US3141782A - Processes for the production of ceramic bodies - Google Patents
Processes for the production of ceramic bodies Download PDFInfo
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- US3141782A US3141782A US721369A US72136958A US3141782A US 3141782 A US3141782 A US 3141782A US 721369 A US721369 A US 721369A US 72136958 A US72136958 A US 72136958A US 3141782 A US3141782 A US 3141782A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/025—Mixtures of materials with different sizes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/51—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on compounds of actinides
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- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C3/00—Reactor fuel elements and their assemblies; Selection of substances for use as reactor fuel elements
- G21C3/42—Selection of substances for use as reactor fuel
- G21C3/58—Solid reactor fuel Pellets made of fissile material
- G21C3/62—Ceramic fuel
- G21C3/623—Oxide fuels
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/30—Nuclear fission reactors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S376/00—Induced nuclear reactions: processes, systems, and elements
- Y10S376/90—Particular material or material shapes for fission reactors
- Y10S376/901—Fuel
Definitions
- the invention relates to processes for the production of ceramic bodies comprising refractory metal oxides, and has as an object to provide a simple process for the production of ceramic bodies of high density from refractory metal oxides at moderate temperatures.
- Refractory metal oxides from which ceramic bodies can be produced by the method of the invention include beryllia, magnesia, the alkaline earths (calcium, strontium, and barium monoxides) titanium dioxide, zirconium dioxide, hafnium dioxide, thorium dioxide, uranium dioxide, and plutonium dioxide, and mixtures of these, for example mixtures of uranium dioxide and beryllia.
- non-stoichiometric oxides in which the oxygen content of the oxide exceeds that necessary for the stoichiometric formula of the oxide, but is not so great as to alter the crystalline form of the oxide from that of the stoichiometric compound.
- non-stoichiometric uranium dioxide may contain oxygen in amount to satisfy a formula U0 where x has a positive value not exceeding 0.25, without altering the cubic crystalline form of pure uranium dioxide. Above UO the crystalline form of the oxide changes to tetragonal and then to other forms incorporating compounds such as U 0
- a description of the non-stoichiometric uranium dioxide compounds is given in the Journal of Inorganic and Nuclear Chemistry, volume 1, No. 6, page 357 (1955).
- High density ceramic bodies may be produced from powders of such oxides by hot pressing at very high temperatures, e.g. at 1600 C., with pressures of about 1 ton/sq. in. or over, or by cold pressing at low temperatures and then sintering at high temperatures.
- a method of producing a compact of a refractory metal oxide comprises hot pressing at a temperature between about 600 C. and 1000 C.
- a powder of said oxide having an average crystallite diameter of less than about 0.1 to 0.25 micron, according to the extent by which the oxygen content of the oxide exceeds stoichiometric proportions.
- a method of producing a compact of a stoichiometric refractory metal oxide comprises hot pressing at a temperature between about 600 C. and 1000 C. a powder of said oxide having an average crystallite diameter of less than about 0.1 micron, and preferably less than about 0.05 micron.
- a method of producing a compact of non-stoichiometric uranium dioxide having a formula UO where x has a positive value not exceeding about 0.25 comprises hot pressing at a temperature between about 600 C. and 1000 C. a powder of said dioxide having an average crystallite diameter of less than about 0.25 micron, and preferably less than about 0.1 micron.
- the hot pressing is carried out at 700 C. to 800 C. and 5 to 10 tons/sq. in., whereby compacts of a density greater than of the theoretical density of the oxide are produced.
- Average crystallite diameter may be determined by X-ray diffraction methods, or by surface area measurement, e.g. by gas adsorption methods. In most circumstances determinations by these two methods give similar values for the average diameter, but in some circumstances they may differ. For example, if the individual crystallites are separate and distinct, but irregular in shape, the average diameter as determined by surface area measurement will be smaller than that given by X-ray ditfraction. On the other hand, if the crystallites are joined together into an aggregate in which some fusion of their surfaces has occurred, then the average diameter as given by surface area measurement will be larger than that given by X-ray difiraction. In such cases it is the X-ray diffraction value which must be relied on.
- Crystallite diameter is not to be confused with apparent particle diameter as seen under a microscope. The latter may be much larger, due to individual visible particles being composed of aggregates or skeletal structures of a large number of crystallites.
