture to molybdenite may vary widely but tests have established that the molybdenite content'of the total mixture should be maintained between about 2 and about 20 percent by weight for optimum results.
- the apparatus employed in the electrodeposition is conventional and is described in the prior art such as the above cited Bureau of Mines publication and patents to Zadra et al.
- the temperature of the molten salts should be maintained between about 900 and about 1,100" C.
- the preferred current density range is from about 10 to about amperes per square decimeter of cathode.
- the anode current density is not critical it is usually maintained at about one-third to one-fifth of that of the cathode.
- any suitable conductive material may be employed in the cathode; however, graphite and tungsten rods have I been found most suitable.
- the anode must be made of graphite or carbon as it supplies the carbon content of the electrowon Mo C.
- the second processing step of the invention is the decarbonization of Mo C to produce pure molybdenum metal by intense heating as exemplified by sintering or are melting under an inert atmosphere. It has been found that a mixture of Mo C and M00 when heated, produces Mo metal, CO, and C0
- the over-all chemical equation may be represented as:
- Optimum temperature for converting the Mo C-MoO mixture to pure Mo has been found to be about 1500 C. However, this temperature may vary somewhat according to reaction conditions and product requirements, e.g., the reaction goes to about 99 percent completion during prolonged heating (2 hours) at 1300 C. Tests indicate the amount of M00 to be mixed with Mo C in the arc melting process (see example) is preferably'about percent of theoretical as indicated in the above chemical equation. When sintering is employed, the amount of M00 is preferably about 110 percent of theoretical. Sintering at a temperature of about 1500" C.
- Example The electrolyte consisted of 32.5 percent KCl, 30.0 percent KF, 30.0 percent Na SiO and contained 7.5 percent MoS (as molybdenite concentrate) by weight.
- the mixed charge was heated externally in a graphite crucible, which served as an anode during electroylsis, to l,000 C. to solubilize the molybdenite feed material.
- the cathode was a graphite rod suspended in the center of the molten bath. Electrolysis was conducted without a protective inert atmosphere at 1,000 C. and at a cathode current density of 60 amps/dm. The molybdenum content was deposited on the cathode as firmly adhering dendritic crystals of Mo C.
- the electrodeposit was withdrawn from the molten bath, air cooled, and then submerged in water to dissolve the adhering electrolyte and free the Mo C crystals. Average yield was 30 grams Mo C per 100 ampere hours of electrolysis.
- the carbide crystals were substantially free from impurities such as aluminum, silicon, copper, and sulfur, commonly present in molybdenite concentrates.
- the M 0 crystals were ground to minus 100- mesh to liberate any entrapped graphite or electrolyte present.
- the ground product was then digested in dilute hydrochloric acid, to dissolve any water insoluble contaminants that might be present, washed and dried.
- the Mo C was mixed with about 125 percent of theoretical chemically pure M00 needed to decarbonize the carbide. This mixture was arc-melted in an inert atmosphere (helium )to produce molybdenum metal ingots of better than 99.8 percent purity.
- Molybdenum ingot had a hardness reading of 186 Viekers Hardness Number.
- molybdenum compounds such as M00 (NI-I MoO Na MoO etc., may be used as feed materials, although generally without the obvious economic advantage to be achieved in the use of molybdenite.
- Alkali halides other than KCl and KF may also be used, alone or in combination. These compounds may comprise any of the alkali or alkaline earth metals, i.e., Li, Na, K, Rb, Cs, Ca, Ba or Sr, as the metallic component while the halide may be of any of the halides, i.e., fluoride, chloride bromide or iodide.
- alkaline solubilizing reagents may also be used in place of the sodium silicate to facilitate dissolution of the molybdenum compounds in the molten electrolyte, e.g., alkali metal hydroxides, oxides, peroxides, carbonates, bicarbonates and borates.
- metal oxides that will form a metal that volatilizes at temperatures below about 2200" C. may be used in .place of the M00 for decarbonization of Mo C, e.g.,
- M00 MgO and ZnO. M00 is added in the same oxide equivalent as M00 as required by the carbon present and the reaction proceeds similarly. M00 is, however, generally preferred as it is less expensive. Decarbonization is also applicable to mixtures of molybdenum carbides and molybdenum metal.
- Mo C produced according to the process of the invention may be utilized for de-oxidation of hydrogen-reduced molybdenum powder.
- This powder is produced in conventional metallurgical processes by reaction of M00 with hydrogen at elevated temperature.
- the product is a molybdenum powder usually having an oxygen content of from about 0.05 to about 0.3 percent.
