US3295601A - Transition zone formation in oil production - Google Patents

Transition zone formation in oil production Download PDF

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US3295601A
US3295601A US353471A US35347164A US3295601A US 3295601 A US3295601 A US 3295601A US 353471 A US353471 A US 353471A US 35347164 A US35347164 A US 35347164A US 3295601 A US3295601 A US 3295601A
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stratum
fluid
well
oil
injection
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Santourian Melcon
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Phillips Petroleum Co
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    • E—FIXED CONSTRUCTIONS
    • E21—EARTH OR ROCK DRILLING; MINING
    • E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
    • E21B43/164—Injecting CO2 or carbonated water
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P90/00—Enabling technologies with a potential contribution to greenhouse gas [GHG] emissions mitigation
    • Y02P90/70—Combining sequestration of CO2 and exploitation of hydrocarbons by injecting CO2 or carbonated water in oil wells

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  • This invention relates to a method of establishing a transition zone downhole around an injection 'well in a miscible fluid drive process in recovering oilfrom an oil-bearing stratum and utilizing this method in such a fluid drive process to produce oil.
  • the premix is formed above ground and injected into thestratum thru an injection well to displace oil radially outwardly from the injection well and a driving fluid is then injected to drive the transition phase thru the stratum toward the production wells thereby producing oil in the production wells.
  • This invention is concerned with a unique method of forming a better transition zone in the stratum around an injection well and to the use of this zone in displacing oil from the stratum by fluid drive.
  • an object of the invention to provide an improved method of forming a miscible phase transition zone in an oil bearing stratum around an injection well. Another object is to provide an improved transition zone which varies gradually in viscosity from the forward area adjacent the in-place oil to the area adjacent the injection well and in which the viscosity gradually varies substantially from that of the in-place oil to that of the miscible fluid utilized in forming the transition zone with the oil. A further object is to provide an improved fluid drive utilizing a more eflicient transition Zone.
  • a broad aspect of the invention comprises injecting into an oil-bearing stratum through an injection well therein a fluid miscible with the oil in the stratum and containing a substantial concentration of CO so as to build up a substantial pressure in an annulus of the stratum around the well. of at least 500 p.s.i.g. and up to about 4000 p.s.i.g., thereafter releasing or reducing the fluid pressure in the well so that the pressure in the stratum producw oil containing dissolved injected fluid by solution gas drive; when the 'well pressure is returned substantiaily to normal, the produced fluid is forced into the stratum through the well and additional miscible fluid is injected so as to again build up the pressure in the stratum to the aforementioned range.
  • the purpose of the formation and driving of the transition zone through an oil-bearing stratum is to avoid or decrease substantially the eifects of viscous fingering which is a common basic problem in the various flooding techniques utilized in secondary recovery methods including gas injection, water flOoding, LPG flooding, etc. It has been found that a transition zone, properly formed in a stratum around an injection well greatly reduces viscousfingering whenthe transition-zone is driven through the stratum in advance of a driving fluid.
  • the invention utilizes a slug of gas consisting of CO and hydrocarbon gases, preferably of 2-4 carbon atoms, or nitrogen, air, H 8, flue gases, and similar gases as the gaseous mixture is injected into the well to establish the transition zone. It is preferred that the gas mixture have a composition of 50 percent CO and a substantial concentration of C -C hydrocarbon gases therein such as 10-50 percent. (Percents are by volume.) Such gas compositions have a very high solubility in the reservoir oil.
  • the volume of the gas mixture injected to form the transition zone is at least 0.05 pore volume and up to 1.0 pore volume of the stratum to be produced. it is preferred to inject a gas mixture having a volume in the range of 0.1 to 0.5 pore volume. While the invention is particularly advantageous in reservoirs containing viscous fluids of low API gravity, it is also applicable to and advantageous in reservoirs containing less viscous hydrocarbons such as those of an API gravity above 35.
  • the reservoir pressure is raised sufficiently (to the range of 500-4000 p.s.i.g.) so that the injection well is readily converted to a producing well by termination of the injection procedure and allowing the reservoir pressure to be rapidly lowered to normal pressure, such as around p.s.i.g.
  • the driving force during this producton is the solution gas drive established by the injection procedure. This process, which may be repeated as many times as desired, establishes an in situ graded viscosity zone in the reservoir from the oil viscosity to that of the gas mixture viscosity.
  • the gas and produced fluid As the gas and produced fluid is injected back into the same well, it provides partial miscibility, unless the injection pressure for a given gas mixture and reservoir oil is suflicicnt for total miscibility.
