US3091017A - Resilient fabrics - Google Patents
Resilient fabrics Download PDFInfo
- Publication number
- US3091017A US3091017A US207860A US3091017A US 3091017 A US3091017 A US 3091017A US 207860 A US207860 A US 207860A US 3091017 A US3091017 A US 3091017A
- Authority
- US
- United States
- Prior art keywords
- coating
- fabric
- composition
- core
- resilient
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/20—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of indefinite length
- B29C44/32—Incorporating or moulding on preformed parts, e.g. linings, inserts or reinforcements
- B29C44/322—Incorporating or moulding on preformed parts, e.g. linings, inserts or reinforcements the preformed parts being elongated inserts, e.g. cables
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/36—Cored or coated yarns or threads
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/208—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
- D03D15/217—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based natural from plants, e.g. cotton
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/573—Tensile strength
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2101/00—Inorganic fibres
- D10B2101/02—Inorganic fibres based on oxides or oxide ceramics, e.g. silicates
- D10B2101/06—Glass
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/02—Cotton
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/04—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of halogenated hydrocarbons
- D10B2321/041—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of halogenated hydrocarbons polyvinyl chloride or polyvinylidene chloride
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/04—Heat-responsive characteristics
- D10B2401/041—Heat-responsive characteristics thermoplastic; thermosetting
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/08—Physical properties foamed
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S57/00—Textiles: spinning, twisting, and twining
- Y10S57/907—Foamed and/or fibrillated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/268—Monolayer with structurally defined element
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
- Y10T428/2969—Polyamide, polyimide or polyester
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/298—Physical dimension
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31935—Ester, halide or nitrile of addition polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3033—Including a strip or ribbon
Definitions
- An object of the invention is to provide a resilient textile fabric which is free from the disadvantages set forth above. Another object of the invention is to produce a fabric having resilient characteristics which remains porous. Another object of the invention is to provide a resilient textile fabric which has an inherent gripping action to any surface which it covers. A further object of the invention is to provide a textile material which has softness and a high cushioning effect. A still further object of the invention is to provide a textile material which is highly resilient so that impressions formed in the material disappear after the pressure causing the depression has ceased. A still further object of the invention is to provide a textile material which may be cut to size and does not fray at its edges so that the customary stage of binding the edges with tape or the like may be dispensed with.
- the foamed plastic covering for the fiber core is formed of a thermoplastic material.
- a thermoplastic material makes possible the locking of the composite strands into the fabric after weaving by heating the thermoplastic material to its softening point thereby uniting each adjacent fiber at its intersection. This procedure yields a product which has greatly increased utility since it can readily be cut without unraveling.
- FIG. 1 is a side elevation partly in section showing apparatus for producing the composite strand.
- FIG. 2 is a side elevation of a second method for producing the composite strand.
- FIG. 3 is a side elevation of a third method for pro ducing the composite strand.
- FIG. 4 is an enlarged cross sectional view of the composite strand before foaming the plastic coating.
- FIG. 5 is an enlarged cross sectional view of the strand shown in FIG. 4 after foaming the plastic coating.
- FIG. 6 is a side elevation showing apparatus for foaming or heat treating and coating the composite strand when woven into a fabric.
- FIG. 7 is an enlarged cross section of the fabric produced in accordance with the invention.
- FIG. 8 is a plan view of the fabric shown in FIG. 7.
- the composite strand used in the invention can be prepared in a number of ways.
- a particularly desirable method is by extruding a plastic composition containing a blowing agent around the fiber core and then subsequently subjecting the plastic coating to heat to cause the blowing agents to expand and give foam-like characteristics to the coating.
- a typical extruder for carrying out this process is shown in FIG. 1.
- the extruder generally indicated at 3 comprises a feed hopper 4, a hollow chamber 5, a screw 6 having a continuous helical projection which fills the hollow chamber, an extrusion head 7 at the end of the hollow chamber and a screen 8 located between the hollow chamber and the extrusion head.
- the granules or plastisol of plastic composition 10 containing the blowing agent is fed from the hopper 4 into the hollow chamber 5.
- the extruder is heated by suitable means (not shown) to bring the plastic composition granules within the extruder to a temperature where they become softened, extrudable and fused.
- the composition is then compressed and forced out of the extrusion head by the rotating of the screw.
- the fiber core 12 is supplied from a spool and fed into the extnuderthrough a tube to the center of the extiusion head 7.
- the fiber core 12 passes out of the extruder in the center of the plastic material, forced out of the extrusion head by the action of the helical screw.
- the strand 11, thus formed, is heated by suitable means such as infra red heat lamps 14 to a temperature which causes the blowing agent contained in the plastic composition to decompose and give off gas thereby creating gas pockets throughout the plastic composition.
- the composite strand is then cooled by suitable means such as by passing over cooling rolls 15 and wound on a collection spool 16.
- the foaming of the plastic composition can be simultaneous with the extrusion of the composition so that the composition foams immediately upon leaving the extrusion nozzle.
- This procedure has the advantage in eliminating the additional heating step.
- the composite strand can then be supplied to any conventional weaving apparatus to weave the strand into a fabric having high tensile strength and (ll? mensional stability while possessing a high degree of resiliency.
- the fiber core can also be coated with the plastic composition, as illustrated in FIGS. 2' and 3, by passing the fiber through a coating bath 21 containing the plastic composition in a liquid form.
- the plastic coating composition can be either liquid prefoamed plastic composi tion or liquid plastic composition containing a blowing agent; This method of coating is particularly suitable for coating a prefoarned composition.
- the fiber core 12 is supplied from a spool 22 and passed intoa tank. 23 containing liquid plastic composition 21.
- the core passesunder guides 24 and 25 which hold the core 12 beneath the level of the liquid plastic composition.
- the plastic composition is of such consistency that a limited amount will cling to and coat the strand as the strand passes through the tank.
- the excess coating carried by the fiber core out of the tank 23 can be conveniently stripped olf by passing the coated fiber through a hollow tube Q16 having an inside diameter corresponding to the desired thickness of the coating.
- the excess coating can also be removed by drawing the coated fiber vertically from the plastic composition 21, as illustrated in FIG. 3 which allows the action. of gravity to limit the thickness of the-coating.
- the coated fiber core is then passed through a heating chamber 27 which causes the blowing agent contained in the composition to decompose thereby foaming the composition and fusing the plastic composition. If the. plastic coating composition is prefoamed, then, the heating step is used to fuse or cure the plastic composition.
- the composite fiber is then passed over cooling rolls 28 and collected on a collecting device 29.
- the plastic coating 30 on the fiber core prior to blowing is. a compact mass and after blowing the coating 31 is over three times larger in'diarneter and contains uniformly dispersed air cells throughout the composition. coating.
- the fiber which makes up the core of the composite thread is used to overcome the weak tensile strength of the foam alone. It can be formed of any of the conventional textile materials such as cotton, wood, hemp, flax, artificial fibers such as viscose, cellulose acetate, nylon, Orlon, Dacron, dynel, Velon and the like as well as animal fibers such as horse hair, pig hair or mineral fibers such as glass and the like.
- the particular fiber selected will depend in great part on the processing condition to which it must be subjected. If a plastic composition is selected which has to be subjected to high temperature, it would not be possible to use fiber such as cellulose acetate and Velon which deteriorate under high heat.
