US307607A - Chaeles weygang - Google Patents
Chaeles weygang Download PDFInfo
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- US307607A US307607A US307607DA US307607A US 307607 A US307607 A US 307607A US 307607D A US307607D A US 307607DA US 307607 A US307607 A US 307607A
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- United States
- Prior art keywords
- add
- size
- sulphate
- solution
- glue
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- Expired - Lifetime
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- 239000000463 material Substances 0.000 description 86
- 150000003839 salts Chemical class 0.000 description 72
- 239000011780 sodium chloride Substances 0.000 description 72
- 239000003292 glue Substances 0.000 description 60
- 239000000243 solution Substances 0.000 description 58
- 238000000034 method Methods 0.000 description 50
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 50
- 239000002253 acid Substances 0.000 description 40
- 239000000203 mixture Substances 0.000 description 34
- 238000004513 sizing Methods 0.000 description 34
- 239000002244 precipitate Substances 0.000 description 32
- 229920002472 Starch Polymers 0.000 description 30
- 239000003513 alkali Substances 0.000 description 30
- 235000019698 starch Nutrition 0.000 description 30
- 239000008107 starch Substances 0.000 description 30
- 230000001376 precipitating Effects 0.000 description 26
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 24
- NLXLAEXVIDQMFP-UHFFFAOYSA-N ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 24
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 22
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 18
- 239000003518 caustics Substances 0.000 description 18
- 235000013312 flour Nutrition 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 18
- 239000011701 zinc Substances 0.000 description 18
- 229910052725 zinc Inorganic materials 0.000 description 18
- 239000002657 fibrous material Substances 0.000 description 16
- BPQQTUXANYXVAA-UHFFFAOYSA-N silicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 16
- 239000000126 substance Substances 0.000 description 16
- BIGPRXCJEDHCLP-UHFFFAOYSA-N Ammonium bisulfate Chemical compound [NH4+].OS([O-])(=O)=O BIGPRXCJEDHCLP-UHFFFAOYSA-N 0.000 description 14
- 239000003795 chemical substances by application Substances 0.000 description 14
- 239000010985 leather Substances 0.000 description 14
- 210000003284 Horns Anatomy 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- 210000000988 Bone and Bones Anatomy 0.000 description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
- 239000000835 fiber Substances 0.000 description 10
- 239000002023 wood Substances 0.000 description 10
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L Calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 8
- XMXNVYPJWBTAHN-UHFFFAOYSA-N Potassium chromate Chemical compound [K+].[K+].[O-][Cr]([O-])(=O)=O XMXNVYPJWBTAHN-UHFFFAOYSA-N 0.000 description 8
- 230000001070 adhesive Effects 0.000 description 8
- 238000010009 beating Methods 0.000 description 8
- UXVMQQNJUSDDNG-UHFFFAOYSA-L cacl2 Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 8
- 229910001628 calcium chloride Inorganic materials 0.000 description 8
- 239000011259 mixed solution Substances 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 239000000853 adhesive Substances 0.000 description 6
- 239000001110 calcium chloride Substances 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 230000000875 corresponding Effects 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 238000003825 pressing Methods 0.000 description 6
- 238000009877 rendering Methods 0.000 description 6
- 239000012047 saturated solution Substances 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000004575 stone Substances 0.000 description 6
- WDIHJSXYQDMJHN-UHFFFAOYSA-L Barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 4
- QVQLCTNNEUAWMS-UHFFFAOYSA-N Barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 4
- ARUVKPQLZAKDPS-UHFFFAOYSA-L Copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 4
- KMUONIBRACKNSN-UHFFFAOYSA-N Potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 4
- 235000015450 Tilia cordata Nutrition 0.000 description 4
- 235000011941 Tilia x europaea Nutrition 0.000 description 4
- 229910001626 barium chloride Inorganic materials 0.000 description 4
- 229910001864 baryta Inorganic materials 0.000 description 4
- 239000001175 calcium sulphate Substances 0.000 description 4
- 235000011132 calcium sulphate Nutrition 0.000 description 4
- 239000003925 fat Substances 0.000 description 4
- 159000000011 group IA salts Chemical class 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000004571 lime Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 240000008564 Boehmeria nivea Species 0.000 description 2
- 240000000218 Cannabis sativa Species 0.000 description 2
- HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 description 2
- 210000003491 Skin Anatomy 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- -1 bone Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 235000009120 camo Nutrition 0.000 description 2
- 235000005607 chanvre indien Nutrition 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000009950 felting Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000011487 hemp Substances 0.000 description 2
- 235000012765 hemp Nutrition 0.000 description 2
- 150000002505 iron Chemical class 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 235000012766 marijuana Nutrition 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000001264 neutralization Effects 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000036633 rest Effects 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/22—Proteins
Definitions
- the principal object of this invention is to' incorporate animal glue, starch, or ilour with a fibrous pulp prepared by paper machinery by precipitating the glue, starch, or flour in the fibrous pulp and-treating these materials in such a manner as to render them more or less impervious to water, while not materially injuring their valuable binding property, so
- the fibers with which they are combined may be caused to unite, and by varying the proceedings as hereinafter described the invention may be applied to the sizing of ordinary paper or for the production of material applicable for some of the many purposes for which parchment,leather, wood, horn, bone, and stone, &c., are employed.
