US3292701A - Method for consolidating incompetent subsurface formations - Google Patents
Method for consolidating incompetent subsurface formations Download PDFInfo
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- US3292701A US3292701A US322856A US32285663A US3292701A US 3292701 A US3292701 A US 3292701A US 322856 A US322856 A US 322856A US 32285663 A US32285663 A US 32285663A US 3292701 A US3292701 A US 3292701A
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Images
Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/02—Subsoil filtering
- E21B43/025—Consolidation of loose sand or the like round the wells without excessively decreasing the permeability thereof
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B33/00—Sealing or packing boreholes or wells
- E21B33/10—Sealing or packing boreholes or wells in the borehole
- E21B33/13—Methods or devices for cementing, for plugging holes, crevices or the like
- E21B33/138—Plastering the borehole wall; Injecting into the formation
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/24—Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/25—Methods for stimulating production
- E21B43/26—Methods for stimulating production by forming crevices or fractures
- E21B43/2605—Methods for stimulating production by forming crevices or fractures using gas or liquefied gas
Definitions
- This invention relates to a method of treating incompetent oilor gas-bearing subterranean formations. It is particularly concerned with a method of bonding particles of such formations into a strong permeable mass through which passages of high uid ow capacity extend.
- incompetent formations are used to designate any formation in which excessive quantities of sand particles move into a well during production of fluids through the well, and includes formations ranging from those in which the sand particles are substantially entirely uncemented to substantially rigid formations in which the particles while cemented one to another do not have adequate strength to withstand the erosive forces that occur during production of fluids from the formation into the well.
- Sand particles carried by the uids into the :borehole of the Well from such formations may plug the Well or production tubing and prevent production of oil from the well.
- Another technique that is employed is to pack fine gravel around a liner to produce a filter bed with small Openings through which the sand particles cannot move.
- the gravel packing technique has the advantage of providing some support to the unconsolidated formation, but suffers the same disadvantage as the unconsolidated formation that the sand particles are not bonded together and may move to plug passages through which oil flows into the well.
- the particles of the 4formation or in a gravel pack be treated by displacing a resin-forming liquid into the gravel pack to coat the particles, and thereafter setting the resin-forming liquid such as by condensation or polymerization to bond the particles into a unitary mass. Care must -be taken to insure preservation of the permeability of the formation after the resin treatment.
- a suitable resin which can be made to set at conditions existing in the pay zone to form a resin of adequate strength and insolubility in formation fluids to produce a bond which will hold the particles together for long periods.
- Another method that has been employed to restrict the production of sand from an incompetent formation is to heat the sand, by passing a hot gas through it, to temperatures at which oil in the formation is coked and bonds the particles together.
- the incompetent formation may not have adequate permeability to permit production of fluids at economical rates, and the deposition of coke in the formation usually further restricts permeability.
- Fracturing the portion of the formation bonded -by the coke to increase the capacity of the formation to carry fluids into the well is hazardous in that it may destroy all of the benefits of sand consolidation gained from the coking operation by opening channels extending from the well to the unconsolidated area beyond the coke.
- This invention relates to a method of consolidating an incompetent subterranean oil-bearing formation penetrated by a well and providing passages of high flow capacity through the formation by injecting a gas into the formation at a rate high enough to create a fracture in the formation and, while holding the fracture open -by continued injection of the gas, controllingV the temperature of the injected gas to coke oil present in the formation to bond particles of the formation together.
- an oxygencontaining gas such as air
- is injected into the formation at a rate higher than fluids can be displaced from the formation adjacent the lborehole of a well thereby fracturingV the formation to carry the injected air from the Well.
- the temperature of the injected oxygen-containing gas is gradually increased at a carefully controlled rate to a maximum temperature of 350 to 600 F. to cause conversion to coke of oil in the formation.
- the deposition of coke in the formation to -bond the particles together can also be accomplished by the injection of inert gases such as flue gases, at a temperature in the range of 500 to 1000 F. and at a rate adequate to create a fracture and hold the fracture open.
- the single figure of the drawing is a diagrammatic View, partially in vertical section, of a well penetrating an incompetent formation which has been treated by the method of this invention.
- a well indicated generally by reference numeral 10 penetrating an incompetent formation 12 between a cap rock 14 and base rock 16.
- Well 10 is illustrated with casing 18 extending from the surface through the incompetent formation 12 into the base rock 16.
- casing 18 is cemented in place in the borehole completely to the surface by any conventional cementing procedure.
- the incompetent formation 12 can be any formation that will benefit from an increase in the strength of bonding of the particles comprising the formation.
- the process of this invention can be used on relatively hard, substantially self-supporting formations, but little is to be gained unless the formation 12 has insufficient strength to prevent movement of particles of the formation into the well as uids are produced through the well.
- the in- 3 competent formation 12 also may be substantially uncemented, and resemble quicksand.
- the upper end of the casing 18 is closed by a suitable cap 20 through which a fuel line 22 extends to supply fuel to a burner 24.
- An inlet line 26 opens into casing 18 above the surface 28 of the ground to supply air for the coking operation.
- Fuel line 22 and line 26 are connected with suitable sources of fuel and air, respectively. The fuel and air sources are not shown in the drawing.
- a ring is cut from casing 18 at the desired location in an interval of incompetent formation 12 to form an opening 30 through the casing.
- a notch is cut through opening 30 and the surrounding cement sheath 32 to provide access of air which is to be injected at a later stage of this process, into the incompetentformation 12.
- a single circumferential opening 30 of the type illustrated in the drawing is preferred because it insures flow of air to the desired location in the formation at closely controlled conditions which are substantially uniform in those areas of the formation treated.
- this invention can be used with the single opening 30 replaced by a plurality of perforations through the casing 18.
- the invention is illustrated in a well in which casing is set through the incompetent formation, the invention is not limited to that type of well completion and may be used in a well which is completed with an open hole through the incompetent oil-bearing formation 12 if the incompetent formation has adequate strength to prevent collapse of the formation during the drilling and consolidation process. Because of the very large area exposed when the well is completed as an open hole, high compressor capacities would be required during the air injection steps to insure treatment of the entire area of formation 12 exposed to the borehole of the well in accordance with'this invention.
