US3202598A - Electrolytic polishing tool - Google Patents

Electrolytic polishing tool Download PDF

Info

Publication number
US3202598A
US3202598A US267106A US26710663A US3202598A US 3202598 A US3202598 A US 3202598A US 267106 A US267106 A US 267106A US 26710663 A US26710663 A US 26710663A US 3202598 A US3202598 A US 3202598A
Authority
US
United States
Prior art keywords
ring
tube
electrode
electrolyte
tool
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US267106A
Inventor
Loren C Covington
Robert L Powell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Titanium Metals Corp
Original Assignee
Titanium Metals Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Titanium Metals Corp filed Critical Titanium Metals Corp
Priority to US267106A priority Critical patent/US3202598A/en
Application granted granted Critical
Publication of US3202598A publication Critical patent/US3202598A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25FPROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
    • C25F7/00Constructional parts, or assemblies thereof, of cells for electrolytic removal of material from objects; Servicing or operating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23HWORKING OF METAL BY THE ACTION OF A HIGH CONCENTRATION OF ELECTRIC CURRENT ON A WORKPIECE USING AN ELECTRODE WHICH TAKES THE PLACE OF A TOOL; SUCH WORKING COMBINED WITH OTHER FORMS OF WORKING OF METAL
    • B23H9/00Machining specially adapted for treating particular metal objects or for obtaining special effects or results on metal objects