- the fiber It is essential, therefore, for the fiber to have sufiicient strength to stand up during processing and weaving.
- a tensile strength of at least 4 pounds is considered minimum, although with certain weaving operations, it. is possible to use a core of lower tensile strength.
- a tensile strength of at least 8 pounds is preferred.
- the diameter of the fiber core will depend on the particular fiber but usually is of the order of from about 0.010 to 0.030 inch.
- the foamed plastic composition canbe any plastic material which can be either extruded or applied as a coating and which can be foamed by the use of blowing agents or mechanical action.
- a material which is thermoplastic since it enables an after heat treatment of the textile fabric to lock the strands in place.
- Such plastic composition can be prepared by forming a plastisol by dispersing a thermoplastic resin in the form of fine particles in a compatible plasticizer.
- Such plastisols can be blended with blowing agents which decompose when heated to their decomposition temperature to liberate a large volume of gas.
- a plastisol can have air incorporated in the mass by mechanical means and the whipped mass coated on the fiber core. In either method, the coating must be heated to a sufficiently high temperature to fuse the thermoplastic composition during processing.
- thermoplastic resin which can be dispersed in a liquid medium can be used in the preparation of the plastic composition.
- Suitable plastic compositions include polymers or copolymers of vinyl chloride, vinyl acetate, vinylidene chloride, ethylene chloride, acrylic acid, methyl acrylate, methyl ethyl acrylate, ethyl 'acrylate and-the like.
- Vinyl chloride polymers containing atleast60 percent vinyl chloride are particularly efiective.
- Thevinyl chloride polymer should preferably have a specific-viscosity'of between 0.17 and 0.31 as measured in a solution of 0.20 grams polymer in milliliters of nitrobenzene at 20 C.
- the polyurethanes which are thermosetting resins, are a class of composition which can be readily foamed and used in the invention.
- a polyurethane is produced by reacting a polyisocyanate with'a reactant containing two or more active hydrogen atoms such as glycol and polyester and the like.
- a solution of polyisocyanate is mixed with a solution of the active hydrogen containing molecules in the presence of a small amount of Water immediately prior'to the coating step.
- the solutions are mixed, the polymerization reaction starts and the water reacts to liberate carbon dioxide which expands the coating into a foam.
- the coating is subjected to heat in order to cure and cross link the polyurethane to produce a foam structure with the desired properties of strength and flexibility.
- a rubber latex can be used as the foama'ble plastic composition.
- rubber is undesirable for most applications, but when the fabric incorporating the composite strand is going to have a decorative covering or the like and the composite strand is not visible rubber is suitable.
- the formulation of a rubber latex is well known in the art. The rubber is in'the form of finely divided particles dispersed in water inthe presence of emulsifiers, vulcanizing and aging ingredients,
- the rubber can be either natural rubber or any of the large groups of materials classified as synthetic rubber, such as butadiene-styrene copolymers, polymerized chloroprene and the like.
- a conventional rubber latex can be foamed by Whipping a substantial volume of air into the latex to form a multiplicity of minute air bubbles uniformly distributed throughout the mass. It is conventional to add to the foam, when the foaming operation is complete, gelling or setting agents such as sodium silicofluoride so that the foam will not collapse prior to vulcanization.
- the rubber composition must be vulcanized to set the foam and this operation is usually carried out by heating in the range of about 200 F. to about 275 F.
- the density of the foam layer applied to the fiber core or blown on the core varies in accordance with the particular plastic composition used.
- a low foam density is desirable from a cost standpoint since less plastic composition is used per yard of fiber core but low density foam can be undesirable from the standpoint of weakness with the resulting tendency to be permanently deformed by heavy loads.
- a foam with high density, although not subject to permanent indent, is costly and has poor resilience. In general, a range of 6 to 30 pounds per cubic foot gives satisfactory foam properties with a range of 10 to 25 being particularly desirable.
- Foam rubber compositions have the advantage that they can be highly filled (up to 100 parts filler per 100 parts rubber) which decreases the cost and also imparts resistance to permanent deformation.
- plastic compositions has vastly superior properties for floor covering due to their high resistance to ordinary Wear.
- the thickness of the solid coating on the fiber is about 0.005 to about 0.030 inch which will yield on blowing a strand having an over-all thickness of about 0.040 to 0.400 inch.
- the preferred over-all thickness is from 0.100 to about 0.250 inch.
- the plastic composition can be expanded from about two to about eight times its original thickness but an expansion of about four to six times is generally preferable.
- the mass is then subjected to heat.
- this heat treatment is necessary to vulcanize and cure the foam.
- the heat treatment is required in order to decompose the blowing agent and fuse the composition.
- Heat can be applied by any of the conventional techniques used for high temperature treatment of sheets or strands; that is, radiant heating elements can be used or the sheet can be passed through a conventional hot air oven maintained at the desired temperature.
- the product is removed from the heating means, it is cooled in order that the foam structure will become set and hardened. Cooling can be effected by permitting the product to stand for a suificient length of time, or alternately, streams of cool air or other cool gas can be blown directly over the product.
- the composite strand is then woven, knitted, braided or otherwise incorporated into a fabric by conventional textile procedures.
- the foamed strand can make up the Whole fabric or it can be combined with other yarn such as cotton, wool, paper fiber or the like in the desired proportion.
- the use of other yarns, particularly paper fiber reduces the cost of the finished fabric.
- a particularly desirable floor covering can be prepared by using paper fiber as the filling and the composite strand as the weft.
- the paper fibers are prepared by twisting together thin paper bands formed of kraft paper or the like. Additional decorative effects can be obtained by twisting together bands of colored paper.
- the woven textile fabric 39, as it leaves the weaving device (not shown) can be conveyed by a continuous belt 50 to a heating chamber 41 where the fabric is subject to heat 6 to soften the coating on the fibers so that they bind together at their junctions.
- the surface of the textile fabric can be coated With a thin soil-resistant coating by spraying the coating composition from a spray nozzle 42 or by any other coating means.
- the coated fabric is conveyed to a second heating chamber 43 where the coating is heated to the fusion point of the composition to form a smooth hard film.
- the fabric can then be Wound on a collecting roll 44.
- a typical fabric is illustrated in FIGS. 7 and 8.
- the fabric is composed of composite strands 45 which give the fabric its resiliency, interwoven with conventional yarns 46.
- the fabric can be provided with a thin coa-ting 47 of soil resistant material.
- the soil resistant coating is applied to permit ease of cleaning of the Woven fabric and also increase the wear resistance of the product. Such a coating is particularly useful in the case of low density foarns to close up any exposed pores.
- the layer of soil resistant composition can be formulated as a plastisol or organosol of a thermoplastic resin.
- a vinyl chloride polymer resin as described above in connection with the foamable plastisol layer, is used in order to insure maximum compatibility with the foamed strands.
- Plastisols useful as wear layers comprise from about 50 to about 150 parts plasticizer per 100 parts resin.
- Organosols are similar to plastisols in that the resin is present in the form of fine, unplasticized particles uniformly dispersed in a fluid mass.
- the dispersion medium in organosol comprises in addition to plasticizer a volatile organic solvent, such as xylene, toluene, cyclohexane, methyl ethyl ketone, methyl isobutyl ketone and the like.
- Plasticizer such as xylene, toluene, cyclohexane, methyl ethyl ketone, methyl isobutyl ketone and the like.
