US3085849A - Process for dyeing and printing cellulose-containing fibres and composition for same - Google Patents
Process for dyeing and printing cellulose-containing fibres and composition for same Download PDFInfo
- Publication number
- US3085849A US3085849A US94704A US9470461A US3085849A US 3085849 A US3085849 A US 3085849A US 94704 A US94704 A US 94704A US 9470461 A US9470461 A US 9470461A US 3085849 A US3085849 A US 3085849A
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- United States
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- dyeing
- sodium
- printing
- salts
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- Expired - Lifetime
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- 238000004043 dyeing Methods 0.000 title claims description 38
- 238000000034 method Methods 0.000 title claims description 19
- 239000000203 mixture Substances 0.000 title claims description 8
- 229920002678 cellulose Polymers 0.000 title description 8
- 239000001913 cellulose Substances 0.000 title description 8
- 239000002253 acid Substances 0.000 claims description 17
- 239000003223 protective agent Substances 0.000 claims description 9
- 150000007513 acids Chemical class 0.000 claims description 8
- 239000000975 dye Substances 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 8
- 238000005562 fading Methods 0.000 claims description 7
- IBYSTTGVDIFUAY-UHFFFAOYSA-N vanadium monoxide Chemical class [V]=O IBYSTTGVDIFUAY-UHFFFAOYSA-N 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 12
- -1 alkali metal salts Chemical class 0.000 description 12
- 229910052700 potassium Inorganic materials 0.000 description 12
- 239000011591 potassium Substances 0.000 description 12
- CMZUMMUJMWNLFH-UHFFFAOYSA-N sodium metavanadate Chemical compound [Na+].[O-][V](=O)=O CMZUMMUJMWNLFH-UHFFFAOYSA-N 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 8
- 159000000000 sodium salts Chemical class 0.000 description 8
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical class [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 8
- 229910052783 alkali metal Inorganic materials 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 239000000344 soap Substances 0.000 description 6
- WKCZSFRAGKIIKN-UHFFFAOYSA-N 2-(4-tert-butylphenyl)ethanamine Chemical compound CC(C)(C)C1=CC=C(CCN)C=C1 WKCZSFRAGKIIKN-UHFFFAOYSA-N 0.000 description 5
- ONMOULMPIIOVTQ-UHFFFAOYSA-N 98-47-5 Chemical compound OS(=O)(=O)C1=CC=CC([N+]([O-])=O)=C1 ONMOULMPIIOVTQ-UHFFFAOYSA-N 0.000 description 5
- 229920003043 Cellulose fiber Polymers 0.000 description 5
- 229920000297 Rayon Polymers 0.000 description 5
- SPXOTSHWBDUUMT-UHFFFAOYSA-N 138-42-1 Chemical class OS(=O)(=O)C1=CC=C([N+]([O-])=O)C=C1 SPXOTSHWBDUUMT-UHFFFAOYSA-N 0.000 description 4
- PAJMKGZZBBTTOY-UHFFFAOYSA-N 2-[[2-hydroxy-1-(3-hydroxyoctyl)-2,3,3a,4,9,9a-hexahydro-1h-cyclopenta[g]naphthalen-5-yl]oxy]acetic acid Chemical compound C1=CC=C(OCC(O)=O)C2=C1CC1C(CCC(O)CCCCC)C(O)CC1C2 PAJMKGZZBBTTOY-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 239000000976 ink Substances 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- 125000001424 substituent group Chemical group 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 4
- IHIXIJGXTJIKRB-UHFFFAOYSA-N trisodium vanadate Chemical compound [Na+].[Na+].[Na+].[O-][V]([O-])([O-])=O IHIXIJGXTJIKRB-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- 229910006069 SO3H Inorganic materials 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- OVOJUAKDTOOXRF-UHFFFAOYSA-N 2,4-dinitrobenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O OVOJUAKDTOOXRF-UHFFFAOYSA-N 0.000 description 2
- JWSNVFJCKKXKRE-UHFFFAOYSA-N 3,5-dinitrobenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1 JWSNVFJCKKXKRE-UHFFFAOYSA-N 0.000 description 2
- HWTDMFJYBAURQR-UHFFFAOYSA-N 80-82-0 Chemical compound OS(=O)(=O)C1=CC=CC=C1[N+]([O-])=O HWTDMFJYBAURQR-UHFFFAOYSA-N 0.000 description 2
- 229910002480 Cu-O Inorganic materials 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 241000083869 Polyommatus dorylas Species 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- WDCYWAQPCXBPJA-UHFFFAOYSA-N 1,3-dinitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC([N+]([O-])=O)=C1 WDCYWAQPCXBPJA-UHFFFAOYSA-N 0.000 description 1
