US3123540A - Van ackeren - Google Patents

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US3123540A
US3123540A US3123540DA US3123540A US 3123540 A US3123540 A US 3123540A US 3123540D A US3123540D A US 3123540DA US 3123540 A US3123540 A US 3123540A
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burner
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riser channels
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B21/00Heating of coke ovens with combustible gases
    • C10B21/10Regulating and controlling the combustion

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  • This invention relates to by-product coke ovens and more particularly to improvements in the structural design and operation of horizontal coking retort ovens having regenerators and heating llues so arranged and equipped that the well known reversal of the heating of the ilues in alternation can be employed.
  • the invention relates more particularly to by-product coke ovens that employ underliring with a high B.t.u. gas such as coke oven gas.
  • a primary object of the invention is the provision of improvements in coke-oven structures so as to provide coke ovens of substantially increased capacity that are capable of and equipped to produce coke of the uniform quality that is now produced only by coke ovens of lesser capacity.
  • my invention consists in the provision of high capacity by-product coke ovens of a height exceeding that of conventional colte ovens by approximately fifty percent by which a coke of the uniform quality demanded by modern industrial technology can be manufactured; this is accomplished by providing, in combination, means for recirculating waste gas from the downflues to the inlet of the upflues, aspirating means for introducing the waste gas along with other fuel gas into the upper burning flues, a higher and a lower gas burner port in each of said ues of which at least the lower gas burner port is operatively connected to means for supplying thereto the recirculated waste gas, and separate gas headers including readily accessible control valves supplying separately the low burners and the high burners, said separate gas headers being selectively connected each to a source of rich gas and preferably the header for the high burner being connectable with sources of both rich and lean gas, so that either a rich gas or a mixture of rich and lean gas can be supplied to the high burner.
  • This arrangement permits the use
  • waste gas is aspirated into the gases flowing in the riser so that there is a dilution of rich gas in this riser before it is heated to cracking temperature.
  • the combination with the foregoing elements of separate gas headers feeding underjet nozzles provides in itself a series of interrelated advantages.
  • My combination of aspirating waste gas along with'separate feeds of flexibly selectable rich or lean gas to the burners furthermore allows one to mix these gases in such final composition that formation of carbon in the flues is avoided.
  • the waste gas contains carbon dioxide and water vapor and, at the high temperatures existing in the ducts, carbon particles forming in the gas stream will automatically react with carbon dioxide and water forming water gas.
  • FIG. 1 is a diagrammatic vertical section, on the lines 1-1 and la-la of FIG. 2 taken longitudinally of a battery of the well known Koppers-Becker underjet type of coke ovens of the abovementioned Becker patent, wherein there is embodied the features above set forth of separate riser channels of the present invention in conjunction with a waste gas recycling system for admixing a combustion medium, in advance of its delivery into both high and low burners in cach of the llame flues, with waste gaseous combustion products from corresponding combustion products lines of the battery, together with separate headers and mains for the said riser channels t0 the high and low burners;
  • FIG. la is an enlarged view of a portion of FIG. 1, showing the junction of the underjet ducts with the aspirator portion of the recirculation ducts 24;
  • FIG. 2 is a vertical section taken transversely of the battery of FG. l along the line II-ll thereof;
  • FIG. 3 is a horizontal section taken on the line ill--Ill of FIG. 2;
  • FIG. 4 is an enlarged view of a fraction of FIG. 1 showing in greater detail, on the line lV-lV of FIG. 5, the regulatory devices for delivering calibrated quantities of coke oven fuel gas into the riser channels in relation to the waste gas recirculating ducts in the underjet coke oven heating systems;
  • FlG. 4a is a still larger detail View of one underjet nozzle and its calibrated orifice tip as shown in the foregoing figures of the drawing;
  • FIG. 5 is a vertical cross-sectional View taken on the line V-V of FIG. 4, transversely of the battery, showing the high burner riser channel system in its relation to the low burner riser channel system;
  • FIG. 6 is a vertical cross-sectional view to illustrate the system as shown in FIG. 1, but modified to have the recirculation ducts connected only to the high burners and their riser channels, and not to the low burners.
  • an oven which incorporates well known cross-over ducts arranged to flow combustion products issuing from the vertically disposed heating iiues of an oven heating wall over the top of an adjacent coking chamber and into similar and similarly positioned heating flues of a heating wall adjacent the opposite side of such coking chamber.
  • the colte oven battery comprises a plurality of coling chambers 2 and heating walls 3 that are disposed in alternation lengthwise of the battery.
  • the heating walls 3 are constituted of a row of vertical llame or combustion heating fines 4 that are disposed side-by-side crosswise of the battery, and are grouped for gas iow purposes in flow groups of several heating iiues 4 having a common cross-over duct 6, whereby combustion products of each such iiow group flow upward and over across the top of a coking chamber 2 into a corresponding flow group adjacent the opposite side of an intermediate coking chamber.
  • Each flow group of fiues 4 is provided with a common horizontal iiue 7 and the ues of a flow group except the end groups are symmetrically disposed in respect of its cross-over duct 6.
  • the two ow groups of tiues at either end of the heating wall 3 are furnished with individual cross-overs which are unsymmetrically located to accommodate the differently proportionate amounts of combustion products produced by the large amounts of underiring gas burned in flues at those locations, for the purposes of overcoming the greater radiation of the heating wall ends.
  • the number of flues connected to these cross-over ducts and the number of cross-over ducts as well can be varied in accordance with desired design.
  • the heating rlues 4 of the heating walls each communicate individually by regenerator port and duct assemblies 8 with two cross-regenerators 9 therebeneath, each such regenerator being arranged to preheat combustion air at such times as the heating flues are being underlired with preheated rich fuel gas as, for example, obtains when the ovens of the battery are underred with coke oven gas.
  • One of the regenerators 9 of the pair of regenerators with which each heating flue 4 is communicably connected is also adapted to preheat lean fuel gas delivered thereto from a lean-fuel-gas main liow box (not shown) to an inlet i2 (shown on FIG. 2) to the sole channels 1l in a well known manner, in those instances where the ovens are operated as gas ovens and are, therefore, underred with extraneously derived lean gas, such as blast furnace or producer gas.
  • each riser channel 13 leads to a low gas burner port 11S
  • each riser channel 15 leads to a high burner port 17 through its associated riser extensions l5.