- This hydrogen-reduced powder is conventionally deoxidized by sintering or arc-melting a charge containing 0.7 to 1.0 gram of carbon black per pounds of the hydrogen reduced molybdenum powder. It has now been found that the molybdenum carbide produced by the process of the invention, when substituted for the carbon black of the conventional process in chemically equivalent amounts, is very effective for rte-oxidizing hydrogen-reduced molybdenum powders to yield pure molybdenum metal.
- a process for electrolytic preparation of molybdenum carbide comprising fusing in a container a mixture of (l) a molybdenum-containing material, (2) a low melting bath from the group consisting of alkali metal halide, alkaline earth metal halide and mixtures thereof, and (3) an inorganic alkali metal compound capable of solubilizing the molybdenum compound in the bath and electrolyzing the fused mixture using a cathode and a carbon anode, to deposit molybdenum carbide at the cathode.
- cathode current density during electrolysis is from about 10 to about 100 amperes per square decimeter of cathode.
- a process for electrowinning molybdenum from molybdenite concentrates comprising fusing in a graphite container 2. mixture of molybdenite concentrate, KCl, KF and sodium metasilicate, electrolyzing the fused mixture, with the graphite container as anode, to deposit molybdenum carbide at the cathode, removing and purifying the deposited molybdenum carbide and subsequently reacting the molybdenum carbide, at high temperature in an inert atmosphere, with M00 to decarbonize the carbide and form high purity molybdenum metal, said high temperature being at least suificient to cause sintering of said molybdenum metal.
- a process for producing molybdenum metal comprising reacting molybdenum carbide with molybdenum oxide at a high temperature in an inert atmosphere, said high temperature being at least sufficient to cause sintering of said molybdenum metal.
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Description
United States Patent 3 330,646 METHOD FOR PRdDUCING MOLYBDENUM FROM MOLYBDENITE (M05 Harold J. Heinen, Curtis L. Barber, and Don H. Baker,
J12, Reno, Nev., assignors to the United States of America as represented by the Secretary of the Interior N0 Drawing. Filed Feb. 3, 1964, Ser. No. 342,315
19 Claims. (CI. 75-84) The invention herein described and claimed may be manufactured and used by or for the Government of the United States of America for governmental purposes without the payment of royalties thereon or therefor.
The present invention relates to electrolytic preparation of molybdenum carbide and recovery of metallic molybdenum from the carbide.
The process of the invention is particularly adapted to recovery of molybdenum metal from molybdenite concentrates. Indigenous molybdenite (M08 occurs in admixture with large percentages of other minerals such as quartz, feldspar, etc. Molybdenite concentrates containing about 90 to 95 percent molybdenite are readily obtained by conventional concentration procedures such as flotation or gravity separation. Recovery of molybdenum metal is conventionally accomplished by roasting the molybdenite concentrate to technical molybdic oxide. This oxide is either sublimed and collected as chemically pure M00 or dissolved in dilute ammonia, filtered and evaporated until ammonium molybdate crystallizes. Ammonium molybdate or molybdic oxide is reduced to molybdenum powder by hydrogen reduction at 1,050 to 1,100 C. The molybdenum powder is then deoxidized, either by sintering in a hydrogen atmosphere at 2,200 to 2,300 C. or by adding carbon and arc-melting in vacuum. Process control is quite involved due to the complex chemistry of molybdenum and the high-purity feed required for metal powder production. These methods are costly and, in addition, involve excessive fume losses of molybdenum and considerable technical difliculties to produce a metal powder of uniform quality and purity.
Recovery of molybdenum metal from the oxide has also been accomplished by electrowinning from a molten bath containing dissolved molybdenum oxide. This procedure is described in Bureau of Mines Report of Investigations 5795, Electrowinning Molybdenum: Preliminary Studies by H. J. Heinen and J. B. Zadra and US. Patents 3,071,523 and 3,075,900 to Zadra et al. These prior art processes have the disadvantage that molybdic oxide, usually chemically pure, is required as feed material.
It is therefore an object of the present invention to provide a simple and efficient process for recovery of high-purity molybdenum metal from molybdenite concentrates.
It is a further object of the invention to provide a method for electrolytic preparation of molybdenum carbide from molybdenite concentrates.
It has now been found that these objectives may be accomplished by electrolytic deposition of Mo C from a fused salt bath comprising an alkali halide and an alkali silicate. Molybdenum metal is then recovered by decarbonization of the carbide by reaction with a metal oxide having a relatively low volatilization temperature.