Definitions

  • This invention relates to a tool including an electrode useful for electrolytic polishing of the interior of a metal tube.
  • Electrolytic machining is becoming accepted as a method for removing or shaping metal.
  • the process in general involves providing an electrode spaced close to the work piece, flooding the space between the work piece and the electrode with an electrolyte while passing electric current between the electrode and the work piece.
  • the work piece is connected to the positive pole of a source of direct electric current and the electrode to the negative pole.
  • Polishing requires a particularly effective control of an electrolytic machining action since the hills of the surface to be polished must be removed preferentially and with little or no metal removal in the valleys.
  • the electrolyte employed is to some extent corrosive and electrolysis is not easily limited to precise areas. Therefore, considerable difficulty has been encountered in electrolytic machining of metal tubes to provide a smooth, polished interior surface.
  • FIG. 1 is a vertical section of a tool embodying features of this invention.
  • FIG. 2 is a horizontal section of the tool of FIG. 1 taken along the line 22.
  • FIG. 3 is a horizontal section of the tool of FIG. 1 taken along the line 33.
  • means for supplying electrolyte are shown as flexible hose which may lead from a suitable source of electrolyte (not shown) and this generally will be capable of feeding electrolyte in required amounts under pressure.
  • Hose 10 is attached as by coupling 12 to the'threaded top of an electrically conductive electrolyte supply tube 14.
  • Electrolyte supply tube 14 may advantageously be fabricated of stainless steel which will provide the required electrical conductivity as well as resistance to corrosion by electrolyte.
  • Electrical connector 16 is held in firm electrical contact with supply tube 14 by lock nut 18 which tightens it against the bottom face of coupling 12 as shown.
  • nut 20 which bears on the top of sleeve 22 which surrounds supply tube 14 and which is preferably fabricated of rigid insulating material such as Bakelite or Micarta.
  • the bottom of sleeve 22 is tapered to engage the correspondingly tapered center hole of sealing ring 24 which is fabricated of insulating material such as polymerized tetraflour ethylene marketed commercially under the trade name Teflon.
  • Sealing ring 24 is of outside diameter to provide a sealing fit when engaged with the in terior wall of a metal tube 26 which is to be polished.
  • sealing ring 24 is indented to accommodate the top of electrolyte distributor ring 28 which is welded to the bottom of supply tube 14 as shown and which is provided with a plurality of radial passages 30 terminating in peripheral outlets and communicating centrally with the interior of supply tube 14.
  • distributor ring 28 may advantageously be fabricated of stainless steel for electrical conductivity and corrosion resistance.
  • Distributor ring 28 is additionally provided with a depending shank 32.
  • the electrode of the tool comprises electrode ring 34' threaded on to distributor ring shank 32.
  • the effective electrode area is actually the outer peripheral surface of electrode ring 34 since the bottom face of electrode ring 34 and shank 32 is insulated as described below.
  • Electrode ring 34 is of electrically conducting and corrosion resistant metal, preferably stainless steel or titanium. It is provided on its upper surface with groove 36 containing 0 ring 38 to provide good sealing between the top of electrode ring 34 and the adjacent surface of distributor ring 28.
  • the bottom of electrode ring 34 is substantially flush with the bottom of shank 32 depending from distributor ring 28. It will be seen that electrode ring 34 is connected to electrolyte supply tube 14 through distributor ring 28 and is disposed below distributor ring 28 considered with respect to the illustration of the tool shown in FIG. 1.
  • Means are provided to electrically insulate the lower surface of the electrode and this is accomplished in the embodiment illustrated by provision of disc 40 which completely covers the lower faces of electrode ring 34 and shank 32 and which is attached and maintained firmly in position by non-conductive means such as nylon screws 42 which engage threaded holes in electrode ring 34.
  • Disc 40 may, like sealing ring 24, advantageously be fabricated of a fluorinated ethylene plastic such as Teflon.
  • Sealing ring 24 is of size to provide sealing engagement with the tube interior sidewall as the tool is passed through the tube.
  • the diameter of sealing ring 24 will be selected to provide the required close sealing fit and additional slight adjustment of its outside diameter may be obtained by turning nut 20 which causes sleeve to exert more or less pressure on the tapered center hole of sealing ring 24, thus causing some expansion or contraction of its external diameter and tightness of fit in the tube.
  • Teflon type material is excellent for fabrication of this element since it is essentially rigid but has some slight flexibility; it is a good electrical insulator, has good corrosion resistance and also presents a slippery surface which is in a sense self-lubricating when passing through the interior of the tube 26 to be polished.
  • a good liquid seal between sealing ring 24 and tube 26 side wall is necessary to prevent electrolyte flowing out of outlets 30 in distributor ring 28 from flowing up the tube. Electrolyte is thereby caused to flow between electrode ring 34 and the side wall of tube 26 to insure proper electrolytic action.
  • Electrode ring 34 is of an outside diameter so that there is clearance all around it at the beginning of the operation of between about 0.002 and 0.01 inch. This provides necessary close spacing between electrode ring 34 and tube 26 sidewall. Proper alignment and centering of electrode ring 34 is maintained by adjacent sealing ring 24 which acts also as a centering and spacing element in addition to its sealing function.
  • a source of direct electric current is connected, the negative pole connected to connector 16 and thus connected through metallic electrolyte supply pipe 14 and distributor ring 28 to electrode ring 34, and the positive pole connected by any convenient means (not shown) and which will be understood by those skilled in the art, to the tube 26 to be polished.
  • the current source should be capable of supplying from about 500 to 1000 amperes per square inch of the peripheral area of electrode ring 34.
  • the tool is then placed in the tube 26 whose interior surface to be polished as shown in FIG. 1 and electrolyte supply hose connected to a source of electrolyte under pressure.
  • the composition of the electrolyte may vary according to various conditions including the metal of tube 26.
  • a suitable electrolyte for example for polishing titanium and stainless steel will be that particularly described and claimed in co-pending application Serial No. 218,499 filed August 22, 1962 by Loren C. Covington and containing about 20% NaCl, 0.4% NaF, 2.8% tartaric acid, 2.8% of 30% H 0 balance water, all percentages being by weight.
  • the speed of tool travel, the electric current employed and the electrolyte flow rate are opera-tively interdependent.
  • the current required increases with increase of tool travel speed due to increase in the rate of metal removal and electrolyte flow must be greater at higher tool travel speeds and higher current input to prevent boiling and resultant resistance increase.
  • Electrolyte flowing downwardly past electrode ring 34 may be recovered and recycled as will be apparent.
  • the tool of this invention promotes efiicient polishing action.
  • the sealing ring 24 keeps the unpolished surface of the tube 26 free from electrolyte thus directing the electrolyte flow from distributor ring past electrode ring 34.
  • Sealing ring 24 also acts to center electrode ring 34 to preserve proper spacing between it and the interior wall of tube 26.
  • the external diameter adjustment of sealing ring 24, by rotation of nut 20, is important to provide the proper sealing fit of this element.
  • a tool including an electrode useful for electrolytic polishing of the interior surface of a metal tube comprising;
  • an electrode including a ring of electrically conductive metal connected to said supply tube and disposed below said distributor ring, and,

