US3109776A - Process for the protection of textiles - Google Patents
Process for the protection of textiles Download PDFInfo
- Publication number
- US3109776A US3109776A US20245A US2024560A US3109776A US 3109776 A US3109776 A US 3109776A US 20245 A US20245 A US 20245A US 2024560 A US2024560 A US 2024560A US 3109776 A US3109776 A US 3109776A
- Authority
- US
- United States
- Prior art keywords
- textiles
- bacitracin
- copper
- zinc
- protection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004753 textile Substances 0.000 title claims description 49
- 238000000034 method Methods 0.000 title claims description 15
- 108010001478 Bacitracin Proteins 0.000 claims description 32
- 229960003071 bacitracin Drugs 0.000 claims description 18
- 229930184125 bacitracin Natural products 0.000 claims description 18
- CLKOFPXJLQSYAH-ABRJDSQDSA-N bacitracin A Chemical compound C1SC([C@@H](N)[C@@H](C)CC)=N[C@@H]1C(=O)N[C@@H](CC(C)C)C(=O)N[C@H](CCC(O)=O)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H]1C(=O)N[C@H](CCCN)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@H](CC=2C=CC=CC=2)C(=O)N[C@@H](CC=2N=CNC=2)C(=O)N[C@H](CC(O)=O)C(=O)N[C@@H](CC(N)=O)C(=O)NCCCC1 CLKOFPXJLQSYAH-ABRJDSQDSA-N 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 16
- UCRLQOPRDMGYOA-DFTDUNEMSA-L zinc;(4r)-4-[[(2s)-2-[[(4r)-2-[(1s,2s)-1-amino-2-methylbutyl]-4,5-dihydro-1,3-thiazole-4-carbonyl]amino]-4-methylpentanoyl]amino]-5-[[(2s,3s)-1-[[(3s,6r,9s,12r,15s,18r,21s)-3-(2-amino-2-oxoethyl)-18-(3-aminopropyl)-12-benzyl-15-[(2s)-butan-2-yl]-6-(carbox Chemical compound [Zn+2].C1SC([C@@H](N)[C@@H](C)CC)=N[C@@H]1C(=O)N[C@@H](CC(C)C)C(=O)N[C@H](CCC([O-])=O)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H]1C(=O)N[C@H](CCCN)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@H](CC=2C=CC=CC=2)C(=O)N[C@@H](CC=2NC=NC=2)C(=O)N[C@H](CC([O-])=O)C(=O)N[C@@H](CC(N)=O)C(=O)NCCCC1 UCRLQOPRDMGYOA-DFTDUNEMSA-L 0.000 claims description 14
- 238000004140 cleaning Methods 0.000 claims description 9
- 230000001473 noxious effect Effects 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 7
- 230000000717 retained effect Effects 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 3
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims description 3
- 229910001431 copper ion Inorganic materials 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 12
- 229910052802 copper Inorganic materials 0.000 description 12
- 239000010949 copper Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 8
- 241000894006 Bacteria Species 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 239000003599 detergent Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 241000233866 Fungi Species 0.000 description 3
- 239000011592 zinc chloride Substances 0.000 description 3
- 235000005074 zinc chloride Nutrition 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- 208000015181 infectious disease Diseases 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 208000035985 Body Odor Diseases 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241000014687 Maribacter flavus Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 206010052428 Wound Diseases 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000000721 bacterilogical effect Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 244000053095 fungal pathogen Species 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000006916 nutrient agar Substances 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/70—Carbohydrates; Sugars; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/20—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing organic materials
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/46—Deodorants or malodour counteractants, e.g. to inhibit the formation of ammonia or bacteria
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
Definitions
- My invention relates to a method of imparting to textiles protection against the action of noxious organisms such as fungi and bacteria which protection is retained after repeated washing and cleaning operations, and more particularly it relates to a method of protecting textiles by impregnating or coating the textiles with a composition selected from the group consisting of zinc bacitracin and copper bacitracin.