  • the invention is applicable to virgin reservoirs as Well as to partially depleted reservoirs.
  • the graded viscosity zone when driven through the stratum prevents or greatly reduces viscous fingering with improved sweep efliciency, and the CO promotes higher displacement efliciency.
  • the same is driven through the stratum or reservoir.
  • the last slug of gas or fluid injected into the stratum is followed by the principal displacing fluid which may be natural gas, air, water,
  • an oil-bearing stratum is penetrated by an injection well 12 and offset production wells 14.
  • the Wells are provided with casings 16 and 18, respectively, which extend thru stratum 10 and are perforated for ingress and egress of fluids.
  • the production wells 14 are provided with tubing strings 20 and injection well 12 contains a tubing string 22 which extends approximately to the bottom of the stratum.
  • the transition zone established around well 12 is designated 24.
  • Storage tank 30 is connected with casing 16 through line 32 and with tubing 22 through line 34 for injection of fluid under the impetus of pump 36.
  • Line 38 connects tubing string 22 with storage tank 30 for flow of produced fluid when producing through the tubing.
  • Line 40 connects the well annulus through casing 16 with line 38 for flow of produced fluids when producing through the annulus.
  • Pump 42 is positioned in line 38 to assist in flow of produced fluids to the storage tank when this is necessary.
  • Line 44 connects with line 32 for the injection of the principal driving fluid after the transition zone has been established.
  • the selected gas mixture is injected either through line 32 or through line 34.
  • the source of this gaseous mixture may be storage tank 30 or a source (not shown) to which line 44 is connected.
  • the gas slug is injected through lines 44 and 34 into tubing string 22 from which the gaseous mixture passes to the bottom of the well and into the stratum into zone 24. Injection is continued until the desired pressure is reached which is preferably close to 4000 p.s.i.g. During this injection the production wells are preferably shut-in so as to facilitate the building up of pressure.
  • the drive of the transition zone through the stratum to the production well(s) may be effected; however, it is more effective to repeat the production and reinjection steps at least once and, preferably, several times in order to establish a sizable transition zone with a good miscibility gradient and then follow the last injection of the produced fluids with the principal driving fluid or with a slug of the gaseous mixture followed by the principal driving fluid.
  • Well 12 represents either a central well in a 5, 7, or 9-spot pattern or one well in a line of wells in a parallel line drive process, while wells 14 represent either the ring wells or production wells in two lines of wells parallel with the line of injection wells represented by well 12.
  • a method of establishing a transition zone downhole around an injection well for use in a miscible fluid drive process in recovering oil from an oil-bearing stratum prior to injection of a driving fluid and forcing same thru said stratum from said injection well to at least one offset production well comprises the steps of:
  • step (4) repeating step (4), thereby establishing a substantial transition zone around said injection well wherein the oil in the resulting solution is of decreasing concentration from the innermost boundary thereof to the well and the injected fluid is of increasing concentration in the same direction.
  • volume of the injected fluid in step (1) is in the range of 0.01 to 1.0 pore volume of the stratum produced.
  • step (1) is a mixture of CO and normally gaseous hydrocarbons of 2 to 4 carbon atoms per molecule and the volurne thereof is in the range of 0.01 to 1.0 pore volume of the stratum produced.
  • a process for establishing a transition zone in an annular section of oil-bearing stratum around an injection well therein for use in a fluid drive production process which comprises the steps of:
  • step (3) thereafter, injecting the solution produced in the preceding step into said stratum and continuing the injection of the gaseous mixture of step (1) so as to again build up the pressure in said well to at least 500 p.s.i.g.;
  • Name-mammal 9 The process of claim 8 wherein the concentration of 1 CO in said gaseous mixture is at least 50 percent by volume and the balance is said hydrocarbons.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Geology (AREA)
  • Mining & Mineral Resources (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Description

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IPYvlZ Jan. 3, 1967 M. SANTOURIAN TRANSITION ZONE FORMATION IN OIL PRODUCTION Filed March 20, 1964 INVENTOR.
MELCON SANTOURIA N A TTORNEYS United States Patent G 3,295,601 TRANSITION ZONE FORMATION IN OIL PRODUCTION Melcon Santourian, Bartlesville, Okla, assignor to Phillips Petroleum Company, a corporation of Delaware Filed Mar. 20, 1964, Ser. No. 353,471
9 Claims. (Cl. 166-9) This invention relates to a method of establishing a transition zone downhole around an injection 'well in a miscible fluid drive process in recovering oilfrom an oil-bearing stratum and utilizing this method in such a fluid drive process to produce oil.