- Organosol compositions useful in the production of soil and wear resistant layers comprise from about 20 to about 150 parts plasticizer and about 20 to about parts solvent per parts resin.
- Sui-table soil resistant compositions are formulated in the conventional manner used in the formulation of plastisols and organosols. If the coloration of the fabric is being relied on for giving decorative characteristics to the product, it is necessary for the soil resistant coating to be transparent or translucent. The soil resistant coating by suitable coloration can give decorative effects to the product. Transparent coatings require formulation Without pigments or fillers. If the coating is opaque, a larger amount of filler can be added to the composition.
- the composition contains the conventional heat and light stabilizers.
- the soil resistant coating layer is preferably sprayed on the fabric to give uniform coverage, but it can be applied by other coating means such as roller coaters and the like.
- roller coaters would have the tendency to coat only the high spots of fabric which, in certain instances such as for economy, would be desirable.
- the coated fabric is subjected to heat in order to fuse thet resin in the coating layer and firmly bond it to the fabric.
- the use of a coating has the additional advantage of bonding the individual fibers and threads in the fabric and thereby prevent unravelling at the edges of the fabric when cut.
- a subsequent heating of the woven fabric incorporating ing the foam strand is highly desirable in certain cases to help lock the fibers in place.
- This feature is particularly advantageous in floor covering because it allows a piece to be cut from roll goods without the necessity of binding the ends as is required with the conventional fioor covering.
- a flexible film can be applied to the surface of the fabric.
- the film can either be transparent or translucent or it can have a surface decoration.
- Example I A suitable plastic composition for coating a fiber core can be prepared by blending the following ingredients:
- the blended plastisol was extruded onto a glass fiber core having a tensile strength of nine pounds.
- the core had an average diameter of 0.020 inch and the coating,
- the extrusion was carried out at a temperature of 315 F.
- the coated strand upon extrusion was subjected to infra red heat lamps to raise the temperature of the composition within'the range of 360 F. to 395 F. thereby causing the blowing agent to decompose and expand the coating to about four times its original thickness.
- the composite strand was The weft was composed of paper strands formed by twisting thin bands of kraft paper together. The woven rug was then heated to within the range of 300 to 325 F. to so-ften'the composite strands and bond them at their point of intersection with the paper strands.
- Example 11 The following ingredients in the proportions indicated were ground on a three roll mill to produce a suitable coating composition:
- composition was then extruded on a nylon core as described in Example I and woven into a rug using a conventional weaving loom.
- Example III The following ingredients in the proportions indicated were ground on a three roll mill to produce a suitable foam coating composition:
- N,N'-dimethyl-N,N-dinitroso terephthalamide blowing agent The composition was then coated on a glass fiber core and heated at about 200 F. to decompose the blowing agent; The foam coated fiber was then subject to a temperature Within the range of 300 to 350 F. to fuse the composition. After cooling, the composite strand could be woven into a fabric by any conventional weaving means.
- Example IV -A rubber latex of the following composition was whipped into a froth by violent agitation in the presence of air:
- the foam was coated on a cotton fiber core by passing the fiber through a coating bath, the excess stripped off and then the coated core subjected to a temperature of 250 F. for 30 minutes to cure and vulcanize the foam rubber.
- the resulting foam layer had a density of 14 pounds per cubic foot.
- Example V An organosol was formulated by grinding the following ingredients on a three-roll mill to produce a suitable coating composition:
- the coating was then heated to 325 F. to fuse the composition.
- the composition can be used as a clear soil resistant layer in the production of products in accordance with the invention.
- Example VI A soil resistant coating composition having the following formulation was prepared:
- Isocyanate equivalent defined as the number of milligrams of NCO group equivalent to the active hydrogen atoms in 1 gram of the polyester.
- the result ing compound contains 3 free NCO groups per molecule and has a molecular weight of 656.
- the polyesters were blended with solvents and flatting agent and then added to a 75 percent by weight solution of the polyisocyanate in methyl Cellosolve acetate.
- the resulting coating had a viscosity of 50 centipOises and contained 56.6 percent non-volatile material.
- the coating formulation contained percent of the theoretical amount of polyisocyanate required to react with the polyesters. 7
- a process for producing a fabric having a high degree of resiliency while being substantially inextensible which comprises extruding onto a thread core a smooth, uniformcoating of a resilient plastic composition containing a blowing agent, heating said coated core to a' temperature sufiiciently high to decompose said blowing agent thereby foaming said plastic composition into a resilient coating on said core, weaving said foamed coated core with other threads into a vfabric and heating said Woven fabric to soften said resilient coating to bind said threads together at their point of contact.
- a process for producing a fabric having a high degree of resiliency while being substantially inextensible which comprises extruding onto a thread core a smooth, uniform coating of a resilient thermoplastic vinyl resinous composition containing a blowing agent, heating said coated core to a temperature sufficiently high to decompose said blowing agent thereby foaming said thermoplastic resinous composition into a resilient coating on said core, weaving said foamed coated core with other threads into a fabric and heating said woven fabric to soften said resilient coating to bind said threads together at their point of contact.
- said thread core has "a tensile strength of at least 8 pounds and a diameter of about 0.010 to about 0.030 inch and said foam coating on said core has a density of about 6 to about pounds per cubic foot and a thickness of about 0.040 to about 0.40 inch.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Botany (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Laminated Bodies (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Description
y 8, I963 P. c. WETTERAU 3, 7
RESILIENT FABRICS Original Filed NOV. 25, 1957 2 Sheets-Sheet 1 INVENTOR.
PAUL 6, W'TTER/IU Afro/5 E; 7
' May 28, 1963 P. c. WETTERAU 3,091,017
RESILIENT FABRICS Original Filed Nov. 25, 1957 2 Sheets-Sheet 2 F/G. a I vawmnwm 2m.
V INVENTOR.
47 PAUL 0. WETTERAU BY r United States Patent 3,091,017 RESHlENT FABRICS Paul C. Wetterau, Mountain Lakes, Ni, assignor to Congolcum-Nairn Inc., Kearney, N.J., a corporation of New York Original application Nov. 25, 1957, Ser. No. 698,477. Divided and this application Jan. 12, 1960, Ser. No. 2,978 9 Claims. (Ci. 28-75} This invention relates to textile fabrics containing plastic fibers and to methods for their preparation and particularly to such fabrics having resilient characteristics.
This application is a division of co-pending application Ser. No. 698,477, filed November 25, 1957, entitled Resilient Fabrics.
The desirability of using resilient materials for upholstery fabrics, floor and wall coverings and the like is well known. Such fabrics are usually produced by applying a resilient coating of rubber or the like to the back of the fabric. In some instances a solid or tubular rubber strand is woven into the fabric. The use of such rubber strands has found wide application in textile material in which extensibility or elastic qualities are desired, such as in bathing suits, under garments and similar articles. The primary disadvantages in using rubber strands are the increased weight of the product and the low tensile strength of the strands. In addition, because of the impervious nature and appearance of rubber, for certain application, it has been necessary to cover the rubber strands with a woven jacket of cotton, rayon or the like. It has been suggested to use such rubber strands in floor coverings. The amount of resilience that has been obtained in this application, however, is substantially less than that obtained with the conventional fiber or rubber impregnated fiber underpadding. It has also been suggested to coat the back of carpets with a foamed rubber compound as a substitute for the conventional underpadding. Such backings have found a great deal of success in floor coverings for automobiles and the like because of the ease of installation, but limited success in the home market because of the relatively high price and also the difliculty in cleaning since dirt accumulates in the woven material on top of the layer of foam where it cannot be easily reached by the conventional cleaning methods.