- I dissolve the same in any convenient manner, and Iadtl the solution to the fibrous pulp in the beating-engine or other suitable mixing apparatus.
- I then add one or more astringent metallic salts of nature appropriate to the kind of material to be produced.
- I then add a caustic alkali or an alkaline earth, or a salt of an alkali or an alkaline earth, taking care that the acid of the metallic salt is in excess, or that otherwise an acid is in excess, the object being to cause the formation of a nascent oxide or an acid or an interchange of elements in the glue in solution, whereby this is energetically attached and precipitated in the fibrous pulp.
- I may for some purposes use non-metallic elements which have chemical affinity for the glue.
- the fibers and the quality of the glue are chosen according to the nature of the material to be produced.
- very strong purposes such as for substitutes for leather-the strongest classcs ot' fibers are employed, such as 7 5 hemp, china-grass, 8:0.
- the fibrous materials are treated in the same manner as in papermaking, and in beating are kept of greater or shorter length, according to the material to be produced.
- the material is to stand great tensile strain, the fibers are kept of as great a length as possible.
- the glue is also chosen according to the material to be produced. For instance, for material to take the place of leather I prefer to employ such as is made from skin and hide pieces.
- a good-proportion is about three hundred-weight of size of average consistency to about one lmndred-wcight olifi hrous pulp, reckoning the latterin dry weight.
- a good-proportion is about three hundred-weight of size of average consistency to about one lmndred-wcight olifi hrous pulp, reckoning the latterin dry weight.
- one and one-half to two and one-half l'lundredweight of size is usually However, as such a variety of maemployed.
- No. 1.I add for every hundred-weight of size in the beating-engine about five pounds of an acid salt of zinc or alumina in a dry state or in solution.
- I prefer the sulphates of these metals, and I can use them. either separately or combined, in a proportion of about two pounds of the sulphate of zinc and about four pounds of the sulphate of alumina.
- a caustic alkali such as soda hydrate-in a proportion of about one pound to every five pounds of metallic sulphate employed
- I prefer to use a sulphate or a sulphate of an alkali and I find that the sulphate of ammonia in a proportion of about eight pounds to every hundred-weight of size gives the best result.
- portion .of the copper or iron salt is about five first add a solution of soda hyposulphite in' about the same proportion as the acid metallic salts employed, and the ammonia sulphate in a proportion of about one-third of the soda hyposulphite employed.
- I may, under certain circumstances, employ an alkaline silicate, for which purpose I prefer to proceed as follows: Imix with every hundredweight of size from one-fourth to three-fourths hundred-weight of an ordinary solution of an alkaline silicate, such as silicate of soda. Iincorporate the size andsilica with the pulp in the beating-engine, and I now add a compound of chloride, by preference ammonia chloride, of which I add a solution to the matter in the beating-engine until no more precipitate forms.
- a salt of chlorine I can use with very good results a small quantity ofhydrochloric acid in a proportion of about one-eighth of the weight of the silicate employed, and I then add ammonia sulphate until no more precipitate will form.
- No. 9.I employ a salt of an alkaline earth, and I prefer to use the calcium chloride with hydrochloric acid in excessthat is, to a saturated solution of ordinary calcium chloride I add from one-half to an equal quantity in I bulk of hydrochloric acid. Of this solution I add about one and one-half gallon to every four gallons of size contained in the beatingengine. I then add a saturated solution of soda hyposulphite,in aproportion ofabout two gallons to every one and one-half gallon of calcium chloride and acid employed, and when thoroughly mixed with the size and the pulp I add a small quantity of ammonia sulphate, for the purpose of improving the precipitate.