- the static pressure in the formation near the top of the exposed interval is substantially less than near the bottom and may cause a fracture to be created near the top of the exposed interval with the result that very little, -if any, of the injected gas enters the lower portion of the exposed interval. For this reason the process is limited to use in open hole where the exposed interval is less than one hundred feet, and preferably less than fty feet.
- a suitable fuel such as natural gas or LPG is displaced through fuel line 22 into burner 24 where the fuel is ignited.
- the relative ratesof displacement of the fuel and air into the well are adjusted lto provide an oxygencontaining gas having a temperature Within the desired range, as hereinafter described.
- an electric heater can be substituted for the burner 24 to heat the oxygen-containing gas to the desired temperature. Coking of oil in the formation is not sensitive to the concentration of oxygen in the injected gas when the oxygen concentration is in the range from the concentration in air down to about one percent of the injected gas.
- a preferred method of controlling the temperature is to inject air at a rate adequate to fracture the formation and then inject fuel, ⁇
- the injected gas can be substantially undiluted air.
- the air is injected from the well into the formation at a high rate which will create a fracture 34 in the formation. Whether the rate of injection of the air is adequate to create the desired fracture can easily be ascertained by observation of the pressure within the Well as air injection continues. lf the formation surrounding the well is relatively open and will accept air from the formation, the rate of llow of air from the well into the formation is substantially directly proportional to the pressure within the well prior to the creation of any fracture. Once a fracture or open channel through the incompetent formain the rate of injection of the air into the well.
- the formation surrounding the Well will be plugged during the drilling or cementing operations and formation 12 will initially not readily acceptair.
- Continued injection of air through line 26 into the well causes the pressure within the well to increase until a pressure break, which indicates the creation of a fracture within the incompetent formation, occurs.
- the rate of displacement of air into the well can then be greatly increased without increasing the pressure in the Well to a pressure as high as the pressure prior to the pressure break.
- an oxygen-containing gas which may be air or air diluted with inert fluids, such as flue gas, is'displaced from the borehole of a well outwardly l through the incompetent formation containing oil.
- the temperature and pressure of the incompetent formation will also inuence the rate at which the temperature of the injected gas can be raised. Increases in temperature or increases in pressure of the incompetent formation increase the reaction rate and make necessary slower initial raising of the temperature of the injected oxygencontaining gas; however, the effect of pressure is relatively minor compared to the effect of temperature on the rate of reaction between the oil and the oxygen-containing gas. If the process is used in a deep formation initially at a high temperature, the formation can be cooled, for example, by injection of a cool inert gas or liquid, such as water, before displacing an oxygen-containing gas into the formation.
- a cool inert gas or liquid such as water
- the temperature of the oxygen-containing gas displaced into the formation is gradually increased at a substantially uniform rate in either a continuous or stepwise manner to a final temperature in the range of 350 to 500 F. adapted to produce a coke having adequate strength and a low solubility in oil bonding together the particles of the formation adjacent the faces of fracture 34, as illustrated by the shading in the drawing.
- Example 1 A thin-walled stainless steel tube, 5 inches in diameter and 5 feet long, was packed with sand and saturated with a crude oil having a gravity of 15.8 API horn the Fruitvale eld in California. A jacket around the tube provided an annular space surrounding the tube into which nitrogen was introduced to permit maintenance of the desired pressure within the tube without exposing the thin-walled tube to high pressure differences. Thermocouples were located at regular intervals through the packed sand. After air ow through the tube was established, the air was heated prior to displacement into the sand in accordance with the schedule set forth in Table I. The run was ended when temperatures within the 5-inch tube indicated that combustion was occurring. The air flux through the tubing was maintained at approximately 29,000 std. cu. ft./sq. ft./hr. and the outlet pressure of the tubing was maintained at approximately 750 lbs/sq. in.
- Example 2 A S-inch tube, 5 feet long, was packed with sand which was then saturated with a Fruitvale cnude oil having a gravity of 15.8 API. Thermocouples were positioned at regular ⁇ intervals along the length of the tubing and the tubing provided with a jacket suitably connected with a source of nitrogen .for maintaining the desired pressure on the outer surface of the tube. Air was passed through the tube to establish permeability and thereafter adjusted to maintain an air flux fof approximately 30,000 std. cu. ft./sq. ft./hr. The pressure at the youtlet of the tube was maintained at approximately 400 lbs/sq. in gauge. The temperature of the air introduced into the tube was gradually increased in accordance with the schedule set forth in Table I and the temperatures indicated 'by the thermocouples recorded. The results of the ⁇ tests of Examples 1 and 2 are presented in Table I.
- Example 2 VIt will be noted'from Table I that the rapid increase to an air inlet temperature of 395 F. in 2 hours and 40 minutes resulted in the initiation of combustion within the tubing, as indicated by a maximum temperature of 1700"V F. The maximum temperature was indicated at a thermocouple located lat a point about two-thirds of the distance to the outlet end of the tube. Similar tests have shown that if the injection of oxygen-containing gases is continued after ya temperature of the type indicated in lExample 1 occurs, reverse combustion is initiated and the peak temperature moves toward the inlet end of the tube.
- Example 2 When the temperature of the inlet air was increased more slowly, as in Example 2, in which approximately 8 hours were required to y:reach ⁇ a temperature of 390 F., combustion was not initiated .in ⁇ the tube and a strong funitary mass of sand particles bonded with coke was produced.
- the coke Ibond created by the hot air injection is physically strong and chemically stable.
- A-fter a period of production of oil, the Well in the Santiago field described in the specific embodiment was stimulated by the injection of air through the Well into the formation -to cause in-situ combustion of oil in the oildbearintg formation remote from the well.
- the deposition of coke to consolidate the formation is preferably accomplished by the injection of an oxygen-containing gas at a controlled, gradually increasing temperature because of the greater strength of the resultant consolidated formation, the coke can also be produced.by the injection of hot insert gases under a pressure and at a rate adequate to fracture the incompetent formation and maintain the fracture open during the deposition of the coke.
- inert gases is used to designate gases having an oxygen concentration below about one percent. Such gases can be obtained, for example, from the exhaust of gas or gasoline fueled internal combustion engines, or the burning of a suitable rocket fuel. Because of the low oxygen concentration in the inertgases, danger of burning coke deposited in the formation is avoided, and it is possible to proceed immediately with the injection of high temperature inert gases.