An object of the invention is to provide a resilient textile fabric which is free from the disadvantages set forth above. Another object of the invention is to produce a fabric having resilient characteristics which remains porous. Another object of the invention is to provide a resilient textile fabric which has an inherent gripping action to any surface which it covers. A further object of the invention is to provide a textile material which has softness and a high cushioning effect. A still further object of the invention is to provide a textile material which is highly resilient so that impressions formed in the material disappear after the pressure causing the depression has ceased. A still further object of the invention is to provide a textile material which may be cut to size and does not fray at its edges so that the customary stage of binding the edges with tape or the like may be dispensed with. A still further object of the invention is to produce a rug or carpet which will dispense with the necessity of using an underpadd-ing thereby simplifying installation. Still further objects of the invention are to provide a textile material which is light in weight, has soundproofing characteristics and highly resistant to wear thereby giving a long service life. Other objects of the invention are to provide a resilient textile fabric which is dimensionally stable and highly resistant to deterioration in normal use.
3,091,017 Patented May 28, 1963 These and other objects of the invention are accomplished by producing a resilient fabric incorporating a composite strand having high tensile strength and limited extensibility comprising a fiber core uniformly surrounded by a smooth foamed plastic composition. The composite strand can be used to make up the entire fabric or it can be woven or otherwise combined with conventional fibers to form a combination fabric. The amount of composite strands incorporated in any fabric will depend on the resiliency desired. The results obtained by incorporating this composite strand in a fabric are two fold in that it not only produces a resilient fabric but also a fabric having a high degree of tensile strength. Heretofore, it has not been possible to commercially weave a foamed plastic strand into a fabric because the strand did not have sufiicient tensile strength to withstand the stresses of weaving and processing. The strand would also stretch thereby making it difficult to weave into a fabric with any degree of uniformity. These failings are overcome by placing the foam on a fiber core which gives the composite strand the necessary tensile strength to undergo processing and also limits its extensibility.
In accordance with one embodiment of the invention, the foamed plastic covering for the fiber core is formed of a thermoplastic material. The use of a thermoplastic material makes possible the locking of the composite strands into the fabric after weaving by heating the thermoplastic material to its softening point thereby uniting each adjacent fiber at its intersection. This procedure yields a product which has greatly increased utility since it can readily be cut without unraveling.
Other objects, features and advantages of the invention will be better understood from the following detailed description when it is read in conjunction with several figures of the drawing in which:
FIG. 1 is a side elevation partly in section showing apparatus for producing the composite strand.
FIG. 2 is a side elevation of a second method for producing the composite strand.
FIG. 3 is a side elevation of a third method for pro ducing the composite strand.
FIG. 4 is an enlarged cross sectional view of the composite strand before foaming the plastic coating.
FIG. 5 is an enlarged cross sectional view of the strand shown in FIG. 4 after foaming the plastic coating.
FIG. 6 is a side elevation showing apparatus for foaming or heat treating and coating the composite strand when woven into a fabric.
FIG. 7 is an enlarged cross section of the fabric produced in accordance with the invention.
FIG. 8 is a plan view of the fabric shown in FIG. 7.
The composite strand used in the invention can be prepared in a number of ways. A particularly desirable method is by extruding a plastic composition containing a blowing agent around the fiber core and then subsequently subjecting the plastic coating to heat to cause the blowing agents to expand and give foam-like characteristics to the coating. A typical extruder for carrying out this process is shown in FIG. 1. The extruder generally indicated at 3 comprises a feed hopper 4, a hollow chamber 5, a screw 6 having a continuous helical projection which fills the hollow chamber, an extrusion head 7 at the end of the hollow chamber and a screen 8 located between the hollow chamber and the extrusion head. The granules or plastisol of plastic composition 10 containing the blowing agent is fed from the hopper 4 into the hollow chamber 5. The extruder is heated by suitable means (not shown) to bring the plastic composition granules within the extruder to a temperature where they become softened, extrudable and fused. The composition is then compressed and forced out of the extrusion head by the rotating of the screw.
The fiber core 12 is supplied from a spool and fed into the extnuderthrough a tube to the center of the extiusion head 7. The fiber core 12 passes out of the extruder in the center of the plastic material, forced out of the extrusion head by the action of the helical screw. The strand 11, thus formed, is heated by suitable means such as infra red heat lamps 14 to a temperature which causes the blowing agent contained in the plastic composition to decompose and give off gas thereby creating gas pockets throughout the plastic composition. The composite strand is then cooled by suitable means such as by passing over cooling rolls 15 and wound on a collection spool 16. In a like manner, the foaming of the plastic composition can be simultaneous with the extrusion of the composition so that the composition foams immediately upon leaving the extrusion nozzle. This procedure has the advantage in eliminating the additional heating step. The composite strand can then be supplied to any conventional weaving apparatus to weave the strand into a fabric having high tensile strength and (ll? mensional stability while possessing a high degree of resiliency.
The fiber core can also be coated with the plastic composition, as illustrated in FIGS. 2' and 3, by passing the fiber through a coating bath 21 containing the plastic composition in a liquid form. The plastic coating composition can be either liquid prefoamed plastic composi tion or liquid plastic composition containing a blowing agent; This method of coating is particularly suitable for coating a prefoarned composition. The fiber core 12 is supplied from a spool 22 and passed intoa tank. 23 containing liquid plastic composition 21. The core passesunder guides 24 and 25 which hold the core 12 beneath the level of the liquid plastic composition. The plastic composition is of such consistency that a limited amount will cling to and coat the strand as the strand passes through the tank. The excess coating carried by the fiber core out of the tank 23 can be conveniently stripped olf by passing the coated fiber through a hollow tube Q16 having an inside diameter corresponding to the desired thickness of the coating. The excess coating can also be removed by drawing the coated fiber vertically from the plastic composition 21, as illustrated in FIG. 3 which allows the action. of gravity to limit the thickness of the-coating. The coated fiber core is then passed through a heating chamber 27 which causes the blowing agent contained in the composition to decompose thereby foaming the composition and fusing the plastic composition. If the. plastic coating composition is prefoamed, then, the heating step is used to fuse or cure the plastic composition. The composite fiber is then passed over cooling rolls 28 and collected on a collecting device 29. As can be seen by reference to FIGS. 4 and 5, the plastic coating 30 on the fiber core prior to blowing is. a compact mass and after blowing the coating 31 is over three times larger in'diarneter and contains uniformly dispersed air cells throughout the composition. coating.
The fiber which makes up the core of the composite thread is used to overcome the weak tensile strength of the foam alone. It can be formed of any of the conventional textile materials such as cotton, wood, hemp, flax, artificial fibers such as viscose, cellulose acetate, nylon, Orlon, Dacron, dynel, Velon and the like as well as animal fibers such as horse hair, pig hair or mineral fibers such as glass and the like. The particular fiber selected, however, will depend in great part on the processing condition to which it must be subjected. If a plastic composition is selected which has to be subjected to high temperature, it would not be possible to use fiber such as cellulose acetate and Velon which deteriorate under high heat. It is essential, therefore, for the fiber to have sufiicient strength to stand up during processing and weaving. As a general rule, a tensile strength of at least 4 pounds is considered minimum, although with certain weaving operations, it. is possible to use a core of lower tensile strength. A tensile strength of at least 8 pounds is preferred. The diameter of the fiber core will depend on the particular fiber but usually is of the order of from about 0.010 to 0.030 inch.