- the textile industry has long sought a satisfactory means for protecting textiles against the action of noxious organisms such as fungi, bacteria and insects during periods of storage and use and after repeated washing and cleaning operations which eventually remove the protecting agents previously available.
- the problem has been complicated by the varying compositions of textiles in use and the widely difierent conditions under which they require protection.
- the practical utility of textiles protected from bacterial activity even after repeated washings is obvious.
- the antibacterial properties of such textiles would tend to lessen the liability of body odors due to the bacteria which contaminate untreated fabrics and which thrive upon perspiration and other body secretions.
- the textile can be suitably treated with one of my compositions by placing the textile in an aqueous solution of bacitracin, adding a solution of about 1% zinc chloride or copper chloride, adjusting the pH of the combined solutions with sodium hydroxide to precipitate either the zinc bacitracin or copper bacitracin onto the textile, removing the textile from the solution and allowing the thus treated textile to dry.
- concentrations as low as 0.05% by weight based on the weight of the textile treated of the above-named compounds are sufiicient to protect textiles.
- concentrations ranging up to and above 2% by weight are desirable.
- concentrations ranging from about 0.1% to about 1% by weight of the above-named compositions are desirable.
- Example I To test the resistance of fabrics treated with zinc bacitracin, two strips of cotton-duck fabric were placed in an aqueous solution of bacitracin, a 1% solution of zinc chloride was then added and the pH was adjusted with sodium hydroxide to precipitate zinc bacitracin onto the fabric. After sutiicient soaking the strips were drained and allowed to dry. The treated strips contained 0.5% zinc bacitracin by weight based on the weight of the strip. The strips were washed and dried a total of 13 times in an automatic washer using a common household detergent. At the end of the 13th washing and drying procedure one disc 25 mm. in diameter was cut from each of the strips and each disc was placed on a separate dish mm.
- each dish containing 15 m1. of nutrient agar inoculated with 0.1 ml. of the organism M. flavus.
- the discs were then incubated for 24 hours at 37 C. After incubation it was observed that no organisms were growing on either of the treated discs.
- One of the said discs had completely inhibited the growth of organisms within 1.7 mm. of the disc while the other disc inhibited growth of organisms within 2.0 mm. of the disc.
- Example II To demonstrate the ability of copper bacitracin to pro tect textiles from noxious organisms, the procedure of Example I was followed except that copper chloride was utilized instead of zinc chloride. At the end of the test it was observed that no organisms were growing on either of the discs treated with copper bacitracin. One of the said discs had completely inhibited the growth of bacteria within 2.0 mm. of the disc while the other disc inhibited growth of bacteria within 1.0 mm. of the disc.
- Example III Two discs, 25 mm. in diameter of untreated cottonduck fabric were washed, dried and tested following the procedure of Example I. At the end of the test it was observed that organisms were growing in great numbers on the untreated fabric.
- a process for protecting textiles against noxious organisms which comprises treating the textiles with at least about 0.05% by weight of a compound se lected from the group consisting of zinc bacitracin and copper bacitracin.
- a process for protecting textiles against noxious organisms which comprises contacting the textiles with a solution containing bacitracin and ions selected from the group consisting of zinc ions and copper ions, adjusting thepI-I of the solution with a base to precipitate at least about 0.05% by weight of a compound selected from the groupconsisting of zinc bacitracin and copper bacitracin and subsequently drying the textiles to remove the solvent.
- a process for protecting textiles against noxious organisms which comprises contacting the textiles with a solution containing bacitracin and :ions selected from the group consisting of zinc ions and copper ions, adjusting the pH of the solution with a base to precipitate onto the textiles from about 0.05 to about 2% by weight based on the weight of the textiles of a compound seleoted'from the group consisting of zinc bacitracin and copper bacitracin and subsequently drying the textiles to remove the solvent.