- the box is placed above the drum of the paper-machine, extending its whole length with the narrow end downward.
- the box is open at the bottom, the aperture being cove-red by a roller which rests upon the drum and revolves with the same, giving oif the glue taken from the box to the layer ofthe pulp upon the drum.
- Flaps attached to the box at each side of the roller are drawn together or opened by means of screws, and thus by opening or pressing on the roller regulate or stop the flow of size from the box
- the glue in material made in this manner being homogencous,snch material does not require the treatment with heat, as hereinafterdescribed.
- the pressure is brought to bear very gradually upon the material, so'as to allow the water to pass out without disturbing the felt ing of the fibers.
- the material is allowed to remain in thepress until no more water escapes, and it isthcn hung up and dried in suitable rooms,which may be slightly warmed forthe purpose of causing a dry atmosphere.
- the processes described under Nos. 1, 2, 3, 4, 5, 6, 7, 9, andthe corresponding processes under Nos. 6 and 11 are adaptable to this method of rendering the material homogeneous.
- the omission of the ammonia chloride as mentioned does not hinder the materiat from becoming adhesive.
- Glue treated by the processes Nos. 8 and 10 does not become adhesive by heat, but in drying the particles of glue set to a solid mass. Therefore material made by processes Nos.
- No. 7 produces a sizing which, when dry, is perfectly foreign to water or damp, and is therefore applicable for all kinds of building purposes, being especially adapted for such purposes, as this process renders the material almost fire-proof. It is also useful for a great number of purposes where wood, bone, stone,
- oils or fats quired, be saturated with oils or fats by im. mersion in oils or fat, or by rubbing these with the material.
- I may mix it in a dry state with the pulp in the beating engine, and when thoroughly mixed with the fibrous pulp I add about five pounds of caustic soda in solution for every ten pounds of starch or fiour, and I proceed as follows: I add to the starch or flour and the pulp in the beating-engine about twenty pounds of a solution of silicate of soda or other alkaline silicate for every ten pounds ofstarch or fiour'employed, and I then add a solution of a salt of an alkaline earth-such as calcium or barium chloride or magnesia sulphate--until no more precipitate will form; or, instead of an alkaline earth, I may employ a salt of chlorine-by preference ammonia chloride for the purpose of precipitation.
- an alkaline earth such as calcium or barium chloride or magnesia sulphate--until no more precipitate will form
- I may employ a salt of chlorine-by preference ammonia chloride for the purpose of precipitation.
- I precipitate with an acid metallic salt, omitting the silica.
- the paper is finished off in the usual manner; but for special purposes, when the material is to be employed for some of the purposes named, I subject it to a very gradual pressure while it is still in a wet statethat is, soon after it leaves the machineand I then dry it by exposing it in any suitable rooms in the same manner as the glue-sized material. Still better results are obtained by partially drying the material before subjecting it to any pressure, and when about onehalf or three-fourths dry to subject it to a strong pressure between soft porous material, allowing it to remain under full pressure for three hours or upward.
- copper sulphate heat may be used to facilitate the adhesion of the particles of starch in the same way as described under the animal-sizing process.
- the copper sulphate colors the starch or flour a bright green or blue.
- the other processes produce almost a colorless sizing.
- I claim 1 An improved process or method for treating fibrous material, which consists in precipitating glue, starch, or flour in the fibrous pulp, and then treating the materials in the manner described, so as to render them more or less waterproof without injuring their binding property, for the purposes specified.
Landscapes
- Paper (AREA)
Description
their-en STATES PaTnriT @rrrca I CHARLES W'EYGANG, OF 7 HERMITAGE VILLAS, CHILDS HILL, CUUNTY OF MIDDLESEX, ENGLAND.
PROCESS OF SIZING PAPER, 81,0.
JPECIFICATION forming part of Letters Patent No. 307,607, dated November d, 188%.
Application filed February 6. 188-]. (No specimens.) Patented in England May Il, 1883, No. 2,251..
To ztZZ toll/0112 it may concern:
Be it known that I, CHARLES YVLYGANG, a subject of the Queen of Great Britain, residing at 7 Hermitage Villas, Ohilds Hill, in the county 01" Middlesex, England, manufacturers agent, have invented a certain new and use ful Improved Process for Sizing Iaper, which is also applicable to the n'ianutacture of mate rial to be employed in the place of leather, parchment, and for many purposes for which wood, bone, horn, and stone are used, (for which I have obtained a patent in Great Britain, No. 2,251., hearing date May 3, 1883,) of which the following is a specification.