It is important to distinguish the fiber core used in accordance with this invention to form the composite strand with the fibers that have been used heretofore for rubber thread wherein, after the rubber coating is applied to the thread core, the thread is subjected to either mechanical or chemical treatment to either destroy it completely or break it into short discontinuous lengths. This type of product has inferior tensile strength and undesirable extensibility to that which is required to be woven into textile fabrics of the invention.
The foamed plastic composition canbe any plastic material which can be either extruded or applied as a coating and which can be foamed by the use of blowing agents or mechanical action. As stated above, it is preferred to use a material which is thermoplastic since it enables an after heat treatment of the textile fabric to lock the strands in place. Such plastic composition can be prepared by forming a plastisol by dispersing a thermoplastic resin in the form of fine particles in a compatible plasticizer. Such plastisols can be blended with blowing agents which decompose when heated to their decomposition temperature to liberate a large volume of gas. Organic compounds containing the N-N or 'N==N-- linkages which decompose to liberate nitrogen are particularly useful as blowing agents in foaming a thermoplastic resinous plastisol composition. Alternately, a plastisol can have air incorporated in the mass by mechanical means and the whipped mass coated on the fiber core. In either method, the coating must be heated to a sufficiently high temperature to fuse the thermoplastic composition during processing.
Any thermoplastic resin which can be dispersed in a liquid medium can be used in the preparation of the plastic composition. Suitable plastic compositions include polymers or copolymers of vinyl chloride, vinyl acetate, vinylidene chloride, ethylene chloride, acrylic acid, methyl acrylate, methyl ethyl acrylate, ethyl 'acrylate and-the like. Vinyl chloride polymers containing atleast60 percent vinyl chloride are particularly efiective. Thevinyl chloride polymer should preferably have a specific-viscosity'of between 0.17 and 0.31 as measured in a solution of 0.20 grams polymer in milliliters of nitrobenzene at 20 C. The polyurethanes, which are thermosetting resins, are a class of composition which can be readily foamed and used in the invention. A polyurethane is produced by reacting a polyisocyanate with'a reactant containing two or more active hydrogen atoms such as glycol and polyester and the like. In the preparation of polyurethanes, a solution of polyisocyanate is mixed with a solution of the active hydrogen containing molecules in the presence of a small amount of Water immediately prior'to the coating step. The solutions are mixed, the polymerization reaction starts and the water reacts to liberate carbon dioxide which expands the coating into a foam. Subsequently, the coating is subjected to heat in order to cure and cross link the polyurethane to produce a foam structure with the desired properties of strength and flexibility.
In certain instances, a rubber latex can be used as the foama'ble plastic composition. Generally rubber is undesirable for most applications, but when the fabric incorporating the composite strand is going to have a decorative covering or the like and the composite strand is not visible rubber is suitable. The formulation of a rubber latex is well known in the art. The rubber is in'the form of finely divided particles dispersed in water inthe presence of emulsifiers, vulcanizing and aging ingredients,
pigments and fillers. The rubber can be either natural rubber or any of the large groups of materials classified as synthetic rubber, such as butadiene-styrene copolymers, polymerized chloroprene and the like. A conventional rubber latex can be foamed by Whipping a substantial volume of air into the latex to form a multiplicity of minute air bubbles uniformly distributed throughout the mass. It is conventional to add to the foam, when the foaming operation is complete, gelling or setting agents such as sodium silicofluoride so that the foam will not collapse prior to vulcanization. The rubber composition must be vulcanized to set the foam and this operation is usually carried out by heating in the range of about 200 F. to about 275 F.
The density of the foam layer applied to the fiber core or blown on the core varies in accordance with the particular plastic composition used. A low foam density is desirable from a cost standpoint since less plastic composition is used per yard of fiber core but low density foam can be undesirable from the standpoint of weakness with the resulting tendency to be permanently deformed by heavy loads. A foam with high density, although not subject to permanent indent, is costly and has poor resilience. In general, a range of 6 to 30 pounds per cubic foot gives satisfactory foam properties with a range of 10 to 25 being particularly desirable. Foam rubber compositions have the advantage that they can be highly filled (up to 100 parts filler per 100 parts rubber) which decreases the cost and also imparts resistance to permanent deformation. The use of plastic compositions has vastly superior properties for floor covering due to their high resistance to ordinary Wear. The thickness of the solid coating on the fiber is about 0.005 to about 0.030 inch which will yield on blowing a strand having an over-all thickness of about 0.040 to 0.400 inch. The preferred over-all thickness is from 0.100 to about 0.250 inch. As a general rule, the plastic composition can be expanded from about two to about eight times its original thickness but an expansion of about four to six times is generally preferable.
After the fiber core has been coated with the resinous composition as a foam or as a thin uniform layer of a foamable composition, the mass is then subjected to heat. In the case of foam rubber, this heat treatment is necessary to vulcanize and cure the foam. In the case of a thermoplastic resinous composition, the heat treatment is required in order to decompose the blowing agent and fuse the composition. Heat can be applied by any of the conventional techniques used for high temperature treatment of sheets or strands; that is, radiant heating elements can be used or the sheet can be passed through a conventional hot air oven maintained at the desired temperature. After the product is removed from the heating means, it is cooled in order that the foam structure will become set and hardened. Cooling can be effected by permitting the product to stand for a suificient length of time, or alternately, streams of cool air or other cool gas can be blown directly over the product.
The composite strand is then woven, knitted, braided or otherwise incorporated into a fabric by conventional textile procedures. The foamed strand can make up the Whole fabric or it can be combined with other yarn such as cotton, wool, paper fiber or the like in the desired proportion. The use of other yarns, particularly paper fiber, reduces the cost of the finished fabric. A particularly desirable floor covering can be prepared by using paper fiber as the filling and the composite strand as the weft. The paper fibers are prepared by twisting together thin paper bands formed of kraft paper or the like. Additional decorative effects can be obtained by twisting together bands of colored paper. The woven textile fabric 39, as it leaves the weaving device (not shown) can be conveyed by a continuous belt 50 to a heating chamber 41 where the fabric is subject to heat 6 to soften the coating on the fibers so that they bind together at their junctions.
The surface of the textile fabric can be coated With a thin soil-resistant coating by spraying the coating composition from a spray nozzle 42 or by any other coating means. The coated fabric is conveyed to a second heating chamber 43 where the coating is heated to the fusion point of the composition to form a smooth hard film. The fabric can then be Wound on a collecting roll 44. A typical fabric is illustrated in FIGS. 7 and 8. The fabric is composed of composite strands 45 which give the fabric its resiliency, interwoven with conventional yarns 46. The fabric can be provided with a thin coa-ting 47 of soil resistant material.
