US3154930A - Refrigeration apparatus - Google Patents

Refrigeration apparatus Download PDF

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US3154930A
US3154930A US227368A US22736862A US3154930A US 3154930 A US3154930 A US 3154930A US 227368 A US227368 A US 227368A US 22736862 A US22736862 A US 22736862A US 3154930 A US3154930 A US 3154930A
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solution
absorber
generator
shell
refrigerant
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US227368A
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Aronson David
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Worthington Corp
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Worthington Corp
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Priority to US227368A priority Critical patent/US3154930A/en
Priority to FR941175A priority patent/FR1369016A/en
Priority to CH874163A priority patent/CH479032A/en
Priority to GB29930/63A priority patent/GB985958A/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B15/00Sorption machines, plants or systems, operating continuously, e.g. absorption type
    • F25B15/02Sorption machines, plants or systems, operating continuously, e.g. absorption type without inert gas
    • F25B15/06Sorption machines, plants or systems, operating continuously, e.g. absorption type without inert gas the refrigerant being water vapour evaporated from a salt solution, e.g. lithium bromide
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2315/00Sorption refrigeration cycles or details thereof
    • F25B2315/001Crystallization prevention
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/27Relating to heating, ventilation or air conditioning [HVAC] technologies
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]
    • Y02B30/62Absorption based systems

Definitions

  • This invention relates to refrigeration apparatus having improved design and construction features. It relates in particular to a vacuum absorption'machine which employs as the circulating absorbent a brine solution consisting of a hydrophilic salt in water which absorbs refrigerant water.
  • a salt brine as the absorbent in such an apparatus is found to be quite effective but often entails operating difficulty in that crystallization is likely to occur.
  • Crystallization of the absorbent solution in the system may occur under varied circumstances. When it does take place, crystals tend to accumulate in particular parts of the machine and thus interrupt free circulation of refrigerant. Crystallization normally occurs during the shut-down period, that is, when the temperature of the entire system is lowered sufiiciently' so that salt in the solution crystallizes. It also occurs frequently in a heat exchanger when air passing over the exchange surface is sufficiently cold to lower the temperature of the strong solution in the heat exchanger below the crystallization point. Sufiicient air leakage into the normally closed absorption system causes partial loss of vacuum and consequently overload of the system; this also may. lead to formation of hydrate crystals.
  • the basic units of an absorption system consist of an absorber, a generator, a condenser, an evaporator and a heat exchanger. These elements are connected by suitable piping, pumping and associated control means to define a closed refrigerant system.
  • the respective elements as shown extensively by the prior .art may be interconnected into a single unit or alternatively they may be interconnected or physically disposed as separate individual units. As a matter of practicality and to provide a commercial package, the units are preferably arranged in such manner as to take up as little volume as possible for the amount of refrigeration produced.
  • the present invention includes a new and novel arrangement of elements in an absorption machine utilizing a saline solution in such manner as to permit more eco nomical and efilcient use of space, and to reduce the hazards of crystallization.
  • This result is achieved primarily through the arrangement of the absorber and the generator which are disposed to encourage refrigerant in the system to gravitate downwardly toward the generator regardless of the load imposed on the unit.
  • Cooperative with this arrangement of parts is the unique control systern which automatically adjusts the flow rate of solution through the system by varying solution density in accordance with the load being imposed on the machine.
  • It is therefore a primary object of the invention to provide an absorption apparatus including essentially an absorber, a generator, a condenser, an evaporator and a heat exchanger connected in a novel circuit arrangement for circulating saline solution, which elements are physically arranged to define a simple compact unit.
  • a further objective is to provide an absorption unit of the type described which employs a saline solution with water as the refrigerant component, said unit being arranged to facilitate start-up and shutdown of the machine while minimizing crystallizing problems normally associated with the use of a saline type absorbent.
  • FIGURE 1 is a diagrammatic view of the absorption unit.
  • FIGURE 2 is a side elevation view in partial cross .section illustrating diagrammatically the arrangement of parts in the refrigeration system.
  • FIGURE 3 is a segmentary view in cross overflow portion of the absorber.
  • FIGURE 4 is a sideelevation view in partial cross section of an alternate arrangement of essential elements including enclosing "shells.
  • the invention in brief contemplates a novel absorption apparatus or refrigeration system including essentially an absorber, a generator, a condenser, an evaporator or chiller and a heat exchanger contained within evacuated shells and spatially arranged to provide a compact, efiicient unit.
  • the respective components are contained in suitable high or low absolute pressure casings in accordance with the function of the particular element in the system.
  • the absorber is positioned above and connected with the section of the generator permitting a gravitational flow of weak solution from the absorber to the generator to concentrate brine solution.
  • the absorber and the evaporator are disposed within a first low pressure shell enclosure whereby water vapor may flow to the absorber and be contacted by sprayed streams of a brine solution.
  • Condenser and generator elements are positioned in a high pressure second shell enclosure and relatively disposed with respect to each other to pass vaporized refrigerant to the condenser.
  • water vapors are boiled from Weak brine solution for the purpose of concentrating the latter. Vapor driven from the brine solution being concentrated is condensed in the indirectly cooled condenser located in the high pressure shell. Flow of condensate is then upward from the high pressure shell to the low pressure shell.
  • Condensate formed in the condenser pan is directed to the low pressure side of the system for cooling the chiller by evaporation.
  • the quantity of refrigerant circulated over heat transfer elements or tubes in the chiller, and the quantity of brine circulated over tubes in the absorber, is in excess of that required for evaporation or absorption in the respective units. Such excess circulation is deemed essential for, the purpose of wetting all heat exchange surfaces through which heat transfer must be made to chilled water or cooling water respectively.
  • the concentration of brine may be controlled by introduction of strong solution to the absorber through supplementary pumping means or by an ejector cooperative with pumping means'to draw concentrated solution into the weak solution circulatory system.
  • Means is also provided for gravity feeding a stream of weak solution from the absorber to the generator for the purpose of concentrating the solution.
  • This flow to the generator is varied as required to hold the concentration of absorbent at that value necessary to meet cooling load imposed on the machine. Since no surge or storage tank .for absorbent exists in the system, the withdrawal of weak solution from the absorber automatically results in its replacement by strong solution, although such replacement may not be on an equivalent one-to-one basis.
  • the preferred absorbent as being a lithium bromide Water solution. It is understood though that other similar hydrophilic saline solutions may be employed, with water being used as the refrigerant. In the various sectors of the cycle, solution will undergo changes and will be found in varied degrees of concentration.
  • weak solution as will be hereinafter useddefines a condition when the solution contains a large amount of refrigerant and is thus characterized by very weak absorbing properties.
  • strong solution on the other hand implies a condition in which there is a relatively low refrigerant content and consequently high absorption capability.
  • FIGURES l and 2 illustrate diagrammatically an absorption unit 16 of the type presently contemplated which includes an elongated shell '11 supported by legs 12 fixed to the underside.
  • the shell 11 may be a unitary, elongated body horizontally disposed, and preferably of welded construction having end plates including removable access openings, defining an air tight inner enclosure.
  • the shell may consist of a plurality of elongated adjacently disposed shell-like bodies so constructed and arranged to define a compact unit.
  • the present embodiment includes a single shell 11 having an upper chamber 13 and a lower chamber 14 separated by a pressure-tight partition 15 welded or fastened along opposite edges to the shell wall.
  • a pressure-tight partition 15 welded or fastened along opposite edges to the shell wall.
  • pumps 17 and 18 Fastened externally to the shell or to support members are pumps 17 and 18 and a heat exchanger 19 which through suitable conduit means are in communication with elements contained within the shell.
  • absorber 21 and evaporator 22 are shown positioned in the upper or lower pressure chamber 13 of shell 11.
  • Absorber 21 includes a liquid-holding tray-like receptacle 23 having an upturned edge 23', positioned substantially horizontally of the shell and extending the length thereof.
  • Tray 23 includes a solution holding sump 25 and is welded along one side to the inner wall of shell 11.
  • the upturned edge 23 is spaced inwardly of the shell wall forming a spray guard and vapor guide.
  • a cooling coil or tube bundle 24 positioned above tray 23 is provided with inlet 26 and outlet 27 for circulating water or other cooling fluid. This cooling water is then conducted to the tube side of the condenser and subsequently circulated through a cooling tower.
  • Conduit 28 connected with liquid holding sump 25 directs weak solution by gravity feed to inlet 17 of the absorber circulating pump 17 which in turn circulates weak solution by way of loop 30 to manifold 29 positioned above tube bundle 24.
  • Spray nozzles 31 inserted in manifold 29 direct streams of brine solution into heat exchange contact with the surface of tube bundle 24 effecting heat transfer to cooling water circulating therethrough.
  • This circulation of brine from the absorber into spray manifold 29 is a continuous process, the weak brine solution being supplemented by the addition of strong solution drawn from the generator as will be hereinafter described.
  • a liquid overflow or weir arrangement 36 connected to conduit 28' and positioned to receive an overflow of weak solution from tray 23.
  • This weir arrangement is an integral part of the absorber control system to pass an amount of solution therethrough in accordance with the load being imposed on the machine.
  • the Weir as shown communicates through conduit 28' directly to heat exchanger 19 positioned at the lower part of the machine.
  • Weir 36 is also communicated through a second parallel conduit 28" connected to conduit 28 with desuperheater 34 to preheat Weak solution prior to introduction into the generator.
  • weir 36 is at a sufiiciently high level in the lower pressure absorber 21 to permit a gravity flow down into the higher pressure generator. This difference in height is essential to account for the normal differential in operating pressures between absorber and generator and also to overcome frictional resistance of the piping and heat exchangers between the said parts.