The need for a transition zone in a miscible fluid flood or drive of a miscible fluid transition zone thru an oilbearing stratum to produce oil thru one or more production wells is clearly taught-in US. Patent 2,867,277 to C. F. Weinaug et ad. The prior art method utilizing this technique involves mixing some of the oil from the stratum to be produced with a less viscous, miscible fluid which forms a mixture of intermediate viscosity relative to the petroleum and to the miscible displacement fluid. The premix is formed above ground and injected into thestratum thru an injection well to displace oil radially outwardly from the injection well and a driving fluid is then injected to drive the transition phase thru the stratum toward the production wells thereby producing oil in the production wells.
This invention is concerned with a unique method of forming a better transition zone in the stratum around an injection well and to the use of this zone in displacing oil from the stratum by fluid drive.
Accordingly, it is an object of the invention to provide an improved method of forming a miscible phase transition zone in an oil bearing stratum around an injection well. Another object is to provide an improved transition zone which varies gradually in viscosity from the forward area adjacent the in-place oil to the area adjacent the injection well and in which the viscosity gradually varies substantially from that of the in-place oil to that of the miscible fluid utilized in forming the transition zone with the oil. A further object is to provide an improved fluid drive utilizing a more eflicient transition Zone. Other objects of the invention will become apparent upon consideration of the accompanying disclosure.
A broad aspect of the invention comprises injecting into an oil-bearing stratum through an injection well therein a fluid miscible with the oil in the stratum and containing a substantial concentration of CO so as to build up a substantial pressure in an annulus of the stratum around the well. of at least 500 p.s.i.g. and up to about 4000 p.s.i.g., thereafter releasing or reducing the fluid pressure in the well so that the pressure in the stratum producw oil containing dissolved injected fluid by solution gas drive; when the 'well pressure is returned substantiaily to normal, the produced fluid is forced into the stratum through the well and additional miscible fluid is injected so as to again build up the pressure in the stratum to the aforementioned range. The foregoing procedure is repeated as many times as required to build up an annular transition zone around the well extending a substantial distance radially into the stratum, the concentration of oil in this transition zone being highest at the most remote fringe of the transition zone and low- Patented Jan. 3, 1967 est at the well bore, while the concentration of the injected miscible fluid is highest at the well bore and lowest at the most remote fringe of the zone. After the fore going procedure has built up the desired transition zone, a driving fluid is injected through the injection well to drive the fluid transition zone toward one or more offset production wells, thereby producing oil from the stratum through these production wells.
The purpose of the formation and driving of the transition zone through an oil-bearing stratum is to avoid or decrease substantially the eifects of viscous fingering which is a common basic problem in the various flooding techniques utilized in secondary recovery methods including gas injection, water flOoding, LPG flooding, etc. It has been found that a transition zone, properly formed in a stratum around an injection well greatly reduces viscousfingering whenthe transition-zone is driven through the stratum in advance of a driving fluid.
The invention. utilizes a slug of gas consisting of CO and hydrocarbon gases, preferably of 2-4 carbon atoms, or nitrogen, air, H 8, flue gases, and similar gases as the gaseous mixture is injected into the well to establish the transition zone. It is preferred that the gas mixture have a composition of 50 percent CO and a substantial concentration of C -C hydrocarbon gases therein such as 10-50 percent. (Percents are by volume.) Such gas compositions have a very high solubility in the reservoir oil. The volume of the gas mixture injected to form the transition zone is at least 0.05 pore volume and up to 1.0 pore volume of the stratum to be produced. it is preferred to inject a gas mixture having a volume in the range of 0.1 to 0.5 pore volume. While the invention is particularly advantageous in reservoirs containing viscous fluids of low API gravity, it is also applicable to and advantageous in reservoirs containing less viscous hydrocarbons such as those of an API gravity above 35.
As a result of injecting the slug of gas selected for the operation, the reservoir pressure is raised sufficiently (to the range of 500-4000 p.s.i.g.) so that the injection well is readily converted to a producing well by termination of the injection procedure and allowing the reservoir pressure to be rapidly lowered to normal pressure, such as around p.s.i.g. The driving force during this producton is the solution gas drive established by the injection procedure. This process, which may be repeated as many times as desired, establishes an in situ graded viscosity zone in the reservoir from the oil viscosity to that of the gas mixture viscosity. As the gas and produced fluid is injected back into the same well, it provides partial miscibility, unless the injection pressure for a given gas mixture and reservoir oil is suflicicnt for total miscibility. The invention is applicable to virgin reservoirs as Well as to partially depleted reservoirs. The graded viscosity zone. when driven through the stratum prevents or greatly reduces viscous fingering with improved sweep efliciency, and the CO promotes higher displacement efliciency.