The salt bath (electrolyte) that has been found to give optimum results comprises a mixture of KCl, KF and anhydrous sodium metasilicate. The KCl and KP salts form a relatively low melting bath and are excellent conductors of electricity, but they do not dissolve appreciable amounts of molybdenite. The function of sodium metasilicate is to dissolve sufficient M08 and form complex ions with the dissolved molybdenum for the satisfactory electrolytic production of Mo C. The carbon content of Mo C is derived, directly or indirectly, from the carbon anode used in the electrolysis. This carbon anode is preferably a graphite crucible that serves as both anode and container for the fused bath. Potassium halide salts are preferred over corresponding sodium halides because high-purity Mo C is produced under parallel electrolytic conditions.
The initial proportions of sodium metasilicate to molybdenite should be regulated between about 1.3 to l and about 4 to 1 by weight, respectively. If insufficient solvent salt is employed, the molybdenite is not completely solubilized and resulting electrodeposit consists of synthetic MoS With increasing quantities of solvent salt in the electrolyte, the electrodeposits gradate from M08 to M0 to M0 0 to a condition where the electrodeposit dissolves as rapidly as it is formed. Electrolytic conditions for producing pure M0 0 are, however, much easier to regulate and reproduce than those for producing pure Mo metal. The proportions of KCl-KF-Na SiO mixture to molybdenite may vary widely but tests have established that the molybdenite content'of the total mixture should be maintained between about 2 and about 20 percent by weight for optimum results.
The apparatus employed in the electrodeposition is conventional and is described in the prior art such as the above cited Bureau of Mines publication and patents to Zadra et al.
Dun'ng electrolysis the temperature of the molten salts should be maintained between about 900 and about 1,100" C. The preferred current density range is from about 10 to about amperes per square decimeter of cathode. Although the anode current density is not critical it is usually maintained at about one-third to one-fifth of that of the cathode.
Any suitable conductive material may be employed in the cathode; however, graphite and tungsten rods have I been found most suitable. However, the anode must be made of graphite or carbon as it supplies the carbon content of the electrowon Mo C.
The second processing step of the invention is the decarbonization of Mo C to produce pure molybdenum metal by intense heating as exemplified by sintering or are melting under an inert atmosphere. It has been found that a mixture of Mo C and M00 when heated, produces Mo metal, CO, and C0 The over-all chemical equation may be represented as:
It is preferred to use chemically pure molybdic oxide rather than other volatile metal oxides to circumvent the addition of impurities to the reduced molybdenum. Any excess CoC added is sublimed during heating. Optimum temperature for converting the Mo C-MoO mixture to pure Mo has been found to be about 1500 C. However, this temperature may vary somewhat according to reaction conditions and product requirements, e.g., the reaction goes to about 99 percent completion during prolonged heating (2 hours) at 1300 C. Tests indicate the amount of M00 to be mixed with Mo C in the arc melting process (see example) is preferably'about percent of theoretical as indicated in the above chemical equation. When sintering is employed, the amount of M00 is preferably about 110 percent of theoretical. Sintering at a temperature of about 1500" C. for about 10 minutes under inert atmosphere has been found to produce a molybdenum powder (rather than ingot as produced in arc melting) containing less than p.p.m. of carbon and 450 p.p.m. of oxygen. An arc-cast ingot made from this powder contained less than 50 p.p.m. carbon and 100 p.p.m. oxygen and had a hardness of 172 V.H.N.
a The following example will serve to more specifically illustrate the invention.
Example The electrolyte consisted of 32.5 percent KCl, 30.0 percent KF, 30.0 percent Na SiO and contained 7.5 percent MoS (as molybdenite concentrate) by weight. The mixed charge was heated externally in a graphite crucible, which served as an anode during electroylsis, to l,000 C. to solubilize the molybdenite feed material. The cathode was a graphite rod suspended in the center of the molten bath. Electrolysis was conducted without a protective inert atmosphere at 1,000 C. and at a cathode current density of 60 amps/dm. The molybdenum content was deposited on the cathode as firmly adhering dendritic crystals of Mo C. The electrodeposit was withdrawn from the molten bath, air cooled, and then submerged in water to dissolve the adhering electrolyte and free the Mo C crystals. Average yield was 30 grams Mo C per 100 ampere hours of electrolysis. The carbide crystals were substantially free from impurities such as aluminum, silicon, copper, and sulfur, commonly present in molybdenite concentrates. The M 0 crystals were ground to minus 100- mesh to liberate any entrapped graphite or electrolyte present. The ground product was then digested in dilute hydrochloric acid, to dissolve any water insoluble contaminants that might be present, washed and dried. The Mo C was mixed with about 125 percent of theoretical chemically pure M00 needed to decarbonize the carbide. This mixture was arc-melted in an inert atmosphere (helium )to produce molybdenum metal ingots of better than 99.8 percent purity.