  • weir 36 as shown in FIGURE 3 may consist of an upright tubular element threaded to the upper end of conduit 28'.
  • a plurality of inlet openings 36' transversing the wall of said element are so arranged and of such shape as to provide an increasing how of solution therethrough as the height of solution in sump 25 increases. tioned above the sump base to assure that some solution will always be present in the sump for circulation to absorberpump 17 even at minimum or no load conditions.
  • absorber 21 is positioned in the upper portion of lower pressure chamber 13. Therefore conduit 28' leading to heat exchanger 19 will require no pumping means but will be fed merely through the gravity head resulting from the difference in elevation of the absorber 21 above generator 38.
  • a minimum head diiference is maintained in order to overcome an expected generator head pressure of about 3.0 inches of mercury, as contrasted with the reduced pressure in the absorber. While theoretically no maximum pressure differential is prescribed, it is found that between the level of strong solution in the generator and the level of weak solution in the absorber at least about 2.5 feet should be maintained.
  • Generator 38 is located at the lower part of chamber 14 in shell 11, said shell thus defining a reservoir or pool for holding substantially the entire volume of absorbent brine solution in the system. This higher pressure portion of the system is normally maintained during operation at the above mentioned 3.0 inches of mercury pressure.
  • a heating coil or tube bundle 46 cooperative with shell 11 is provided with inlet header 47 and outlet header 48 for circulating stream from a boiler or other heat source of supply exterior to the absorption machine.
  • Control means such as a remotely operable valve 45 is interposed in the steam loop return leg to vary the outflow of steam condensate from coil 46 in response to the load imposed on the absorber.
  • Valve 45 may be controlled by sensing or monitoring means communicated with the chilled water coil to sense the condition of water leaving the evaporator.
  • the lowest portion of inlets 36 are posi-
  • the steam loop generally consists of tubes supported in the generator liquid holding portion, carrying steam at a temperature of about 240 F. into the generator 38 for the purpose of heating or boiling weak solution contained therein.
  • Such boiling permits vaporous refrigerant, that is water vapor, to rise from the generator and pass into heat exchange contact with the desuperheater coil 34 positioned thereabove, and then to pass on to the condenser.
  • Ejector I 54 is arranged and operated in conjunction with absorber circulating pump 17 and is preferably connected across the pump so that ejector inlet 56 communicates with the pump discharge 57, and ejector outlet 58 communicates with the pump suction 17'.
  • the overflow device 51 in the generator is so positioned as to maintain a substantially constant level of solution in the generator regardless of solution boiling rate. Although this liquid level will be maintained relatively constant, within slight limitations depending on the load, the rate of overflow of concentrated solution into heat exchanger 19 will increase as the load on the ma chine increases, due to the coacting operation of weir 36 which serves to vary the feed rate to generator 38 in accordance with liquid level in absorber holding sump The liquid level in holding sump 25 will rise as the boiling rate in generator 38 increases because of the increase .in volume of solution in generator resulting from the increased fraction of steam bubbles in the solution.
  • the total mass o-fsolution produces the change in flow rate mentioned above.
  • Concentrated brine is drawn to ejector suction inlet 53 through heat exchanger 19 for introduction into the absorbent pump circuit to combine with a flow of weak solution in lines 28 and 30 comprising the external absorption circulating loop.
  • Mixed solution is then carried to the upper part of the absorber to be sprayed into contact with refrigerant vapors.
  • solution in the various pipes and conduits connecting the respective components will also gravitate-to- ,ward the bottom of the machine. This is especially true and beneficial when the absorber is subject to emergency shut-down due to a power failure or other such contingency in that a gradual lowering of the temperature of the solution will not prompt crystallization throughout the machine but rather will permit such to occur only at a limited number of places including perhaps the generator.
  • generator 38 in eitect functions as an accumulator for at'least a large portion of solution in the entire circuit, automatic control of the machine in response to load variations will be reflected in the generator by a change in boiling rate and solution density. Increase or decrease in the boiling rate of the solutionas required will be such as to bring the system into balance with the de'mandplaced thereon.
  • Desuperheater 34 consisting of a tube bundle 64 is supported above and laterally to one side of generator 38 in the higher pressure section of shell 11.
  • Inlet 33 of desuperheater coil is connected through conduit 28" to conduit 28' to receive a portion of the flow ofweak solution from the :weir 36.
  • This flow in passing through the desuperheater coil receives heat by transfer from upwardly passing hot vaporous refrigerant prior-to the latter entering condenser 66. Heated solution in coil 64- is then directed through conduit 37 into generator 38 for boiling.
  • the desuperheater While the desuperheater is not considered essential to operation of the system, it is found when employed as herein described to increase overall efiiciency of the absorption unit by conserving heat which could be otherwise wasted.
  • the desuperheater as with previously described tube bundle elements, extends substantially longitudinally within elongated shell 11 and is carried by support brackets to define a passagefor hotrefrig'e nant vapors 'enteringthe condenser.
  • Condenser 66 is likewise positioned in the higher pressure lower portion 14of shell 11 above generator 38.
  • T he condenser includes a receptacle or tray-like element 71 extending longitudinally of the shell and fastened to the ,Wall thereof for holding condensate.
  • An upturned flange, 68 at the tray inner edge forms a vapor guide means adjacent the desuperheater tube 64 for directing .desuperheated vapor onto the top of the condenser tube bundle 69. and also forms the side of refrigerant reservoir 71?.
  • Condenser 66 may be of the single or multi-pass type as required.
  • Tube bundle 69' is providedwith inlet and outlet heads 72 and 73 which communicate with a source of condenser water or cooling fluid which as previously noted may flow directly through the absorber coil 24 or be'passed to a cooling tower or other heat exchange Ineans Y V Evaporator 22 as shown in FIGURES l and 2 is positioned in the lower pressure upper portion 13 of shell 11 extending in a transverse direction immediately below absorber 21.
  • a loop conduit 74 is in communication with the condenser tray 71159 receive condensate and-pass same upwardly for flashinginto evaporator 22.
  • This loop-as shown may be positioned external to the shell 11 and functions as a seal to prevent or at least limit enitrance of steam from the condenser to the low pressure evaporator. Normally, saturated condensate will be forced upwardsjby the high condenser pressure and will enter the evaporator. Entering condensate will then flash resulting in about 9% of steam entering with liquid.
  • evaporator or chiller 22 includes a tray-like.receptacle 76 having upturned lateral edges extending transversely of the shell 11 and fastened above partition 15 to hold a pool of refrigerant.
  • Conduit means connected to tray 76 communicates the refrigerant pool with pump 18 for circulating refrigerant to manifold header 78 positioned above the evaporator tube bundle 79.
  • Tube bundle is positioned directly over tray 76 to receive a spray of liquid refrigerant from nozzles in the manifold and is connected to the supply of liquid to be chilled.
  • manifold nozzles are positioned in the evaporator upper portion .to direct refrigerant onto the surface of tube bundle 79 to achieve maximum tube surface wetting and maximum evaporation effect.
  • Tube bundle 79 is provided with suitable irlet and outlet means connected to the supply of chilled liquid.
  • This chilled liquid is generally maintained within the range of about 45 to 55 F. and used primarily for air conditioning but is adaptable for use to other applications. Since the condition of chilled water is a reasonable measure of the load imposed on the absorption unit suitable temperature responsive means may be connected to the chiller circuit with means as previously mentioned for controlling operation of the steam condensate valve 45 in accordance with the load imposed on the machine.
  • the herein disclosed principles can be embodied in an arrangement of two distinctly separated shells for high and low pressures, interconnected by suitable conduit means.
  • the arrangement may embody a cylindrical upper shell housing the absorber 91 above the evaporator 92.
  • T he lower, high pressure shell 93 comprises an elongated rectangular closed chamber having longitudinal compartments.
  • Condenser 94 is positioned in the top compartment adjacent the intermediate positioned generator 95.
  • Heat exchanger '96 in the bottom compartment is again disposed to receive conducted heat from the generator.
  • a preferred means as herein indicated consists of the introduction of a controlled amount of steam into the generator in accordance with the load being imposed on the unit.
  • Novelty in the control system resides in the means by which such introduction of heat to the generator is automatically utilized to provide a variable flow rate of solution through the system by way of a variable density pool of solution in the generator.
  • Temperature sensing means in the downstream leg may include any of a number of commercial devices prsently on the open market for the purpose and continuously monitors the condition of water in the outlet side of tube bundle 79.
  • the temperature sensing mechanism includes for example an electrical, pneumatic or mechanical connection, which cooperates with valve 45 interposed in the downstream leg of steam coil 46.
  • Valve 45 is operable preferably automatically to vary the egress of condensate from tube bundle '46 in response to variations registered in the temperature sensing means.
  • Tube bundle 46 is arranged in the generator and so connected to the steam line that steam enters the tubes and condenser.
  • Valve 45 is interposed in the steam loop return line to vary the flow of steam in response to the load imposed on the absorber.
  • Valve 45 may be controlled by sensing or monitoring means communicated with the chilled water coil to sense the condition of water leaving the evaporator. This arrangement is effect inactivates a portion of the tube bundle 46 to decrease the available heattransfer surface thereof. That is, when valve 45 is throttled down, condensate forming in the lower tubes of tube bundle 46 blocks further flow of steam and thus limits the heat transfer portion to those tubes in the upper portion of the tube bundle.