  • Each low burner riser channel 13 for all ues 4 in a heating wall communicates by means of underjet duct pipe connections 26 with a header pipe 19 below the mat 14, and each high burner riser channel 15 for each flue 4 likewise communicates, by means of underjet duct pipe connection 26a, to a separate header pipe 19a, whereby all the heating flues 4 in a single heating wall are simultaneously supplied with fuel gas from one side of the battery.
  • the wall header pipes i9 and 19a communicate through individual pipe connections 2t? and 21 with, respectively, separate principal supply mains 22 and 22a that extend lengthwise along the side of the battery and communicate through gas main 3@ with a reservoir (not shown) of coke-oven gas from the battery.
  • Valve and gas flow reversing mechanism 23 is provided to supply fuel gas to each heating wall in alternation with an associated heating wall thereadjacent.
  • the two sets of underjet riser channels 13 and 15 that are each associated with corresponding on and off heating iues of adjacent heating walls employing the same cross-over duct 6, are communicably connected adjacent their lower ends by means of a waste gas recirculation induction duct 24 located in mat 114.
  • a waste gas recirculation induction duct 24 located in mat 114.
  • Waste combustion gases from the flues 4 are supplied through ducts 24 to risers 13 and 15 to respectively the low and high burner ports 18 and 17.
  • the recirculation duct 24 can be arranged with respect to the mat in one of a number of ways, but is preferably arranged as shown in common assignees copending application of Linwood G. Tucker, Jr., Serial No. 622,170, filed November 14, 1956, entitled Recirculating Underjet Coking Retort Oven, in considerable detail, and, diagrammatically, in FIG. 5.
  • Each branch pipe has a nozzle 27 containing a removable calibrated orifice tip as shown in FIG. 4a. These removable nozzles are described and claimed in the aforesaid Rueckel patent.
  • the rate at which fuel gas is delivered to the individual underjet riser channels 13 and 15 is controlled by controlling the gas pressure in the separate supply mains 22 and 22a and by means of selecting a suitable size of 27a. These nozzles 27 are withdrawable downwardly through the pipes 216, 26a for removal and replacement of orilice ips 27a.
  • fuel gas is individually injected into the riser channels 13 and 1.5, in the form of a jet which exerts a selective ejector effect on waste combustion gases contained in the recirculation induction ducts 24, causing waste gases of combustion to ilow downwardly from an off fiame liuc 4 through its idle burners 17, 113, and their riser channels 15, l5 to the recirculation duct 24, and thence, individually upwardly with the jets of fuel gas for the separate high and low burners, to admix with the fuel gas as a diluent to enter the burners i7 and 1S separately for the on combustion lines 4.
  • the recirculated waste fuel gas also contains carbon dioxide and Water vapor. These components at the high temperatures prevailing in the risers and lines react with carbon molecules and prevent the deposition of carbon in the risers and riser extensions l5 of the high gas burners i7, which would otherwise occur through the cracking of the undiluted rich fuel gases of higher caloric value, by the intense heat given off at the lower gas burner ports 1S.
  • Fuel gas liowing through line 22a to the riser channels 15 for the high burner ports 17 is preferably fed at a higher pressure through the orifices 27 in the connections 26a, than the pressure at which the fuel gas is fed through line 22 to the orifices 27 to the riser channels 13 for the lower burner ports 13. This is done to provide a greater velocity of liow through the venturi 24 and to aspirate a greater portion of waste gas from the recirculation ducts 24 through the riser channels 15 than through riser channels 13.
  • a more dilute and less easily cracked fuel Gas is provided in risers l5, l5 and more carbon dioxide and water is supplied for faster and more complete reaction with carbon particles tending to form therein.
  • Such denser gas in mixture with the fuel gas acts, after the mixture of gas emerges from the calibrated orifices in the tip of the nozzle 27, to induce larger portions of waste gas to be aspirated from the recirculation ducts 24 into venturi 24 of the high burner lines l5, than the undiluted fuel gas does for the low burner lines 13.
  • the lower burners i3 are separately supplied with the coke-oven gas at a pressure such that a minor aspiration and admixture of waste gas occurs.
  • the coke-oven gas is separately introduced at a higher pressure from line 22a and header 19a to the high burner riser channels l5, with orifices in the tips 27a calibrated to produce a jet velocity higher than the jet velocity of the gas from the tips in the nozzles 27 for the low burner riser channels 13.
  • the jet velocity is so chosen that the heating value of the final gas mixture delivered at the high burners 17, these being from one to several feet above the base of the flues, is within the range of approximately to 350 B.t.u. per cu. ft. of gas mixture.
  • the valve 3l in the blast furnace gas main 2S is opened and controlled amounts of blast furnace gas are mixed with the rich gas in the high burner rich gas main 22a before the rich gas branches off through the pipe connections 2l to emerge as a jet from the orifice tips in the nozzles 27 for the high burner riser channels 1S.
  • the water and carbon dioxide content of recirculated waste gas are especially advantageous in suppressing the tendency for carbon deposition.
  • the sensible heat content of the hot recirculated waste gas is also advantageous in maintaining a high flame temperature.
  • External mixing of rich and lean gas from line 28 provides a control for the heat value and composition of the final mixture supplied to the high burners, after mixing with recirculated waste gas, over a much wider range than could be attained by providing only internal mixing of rich fuel gas with recirculated waste gas without external mixing with lean gas.
  • External mixing with lean gas in this way provides a two-edged means of control of final composition by (l) its effect on the composition of the external mixture fed to the battery, and (2) by the effect on the ratio of recirculated waste gas caused by increasing the volume and specific gravity of the external gas mixture fed to the aspirating nozzle jets of the waste gas recirculating system.
  • This increased volurne and specific gravity of the motive gas fed to the aspirating jets provides the possibility of recirculating much more waste gas than could be aspirated by a nozzle jet recirculation system which has rather narrow limitations.
  • valve 3l is adjusted, and the orifices in the nozzles 27 are selected, relative to the gas pressure in the rich gas rnain 22a to adjust the amounts of blast furnace gas and waste gas that are introduced into the rich gas to attain the desired heating value selected within the aforesaid 170 to 350 B.t.u. range, for the final gas mixture to be delivered to the high burners f7.
  • My improvement is not limited to coking retort ovens in which the high and low burners are both connected for waste gas recirculation.