- Oxide powders having average crystallite diameters less than the critical size may be prepared by a variety of methods according to the metal oxide required.
- magnesia which has been prepared by the thermal decomposition in air or in vacuo of precipitated magnesium hydroxide at temperatures between 300 C. and 800 C. has a crystallite size less than 0.1 micron, as shown by the following table:
- oxide powders of average crystallite diameter below 0.1 micron may be instanced the following: the production of stoichiometric uranium dioxide U0 by the hydrogen reduction of the higher oxides of uranium U0 and U 0 the production of beryllia by the thermal decomposition of beryllium hydroxide; and production of thoria and plutonium dioxide by the thermal decomposition of suitable compounds of thorium and plutonium, for example their hydroxides, oxalates, or carbonates.
- Non-stoichiometric uranium dioxide of the required particle size may be prepared by controlled oxidation of hydrogen-reduced U Oxidation may occur during cooling after the reduction process, or the reduced material may be subsequently heated for a controlled period in air.
- stoichiometric uranium dioxide will also oxidise spontaneously in air at normal temperatures, its oxygen content tending over a long period to a maximum, less than that corresponding to about UO this maximum varying according to the particle size and method of manufacture of the starting material.
- One advantage of producing dense compacts of refractory metal oxides by the method of the invention is, that no subsequent sintering step is necessary, so that cracking and distortion due to shrinkage are eliminated and compacts of accurate dimensions and high surface finish are produced directly by a single stage process if suitable die materials are used.
- Another advantage is that high temperatures, i.e. over 1000 C., are not employed, so that more convenient die materials may be used, e.g. nickelchrome steels such as Stellite, which have high oxidation resistance, may be used below about 800 C.
- Example I Magnesium hydroxide of very high purity (greater than 99.9%) was prepared by the following method: 330 ml. 0.880 ammonia solution was added to a solution of 500 gm. magnesium chloride hexahydrate in 180 ml. demineralised water at 70 C., care being taken to free the air in contact with the solutions from carbon dioxide; after stirring at 70 C. for 48 hrs., the precipitate was allowed to settle, and the mother liquor decanted off; after centrifuging, the remaining water was removed by evaporation at 70 C. under reduced pressure; the precipitate was then stored in a desiccator containing potassium hydroxide and phosphorus pentoxide.
- Example 11 A sample of non-stoichiometric uranium dioxide having a formula U0 produced by oxidation in air of hydrogen-reduced U 0 and having an average crystallite diameter of about 0.1 micron was hot pressed in a die of titanium carbide (bonded with nickel), at 800 C. and 5 tons/sq. in., and gave a strong compact having a density of 10.0 gm./cc., which is 90% of theoretical (about 11.1 gm./cc. for U0).
- Another sample of the same coma, position hot pressed at 800 C. and 10 tons/sq. in. was also strong, and had a compacted density of 10.75
- Example III A sample of beryllia, prepared by the thermal decomposition of beryllium hydoxide at 700 C. and having an average crystallite diameter of about 0.02 micron, was hot pressed in Stellite dies at 800 C., and gave a strong 10 compact having a density of 2.70 gm./cc., which is 89.5%
- Example IV A sample of non-stoichiometric uranium dioxide having 15 a formula Uoz og, produced by hydrogen-reduction of U 0 under conditions in which subsequent oxidation was substantially less compared with the sample of Example II, and having an average crystallite diameter-of about 0.25 micron was hot pressed as in Example II, at 10 tons/sq. in., and gave a strong compact having a density of 9.9 gm./cc. which is 90% of theoretical (about 11.0 gm./cc. for UO We claim:
- a method of producing a compact of a refractory metal oxide comprising providing a powder from the group consisting of stoichiometric refractcory metal oxide powders having an average crystallite diameter of less than about 0.1 micron and non-stoichiometric refractory metal oxide powders wherein the excess of oxygen in the oxide is not so great as to alter the crystalline form of the corresponding stoichiometric compound and having an average crystallite diameter of less than about 0.10.25 micron, and hot pressing the powder at a temperature of about 600-1000 C. and at a pressure of at least 5 tons per square inch.