- the temperature of the inert gases may range from approximately 400 to l300 F. and is preferably in the range of 650 to 1000 F. Because of the high temperature of the inert gas, the injection lof the gas will create the desired coke bond in a short time compared with the time required for the coking operation with the oxygencontaining gas. For example, if the inert gases are injected at a .temperature of 1000 F., an adequate zone of 'consolidation islobtained in a period of eight hours.
- the rate at which the gas is injected into the formation to create the fracture and maintain the fracture open during the deposition of the coke will depend upon the permeability of the formation and the mobility of the oil in the formation. It is not possible to yspecify a particular ⁇ rate of gas injection that is applicable to all incompetent formations to be treated by this invention; however, ⁇ the i rate of gas injection must exceed the rate at which liquids in the formation can be made to ow away from the borehole through the formation when the borehole pressure is below the minimum pressure required to fracture the formation. whether or not the injection rate is adequate to create a fracture.
- a pressure break as the gas injection rate is increased or achange in the rate of increase of pressure with increased gas injection rate gives a quick .and accurate indication of the creation of a fracture. Maintenance of the gas injection rate to maintain the borehole pressure at or above the pressure at which the break occurs will insure holding the fracture open during the conversion of heavy oils to coke to consolidate the formation.
- a method of consolidating and increasing the ow capacity of an incompetent underground oil-bearing formation penetrated by a well comprising injecting a gasV down the well and into the formation at a rate creating Ia fracture in the formation, continuing the injection of the gas at a rate maintaining the fracture open, and while maintaining the fracture open by the injection of gas increasing the temperature of the injected gas to above 350 F. to deposit coke in the formation adjacent the fracture and bond the particels of the formation into a consolidated mass.
- a method of consolidating and increasing the fluid ⁇ iiow capacity of an incompetent underground oil-bearing formation penetrated by a well comprising injecting gas down the well and into the formation at a rate faster than formation fluids Will flow through the formation in the absence of a fracture whereby said formation is fractured, continuing the injection of the gas at a rate holding the fracture open, and while maintaining the fracture open by the injection of gas increasing the temperature of the gas to a final temperature above 350 F. at a rate to avoid ignition of the oil in the formation adjacent the fracture whereby coke is deposited in the formation-adjacent the fracture to consolidate the formation.
- a method of consolidating an incompetent underground oil-bearing formation penetrated by a well and increasing the iiow capacity of the formation into the well comprising injecting an oxygen-containing gas down the well and into the formation at a rate causing fracturing of the formation, continuing the injection of the oxygencontaining gas at a rate to hold Ithe fracture open, and increasing the temperature of said oxygen-containing gas to Iapproximately 250 F. in a period of at least about four hours, thereafter gradually increasing the temperature of ⁇ No difficulty is encountered in determining ⁇ the injected gas to a final temperature in the range of 350 to 500 F. adapted to convert hydrocarbons adjacent the fracture in the formation to coke to consolidate the formation while injecting the gas at a rate maintaining the fracture open.
- a method of consolidating an incompetent underground oil-bearing formation penetrated by the lborehole of a well and increasing the flow capacity of said formation into said borehole comprising displacing air down the well and into said formation at a rate creating a fracture in the formation, ⁇ continuing the injection of air at a rate to hold ⁇ the fracture open while burning fuel in the yborehole to raise the temperature of the gas injected into the formation, and periodically increasing the ratio of fuel to air to increase the temperature of the air and combustion products to ⁇ a nal temperature in the range of 350 to 500 F. whereby oil in the formation is coked to consolidate the formation, the rate of increasing the ratio of fuel to air being controlled to avoid ignition of oil adjacent the fracture.
- a method of consolidating an incompetent underground oil-bearing formation penetrated by the borehole of a well and increasing the flow capacity of the formation into said borehole comprising injecting a gas from the 'borehole of the well into the formation at a rate creating a fracture in the formation, continuing the injection of the gas at a rate maintaining the fracture open while heating said gas with an electric heater Suspended in the borehole of the well adjacent the formation, and gradually increasing the temperature of the gas injected into the formation to a nal temperature exceeding 350 F. to convert oil in the formation to coke and thereby consolidate said formation.
- a method of consolidating an incompetent under ground oil-bearing formation penetrated by the borehole of a well comprising injecting a gas down the well and into the formation at a rate creating a fracture in said formation, injecting an inert gas -at ya temperature in t-he range of 400 to 1300 F. down the well and into the formation at a rate maintaining the fracture open to convert oil in said formation vadjacent the fracture to coke to consolidate the formation.
- a method of consolidating an incompetent underground oil-bearing formation penetrated lby the bore- -hole of a Well comprising setting casing in said borehole through the incompetent formation, cutting a notch in the casing opposite the incompetent formation, injecting a gas down the well ⁇ and through the notch into the formation at a rate creating a fracture in the formation, continuing the injection of the gas at a Irate adapted to maintain the fracture open while increasing the temperature of the gas to at least 350 F. at a rate avoiding combustion of oil Iadjacent the fracture to convert oil in the formation adjacent the fracture to coke and thereby consolidate the formation.
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Description
Dec- 20, 1966 l R. J. GOODWIN ETAL 3,292,701
METHOD FOR CONSOLIDATING INCOMPETENT SUBSURFACE FORMATIONS Filed Nov. l2, 1963 BY MMM Arme/wey.
United States Patent O This invention relates to a method of treating incompetent oilor gas-bearing subterranean formations. It is particularly concerned with a method of bonding particles of such formations into a strong permeable mass through which passages of high uid ow capacity extend.
Many subsurface formations from which oil or lgas is produced are incompetent formations in which the in-dividual sand particles of the formation are weakly bonded to one another. The term incompetent formations is used to designate any formation in which excessive quantities of sand particles move into a well during production of fluids through the well, and includes formations ranging from those in which the sand particles are substantially entirely uncemented to substantially rigid formations in which the particles while cemented one to another do not have adequate strength to withstand the erosive forces that occur during production of fluids from the formation into the well. Sand particles carried by the uids into the :borehole of the Well from such formations may plug the Well or production tubing and prevent production of oil from the well. If the oilor gas-bearing formation is under a high pressure, the sand carried into the well frequently ows at a high velocity through borehole equipment and causes serious erosion of the equipment. Both plugging and erosion of the well equipment make expensive shutdown and workover of the well necessary to allow further production from the well.