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
- GVBHCMNXRKOJRH-UHFFFAOYSA-N 2,4,5,6-tetrachloropyrimidine Chemical compound ClC1=NC(Cl)=C(Cl)C(Cl)=N1 GVBHCMNXRKOJRH-UHFFFAOYSA-N 0.000 description 1
- JVMSQRAXNZPDHF-UHFFFAOYSA-N 2,4-diaminobenzenesulfonic acid Chemical compound NC1=CC=C(S(O)(=O)=O)C(N)=C1 JVMSQRAXNZPDHF-UHFFFAOYSA-N 0.000 description 1
- NUMXHEUHHRTBQT-AATRIKPKSA-N 2,4-dimethoxy-1-[(e)-2-nitroethenyl]benzene Chemical compound COC1=CC=C(\C=C\[N+]([O-])=O)C(OC)=C1 NUMXHEUHHRTBQT-AATRIKPKSA-N 0.000 description 1
- ZMCHBSMFKQYNKA-UHFFFAOYSA-N 2-aminobenzenesulfonic acid Chemical compound NC1=CC=CC=C1S(O)(=O)=O ZMCHBSMFKQYNKA-UHFFFAOYSA-N 0.000 description 1
- 240000008564 Boehmeria nivea Species 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- 125000006414 CCl Chemical group ClC* 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 101000976697 Homo sapiens Inter-alpha-trypsin inhibitor heavy chain H1 Proteins 0.000 description 1
- 102100023490 Inter-alpha-trypsin inhibitor heavy chain H1 Human genes 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 150000001454 anthracenes Chemical class 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- POJOORKDYOPQLS-UHFFFAOYSA-L barium(2+) 5-chloro-2-[(2-hydroxynaphthalen-1-yl)diazenyl]-4-methylbenzenesulfonate Chemical compound [Ba+2].C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O.C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O POJOORKDYOPQLS-UHFFFAOYSA-L 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229940018564 m-phenylenediamine Drugs 0.000 description 1
- 150000002696 manganese Chemical class 0.000 description 1
- ALTWGIIQPLQAAM-UHFFFAOYSA-N metavanadate Chemical compound [O-][V](=O)=O ALTWGIIQPLQAAM-UHFFFAOYSA-N 0.000 description 1
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical class N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 125000000714 pyrimidinyl group Chemical group 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- ORFSSYGWXNGVFB-UHFFFAOYSA-N sodium 4-amino-6-[[4-[4-[(8-amino-1-hydroxy-5,7-disulfonaphthalen-2-yl)diazenyl]-3-methoxyphenyl]-2-methoxyphenyl]diazenyl]-5-hydroxynaphthalene-1,3-disulfonic acid Chemical compound COC1=C(C=CC(=C1)C2=CC(=C(C=C2)N=NC3=C(C4=C(C=C3)C(=CC(=C4N)S(=O)(=O)O)S(=O)(=O)O)O)OC)N=NC5=C(C6=C(C=C5)C(=CC(=C6N)S(=O)(=O)O)S(=O)(=O)O)O.[Na+] ORFSSYGWXNGVFB-UHFFFAOYSA-N 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- YXZRCLVVNRLPTP-UHFFFAOYSA-J turquoise blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Cu+2].NC1=NC(Cl)=NC(NC=2C=C(NS(=O)(=O)C3=CC=4C(=C5NC=4NC=4[N-]C(=C6C=CC(=CC6=4)S([O-])(=O)=O)NC=4NC(=C6C=C(C=CC6=4)S([O-])(=O)=O)NC=4[N-]C(=C6C=CC(=CC6=4)S([O-])(=O)=O)N5)C=C3)C(=CC=2)S([O-])(=O)=O)=N1 YXZRCLVVNRLPTP-UHFFFAOYSA-J 0.000 description 1
- WQEVDHBJGNOKKO-UHFFFAOYSA-K vanadic acid Chemical compound O[V](O)(O)=O WQEVDHBJGNOKKO-UHFFFAOYSA-K 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
- D06P1/628—Compounds containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/67341—Salts or hydroxides of elements different from the alkaline or alkaline-earth metals or with anions containing those elements
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/918—Cellulose textile
Definitions
- the present invention concerns a process for the dyeing and printing of fibres containing cellulose with reactive dyestuffs, the dyes and printing pastes used accr-oding to thech invention and the material fast dyed or printed there- 'Wl
- the shade and colour strength of certain substantive dyestuffs is disadvantageously influenced.
- This phenomenon is known in the trade as boil fading. This boil fading, which is principally due to a reduction process, is caused either by the textiles themselves or by impurities adhering to them or also present in the dyebath. This phenomenon can be prevented or at least minimised by the addition of salts of nitrated aromatic sulphonic acids to the dye bath or to the printing paste.