- a method according to claim 1 wherein the powder is selected from the group consisting of magnesia, beryllia, and uranium dioxide.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Physics & Mathematics (AREA)
- Dispersion Chemistry (AREA)
- Plasma & Fusion (AREA)
- Manufacturing & Machinery (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Description
3,141,782 PROCESSES FOR THE PRODUCTEON F CERAMIC BODEES David Thomas Livey, Harwell, and Peter Murray, Reginald Scott, and .lacl; Williams, Abingdon, England, assignors to The United Kingdom Atomic Energy Authority, London, England No Drawing. Filed Mar. 14, N58, Ser. No. 721,369 Claims priority, application Great Britain Mar. 14, 1957 Claims. (Cl. 10555) The invention relates to processes for the production of ceramic bodies comprising refractory metal oxides, and has as an object to provide a simple process for the production of ceramic bodies of high density from refractory metal oxides at moderate temperatures.
Refractory metal oxides from which ceramic bodies can be produced by the method of the invention include beryllia, magnesia, the alkaline earths (calcium, strontium, and barium monoxides) titanium dioxide, zirconium dioxide, hafnium dioxide, thorium dioxide, uranium dioxide, and plutonium dioxide, and mixtures of these, for example mixtures of uranium dioxide and beryllia.
They also include non-stoichiometric oxides, in which the oxygen content of the oxide exceeds that necessary for the stoichiometric formula of the oxide, but is not so great as to alter the crystalline form of the oxide from that of the stoichiometric compound. For example, non-stoichiometric uranium dioxide may contain oxygen in amount to satisfy a formula U0 where x has a positive value not exceeding 0.25, without altering the cubic crystalline form of pure uranium dioxide. Above UO the crystalline form of the oxide changes to tetragonal and then to other forms incorporating compounds such as U 0 A description of the non-stoichiometric uranium dioxide compounds is given in the Journal of Inorganic and Nuclear Chemistry, volume 1, No. 6, page 357 (1955).
High density ceramic bodies may be produced from powders of such oxides by hot pressing at very high temperatures, e.g. at 1600 C., with pressures of about 1 ton/sq. in. or over, or by cold pressing at low temperatures and then sintering at high temperatures.
The improved sintering of non-stoichiometric uranium dioxides as compared with stoichiometric uranium dioxide has been disclosed, for example, in co-pending U.K. application No. 19,835/51 and is described in Process in Nuclear Energy, Series V, volume 1, pages 454 to 463 (Pergamon Press, 1956).
It has not hitherto been possible, however, to produce high density compacts of these oxides by pressing at moderate temperatures, i.e. below 1000 0, without a subsequent sintering step at high temperatures. Such a sintering step leads to distortion of the compact, which is a disadvantage when accurate dimensions are required. Moreover it is desirable to avoid the use of such high temperatures to simplify equipment and reduce reactions of the oxide with mould and die materials.
It has now been discovered that if the crystallite size of these metal oxides, as shown by surface area measurement and X-ray diffraction studies, is less than a critical size, about 0.1 micron for stoichiometric oxides, and about 0.1 to 0.25 micron for non-stoichiometric oxides, depending on the extent by which the oxygen content of the oxide exceeds stoichiometric proportions, then strong, high density compacts of the oxides can be obtained by hot pressing at temperatures below 1000 C., using pressures less than or about 10 tons/sq. in. It is believed that this etfect is almost entirely due to the smallness of the crystallites of the oxides, which gives rise to rapid sintering at these temperatures and pressures.
According to the invention, a method of producing a compact of a refractory metal oxide comprises hot pressing at a temperature between about 600 C. and 1000 C.
a powder of said oxide having an average crystallite diameter of less than about 0.1 to 0.25 micron, according to the extent by which the oxygen content of the oxide exceeds stoichiometric proportions.
Also according to the invention, a method of producing a compact of a stoichiometric refractory metal oxide comprises hot pressing at a temperature between about 600 C. and 1000 C. a powder of said oxide having an average crystallite diameter of less than about 0.1 micron, and preferably less than about 0.05 micron.
Also according to the invention, a method of producing a compact of non-stoichiometric uranium dioxide having a formula UO where x has a positive value not exceeding about 0.25, comprises hot pressing at a temperature between about 600 C. and 1000 C. a powder of said dioxide having an average crystallite diameter of less than about 0.25 micron, and preferably less than about 0.1 micron.
Preferably the hot pressing is carried out at 700 C. to 800 C. and 5 to 10 tons/sq. in., whereby compacts of a density greater than of the theoretical density of the oxide are produced.