  • the apparatus system is also of utility when the structure is equipped for recirculation only to the high burners.
  • the apparatus as shown in FIG. 6, is the same as abovedescribed in FIGS. l to 5, except that the riser channels f3 for the low burners l are not equipped with the venturi aspirators 2d', nor otherwise connected up to the recirculation ducts 245. Only the rich gas risers 15 for the high burners communicate with the recirculation ducts through venturi aspirators 24.
  • the low burner rich gas riser channels 13 are, instead, formed of straight sides all the Way down to the iet nozzles 27.
  • the low burner when it is not supplied with a recirculation duct is customarily provided with an air intake (not shown) for decarbonizing the riser during the olf period. Otherwise, the operation is the same as disclosed in connection with FIGS. 1 to 5, the difference being the waste gas is recirculated into the high burner rich gas riser channels l5 by the jet action of the rich gas to produce the required gas mixture of reduced heating value for delivery by the low burners i8, whereas no dilution of gas from the low burners 17 occurs.
  • the modification shown in FIG. 6 can be employed when, for example, a fuel gas or fuel gas mixture, such as a mixture of colte oven gas and blast ⁇ furnace gas is available.
  • This modification can be employed to advantage when the low yburners are decarbonized with air during the offcycle since the valuable effect of burning, during the off-cycle, carbon deposits with the remaining air in the waste-heat gas, which is an advantageous feature of waste-gas recirculation, is not available to the low burners.
  • a regenerative masonry underjet colring retor oven comprising: a row of coking chambers with t-wo sets of vertical heating iiues therefor operable in alternation as on and 0E burning combustion ues; a ⁇ fuel gas low burner at the bottom of each flue and a fuel gas high burner at a level above the bottom of each flue; air regenerators below said row of coking chambers and heating ilues and communicably connected with the bottoms of the heating lines, said regenerators being mounted above an accessible basement space; separate fuel ⁇ gas riser channels in the regenerator masonry extending from the basement space individually upwardly to the separate high and low burners in each of the heating llues; waste gas recirculating ducts communicably connecting the high burner riser channels of the two sets of heating tlues with each other in the region of the bottoms of the regenerators; fuel gas introduction means comprising individual fuel gas underjet ducts for each of the
  • the rich gas introduction means includes separate gas headers for the high and low burner rich gas riser channels and separate high and low burner gas mains, with an individual valve control remote from the battery, for the separate high and low burner gas mains.
  • a combination of heating elements therefor providing uniform heating for high-chambered ovens comprising (a) paired flues operable alternately in on and off combustion position,
  • a second rich gas main communicably connected with the low-burner supply headers and (i) controllable conduit means connected to said first rich gas main for introducing thereto a fuel gas of greater density than the rich gas feed.
  • heating walls comprising (a) a first and a second set of vertical flues operable in alternation as on and olf combustion lues,
  • waste -gas recirculating ducts communicably connecting fuel gas riser channels in said first set of Iliues with fuel gas riser channels ⁇ from said second set of flues
  • said velocity increasing means being so disposed with respect to said waste gas recirculating ducts as to aspirato a flow of waste combustion products from the olf heating ilues to the on heating fines through said waste gas recirculating ducts and the fuel gas riser channels connected thereto,
  • said gas introduction means including I(11) a first rich gas main communicating with said high burner fuel gas riser channels,
  • each of the fuel gas riser channels from the first set of flues is communicably connected with at least one gas riser channel from the second set of llues.
  • heating walls comprising (a) a first and a second set of vertical ilues operable in alternation as on and off combustion flues,
  • said gas introduction means including (1) a rst rich gas main Communicating With said high burner fuel gas riser channels and (2) a second rich gas main communicating with said low burner fuel gas riser channels.
  • heating walls comprising (a) a first and a second set of vertical fiues operable in alternation as on and oil combustion ues,
  • said nozzles being so disposed with respect to said waste lgas recirculating ducts as to aspirate a flow of waste combustion products from the oit heating iiues to the on heating fines through said waste gas recirculating :ducts and the fuel gas riser channels connected thereto,
  • said gas introduction means including (1) a -iirst rich gas main communicating with said high burner fuel gas riser channels,

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  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
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  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)

Description

March 3, 1964 .1. VAN ACKEREN HIGH CHAMBERED HORIZONTAL COKE OVENS 5 Sheets-Sheet l -1a. f? l Filed April 13, 1961 l-SECTION I ELAST FURNACE,
GAS INVENTOR.
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.4 7 raf-M57 March 3, 1964 J. VAN ACKEREN 3,123,540
HIGH CHAMBERED HORIZONTAL COKE ovENs Filed April l5, 1961 5 Sheets-Sheet 2 IN V EN TOR. Josef/l YAA/ cwfenl.
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United States Patent O 3,123,540 HIGH CHAMBERED HREZQNTAL COKE OVENS Joseph van Ackeren, Pittsburgh, Pa., assigner to Koppers Company, Inc., a corporation of Delaware Filed Apr. 13, 196i, Ser. No. 102,791 9 Claims. (Cl. 1262-141) This invention relates to by-product coke ovens and more particularly to improvements in the structural design and operation of horizontal coking retort ovens having regenerators and heating llues so arranged and equipped that the well known reversal of the heating of the ilues in alternation can be employed. The invention relates more particularly to by-product coke ovens that employ underliring with a high B.t.u. gas such as coke oven gas.
A primary object of the invention is the provision of improvements in coke-oven structures so as to provide coke ovens of substantially increased capacity that are capable of and equipped to produce coke of the uniform quality that is now produced only by coke ovens of lesser capacity.
Increasing the width of the coking chamber increases also the coking time and consequently this expedient will not increase the output of the oven per unit of time. Attempts, therefore, have been made to increase the capacity of the coke ovens by increasing the height of the coking chamber. This expedient has not proved entirely satisfactory because it has not heretofore been possible to greatly increase oven heights without encountering a marked reduction in coke quality because it has not been possible to heat the coal in the tall ovens uniformly.
