US321191A - Thomas e - Google Patents
Thomas e Download PDFInfo
- Publication number
- US321191A US321191A US321191DA US321191A US 321191 A US321191 A US 321191A US 321191D A US321191D A US 321191DA US 321191 A US321191 A US 321191A
- Authority
- US
- United States
- Prior art keywords
- skins
- oil
- leather
- glazed
- naphtha
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 210000003491 Skin Anatomy 0.000 description 23
- 239000010985 leather Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 8
- 239000004519 grease Substances 0.000 description 5
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 4
- 235000015450 Tilia cordata Nutrition 0.000 description 4
- 235000011941 Tilia x europaea Nutrition 0.000 description 4
- 239000004571 lime Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000004040 coloring Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- HCBIBCJNVBAKAB-UHFFFAOYSA-N Procaine hydrochloride Chemical compound Cl.CCN(CC)CCOC(=O)C1=CC=C(N)C=C1 HCBIBCJNVBAKAB-UHFFFAOYSA-N 0.000 description 1
- 210000002268 Wool Anatomy 0.000 description 1
- -1 alum Substances 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000037336 dry skin Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000000266 injurious Effects 0.000 description 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000012261 resinous substance Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/32—Material containing basic nitrogen containing amide groups leather skins
Definitions
- My invention relates to that class of leather which is commercially known as French glazed kid, and which is chiefly employed in the manufacture of ladies fine shoes.
- the object of my invention is to obtain a glazed-kid leather which shall combine, with a perfectly-glazed surface of the highest finish, all the suppleness, strength, and toughness of the best oil-tanned leather, and which shall consequently be free from the objectionable tendency to crack under strain, which, as stated, is inherent in all the glazed alumtanned shoe-leather heretofore manufactured.
- The'skins are then removed to a second clean bath of pure naphtha, and drenched therein as in the first case; and this operation of subjecting the skins to afresh supply of naphtha in a clean Vessel is repeated again and again until the naptha in which the skins are last placed will remain pure, and so far unaffected thereby as not to show upon proper test the least trace of oil or grease.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Description
UNITED STATES PATENT OE'ETCE.
THOMAS R. CLARK, OF NEXV YORK, N. Y.
MANUFACTURE OF GLAZED LEATHER.
SPECIFICATION forming part of Letters Patent No. 321,191, dated June 30, 1885.
' Application filed November 28, 1884. (No specimens.)
To all whom it may concern.-
as is well known to the art, to produc) a fine Be it known that I, THOMAS R. CLARK, of black glazed or'polished surface.
the city, county, and State of New York, have invented a new and useful Improvement in the Manufacture of Glazed Leather; and I do hereby declare that the following is a full and exact description thereof.
My invention relates to that class of leather which is commercially known as French glazed kid, and which is chiefly employed in the manufacture of ladies fine shoes.
In the manufacture of this class of leather the presence of any trace of oil or grease in the skin is fatal to the production thereon of the fine glazed surface constituting its distinguishing characteristic, and for which it is so highly prized. Heretofore, consequently, glazed-kid leather has been manufactured chiefly of skins tawed with lime, alum, and salt, and occasionally of skins tanned with bark by processes involving the use of lime, the use of skins tawed with oil being wholly discarded. It is, however; well known that the fiber of the skins is measurably weakened by the use of lime in tawing the same, and that for this reason all the glazed kid heretofore produced is lacking to a cetain extent in toughness,and also cracks upon its glazed surface to a greater or less degree.