Average crystallite diameter may be determined by X-ray diffraction methods, or by surface area measurement, e.g. by gas adsorption methods. In most circumstances determinations by these two methods give similar values for the average diameter, but in some circumstances they may differ. For example, if the individual crystallites are separate and distinct, but irregular in shape, the average diameter as determined by surface area measurement will be smaller than that given by X-ray ditfraction. On the other hand, if the crystallites are joined together into an aggregate in which some fusion of their surfaces has occurred, then the average diameter as given by surface area measurement will be larger than that given by X-ray difiraction. In such cases it is the X-ray diffraction value which must be relied on.
. Crystallite diameter is not to be confused with apparent particle diameter as seen under a microscope. The latter may be much larger, due to individual visible particles being composed of aggregates or skeletal structures of a large number of crystallites.
Oxide powders having average crystallite diameters less than the critical size may be prepared by a variety of methods according to the metal oxide required. For example, magnesia which has been prepared by the thermal decomposition in air or in vacuo of precipitated magnesium hydroxide at temperatures between 300 C. and 800 C. has a crystallite size less than 0.1 micron, as shown by the following table:
Average Crystallite diameter (micron) Temperature of Surface Area decomposition, C. (sq.m./gm.)
From surface From X-ray area diffraction As further examples of methods of preparing oxide powders of average crystallite diameter below 0.1 micron may be instanced the following: the production of stoichiometric uranium dioxide U0 by the hydrogen reduction of the higher oxides of uranium U0 and U 0 the production of beryllia by the thermal decomposition of beryllium hydroxide; and production of thoria and plutonium dioxide by the thermal decomposition of suitable compounds of thorium and plutonium, for example their hydroxides, oxalates, or carbonates.
Non-stoichiometric uranium dioxide of the required particle size may be prepared by controlled oxidation of hydrogen-reduced U Oxidation may occur during cooling after the reduction process, or the reduced material may be subsequently heated for a controlled period in air. stoichiometric uranium dioxide will also oxidise spontaneously in air at normal temperatures, its oxygen content tending over a long period to a maximum, less than that corresponding to about UO this maximum varying according to the particle size and method of manufacture of the starting material.
One advantage of producing dense compacts of refractory metal oxides by the method of the invention is, that no subsequent sintering step is necessary, so that cracking and distortion due to shrinkage are eliminated and compacts of accurate dimensions and high surface finish are produced directly by a single stage process if suitable die materials are used. Another advantage is that high temperatures, i.e. over 1000 C., are not employed, so that more convenient die materials may be used, e.g. nickelchrome steels such as Stellite, which have high oxidation resistance, may be used below about 800 C.
The invention will be more readily understood if reference is made to the following examples:
Example I Magnesium hydroxide of very high purity (greater than 99.9%) was prepared by the following method: 330 ml. 0.880 ammonia solution was added to a solution of 500 gm. magnesium chloride hexahydrate in 180 ml. demineralised water at 70 C., care being taken to free the air in contact with the solutions from carbon dioxide; after stirring at 70 C. for 48 hrs., the precipitate was allowed to settle, and the mother liquor decanted off; after centrifuging, the remaining water was removed by evaporation at 70 C. under reduced pressure; the precipitate was then stored in a desiccator containing potassium hydroxide and phosphorus pentoxide.
Samples of this pure magnesium hydroxide were heated at 700 C. in air to form magnesia by thermal decomposition. The particle size of the magnesium powder thus formed was found from nitrogen gas adsorption methods to be about 0.047 micron and the crystallite size as measured by Y-ray diffraction was about 0.045 micron. This powder was then hot pressed for 10 minutes in Stellite dies at 800 C. and tons/ sq. in. The compact so formed was strong and had a density of 3.16 gm./cc. which is 86.5% of the theoretical density of magnesia (3.65 gm./cc.). Another sample hot pressed at 800 C. and tons/sq. in. was also strong and had a compacted density of 3.5 gm./cc. which is 96% of theoretical.
Example 11 A sample of non-stoichiometric uranium dioxide having a formula U0 produced by oxidation in air of hydrogen-reduced U 0 and having an average crystallite diameter of about 0.1 micron was hot pressed in a die of titanium carbide (bonded with nickel), at 800 C. and 5 tons/sq. in., and gave a strong compact having a density of 10.0 gm./cc., which is 90% of theoretical (about 11.1 gm./cc. for U0 Another sample of the same coma, position hot pressed at 800 C. and 10 tons/sq. in. was also strong, and had a compacted density of 10.75
gm./cc., which is 96% of theoretical.