The principal object of this invention is to' incorporate animal glue, starch, or ilour with a fibrous pulp prepared by paper machinery by precipitating the glue, starch, or flour in the fibrous pulp and-treating these materials in such a manner as to render them more or less impervious to water, while not materially injuring their valuable binding property, so
- that the fibers with which they are combined may be caused to unite, and by varying the proceedings as hereinafter described the invention may be applied to the sizing of ordinary paper or for the production of material applicable for some of the many purposes for which parchment,leather, wood, horn, bone, and stone, &c., are employed.
For the purpose of sizing with animal glue I dissolve the same in any convenient manner, and Iadtl the solution to the fibrous pulp in the beating-engine or other suitable mixing apparatus. I then add one or more astringent metallic salts of nature appropriate to the kind of material to be produced. I then add a caustic alkali or an alkaline earth, or a salt of an alkali or an alkaline earth, taking care that the acid of the metallic salt is in excess, or that otherwise an acid is in excess, the object being to cause the formation of a nascent oxide or an acid or an interchange of elements in the glue in solution, whereby this is energetically attached and precipitated in the fibrous pulp.
Instead of first adding the acid metallic salt, I may in some cases add the alkaline salt first, and under certain circumstances I can mix the separate chemical agents together and add the mixture to the pulp and size in the beatingengine.
In some cases I mix one or more of the chemical agents employed with the size before I introduce the latter into the beating'engine, and sometimes I mix the glue in a precipitated form with the pulp in the beating-engine. Sometimes I mix the glue with certain chemical agents which do not precipitateit, butonly thicken it, and I incorporate this thickened glue or size with the fibrous pulp While this is being formed into sheets.
Instead of employing metallic salts, I may for some purposes use non-metallic elements which have chemical affinity for the glue.
Having in theabove given an outline of my invention, I now describe the various methods for carrying the same into efirect.
For sizing ordinary paper the practical manufacturer will be able to proceed from the following details: For special purposes the fibers and the quality of the glue are chosen according to the nature of the material to be produced. Thus, for very strong purposes such as for substitutes for leather-the strongest classcs ot' fibers are employed, such as 7 5 hemp, china-grass, 8:0. The fibrous materials are treated in the same manner as in papermaking, and in beating are kept of greater or shorter length, according to the material to be produced. Thus, if the material is to stand great tensile strain, the fibers are kept of as great a length as possible. The glue is also chosen according to the material to be produced. For instance, for material to take the place of leather I prefer to employ such as is made from skin and hide pieces. For almost all other purposes it is chosen according to the color required. I prefer to use the glue in the form of size, the quantity varying for the different purposes. For instance, for the 0 purpose of making the material to take the place of leather, a good-proportion is about three hundred-weight of size of average consistency to about one lmndred-wcight olifi hrous pulp, reckoning the latterin dry weight. For 9 5 material to be used in the place of horn, bone, and such like purposes I use from five to six hundred-weight of size to about one hundredweight of fibrous pulp, dry weight. For most other purposes from one and one-half to two and one-half l'lundredweight of size is usually However, as such a variety of maemployed.
terial can be produced, I do not confine} myself in any way to the proportions given above. When the gluehas been dissolved, I incorpo rate it with the fibrous materials in the beating-engine after the fibrous material has been beaten to the requisite ,conditiomand I then proceed to precipitate the glue by either of the following processes:
No. 1.I add for every hundred-weight of size in the beating-engine about five pounds of an acid salt of zinc or alumina in a dry state or in solution. I prefer the sulphates of these metals, and I can use them. either separately or combined, in a proportion of about two pounds of the sulphate of zinc and about four pounds of the sulphate of alumina. I now add a salt of an alkali until no more precipitate will form, and I can employ a caustic alkali-such as soda hydrate-in a proportion of about one pound to every five pounds of metallic sulphate employed; but I prefer to use a sulphate or a sulphate of an alkali, and I find that the sulphate of ammonia in a proportion of about eight pounds to every hundred-weight of size gives the best result. I prefer to add the chemicals in a state of solution; but they may be added in a dry state, in which case Ifirst reduce them to powder. Instead of mixing the metallic salts with the size in the beating-engine, the same results are obtained by mixing them with the size previous to its introduction into the beating-engine; also, the same results are obtained by mixing one of the metallic salts with the size and com- Thus I bining the other with the alkali. would add the sulphate of alumina with the size, and to a solution of sulphate of zinc I would add a caustic alkali until the precipitate formed is redissolved, and this mixed solution I use in the same manner as the alkaline salt alone.