  • valve 45 is set fully open to provide maximum steam flow to heat the solution contained in the generator 38. After a shut-down, virtually all of the solution will normally have drained to the generator and thus restrict crystallization on cooling down to this portion of the system. With introduction of steam, the brine solution will eventually reach the brine boiling point. A portion of the solution will then be boiled out and vapor passed upwardly into contact with desuperheater tubes 64 and flow thence to condenser 66.
  • Sfilf-balancing of the system to adjust for these varying load conditions is achieved as follows. If a heavier load is suddenly put on the machine while running at a particular rate, until the solution flow rate adjusts itself, the output temperature of chilled water will rise. This change in temperature will be detected in the downstream leg of coil 79 and thus effect an increased steam condensate rate through valve 45 whereby a more rapid rate of solution flow through the entire system is initiated.
  • the absorbent loop 3t) during any load operation will circulate weak refrigerant from absorber sump 25 through pump 17 and thence to spray manifold 29 for reintroduc tion as sprays to the absorber upper portion. Part of this flow is directed through ejector 54 connected across pump 17 to induce strong solution from heat exchanger 19 into the weak solution stream in the absorbent circuit. This mixing in effect concentrates the solution being sprayed into the absorber. For efficient operation, the rate of flow of brine sprayed into the absorber is maintained in excess of what is required to absorb vaporous water entering the absorber from the evaporator.
  • Condenser coil 69 circulates condensing water or liquid in a closed circuit with the absorber coil 24.
  • the pressure in this high pressure section of the system will be approximately 3.0 inches of mercury or thereabouts.
  • said refrigerant is directed into the seal conduit 74 having a loop section extending below the level of the condenser in order to maintain a liquid trap and thus minimize passage of steam to the evaporator 22.
  • Vapor from evaporator 22 will rise and be directed along the lower surface of tray 23, against the wall of shell 11,- and passed upwardly into absorber 21.
  • the temperature and pressure are sufficiently depressed to draw vapor from the evaporator.
  • Brine being directed from spray nozzles 31,0nto the surface of tube bundle 24 mixes with entering refrigerant vapor.
  • the vapor condenses, gives off heat of condensation and further dilutes the solution which now accumulates in tray 23.
  • the heat given oif by condensing vapors is carried away by water or other fluid circulatory means through coil 24 which then as previously mentioned may be directed to condenser coil 69.
  • the arrangement fiow control means in both the generator and the absorber is such to assure completely automatic adjustment of the system to any variation in load imposed thereon.
  • An absorption refrigeration machine of the vacuum type connected to form a closed saline solution circulatory system comprising; a first horizontally disposed elongated shell defining a higher pressure chamber, a generator cooperating with said shell holding a supply of strong solution, and a condenser disposed in and cooperating with said higher pressure shell to receive vaporized refrigerant from the generator to be condensed therein, a second horizontally disposed elongated shell defining a lower pressure chamber, an absorber cooperative with said second elongated shell and holding weak.
  • An absorption refrigeration machine defining a closed saline solution circulatory system comprising; a generator holding a pool of strong refrigerant solution to 'be vaporized, a. condenser to receiverefrigerant vapors from the generator and to condense the same, an elongated high pressure shell enclosing said generator and said condenser, an absorber holding a supply of weak refrigerant solution, an evaporator flashing refrigerant received from the condenser and having cooling coils therein for circulating chilled liquid, an elongated low pressure shell enclosing said absorber and said evaporator, said high and low pressure shells respectively being arranged relative to each other such that the absorber in said low pressure shell is positioned at an elevation sufficiently above said generator that the level of weak refrigerant solution in the absorber is above the surface of strong solution in the generator thus permitting a gravity flow tothe latter, a pump circuit including a pump means communicated with said absorber liquid holding portion to receive
  • first conduit means communicating the weak solution holding portion of said absorber with the pump and forming a portion of said pumping circuit
  • second conduit means communicating the weak refrigerant holding portion of 1 1 said absorber with the generator
  • third conduit means communicating the strong solution holding portion of said generator with the pump circuit to introduce a flow of strong solution into the stream of weak solution in said pumping circuit.
  • An absorption refrigeration machine defining a closed. saline solution circulatory system comprising a generator holding a pool' of absorbent solution tobe concentrated by vaporization, a condenser to receive refrigerant vapors from the generator and to condense same, an elongated high pressure shell enclosing said generator and condenser respectively, an absorber holding a supply of weak solution, an evaporator flashing refrigerant received from the condenser and having cooling coils therein for circulating chilled liquid, an elongated low pressure shell enclosing said absorber and evaporator, said high and low pressure shells being arranged relative to each other.
  • a pumping circuit including a pump communicated with said absorber liquid holding portion to receive a continuous stream of Weak solution and to spray said solution into the absorber, a first conduit forming a part of said pumping circuit and communicating the solution holding portion of said absorber with the pump suction overflow means positioned insaid absorber and having an inlet dispose d to receive liquid not passed to said first conduit, second conduit means communicating said overflow means with said generator for delivering a stream of weak refrigerant thereto, and a third conduit communicating the strong solution holding portion of said generator withthe pumping circuit to introduce a stream of strong solution to the weak solution in. said" pumping circuit.
  • An absorption refrigeration machine defining a closed saline solution circulatory system comprising; a generator holding a pool of absorbent solution to be concentrated by vaporization, a condenser to receive refrigerant vapors from the generator and to condense the same, an elongated high pressure shell enclosing said generator and condenser, an absorber holding a supply of Weak solution, an evaporator flashing refrigerant received from the condenser and having cooling coils therein for circulating chilled liquid, an elongated low pressure shell enclosing said absorber and evaporator, said-high pressure and low pressure shells being.
  • a pumping circuit including a pump having a suction side communicated with said absorber liquid holding portion to receive a continuous stream of weak solution aud'to spray said solution into the absorber, overflow means in said absorber having an inlet posi tioned to receive liquid not passed to said pumping circuit, a first conduit cornmunicatingthe weak solution holding portion of said absorber with the pump inlet and forming a part of said pumping circuit, a second conduit communicating said overflow means in the absorber with the generator to. conduct gravity. flow of weak solution to latter, overflow means positioned in saidgenerator to maintain a maximum level'of strong solutionmaintained therein, and
  • third conduit means communicating said overflow means in said generator with said pumping circuit to introduce a stream of strong solution into the weak solution circulating. in said. pumping circuit.
  • the pumping circuit includes a pump having inletand' outlet, the inlet communicated' with the weak solutionv holding. portion of said absorber, said pump outlet communicated with the absorber for: introducing streams of weak. refrigerant thereto, ejector means disposed in said pumping circuit across said pump, and said third conduit communicates. the strongsolution holdingportion of said generator with the suction inlet of said ejector.
  • an absorption refrigerationsystem employinga saline solution refrigerant, anelongated casing, having. end panels fixed thereto forming a pressure tight enclosure, a partition. extending longitudially of. the casing and having the. edges thereof.
  • the absorber overflow. means includes a weir arrangement having anoverflow. lip positioned above said'tray outlet at-a heightto. provide a maximum amount of solution in said absorben tray.
  • an absorption refrigeration system employing a saline. solution refrigerant, anelongated casing-having; end panels fixed' thereto and" forming a pressure tight enclosure, a partition extending longitudinally ofv the casing, and havingthe edges thereof fastened'tothe walls of. said casingdefiningan upper low pressure chamber'and a lower high pressure chamber, an absorber and an evaporator positioned in the. upper low pressure chamber, a generator and. condenser positioned in the lower high pressure chamber, said evaporator including a coil for circulating chilled water and positioned-to contact streams of refrigerant passed over said coil, temperature monitoring means positioned. in the downstream-side of said-coil circulating chilled.
  • said-generator including acoil havingan. inlet. connected to a source of steann. flow control means positioned in. the downstream leg of said coil for varying the baclc pressuretherein and-controlling the flow oflsteam through the coil, means communicating said. valve. with. saidtemperature: monitoring, means in the chilled water coil. toadjust the. flow of steam into saidgenerator coilin accordancewith the outlet temperature of water in said chilled coil, a first overflow means. positioned in saidgenerator and having an openingv to receive solution contained therein and to maintain said.
  • pumping means communicating said overflow means with said absorber forintroducing said concentrated solution from the genera- 33 tor into the absorber, and overflow means in said absorber positioned therein to receive weak refrigerant solution and to pass said solution via gravity flow to the generator.
  • overfiow means in said absorber comprises a weir apparatus adjacent one edge of said tray to receive excessive weak solution from the tray.