The soil resistant coating is applied to permit ease of cleaning of the Woven fabric and also increase the wear resistance of the product. Such a coating is particularly useful in the case of low density foarns to close up any exposed pores. The layer of soil resistant composition can be formulated as a plastisol or organosol of a thermoplastic resin. Preferably a vinyl chloride polymer resin, as described above in connection with the foamable plastisol layer, is used in order to insure maximum compatibility with the foamed strands. Plastisols useful as wear layers comprise from about 50 to about 150 parts plasticizer per 100 parts resin. Organosols are similar to plastisols in that the resin is present in the form of fine, unplasticized particles uniformly dispersed in a fluid mass. The dispersion medium in organosol comprises in addition to plasticizer a volatile organic solvent, such as xylene, toluene, cyclohexane, methyl ethyl ketone, methyl isobutyl ketone and the like. Organosol compositions useful in the production of soil and wear resistant layers comprise from about 20 to about 150 parts plasticizer and about 20 to about parts solvent per parts resin.
Sui-table soil resistant compositions are formulated in the conventional manner used in the formulation of plastisols and organosols. If the coloration of the fabric is being relied on for giving decorative characteristics to the product, it is necessary for the soil resistant coating to be transparent or translucent. The soil resistant coating by suitable coloration can give decorative effects to the product. Transparent coatings require formulation Without pigments or fillers. If the coating is opaque, a larger amount of filler can be added to the composition.
. The composition contains the conventional heat and light stabilizers.
The soil resistant coating layer is preferably sprayed on the fabric to give uniform coverage, but it can be applied by other coating means such as roller coaters and the like. The use of roller coaters would have the tendency to coat only the high spots of fabric which, in certain instances such as for economy, would be desirable. After the coating is applied, the coated fabric is subjected to heat in order to fuse thet resin in the coating layer and firmly bond it to the fabric. The use of a coating has the additional advantage of bonding the individual fibers and threads in the fabric and thereby prevent unravelling at the edges of the fabric when cut.
A subsequent heating of the woven fabric incorporating ing the foam strand is highly desirable in certain cases to help lock the fibers in place. This feature is particularly advantageous in floor covering because it allows a piece to be cut from roll goods without the necessity of binding the ends as is required with the conventional fioor covering. Instead of a soil resistant coating, a flexible film can be applied to the surface of the fabric. The film can either be transparent or translucent or it can have a surface decoration.
The following examples are given for purposes of illustrat-ion.
then formed into a flat woven mg as the filling.
Example I A suitable plastic composition for coating a fiber core can be prepared by blending the following ingredients:
Parts The blended plastisol was extruded onto a glass fiber core having a tensile strength of nine pounds. The core had an average diameter of 0.020 inch and the coating,
an average thickness of 0.010 inch. The extrusion was carried out at a temperature of 315 F. The coated strand upon extrusion was subjected to infra red heat lamps to raise the temperature of the composition within'the range of 360 F. to 395 F. thereby causing the blowing agent to decompose and expand the coating to about four times its original thickness. The composite strand was The weft was composed of paper strands formed by twisting thin bands of kraft paper together. The woven rug was then heated to within the range of 300 to 325 F. to so-ften'the composite strands and bond them at their point of intersection with the paper strands.
Example 11 The following ingredients in the proportions indicated were ground on a three roll mill to produce a suitable coating composition:
7 Oklahoma.
The composition was then extruded on a nylon core as described in Example I and woven into a rug using a conventional weaving loom.
Example III The following ingredients in the proportions indicated were ground on a three roll mill to produce a suitable foam coating composition:
' Parts Polyvinyl chloride (dispersion grade) 100 Didecyl phthalate 100 Stabilizers Wetting agent 3.5
N,N'-dimethyl-N,N-dinitroso terephthalamide blowing agent The composition was then coated on a glass fiber core and heated at about 200 F. to decompose the blowing agent; The foam coated fiber was then subject to a temperature Within the range of 300 to 350 F. to fuse the composition. After cooling, the composite strand could be woven into a fabric by any conventional weaving means.
Example IV -A rubber latex of the following composition was whipped into a froth by violent agitation in the presence of air:
Phenyl-B-naphthylamine dispersion aid 1.0
' V V 7 Parts.
' 62% solids natural rubber latex 100 20% potassium oleate soap 1.8 50% Zinc diethyldithiocarbonate 1.0 60% sulfur dispersion 2.0 50% zinc salt of mercaptobenzothiozole 1.5
After the whipping process, 5.0 parts of zinc oxide as a 50 percent dispersion and ZiOpa-rts of sodium silicofluoride. as a 20 percent dispersion were added to promote gelling.
The foam was coated on a cotton fiber core by passing the fiber through a coating bath, the excess stripped off and then the coated core subjected to a temperature of 250 F. for 30 minutes to cure and vulcanize the foam rubber. The resulting foam layer had a density of 14 pounds per cubic foot.
Example V An organosol was formulated by grinding the following ingredients on a three-roll mill to produce a suitable coating composition:
- Parts Polyvinyl chloride (dispersion grade) Dioctyl phthalate 15 Tricresyl phosphate 15 Petroleum mineral spirits 20 Methylethyl keton v 2 Stabilizers 5 The composition was sprayed on the surface of'the rug prepared in Example I to form uniform coating of about.
oneto two mils thick. The coating was then heated to 325 F. to fuse the composition. The composition can be used as a clear soil resistant layer in the production of products in accordance with the invention.
Example VI A soil resistant coating composition having the following formulation was prepared:
Multr0n R-12, Mobay Chemical Co., St. Louis, Mo.
Multron R-16, Mobay Chemical 00., St. Louis, Mo.
3 Isocyanate equivalent defined as the number of milligrams of NCO group equivalent to the active hydrogen atoms in 1 gram of the polyester.
*Polyisocyanate prepared by reacting 3 mils of tolylene,
diisocyanate with 1 mil of trimetliylol propane, The result ing compound contains 3 free NCO groups per molecule and has a molecular weight of 656.
in thepreparation of the coating, the polyesters were blended with solvents and flatting agent and then added to a 75 percent by weight solution of the polyisocyanate in methyl Cellosolve acetate. The resulting coatinghad a viscosity of 50 centipOises and contained 56.6 percent non-volatile material. The coating formulation contained percent of the theoretical amount of polyisocyanate required to react with the polyesters. 7
Any departure from the above description which conforms to the present, invention is intended to be included within the scope of the claims.
What is claimed is:
1. A process for producing a fabric having a high degree of resiliency while being substantially inextensible which comprises extruding onto a thread core a smooth, uniformcoating of a resilient plastic composition containing a blowing agent, heating said coated core to a' temperature sufiiciently high to decompose said blowing agent thereby foaming said plastic composition into a resilient coating on said core, weaving said foamed coated core with other threads into a vfabric and heating said Woven fabric to soften said resilient coating to bind said threads together at their point of contact.
2. A process for producing a fabric having a high degree of resiliency while being substantially inextensible which comprises extruding onto a thread core a smooth, uniform coating of a resilient thermoplastic vinyl resinous composition containing a blowing agent, heating said coated core to a temperature sufficiently high to decompose said blowing agent thereby foaming said thermoplastic resinous composition into a resilient coating on said core, weaving said foamed coated core with other threads into a fabric and heating said woven fabric to soften said resilient coating to bind said threads together at their point of contact.
3. The process of claim 2 wherein said vinyl resin is a vinyl chloride resin.
4. The process of claim 2 wherein said thread core is a glass thread.
5. The process of claim 2 wherein said thread core is a nylon thread.
6. The process of claim 2 wherein said thread core is a cotton thread.
7. The process of claim 2 wherein said thread core has a tensile strength of at least 8 pounds and a diameter of about 0.010 to about 0.030 inch and said foam coating on said core has a density of about 6 to about 30 pounds per cubic foot and a thickness of about 0.040 to about 0.40 inch.