Example III A sample of beryllia, prepared by the thermal decomposition of beryllium hydoxide at 700 C. and having an average crystallite diameter of about 0.02 micron, was hot pressed in Stellite dies at 800 C., and gave a strong 10 compact having a density of 2.70 gm./cc., which is 89.5%
of theoretical (3.025 gm./cc.).
Example IV A sample of non-stoichiometric uranium dioxide having 15 a formula Uoz og, produced by hydrogen-reduction of U 0 under conditions in which subsequent oxidation was substantially less compared with the sample of Example II, and having an average crystallite diameter-of about 0.25 micron was hot pressed as in Example II, at 10 tons/sq. in., and gave a strong compact having a density of 9.9 gm./cc. which is 90% of theoretical (about 11.0 gm./cc. for UO We claim:
1. A method of producing a compact of a refractory metal oxide comprising providing a powder from the group consisting of stoichiometric refractcory metal oxide powders having an average crystallite diameter of less than about 0.1 micron and non-stoichiometric refractory metal oxide powders wherein the excess of oxygen in the oxide is not so great as to alter the crystalline form of the corresponding stoichiometric compound and having an average crystallite diameter of less than about 0.10.25 micron, and hot pressing the powder at a temperature of about 600-1000 C. and at a pressure of at least 5 tons per square inch.
2. A method according to claim 1 wherein the powder is hot pressed at a temperature of about 700-800 C. and at a pressure of about 5-10 tons per square inch.
3. A method according to claim 2 wherein the powder has an average crystallite diameter of less than about 0.05
micron.
4-. A method according to claim 1 wherein the powder is selected from the group consisting of magnesia, beryllia, and uranium dioxide.
5. A method according to claim 4 wherein the powder is non-stoichiometric uranium dioxide having the formula UO where x has a positive value not exceeding about 0.25.
OTHER REFERENCES The Properties of Magnesia Powders Prepared by the Decomposition of Magnesium Hydroxide, by Livey, Wanklyn, Hewitt, and Murray, A.E.R.E. M/ R, 1957, May
Claims (1)
1. A METHOD OF PRODUCING A COMPACT OF A REFRACTORY METAL OXIDE COMPRISING PROVIDING A POWDER FROM THE GROUP CONSISTING OF STOICHIOMETRIC REFRACTORY METAL OXIDE POWDERS HAVING AN AVERAGE CRYSTALLITE DIAMETER OF LESS THAN ABOUT 0.1 MICRON AND NON-STOICHIOMETRIC REFRACTORY METAL OXIDE POWDERS WHEREIN THE EXCESS OF OXYGEN IN THE OXIDE IS NOT SO GREAT AS TO ALTER THE CRYSTALLINE FORM OF THE CORRESPONDING STOICHIOMETRIC COMPOUND AND HAVING AN AVERAGE CRYSTALLITE DIAMETER OF LESS THAN ABOUT 0.1-0.25 MICRON, AND HOT PRESSING THE POWDER AT A TEMPERATURE OF ABOUT 600-1000*C. AND AT A PRESSURE OF AT LEAST 5 TONS PER SQUARE INCH.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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GB3141782X | 1957-03-14 |
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US3141782A true US3141782A (en) | 1964-07-21 |
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US721369A Expired - Lifetime US3141782A (en) | 1957-03-14 | 1958-03-14 | Processes for the production of ceramic bodies |
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FR (1) | FR1193260A (en) |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3236595A (en) * | 1961-10-02 | 1966-02-22 | Eastman Kodak Co | Magnesium oxide infrared transmitting optical elements |
US3278273A (en) * | 1962-12-28 | 1966-10-11 | Robert J Fischer | Single crystal barium titanate |
US3327027A (en) * | 1960-10-28 | 1967-06-20 | Gen Electric | Process for the production of plutonium oxide-containing nuclear fuel powders |
US3343915A (en) * | 1964-10-30 | 1967-09-26 | Ronald C Rossi | Densification of refractory compounds |