  • a self-adjusting absorption system for circulating a saline solution and including; an absorber, a generator, an evaporator and a condenser, an elongated casing enclosing said elements, a partition disposed longitudinally of the casing and fastened to a wall thereof defining low pressure chambers in the upper portion and a higher pressure chamber in the lower portion, said absorber including a tray holding weak solution, a sump receiving weak solution from said tray, a weir forming a portion of said tray to vary flow with the level of solution in the tray, pump means external of said casing and having an inlet and a discharge, said discharge being connected to the absorber for introducing sprayed streams of solution thereto, first conduit means communicating said sump with the pump inlet, said generator havin a strong solution holding portion, overflow means in said generator solution holding portion to maintain a maximum level of solution therein, second conduit means communicating said absorber weir to said generator for introducing a gravity fiow of excessive Weak solution therto,
  • an absorption refrigeration machine forming a closed circulatory system for saline solution the combination of a first horizontally disposed shell defining a higher pressure chamber, a generator cooperating with said first shell holding a supply of strong solution, and a condenser disposed in and cooperating with said higher pressure shell to receive vaporized refrigerant from the generator to be condensed therein, a second horizontally disposed shell defining a lower pressure chamber, an absorber cooperative with said second shell and holding weak solution, and an evaporator positioned in and cooperative with said lower pressure shell and arranged to pass refrigerant vapors to the absorber, said second shell being positinned with relation to the first shell to permit a gravity flow or" weak solution held in the absorber to fiow to the generator, a having its suction connected to the absorber to receive weal; solution therefrom and to recirculate solution to be sprayed into the absorber, conduit means communicating the weak solution holding portion of the absorber with the generator carryin a gravity stream of weak solution to

Description

Nov. 3, 1964 D. ARONSON 3,154,930
REFRIGERATION APPARATUS Filed Oct. 1, 1962 2 Sheets-Sheet 1 COQLING' TuWER DAVID ARONSON INVENTOR. BY 4% Nov. 3, 1964 D. ARONSON REFRIGERATION APPARATUS 2 Sheets-Sheet 2 Filed Oct. 1, 1962 O O o on 6o 0 4 q o a c n \o o o o o o low m o R o o o U o o m Am a E In /T R3 o 00 T6 M 6 u a 0 Am 0 R o 6 E0 W o M G o n m( D .R 0 A we "a E w V S n No B o E m D o n a o C PuMP REFRIG.
ABSORBER PUMP Fl G. 2
DAVID ARONSON INVENTOR. I )4 ML,
United States Patent 3,154,939 REFRIGERATIGN APPARATUS David Aronson, Upper Montclair, N.J., assignor to Worthington Corporation, Harrison, N.J., a corporation of Delaware Filed Oct. 1, 1962, Ser. No. 227,368 18 Claims. (Cl. 62-143) This invention relates to refrigeration apparatus having improved design and construction features. It relates in particular to a vacuum absorption'machine which employs as the circulating absorbent a brine solution consisting of a hydrophilic salt in water which absorbs refrigerant water.
A salt brine as the absorbent in such an apparatus is found to be quite effective but often entails operating difficulty in that crystallization is likely to occur. Crystallization of the absorbent solution in the system may occur under varied circumstances. When it does take place, crystals tend to accumulate in particular parts of the machine and thus interrupt free circulation of refrigerant. Crystallization normally occurs during the shut-down period, that is, when the temperature of the entire system is lowered sufiiciently' so that salt in the solution crystallizes. It also occurs frequently in a heat exchanger when air passing over the exchange surface is sufficiently cold to lower the temperature of the strong solution in the heat exchanger below the crystallization point. Sufiicient air leakage into the normally closed absorption system causes partial loss of vacuum and consequently overload of the system; this also may. lead to formation of hydrate crystals.
Normally, the basic units of an absorption system consist of an absorber, a generator, a condenser, an evaporator and a heat exchanger. These elements are connected by suitable piping, pumping and associated control means to define a closed refrigerant system. The respective elements as shown extensively by the prior .art may be interconnected into a single unit or alternatively they may be interconnected or physically disposed as separate individual units. As a matter of practicality and to provide a commercial package, the units are preferably arranged in such manner as to take up as little volume as possible for the amount of refrigeration produced.
The present invention includes a new and novel arrangement of elements in an absorption machine utilizing a saline solution in such manner as to permit more eco nomical and efilcient use of space, and to reduce the hazards of crystallization. This result is achieved primarily through the arrangement of the absorber and the generator which are disposed to encourage refrigerant in the system to gravitate downwardly toward the generator regardless of the load imposed on the unit. Cooperative with this arrangement of parts is the unique control systern which automatically adjusts the flow rate of solution through the system by varying solution density in accordance with the load being imposed on the machine.
It is therefore a primary object of the invention to provide an absorption apparatus including essentially an absorber, a generator, a condenser, an evaporator and a heat exchanger connected in a novel circuit arrangement for circulating saline solution, which elements are physically arranged to define a simple compact unit.
A further objective is to provide an absorption unit of the type described which employs a saline solution with water as the refrigerant component, said unit being arranged to facilitate start-up and shutdown of the machine while minimizing crystallizing problems normally associated with the use of a saline type absorbent.
It is a still further object of the invention to provide an absorption unit of the. type described which includes means for gravitational flow of solution to the generator to avoid crystallization particularly in the absorber section during shutdown.
It is a still further object to provide an apparatus of the type described in which a control means causes the rate of solution flow through the system to adjust automatically in accordance with the heat input to the generator.
I Other objects of the invention not specifically mentioned will become clear to one skilled in the art from the following description made in conjunction with the drawings, in which:
In the drawings: FIGURE 1 is a diagrammatic view of the absorption unit.
FIGURE 2 is a side elevation view in partial cross .section illustrating diagrammatically the arrangement of parts in the refrigeration system.
FIGURE 3 is a segmentary view in cross overflow portion of the absorber.
FIGURE 4 is a sideelevation view in partial cross section of an alternate arrangement of essential elements including enclosing "shells.
The invention in brief contemplates a novel absorption apparatus or refrigeration system including essentially an absorber, a generator, a condenser, an evaporator or chiller and a heat exchanger contained within evacuated shells and spatially arranged to provide a compact, efiicient unit. The respective components are contained in suitable high or low absolute pressure casings in accordance with the function of the particular element in the system. To utilize the presently disclosed control features, the absorber is positioned above and connected with the section of the generator permitting a gravitational flow of weak solution from the absorber to the generator to concentrate brine solution.
In the present embodiment of the invention the absorber and the evaporator are disposed within a first low pressure shell enclosure whereby water vapor may flow to the absorber and be contacted by sprayed streams of a brine solution. Condenser and generator elements are positioned in a high pressure second shell enclosure and relatively disposed with respect to each other to pass vaporized refrigerant to the condenser. In the generator refrigerant water vapors are boiled from Weak brine solution for the purpose of concentrating the latter. Vapor driven from the brine solution being concentrated is condensed in the indirectly cooled condenser located in the high pressure shell. Flow of condensate is then upward from the high pressure shell to the low pressure shell. Condensate formed in the condenser pan is directed to the low pressure side of the system for cooling the chiller by evaporation. The quantity of refrigerant circulated over heat transfer elements or tubes in the chiller, and the quantity of brine circulated over tubes in the absorber, is in excess of that required for evaporation or absorption in the respective units. Such excess circulation is deemed essential for, the purpose of wetting all heat exchange surfaces through which heat transfer must be made to chilled water or cooling water respectively. The concentration of brine may be controlled by introduction of strong solution to the absorber through supplementary pumping means or by an ejector cooperative with pumping means'to draw concentrated solution into the weak solution circulatory system. Means is also provided for gravity feeding a stream of weak solution from the absorber to the generator for the purpose of concentrating the solution. This flow to the generator is varied as required to hold the concentration of absorbent at that value necessary to meet cooling load imposed on the machine. Since no surge or storage tank .for absorbent exists in the system, the withdrawal of weak solution from the absorber automatically results in its replacement by strong solution, although such replacement may not be on an equivalent one-to-one basis.
The apparatus and its mode of operation is herein described in terms of high and low pressures. This terminology is merely for the purpose of comparative identification since in actuality this unit operates under vacuum. For example, under standard conditions, pressure in the absorber will approximately 0.3 inch mercury whereas that in the generator-condenser high pressure section will be about 3.0 inches mercury.
In the following description reference is made to the preferred absorbent as being a lithium bromide Water solution. It is understood though that other similar hydrophilic saline solutions may be employed, with water being used as the refrigerant. In the various sectors of the cycle, solution will undergo changes and will be found in varied degrees of concentration. For example, the term weak solution as will be hereinafter useddefines a condition when the solution contains a large amount of refrigerant and is thus characterized by very weak absorbing properties. The term strong solution on the other hand implies a condition in which there is a relatively low refrigerant content and consequently high absorption capability.
Under normal operating conditions weak solution will enter the generator at a concentration of from 55 to 61% and leave at about 66% concentration. It should be understood that any salt in the refrigerant is present only as contaminant and diminishes performance. Systems may however be designed to use a very weak brine to avoid freezing, but for normal air conditioning such is not the case. The condenser and evaporator will hold essentially pure refrigerant. The absorber includes a spray of solution and also a pool of the solution in concentrations varying from about 55% to 63%. It is further understood that as a matter of practicality the solution may also contain a small amount of a compatible rust inhibitor to avoid undue corrosion of metallic parts in the machine.
Referring to the drawings, FIGURES l and 2 illustrate diagrammatically an absorption unit 16 of the type presently contemplated which includes an elongated shell '11 supported by legs 12 fixed to the underside. The shell 11 may be a unitary, elongated body horizontally disposed, and preferably of welded construction having end plates including removable access openings, defining an air tight inner enclosure. Alternatively, the shell may consist of a plurality of elongated adjacently disposed shell-like bodies so constructed and arranged to define a compact unit.
As shown, the present embodiment includes a single shell 11 having an upper chamber 13 and a lower chamber 14 separated by a pressure-tight partition 15 welded or fastened along opposite edges to the shell wall. Fastened externally to the shell or to support members are pumps 17 and 18 and a heat exchanger 19 which through suitable conduit means are in communication with elements contained within the shell.
Referring to FIGURES 1 and 2, absorber 21 and evaporator 22 are shown positioned in the upper or lower pressure chamber 13 of shell 11. Absorber 21 includes a liquid-holding tray-like receptacle 23 having an upturned edge 23', positioned substantially horizontally of the shell and extending the length thereof. Tray 23 includes a solution holding sump 25 and is welded along one side to the inner wall of shell 11. The upturned edge 23 is spaced inwardly of the shell wall forming a spray guard and vapor guide. As shown, a cooling coil or tube bundle 24 positioned above tray 23 is provided with inlet 26 and outlet 27 for circulating water or other cooling fluid. This cooling water is then conducted to the tube side of the condenser and subsequently circulated through a cooling tower.