- alkali metal and ammonium salts of mononitrobenzene sulphonic acid especially m-nitrobenzene sulphonic acid, and dinitrobenzcne sulphonic acid as well as mixtures of same are suitable.
- the vanadates usual as contact substances in oxidationreduction processes are used as salts of vanadium oxygen acids. As they are used in the present process in very small amounts, in order to attain a good distribution they should be Water soluble in the dyeing or printing agent. Aduantageously soluble salts as ammonium vanadates, alkali metal vanadates and mixtures of same are applicable. 'lhe alkali vanadates are preferred but also ammonium and amine salts of vanadic acids can be used. It has been found that simple salts, double salts and also complex salts of meta-, orthoand pyro-vanadates can be used; preferred compounds are the ammonium, sodium, potassium and lithium metavanadates.
- the reactive dyestuffs with which dyeings and prints without boil fading effects are obtained according to the 3,085,849 Patented Apr. 16, 1963 invention on fibres containing cellulose such as cotton, viscose rayon, staple fibre, jute, ramie and hemp by the new process, can belong to the most various classes of dyestuffs, for example, the azo, anthraquinone or phthalocyanine series. In particular they can also contain heavy metal bound in complex linkage.
- the reactive egroups of these dyestuffs can be any substituent which reacts with alkalies while splitting off as anion at temperatures such as are usual in dyeing and printing processes with reactive dyestuffs.
- the reactive substituent can be the radical of a fl-halogen fatty acid or the radical of a cyclic carbimide halide which contains at least one halogen atom at a ring carbon atom adjacent to a tertiary ring nitrogen atom.
- this substituent can consist of an azine ring of aromatic character which contains at least two tertiary ring nitro-' gen atoms and at least one halogen of the atomic numbers 17 to 35 at ring carbon atoms adjacent thereto, that is, for example, a mono-, dior tri-halogen diazinyl radical and, in particular, a trichloropyrimidyl radical.
- the fibres containing cellulose are dyed and printed with reactive dyestuffs with the addition of protecting agents according to the present process, by the methods usual for this class of dyestuffs.
- the advantageous effect of the protecting agents used according to this invention is apparent particularly in the Wet development processes such as e.g. the so-called pad-steam process and the single bath-steam process; but also the use of the protecting agents according to the invention is often indicated in dry development process, i.e. in the so-called thermofix process. Their effect is particularly striking in the dyeing and printing of synthetic silks such as viscose and cuprammonimn rayon and staple fibre.
- the use of the protecting agents as defined in the dyeing and printing of fibres containing cellulose with reactive dyestuffs does not cause any disadvantageous side effects, for example it does not prejudice the fastness of the dyeings and prints. Often, even an easier fixation of the dyestuffs onto the fibre is noticeable in that stronger dyeings are obtained than when there are no protecting agents present.
- reactive dyestuffs having a polyhalogenpyrimidine group as reactive substituent are isomeric mixtures as on being reacted with trior tetra-halogen pyrimidines it is ditficult to determine which halogen atom reacts with the amino group of the dyestuff.
- the pyrimidine radical can be bound in the 2- or 4-position.
- the bond is shown in the 2-position of the pyrimidine ring.
- parts are given in the examples as parts by weight.
- the relationship of parts by weight to parts by volume is as that of grammes to cubic centimetres.
- the temperatures are in degrees centigrade.
- EXAMPLE 1 50 parts of urea, 20 parts of sodium carbonate, 10 parts of the sodium salt of 3-nitrobenzene sulphonic acid and 1 minutes. The goods so treated are rinsed hot and soaped at the boil for 30 minutes with a solution which contains 1 part of grain soap per 1000 parts of water. A strong, vivid yellow dyeing is obtained. If the same procedure is followed but no sodium metavanadate is used, then a considerably weaker and more cloudy dyeing is obtained.
- N O SOaH HOaS- J CH3 4 ⁇ N 11038 s opera-om-o O--NHC SOaH g I /N Yellow.
- the goods are first rinsed cold and then soaped C for 3 minutes at the boil with a solution of 1 part of I 51 grain soap in 1000 parts of water. A pure, level orange H038 HOgS- S03H dyeing is obtained.
- H0 NH-CO-CH O-CH3 1 4.--.
- N N- Brilliant red.
- HOxS- NHO N C O 3-... HOaS- N N Reddish black.