Briefly stated, my invention consists in the provision of high capacity by-product coke ovens of a height exceeding that of conventional colte ovens by approximately fifty percent by which a coke of the uniform quality demanded by modern industrial technology can be manufactured; this is accomplished by providing, in combination, means for recirculating waste gas from the downflues to the inlet of the upflues, aspirating means for introducing the waste gas along with other fuel gas into the upper burning flues, a higher and a lower gas burner port in each of said ues of which at least the lower gas burner port is operatively connected to means for supplying thereto the recirculated waste gas, and separate gas headers including readily accessible control valves supplying separately the low burners and the high burners, said separate gas headers being selectively connected each to a source of rich gas and preferably the header for the high burner being connectable with sources of both rich and lean gas, so that either a rich gas or a mixture of rich and lean gas can be supplied to the high burner. This arrangement permits the use of a simple regenerator-air and waste-gas duct at the base of the ilues.
The interrelation of the several elements of my novel combination of structural features incorporated in coke ovens of heights exceeding that of conventional ovens allows one to obtain the advantages of each of these combined elements without encountering the disadvantages that heretofore have been believed to be inherent and inseparable trom the use of such elements. For example, the use of high and low burners together in a single flue has heretofore been believed to be substantially inoperable when a gas rich enough to give reasonably short coking times was employed because the higher burner would soon be plugged by carbon deposition therein as a result of the heating and cracking of the heating gas by the llame from the lower burner. Consequently it was thought that the best that could be accomplished was putting the high burner and low burner in adjacent tlues. Even here trouble was encountered with carbon deposition of the higher burner because the riser to the nozzle 3,123,54@ Patented Mar. 3, 1961i "ice of the high burner would still be heated by the adjacent flue to temperatures that would cause cracking of the gas in the riser. Furthermore, this arrangement of burners in separate flues created a condition of relatively cool spots at the base of the high ilue burner and prevented the attainment of uniform coking rates and coke qualit` when in substantially higher ovens it is necessary that the high burner has to be located at elevations which create a substantially cooler area below that burner.
I have now solved this problem and can provide the advantages of heating the tall ovens by burners in a single flue through the interaction of the several elements enumerated above. Firstly, waste gas is aspirated into the gases flowing in the riser so that there is a dilution of rich gas in this riser before it is heated to cracking temperature. Secondly, by being in the same flue, we have the further advantage of mingling with partially burned gas from the lower burner so as to extend the flame length or flame propogation from the upper burner, thus providing an unexpected advantage of more uniform heating vertically up the oven wall. Thirdly, the combination with the foregoing elements of separate gas headers feeding underjet nozzles provides in itself a series of interrelated advantages. In the rst place, by remotely operable valves, one can for example feed a mixture of blast furnace gas and rich gas into preferably the high-burner riser and this denser gas can be employed at any selected pressure (because it is fed through a separate system and because the nozzle itself can have a selected orifice as shown in Rueckel Patent No. 2,470,112) and consequent velocity to aspirate a calculated amount of waste gas into the llue. This permits a flexibility and accuracy of adjustment that can permit one for the rst time with high ovens to control to a novel degree of accuracy the temperatures at any point in the flues. My combination of aspirating waste gas along with'separate feeds of flexibly selectable rich or lean gas to the burners furthermore allows one to mix these gases in such final composition that formation of carbon in the flues is avoided. Again there is an inteirelation here of elements of the cornbination that operate together to give a most advantageous result; the waste gas contains carbon dioxide and water vapor and, at the high temperatures existing in the ducts, carbon particles forming in the gas stream will automatically react with carbon dioxide and water forming water gas.
In the accompanying drawings forming a part of this specication, and showing for purposes of exemplication the best mode of practicing the same, the invention is embodied in a cross-over llue interconnected combustion flue system of the type described in Patent 1,374,546 of Joseph Becker. The invention, however, is not limited in its application to this system, but is equally applicable, as aforesaid, to the twin or hairpin llue system.
FIG. 1 is a diagrammatic vertical section, on the lines 1-1 and la-la of FIG. 2 taken longitudinally of a battery of the well known Koppers-Becker underjet type of coke ovens of the abovementioned Becker patent, wherein there is embodied the features above set forth of separate riser channels of the present invention in conjunction with a waste gas recycling system for admixing a combustion medium, in advance of its delivery into both high and low burners in cach of the llame flues, with waste gaseous combustion products from corresponding combustion products lines of the battery, together with separate headers and mains for the said riser channels t0 the high and low burners;
FIG. la is an enlarged view of a portion of FIG. 1, showing the junction of the underjet ducts with the aspirator portion of the recirculation ducts 24;
FIG. 2 is a vertical section taken transversely of the battery of FG. l along the line II-ll thereof;
FIG. 3 is a horizontal section taken on the line ill--Ill of FIG. 2;
FIG. 4 is an enlarged view of a fraction of FIG. 1 showing in greater detail, on the line lV-lV of FIG. 5, the regulatory devices for delivering calibrated quantities of coke oven fuel gas into the riser channels in relation to the waste gas recirculating ducts in the underjet coke oven heating systems;
FlG. 4a is a still larger detail View of one underjet nozzle and its calibrated orifice tip as shown in the foregoing figures of the drawing;
FIG. 5 is a vertical cross-sectional View taken on the line V-V of FIG. 4, transversely of the battery, showing the high burner riser channel system in its relation to the low burner riser channel system;
FIG. 6 is a vertical cross-sectional view to illustrate the system as shown in FIG. 1, but modified to have the recirculation ducts connected only to the high burners and their riser channels, and not to the low burners.
The various features of the invention are shown in an oven which incorporates well known cross-over ducts arranged to flow combustion products issuing from the vertically disposed heating iiues of an oven heating wall over the top of an adjacent coking chamber and into similar and similarly positioned heating flues of a heating wall adjacent the opposite side of such coking chamber.
As can be seen in FIGS. 1 to 5, the colte oven battery comprises a plurality of coling chambers 2 and heating walls 3 that are disposed in alternation lengthwise of the battery. The heating walls 3 are constituted of a row of vertical llame or combustion heating fines 4 that are disposed side-by-side crosswise of the battery, and are grouped for gas iow purposes in flow groups of several heating iiues 4 having a common cross-over duct 6, whereby combustion products of each such iiow group flow upward and over across the top of a coking chamber 2 into a corresponding flow group adjacent the opposite side of an intermediate coking chamber. Each flow group of fiues 4 is provided with a common horizontal iiue 7 and the ues of a flow group except the end groups are symmetrically disposed in respect of its cross-over duct 6. The two ow groups of tiues at either end of the heating wall 3 are furnished with individual cross-overs which are unsymmetrically located to accommodate the differently proportionate amounts of combustion products produced by the large amounts of underiring gas burned in flues at those locations, for the purposes of overcoming the greater radiation of the heating wall ends. In this connection, it is to be understood that the number of flues connected to these cross-over ducts and the number of cross-over ducts as well, can be varied in accordance with desired design.