Conduit 28 connected with liquid holding sump 25 directs weak solution by gravity feed to inlet 17 of the absorber circulating pump 17 which in turn circulates weak solution by way of loop 30 to manifold 29 positioned above tube bundle 24. Spray nozzles 31 inserted in manifold 29 direct streams of brine solution into heat exchange contact with the surface of tube bundle 24 effecting heat transfer to cooling water circulating therethrough. This circulation of brine from the absorber into spray manifold 29 is a continuous process, the weak brine solution being supplemented by the addition of strong solution drawn from the generator as will be hereinafter described.
Referring to FIGURE 3, also associated with tray 23 in absorber 21 is a liquid overflow or weir arrangement 36 connected to conduit 28' and positioned to receive an overflow of weak solution from tray 23. This weir arrangement is an integral part of the absorber control system to pass an amount of solution therethrough in accordance with the load being imposed on the machine. The Weir as shown communicates through conduit 28' directly to heat exchanger 19 positioned at the lower part of the machine. Weir 36 is also communicated through a second parallel conduit 28" connected to conduit 28 with desuperheater 34 to preheat Weak solution prior to introduction into the generator.
As shown in the drawings, weir 36 is at a sufiiciently high level in the lower pressure absorber 21 to permit a gravity flow down into the higher pressure generator. This difference in height is essential to account for the normal differential in operating pressures between absorber and generator and also to overcome frictional resistance of the piping and heat exchangers between the said parts.
An embodiment of weir 36 as shown in FIGURE 3, may consist of an upright tubular element threaded to the upper end of conduit 28'. A plurality of inlet openings 36' transversing the wall of said element are so arranged and of such shape as to provide an increasing how of solution therethrough as the height of solution in sump 25 increases. tioned above the sump base to assure that some solution will always be present in the sump for circulation to absorberpump 17 even at minimum or no load conditions.
According to the invention absorber 21 is positioned in the upper portion of lower pressure chamber 13. Therefore conduit 28' leading to heat exchanger 19 will require no pumping means but will be fed merely through the gravity head resulting from the difference in elevation of the absorber 21 above generator 38. In order to overcome an expected generator head pressure of about 3.0 inches of mercury, as contrasted with the reduced pressure in the absorber, a minimum head diiference is maintained. While theoretically no maximum pressure differential is prescribed, it is found that between the level of strong solution in the generator and the level of weak solution in the absorber at least about 2.5 feet should be maintained.
Generator 38 is located at the lower part of chamber 14 in shell 11, said shell thus defining a reservoir or pool for holding substantially the entire volume of absorbent brine solution in the system. This higher pressure portion of the system is normally maintained during operation at the above mentioned 3.0 inches of mercury pressure. A heating coil or tube bundle 46 cooperative with shell 11 is provided with inlet header 47 and outlet header 48 for circulating stream from a boiler or other heat source of supply exterior to the absorption machine.
Control means such as a remotely operable valve 45 is interposed in the steam loop return leg to vary the outflow of steam condensate from coil 46 in response to the load imposed on the absorber. Valve 45 may be controlled by sensing or monitoring means communicated with the chilled water coil to sense the condition of water leaving the evaporator.
The lowest portion of inlets 36 are posi- The steam loop generally consists of tubes supported in the generator liquid holding portion, carrying steam at a temperature of about 240 F. into the generator 38 for the purpose of heating or boiling weak solution contained therein. Such boiling permits vaporous refrigerant, that is water vapor, to rise from the generator and pass into heat exchange contact with the desuperheater coil 34 positioned thereabove, and then to pass on to the condenser.
As water vapor is driven from the weak solution, residual solution in the generator becomes more concentrated and is conducted through an overflow means 51 communicated by conduit, 52 to the heat exchanger,
and thence through conduit 52 to ejector 54. f Ejector I 54 is arranged and operated in conjunction with absorber circulating pump 17 and is preferably connected across the pump so that ejector inlet 56 communicates with the pump discharge 57, and ejector outlet 58 communicates with the pump suction 17'. a Y
The overflow device 51 in the generator is so positioned as to maintain a substantially constant level of solution in the generator regardless of solution boiling rate. Although this liquid level will be maintained relatively constant, within slight limitations depending on the load, the rate of overflow of concentrated solution into heat exchanger 19 will increase as the load on the ma chine increases, due to the coacting operation of weir 36 which serves to vary the feed rate to generator 38 in accordance with liquid level in absorber holding sump The liquid level in holding sump 25 will rise as the boiling rate in generator 38 increases because of the increase .in volume of solution in generator resulting from the increased fraction of steam bubbles in the solution.
For the purpose of illustration, the total mass o-fsolution produces the change in flow rate mentioned above.
I This explanation must be modified by 'the' consideration that the concentration of solution in absorber and generator is subject to change with load conditions of the system. At light load the concentration ofsolution in the generator 38 and in the absorber will tend to be higher than at heavy load conditions. will shift the control characteristics of the Weir 36. The recycle rate of solution from absorber 21 to generator 38 is not sharply critical in terms of process requirements so that secondary influences can be tolerated without upsetting the basic machine control.
Concentrated brine is drawn to ejector suction inlet 53 through heat exchanger 19 for introduction into the absorbent pump circuit to combine with a flow of weak solution in lines 28 and 30 comprising the external absorption circulating loop. Mixed solution is then carried to the upper part of the absorber to be sprayed into contact with refrigerant vapors.
It may readily be seen that by positioning generator 38 ,at the lowest portion of the shell 11, or if in a diiferent shell, substantially below the absorber solution level, an
advantage is gained over what has been taught by the prior art. Most notably, brine solution will flow by gravity downward to accumulate in the generator 38.
Further, solution in the various pipes and conduits connecting the respective components will also gravitate-to- ,ward the bottom of the machine. This is especially true and beneficial when the absorber is subject to emergency shut-down due to a power failure or other such contingency in that a gradual lowering of the temperature of the solution will not prompt crystallization throughout the machine but rather will permit such to occur only at a limited number of places including perhaps the generator.
In that generator 38 is directly connected through coil 46 to the heat supply, there will be a minimum delay in starting up the machine since heat directed into the generator will be concentrated on the major portion of the solution. Thus, any crystallization will be overcome rapidly and result in a normally trouble-free start-up.
Since generator 38 in eitect functions as an accumulator for at'least a large portion of solution in the entire circuit, automatic control of the machine in response to load variations will be reflected in the generator by a change in boiling rate and solution density. Increase or decrease in the boiling rate of the solutionas required will be such as to bring the system into balance with the de'mandplaced thereon. I
Desuperheater 34 consisting of a tube bundle 64 is supported above and laterally to one side of generator 38 in the higher pressure section of shell 11. Inlet 33 of desuperheater coil is connected through conduit 28" to conduit 28' to receive a portion of the flow ofweak solution from the :weir 36. This flow in passing through the desuperheater coil receives heat by transfer from upwardly passing hot vaporous refrigerant prior-to the latter entering condenser 66. Heated solution in coil 64- is then directed through conduit 37 into generator 38 for boiling.
While the desuperheater is not considered essential to operation of the system, it is found when employed as herein described to increase overall efiiciency of the absorption unit by conserving heat which could be otherwise wasted. The desuperheater, as with previously described tube bundle elements, extends substantially longitudinally within elongated shell 11 and is carried by support brackets to define a passagefor hotrefrig'e nant vapors 'enteringthe condenser.
Condenser 66 is likewise positioned in the higher pressure lower portion 14of shell 11 above generator 38. T he condenser includes a receptacle or tray-like element 71 extending longitudinally of the shell and fastened to the ,Wall thereof for holding condensate. An upturned flange, 68 at the tray inner edge forms a vapor guide means adjacent the desuperheater tube 64 for directing .desuperheated vapor onto the top of the condenser tube bundle 69. and also forms the side of refrigerant reservoir 71?. Condenser 66 may be of the single or multi-pass type as required. Tube bundle 69'is providedwith inlet and outlet heads 72 and 73 which communicate with a source of condenser water or cooling fluid which as previously noted may flow directly through the absorber coil 24 or be'passed to a cooling tower or other heat exchange Ineans Y V Evaporator 22 as shown in FIGURES l and 2 is positioned in the lower pressure upper portion 13 of shell 11 extending in a transverse direction immediately below absorber 21. A loop conduit 74 is in communication with the condenser tray 71159 receive condensate and-pass same upwardly for flashinginto evaporator 22. This loop-as shown may be positioned external to the shell 11 and functions as a seal to prevent or at least limit enitrance of steam from the condenser to the low pressure evaporator. Normally, saturated condensate will be forced upwardsjby the high condenser pressure and will enter the evaporator. Entering condensate will then flash resulting in about 9% of steam entering with liquid.
It is understood that the light differential which exists between condenser 66 and evaporator 22 is such thatthe condenser pressure will be sufficiently great to overcome the head differential and frictional resistance .to force refrigerant water up into flash chamber 75 from which the refrigerant may then be'introduced directly into the v evaporator.
