Classifications

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  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
  • C10M159/12—Reaction products
  • C10M159/16—Reaction products obtained by Mannich reactions
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  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
  • C10M2201/08—Inorganic acids or salts thereof
  • C10M2201/082—Inorganic acids or salts thereof containing nitrogen
  • C10M2201/083—Inorganic acids or salts thereof containing nitrogen nitrites
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  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
  • C10M2205/18—Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
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  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
  • C10M2207/10—Carboxylix acids; Neutral salts thereof
  • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
  • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
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  • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
  • C10M2207/10—Carboxylix acids; Neutral salts thereof
  • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
  • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
  • C10M2207/122—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
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  • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
  • C10M2207/40—Fatty vegetable or animal oils
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  • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
  • C10M2207/40—Fatty vegetable or animal oils
  • C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
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  • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
  • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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  • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
  • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
  • C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
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  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
  • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
  • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
  • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
  • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
  • C10M2215/062—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups bound to the aromatic ring
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
  • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
  • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
  • C10M2215/064—Di- and triaryl amines
  • C10M2215/065—Phenyl-Naphthyl amines
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  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
  • C10M2215/26—Amines
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
  • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
  • C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
  • C10M2227/04—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having a silicon-to-carbon bond, e.g. organo-silanes
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
  • C10M2229/02—Unspecified siloxanes; Silicones
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
  • C10M2229/04—Siloxanes with specific structure
  • C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
• • C—CHEMISTRY; METALLURGY
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  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2010/00—Metal present as such or in compounds
  • C10N2010/04—Groups 2 or 12
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  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2040/00—Specified use or application for which the lubricating composition is intended
  • C10N2040/25—Internal-combustion engines
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2040/00—Specified use or application for which the lubricating composition is intended
  • C10N2040/25—Internal-combustion engines
  • C10N2040/252—Diesel engines
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2040/00—Specified use or application for which the lubricating composition is intended
  • C10N2040/25—Internal-combustion engines
  • C10N2040/252—Diesel engines
  • C10N2040/253—Small diesel engines

Definitions

• This invention relates to lubricants.
• the invention relates to lubricating oil compositions, having good anti-wear properties, comprising mineral oil and alkaline earth metal salts of acetic acid and aminoalkyl phenol.
• lubricants can be made according to the invention which are particularly effective for lubrication of marine diesel engines.
• Marine diesel engines have become widespread in their use. In these engines there has always been a serious wear problem with regard to the piston, the piston rings and the surface of the cylinder liner. This problem of wear has been aggravated 'by use of low cost residual type fuel oils which generally contain 2 to 4 wt. percent sulfur. Because of their high sulfur content, acid formed by the combustion of the sulfur, tends to corrode the steel surfaces of the engine to give very high rates of wear.
• a fluid or semifiuid lubricant is sprayed directly onto the cylinder upon each stroke of the piston by means of a centralized forcefeed lubrication system.
• the lubricant is to a large extent consumed during each stroke of the piston, thereby requiring continuous application of the lubricant.
• the lubricant should have a fluid or semi-fluid consistency. This is desired in order that the lubricant may be readily pumped through the aforementioned forced lubrication systems normally associated with marine diesel engines and will spread or wet the pistons sufliciently during each stroke to achieve an overall coating on the piston surface. As indicated above, another requirement of such lubricants is that they have good antiwear properties. Because of the giant size of the pistons and cylinders used in such engines (cg. piston and cylinder diameters of 36 to 60 inches are common), Wear is a serious problem. Once the cylinder liner has worn more than about 0.6% of its diameter, it is necessary that it be replaced.
• Lubricants of this type should be able to minimize the Wear due to corrosiveness caused by the degradation products of the oil and particularly of the sulfur.
• the lubricant should also be storage stable, even when subject to long periods of vibration as occurs during storage in a ships engine room and in the presence of minor amounts of moisture.
• a commercial lubricant which found Widespread acceptance for such marine diesel lubrication and which met the above requirements, is obtained by thickening mineral oil with mixed calcium salts of acetic acid and an intermediate molecular weight fatty acid, e.g. C to C or C fatty acids.
• Intermediate fatty acids that have been used include those available under the trade-name Wccoline AAC acid, which is a mixture of fatty acids derived from coconut oil comprising capric, caprylic and lauric acids. Using a molar ratio of about 12 moles of acetic acid (or 6 moles of acetic anhydride) per mole of the Wecoline AAC acid had proved to form a very successful lubricant.
