US3157503A - Diazotype reproduction materials - Google Patents

Diazotype reproduction materials Download PDF

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Publication number
US3157503A
US3157503A US266231A US26623163A US3157503A US 3157503 A US3157503 A US 3157503A US 266231 A US266231 A US 266231A US 26623163 A US26623163 A US 26623163A US 3157503 A US3157503 A US 3157503A
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US
United States
Prior art keywords
support
layer
heat
diazotype
coated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US266231A
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English (en)
Inventor
Kosar Jaromir
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Keuffel and Esser Co
Original Assignee
Keuffel and Esser Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Keuffel and Esser Co filed Critical Keuffel and Esser Co
Priority to US266231A priority Critical patent/US3157503A/en
Priority to DE19641447738 priority patent/DE1447738A1/de
Priority to BE645320A priority patent/BE645320A/xx
Priority to NL6402882A priority patent/NL6402882A/xx
Priority to AT622465A priority patent/AT265016B/de
Priority to AT242264A priority patent/AT253928B/de
Priority to GB11669/64A priority patent/GB1060744A/en
Priority to FR967921A priority patent/FR1386060A/fr
Application granted granted Critical
Publication of US3157503A publication Critical patent/US3157503A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/52—Compositions containing diazo compounds as photosensitive substances
    • G03C1/61—Compositions containing diazo compounds as photosensitive substances with non-macromolecular additives
    • G03C1/615—Substances generating bases
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C1/00—Refining of pig-iron; Cast iron
    • C21C1/02—Dephosphorising or desulfurising
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28—Manufacture of steel in the converter
    • C21C5/42—Constructional features of converters
    • C21C5/46—Details or accessories
    • C21C5/4606—Lances or injectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01C—RESISTORS
    • H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material