8. The process of claim 2 wherein prior to said heating the fabric is coated on one surface with a thin coating of a wear resistant vinyl resin composition.
9. The process of claim 8 wherein said thread core has "a tensile strength of at least 8 pounds and a diameter of about 0.010 to about 0.030 inch and said foam coating on said core has a density of about 6 to about pounds per cubic foot and a thickness of about 0.040 to about 0.40 inch.
References Cited in the file of this patent UNITED STATES PATENTS 1,805,576 Felix May 19, 1931 1,819,344 Slade Aug. 18, 1931 1,923,168 Simmons Aug. 22, 1933 2,218,385 Schulze Oct. 15, 1940 2,268,160 Miles Dec. 30, 1941 2,409,660 Briggs Oct. 22, 1946 2,806,248 Craig Sept. 17, 1957 2,862,282 Beebe Dec. 2, 1958 2,862,284 Wiczer Dec. 2, 1958 2,913,769 Kastli Nov. 24, 1959 2,948,020 DAscoli Aug. 9, 1960 FOREIGN PATENTS 542,577 Belgium Nov. 30, 1955
Claims (1)
1. A PROCESS FOR PRODUCING A FABRIC HAVING A HIGH DEGREE OF RESILIENCY WHILE BEING SUBSTANTIALLY INEXTENSIBLE WHICH COMPRISES EXTRUDING ONTO A THREAD CORE A SMOOTH, UNIFORM COATING OF A RESILIENT PLASTIC COMPOSITION CONTAINING A BLOWING AGENT, HEATING SAID COATED CORE TO A TEMPERATURE SUFFICIENTLY HIGH TO DECOMPOSE SAID BLOWING AGENT THEREBY FOAMING SAID PLASTIC COMPOSITION INTO A RESILIENT COATING ON SAID CORE, WEAVING SAID FOAMED COATED CORE WITH OTHER THREADS INTO A FABRIC AND HEATING SAID WOVEN FABRIC TO SOFTEN SAID RESILIENT COATING TO BIND SAID THREADS TOGETTHER AT THEIR POINT OF CONTACT.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US69847757 US3091019A (en) | 1957-11-25 | 1957-11-25 | Resilient fabrics of expanded core yarns |
US207860 US3091017A (en) | 1957-11-25 | 1960-01-12 | Resilient fabrics |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US69847757 US3091019A (en) | 1957-11-25 | 1957-11-25 | Resilient fabrics of expanded core yarns |
US207860 US3091017A (en) | 1957-11-25 | 1960-01-12 | Resilient fabrics |
Publications (1)
Publication Number | Publication Date |
---|---|
US3091017A true US3091017A (en) | 1963-05-28 |
Family
ID=26669896
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US69847757 Expired - Lifetime US3091019A (en) | 1957-11-25 | 1957-11-25 | Resilient fabrics of expanded core yarns |
US207860 Expired - Lifetime US3091017A (en) | 1957-11-25 | 1960-01-12 | Resilient fabrics |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US69847757 Expired - Lifetime US3091019A (en) | 1957-11-25 | 1957-11-25 | Resilient fabrics of expanded core yarns |
Country Status (1)
Country | Link |
---|---|
US (2) | US3091019A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3335560A (en) * | 1963-10-29 | 1967-08-15 | Ichikawa Ryotaro | Hollow twist synthetic resin and method of producing same |
US3660974A (en) * | 1970-08-31 | 1972-05-09 | Owens Corning Fiberglass Corp | Industrial belt construction |
US3694873A (en) * | 1970-04-02 | 1972-10-03 | Richard P Crowley | Method of preparing a tufted rug with cellular fibers |
US5411689A (en) * | 1993-03-25 | 1995-05-02 | Sealed Air Corporation | Method for accelerating removal of residual blowing agent from extruded flexible foams |
US20050255775A1 (en) * | 2004-05-14 | 2005-11-17 | Chilewich L.L.C. | Fiberglass fabric flooring system |
EP2530195A1 (en) * | 2011-05-31 | 2012-12-05 | Mattes & Ammann GmbH & Co. KG | Knit or woven fabric, method and thread for producing same and use of same |
US20150031481A1 (en) * | 2013-07-29 | 2015-01-29 | Psi 91, Inc. | Game ball |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3244545A (en) * | 1961-05-10 | 1966-04-05 | Owens Corning Fiberglass Corp | Cellular resins reinforced with siliceous material |
GB971655A (en) * | 1961-12-29 | 1964-09-30 | Sekisui Adoheya Kogyo Kabushik | Method for the preparation of foamed thermoplastic resincoated articles |
US3326865A (en) * | 1963-03-27 | 1967-06-20 | Dow Chemical Co | Sulfoxide resins |
US3300554A (en) * | 1963-09-27 | 1967-01-24 | Western Electric Co | Method of making cellular articles |
US3547608A (en) * | 1967-11-08 | 1970-12-15 | Noboru Kitazawa | Method of manufacturing an impregnated fibrous grinding article |
US3538700A (en) * | 1968-07-16 | 1970-11-10 | Union Carbide Corp | Glass rovings impregnated with thermoplastic polyurethane resins |
US3546325A (en) * | 1968-11-19 | 1970-12-08 | Celfil Co | Method of manufacturing filter ropes |
US4263362A (en) * | 1979-11-23 | 1981-04-21 | Ppg Industries, Inc. | Coating composition for glass fibers and coated glass fibers made from same |
US5695580A (en) * | 1995-09-21 | 1997-12-09 | Huarng; Hermes | Composite material made integrally of a foam material and a fiber material and method of making same |
DE102006011610A1 (en) * | 2006-03-14 | 2007-09-20 | Gottlieb Binder Gmbh & Co. Kg | Seat fastening system and tubular fastening strap |
JP7377497B2 (en) | 2018-03-01 | 2023-11-10 | 株式会社レゾナック | Anisotropic thermally conductive resin member and manufacturing method thereof |
JP7388348B2 (en) * | 2018-03-01 | 2023-11-29 | 株式会社レゾナック | Anisotropically thermally conductive resin fiber, anisotropically thermally conductive resin member, and manufacturing method thereof |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE542577A (en) * | 1954-11-04 | |||
US1805576A (en) * | 1926-09-24 | 1931-05-19 | Benjamin B Felix | Cushioning strip |
US1819344A (en) * | 1928-04-05 | 1931-08-18 | Slade Edward | Brake lining and method of making the same |
US1923168A (en) * | 1931-02-05 | 1933-08-22 | United Shoe Machinery Corp | Method of making woven fabrics |
US2218385A (en) * | 1935-02-20 | 1940-10-15 | Gen Electric | Method of making an insulated electrical conductor |
US2268160A (en) * | 1939-06-21 | 1941-12-30 | Du Pont | Spongy superpolymer |
US2409660A (en) * | 1945-08-11 | 1946-10-22 | Walter S Briggs | Mop yarn and mop made therefrom |
US2806248A (en) * | 1944-06-09 | 1957-09-17 | Burnie J Craig | Apparatus for making a threadlike member |
US2862282A (en) * | 1954-12-27 | 1958-12-02 | Soo Valley Company | Fly casting line with tapered cellular waterproof plastic coating |
US2862284A (en) * | 1953-05-04 | 1958-12-02 | Sol B Wiczer | Modified filament and method |