Several laboratory-scale electrolytic runs were made under the operating conditions stated above and demonstrated that reproducible results can readily be obtained by the process of the invention. Typical analyses of the electrowon Mo C and Mo ingots obtained from molybdenite feed are shown in the following table.
1 Molybdenum ingot had a hardness reading of 186 Viekers Hardness Number.
2 Not determined.
The high degree of purity of metallic molybdenum obtained from the process of the invention is apparent from the data given in the table.
Although the above example utilizes reactants that have generally been found to give optimum results, the invention is not limited to these materials. Other molybdenum compounds such as M00 (NI-I MoO Na MoO etc., may be used as feed materials, although generally without the obvious economic advantage to be achieved in the use of molybdenite.
Alkali halides other than KCl and KF may also be used, alone or in combination. These compounds may comprise any of the alkali or alkaline earth metals, i.e., Li, Na, K, Rb, Cs, Ca, Ba or Sr, as the metallic component while the halide may be of any of the halides, i.e., fluoride, chloride bromide or iodide.
Other alkaline solubilizing reagents may also be used in place of the sodium silicate to facilitate dissolution of the molybdenum compounds in the molten electrolyte, e.g., alkali metal hydroxides, oxides, peroxides, carbonates, bicarbonates and borates.
Other metal oxides that will form a metal that volatilizes at temperatures below about 2200" C. may be used in .place of the M00 for decarbonization of Mo C, e.g.,
6. M00 MgO and ZnO. M00 is added in the same oxide equivalent as M00 as required by the carbon present and the reaction proceeds similarly. M00 is, however, generally preferred as it is less expensive. Decarbonization is also applicable to mixtures of molybdenum carbides and molybdenum metal.
When alkali halides or silicates, as well as Mo compounds and decarbonizing compounds, other than those of the example are used the optimum proportions of the reactants may vary from those disclosed above. Optimum proportions may, however, be readily determined empirically by those skilled in the art.
It has been further found that the Mo C produced according to the process of the invention may be utilized for de-oxidation of hydrogen-reduced molybdenum powder. This powder is produced in conventional metallurgical processes by reaction of M00 with hydrogen at elevated temperature. The product is a molybdenum powder usually having an oxygen content of from about 0.05 to about 0.3 percent.
This hydrogen-reduced powder is conventionally deoxidized by sintering or arc-melting a charge containing 0.7 to 1.0 gram of carbon black per pounds of the hydrogen reduced molybdenum powder. It has now been found that the molybdenum carbide produced by the process of the invention, when substituted for the carbon black of the conventional process in chemically equivalent amounts, is very effective for rte-oxidizing hydrogen-reduced molybdenum powders to yield pure molybdenum metal.
What is claimed is:
1. A process for electrolytic preparation of molybdenum carbide comprising fusing in a container a mixture of (l) a molybdenum-containing material, (2) a low melting bath from the group consisting of alkali metal halide, alkaline earth metal halide and mixtures thereof, and (3) an inorganic alkali metal compound capable of solubilizing the molybdenum compound in the bath and electrolyzing the fused mixture using a cathode and a carbon anode, to deposit molybdenum carbide at the cathode.
2. The process of claim 1 in which the container is graphite and is the anode.
3. The process of claim 1 in which the molybdenum material is a molybdenite concentrate.
4. The process of claim 3 in which the molybdenite content of the mixture is from about 2 to about 20 percent by weight.
5. The process of claim 1 in which the low melting bath is a mixture of KCl and KP.
6. The process of claim 1 in which the solubilizing alkali metal compound is sodium metasilicate.
7. The process of claim 6 in which the ratio by weight of sodum metasilicate to molybdenite is from about 1.3 to 1 to about 4 to 1.
8. The process of claim 1 in which the temperature of the fused mixture is maintained at about 900 to about 1100 C. during electrolysis.
9. The process of claim 1 in which the cathode current density during electrolysis is from about 10 to about 100 amperes per square decimeter of cathode.
10. The process of claim 1 in which the product molybdenum carbide is further reacted at high temperature in an inert atmosphere with an oxide of a metal which volatilizes at temperatures below about 2200 C. to decarbonize the Mo C and form high purity molybdenum metal, said high temperature being at least suflicient to cause sintering of said molybdenum metal.
11. The process of claim 10 in which the high temperature is about 1500" C.
12. The process of claim 10 in which the high temperature is supplied by an electric arc, whereby molten molybdenum is produced.