Description

1965 1.. c. COVINGTON ETAL 3,202,598
ELECTROLYTIC POLISHING TOOL Filed March 22, 1963 INVENTORS. Loren C. Covington Robert L. Powell United States Patent 3,202,598 ELECTROLYTIC POLISHlNG TOOL Loren C. Covington, Henderson, and Robert L. Powell,
Las Vegas, Nev., assignors to Titanium Metals Corporation of America, New York, N.Y., a corporation of Delaware Filed Mar. 22, 1963, Ser. No. 267,106 1 Claim. (Cl. 204224) This invention relates to a tool including an electrode useful for electrolytic polishing of the interior of a metal tube.
Electrolytic machining is becoming accepted as a method for removing or shaping metal. The process in general involves providing an electrode spaced close to the work piece, flooding the space between the work piece and the electrode with an electrolyte while passing electric current between the electrode and the work piece. The work piece is connected to the positive pole of a source of direct electric current and the electrode to the negative pole.
Polishing requires a particularly effective control of an electrolytic machining action since the hills of the surface to be polished must be removed preferentially and with little or no metal removal in the valleys. The electrolyte employed is to some extent corrosive and electrolysis is not easily limited to precise areas. Therefore, considerable difficulty has been encountered in electrolytic machining of metal tubes to provide a smooth, polished interior surface.
It is therefore an object of this invention to provide an improved tool including an electrode for electrolytic polishing of the interior surface of a metal tube. Another object of this invention is to provide a tool including an electrode which, when employed in an electrolytic machining process, can produce a bright polished surface on the interior of a metal tube. These and other objects of this invention will be apparent from the following description thereof and from the annexed drawings, in which:
FIG. 1 is a vertical section of a tool embodying features of this invention.
FIG. 2 is a horizontal section of the tool of FIG. 1 taken along the line 22.
FIG. 3 is a horizontal section of the tool of FIG. 1 taken along the line 33.
Referring now to FIGS. 1, 2, and 3, and particularly to FIG. 1 on which the numerals identifying the various parts are referred to generally reading from top to bot tom, means for supplying electrolyte are shown as flexible hose which may lead from a suitable source of electrolyte (not shown) and this generally will be capable of feeding electrolyte in required amounts under pressure. Hose 10 is attached as by coupling 12 to the'threaded top of an electrically conductive electrolyte supply tube 14. Electrolyte supply tube 14 may advantageously be fabricated of stainless steel which will provide the required electrical conductivity as well as resistance to corrosion by electrolyte. Electrical connector 16 is held in firm electrical contact with supply tube 14 by lock nut 18 which tightens it against the bottom face of coupling 12 as shown.
Also threaded on a top part of supply tube 14 is nut 20 which bears on the top of sleeve 22 which surrounds supply tube 14 and which is preferably fabricated of rigid insulating material such as Bakelite or Micarta. The bottom of sleeve 22 is tapered to engage the correspondingly tapered center hole of sealing ring 24 which is fabricated of insulating material such as polymerized tetraflour ethylene marketed commercially under the trade name Teflon. Sealing ring 24 is of outside diameter to provide a sealing fit when engaged with the in terior wall of a metal tube 26 which is to be polished. The bottom of sealing ring 24 is indented to accommodate the top of electrolyte distributor ring 28 which is welded to the bottom of supply tube 14 as shown and which is provided with a plurality of radial passages 30 terminating in peripheral outlets and communicating centrally with the interior of supply tube 14. Like supply tube 14, distributor ring 28 may advantageously be fabricated of stainless steel for electrical conductivity and corrosion resistance. Distributor ring 28 is additionally provided with a depending shank 32.
The electrode of the tool comprises electrode ring 34' threaded on to distributor ring shank 32. The effective electrode area is actually the outer peripheral surface of electrode ring 34 since the bottom face of electrode ring 34 and shank 32 is insulated as described below. Electrode ring 34 is of electrically conducting and corrosion resistant metal, preferably stainless steel or titanium. It is provided on its upper surface with groove 36 containing 0 ring 38 to provide good sealing between the top of electrode ring 34 and the adjacent surface of distributor ring 28. The bottom of electrode ring 34 is substantially flush with the bottom of shank 32 depending from distributor ring 28. It will be seen that electrode ring 34 is connected to electrolyte supply tube 14 through distributor ring 28 and is disposed below distributor ring 28 considered with respect to the illustration of the tool shown in FIG. 1.
Means are provided to electrically insulate the lower surface of the electrode and this is accomplished in the embodiment illustrated by provision of disc 40 which completely covers the lower faces of electrode ring 34 and shank 32 and which is attached and maintained firmly in position by non-conductive means such as nylon screws 42 which engage threaded holes in electrode ring 34. Disc 40 may, like sealing ring 24, advantageously be fabricated of a fluorinated ethylene plastic such as Teflon.