The object of my invention is to obtain a glazed-kid leather which shall combine, with a perfectly-glazed surface of the highest finish, all the suppleness, strength, and toughness of the best oil-tanned leather, and which shall consequently be free from the objectionable tendency to crack under strain, which, as stated, is inherent in all the glazed alumtanned shoe-leather heretofore manufactured. I have, as the result of a long-continued series of experiments, attained my object by first subjecting skins which have been thoroughly tanned or tawed by any of the customary processes, in which the skin is toughened and cured by means of oil or grease, or compounds of oil or of grease, to the detergent action of naphtha, or any of its known equivalents, the skin being completely drenched in successive baths of pure naphtha, repeated until every trace of oil or grease or solvent animal matter is removed, and thereafter coloring and polishin g one side of the cleansed skin, in manner It is unnecessary to describe the mzthod of tanning or tawing the skins with oil to toughen and cure them, which constitutes the first step in my process, Any of the processes of oil-tanning, which are well known to the art, may be employed, and I select for my purpose such of the known processes as have been found to produce the toughest and most durable, as well as soft and supple leather, from the particular character of skins in hand. After the skin has been tawed with oil and finished to the white, and brought to a soft and pliable condition, I thoroughly dry the same to remove therefrom, so far as practicable, every trace of moisture, and then immerse the dry skins in a bath of pure refined naphtha-preferably the ordinary commercial naptha of about Baumor other equivalent volatile hydrocarbon oil, in a tank or close vessel, which is either made to revolve, or in which the skins are otherwise agitated by means of rotating arms or stirring devices, so as to in sure a rapid and thorough permeation thereof by the fluid. This agitation is continued until the naphtha becomes so fully saturated with the greasy and oily matter extracted thereby from the skins as that it will take up no more. The'skins are then removed to a second clean bath of pure naphtha, and drenched therein as in the first case; and this operation of subjecting the skins to afresh supply of naphtha in a clean Vessel is repeated again and again until the naptha in which the skins are last placed will remain pure, and so far unaffected thereby as not to show upon proper test the least trace of oil or grease. \Vhere the skins, in the original step of tanning or tawing, were treated with impure oil, it becomes necessary, at this stage of my process, to further purify them from the traces of gummy or resinous matters which have resisted the solvent action' of the pure naphtha, and for this purpose I subject such skins to a drenching with alcohol, wood spirits, ammonia, or other equivalent solvent for gummy and resinous substances. The skins are then hung up: and dried and staked out, preparatory to being colored, and are finally dyed and polished by the use of polishing-machines, in manner as is well known to the art, for the purpose of producing thereon the desired glazed surface.
The simplicity of my process renders it comparatively inexpensive, and as a result I obtain the finest quality of glazed leather, having all the toughness and desirable qualities which are inherent in oil-tanned skins, with a peculiar toughness in the glazed surface, which is wholly novel,and has heretofore been deemed to be unattainable.
I am aware that old belting, which has become oily in use, and especially the card leather used in woolen-mills, and which becomes completely saturated with oil from the wool, has been cleansed and the oil extracted therefrom by first warming the leather, then immersing it in naphtha, and, after letting it stand for a few hours, submitting it to pressure. I do not,thereibre,claim the use of naphtha in extracting oil from leather for cleansing the same, and recovering the oil, my use of naphtha being merely one ofa series ofsteps in a novel process for converting skins,tawed with oil or oily compounds without the use of lime or other chemicals injurious to the fiber of the skin, into an exceedingly tough and suple glazed leather, such as has not heretofore been produced.
subjecting them to repeated drenchings in.
successive baths of clean naphtha until fully cleansed and whitened; fourth, washing them in alcohol, or an equivalentsolvent; and, fifth, drying and staking the same preparatory to coloring and finishing them.
In testimony whereof I have signed my name to this specification in the presence of two subscribing witnesses.
THOS. R. CLARK.
Vitnesses:
A. PEYROUNET, H. LORENZ.
Publications (1)
Publication Number | Publication Date |
---|---|
US321191A true US321191A (en) | 1885-06-30 |
Family
ID=2390331
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US321191D Expired - Lifetime US321191A (en) | Thomas e |
Country Status (1)
Country | Link |
---|---|
US (1) | US321191A (en) |
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0
- US US321191D patent/US321191A/en not_active Expired - Lifetime
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