• marine diesel lubricants superior in several respects to those made from the Wecoline AAC and acetic acid, can be prepared by using an aminoalkyl phenol in place of part or all of the intermediate molecular weight fatty acid, i.e. the Wecoline AAC acid.
• the aminoalkyl phenol By the use of the aminoalkyl phenol, marine diesel lubricants can be prepared which are su perior to said intermediate fatty acid type lubricant by having a reduced tendency to gel under very hot and wet conditions.
• the aminoalkyl phenol results in a better dispersion of calcium acetate, excellent oxidation stability, etc.
• Aminoalkyl phenols contemplated for use in the present invention are known, for example see US. Patents 2,353,491; 2,459,112 and 3,036,003. These materials can be prepared by reacting aldehyde, alkylene polyamine, and phenol or alkyl phenol. The reaction is preferably carried out in the presence of a mineral oil diluent. Generally, the reactants will be utilized in a ratio of about 0.5 to 2.0 moles of the aldehyde and the alkyl phenol for each nitrogen atom present in the polyamine.
• aldehydes in general are contemplated, preferred aldehydes will be the C to C aliphatic aldehydes, such as formaldehyde, acetaldehyde, propionaldehyde, etc., with form-aldehyde being especially preferred.
• R is a substituted or unsubstituted C to C alkylene radical and n is an integer from 1 to 10.
• Representative amines within the above formula include diethylenetriamine, tetraethylenepentamine, ethylene diamine, propylene diamine, etc.
• Preferred polyamines are the alkylene diamines, with ethylene diamine being particularly preferred.
• Suitable amines include polymerized ethylene imines having a molecular Weight of about 1,000 to 40,000.
• the alkylphenols are typified by at least one phenol nucleus having at least one alkyl group of 4 to 20, preferably 6 to 12, carbon atoms attached thereto. Examples of such compounds will include nonylphenol, isooctylphenol, dilaurylphenol, etc.
• a typical reaction procedure involves adding the aidehyde compound to a mineral oil solution of alkyl phenol and the polyamine.
• the resulting mixture is heated to a temperature within the range of about to 350, e.g. to 200 F. and maintained at said temperature for about 1 to 4 hours.
• the final reaction mixture can then be further heated to a higher temperature, e.g., about 320 F., to remove any water which may be present.
• reaction time, temperature, and relative mole ratios f the reactants may be readily varied to form a variety of similar compounds.
• a preferred form of compound believed to have the approximate general formula:
• the alkaline earth metal component of the mixed salt composition is preferably calcium since it results in the production of stable lubricants having load carrying and anti-wear characteristics even without the use of conventional extreme pressure and stabilizing agents.
• the other alkaline earth metals such as barium, strontium and magnesium can be used, but are not as good as calcium in these respects.
• the anhydrous mixture of alkaline earth metal salts of the invention can be prepared by coneutralization of a mixture of the acetic acid and aminoalkyl phenol with suitable bases, particularly lime.
• the coneutralization step can be carried out in situ in the oil menstruum to which the mixture of salts is to be applied in actual use.
• the maximum tempenature at which coneutralization is carried out, or the temperature to which the coneutralized material is heated, will generally be in the range of about 250 to about 350 F.
• the salt mixture is preferably heated until anhydrous, i.e. there is no free or unbound water present.
• This alkalinity acts to neutralize corrosive acids formed by degradation of the lubricant during use and also imparts greater stability to the
• the mixture of alkaline earth metal salts of the inven tion can also be prepared by separately preforming the salt of the aminoalkyl phenol, then forming the acetate salt by neutralization in the presence of the aminoalkyl phenate, then heating under substantially dehydration conditions.
• the mixed salt lubricants of the invention can be prepared by using 1 to 100, preferably 5 to 40, mole equivalents of acetic acid or acetic anhydride per mole equivalent of aminoalkyl phenol.
• lubricants designed for marine diesel lubrication good results are obtained by using a ratio of about 10 to 15, e.g. 12, mole equivalents of the acetic acid or its anhydride per mole equivalent of aminoalkyl phenol.
• the finished lubricant will generally be a fluid or semi-fluid comprising a major amount of lubricating oil and about 3 to 20, preferably 5 to 12 wt. percent of the mixed salt combination.