Definitions

  • This invention relates to diazotype reproduction mat rials and to methods for their preparation and use, and refers more particularly to heat-developable two-compo nent photosensitive diazotype reproduction materials and methods for their preparation and use.
  • Diazotype reproduction materials are Widely used commercially because of their combined advantages of quality and low cost.
  • Two types are generally used: the semiwet developing type and the dry developing type.
  • Each has its own inherent disadvantage.
  • the handling of a liquid developer is a negative factor.
  • the dry developing type the machine requirements for confining and exhausting noxious ammonia fumes are negative factors.
  • the loading of concentrated ammonia water and the removal of spent ammonia water from the machine are disagreeable tasks in the daily use of dry developing machines.
  • Thermographic reproduction processes have been used to avoid or eliminate some of the disadvantages of the diazotype processes, but they possess other objectionable properties such as the retention of sensitivity to heat even after the desired reproduction has been made. In addition these materials are not necessarily photosensitive.
  • the present invention combines the advantages of the diazotype process with that of the thermographic process While avoiding some of the disadvantages of both.
  • the quality and low-cost of the diazotype process is combined with the simplicity of development of the thermographic process.
  • the use of liquid developers and gaseous ammonia is avoided, and the final reproduction is insensitivejo further application of heat.
  • one object is to provide a heat-developable photosensitive diazotype reproduction material which does not have the disadvantages of the prior art.
  • Another object of the present invention is to provide a heat-developable two-component photosensitive diazotype reproduction material.
  • Another object is to provide a diazotype reproduction material which is developable without the use of liquid developers or gaseous ammonia.
  • Another object is to provide a heat-developable reproduction material which, after development is stable to further undesirable development due to the application of heat.
  • Another object is to provide a method for the preparation of heat-developable two-component photosensitive diazotype reproduction material.
  • Another object is to provide a method for the use of heat-developable two-component photosensitive diazotype reproduction material.
  • Another object is to provide a developing sheet for the heat-development of a two-component photosensitive diazotype reproduction material.
  • Another object is to provide a method for the use of a developing sheet in the heat-development of a two-component photosensitive diazotype reproduction material.
  • Another object of the present invention is to provide a reproduction material which has good quality and low cost.
  • FIGURE 1 is a sectional view of a heat-developable ice two-component photosensitive diazotype reproduction material 16 comprising a support 11 and a heat-developable two-component photosensitive diazotype layerlZ coated on said support.
  • FIGURE 2 is a sectional view of a heat-developable two-component photosensitive diazotype reproduction material 29 comprising a support 21, a precoat layer 22 coated on said support, and a two component photosensitive diazotype layer 23 coated over said precoat layer on said support.
  • FIGURE 3 is a sectional view of a developing sheet 36 comprising a support 31 and a base-releasing agent 32 impregnated in said support in contact With a two-component photosensitive diazotype reproduction material 40 comprising a support 41 and a two-component photosensitive diazotype layer 42 coated on said support.
  • thermosensitive base-releasing agents of the present invention is a group of chemical structural formulas of the thermosensitive base-releasing agents of the present invention:
  • the base-releasing agent can be incorporated into the sensitized layer, into a separate precoat layer between the support and the sensitized layer, or it can be impregnated into a separate support to make a developing sheet. Compatibility with the other chemicals in the sensitizing solution determines Whether or not it can be incorporated into the various systems. Generally where it is incorporated with the sensi izing solution adjustments are required to prevent precoupling of the diazonium compound and the coupler. Base is released under the influence of heat.
  • the agent can either be coated on the same support in a precoat layer between the support and the sensitizing layer or it can ,be coated or impregnated into a separate support to form a developing sheet.
  • the base-releasing agents found to be suitable for the present invention are organic nitrogen compounds such 'as hexamethylenetetramine, thiosemicarbazide, and combinations of these with other organic nitrogen com,- pounds. Combinations of hexamethylenetetramine with semicarbazide hydrochloride for example were found to be satisfactory for purposes of the present invention.
  • thermosensitive diazotype reproduction materials with the base releasing agent in either the sensitizing layer or a precoat layer is the same. Both are exposed conventionally through a master to actinic radiations to form latent images in the reproduction material. the master, both can be heated in the temperature range between the heat activation temperature of the thermosensitive base-releasing agent and the scorchingtemperature of the reproduction material support. Temperatures of about 140 to 160 C. have been found to be adequate for development purposes.
  • the developing sheet In the case of a developing sheet, the developing sheet is placed in face-to-face contact with van exposed twocomponent photosensitive diazotype reproduction material and. the assembly heated preferably from the developing sheet side. The heat releases the base from the base-releasing agent and the base migrates to the exposed diazotype reproduction material and thus permits coupling to take place. Reproduction of the original image is thus effected.
  • Example 1 A support was coated with a sensitizing solution prepared according. to the following formula:
  • the sensitized support was exposed to actinic radiations through a master and then heated at 160 C. for a few seconds. A red-violet image corresponding to the master image was produced on a yellow background.
  • Example 2 Hexamethylenetetramine was used in the following formula to make a precoat solution:
  • Example 1 After removal of This was coated on a support and dried.
  • Example 3 Hexamethylenetetramine was used in the following solution to prepare a developing sheet:
  • Example 5 V A 'precoat solution was prepared according to the following formula:
  • a stock solution was prepared according to the following formula:
  • a sheet for the thermal development of a photosensitive diazo layer comprising a photosensitive diazonium compound and a coupler therefor, which comprises:
  • thermosensitive base-releasing agent selected from the group consisting of: hexamethylene tetramine, thiosemicarbazide, and mixtures of hexamethylene tetramine with one of the following: semicarbazide hydrochloride, carboxymethyl trimethyl ammonium chloride hydrazide, carbohydrazide, succinhydrazide, and acetone semicarbazone coated on said support,
  • a sheet for the thermal development of a photosensitive diazo layer comprising a photosensitive diazonium compound and a coupler therefor, which comprises:
  • a sheet for the thermal development of a photosensitive diazo layer comprising a photosensitive diazonium compound and a coupler therefor, which comprises:
  • thermosensitive base-releasing hexamethylene tetramine coated on said support between said support and said diazo layer thermosensitive base-releasing hexamethylene tetramine coated on said support between said support and said diazo layer.
  • a method for thermally developing a photosensitive diazo layer comprising a photosensitive diazonium compound and a coupler therefor, which comprises the steps of:
  • thermosensitive base-releasing agent a member selected from the group consisting of: hexamethylene tetramine, thiosemicarbazide, and mixtures of hexamethylene tetramine with one of the following: sernicarbazide hydrochloride, carboxymethyl trimethyl ammonium chloride hydrazine, carbohydrazide, succinhyclrazide, and acetone semicarbazone.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Heat Sensitive Colour Forming Recording (AREA)
  • Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
US266231A 1963-03-19 1963-03-19 Diazotype reproduction materials Expired - Lifetime US3157503A (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
US266231A US3157503A (en) 1963-03-19 1963-03-19 Diazotype reproduction materials
DE19641447738 DE1447738A1 (de) 1963-03-19 1964-03-14 Reproduktionsmaterial fuer die Diazotypie
BE645320A BE645320A (fr) 1963-03-19 1964-03-17
NL6402882A NL6402882A (fr) 1963-03-19 1964-03-18
AT622465A AT265016B (de) 1963-03-19 1964-03-19 Entwicklerbogen für die Wärmeentwicklung von lichtempfindlichem Zweikomponenten-Diazotypiematerial
AT242264A AT253928B (de) 1963-03-19 1964-03-19 Wärmeentwickelbares lichtempfindliches Zweikomponenten-Diazotypiematerial
GB11669/64A GB1060744A (en) 1963-03-19 1964-03-19 Improvements in and relating to diazotype reproduction
FR967921A FR1386060A (fr) 1963-03-19 1964-03-19 Matériel de reproduction pour la diazotypie