Several methods have been used to combat the flow of sands into the well from unconsolidated formations. One of the techniques is to install a slotted liner in the borehole of the well through the pay zone. The slots of the liner are narrow enough to prevent flow of sand through them. Slotted liners frequently fail to accomplish the desired purpose because the movement of the sand around the liner may lblock the passages in the liner and prevent flow into the well.
Another technique that is employed is to pack fine gravel around a liner to produce a filter bed with small Openings through which the sand particles cannot move. The gravel packing technique has the advantage of providing some support to the unconsolidated formation, but suffers the same disadvantage as the unconsolidated formation that the sand particles are not bonded together and may move to plug passages through which oil flows into the well.
It has also been suggested that the particles of the 4formation or in a gravel pack be treated by displacing a resin-forming liquid into the gravel pack to coat the particles, and thereafter setting the resin-forming liquid such as by condensation or polymerization to bond the particles into a unitary mass. Care must -be taken to insure preservation of the permeability of the formation after the resin treatment. One of the difficulties with such a method is finding a suitable resin which can be made to set at conditions existing in the pay zone to form a resin of adequate strength and insolubility in formation fluids to produce a bond which will hold the particles together for long periods. One problem encountered in lforming a mass of adequate strength is in obtaining satisfactory adhesion of the resin to the par- 3,292,701 Patented Dec.' 20, 1966 ICC ticles which are ordinarily covered with oil and water, or both, when the resin-forming liquid is displaced through the gravel pack. Moreover, when oil in the formation is highly viscous, the resin-forming liquid may finger through the formation, rather than displace the oil, and wet only a small part of the formation. Because of these difficulties, and the relatively high cost of the large amount of resin required, the use of resins to consolidate formations has not been Widely adopted.
Another method that has been employed to restrict the production of sand from an incompetent formation is to heat the sand, by passing a hot gas through it, to temperatures at which oil in the formation is coked and bonds the particles together. The incompetent formation may not have adequate permeability to permit production of fluids at economical rates, and the deposition of coke in the formation usually further restricts permeability. Fracturing the portion of the formation bonded -by the coke to increase the capacity of the formation to carry fluids into the well is hazardous in that it may destroy all of the benefits of sand consolidation gained from the coking operation by opening channels extending from the well to the unconsolidated area beyond the coke.
This invention relates to a method of consolidating an incompetent subterranean oil-bearing formation penetrated by a well and providing passages of high flow capacity through the formation by injecting a gas into the formation at a rate high enough to create a fracture in the formation and, while holding the fracture open -by continued injection of the gas, controllingV the temperature of the injected gas to coke oil present in the formation to bond particles of the formation together. In a preferred embodiment of this invention, an oxygencontaining gas, such as air, is injected into the formation at a rate higher than fluids can be displaced from the formation adjacent the lborehole of a well thereby fracturingV the formation to carry the injected air from the Well. The temperature of the injected oxygen-containing gas is gradually increased at a carefully controlled rate to a maximum temperature of 350 to 600 F. to cause conversion to coke of oil in the formation. The deposition of coke in the formation to -bond the particles together can also be accomplished by the injection of inert gases such as flue gases, at a temperature in the range of 500 to 1000 F. and at a rate adequate to create a fracture and hold the fracture open.
The single figure of the drawing is a diagrammatic View, partially in vertical section, of a well penetrating an incompetent formation which has been treated by the method of this invention.
For convenience in description, this invention will be described with reference to the drawing for that embodiment in which the gas injected is air heated by admixture with hot combustion products. Referring to the drawing, a well indicated generally by reference numeral 10 is shown penetrating an incompetent formation 12 between a cap rock 14 and base rock 16. Well 10 is illustrated with casing 18 extending from the surface through the incompetent formation 12 into the base rock 16. In the embodiment shown in the drawing, casing 18 is cemented in place in the borehole completely to the surface by any conventional cementing procedure.
The incompetent formation 12 can be any formation that will benefit from an increase in the strength of bonding of the particles comprising the formation. The process of this invention can be used on relatively hard, substantially self-supporting formations, but little is to be gained unless the formation 12 has insufficient strength to prevent movement of particles of the formation into the well as uids are produced through the well. The in- 3 competent formation 12 also may be substantially uncemented, and resemble quicksand.
The upper end of the casing 18 is closed by a suitable cap 20 through which a fuel line 22 extends to supply fuel to a burner 24. An inlet line 26 opens into casing 18 above the surface 28 of the ground to supply air for the coking operation. Fuel line 22 and line 26 are connected with suitable sources of fuel and air, respectively. The fuel and air sources are not shown in the drawing.
In the preferred embodiment of the invention illustrated in the drawing, a ring is cut from casing 18 at the desired location in an interval of incompetent formation 12 to form an opening 30 through the casing. A notch is cut through opening 30 and the surrounding cement sheath 32 to provide access of air which is to be injected at a later stage of this process, into the incompetentformation 12. A single circumferential opening 30 of the type illustrated in the drawing is preferred because it insures flow of air to the desired location in the formation at closely controlled conditions which are substantially uniform in those areas of the formation treated. However, this invention can be used with the single opening 30 replaced by a plurality of perforations through the casing 18. Although the invention is illustrated in a well in which casing is set through the incompetent formation, the invention is not limited to that type of well completion and may be used in a well which is completed with an open hole through the incompetent oil-bearing formation 12 if the incompetent formation has adequate strength to prevent collapse of the formation during the drilling and consolidation process. Because of the very large area exposed when the well is completed as an open hole, high compressor capacities would be required during the air injection steps to insure treatment of the entire area of formation 12 exposed to the borehole of the well in accordance with'this invention. If a long interval ofthe formation is exposed by an open hole, the static pressure in the formation near the top of the exposed interval is substantially less than near the bottom and may cause a fracture to be created near the top of the exposed interval with the result that very little, -if any, of the injected gas enters the lower portion of the exposed interval. For this reason the process is limited to use in open hole where the exposed interval is less than one hundred feet, and preferably less than fty feet.