As a structural expedient this head difference between evaporator and condenser should not exceed about two feet and may be muchless depending on other structural features of the machine. 1 7' e i Evaporator or chiller 22 includes a tray-like.receptacle 76 having upturned lateral edges extending transversely of the shell 11 and fastened above partition 15 to hold a pool of refrigerant. Conduit means connected to tray 76 communicates the refrigerant pool with pump 18 for circulating refrigerant to manifold header 78 positioned above the evaporator tube bundle 79. Tube bundle is positioned directly over tray 76 to receive a spray of liquid refrigerant from nozzles in the manifold and is connected to the supply of liquid to be chilled. For this purpose manifold nozzles are positioned in the evaporator upper portion .to direct refrigerant onto the surface of tube bundle 79 to achieve maximum tube surface wetting and maximum evaporation effect. Tube bundle 79 is provided with suitable irlet and outlet means connected to the supply of chilled liquid.
This chilled liquid is generally maintained within the range of about 45 to 55 F. and used primarily for air conditioning but is adaptable for use to other applications. Since the condition of chilled water is a reasonable measure of the load imposed on the absorption unit suitable temperature responsive means may be connected to the chiller circuit with means as previously mentioned for controlling operation of the steam condensate valve 45 in accordance with the load imposed on the machine.
While the absorption machine and disposition of major components have been described in connection with essentially a single shell design having a pressure wall separating the high pressure section from the low pressure section, it is not intended that the invention be contingent wholly on the shell configuration.
For example, the herein disclosed principles can be embodied in an arrangement of two distinctly separated shells for high and low pressures, interconnected by suitable conduit means. As shown in FIGURE 4 for example, the arrangement may embody a cylindrical upper shell housing the absorber 91 above the evaporator 92.
T he lower, high pressure shell 93 comprises an elongated rectangular closed chamber having longitudinal compartments. Condenser 94 is positioned in the top compartment adjacent the intermediate positioned generator 95. Heat exchanger '96 in the bottom compartment is again disposed to receive conducted heat from the generator.
The pumping and piping means by which the absorber elements are connected is similar to what has been disclosed with respect to the previously described arrangement. This phase of the machine will therefore require no further elaboration.
It is readily seen however that the latter embodiment of the invention provides a compact grouping which is easily enclosed to form a unitary machine.
Operation and Control The presently disclosed arrangement of components permits the use of several means by which control of the machine might be accomplished. A preferred means as herein indicated consists of the introduction of a controlled amount of steam into the generator in accordance with the load being imposed on the unit. Novelty in the control system resides in the means by which such introduction of heat to the generator is automatically utilized to provide a variable flow rate of solution through the system by way of a variable density pool of solution in the generator.
The following description directed to the mode of operation will be made as related to a system in which steam is introduced into the generator under a head of about 12 psi. gauge, and water is the fluid to be chilled to about 45 F.
Under normal operating conditions, water to be chilled will be circulated through tube bundle 79 in chiller 22 communicated externally of casing 11 to a supply of water. Temperature sensing means in the downstream leg may include any of a number of commercial devices prsently on the open market for the purpose and continuously monitors the condition of water in the outlet side of tube bundle 79.
The temperature sensing mechanism includes for example an electrical, pneumatic or mechanical connection, which cooperates with valve 45 interposed in the downstream leg of steam coil 46. Valve 45 is operable preferably automatically to vary the egress of condensate from tube bundle '46 in response to variations registered in the temperature sensing means. Tube bundle 46 is arranged in the generator and so connected to the steam line that steam enters the tubes and condenser. Valve 45 is interposed in the steam loop return line to vary the flow of steam in response to the load imposed on the absorber. Valve 45 may be controlled by sensing or monitoring means communicated with the chilled water coil to sense the condition of water leaving the evaporator. This arrangement is effect inactivates a portion of the tube bundle 46 to decrease the available heattransfer surface thereof. That is, when valve 45 is throttled down, condensate forming in the lower tubes of tube bundle 46 blocks further flow of steam and thus limits the heat transfer portion to those tubes in the upper portion of the tube bundle.
At start-up of the machine, valve 45 is set fully open to provide maximum steam flow to heat the solution contained in the generator 38. After a shut-down, virtually all of the solution will normally have drained to the generator and thus restrict crystallization on cooling down to this portion of the system. With introduction of steam, the brine solution will eventually reach the brine boiling point. A portion of the solution will then be boiled out and vapor passed upwardly into contact with desuperheater tubes 64 and flow thence to condenser 66.
Under a steady load condition, the amount of heat passed into the generator 38 will be sufficient to maintain a steady solution boiling rate. This steady state for any particular load is achieved by means of the combined effect of reduced density of brine in the generator leading to increased quantity of brine in the absorber and thus greater flowof weak solution across the absorber weir 36. For an intermediary load, this rate will be such that for purposes of description it could be said that about half the solution is in the lower pressure shell while the remaining half is in the higher pressure portion. At maximum load on the other hand virtually all the solution will be in the upper low pressure absorber and evaporator while the generator holds a relatively small proportion..
Sfilf-balancing of the system to adjust for these varying load conditions is achieved as follows. If a heavier load is suddenly put on the machine while running at a particular rate, until the solution flow rate adjusts itself, the output temperature of chilled water will rise. This change in temperature will be detected in the downstream leg of coil 79 and thus effect an increased steam condensate rate through valve 45 whereby a more rapid rate of solution flow through the entire system is initiated.
At the higher rate of boil, solution in the generator will become less dense by virtue of intense bubble formation. To maintain the desired generator liquid level, strong solution will now flow through overflow arrangement 51 and pass through heat exchanger 19. This strong or concentrated overflow solution from the generator is now fed to suction inlet 53 of ejector 54 for injection into the absorption refrigerant circulation loop thus compensating for the overflow from absorber to generator.
The absorbent loop 3t) during any load operation will circulate weak refrigerant from absorber sump 25 through pump 17 and thence to spray manifold 29 for reintroduc tion as sprays to the absorber upper portion. Part of this flow is directed through ejector 54 connected across pump 17 to induce strong solution from heat exchanger 19 into the weak solution stream in the absorbent circuit. This mixing in effect concentrates the solution being sprayed into the absorber. For efficient operation, the rate of flow of brine sprayed into the absorber is maintained in excess of what is required to absorb vaporous water entering the absorber from the evaporator.
Consequently, under increasing load conditions, the rate of absorbent introduction for absorbing refrigerant vapor will become increased. The weak solution thereby formed will build up in the absorber tray 23 and in sump 25.
Gravity flow of weak solution from sump 25 through conduit 28 will be relatively constant to supply a steady circulatory flow. Excessive weak solution built up in tray 23 will enter the overflow weir 36.
Weak solution flowing over weir 36 flows under gravity head in two streams, one stream through conduit 28 passes directly to heat exchanger 19; the other stream is directed through conduit 28" to the inlet of desuperheater coil 64. It is seen then that for varied load conditions only a single self-adjustment in the cycle is made eifecting heat input to bring the system into balance with the load. This single valve adjustment is normally fully automatic and constitutes the sole moving part of the control system which could cause an inadvertent misfunction.
' In the instant control arrangement as previously noted, boiling of brine in the generator causes a portion of solution to pass off in vapor phase thus concentrating the brine remaining in the generator which will flow through ejector 54. Water vapor rising through the desuperheater 34 will transfer heat to weak solution passing therethrough from the absorber. This heat transfer lowers the temperature of the Water vapor entering the upper portion of condenser 66 prior to contact with condenser coil 69.
Condenser coil 69 circulates condensing water or liquid in a closed circuit with the absorber coil 24. The pressure in this high pressure section of the system will be approximately 3.0 inches of mercury or thereabouts. From tray 71 in the condenser 66 where condensed water vapor passes, said refrigerant is directed into the seal conduit 74 having a loop section extending below the level of the condenser in order to maintain a liquid trap and thus minimize passage of steam to the evaporator 22.
From loop 74 liquid refrigerant entering the low pressure circuit will flash cool into evaporator 22 containing chiller coil 79. This flashing of refrigerant into the evaporator serves to chill the refrigerant therein to a temperature of about 40 F. Tray 76 in the evaporator holds a pool of liquid refrigerant for circulation through refrigerant pump 18 to spray nozzles positioned above coil.
79. As refrigerant is sprayed over the surfaces of tube bundle 79, the tubes are maintained in the condition of being continuously wetted thus assuring an eificient heat transfer condition. Contact of refrigerant with the sur faces of coil 79 causes the refrigerant to vaporize as a result of heat being drawn from the chilled water. 7 The amount of refrigerant introduced to the evaporator both by circulation through the spray nozzles or through flashing is in excess of the requirements for vaporizing, but is needed to wet all heat transfer surfaces.
Vapor from evaporator 22 will rise and be directed along the lower surface of tray 23, against the wall of shell 11,- and passed upwardly into absorber 21. In the low pressure absorber, the temperature and pressure are sufficiently depressed to draw vapor from the evaporator. Brine being directed from spray nozzles 31,0nto the surface of tube bundle 24 mixes with entering refrigerant vapor. During absorption, the vapor condenses, gives off heat of condensation and further dilutes the solution which now accumulates in tray 23. The heat given oif by condensing vapors is carried away by water or other fluid circulatory means through coil 24 which then as previously mentioned may be directed to condenser coil 69.
The advantages realized by thepresent arrangement and the solution density control system based thereon are wide in their implications. Primarily, the unique arrangement substantially avoids inconveniences in operation arising from crystallization of solution in the mameans including a pump having a suction connected to.
a a 1O chine due to either emergency or normal shutdown. Further, the number of working parts or moving parts is reduced by elimination of at least one pump, a feature which reduces maintenance costs as well as original costs. Also, the arrangement fiow control means in both the generator and the absorber is such to assure completely automatic adjustment of the system to any variation in load imposed thereon.