In operation of the tool of this invention, it is first equipped with sized elements suitable for the particular diameter tube to be polished. Sealing ring 24 is of size to provide sealing engagement with the tube interior sidewall as the tool is passed through the tube. Ordinarily the diameter of sealing ring 24 will be selected to provide the required close sealing fit and additional slight adjustment of its outside diameter may be obtained by turning nut 20 which causes sleeve to exert more or less pressure on the tapered center hole of sealing ring 24, thus causing some expansion or contraction of its external diameter and tightness of fit in the tube. Teflon type material is excellent for fabrication of this element since it is essentially rigid but has some slight flexibility; it is a good electrical insulator, has good corrosion resistance and also presents a slippery surface which is in a sense self-lubricating when passing through the interior of the tube 26 to be polished. A good liquid seal between sealing ring 24 and tube 26 side wall is necessary to prevent electrolyte flowing out of outlets 30 in distributor ring 28 from flowing up the tube. Electrolyte is thereby caused to flow between electrode ring 34 and the side wall of tube 26 to insure proper electrolytic action.
Electrode ring 34 is of an outside diameter so that there is clearance all around it at the beginning of the operation of between about 0.002 and 0.01 inch. This provides necessary close spacing between electrode ring 34 and tube 26 sidewall. Proper alignment and centering of electrode ring 34 is maintained by adjacent sealing ring 24 which acts also as a centering and spacing element in addition to its sealing function.
With the tool set up as described above, a source of direct electric current is connected, the negative pole connected to connector 16 and thus connected through metallic electrolyte supply pipe 14 and distributor ring 28 to electrode ring 34, and the positive pole connected by any convenient means (not shown) and which will be understood by those skilled in the art, to the tube 26 to be polished. The current source should be capable of supplying from about 500 to 1000 amperes per square inch of the peripheral area of electrode ring 34.
The tool is then placed in the tube 26 whose interior surface to be polished as shown in FIG. 1 and electrolyte supply hose connected to a source of electrolyte under pressure. The composition of the electrolyte may vary according to various conditions including the metal of tube 26. A suitable electrolyte for example for polishing titanium and stainless steel will be that particularly described and claimed in co-pending application Serial No. 218,499 filed August 22, 1962 by Loren C. Covington and containing about 20% NaCl, 0.4% NaF, 2.8% tartaric acid, 2.8% of 30% H 0 balance water, all percentages being by weight.
With electrolyte flowing under 60 pounds-per square inch pressure at a rate of about 15 gallons per minute, electric power is turned on and the tool is moved through the tube 26 in an upward direction with reference to FIG. 1 and at a speed of /2-inch per minute, these values being typical of polishing the interior of a l /z-inch internal diameter stainless steel tube. The interior surf-ace of tube 26 over which electrode ring 34 has passed will be polished to a smooth, almost mirror finish.
The speed of tool travel, the electric current employed and the electrolyte flow rate are opera-tively interdependent. The current required increases with increase of tool travel speed due to increase in the rate of metal removal and electrolyte flow must be greater at higher tool travel speeds and higher current input to prevent boiling and resultant resistance increase.
Electrolyte flowing downwardly past electrode ring 34 (referring to FIG. 1) may be recovered and recycled as will be apparent.
The tool of this invention promotes efiicient polishing action. The sealing ring 24 keeps the unpolished surface of the tube 26 free from electrolyte thus directing the electrolyte flow from distributor ring past electrode ring 34. Sealing ring 24 also acts to center electrode ring 34 to preserve proper spacing between it and the interior wall of tube 26. The external diameter adjustment of sealing ring 24, by rotation of nut 20, is important to provide the proper sealing fit of this element.
Covering and insulating the bottom face of electrode ring 34, and any other connected bottom face exposed metal surface as the bottom face of shank 32, is also important. This prevents any electrolytic action between these surfaces and the interior of tube 26 which might roughen and etch the polished surface previously obtained. Surprisingly, we have found that flow of the electrolyte over the polished surface does no harm but any stray current as from the lower face of the electrode ring 34 will cause a frosted effect and destruction of the high polish otherwise obtained.
We claim:
A tool including an electrode useful for electrolytic polishing of the interior surface of a metal tube comprising;
(a) an electrically conductive electrolyte supply tube,
(b) means for connecting electric current to said supply tube,
(c) means for supplying electrolyte to the interior of said supply tube,
(d) an electrolyte distributor ring attached to a lower part of said supply tube having peripheral outlets communicating with the interior of said supply tube,
(e) a sealing ring of electrically insulating material surrounding said supply tube,
(f) means including a rigid sleeve surrounding said supply tube and having a tapered lower end engaging the walls of a central hole in said sealing ring and a nut threaded on to said supply tube bearing on the top of said sleeve thereby to adjust the outside diameter of sealing ring by pressure of the lower end of said sleeve against the wall of said central hole in said sealing ring, to provide sealing engagement of the said sealing ring with the interior of a metal tube to be polished,
(g) an electrode including a ring of electrically conductive metal connected to said supply tube and disposed below said distributor ring, and,
(h) electrical insulating means covering the lower face of said electrode.
References Cited by the Examiner UNITED STATES PATENTS 2,707,474 5/55 Wiginton l34166 X FOREIGN PATENTS 137,738 1/60 Russia.
JOHN H. MACK, Primary Examiner.
US267106A 1963-03-22 1963-03-22 Electrolytic polishing tool Expired - Lifetime US3202598A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US267106A US3202598A (en) 1963-03-22 1963-03-22 Electrolytic polishing tool