The heating rlues 4 of the heating walls each communicate individually by regenerator port and duct assemblies 8 with two cross-regenerators 9 therebeneath, each such regenerator being arranged to preheat combustion air at such times as the heating flues are being underlired with preheated rich fuel gas as, for example, obtains when the ovens of the battery are underred with coke oven gas. One of the regenerators 9 of the pair of regenerators with which each heating flue 4 is communicably connected, is also adapted to preheat lean fuel gas delivered thereto from a lean-fuel-gas main liow box (not shown) to an inlet i2 (shown on FIG. 2) to the sole channels 1l in a well known manner, in those instances where the ovens are operated as gas ovens and are, therefore, underred with extraneously derived lean gas, such as blast furnace or producer gas.
When the battery is heated by rich fuel gas of higher caloric value, this rich gas is delivered into the bottom of the heating flues 4 in accordance with the underjet principle by means of separate low burner and high burner rich gas riser channels 13 and 15, respectively, that extend from the lower surface of the supporting CFI mat 14 of the battery upwards through regenerator walls 16 to the heating flues 4. As shown in FIGS. l, 2, and 4 of the drawings, each riser channel 13 leads to a low gas burner port 11S, and each riser channel 15 leads to a high burner port 17 through its associated riser extensions l5. Each low burner riser channel 13 for all ues 4 in a heating wall communicates by means of underjet duct pipe connections 26 with a header pipe 19 below the mat 14, and each high burner riser channel 15 for each flue 4 likewise communicates, by means of underjet duct pipe connection 26a, to a separate header pipe 19a, whereby all the heating flues 4 in a single heating wall are simultaneously supplied with fuel gas from one side of the battery. The wall header pipes i9 and 19a communicate through individual pipe connections 2t? and 21 with, respectively, separate principal supply mains 22 and 22a that extend lengthwise along the side of the battery and communicate through gas main 3@ with a reservoir (not shown) of coke-oven gas from the battery. Valve and gas flow reversing mechanism 23 is provided to supply fuel gas to each heating wall in alternation with an associated heating wall thereadjacent.
The two sets of underjet riser channels 13 and 15 that are each associated with corresponding on and off heating iues of adjacent heating walls employing the same cross-over duct 6, are communicably connected adjacent their lower ends by means of a waste gas recirculation induction duct 24 located in mat 114. Such waste gas recirculation system is shown in detail in US. Patent No. 2,306,678 of Joseph van Ackeren. Waste combustion gases from the flues 4 are supplied through ducts 24 to risers 13 and 15 to respectively the low and high burner ports 18 and 17. The recirculation duct 24 can be arranged with respect to the mat in one of a number of ways, but is preferably arranged as shown in common assignees copending application of Linwood G. Tucker, Jr., Serial No. 622,170, filed November 14, 1956, entitled Recirculating Underjet Coking Retort Oven, in considerable detail, and, diagrammatically, in FIG. 5.
Fuel gas contained under pressure in the separate header pipes 19 and lila of the distributive system, is allocated individually to low and high risers 13, 15, for each heating liue of an associated heating wall by means of the respectively aligned separate underjet duct branch pipe connections 26, 26a. Each branch pipe has a nozzle 27 containing a removable calibrated orifice tip as shown in FIG. 4a. These removable nozzles are described and claimed in the aforesaid Rueckel patent. The rate at which fuel gas is delivered to the individual underjet riser channels 13 and 15 is controlled by controlling the gas pressure in the separate supply mains 22 and 22a and by means of selecting a suitable size of 27a. These nozzles 27 are withdrawable downwardly through the pipes 216, 26a for removal and replacement of orilice ips 27a.
By means of the above-described system, fuel gas is individually injected into the riser channels 13 and 1.5, in the form of a jet which exerts a selective ejector effect on waste combustion gases contained in the recirculation induction ducts 24, causing waste gases of combustion to ilow downwardly from an off fiame liuc 4 through its idle burners 17, 113, and their riser channels 15, l5 to the recirculation duct 24, and thence, individually upwardly with the jets of fuel gas for the separate high and low burners, to admix with the fuel gas as a diluent to enter the burners i7 and 1S separately for the on combustion lines 4.
Referring to FIGS. 1, 2, and 4, when riser channels 13 and 15 are delivering fuel gas to a ilue 4 thereabove through the high and low gas burner ports 17 and 1S, respectively, to cause such flue to operate as an upliow flue, the corresponding liuc 4 of the adjacent heating wall, with which said flue is connected by cross-over duct 6 operates as a down-dow lue and is filled with combustion products flowing downwardly to outflow regenerators. The recirculation duct 24 communicating with such downflow flue carries a portion of these combustion products from the downflow ue into the risers 13 and l5. These combustion products, which are relatively inert, mix with the rich fuel gas in the risers i3 and l5 and thus there is fed to the low gas burner port i8 and the high gas burner port 17 and the heating flue 4 thereabove, a diluted fuel gas of lower calorific value and of slower combustion characteristics than would otherwise obtain with undiluted rich fuel gas. This has the beneficial effect of making it possible to maintain a reduced temperature gradient between the tops and bottoms of the heating flues 4 to promote uniformity of heat distribution throughout the adjacent coal charge in the intervening coking chambers 2.
The recirculated waste fuel gas also contains carbon dioxide and Water vapor. These components at the high temperatures prevailing in the risers and lines react with carbon molecules and prevent the deposition of carbon in the risers and riser extensions l5 of the high gas burners i7, which would otherwise occur through the cracking of the undiluted rich fuel gases of higher caloric value, by the intense heat given off at the lower gas burner ports 1S.
Fuel gas liowing through line 22a to the riser channels 15 for the high burner ports 17 is preferably fed at a higher pressure through the orifices 27 in the connections 26a, than the pressure at which the fuel gas is fed through line 22 to the orifices 27 to the riser channels 13 for the lower burner ports 13. This is done to provide a greater velocity of liow through the venturi 24 and to aspirate a greater portion of waste gas from the recirculation ducts 24 through the riser channels 15 than through riser channels 13. Thus, a more dilute and less easily cracked fuel Gas is provided in risers l5, l5 and more carbon dioxide and water is supplied for faster and more complete reaction with carbon particles tending to form therein.