• concentrates of 20 to 45 wt. percent of the mixed salts in oil can be made by the in situ technique, after which the concentrate is diluted with additional oil to form the finished lubricant. This dilution is readily made by adding the additional oil and mixing.
• Both the concentrate and finished lubricant can be homogenized in a Morehouse mill, Charlotte mill, Gaulin homogenizer etc. If enough of the mixed salt is used in the oil a soft solid grease is obtained. However, these greases do not seem to have very good structural stability.
• the mixed salt composition of the invention is preferably used in the form of fluid or semifiuid lubricant.
• Mineral oil is the preferred lubricating oil, although various synthetic oils such as polysilicone, silanes, esters, Ucons, etc. may be used for special uses.
• additives can be added to the finished lubricant in amounts of 0.1 to 10.0 wt. percent, based on the weight of the finished lubricant.
• corrosion inhibitors such as sodium nitrite, lanolin, woo-l grease stearin; antioxidants such as phenyl-alpha-naphthylamine; extreme pressure agent-s; dyes; etc.
• the aminoalkyl nonylphenol used above was a commercial product consisting of about 75 wt. percent mono nonyl phenol and about 25 wt. percent of a mixture which was predominantly di-nonyl phenol with a small amount of phenol.
• the nonyl groups were derived fromtriisopropylene.
• Part B.Preparati0n of grease concentrate 10.2 parts of hydrated lime and 64.8 parts of mineral lubricating oil of 80 SSU viscosity at 210 F. were added to a steam-jacketed grease kettle and intimately mixed to a smooth slurry. While stirring, 3 parts of the oil solution of the aminoalkyl nonylphenol of Part A was added to the kettle. Next, 16 parts of glacial acetic acid was added to the kettle slowly while maintaining the temperautre of the grease composition below 200 F. After all of the acetic acid had been added, the batch was then passed through a Morehouse mill in order to obtain more thorough mixing.
• the composition was returned to the grease kettle and then 6 parts of the oil solution of aminoalkyl nonylphenol of Part A was added to the composition.
• the temperature of the kettle contents was raised to 205 F. and a small amount of additional lime was added to bring the free alkalinity to 0.28 wt. percent calculated as NaOH.
• the composition was then heated to a temperature of 320 P. which was held for 20 minutes following which the product was cooled to about 100 P. where it was again passed through the Morehouse mill.
• the product was an excellent, smooth grease composition having a free alkalinity of 0.15% calculated as NaOI-l.
• Part C A finished lubricant was obtained by mixing 25 wt. percent of the product of Part B above with 75 wt. percent of additional mineral lubricating oil of 80 SUS 210 F. By this dilution the final product was obtained.
• Example II Using the same technique as that of Example I, a second lubricant was prepared having a molar ratio of acetic acid to aminoalkyl nonylphenol of 12:1. The product of Example II was compared with a commercial marine diesel lubricant using mixed metal salts of acetic acid and coconut acids. The formulations of the compositions and their properties are summarized in Table II which follows:
• Example II showed very little change in viscosity upon heat soaking.
• the product of Example II had a viscosity of 46.5 SUS at 300 E, while the same sample after being heat soaked for 4 hours at 300 F. had a viscosity of 47.2 SUS.
• the commercial lubricant increased in viscosity from 68 SUS to 81.5 SUS after 4 hours of heat soaking at 300 F.
• a minimum change in viscosity upon heat soaking is desired since the lubricant may be in lubrication lines near the hot engine for a considerable length of time.
• the product of Example II gave a wear scar diameter of 0.22 mm. in the 4- Ball Wear Test (1800 r.p.m./1 hour/ C./10 kg. load). Both the commercial lubricant and the product of Example II completely passed through a mesh screen without leaving any residue.
• the Manzell lubricator test of Table II is carried out by passing the lubricant under test through a Manzell lubricator at the rate of 2 quarts of lubricant a day.
• the Manzell lubricator includes a sight-glass filled with an aqueous solution containing 20 Wt. percent of calcium nitrate tetrahydrate as the sight-glass fluid. These lubricators are widely used in conjunction with marine diesel engines.
• the lubricator permits visual observation of the rate of flow of the lubricant which is forced into the bottom of the sight-glass and then floats up through the higher density sight-glass fluid to an upper line from where it is then forced to the cylinder being lubricated.