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US267106A US3202598A (en) 1963-03-22 1963-03-22 Electrolytic polishing tool

Publications (1)

Publication Number Publication Date
US3202598A true US3202598A (en) 1965-08-24

Family

ID=23017332

Family Applications (1)

Application Number Title Priority Date Filing Date
US267106A Expired - Lifetime US3202598A (en) 1963-03-22 1963-03-22 Electrolytic polishing tool

Country Status (1)

Country Link
US (1) US3202598A (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4174268A (en) * 1978-09-01 1979-11-13 Trw Inc. Electrode guide
US4318786A (en) * 1980-03-10 1982-03-09 Westinghouse Electric Corp. Electrolytic decontamination
US4369101A (en) * 1980-05-02 1983-01-18 Nukem Gmbh Apparatus for electropolishing tubes
EP0180892A1 (en) * 1984-11-09 1986-05-14 Siemens Aktiengesellschaft Apparatus for electropolishing the inner surfaces of tubes
US4645581A (en) * 1984-08-17 1987-02-24 Kraftwerk Union Aktiengesellschaft Apparatus for electropolishing the inner surface of U-shaped heat exchanger tubes
EP0247209A1 (en) * 1986-05-20 1987-12-02 Poligrat Gmbh Apparatus and process for electrochemically polishing the inner surfaces of pipes
US4806216A (en) * 1988-01-21 1989-02-21 The United States Of America As Represented By The United States Department Of Energy Electrochemical polishing of notches
US6203689B1 (en) * 1997-09-23 2001-03-20 Korea Advanced Institute Science And Technology Electropolishing apparatus and method
US6217726B1 (en) * 1997-05-22 2001-04-17 Therma Corporation, Inc. Tube inner surface electropolishing device with electrolyte dam
US6428681B1 (en) 2000-12-06 2002-08-06 Therma Corporation, Inc. System and method for reversing electrolyte flow during an electropolishing operation
US6660156B2 (en) 2000-02-02 2003-12-09 Therma Corporation, Inc. Pipe electropolishing apparatus using an electrolyte heater and cooler
US6712668B2 (en) 2000-12-06 2004-03-30 Therma Corporation, Inc. System and method for electropolishing nonuniform pipes
USD776935S1 (en) * 2014-05-12 2017-01-24 Ensitech IP Pty Limited Electrolytic brush
USD777442S1 (en) * 2014-05-12 2017-01-31 Ensitech IP Pty Limited Electrolytic brush