It has been found that in the absence of the abovedescribed provision for recirculation of waste gas, preferably in greater volume in the high burner risers, in each twenty-five to thirty minutes period of ori-flow operation of these lines in the regenerative cycle carbon builds up to an extent that drastically prevents uniform heating. An additional means for increasing the proportion of waste gas in the high burner risers is also provided by my combined apparatus. When a still greater difference in volume of waste gas is required for the high burner riser passages 15, 15', then blast furnace gas from line 2S is mixed with the coke oven gas in the main 22a. This blast furnace gas is denser than fuel gas such as coke oven gas and contains larger amounts of carbon dioxide. Such denser gas in mixture with the fuel gas acts, after the mixture of gas emerges from the calibrated orifices in the tip of the nozzle 27, to induce larger portions of waste gas to be aspirated from the recirculation ducts 24 into venturi 24 of the high burner lines l5, than the undiluted fuel gas does for the low burner lines 13.
Valves 29 in the mains 22, 22a, at a region remote from the oven battery, separately control the flow to all of the high 17 and low l5 burners of the battery from a single region.
ln operation of my novel combination by underring with gas having a heating value of about 500 B.t.u. or more per cu. ft., the lower burners i3 are separately supplied with the coke-oven gas at a pressure such that a minor aspiration and admixture of waste gas occurs. The coke-oven gas is separately introduced at a higher pressure from line 22a and header 19a to the high burner riser channels l5, with orifices in the tips 27a calibrated to produce a jet velocity higher than the jet velocity of the gas from the tips in the nozzles 27 for the low burner riser channels 13. The jet velocity is so chosen that the heating value of the final gas mixture delivered at the high burners 17, these being from one to several feet above the base of the flues, is within the range of approximately to 350 B.t.u. per cu. ft. of gas mixture.
To supply blast furnace gas to the high burner, the valve 3l in the blast furnace gas main 2S is opened and controlled amounts of blast furnace gas are mixed with the rich gas in the high burner rich gas main 22a before the rich gas branches off through the pipe connections 2l to emerge as a jet from the orifice tips in the nozzles 27 for the high burner riser channels 1S.
The water and carbon dioxide content of recirculated waste gas are especially advantageous in suppressing the tendency for carbon deposition. The sensible heat content of the hot recirculated waste gas is also advantageous in maintaining a high flame temperature. External mixing of rich and lean gas from line 28 provides a control for the heat value and composition of the final mixture supplied to the high burners, after mixing with recirculated waste gas, over a much wider range than could be attained by providing only internal mixing of rich fuel gas with recirculated waste gas without external mixing with lean gas. External mixing with lean gas in this way provides a two-edged means of control of final composition by (l) its effect on the composition of the external mixture fed to the battery, and (2) by the effect on the ratio of recirculated waste gas caused by increasing the volume and specific gravity of the external gas mixture fed to the aspirating nozzle jets of the waste gas recirculating system. This increased volurne and specific gravity of the motive gas fed to the aspirating jets provides the possibility of recirculating much more waste gas than could be aspirated by a nozzle jet recirculation system which has rather narrow limitations.
Accordingly, the valve 3l is adjusted, and the orifices in the nozzles 27 are selected, relative to the gas pressure in the rich gas rnain 22a to adjust the amounts of blast furnace gas and waste gas that are introduced into the rich gas to attain the desired heating value selected within the aforesaid 170 to 350 B.t.u. range, for the final gas mixture to be delivered to the high burners f7.
My improvement is not limited to coking retort ovens in which the high and low burners are both connected for waste gas recirculation. The apparatus system is also of utility when the structure is equipped for recirculation only to the high burners. In such case, the apparatus, as shown in FIG. 6, is the same as abovedescribed in FIGS. l to 5, except that the riser channels f3 for the low burners l are not equipped with the venturi aspirators 2d', nor otherwise connected up to the recirculation ducts 245. Only the rich gas risers 15 for the high burners communicate with the recirculation ducts through venturi aspirators 24. The low burner rich gas riser channels 13 are, instead, formed of straight sides all the Way down to the iet nozzles 27. The low burner when it is not supplied with a recirculation duct is customarily provided with an air intake (not shown) for decarbonizing the riser during the olf period. Otherwise, the operation is the same as disclosed in connection with FIGS. 1 to 5, the difference being the waste gas is recirculated into the high burner rich gas riser channels l5 by the jet action of the rich gas to produce the required gas mixture of reduced heating value for delivery by the low burners i8, whereas no dilution of gas from the low burners 17 occurs.
The modification shown in FIG. 6 can be employed when, for example, a fuel gas or fuel gas mixture, such as a mixture of colte oven gas and blast `furnace gas is available. This modification can be employed to advantage when the low yburners are decarbonized with air during the offcycle since the valuable effect of burning, during the off-cycle, carbon deposits with the remaining air in the waste-heat gas, which is an advantageous feature of waste-gas recirculation, is not available to the low burners.
The invention as hereinabove set forth, is embodied in a particular form of construction, but may be variously embodied within the scope of the following claims.
I Claim:
l. `ln a regenerative masonry underjet colring retor oven, the combination comprising: a row of coking chambers with t-wo sets of vertical heating iiues therefor operable in alternation as on and 0E burning combustion ues; a `fuel gas low burner at the bottom of each flue and a fuel gas high burner at a level above the bottom of each flue; air regenerators below said row of coking chambers and heating ilues and communicably connected with the bottoms of the heating lines, said regenerators being mounted above an accessible basement space; separate fuel `gas riser channels in the regenerator masonry extending from the basement space individually upwardly to the separate high and low burners in each of the heating llues; waste gas recirculating ducts communicably connecting the high burner riser channels of the two sets of heating tlues with each other in the region of the bottoms of the regenerators; fuel gas introduction means comprising individual fuel gas underjet ducts for each of the high and low riser channels with regulable orifice means for individually admitting fuel 4gas into the separate risers in the form of a jet, the regulable orifice means of the underjets for the high burner riser channels being so disposed with respect to recirculating ducts in communication therewith as to aspirato a flow of waste gaseous combustion products individually into the high burner riser channels when operable for oniiow from heating lines of the set then operable as off burning flues, through their idle high burner rich gas risers and through the interconnecting waste gas recirculating ducts, at a velocity independent of the velocity of flow of the jets into the lower burner riser channels, to dilute the rich gas for the high burner riser channels to a composition which remains substantially undecomposed and free of carbon deposition while rising to the high burners.