During the drilling of the well and the cutting of the opening 30, it is desirable to maintain a liquid within the well under a pressure higher than the pressure of fluids in formation 12 to prevent flow of fluids from the formation into the well. The higher pressure in the borehole of the well may cause displacement of some of the oil from the formation 12 adjacent the well. In some instances oil present in formation 12 may not contain enough fheavy residual oils to create a strong bond of coke. If for either reason there is insufficient cokable oil in the formation 12 adjacent the Well, it will be desirable to displace a readily cokable liquid, preferably a heavy crude oil or residual oil from the well 10 into the formation 12 surrounding -the well. Thereafter air is displaced down the casing and a suitable fuel such as natural gas or LPG is displaced through fuel line 22 into burner 24 where the fuel is ignited. The relative ratesof displacement of the fuel and air into the well are adjusted lto provide an oxygencontaining gas having a temperature Within the desired range, as hereinafter described. If desired, an electric heater can be substituted for the burner 24 to heat the oxygen-containing gas to the desired temperature. Coking of oil in the formation is not sensitive to the concentration of oxygen in the injected gas when the oxygen concentration is in the range from the concentration in air down to about one percent of the injected gas. Because of the lack of sensitivity to the oxygen concentration, the necessary temperature control can be obtained by dilu- :ion of the combustion products from a burner with cold air and the changing oxygen concentration does not interfere with control of the coking. A preferred method of controlling the temperature is to inject air at a rate adequate to fracture the formation and then inject fuel,`
which is burned at the burner 24, at a gradually increasing rate to obtain the desired temperature of the gases passing through notch 30. When an electric heater is used for heating and controlling the temperature, the injected gas can be substantially undiluted air.
The air is injected from the well into the formation at a high rate which will create a fracture 34 in the formation. Whether the rate of injection of the air is adequate to create the desired fracture can easily be ascertained by observation of the pressure within the Well as air injection continues. lf the formation surrounding the well is relatively open and will accept air from the formation, the rate of llow of air from the well into the formation is substantially directly proportional to the pressure within the well prior to the creation of any fracture. Once a fracture or open channel through the incompetent formain the rate of injection of the air into the well.
In some instances, the formation surrounding the Well will be plugged during the drilling or cementing operations and formation 12 will initially not readily acceptair. Continued injection of air through line 26 into the well causes the pressure within the well to increase until a pressure break, which indicates the creation of a fracture within the incompetent formation, occurs. The rate of displacement of air into the well can then be greatly increased without increasing the pressure in the Well to a pressure as high as the pressure prior to the pressure break.
It is essential when injecting oxygen-containing gases into an oil-bearing formation to control the temperature of the injected gas carefully in accordance with a predetermined schedule to cause the formation of a coke of the desired characteristics and yet avoid burning coke from the formation. In the preferred embodiment of the process of this invention, an oxygen-containing gas, which may be air or air diluted with inert fluids, such as flue gas, is'displaced from the borehole of a well outwardly l through the incompetent formation containing oil. The
containing gas temperature rather quickly to 225 F.'
Further increases in temperature are made more slowly. A period of about four hours should be used to raise the temperature of the oxygen-containing gas from the initial injection temperature to 250 F. The particular timetemperature schedule of the injected gas below 250 F isl not highly critical, but it is preferred that the rate of temperature increase to that temperature be substantially uniform. For example, if the temperature increase is stepwise, three or more substantially equal steps should be used. 'Ihe period for increasing the temperature from 250 F. to the nal temperature at which the oxygencontaining gas is displaced into the formation is preferably at least about 48 hours. It will be desirable to run preliminary tests on oil from the unconsolidated sands whenever a coking operation is to be performed to aid in selection of the desired time-temperature schedule, but
the schedule of four hours to 250 F.y and 48 hours to it possible to raise the temperature from 250 F. to the final temperature in 24 hours in some instances.
The temperature and pressure of the incompetent formation will also inuence the rate at which the temperature of the injected gas can be raised. Increases in temperature or increases in pressure of the incompetent formation increase the reaction rate and make necessary slower initial raising of the temperature of the injected oxygencontaining gas; however, the effect of pressure is relatively minor compared to the effect of temperature on the rate of reaction between the oil and the oxygen-containing gas. If the process is used in a deep formation initially at a high temperature, the formation can be cooled, for example, by injection of a cool inert gas or liquid, such as water, before displacing an oxygen-containing gas into the formation.
The temperature of the oxygen-containing gas displaced into the formation is gradually increased at a substantially uniform rate in either a continuous or stepwise manner to a final temperature in the range of 350 to 500 F. adapted to produce a coke having adequate strength and a low solubility in oil bonding together the particles of the formation adjacent the faces of fracture 34, as illustrated by the shading in the drawing.
Tests on cores of unconsolidated sands saturated with a readily cokable oil in which air is displaced through the unconsolidated sand at a maximum temperature of approximately 300 F. have resulted in the formation of little, if any, coke, and have not produced the desired consolidation of the sand. In those experimental runs at air injection temperatures less than 350 F. in which coke was formed, the coke was soluble in hydrocarbon solvents. The temperature of the air displaced from the borehole into the formation should not exceed 500 to 600 F. It has been found that oxygen-containing gas teniperatures in excess of 600 F. cause a marked decrease in the strength of the coked mass adjacent' the borehole. The following examples illustrate the necessity of increasing the temperature at a controlled rate to the desired final temperature.
Example 1 A thin-walled stainless steel tube, 5 inches in diameter and 5 feet long, was packed with sand and saturated with a crude oil having a gravity of 15.8 API horn the Fruitvale eld in California. A jacket around the tube provided an annular space surrounding the tube into which nitrogen was introduced to permit maintenance of the desired pressure within the tube without exposing the thin-walled tube to high pressure differences. Thermocouples were located at regular intervals through the packed sand. After air ow through the tube was established, the air was heated prior to displacement into the sand in accordance with the schedule set forth in Table I. The run was ended when temperatures within the 5-inch tube indicated that combustion was occurring. The air flux through the tubing was maintained at approximately 29,000 std. cu. ft./sq. ft./hr. and the outlet pressure of the tubing was maintained at approximately 750 lbs/sq. in.