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Hematology (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Molecular Biology (AREA)
- Textile Engineering (AREA)
- Biochemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL262716D NL262716A (enrdf_load_stackoverflow) | 1960-04-06 | ||
NL121340D NL121340C (enrdf_load_stackoverflow) | 1960-04-06 | ||
US20245A US3109776A (en) | 1960-04-06 | 1960-04-06 | Process for the protection of textiles |
DEC23662A DE1175646B (de) | 1960-04-06 | 1961-03-16 | Verfahren zum Schutz von Textilien |
GB10342/61A GB915797A (en) | 1960-04-06 | 1961-03-21 | Improvements relating to protecting textile materials against the action of bacteriaand other organisms |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US20245A US3109776A (en) | 1960-04-06 | 1960-04-06 | Process for the protection of textiles |
Publications (1)
Publication Number | Publication Date |
---|---|
US3109776A true US3109776A (en) | 1963-11-05 |
Family
ID=21797520
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US20245A Expired - Lifetime US3109776A (en) | 1960-04-06 | 1960-04-06 | Process for the protection of textiles |
Country Status (4)
Country | Link |
---|---|
US (1) | US3109776A (enrdf_load_stackoverflow) |
DE (1) | DE1175646B (enrdf_load_stackoverflow) |
GB (1) | GB915797A (enrdf_load_stackoverflow) |
NL (2) | NL262716A (enrdf_load_stackoverflow) |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2633446A (en) * | 1950-06-10 | 1953-03-31 | Fairforest Company | Method of treating textile articles |
US2680701A (en) * | 1950-08-24 | 1954-06-08 | Multibiotics Corp | Antibiotic-impregnated gauze pads and method of making same |
US2803584A (en) * | 1953-12-16 | 1957-08-20 | Commercial Solvents Corp | Zinc bacitracin-containing troche |
US2809149A (en) * | 1954-12-23 | 1957-10-08 | Cusumano Frank Ramo | Antibiotic-impregnated gauze pads and method of making same |
US2813056A (en) * | 1955-03-29 | 1957-11-12 | A O Edwards | Oligodynamic silver solution and process of rendering a surface microbicidal |
US2813059A (en) * | 1954-11-12 | 1957-11-12 | A O Edwards | Oligodynamic silver treating process and microbicidal product |
US2830011A (en) * | 1957-02-07 | 1958-04-08 | American Cyanamid Co | Textile fabrics containing neomycin |
US2951766A (en) * | 1957-07-15 | 1960-09-06 | Le Roy A White | Antiseptic plastic |
-
0
- NL NL121340D patent/NL121340C/xx active
- NL NL262716D patent/NL262716A/xx unknown
-
1960
- 1960-04-06 US US20245A patent/US3109776A/en not_active Expired - Lifetime
-
1961
- 1961-03-16 DE DEC23662A patent/DE1175646B/de active Pending
- 1961-03-21 GB GB10342/61A patent/GB915797A/en not_active Expired
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2633446A (en) * | 1950-06-10 | 1953-03-31 | Fairforest Company | Method of treating textile articles |
US2680701A (en) * | 1950-08-24 | 1954-06-08 | Multibiotics Corp | Antibiotic-impregnated gauze pads and method of making same |
US2803584A (en) * | 1953-12-16 | 1957-08-20 | Commercial Solvents Corp | Zinc bacitracin-containing troche |
US2813059A (en) * | 1954-11-12 | 1957-11-12 | A O Edwards | Oligodynamic silver treating process and microbicidal product |
US2809149A (en) * | 1954-12-23 | 1957-10-08 | Cusumano Frank Ramo | Antibiotic-impregnated gauze pads and method of making same |
US2813056A (en) * | 1955-03-29 | 1957-11-12 | A O Edwards | Oligodynamic silver solution and process of rendering a surface microbicidal |
US2830011A (en) * | 1957-02-07 | 1958-04-08 | American Cyanamid Co | Textile fabrics containing neomycin |
US2951766A (en) * | 1957-07-15 | 1960-09-06 | Le Roy A White | Antiseptic plastic |
Also Published As
Publication number | Publication date |
---|---|
NL262716A (enrdf_load_stackoverflow) | |
DE1175646B (de) | 1964-08-13 |
NL121340C (enrdf_load_stackoverflow) | |
GB915797A (en) | 1963-01-16 |
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