13. The process of claim 10 in which the high temperature causes sintering of the molybdenum metal.
14. The process of claim 10 in which the decarbonizing metal oxide is molybdic oxide.
15. The process of claim 10 in which the decarbonizing metal oxide is M00 16. A process for electrowinning molybdenum from molybdenite concentrates comprising fusing in a graphite container 2. mixture of molybdenite concentrate, KCl, KF and sodium metasilicate, electrolyzing the fused mixture, with the graphite container as anode, to deposit molybdenum carbide at the cathode, removing and purifying the deposited molybdenum carbide and subsequently reacting the molybdenum carbide, at high temperature in an inert atmosphere, with M00 to decarbonize the carbide and form high purity molybdenum metal, said high temperature being at least suificient to cause sintering of said molybdenum metal.
17. A process for producing molybdenum metal comprising reacting molybdenum carbide with molybdenum oxide at a high temperature in an inert atmosphere, said high temperature being at least sufficient to cause sintering of said molybdenum metal.
18. The process of claim 17 in which the high temperature is about 1500 C.
19. The process of claim 17 in which the high temperature causes sintering of the mixture.
References Cited BENJAMIN R. PADGETT, Primary Examiner.
CARL D. QUARFORTH, Examiner.
M. J. SCOLNICK. Assistant Examiner.
Claims (2)
1. A PROCESS FOR ELECTROLYTIC PREPARATION OF MOLYBDENUM CARBIDE COMPRISING FUSING IN A CONTAINER A MIXTURE OF (1) A MOLYBDENUM-CONTAINING MATERIAL, (2) A LOW MELTING BATH FROM THE GROUP CONSISTING OF ALKALI METAL HALIDE, ALKALINE EARTH METAL HALIDE AND MIXTURES THEREOF, AND (3) AN INORGANIC ALKALI METAL COMPOUND CAPABLE OF SOLUBILIZING THE MOLYBDENUM COMPOUND IN THE BATH AND ELECTROLYZING THE FUSED MIXTURE USING A CATHODE AND A CARBON ANODE, TO DEPOSIT MOLYBDENUM CARBIDE AT THE CATHODE.
17. A PROCESS FOR PRODUCING MOLYBDENUM METAL COMPRISING REACTING MOLYBDENUM CARBIDE WITH MOLYBDENUM OXIDE AT A HIGH TEMPERATURE IN AN INERT ATMOSPHERE, SAID HIGH TEMPERATURE BEING AT LEAST SUFFICIENT TO CAUSE SINTERING OF SAID MOLYBDENUM METAL.
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Cited By (6)
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US3375180A (en) * | 1965-04-02 | 1968-03-26 | Interior Usa | Electrochemical preparation of metal sulfides |
US3406056A (en) * | 1964-11-17 | 1968-10-15 | Heurtey Sa | Methods of and devices for purifying high melting-point metals |
US3966459A (en) * | 1974-09-24 | 1976-06-29 | Amax Inc. | Process for thermal dissociation of molybdenum disulfide |
US5882620A (en) * | 1995-06-07 | 1999-03-16 | International Carbitech Industries, Inc. | Pyrometallurgical process for forming tungsten carbide |
US20040052672A1 (en) * | 2000-11-15 | 2004-03-18 | Fray Derek John | Metal and alloy powders and powder fabrication |
RU2811044C1 (en) * | 2023-05-23 | 2024-01-10 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Кабардино-Балкарский государственный университет им. Х.М. Бербекова" (КБГУ) | Method for producing silicon carbide powder |
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Cited By (6)
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US3406056A (en) * | 1964-11-17 | 1968-10-15 | Heurtey Sa | Methods of and devices for purifying high melting-point metals |
US3375180A (en) * | 1965-04-02 | 1968-03-26 | Interior Usa | Electrochemical preparation of metal sulfides |
US3966459A (en) * | 1974-09-24 | 1976-06-29 | Amax Inc. | Process for thermal dissociation of molybdenum disulfide |
US5882620A (en) * | 1995-06-07 | 1999-03-16 | International Carbitech Industries, Inc. | Pyrometallurgical process for forming tungsten carbide |
US20040052672A1 (en) * | 2000-11-15 | 2004-03-18 | Fray Derek John | Metal and alloy powders and powder fabrication |
RU2811044C1 (en) * | 2023-05-23 | 2024-01-10 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Кабардино-Балкарский государственный университет им. Х.М. Бербекова" (КБГУ) | Method for producing silicon carbide powder |
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