• the product of Example II Went for over a 100 day trial without fogging the sight-glass.
• the commercial lubricant went for only 14 days before the sight-glass had become sufiiciently fogged so as to require disassembling and cleaning.
• the base number of Table II indicates that both the product of Example II and the commercial lubricant had good reserve alkalinity for neutralizing the aforementioned sulfur corrosive compounds, e.g. sulfuric acid, which forms upon combustion of the fuel oil.
• the alkalinity of the product of Example II was equivalent to 37.8 mg. KOH per gram of product.
• the Thermal Stability test is carried by filling an ASTM pour point jar full with the lubrciant to be tested. The test lubricant is heated for four hours and is then cooled for 45 minutes. The jar is then examined to see if the lubricant has gelled. It is seen that at the 190 C. heating level, that the commercial lubricant had gelled while the product of Example II had not. This gelling or lack of gelling is used as an indication of the spreading ability of the lubricant when it hits the hot cylinder it is being used to lubricate.
• a cylinder at a temperature of 190 C. when hit by the commercial lubricant of Table II would cause the lubricant to gel so as to interfere with the spreadability of the lubricant along the cylinder walls.
• the product of Example II will not form a gel at this temperature and as a result will remain fluid so that it can rapidly spread along the cylinder to more evenly Wet the cylinder with the lubricant.
• reaction mixture was then aged for an additional hour while stirring. About 70 ppm. of a silicone antifoamant was added.
• the reaction mixture was dehydrated by heating to a temperature of about 320 F. while blowing with dry nitrogen gas. The mixture was then filtered while hot (about 300 F.), using a filter aid, to remove excess calcium hydroxide and other insoluble materials. A clear, dark, reddish-brown material was produced.
• Part B Preparation of grease concentrate 10.77 parts of hydrated lime and 30.96 parts of mineral lubricating oil of 80 SUS viscosity at 210 F. were added to a steam-jacketed grease kettle and intimately mixed to a smooth slurry. While stirring, 39.2 parts of the oil solution of the calcium aminoalkyl nonylphenol of Part A was added to the kettle. Next, 19 parts of glacial acetic acid was added to the kettle slowly while: maintaining the temperature of the grease composition below 200 F.
• Part C A finished lubricant was obtained by adding to the product of Part B above, additional mineral lubricating oil of 80 SUS 210 F.
• a lubricant suitable for lubrication of marine diesel engines comprising a major amount of mineral lubricating oil and about 5 to 12 wt. percent of anhydrous mixed calcium salts of acetic acid and aminoalkyl phenol in a ratio of to 15 molar equivalent proportions of acetic acid per molar equivalent proportion of aminoalkyl phenol, said anhydrous mixed salts being prepared by dehydrating by heating a mixture of calcium salt of said aminoalkyl phenol and acetic acid neutralized with lime in situ in said oil, said aminoalkyl phenol being the condensation reaction product of aldehyde, polyamine and a phenol reacted in a molar proportion of about 0.5 to 2.0 moles of aldehyde per nitrogen atom present in the polyamine and about equi-molar proportions of aldehyde and phenol, wherein said aldehyde is a C to C aldehyde, wherein said polyamine is selected from the group consisting of polyamines of the general formula:
• R is a C to C divalent hydrocarbon radical and n is an integer of 1 to 10, and polymers of ethylene imine having a molecular weight of about 1,000 to 40,000 and wherein said phenol is selected from the group consisting of phenol and alkyl phenols having 4 to 20 carbon atoms in each alkyl group.
• a marine diesel lubricant consisting essentially of mineral lubricating oil and about 5 to 12 wt. percent anhydrous co-neutralized and co-dehydrated calcium salts of about 10 to 15 mole equivalent proportions of acetic acid and a mole equivalent proportion of an aminoalkyl alkylphenol prepared by the reaction of molar proportions of formaldehyde and nonyl phenol further reacted with a one-half molar proportion of ethylene diamine.

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• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• General Chemical & Material Sciences (AREA)
• Oil, Petroleum & Natural Gas (AREA)
• Organic Chemistry (AREA)
• Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
• Lubricants (AREA)

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  • GB GB1053646D patent/GB1053646A/en active Active
• 1962
  • 1962-09-24 US US226777A patent/US3230169A/en not_active Expired - Lifetime

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