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2707474A (en) * 1953-04-20 1955-05-03 William K Wiginton Tools for baths of filter cleaners

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2707474A (en) * 1953-04-20 1955-05-03 William K Wiginton Tools for baths of filter cleaners

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4174268A (en) * 1978-09-01 1979-11-13 Trw Inc. Electrode guide
US4318786A (en) * 1980-03-10 1982-03-09 Westinghouse Electric Corp. Electrolytic decontamination
US4369101A (en) * 1980-05-02 1983-01-18 Nukem Gmbh Apparatus for electropolishing tubes
US4645581A (en) * 1984-08-17 1987-02-24 Kraftwerk Union Aktiengesellschaft Apparatus for electropolishing the inner surface of U-shaped heat exchanger tubes
EP0180892A1 (en) * 1984-11-09 1986-05-14 Siemens Aktiengesellschaft Apparatus for electropolishing the inner surfaces of tubes
US4772367A (en) * 1986-05-20 1988-09-20 Poligrat Gmbh Apparatus for and a method of electrochemically polishing pipe inside surfaces
EP0247209A1 (en) * 1986-05-20 1987-12-02 Poligrat Gmbh Apparatus and process for electrochemically polishing the inner surfaces of pipes
US4806216A (en) * 1988-01-21 1989-02-21 The United States Of America As Represented By The United States Department Of Energy Electrochemical polishing of notches
US6217726B1 (en) * 1997-05-22 2001-04-17 Therma Corporation, Inc. Tube inner surface electropolishing device with electrolyte dam
US6203689B1 (en) * 1997-09-23 2001-03-20 Korea Advanced Institute Science And Technology Electropolishing apparatus and method
US6660156B2 (en) 2000-02-02 2003-12-09 Therma Corporation, Inc. Pipe electropolishing apparatus using an electrolyte heater and cooler
US6428681B1 (en) 2000-12-06 2002-08-06 Therma Corporation, Inc. System and method for reversing electrolyte flow during an electropolishing operation
US6712668B2 (en) 2000-12-06 2004-03-30 Therma Corporation, Inc. System and method for electropolishing nonuniform pipes
USD776935S1 (en) * 2014-05-12 2017-01-24 Ensitech IP Pty Limited Electrolytic brush
USD777442S1 (en) * 2014-05-12 2017-01-31 Ensitech IP Pty Limited Electrolytic brush

Similar Documents

Publication Publication Date Title
US3202598A (en) Electrolytic polishing tool
US2363973A (en) Method of copper plating stainless steel cooking vessels
US3891531A (en) Electrolytic diaphragm cells including current connection means between the cell base and anode
US3485744A (en) Zirconium electrode for electro-chemical machining
KR101510042B1 (en) Rotational metal bar electropolishing device
US2329961A (en) Apparatus for electrolytic protection of vessels from corrosion
US3928167A (en) Improvements in methods of producing electrolytic anode assemblies
US4401540A (en) Apparatus for reducing end effect in anodes
US2412186A (en) Method of bright polishing stainless steel tubes
US3278411A (en) Electrolyzing electrode
US1159869A (en) Vapor electric device.
US2773821A (en) Composition for use in electropolishing
US3152057A (en) Electrolytic bridge assembly
US4305804A (en) Plating barrel contact
US3873434A (en) Corrosion control assembly
US2349356A (en) Holder for electrolytic deplating
US3138549A (en) Anode supporting assembly for cathodic protection
US3208928A (en) Reference electrode bridge assembly
US3729390A (en) Electrotinning process to prevent plating on the cathode contact roll
US3112554A (en) Process of manufacturing field-effect transistors
US2108978A (en) Rack
US1571948A (en) Electron-discharge device
US2010758A (en) Electrolytic condenser insulation
US3788964A (en) Arrangement for electro-chemical treatment of an electrically conductive workpiece
JPS5932590Y2 (en) Large iron electrode device for heat exchangers