' It is understood that certain changes and modifications may be made in the disclosed method and apparatus by those skilled in the art without departing from the spirit and scope of the invention.
What is claimed is:
1. An absorption refrigeration machine of the vacuum type connected to form a closed saline solution circulatory system comprising; a first horizontally disposed elongated shell defining a higher pressure chamber, a generator cooperating with said shell holding a supply of strong solution, and a condenser disposed in and cooperating with said higher pressure shell to receive vaporized refrigerant from the generator to be condensed therein, a second horizontally disposed elongated shell defining a lower pressure chamber, an absorber cooperative with said second elongated shell and holding weak.
solution, and an evaporator positioned in and cooperative with said lower pressure shell and arranged to pass refrigerant vapors to the absorber, said second shell being positioned with relation to the first shell to permit a gravity flow of weak solution from the absorber to the generator, conduit means communicating the weak solution holding portion of said absorber with the generator for conducting said gravity flow of weak solution, and pumping said absorber and to said generator respectively and receiving streams of solution therefrom, said pump having a discharge outlet connected to said absorber and passing said solution thereto.
' 2. In an absorption refrigeration machine substantially as defined in claim 1 wherein the second shell defining a low pressure chamber is positioned above said first shell defining a high pressure chamber to permit gravity flow of weak solution held in the absorber to pass to the generator against the high pressure of said first shell.
3. In an absorption refrigeration machine substantially as defined in claim 1 wherein said low pressure second shell is positioned above the high pressure first shell a suflicient distance such that the level of weak solution held in the'absorber is above the level of strong solution held in the generator a distance not substantially less than about S'feet.
.4. An absorption refrigeration machine defining a closed saline solution circulatory system comprising; a generator holding a pool of strong refrigerant solution to 'be vaporized, a. condenser to receiverefrigerant vapors from the generator and to condense the same, an elongated high pressure shell enclosing said generator and said condenser, an absorber holding a supply of weak refrigerant solution, an evaporator flashing refrigerant received from the condenser and having cooling coils therein for circulating chilled liquid, an elongated low pressure shell enclosing said absorber and said evaporator, said high and low pressure shells respectively being arranged relative to each other such that the absorber in said low pressure shell is positioned at an elevation sufficiently above said generator that the level of weak refrigerant solution in the absorber is above the surface of strong solution in the generator thus permitting a gravity flow tothe latter, a pump circuit including a pump means communicated with said absorber liquid holding portion to receive a continuous stream of weak solution and to. spray said solution into the absorber, first conduit means communicating the weak solution holding portion of said absorber with the pump and forming a portion of said pumping circuit, second conduit means communicating the weak refrigerant holding portion of 1 1 said absorber with the generator, and third conduit means communicating the strong solution holding portion of said generator with the pump circuit to introduce a flow of strong solution into the stream of weak solution in said pumping circuit.
5. An absorption refrigeration machine defining a closed. saline solution circulatory system comprising a generator holding a pool' of absorbent solution tobe concentrated by vaporization, a condenser to receive refrigerant vapors from the generator and to condense same, an elongated high pressure shell enclosing said generator and condenser respectively, an absorber holding a supply of weak solution, an evaporator flashing refrigerant received from the condenser and having cooling coils therein for circulating chilled liquid, an elongated low pressure shell enclosing said absorber and evaporator, said high and low pressure shells being arranged relative to each other. such that the absorber in said low pressure shell is positioned at an elevation sufliciently above said generator that the level of weak refrigerant solution in the absorber is above the surface of strong solution in the generator thus permitting a gravity flow of solution to the latter, a pumping circuit including a pump communicated with said absorber liquid holding portion to receive a continuous stream of Weak solution and to spray said solution into the absorber, a first conduit forming a part of said pumping circuit and communicating the solution holding portion of said absorber with the pump suction overflow means positioned insaid absorber and having an inlet dispose d to receive liquid not passed to said first conduit, second conduit means communicating said overflow means with said generator for delivering a stream of weak refrigerant thereto, and a third conduit communicating the strong solution holding portion of said generator withthe pumping circuit to introduce a stream of strong solution to the weak solution in. said" pumping circuit.
6.. An absorption refrigeration machine defining a closed saline solution circulatory system comprising; a generator holding a pool of absorbent solution to be concentrated by vaporization, a condenser to receive refrigerant vapors from the generator and to condense the same, an elongated high pressure shell enclosing said generator and condenser, an absorber holding a supply of Weak solution, an evaporator flashing refrigerant received from the condenser and having cooling coils therein for circulating chilled liquid, an elongated low pressure shell enclosing said absorber and evaporator, said-high pressure and low pressure shells being. arranged relative to each other such that the absorber in said low pressure shell is positioned at an elevation sufficiently above said generator that the level of weak refrigerant solution in the absorber is above the surface of strong solution held in the generator permitting a gravity flow of said weak solution to the latter, a pumping circuit includinga pump having a suction side communicated with said absorber liquid holding portion to receive a continuous stream of weak solution aud'to spray said solution into the absorber, overflow means in said absorber having an inlet posi tioned to receive liquid not passed to said pumping circuit, a first conduit cornmunicatingthe weak solution holding portion of said absorber with the pump inlet and forming a part of said pumping circuit, a second conduit communicating said overflow means in the absorber with the generator to. conduct gravity. flow of weak solution to latter, overflow means positioned in saidgenerator to maintain a maximum level'of strong solutionmaintained therein, and
third conduit means communicating said overflow means in said generator with said pumping circuit to introduce a stream of strong solution into the weak solution circulating. in said. pumping circuit.
7. In an absorption refrigeration machine substantially as defined in claim 4-wherein the absorber and the evaporatorpositioned'in the lowpressure shell are so disposed that the evaporator is beneath the absorber.
8. In an absorption refrigeration machine substantially as defined in claim 4 wherein the condenser and thegenerator heldin saidhigh pressure chamber are so disposed that the condenser is positioned above the generator.
9; In an absorption refrigeration machine substantially as defined'in claim 4 wherein said second conduit means. and third conduit means are positioned'in heat exchange. contact within a heat exchanger.
10. In an absorption refrigeration machine substantially as defined in claim 4 wherein. the pumping circuit includes a pump having inletand' outlet, the inlet communicated' with the weak solutionv holding. portion of said absorber, said pump outlet communicated with the absorber for: introducing streams of weak. refrigerant thereto, ejector means disposed in said pumping circuit across said pump, and said third conduit communicates. the strongsolution holdingportion of said generator with the suction inlet of said ejector.
11. In an absorption refrigerationsystem employinga saline solution refrigerant, anelongated casing, having. end panels fixed thereto forming a pressure tight enclosure, a partition. extending longitudially of. the casing and having the. edges thereof. fastened to'the casing wall defining upperand lower chambers, a generator and acondenser positioned in the lower chamber, said generator havinga portion holding a pool of concentrated solution, and overflow means positioned in said generator for receiving a portion of said solution, an evaporator and an absorber positioned in the upper of said chambers, said absorber having a tray holding Weak solution, an outlet, and overflow means'communicated with said tray and having an outlet positioned above said'tray outlet, a pumping circuit having a pump connected-to receive. weak solution from said absorber tray, and. to introduce streams of weak solution into the upper portion. of saidabsorber, first conduit means communicating. said absorber tray with the pump inlet, second conduit means communicating said absorber overflow means to said generator, and third conduit means communicating the generator overflow to the pumping circuit for introducing a stream of concentrated solution into for mixture with the weak solutionin said pumping circuit.
12; In an absorption refrigeration system substantially as describedin claim 11 in which the absorber overflow. means includes a weir arrangement having anoverflow. lip positioned above said'tray outlet at-a heightto. provide a maximum amount of solution in said absorben tray.
13. In an absorption refrigeration system employing a saline. solution refrigerant, anelongated casing-having; end panels fixed' thereto and" forming a pressure tight enclosure, a partition extending longitudinally ofv the casing, and havingthe edges thereof fastened'tothe walls of. said casingdefiningan upper low pressure chamber'and a lower high pressure chamber, an absorber and an evaporator positioned in the. upper low pressure chamber, a generator and. condenser positioned in the lower high pressure chamber, said evaporator including a coil for circulating chilled water and positioned-to contact streams of refrigerant passed over said coil, temperature monitoring means positioned. in the downstream-side of said-coil circulating chilled. water, said-generator including acoil havingan. inlet. connected to a source of steann. flow control means positioned in. the downstream leg of said coil for varying the baclc pressuretherein and-controlling the flow oflsteam through the coil, means communicating said. valve. with. saidtemperature: monitoring, means in the chilled water coil. toadjust the. flow of steam into saidgenerator coilin accordancewith the outlet temperature of water in said chilled coil, a first overflow means. positioned in saidgenerator and having an openingv to receive solution contained therein and to maintain said. solution at a predetermined height, pumping means communicating said overflow means with said absorber forintroducing said concentrated solution from the genera- 33 tor into the absorber, and overflow means in said absorber positioned therein to receive weak refrigerant solution and to pass said solution via gravity flow to the generator.
14. In an absorption unit substantially as defined in claim 13 wherein the overfiow means in said absorber comprises a weir apparatus adjacent one edge of said tray to receive excessive weak solution from the tray.