- EXAMPLE 6 3 parts of the dyestuff obtained by condensing 1 mol of copper phthalocyanine disulphonic acid disulphochloride with 2 mols of 4,4'-diaminodiphenyl-2,2-disulphonic acid and then with 2 mols of fl-chlorocrotonic acid chloride, are dissolved in 2000 parts of water and 10 parts of the sodium salt of 3-nitrobenzenersulphonic acid, 0.3 part of sodium metavanadate and 5 parts of trisodium phosphate are added. 100 parts of cotton are entered at -25 and the bath is heated to 80-85 while gradually adding 100 g. of sodium chloride per litre in portions. Dyeing is continued for 60 minutes at this temperature,
- Process for the dyeing and printing of cellulosecontaining fibre which comprises treating in alkaline medium, said fibre with a composition containing a reactive dyestuif and, as protective agents against boil fading phenomena, salts of nitrated aromatic sulphonic acids and small amounts of soluble salts of vanadium oxygen acids.
- the soluble salt of vanadium oxygen acid is a member selected from the group consisting of ammonium vanadates and alkali metal vanadates.
- a dyeing and printing composition for cellulosecontaining fibres comprising, in alkaline medium, a reactive dyestuif and, as protective agents against boil fad- Refet'ences Cited in the file of this patent UNITED STATES PATENTS 2,205,887 Kern June 25, 1940 2,278,540 Ellis et a1. Apr. 7, 1942 2,880,052 Conciatori et al. Mar. 31, 1959 2,891,941 Fasciati et al. June 23, 1958
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH276760A CH365695A (de) | 1960-03-11 | 1960-03-11 | Verfahren zum Färben und Bedrucken von Textilfasern aus cellulosehaltigem Material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3085849A true US3085849A (en) | 1963-04-16 |
Family
ID=4241146
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US94704A Expired - Lifetime US3085849A (en) | 1960-03-11 | 1961-03-10 | Process for dyeing and printing cellulose-containing fibres and composition for same |
Country Status (7)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0209494A1 (de) * | 1985-07-19 | 1987-01-21 | Ciba-Geigy Ag | Verfahren zum Nuancenstabilen Färben oder Bedrucken |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57105459A (en) * | 1980-12-22 | 1982-06-30 | Sumitomo Chem Co Ltd | Liquid composition of reactive dye |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2205887A (en) * | 1938-06-02 | 1940-06-25 | Nat Aniline & Chem Co Inc | Coloring textile materials |
| US2278540A (en) * | 1937-09-01 | 1942-04-07 | Celanese Corp | Production or treatment of pigments and textile and other materials containing them |
| US2880052A (en) * | 1954-05-17 | 1959-03-31 | Celanese Corp | Dyeing cellulose derivatives and aftertreating for improved washfastness |
| US2891941A (en) * | 1956-06-29 | 1959-06-23 | Ciba Ltd | Water soluble triazine azo dyestuffs |
-
0
- BE BE601246D patent/BE601246A/xx unknown
-
1960
- 1960-03-11 CH CH276760A patent/CH365695A/de unknown
-
1961
- 1961-03-10 GB GB8792/61A patent/GB914051A/en not_active Expired
- 1961-03-10 US US94704A patent/US3085849A/en not_active Expired - Lifetime
- 1961-03-10 ES ES0265555A patent/ES265555A1/es not_active Expired
- 1961-03-10 DE DEG31801A patent/DE1132539B/de active Pending
- 1961-03-10 FR FR855272A patent/FR1283569A/fr not_active Expired
- 1961-03-13 BE BE601240A patent/BE601240A/fr unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2278540A (en) * | 1937-09-01 | 1942-04-07 | Celanese Corp | Production or treatment of pigments and textile and other materials containing them |
| US2205887A (en) * | 1938-06-02 | 1940-06-25 | Nat Aniline & Chem Co Inc | Coloring textile materials |
| US2880052A (en) * | 1954-05-17 | 1959-03-31 | Celanese Corp | Dyeing cellulose derivatives and aftertreating for improved washfastness |
| US2891941A (en) * | 1956-06-29 | 1959-06-23 | Ciba Ltd | Water soluble triazine azo dyestuffs |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0209494A1 (de) * | 1985-07-19 | 1987-01-21 | Ciba-Geigy Ag | Verfahren zum Nuancenstabilen Färben oder Bedrucken |
| US4828572A (en) * | 1985-07-19 | 1989-05-09 | Ciba-Geigy Corporation | Process for dyeing or printing textile fibre materials in stable black shades using metal complex reactive dyes with a red shift and a yellow or green shift |
Also Published As
| Publication number | Publication date |
|---|---|
| BE601240A (fr) | 1961-09-13 |
| BE601246A (US07223432-20070529-C00017.png) | |
| CH365695A (de) | 1962-08-15 |
| ES265555A1 (es) | 1961-10-16 |
| DE1132539B (de) | 1962-07-05 |
| GB914051A (en) | 1962-12-28 |
| FR1283569A (fr) | 1962-02-02 |
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