US2913769A (en) * | 1948-04-08 | 1959-11-24 | Kastli Leo | Process of puffing dry regenerated cellulose and cellulose acetate textile fibers by generating oxygen in situ and precipitating barium sulphate within the fibers |
US2948020A (en) * | 1953-11-06 | 1960-08-09 | Anaconda Wire & Cable Co | Method of making high frequency cable |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1002829A (en) * | 1908-10-07 | 1911-09-12 | Knuland Shaffer | Sponge thread. |
BE351699A (en) * | 1927-06-09 | 1900-01-01 | ||
US2298986A (en) * | 1940-02-07 | 1942-10-13 | Dunlop Rubber Co | Cushioning material of spongelike or cellular rubber |
US2419328A (en) * | 1943-08-10 | 1947-04-22 | Watson John Hill | Manufacture of string or the like |
US2484125A (en) * | 1943-09-25 | 1949-10-11 | Silvain Andre | Elastic fabric |
US2631355A (en) * | 1944-06-09 | 1953-03-17 | Burnie J Craig | Composition and process of making the same |
US2520699A (en) * | 1944-08-16 | 1950-08-29 | Angus George Co Ltd | Belting |
US2600143A (en) * | 1947-02-14 | 1952-06-10 | Sidney P Vaughn | Cellulose sponge yarn |
US2769222A (en) * | 1950-04-10 | 1956-11-06 | Southwell Mary Elizabeth | Fabric and method of making same |
US2812570A (en) * | 1951-10-26 | 1957-11-12 | Franz R Lushas | Hardened molded articles |
-
1957
- 1957-11-25 US US69847757 patent/US3091019A/en not_active Expired - Lifetime
-
1960
- 1960-01-12 US US207860 patent/US3091017A/en not_active Expired - Lifetime
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1805576A (en) * | 1926-09-24 | 1931-05-19 | Benjamin B Felix | Cushioning strip |
US1819344A (en) * | 1928-04-05 | 1931-08-18 | Slade Edward | Brake lining and method of making the same |
US1923168A (en) * | 1931-02-05 | 1933-08-22 | United Shoe Machinery Corp | Method of making woven fabrics |
US2218385A (en) * | 1935-02-20 | 1940-10-15 | Gen Electric | Method of making an insulated electrical conductor |
US2268160A (en) * | 1939-06-21 | 1941-12-30 | Du Pont | Spongy superpolymer |
US2806248A (en) * | 1944-06-09 | 1957-09-17 | Burnie J Craig | Apparatus for making a threadlike member |
US2409660A (en) * | 1945-08-11 | 1946-10-22 | Walter S Briggs | Mop yarn and mop made therefrom |
US2913769A (en) * | 1948-04-08 | 1959-11-24 | Kastli Leo | Process of puffing dry regenerated cellulose and cellulose acetate textile fibers by generating oxygen in situ and precipitating barium sulphate within the fibers |
US2862284A (en) * | 1953-05-04 | 1958-12-02 | Sol B Wiczer | Modified filament and method |
US2948020A (en) * | 1953-11-06 | 1960-08-09 | Anaconda Wire & Cable Co | Method of making high frequency cable |
BE542577A (en) * | 1954-11-04 | |||
US2862282A (en) * | 1954-12-27 | 1958-12-02 | Soo Valley Company | Fly casting line with tapered cellular waterproof plastic coating |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3335560A (en) * | 1963-10-29 | 1967-08-15 | Ichikawa Ryotaro | Hollow twist synthetic resin and method of producing same |
US3694873A (en) * | 1970-04-02 | 1972-10-03 | Richard P Crowley | Method of preparing a tufted rug with cellular fibers |
US3660974A (en) * | 1970-08-31 | 1972-05-09 | Owens Corning Fiberglass Corp | Industrial belt construction |
US5411689A (en) * | 1993-03-25 | 1995-05-02 | Sealed Air Corporation | Method for accelerating removal of residual blowing agent from extruded flexible foams |
US20080006364A1 (en) * | 2004-05-14 | 2008-01-10 | Chilewich Llc | Fiberglass fabric flooring system |
EP1755880A2 (en) * | 2004-05-14 | 2007-02-28 | Chilewich L.l.c. | Fiberglass fabric flooring system |
US20050255775A1 (en) * | 2004-05-14 | 2005-11-17 | Chilewich L.L.C. | Fiberglass fabric flooring system |
US7326661B2 (en) | 2004-05-14 | 2008-02-05 | Chilewich L.L.C. | Fiberglass fabric flooring system |
EP1755880A4 (en) * | 2004-05-14 | 2009-09-23 | Chilewich L L C | Fiberglass fabric flooring system |
US7850802B2 (en) | 2004-05-14 | 2010-12-14 | Chilewich L.L.C. | Fiberglass fabric flooring system |
EP2530195A1 (en) * | 2011-05-31 | 2012-12-05 | Mattes & Ammann GmbH & Co. KG | Knit or woven fabric, method and thread for producing same and use of same |
US20150031481A1 (en) * | 2013-07-29 | 2015-01-29 | Psi 91, Inc. | Game ball |
US9089740B2 (en) * | 2013-07-29 | 2015-07-28 | Psi 91, Inc. | Game ball |
US9956458B2 (en) | 2013-07-29 | 2018-05-01 | Psi 91, Inc. | Game ball |
Also Published As
Publication number | Publication date |
---|---|
US3091019A (en) | 1963-05-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3091017A (en) | Resilient fabrics | |
US4265972A (en) | Coated fibers and related process | |
US3485711A (en) | Low-density web-like cushioning structure of cellular filamentary material | |
US3837988A (en) | Composite mat | |
US2784630A (en) | Method of making flocked fabric and flocked vinyl | |
US5305565A (en) | Floor mat with prevention of waving | |
US3284274A (en) | Cellular polymeric sheet material and method of making same | |
US5290591A (en) | Decorative inlaid types of sheet materials for commercial use | |
US3933548A (en) | Production of urethane foams and laminates thereof | |
US5169704A (en) | Decorative inlaid sheet materials having multiple printed layers | |
US3100926A (en) | Method of producing expanded fabric-like material | |
US3761346A (en) | Composite linear material and process of making such material | |
US3620890A (en) | Floor and wall covering and method of making same | |
US3694873A (en) | Method of preparing a tufted rug with cellular fibers | |
US3634184A (en) | Elastomeric film and products therefrom | |
US3389446A (en) | Process for producing foam fabrics | |
US5571588A (en) | Durable inlaid floor coverings having a uniform, unpatterned decorative appearance | |
US3709752A (en) | Method of making suede-like plastic | |
US3275720A (en) | Method of extruding foamed fibers having outer skins integral therewith | |
US5407617A (en) | Method of forming latex-, PVC- and plasticizer-free foamed floor or wall coverings | |
US3238055A (en) | Poromeric material and method of making same | |
US2903387A (en) | Fibrous webs and method for their production | |
US2962406A (en) | Method of making upholstery materials | |
US4618530A (en) | Process for the preparation of a composite mat | |
DE102012216871A1 (en) | Eco-friendly tufted carpet for a vehicle with improved abrasion resistance |