15. A self-adjusting absorption system for circulating a saline solution and including; an absorber, a generator, an evaporator and a condenser, an elongated casing enclosing said elements, a partition disposed longitudinally of the casing and fastened to a wall thereof defining low pressure chambers in the upper portion and a higher pressure chamber in the lower portion, said absorber including a tray holding weak solution, a sump receiving weak solution from said tray, a weir forming a portion of said tray to vary flow with the level of solution in the tray, pump means external of said casing and having an inlet and a discharge, said discharge being connected to the absorber for introducing sprayed streams of solution thereto, first conduit means communicating said sump with the pump inlet, said generator havin a strong solution holding portion, overflow means in said generator solution holding portion to maintain a maximum level of solution therein, second conduit means communicating said absorber weir to said generator for introducing a gravity fiow of excessive Weak solution therto, and third conduit means for introducing strong solution into the weak solution in said first conduit means.
16. In an absorption refrigeration machine forming a closed circulatory system for saline solution the combination of a first horizontally disposed shell defining a higher pressure chamber, a generator cooperating with said first shell holding a supply of strong solution, and a condenser disposed in and cooperating with said higher pressure shell to receive vaporized refrigerant from the generator to be condensed therein, a second horizontally disposed shell defining a lower pressure chamber, an absorber cooperative with said second shell and holding weal; solution, and an evaporator positioned in and cooperative with said lower pressure shell and arranged to pass refrigerant vapors to the absorber, said second shell being positioned with relation to the first shell to permit a gravity flow of weak solution held in the absorber to fiow to the generator, a pump having its suction connected to the absorber to receive weak solution therefrom and to recirculate solution to be supplied to the absorber, conduit means communicating the weak solution holdin portion of the absorber with the generator carrying a gravity stream of weak solution to the latter in an amount proportioned to the cooling load on the machine, an ejector connected to the general receiving a stream of strong solution therefrom, said ejector also receiving a portion of the solution discharged from the pump to entrain said strong solution and forward the solution mixture to the pump suction for recirculation to the absorber.
17. In an absorption refrigeration machine forming a closed circulatory system for saline solution the combination of a first horizontally disposed shell defining a higher pressure chamber, a generator cooperating with said first shell holding a supply of strong solution, and a condenser disposed in and cooperating with said higher pressure shell to receive vaporized refrigerant from the generator to be condensed therein, a second horizontally disposed shell defining a lower pressure chamber, an absorber cooperative with said second shell and holding weak solution, and an evaporator positioned in and cooperative with said lower pressure shell and arranged to pass refrigerant vapors to the absorber, said second shell being positinned with relation to the first shell to permit a gravity flow or" weak solution held in the absorber to fiow to the generator, a having its suction connected to the absorber to receive weal; solution therefrom and to recirculate solution to be sprayed into the absorber, conduit means communicating the weak solution holding portion of the absorber with the generator carryin a gravity stream of weak solution to the latter in an amount proportional to the cooling load on the machine, an ejector cooperating with said pump and connected thereto receiving solution from the pump discharge and directing solution to the pump suction, said ejector connected to the generator and receiving strong solution therefrom to be entrained in solution passing through the ejector to the pump suction, the mixture thus including strong solution from the generator then being forwarded to the absorber.
18. in an absorption refrigeration machine forming a closed circulatory system for saline solution the combination of a first horizontally disposed shell defining a higher pressure chamber, a generator cooperating with said first shell holding a supply of strong solution, and a condenser disposed in and cooperating with said higher pressure shell to receive vaporized refrigerant from the generator to be condensed therein, a second horizontally disposed shell defining a lower pressure chamber, an absorber cooperative with said second shell and holding weak solution, and an evaporator positioned in and cooperative with said lower pressure shell and arranged to pass refrigerant vapors to the absorber, said second shell being positioned with relation to the first shell to permit a gravity flow of weak solution held in the absorber to flow to the generator, a pump having suction and discharge, an ejector having a first inlet connected to the pump discharge and an outlet connected to the pump suction, first conduit means communicating the absorber with the pump suction passing weak solution thereto, second conduit means communicating the absorber with the generator passing a gravity flow of weak solution, said second conduit means receiving weak solution from the absorber at a higher elevation than the first conduit means and third conduit means connecting the generator with the ejector carrying strong solution from the generator to be entrained in weak solution passing through the ejector, whereby a mixture of weak and strong solution is circulated through the pump and supplied to the absorber.
References fitted by the Examiner UNITED STATES PATENTS RGBERT A. OLEARY, Primary Examiner.

Claims (1)

1. AN ABSORPTION REFRIGERATION MACHINE OF THE VACUUM TYPE CONNECTED TO FORM A CLOSED SALINE SOLUTION CIRCULATORY SYSTEM COMPRISING; A FIRST HORIZONTALLY DISPOSED ELONGATED SHELL DEFINING A HIGHER PRESSURE CHAMBER, A GENERATOR COOPERATING WITH SAID SHELL HOLDING A SUPPLY OF STRONG SOLUTION, AND A CONDENSER DISPOSED IN AND COOPERATING WITH SAID HIGHER PRESSURE SHELL TO RECEIVE VAPORIZED REFRIGERANT FROM THE GENERATOR TO BE CONDENSED THEREIN, A SECOND HORIZONTALLY DISPOSED ELONGATED SHELL DEFINING A LOWER PRESSURE CHAMBER, AN ABSORBER COOPERATIVE WITH SAID SECOND ELONGATED SHELL AND HOLDING WEAK SOLUTION, AND AN EVAPORATOR POSITIONED IN AND COOPERATIVE WITH SAID LOWER PRESSURE SHELL AND ARRANGED TO PASS REFRIGERANT VAPORS TO THE ABSORBER, SAID SECOND SHELL BEING POSITIONED WITH RELATION TO THE FIRST SHELL TO PERMIT A GRAVITY FLOW OF WEAK SOLUTION FROM THE ABSORBER TO THE GENERATOR, CONDUIT MEANS COMMUNICATING THE WEAK SOLUTION HOLDING PORTION OF SAID ABSORBER WITH THE GENERATOR FOR CONDUCTING SAID GRAVITY FLOW OF WEAK SOLUTION, AND PUMPING MEANS INCLUDING A PUMP HAVING A SUCTION CONNECTED TO SAID ABSORBER AND TO SAID GENERATOR RESPECTIVELY AND RECEIVING STREAMS OF SOLUTION THEREFROM, SAID PUMP HAVING A DISCHARGE OUTLET CONNECTED TO SAID ABSORBER AND PASSING SAID SOLUTION THERETO.
US227368A 1962-10-01 1962-10-01 Refrigeration apparatus Expired - Lifetime US3154930A (en)

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CH874163A CH479032A (en) 1962-10-01 1963-07-12 Refrigeration machine
GB29930/63A GB985958A (en) 1962-10-01 1963-07-29 Refrigeration apparatus

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US3241330A (en) * 1963-08-08 1966-03-22 Borg Warner Prevention of concentrated solution flashing in an absorption refrigeration system
US3260066A (en) * 1964-12-01 1966-07-12 Worthington Corp Heat exchange means for an absorption refrigeration system
US3264835A (en) * 1964-08-21 1966-08-09 Trane Co Method of and apparatus for removing parts of a refrigerating system
US3266268A (en) * 1965-01-19 1966-08-16 Worthington Corp Sub-cooling steam condensate in tube side of heat exchanger for an absorption refrigeration system
US3299668A (en) * 1965-04-01 1967-01-24 Carrier Corp Absorption refrigeration systems
US3300999A (en) * 1963-11-18 1967-01-31 American Radiator & Standard Decrystallizating means for absorption refrigeration systems
US5293759A (en) * 1992-07-15 1994-03-15 Industrial Technology Research Institute Direct heat recovery absorption refrigeration system
WO1997014924A2 (en) * 1995-10-14 1997-04-24 Interotex Limited Heat pumps
EP1022522A2 (en) * 1999-01-25 2000-07-26 Carrier Corporation Compact absorption machine
US20240027106A1 (en) * 2022-07-19 2024-01-25 King Fahd University Of Petroleum And Minerals Absorption chiller refrigerator system

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US2709346A (en) * 1951-11-02 1955-05-31 Servel Inc Generator condensate lift in absorption refrigeration apparatus
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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3241330A (en) * 1963-08-08 1966-03-22 Borg Warner Prevention of concentrated solution flashing in an absorption refrigeration system
US3300999A (en) * 1963-11-18 1967-01-31 American Radiator & Standard Decrystallizating means for absorption refrigeration systems
US3264835A (en) * 1964-08-21 1966-08-09 Trane Co Method of and apparatus for removing parts of a refrigerating system
US3260066A (en) * 1964-12-01 1966-07-12 Worthington Corp Heat exchange means for an absorption refrigeration system
US3266268A (en) * 1965-01-19 1966-08-16 Worthington Corp Sub-cooling steam condensate in tube side of heat exchanger for an absorption refrigeration system
US3299668A (en) * 1965-04-01 1967-01-24 Carrier Corp Absorption refrigeration systems
US5293759A (en) * 1992-07-15 1994-03-15 Industrial Technology Research Institute Direct heat recovery absorption refrigeration system
WO1997014924A2 (en) * 1995-10-14 1997-04-24 Interotex Limited Heat pumps
WO1997014924A3 (en) * 1995-10-14 1997-07-24 Interotex E E I G Heat pumps
US6035650A (en) * 1995-10-14 2000-03-14 Interotex Limited Heat pumps
EP1022522A2 (en) * 1999-01-25 2000-07-26 Carrier Corporation Compact absorption machine
EP1022522A3 (en) * 1999-01-25 2000-11-15 Carrier Corporation Compact absorption machine
US20240027106A1 (en) * 2022-07-19 2024-01-25 King Fahd University Of Petroleum And Minerals Absorption chiller refrigerator system

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GB985958A (en) 1965-03-10

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