After establishing the transition zone, the same is driven through the stratum or reservoir. The last slug of gas or fluid injected into the stratum is followed by the principal displacing fluid which may be natural gas, air, water,
, steam, flue gases, or combinations thereof.
A more complete understanding of the invention may be had by reference to the accompanying schematic draw- 3 ing which is an elevation of a partial section of an arrangement of wells penetrating an oil-bearing stratum for use in effecting the invention.
Referring to the drawing, an oil-bearing stratum is penetrated by an injection well 12 and offset production wells 14. The Wells are provided with casings 16 and 18, respectively, which extend thru stratum 10 and are perforated for ingress and egress of fluids. The production wells 14 are provided with tubing strings 20 and injection well 12 contains a tubing string 22 which extends approximately to the bottom of the stratum. The transition zone established around well 12 is designated 24.
Storage tank 30 is connected with casing 16 through line 32 and with tubing 22 through line 34 for injection of fluid under the impetus of pump 36. Line 38 connects tubing string 22 with storage tank 30 for flow of produced fluid when producing through the tubing. Line 40 connects the well annulus through casing 16 with line 38 for flow of produced fluids when producing through the annulus. Pump 42 is positioned in line 38 to assist in flow of produced fluids to the storage tank when this is necessary. Line 44 connects with line 32 for the injection of the principal driving fluid after the transition zone has been established.
To start the operation, the selected gas mixture is injected either through line 32 or through line 34. The source of this gaseous mixture may be storage tank 30 or a source (not shown) to which line 44 is connected. For the purposes of illustration, it will be assumed that the gas slug is injected through lines 44 and 34 into tubing string 22 from which the gaseous mixture passes to the bottom of the well and into the stratum into zone 24. Injection is continued until the desired pressure is reached which is preferably close to 4000 p.s.i.g. During this injection the production wells are preferably shut-in so as to facilitate the building up of pressure. After the maximum desired pressure has been built up in the well adjacent the stratum, it is desirable in some applications to maintain the pressure at the maximum level for an extended period of time such as one day to a week or longer to provide time for the injected gas to go into solution and migrate deep into the formation. However, in some applications this is not necessary and immediate release of pressure on the injection well effects the desired production by solution gas drive. During the production phase of the transition zone build-up, the produced fluids are passed into storage tank 30 and this produced fluid is then reinjected into the well either through tubing 22 or through the surrounding annulus. After the produced fluid has been reinjected, additional miscible gaseous mixture from line 44 is injected until the pressure is again built up to the desired maximum. At this point, the drive of the transition zone through the stratum to the production well(s) may be effected; however, it is more effective to repeat the production and reinjection steps at least once and, preferably, several times in order to establish a sizable transition zone with a good miscibility gradient and then follow the last injection of the produced fluids with the principal driving fluid or with a slug of the gaseous mixture followed by the principal driving fluid. 1
Upon injecting the principal driving fluid through line 44, wells 14 are opened to production and as the transition zone is forced toward these wells, oil is produced therein and recovered through tubing 20.
Well 12 represents either a central well in a 5, 7, or 9-spot pattern or one well in a line of wells in a parallel line drive process, while wells 14 represent either the ring wells or production wells in two lines of wells parallel with the line of injection wells represented by well 12.
Certain modifications of the invention will become apparent to those skilled in the art and the illustrative details disclosed are not to be construed as imposing unnecessary limitations on the invention.
I claim:
1. A method of establishing a transition zone downhole around an injection well for use in a miscible fluid drive process in recovering oil from an oil-bearing stratum prior to injection of a driving fluid and forcing same thru said stratum from said injection well to at least one offset production well, which method comprises the steps of:
(1) injecting into said stratum thru said injection well,
a fluid miscible with the oil in said stratum and containing a substantial concentration of C0 (2) continuing the injection of said fluid into said stratum until the well pressure reaches at least 500 p.s.1.g.;
(3) thereafter, releasing the fluid pressure in said well so that fluid pressure built up in said stratum and solution gas drive causes fluid flow into said injection well thereby producing fluid containing a substantial concentration of stratum oil;
(4) forcing the produced fluid of the preceding step into said stratum to again build up a pressure therein of at least 500 p.s.i.g.;
(5) repeating step (3); and
(6) repeating step (4), thereby establishing a substantial transition zone around said injection well wherein the oil in the resulting solution is of decreasing concentration from the innermost boundary thereof to the well and the injected fluid is of increasing concentration in the same direction.
