US3109776A - Process for the protection of textiles - Google Patents

Process for the protection of textiles Download PDF

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Publication number
US3109776A
US3109776A US20245A US2024560A US3109776A US 3109776 A US3109776 A US 3109776A US 20245 A US20245 A US 20245A US 2024560 A US2024560 A US 2024560A US 3109776 A US3109776 A US 3109776A
Authority
US
United States
Prior art keywords
textiles
bacitracin
copper
zinc
protection
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US20245A
Other languages
English (en)
Inventor
Edward B Hodge
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commercial Solvents Corp
Original Assignee
Commercial Solvents Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL262716D priority Critical patent/NL262716A/xx
Priority to NL121340D priority patent/NL121340C/xx
Application filed by Commercial Solvents Corp filed Critical Commercial Solvents Corp
Priority to US20245A priority patent/US3109776A/en
Priority to DEC23662A priority patent/DE1175646B/de
Priority to GB10342/61A priority patent/GB915797A/en
Application granted granted Critical
Publication of US3109776A publication Critical patent/US3109776A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00Medicinal preparations containing organic active ingredients
    • A61K31/70Carbohydrates; Sugars; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/20Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing organic materials
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42Use of materials characterised by their function or physical properties
    • A61L15/46Deodorants or malodour counteractants, e.g. to inhibit the formation of ammonia or bacteria
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic

Definitions

  • My invention relates to a method of imparting to textiles protection against the action of noxious organisms such as fungi and bacteria which protection is retained after repeated washing and cleaning operations, and more particularly it relates to a method of protecting textiles by impregnating or coating the textiles with a composition selected from the group consisting of zinc bacitracin and copper bacitracin.
  • the textile industry has long sought a satisfactory means for protecting textiles against the action of noxious organisms such as fungi, bacteria and insects during periods of storage and use and after repeated washing and cleaning operations which eventually remove the protecting agents previously available.
  • the problem has been complicated by the varying compositions of textiles in use and the widely difierent conditions under which they require protection.
  • the practical utility of textiles protected from bacterial activity even after repeated washings is obvious.
  • the antibacterial properties of such textiles would tend to lessen the liability of body odors due to the bacteria which contaminate untreated fabrics and which thrive upon perspiration and other body secretions.
  • the textile can be suitably treated with one of my compositions by placing the textile in an aqueous solution of bacitracin, adding a solution of about 1% zinc chloride or copper chloride, adjusting the pH of the combined solutions with sodium hydroxide to precipitate either the zinc bacitracin or copper bacitracin onto the textile, removing the textile from the solution and allowing the thus treated textile to dry.
  • concentrations as low as 0.05% by weight based on the weight of the textile treated of the above-named compounds are sufiicient to protect textiles.
  • concentrations ranging up to and above 2% by weight are desirable.
  • concentrations ranging from about 0.1% to about 1% by weight of the above-named compositions are desirable.
  • Example I To test the resistance of fabrics treated with zinc bacitracin, two strips of cotton-duck fabric were placed in an aqueous solution of bacitracin, a 1% solution of zinc chloride was then added and the pH was adjusted with sodium hydroxide to precipitate zinc bacitracin onto the fabric. After sutiicient soaking the strips were drained and allowed to dry. The treated strips contained 0.5% zinc bacitracin by weight based on the weight of the strip. The strips were washed and dried a total of 13 times in an automatic washer using a common household detergent. At the end of the 13th washing and drying procedure one disc 25 mm. in diameter was cut from each of the strips and each disc was placed on a separate dish mm.
  • each dish containing 15 m1. of nutrient agar inoculated with 0.1 ml. of the organism M. flavus.
  • the discs were then incubated for 24 hours at 37 C. After incubation it was observed that no organisms were growing on either of the treated discs.
  • One of the said discs had completely inhibited the growth of organisms within 1.7 mm. of the disc while the other disc inhibited growth of organisms within 2.0 mm. of the disc.
  • Example II To demonstrate the ability of copper bacitracin to pro tect textiles from noxious organisms, the procedure of Example I was followed except that copper chloride was utilized instead of zinc chloride. At the end of the test it was observed that no organisms were growing on either of the discs treated with copper bacitracin. One of the said discs had completely inhibited the growth of bacteria within 2.0 mm. of the disc while the other disc inhibited growth of bacteria within 1.0 mm. of the disc.
  • Example III Two discs, 25 mm. in diameter of untreated cottonduck fabric were washed, dried and tested following the procedure of Example I. At the end of the test it was observed that organisms were growing in great numbers on the untreated fabric.
  • a process for protecting textiles against noxious organisms which comprises treating the textiles with at least about 0.05% by weight of a compound se lected from the group consisting of zinc bacitracin and copper bacitracin.
  • a process for protecting textiles against noxious organisms which comprises contacting the textiles with a solution containing bacitracin and ions selected from the group consisting of zinc ions and copper ions, adjusting thepI-I of the solution with a base to precipitate at least about 0.05% by weight of a compound selected from the groupconsisting of zinc bacitracin and copper bacitracin and subsequently drying the textiles to remove the solvent.
  • a process for protecting textiles against noxious organisms which comprises contacting the textiles with a solution containing bacitracin and :ions selected from the group consisting of zinc ions and copper ions, adjusting the pH of the solution with a base to precipitate onto the textiles from about 0.05 to about 2% by weight based on the weight of the textiles of a compound seleoted'from the group consisting of zinc bacitracin and copper bacitracin and subsequently drying the textiles to remove the solvent.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Hematology (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Molecular Biology (AREA)
  • Textile Engineering (AREA)
  • Biochemistry (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
US20245A 1960-04-06 1960-04-06 Process for the protection of textiles Expired - Lifetime US3109776A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
NL262716D NL262716A (enrdf_load_stackoverflow) 1960-04-06
NL121340D NL121340C (enrdf_load_stackoverflow) 1960-04-06
US20245A US3109776A (en) 1960-04-06 1960-04-06 Process for the protection of textiles
DEC23662A DE1175646B (de) 1960-04-06 1961-03-16 Verfahren zum Schutz von Textilien
GB10342/61A GB915797A (en) 1960-04-06 1961-03-21 Improvements relating to protecting textile materials against the action of bacteriaand other organisms