Example 2 A S-inch tube, 5 feet long, was packed with sand which was then saturated with a Fruitvale cnude oil having a gravity of 15.8 API. Thermocouples were positioned at regular `intervals along the length of the tubing and the tubing provided with a jacket suitably connected with a source of nitrogen .for maintaining the desired pressure on the outer surface of the tube. Air was passed through the tube to establish permeability and thereafter adjusted to maintain an air flux fof approximately 30,000 std. cu. ft./sq. ft./hr. The pressure at the youtlet of the tube was maintained at approximately 400 lbs/sq. in gauge. The temperature of the air introduced into the tube was gradually increased in accordance with the schedule set forth in Table I and the temperatures indicated 'by the thermocouples recorded. The results of the `tests of Examples 1 and 2 are presented in Table I.
TABLE I Example l Time, T., F., T. max.,
min. Injected F. Air
Example 2 VIt will be noted'from Table I that the rapid increase to an air inlet temperature of 395 F. in 2 hours and 40 minutes resulted in the initiation of combustion within the tubing, as indicated by a maximum temperature of 1700"V F. The maximum temperature was indicated at a thermocouple located lat a point about two-thirds of the distance to the outlet end of the tube. Similar tests have shown that if the injection of oxygen-containing gases is continued after ya temperature of the type indicated in lExample 1 occurs, reverse combustion is initiated and the peak temperature moves toward the inlet end of the tube. When the temperature of the inlet air was increased more slowly, as in Example 2, in which approximately 8 hours were required to y:reach `a temperature of 390 F., combustion was not initiated .in `the tube and a strong funitary mass of sand particles bonded with coke was produced.
The rates of raising the temperature of the injected air set lforth in Table I are somewhat higher than are possible in subsurface formations. The radial flow pattern of gases displaced from a well into a formation ycauses a rapid reduction -in the flux as the distance into the formation increases and prevents maintenance of the high air flux used in the experimental tubes. Field tests have indicated that slower rates of increasing the temperature of the injected oxygen-containing gas are required in the field than in the experi-mental cores.
-In the Santiago field in California, air was injected into an incompetent oil-'bearing lformation at a rate of 1,170,000 cubic feet per day when .a pressure drop indicated that the formation had fractured. The borehole pressure just before the pressure |break was 560 pounds per square inch. After the pressure lbreak air was -injected at a rate of 1,400,000 cubic feet per day and a borehole press-ure of 535 pounds per square inch. Air injection `at the increased rate was continued for 24 hours at the resenvoir temperature. The temperature of the air was then increased to 150 F. by control of the rate of supplying propane gas to a burner in the Iborehole. Tihe temperature of the injected .gas was increased to 200 F. over an 8-hour period by increasing the rate of fuel supply to the burner and then held for 16 hours at 200 F. The temperature of the injected gas was then increased to 250 F. over an 8hour period and held for "16 hours at 250 F. The sequence of raising the temperature and then holding the temperature was continued until the temperat'ure of the .gases displaced into the formation reached 400 F. Throughout the air-injection procedure, the airinjection rate was high enough to maintain the pressure in the borehole at the -fracturinlg pressure. No detrimental combustion of the oil in the formation surrounding the borehole was exlperienecd, and subsequent production of oil from the well :indicated that the sands were consolidated adequately lto prevent :dow of sand into the well. The lprocedure in the Santiago field was conservatively designed to prevent detrimental combustion. Subsequent laboratory tests show that more rapid increases in the temperature of the air displaced into the 'formation can be used without causing destructive combustion of coke formed adjacent Vthe borehole wall.
Sui-table consolidation of the formation and prevention of forward burning which destroys coke formed adjacent to .the borehole of the well cannot be obtained merely by maintaining a low temperature of oxygen-containing lgas displaced into the formation. A number of field tests of tin-situ combustion processes have shown that continued i11- jection of oxygen-containing gases at the formation temperature into the formation will eventually cause combustion to be initiated at some distance from the injection well. Once the combustion is initiated, the temperature will build up to excessive levels and eventually reverse combustion occurs causing the combustion front kto move to the injection well. Continued displacement of oxygencontaininig gas after :the combustion front reaches or approaches the injection well causes a second reversal in the direction of movement of the combustion `front to forward combustion which completely consumes any coke deposited adjacent the injection well. llt is necessary to raise the temperature of the injected Igas to condition the oil in the formation adjacent the linjection borehole, where- -by the subsequent combustion will not travel -by reverse combustion to destroy coke reaching the desired thickness of the sleeve of coke bonded particles surrounding the borehole.
The coke Ibond created by the hot air injection is physically strong and chemically stable. A-fter a period of production of oil, the Well in the Santiago field described in the specific embodiment was stimulated by the injection of air through the Well into the formation -to cause in-situ combustion of oil in the oildbearintg formation remote from the well. Arfter the combustion had proceeded :for a time adequate to heat the formation, the well was again placed on production. No sand flowed into the well yduring the subsequent production thereby indicating that the coke bond was not destroyed.
Although the deposition of coke to consolidate the formation is preferably accomplished by the injection of an oxygen-containing gas at a controlled, gradually increasing temperature because of the greater strength of the resultant consolidated formation, the coke can also be produced.by the injection of hot insert gases under a pressure and at a rate adequate to fracture the incompetent formation and maintain the fracture open during the deposition of the coke. The term inert gases is used to designate gases having an oxygen concentration below about one percent. Such gases can be obtained, for example, from the exhaust of gas or gasoline fueled internal combustion engines, or the burning of a suitable rocket fuel. Because of the low oxygen concentration in the inertgases, danger of burning coke deposited in the formation is avoided, and it is possible to proceed immediately with the injection of high temperature inert gases. The temperature of the inert gases may range from approximately 400 to l300 F. and is preferably in the range of 650 to 1000 F. Because of the high temperature of the inert gas, the injection lof the gas will create the desired coke bond in a short time compared with the time required for the coking operation with the oxygencontaining gas. For example, if the inert gases are injected at a .temperature of 1000 F., an adequate zone of 'consolidation islobtained in a period of eight hours.