2. `Coke oven as claimed in claim l, and in which the two sets of heating flues are constituted of crossover iiue interconnected combustion ilues on opposite sides of an intervening coking chamber.
3. Coke oven as claimed in claim l, and in which the rich gas introduction means includes separate gas headers for the high and low burner rich gas riser channels and separate high and low burner gas mains, with an individual valve control remote from the battery, for the separate high and low burner gas mains.
4. Coke oven as claimed in claim 3, and which includes valve-controlled conduit means communicably connected with the high burner gas main for feed thereto of a denser fuel gas than the rich gas fed into said main, to augment the Volume of waste gas recirculated by the rich gas into the high burner rich gas riser channels from the waste `gas recirculating ducts.
5. In a horizontal coke oven battery a combination of heating elements therefor providing uniform heating for high-chambered ovens, the said combination comprising (a) paired flues operable alternately in on and off combustion position,
(b) a high and a low burner in each of said flues,
(c) separate gas riser ducts connected to and feeding each burner,
(d) a waste gas recirculation duct connecting the high burner gas riser duct of the off-flue to at least one of the gas riser ducts to the on-liue,
(e) an aspirator duct between the recirculation duct and said high burner gas riser duct,
(f) separate highand low-burner su :ply headers for the riser ducts feeding respectively the high and low burners,
(g) a first rich gas main communicably connected with the high-burner supply headers,
(h) a second rich gas main communicably connected with the low-burner supply headers and (i) controllable conduit means connected to said first rich gas main for introducing thereto a fuel gas of greater density than the rich gas feed.
6. In a horizontal coke oven battery having side-byside coking chambers and heating walls, said heating walls comprising (a) a first and a second set of vertical flues operable in alternation as on and olf combustion lues,
(b) a low burner port at the bottom of each of said fines,
(c) a high burner port at a level in each of said ilues above the bottom thereof,
(d) a separate fuel gas riser channel extending downwardly from each of said Vlow burner and high burner ports,
(e) waste -gas recirculating ducts communicably connecting fuel gas riser channels in said first set of Iliues with fuel gas riser channels `from said second set of flues,
(f) gas introduction means connected with cach of said separate fuel gas riser channels for individually introducing fuel gas thereinto,
g) means for increasing the velocity of the gas flow mounted in all gas introduction means connected with fuel gas riser channels having waste gas recirculating ducts communicating therewith,
(It) said velocity increasing means being so disposed with respect to said waste gas recirculating ducts as to aspirato a flow of waste combustion products from the olf heating ilues to the on heating fines through said waste gas recirculating ducts and the fuel gas riser channels connected thereto,
(i) said gas introduction means including I(11) a first rich gas main communicating with said high burner fuel gas riser channels,
(2) a second rich gas main communicating with said low burner .fuel gas riser channels and (3) controllable conduit means connected to said rst rich gas main for introducing thereto a fuel gas of greater density than the rich gas feed.
7. A horizontal coke oven battery substantially as claimed in claim 6, wherein each of the fuel gas riser channels from the first set of flues is communicably connected with at least one gas riser channel from the second set of llues.
8. :In a horizontal coke oven battery having side-by-side coking chambers and heating walls, said heating walls comprising (a) a first and a second set of vertical ilues operable in alternation as on and off combustion flues,
(b) a low burner port at the bottom of each of said flues,
(c) a high burner port at a level in each of said flue above the bottom thereof,
(d) a separate fuel gas riser channel extending downwardly from each of said low burner and high burner ports,
(e) a waste gas recirculating duct communicably connecting each of the fuel gas riser channels from said first set of iiues with at least one fuel gas riser channel from said second set of flues,
(f) gas introduction means connected with each of said separate fuel gas riser channels for individually introducing fuel gas thereinto,
(g) nozzles mounted in all gas introduction means connected with fuel gas riser channels having waste gas recirculating ducts communicating therewith,
(lz) said nozzles being so disposed with respect to said waste gas recirculating ducts as to aspirato a flow of waste combustion products from the olf heating flues to the on heating flues through said waste ygas recirculating ducts and the fuel gas riser channels connected thereto,
(i) said gas introduction means including (1) a rst rich gas main Communicating With said high burner fuel gas riser channels and (2) a second rich gas main communicating with said low burner fuel gas riser channels.
9. In a horizontal coke oven battery having side-by-side coking chambers and heating Walls, said heating walls comprising (a) a first and a second set of vertical fiues operable in alternation as on and oil combustion ues,
(b) a low burner port at the bottom of each of said yflues, v
(c) a high burner port at a level in each of said tlues above the bottom thereof,
(d) a separate fuel gas riser channel extending downward-ly from each of said low burner and high burner ports,
(e) a Waste gas recirculating duct communicably connecting each of the fuel gas riser channels from said irst set of flues with at least one fuel gas riser channel from said second set of ues,
(f) gas introduction means connected with each of said separate -fuel gas riser channels for individually introducing fuel gas thereinto,
(g) nozzles mounted in all gas introduction means connected with fuel gas riser channels having Waste gas recirculating ducts communicating therewith,
(h) said nozzles being so disposed with respect to said waste lgas recirculating ducts as to aspirate a flow of waste combustion products from the oit heating iiues to the on heating fines through said waste gas recirculating :ducts and the fuel gas riser channels connected thereto,
(i) said gas introduction means including (1) a -iirst rich gas main communicating with said high burner fuel gas riser channels,
(2) a second rich gas main communicating with said low burner fuel gas riser channels and (3) controllable conduit means connected to said iirst rich gas main for introducing thereto a fuel gas of greater density than the rich gas feed.