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US20245A US3109776A (en) 1960-04-06 1960-04-06 Process for the protection of textiles

Publications (1)

Publication Number Publication Date
US3109776A true US3109776A (en) 1963-11-05

Family

ID=21797520

Family Applications (1)

Application Number Title Priority Date Filing Date
US20245A Expired - Lifetime US3109776A (en) 1960-04-06 1960-04-06 Process for the protection of textiles

Country Status (4)

Country Link
US (1) US3109776A (enrdf_load_stackoverflow)
DE (1) DE1175646B (enrdf_load_stackoverflow)
GB (1) GB915797A (enrdf_load_stackoverflow)
NL (2) NL262716A (enrdf_load_stackoverflow)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2633446A (en) * 1950-06-10 1953-03-31 Fairforest Company Method of treating textile articles
US2680701A (en) * 1950-08-24 1954-06-08 Multibiotics Corp Antibiotic-impregnated gauze pads and method of making same
US2803584A (en) * 1953-12-16 1957-08-20 Commercial Solvents Corp Zinc bacitracin-containing troche
US2809149A (en) * 1954-12-23 1957-10-08 Cusumano Frank Ramo Antibiotic-impregnated gauze pads and method of making same
US2813056A (en) * 1955-03-29 1957-11-12 A O Edwards Oligodynamic silver solution and process of rendering a surface microbicidal
US2813059A (en) * 1954-11-12 1957-11-12 A O Edwards Oligodynamic silver treating process and microbicidal product
US2830011A (en) * 1957-02-07 1958-04-08 American Cyanamid Co Textile fabrics containing neomycin
US2951766A (en) * 1957-07-15 1960-09-06 Le Roy A White Antiseptic plastic

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2633446A (en) * 1950-06-10 1953-03-31 Fairforest Company Method of treating textile articles
US2680701A (en) * 1950-08-24 1954-06-08 Multibiotics Corp Antibiotic-impregnated gauze pads and method of making same
US2803584A (en) * 1953-12-16 1957-08-20 Commercial Solvents Corp Zinc bacitracin-containing troche
US2813059A (en) * 1954-11-12 1957-11-12 A O Edwards Oligodynamic silver treating process and microbicidal product
US2809149A (en) * 1954-12-23 1957-10-08 Cusumano Frank Ramo Antibiotic-impregnated gauze pads and method of making same
US2813056A (en) * 1955-03-29 1957-11-12 A O Edwards Oligodynamic silver solution and process of rendering a surface microbicidal
US2830011A (en) * 1957-02-07 1958-04-08 American Cyanamid Co Textile fabrics containing neomycin
US2951766A (en) * 1957-07-15 1960-09-06 Le Roy A White Antiseptic plastic

Also Published As

Publication number Publication date
NL262716A (enrdf_load_stackoverflow)
DE1175646B (de) 1964-08-13
NL121340C (enrdf_load_stackoverflow)
GB915797A (en) 1963-01-16

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