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US266231A US3157503A (en) 1963-03-19 1963-03-19 Diazotype reproduction materials

Publications (1)

Publication Number Publication Date
US3157503A true US3157503A (en) 1964-11-17

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US266231A Expired - Lifetime US3157503A (en) 1963-03-19 1963-03-19 Diazotype reproduction materials

Country Status (7)

Country Link
US (1) US3157503A (fr)
AT (2) AT253928B (fr)
BE (1) BE645320A (fr)
DE (1) DE1447738A1 (fr)
FR (1) FR1386060A (fr)
GB (1) GB1060744A (fr)
NL (1) NL6402882A (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3255011A (en) * 1963-05-31 1966-06-07 Gen Aniline & Film Corp Two-component diazotype photoprinting material susceptible to thermal development
US3318699A (en) * 1963-10-12 1967-05-09 Keuffel & Esser Co Process and material for the development of diazotype copies
US3389995A (en) * 1964-09-15 1968-06-25 Gen Aniline & Film Corp Two-component heat developable diazotypes containing amidine compounds
US3458314A (en) * 1963-09-25 1969-07-29 Keuffel & Esser Co Process and device for developing a two-component diazotype material
US3918974A (en) * 1970-05-01 1975-11-11 Mita Industrial Co Ltd Process for the diazo-type multicolor reproduction
WO1982002689A1 (fr) * 1981-02-13 1982-08-19 Jean J Robillard Procede de formation d'images en couleurs sur des materiaux textiles et films photosensibles utilises dans ce procede
US6280913B1 (en) 2000-06-13 2001-08-28 Eastman Kodak Company Photographic element comprising an ion exchanged photographically useful compound
CN114813722A (zh) * 2022-04-25 2022-07-29 中国科学院新疆理化技术研究所 一种检测乌洛托品的比色试剂

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2653091A (en) * 1950-01-31 1953-09-22 Rca Corp Photographic diazotype composition and heat development thereof
US2732299A (en) * 1952-07-22 1956-01-24 Light sensitive
US2774669A (en) * 1953-04-13 1956-12-18 Dick Co Ab Diazotype reproduction process
GB816601A (en) * 1954-07-09 1959-07-15 Arnold Tanenbaum Improvements in or relating to diazotype processes
FR1249913A (fr) * 1959-11-23 1961-01-06 Bauchet & Cie Ets Produit diazotype développable par la chaleur
US2982675A (en) * 1955-05-12 1961-05-02 Process Methods Corp Method of water- and grease-proofing paper products

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2653091A (en) * 1950-01-31 1953-09-22 Rca Corp Photographic diazotype composition and heat development thereof
US2732299A (en) * 1952-07-22 1956-01-24 Light sensitive
US2774669A (en) * 1953-04-13 1956-12-18 Dick Co Ab Diazotype reproduction process
GB816601A (en) * 1954-07-09 1959-07-15 Arnold Tanenbaum Improvements in or relating to diazotype processes
US2982675A (en) * 1955-05-12 1961-05-02 Process Methods Corp Method of water- and grease-proofing paper products
FR1249913A (fr) * 1959-11-23 1961-01-06 Bauchet & Cie Ets Produit diazotype développable par la chaleur

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3255011A (en) * 1963-05-31 1966-06-07 Gen Aniline & Film Corp Two-component diazotype photoprinting material susceptible to thermal development
US3458314A (en) * 1963-09-25 1969-07-29 Keuffel & Esser Co Process and device for developing a two-component diazotype material
US3318699A (en) * 1963-10-12 1967-05-09 Keuffel & Esser Co Process and material for the development of diazotype copies
US3389995A (en) * 1964-09-15 1968-06-25 Gen Aniline & Film Corp Two-component heat developable diazotypes containing amidine compounds
US3918974A (en) * 1970-05-01 1975-11-11 Mita Industrial Co Ltd Process for the diazo-type multicolor reproduction
WO1982002689A1 (fr) * 1981-02-13 1982-08-19 Jean J Robillard Procede de formation d'images en couleurs sur des materiaux textiles et films photosensibles utilises dans ce procede
US6280913B1 (en) 2000-06-13 2001-08-28 Eastman Kodak Company Photographic element comprising an ion exchanged photographically useful compound
CN114813722A (zh) * 2022-04-25 2022-07-29 中国科学院新疆理化技术研究所 一种检测乌洛托品的比色试剂

Also Published As

Publication number Publication date
AT253928B (de) 1967-04-25
FR1386060A (fr) 1965-01-15
NL6402882A (fr) 1964-09-21
DE1447738A1 (de) 1969-03-13
AT265016B (de) 1968-09-25
BE645320A (fr) 1964-09-17
GB1060744A (en) 1967-03-08

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