8 The creation of a coke bond by the injection of hot` gases while holding the fracture open apparently results in a zone of consolidated formation completely encasing r Subsequent production of oil through the formation to prevent the `surfaces from mating when the pressure is released and the well is placed on production. ln the process herein described, there is no ldanger of destroying the consolidation of the formation; whereas if attempts are made to fracture formations after they have consolidated by the deposition of coke, the benets derived from the consolidation ordinarily lare destroyed.
The rate at which the gas is injected into the formation to create the fracture and maintain the fracture open during the deposition of the coke will depend upon the permeability of the formation and the mobility of the oil in the formation. It is not possible to yspecify a particular `rate of gas injection that is applicable to all incompetent formations to be treated by this invention; however, `the i rate of gas injection must exceed the rate at which liquids in the formation can be made to ow away from the borehole through the formation when the borehole pressure is below the minimum pressure required to fracture the formation. whether or not the injection rate is adequate to create a fracture. A pressure break as the gas injection rate is increased or achange in the rate of increase of pressure with increased gas injection rate gives a quick .and accurate indication of the creation of a fracture. Maintenance of the gas injection rate to maintain the borehole pressure at or above the pressure at which the break occurs will insure holding the fracture open during the conversion of heavy oils to coke to consolidate the formation.
We claim:
1. A method of consolidating and increasing the ow capacity of an incompetent underground oil-bearing formation penetrated by a well comprising injecting a gasV down the well and into the formation at a rate creating Ia fracture in the formation, continuing the injection of the gas at a rate maintaining the fracture open, and while maintaining the fracture open by the injection of gas increasing the temperature of the injected gas to above 350 F. to deposit coke in the formation adjacent the fracture and bond the particels of the formation into a consolidated mass.
2. A method of consolidating and increasing the fluid` iiow capacity of an incompetent underground oil-bearing formation penetrated by a well comprising injecting gas down the well and into the formation at a rate faster than formation fluids Will flow through the formation in the absence of a fracture whereby said formation is fractured, continuing the injection of the gas at a rate holding the fracture open, and while maintaining the fracture open by the injection of gas increasing the temperature of the gas to a final temperature above 350 F. at a rate to avoid ignition of the oil in the formation adjacent the fracture whereby coke is deposited in the formation-adjacent the fracture to consolidate the formation.
'3. A method of consolidating an incompetent underground oil-bearing formation penetrated by a well and increasing the iiow capacity of the formation into the well comprising injecting an oxygen-containing gas down the well and into the formation at a rate causing fracturing of the formation, continuing the injection of the oxygencontaining gas at a rate to hold Ithe fracture open, and increasing the temperature of said oxygen-containing gas to Iapproximately 250 F. in a period of at least about four hours, thereafter gradually increasing the temperature of` No difficulty is encountered in determining` the injected gas to a final temperature in the range of 350 to 500 F. adapted to convert hydrocarbons adjacent the fracture in the formation to coke to consolidate the formation while injecting the gas at a rate maintaining the fracture open.
4. A method as set forth in claim 3 in which the temperature of the injected gas is raised from 250 F. lat a substantially uniform rate to a final temperature in the range of 350 to 500 F. over a period of at least about 48 hours.
5'. A method as set forth in claim 3 in which the temperature of the injected gas is raised from 250 F. at a substantially uni-form rate to a final temperature in the range of 350 to 500 F. over a period of at least about 24 hours.
6. A method of consolidating an incompetent underground oil-bearing formation penetrated by the lborehole of a well and increasing the flow capacity of said formation into said borehole comprising displacing air down the well and into said formation at a rate creating a fracture in the formation, `continuing the injection of air at a rate to hold `the fracture open while burning fuel in the yborehole to raise the temperature of the gas injected into the formation, and periodically increasing the ratio of fuel to air to increase the temperature of the air and combustion products to `a nal temperature in the range of 350 to 500 F. whereby oil in the formation is coked to consolidate the formation, the rate of increasing the ratio of fuel to air being controlled to avoid ignition of oil adjacent the fracture.
7. A method of consolidating an incompetent underground oil-bearing formation penetrated by the borehole of a well and increasing the flow capacity of the formation into said borehole comprising injecting a gas from the 'borehole of the well into the formation at a rate creating a fracture in the formation, continuing the injection of the gas at a rate maintaining the fracture open while heating said gas with an electric heater Suspended in the borehole of the well adjacent the formation, and gradually increasing the temperature of the gas injected into the formation to a nal temperature exceeding 350 F. to convert oil in the formation to coke and thereby consolidate said formation.
8. A method of consolidating an incompetent under ground oil-bearing formation penetrated by the borehole of a well comprising injecting a gas down the well and into the formation at a rate creating a fracture in said formation, injecting an inert gas -at ya temperature in t-he range of 400 to 1300 F. down the well and into the formation at a rate maintaining the fracture open to convert oil in said formation vadjacent the fracture to coke to consolidate the formation.
9. A method as set forth in claim 8 in which the inert gas is the exhaust gas from an internal combustion engine.
10. A method as set forth in claim 8 in which the inert gas is the exhaust gas from `a rocket fuel.
11. A method of consolidating an incompetent underground oil-bearing formation penetrated lby the bore- -hole of a Well comprising setting casing in said borehole through the incompetent formation, cutting a notch in the casing opposite the incompetent formation, injecting a gas down the well `and through the notch into the formation at a rate creating a fracture in the formation, continuing the injection of the gas at a Irate adapted to maintain the fracture open while increasing the temperature of the gas to at least 350 F. at a rate avoiding combustion of oil Iadjacent the fracture to convert oil in the formation adjacent the fracture to coke and thereby consolidate the formation.
12. A method -as set forth in claim 11 in which the gas is Ian oxygen-containing gas and the final temperature is 350 to 500 F.
References Cited by the Examiner UNITED STATES PATENTS 3,003,555 l0/l961 Freeman et al 166-39 X 3,004,594 10/ 1961 Crawford 166-42.1 X 3,l38,205 6/1964 Kerver et al 166-42.1 3,147,805 9/1964 Goodwin et al. 166--25 3,221,813 12/1965 Clossmann et al 166-1l `CHAIULES E. OCON'NELL, Primary Examiner.