US3375306A (en) * | 1960-04-29 | 1968-03-26 | Atomic Energy Authority Uk | Method of producing dense,sintered bodies of uo2 or uo2-puo2 mixtures |
US3379523A (en) * | 1964-12-14 | 1968-04-23 | Canadian Patents Dev | Hot-pressing of decomposable compounds to form oxide-containing products |
US3402226A (en) * | 1961-10-02 | 1968-09-17 | Eastman Kodak Co | Process of hot pressing magnesium oxide infrared transmitting optical elements |
US3405207A (en) * | 1965-07-20 | 1968-10-08 | Fred W. Vahldiek | Cyclic high-pressure hot-pressing of oxides |
US3459503A (en) * | 1966-01-03 | 1969-08-05 | Eastman Kodak Co | Hot pressing titanium dioxide |
US3462371A (en) * | 1967-03-09 | 1969-08-19 | Ca Atomic Energy Ltd | Nuclear reactor fuel |
US3476908A (en) * | 1965-05-25 | 1969-11-04 | Nord Aviat Soc Nationale De Co | Arc spot-welding |
US3529046A (en) * | 1968-06-20 | 1970-09-15 | Atomic Energy Commission | Utilizing lithium oxide and precursors as sintering aid for hot pressing beryllium oxide |
US3545987A (en) * | 1966-09-28 | 1970-12-08 | Gen Electric | Transparent yttria-based ceramics and method for producing same |
Citations (3)
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US2091569A (en) * | 1935-09-30 | 1937-08-31 | Norton Co | Article of self bonded granular material and method of making the same |
US2538959A (en) * | 1947-02-12 | 1951-01-23 | Archibald H Ballard | Process for molding refractory oxides |
US2698990A (en) * | 1950-01-25 | 1955-01-11 | Union Carbide & Carbon Corp | Chromium-alumina metal ceramics |
-
1958
- 1958-03-14 FR FR1193260D patent/FR1193260A/en not_active Expired
- 1958-03-14 US US721369A patent/US3141782A/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2091569A (en) * | 1935-09-30 | 1937-08-31 | Norton Co | Article of self bonded granular material and method of making the same |
US2538959A (en) * | 1947-02-12 | 1951-01-23 | Archibald H Ballard | Process for molding refractory oxides |
US2698990A (en) * | 1950-01-25 | 1955-01-11 | Union Carbide & Carbon Corp | Chromium-alumina metal ceramics |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3375306A (en) * | 1960-04-29 | 1968-03-26 | Atomic Energy Authority Uk | Method of producing dense,sintered bodies of uo2 or uo2-puo2 mixtures |
US3327027A (en) * | 1960-10-28 | 1967-06-20 | Gen Electric | Process for the production of plutonium oxide-containing nuclear fuel powders |
US3402226A (en) * | 1961-10-02 | 1968-09-17 | Eastman Kodak Co | Process of hot pressing magnesium oxide infrared transmitting optical elements |
US3236595A (en) * | 1961-10-02 | 1966-02-22 | Eastman Kodak Co | Magnesium oxide infrared transmitting optical elements |
US3278273A (en) * | 1962-12-28 | 1966-10-11 | Robert J Fischer | Single crystal barium titanate |
US3343915A (en) * | 1964-10-30 | 1967-09-26 | Ronald C Rossi | Densification of refractory compounds |
US3379523A (en) * | 1964-12-14 | 1968-04-23 | Canadian Patents Dev | Hot-pressing of decomposable compounds to form oxide-containing products |
US3476908A (en) * | 1965-05-25 | 1969-11-04 | Nord Aviat Soc Nationale De Co | Arc spot-welding |
US3405207A (en) * | 1965-07-20 | 1968-10-08 | Fred W. Vahldiek | Cyclic high-pressure hot-pressing of oxides |
US3459503A (en) * | 1966-01-03 | 1969-08-05 | Eastman Kodak Co | Hot pressing titanium dioxide |
US3545987A (en) * | 1966-09-28 | 1970-12-08 | Gen Electric | Transparent yttria-based ceramics and method for producing same |
US3462371A (en) * | 1967-03-09 | 1969-08-19 | Ca Atomic Energy Ltd | Nuclear reactor fuel |
US3529046A (en) * | 1968-06-20 | 1970-09-15 | Atomic Energy Commission | Utilizing lithium oxide and precursors as sintering aid for hot pressing beryllium oxide |
Also Published As
Publication number | Publication date |
---|---|
FR1193260A (en) | 1959-11-02 |
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