2. The process of claim 1 wherein the injected fluid of step (1) is at least 50 volume percent C0 3. The process of claim 2 wherein the injected fluid contains a concentration of normally gaseous hydrocarbons in the range of 10 to 50 volume percent.
4. A process for producing oil from an oil-bearing stratum penetrated by an injection well and at least one offset production well which comprises the steps of:
(l) establishing a transition zone around said injection well by the method of claim 1 while maintaining said at least one production well shut-in;
(2) thereafter, opening said at least one production well to flow and driving the oil solution in said transi tion zone outwardly from said injection well toward said at least one production well so as to produce oil therein by injecting a driving fluid into said injection well; and
(3) recovering produced oil'from said at least one production well.
5. The process of claim 4 wherein the volume of the injected fluid in step (1) is in the range of 0.01 to 1.0 pore volume of the stratum produced.
6. The process of claim 4 wherein the fluid injected in step (1) is a mixture of CO and normally gaseous hydrocarbons of 2 to 4 carbon atoms per molecule and the volurne thereof is in the range of 0.01 to 1.0 pore volume of the stratum produced.
7. A process for establishing a transition zone in an annular section of oil-bearing stratum around an injection well therein for use in a fluid drive production process which comprises the steps of:
(1) injecting 'a gaseous mixture of CO and C to C hydrocarbons into said stratum thru said injection Well until the pressure therein is raised to at least 500 p.s.i.g., thereby forming a solution of said mixture in the oil in said annulus;
(2) thereafter, discontinuing the injection of said mixture and decreasing the pressure in said well so as to allow substantial production of said solution in said well by solution gas drive;
(3) thereafter, injecting the solution produced in the preceding step into said stratum and continuing the injection of the gaseous mixture of step (1) so as to again build up the pressure in said well to at least 500 p.s.i.g.;
Name-mammal 9. The process of claim 8 wherein the concentration of 1 CO in said gaseous mixture is at least 50 percent by volume and the balance is said hydrocarbons.
References Cited by the Examiner UNITED STATES PATENTS Whorton et a1 166--7 Weinang et al. 166-9 Martin et a1. 166-9 Archer 166-9 Santourian 1669 CHARLES E. OCONNELL, Primary Examiner.
S. J. NOVOSAD, Assistant Examiner.

Claims (1)

1. A METHOD OF ESTABLISHING A TRANSITION ZONE DOWNHOLE AROUND AN INJECTION WELL FOR USE IN A MISCIBLE FLUID DRIVE PROCESS IN RECOVERING OIL FROM AN OIL-BEARING STRATUM PRIOR TO INJECTION OF A DRIVING FLUID AND FORCING SAME THRU SAID STRATUM FROM SAID INJECTION WELL TO AT LEAST ONE OFFSET PRODUCTION WELL, WHICH METHOD COMPRISES THE STEPS OF: (1) INJECTING INTO SAID STRATUM THRU SAID INJECTION WELL, A FLUID MISCIBLE WITH THE OIL IN SAID STRATUM AND CONTAINING A SUBSTANTIAL CONCENTRATION OF CO2; (2) CONTINUING THE INJECTION OF SAID FLUID INTO SAID STRATUM UNTIL THE WELL PRESSURE REACHES AT LEAST 500 P.S.I.G.; (3) THEREAFTER, RELEASING THE FLUID PRESSURE IN SAID WELL SO THAT FLUID PRESSURE BUILT UP IN SAID STRATUM AND SOLUTION GAS DRIVE CAUSES FLUID FLOW INTO SAID INJEC-
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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4224992A (en) * 1979-04-30 1980-09-30 The United States Of America As Represented By The United States Department Of Energy Method for enhanced oil recovery
US4343362A (en) * 1980-01-29 1982-08-10 Institutul De Cercetari Si Proiectari Pentru Petrol Si Gaze Recovery of oil from an oil reservoir by miscible displacement
US4385662A (en) * 1981-10-05 1983-05-31 Mobil Oil Corporation Method of cyclic solvent flooding to recover viscous oils
US4510997A (en) * 1981-10-05 1985-04-16 Mobil Oil Corporation Solvent flooding to recover viscous oils