S. I. NOVOSAD, Assistant Examiner.
Claims (1)
- 8. A METHOD OF CONSOLIDATING AN INCOMPONENT UNDERGROUND OIL-BEARING FORMATION PENETRATED BY THE BOREHOLE OF A WELL COMPRISING INJECTING A GAS DOWN THE WELL AND INTO THE FORMATION AT A RATE CREATING A FRACTURE IN SAID FORMATION, INJECTIN AN INERT GAS AT A TEMPERATURE IN THE RANGE OF 400* TO 1300*F. DOWN THE WELL AND INTO THE FORMATION AT A RATE MAINTAINING THE FRACTURE OPEN TO CONVERT OIL IN SAID FORMATION ADJACENT THE FRACTURE TO COKE TO CONSOLIDATE THE FORMATION.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US322856A US3292701A (en) | 1963-11-12 | 1963-11-12 | Method for consolidating incompetent subsurface formations |
GB45727/64A GB1056258A (en) | 1963-11-12 | 1964-11-10 | Method of consolidating an incompetent oil bearing formation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US322856A US3292701A (en) | 1963-11-12 | 1963-11-12 | Method for consolidating incompetent subsurface formations |
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US3292701A true US3292701A (en) | 1966-12-20 |
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US322856A Expired - Lifetime US3292701A (en) | 1963-11-12 | 1963-11-12 | Method for consolidating incompetent subsurface formations |
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US (1) | US3292701A (en) |
GB (1) | GB1056258A (en) |
Cited By (9)
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---|---|---|---|---|
US3371713A (en) * | 1966-07-25 | 1968-03-05 | Pan American Petroleum Corp | Submerged combustion in wells |
US3388743A (en) * | 1966-01-18 | 1968-06-18 | Phillips Petroleum Co | Method of consolidating an unconsolidated oil sand |
US3437144A (en) * | 1966-08-26 | 1969-04-08 | Phillips Petroleum Co | Consolidation of formations |
US3454959A (en) * | 1967-09-29 | 1969-07-08 | Gulf Research Development Co | Method of consolidating incompetent formations |
US3483926A (en) * | 1968-07-25 | 1969-12-16 | Shell Oil Co | Consolidation of oil-bearing formations |
US3945679A (en) * | 1975-03-03 | 1976-03-23 | Shell Oil Company | Subterranean oil shale pyrolysis with permeating and consolidating steps |
US4703800A (en) * | 1984-04-25 | 1987-11-03 | Hanna Mohsen R | Method for consolidating formation surrounding borehole |
US20110000221A1 (en) * | 2008-03-28 | 2011-01-06 | Moses Minta | Low Emission Power Generation and Hydrocarbon Recovery Systems and Methods |
US9840898B2 (en) | 2013-12-13 | 2017-12-12 | Chevron U.S.A. Inc. | System and methods for controlled fracturing in formations |
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US3003555A (en) * | 1956-09-18 | 1961-10-10 | Jersey Prod Res Co | Oil production from unconsolidated formations |
US3004594A (en) * | 1956-11-19 | 1961-10-17 | Phillips Petroleum Co | Process for producing oil |
US3138205A (en) * | 1960-12-14 | 1964-06-23 | Jersey Prod Res Co | Hydraulic fracturing method |
US3147805A (en) * | 1962-01-19 | 1964-09-08 | Gulf Research Development Co | Method for consolidating an unconsolidated formation |
US3221813A (en) * | 1963-08-12 | 1965-12-07 | Shell Oil Co | Recovery of viscous petroleum materials |
-
1963
- 1963-11-12 US US322856A patent/US3292701A/en not_active Expired - Lifetime
-
1964
- 1964-11-10 GB GB45727/64A patent/GB1056258A/en not_active Expired
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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US3003555A (en) * | 1956-09-18 | 1961-10-10 | Jersey Prod Res Co | Oil production from unconsolidated formations |
US3004594A (en) * | 1956-11-19 | 1961-10-17 | Phillips Petroleum Co | Process for producing oil |
US3138205A (en) * | 1960-12-14 | 1964-06-23 | Jersey Prod Res Co | Hydraulic fracturing method |
US3147805A (en) * | 1962-01-19 | 1964-09-08 | Gulf Research Development Co | Method for consolidating an unconsolidated formation |
US3221813A (en) * | 1963-08-12 | 1965-12-07 | Shell Oil Co | Recovery of viscous petroleum materials |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3388743A (en) * | 1966-01-18 | 1968-06-18 | Phillips Petroleum Co | Method of consolidating an unconsolidated oil sand |
US3371713A (en) * | 1966-07-25 | 1968-03-05 | Pan American Petroleum Corp | Submerged combustion in wells |
US3437144A (en) * | 1966-08-26 | 1969-04-08 | Phillips Petroleum Co | Consolidation of formations |
US3454959A (en) * | 1967-09-29 | 1969-07-08 | Gulf Research Development Co | Method of consolidating incompetent formations |
US3483926A (en) * | 1968-07-25 | 1969-12-16 | Shell Oil Co | Consolidation of oil-bearing formations |
US3945679A (en) * | 1975-03-03 | 1976-03-23 | Shell Oil Company | Subterranean oil shale pyrolysis with permeating and consolidating steps |
US4703800A (en) * | 1984-04-25 | 1987-11-03 | Hanna Mohsen R | Method for consolidating formation surrounding borehole |
US20110000221A1 (en) * | 2008-03-28 | 2011-01-06 | Moses Minta | Low Emission Power Generation and Hydrocarbon Recovery Systems and Methods |
US8984857B2 (en) * | 2008-03-28 | 2015-03-24 | Exxonmobil Upstream Research Company | Low emission power generation and hydrocarbon recovery systems and methods |
US9840898B2 (en) | 2013-12-13 | 2017-12-12 | Chevron U.S.A. Inc. | System and methods for controlled fracturing in formations |
US9890627B2 (en) | 2013-12-13 | 2018-02-13 | Chevron U.S.A. Inc. | System and methods for controlled fracturing in formations |
US10400568B2 (en) | 2013-12-13 | 2019-09-03 | Chevron U.S.A. Inc. | System and methods for controlled fracturing in formations |
Also Published As
Publication number | Publication date |
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GB1056258A (en) | 1967-01-25 |
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