References Cited in the iile of this patent UNITED STATES PATENTS 1,341,258 Buhler May 25, 1920 2,224,920 Otto Dec. 17, 1940 2,306,366 Becker Dec. 29, 1942 2,507,554 Van Ackeren May 16, 1950 2,554,818 Davis May 29, 1951 2,799,632 Van Ackeren July 16, 1957 FOREIGN PATENTS 577,126 Canada June 2, 1959

Claims (1)

1. IN A REGENERATIVE MASONRY UNDERJET COKING RETORTOVEN, THE COMBINATION COMPRISING: A ROW OF COKING CHAMBERS, WITH TWO SETS OF VERTICAL HEATING FLUES THEREFOR OPERABLE IN ALTERNATION AS "ON" AND "OFF" BURNING COMBUSTION FLUES; A FUEL GAS LOW BURNER AT THE BOTTOM OF EACH FLUE AND A FUEL GAS HIGH BURNER AT A LEVEL ABOVE THE BOTTOM OF EACH FLUE; AIR REGENERATORS BELOW SAID ROW OF COKING CHAMBERS AND HEATING FLUES AND COMMUNICABLY CONNECTED WITH THE BOTTOMS OF THE HEATING FLUES, SAID REGENERATORS BEING MOUNTED ABOVE AN ACCESSIBLE BASEMENT SPACE; SEPARATE FUEL GAS RISER CHANNELS IN THE REGENERATOR MASONRY EXTENDING FROM THE BASEMENT SPACE INDIVIDUALLY UPWARDLY TO THE SEPARATE HIGH AND LOW BURNERS INEACH OF THE HEATING FLUES; WASTE GAS RECIRCULATING DUCTS COMMUNICABLY CONNECTING THE HIGH BURNER RISER CHANNELS OF THE TWO SETS OF HEATING FLUES WITH EACH OTHER IN THE REGION OF THE BOTTOMS OF THE REGENERATORS; FUEL GAS INTRODUCTION MEANS COMPRISING INDIVIDUAL FUEL GAS UNDERJET DUCTS FOR EACH OF THE HIGH AND LOW RISER CHANNELS WITH REGULABLE ORIFICE MEANS FOR INDIVIDUALLY ADMITTING FUEL GAS INTO THE SEPARATE RISERS IN THE FORM OF A JET, THE REGULABLE ORIFICE MEANS OF THE UNDERJETS FOR THE HIGH BURNER RISER CHANNELS BEING SO DISPOSED WITH RESPECT TO RECIRCULATING DUCTS INCOMMUNICATION THEREWITH AS TO ASPIRATE A FLOW OF WASTE GASEOUS COMBUSTION PRODUCTS INDIVIDUALLY INTO THE HIGH BURNER RISER CHANNELS WHEN OPERABLE FOR ONFLOW FROM HEATING FLUES OF THE SET THEN OPERABLE AS "OFF" BURNING FLUES, THROUGH THEIR IDLE HIGH BURNER RICH GAS RISERS AND THROUGH THE INTERCONNECTING WASTE GAS RECIRCULATING DUCTS, AT A VELOCITY INDEPENDENT OF THE VELOCITY OF FLOW OF THE JETS INTO THE LOWER BURNER RISER CHANNELS, TO DILUTE THE RIGH GAS FOR THE HIGH BURNER RISER CHANNELS TO A COMPOSITION WHICH REMAINS SUBSTANTIALLY UNDECOMPOSED AND FREE OF CARBON DEPOSITION WHILE RISING TO THE HIGH BURNERS.
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US3192134A (en) * 1961-10-19 1965-06-29 Koppers Co Inc High and low burner gun flue coke oven with waste gas recirculation and decarbonizing air
US3261763A (en) * 1963-08-27 1966-07-19 Koppers Co Inc Gun flue coking retort oven
US3345051A (en) * 1964-03-11 1967-10-03 Koppers Co Inc Coke oven structure and method of heating
US3419475A (en) * 1964-09-01 1968-12-31 Koppers Co Inc High chambered coke oven structure
US3839158A (en) * 1969-10-02 1974-10-01 Koppers Co Inc Coke oven heating system
US3963582A (en) * 1974-11-26 1976-06-15 Koppers Company, Inc. Method and apparatus for suppressing the deposition of carbonaceous material in a coke oven battery
US4061544A (en) * 1976-05-03 1977-12-06 Koppers Company, Inc. Apparatus for providing waste gas recirculation in coke oven batteries

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US2224920A (en) * 1940-12-17 Underfired regenerator coke oven
US2306366A (en) * 1940-11-05 1942-12-29 Koppers Co Inc Coke oven structure
US2507554A (en) * 1945-08-14 1950-05-16 Koppers Co Inc Gas burner for coke ovens
US2554818A (en) * 1948-08-23 1951-05-29 Allied Chem & Dye Corp Simultaneously firing a coke-oven battery with rich and lean fuel gases
US2799632A (en) * 1951-07-14 1957-07-16 Koppers Co Inc Recirculation underjet coking retort oven
CA577126A (en) * 1959-06-02 Van Ackeren Joseph Coke oven structure

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US2224920A (en) * 1940-12-17 Underfired regenerator coke oven
CA577126A (en) * 1959-06-02 Van Ackeren Joseph Coke oven structure
US1341258A (en) * 1917-02-23 1920-05-25 Henry W Buhler Coke-oven
US2306366A (en) * 1940-11-05 1942-12-29 Koppers Co Inc Coke oven structure
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US2554818A (en) * 1948-08-23 1951-05-29 Allied Chem & Dye Corp Simultaneously firing a coke-oven battery with rich and lean fuel gases
US2799632A (en) * 1951-07-14 1957-07-16 Koppers Co Inc Recirculation underjet coking retort oven

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3192134A (en) * 1961-10-19 1965-06-29 Koppers Co Inc High and low burner gun flue coke oven with waste gas recirculation and decarbonizing air
US3261763A (en) * 1963-08-27 1966-07-19 Koppers Co Inc Gun flue coking retort oven
US3345051A (en) * 1964-03-11 1967-10-03 Koppers Co Inc Coke oven structure and method of heating
US3419475A (en) * 1964-09-01 1968-12-31 Koppers Co Inc High chambered coke oven structure
US3839158A (en) * 1969-10-02 1974-10-01 Koppers Co Inc Coke oven heating system
US3963582A (en) * 1974-11-26 1976-06-15 Koppers Company, Inc. Method and apparatus for suppressing the deposition of carbonaceous material in a coke oven battery
US4061544A (en) * 1976-05-03 1977-12-06 Koppers Company, Inc. Apparatus for providing waste gas recirculation in coke oven batteries

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