US4531586A (en) * 1981-10-01 1985-07-30 Mobil Oil Corporation Method of solvent stimulation of heavy oil reservoirs
US4589486A (en) * 1984-05-01 1986-05-20 Texaco Inc. Carbon dioxide flooding with a premixed transition zone of carbon dioxide and crude oil components
US4628999A (en) * 1983-12-21 1986-12-16 Laszlo Kiss Process employing CO2 /CH gas mixtures for secondary exploitation of oil reservoirs
US4733724A (en) * 1986-12-30 1988-03-29 Texaco Inc. Viscous oil recovery method
US4736792A (en) * 1986-12-30 1988-04-12 Texaco Inc. Viscous oil recovery method
US5725054A (en) * 1995-08-22 1998-03-10 Board Of Supervisors Of Louisiana State University And Agricultural & Mechanical College Enhancement of residual oil recovery using a mixture of nitrogen or methane diluted with carbon dioxide in a single-well injection process
US6443229B1 (en) 2000-03-23 2002-09-03 Daniel S. Kulka Method and system for extraction of liquid hydraulics from subterranean wells
EP1258595A2 (en) 2001-05-16 2002-11-20 The Boc Group, Inc. Enhanced oil recovery method using CO2 injection

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2623596A (en) * 1950-05-16 1952-12-30 Atlantic Refining Co Method for producing oil by means of carbon dioxide
US2867277A (en) * 1956-02-14 1959-01-06 Univ Kansas Res Foundation Production of hydrocarbon material
US2875832A (en) * 1952-10-23 1959-03-03 Oil Recovery Corp Gaseous hydrocarbon and carbon dioxide solutions in hydrocarbons
US3120262A (en) * 1962-11-13 1964-02-04 Pan American Petroleum Corp Waterflood method
US3126951A (en) * 1964-03-31 Santourian

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3126951A (en) * 1964-03-31 Santourian
US2623596A (en) * 1950-05-16 1952-12-30 Atlantic Refining Co Method for producing oil by means of carbon dioxide
US2875832A (en) * 1952-10-23 1959-03-03 Oil Recovery Corp Gaseous hydrocarbon and carbon dioxide solutions in hydrocarbons
US2867277A (en) * 1956-02-14 1959-01-06 Univ Kansas Res Foundation Production of hydrocarbon material
US3120262A (en) * 1962-11-13 1964-02-04 Pan American Petroleum Corp Waterflood method

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4224992A (en) * 1979-04-30 1980-09-30 The United States Of America As Represented By The United States Department Of Energy Method for enhanced oil recovery
US4343362A (en) * 1980-01-29 1982-08-10 Institutul De Cercetari Si Proiectari Pentru Petrol Si Gaze Recovery of oil from an oil reservoir by miscible displacement
US4531586A (en) * 1981-10-01 1985-07-30 Mobil Oil Corporation Method of solvent stimulation of heavy oil reservoirs
US4385662A (en) * 1981-10-05 1983-05-31 Mobil Oil Corporation Method of cyclic solvent flooding to recover viscous oils
US4510997A (en) * 1981-10-05 1985-04-16 Mobil Oil Corporation Solvent flooding to recover viscous oils
US4628999A (en) * 1983-12-21 1986-12-16 Laszlo Kiss Process employing CO2 /CH gas mixtures for secondary exploitation of oil reservoirs
US4589486A (en) * 1984-05-01 1986-05-20 Texaco Inc. Carbon dioxide flooding with a premixed transition zone of carbon dioxide and crude oil components
US4733724A (en) * 1986-12-30 1988-03-29 Texaco Inc. Viscous oil recovery method
US4736792A (en) * 1986-12-30 1988-04-12 Texaco Inc. Viscous oil recovery method
US5725054A (en) * 1995-08-22 1998-03-10 Board Of Supervisors Of Louisiana State University And Agricultural & Mechanical College Enhancement of residual oil recovery using a mixture of nitrogen or methane diluted with carbon dioxide in a single-well injection process
US6443229B1 (en) 2000-03-23 2002-09-03 Daniel S. Kulka Method and system for extraction of liquid hydraulics from subterranean wells
EP1258595A2 (en) 2001-05-16 2002-11-20 The Boc Group, Inc. Enhanced oil recovery method using CO2 injection
EP1258595A3 (en) * 2001-05-16 2004-03-03 The Boc Group, Inc. Enhanced oil recovery method using CO2 injection

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