No. 2.I add a solution of ammonia chloride to the size in the beating-engine, or I incorporate the ammonia chloride with the size before putting the latterinto the beating-engine. I employ a proportion of about seven pounds of ammonia chloride for every huntired-weight of size, and when the size and the salt are thoroughly mixed with the pulp I add about three pounds of bichromate of potashin solution for every hundred-weight of size. I then add a sulphate of an alkali in a dry state or in solution, and I prefer to employ the sulphate of ammonia, which is added until the size is all precipitated, the proportion being about seven pounds of sulphate of ammonia for every one hundred-weight of size. For the purpose of improving the precipitate I add a small quantity. of an acid salt of alumina in solution, such as the sulphate of alumina in a proportion of about two pounds to every one hundred-weight of size.
Nos. 3 and 4.-Instead of employing bichromate of potash, as just described, I can employ with advantage sulphate of copper or iron alone or together, or eitherone combined with an acid salt of zinc or alumina. The proengine.
portion .of the copper or iron salt is about five first add a solution of soda hyposulphite in' about the same proportion as the acid metallic salts employed, and the ammonia sulphate in a proportion of about one-third of the soda hyposulphite employed.
No. 5.-I dissolve ammonia chloride with size, asbefore mentioned, and then sulphate of aluminain a proportion of about six pounds to every one hundred-weight of size, and when thoroughly incorporated with the pulp in the beat-ingengine I add for every one hundredweight of size about two pounds of an alkaline chromate, such as chromate of potash in solution. For the purpose of improving the precipitate, I may finally add a small quantity of ammonia sulphate in a proportion of about two pounds for every hundred-weight of size.
7N0. 6.Instead of employing ammonia chloride alone, as described, I sometimes combine it with calcium sulphate and hydrochloric acid. For this purpose I first dissolve the. ammonia chloride in water, and then I add about six pounds of calcined calcium sulphate to every six pounds of ammonia chloride, and then I add about three pounds of hydrochloric acid. I allow the mixture to remain a few hours before using, stirring it from time to time, and I then employ it as I would the ammonia chloride alone, precipitating the glue in the same way as already described. In employing this mixture, however, I precipitate with very good results by using ammonia sulphate alone in a proportion of wood, 8t'c.-the ammonia chloride is omitted.-
No. 7.To astro'ng solution of hydrochloric acid I add a dilute solution of an alkaline silicate until the slightest signs of precipitation appear. Of this solution I add from one and one-half to two and one-half gallons to every four gallons of size contained in the beating- I then add for every gallon of acid silica used about an equal quantity of soda 7 hyposulphite in a saturated solution, and when thoroughly mixed I add a small proportion of ammonia sulphate, for the purpose of improving the precipitate, for this purpose a proportion of two to three pounds being sufficient.
No. 8.- Instead of employing an acid silicate,
I may, under certain circumstances, employ an alkaline silicate, for which purpose I prefer to proceed as follows: Imix with every hundredweight of size from one-fourth to three-fourths hundred-weight of an ordinary solution of an alkaline silicate, such as silicate of soda. Iincorporate the size andsilica with the pulp in the beating-engine, and I now add a compound of chloride, by preference ammonia chloride, of which I add a solution to the matter in the beating-engine until no more precipitate forms. Instead of employing a salt of chlorine, I can use with very good results a small quantity ofhydrochloric acid in a proportion of about one-eighth of the weight of the silicate employed, and I then add ammonia sulphate until no more precipitate will form.
No. 9.I employ a salt of an alkaline earth, and I prefer to use the calcium chloride with hydrochloric acid in excessthat is, to a saturated solution of ordinary calcium chloride I add from one-half to an equal quantity in I bulk of hydrochloric acid. Of this solution I add about one and one-half gallon to every four gallons of size contained in the beatingengine. I then add a saturated solution of soda hyposulphite,in aproportion ofabout two gallons to every one and one-half gallon of calcium chloride and acid employed, and when thoroughly mixed with the size and the pulp I add a small quantity of ammonia sulphate, for the purpose of improving the precipitate.
No. l0.-In cases where it is desired to make a very opaque material of a good color I employ a soluble salt of baryta or calcium in conjunction with a sulphate or'a sulphite. For this purpose I add to every hundred-weight of size, either before or after its introduction into the beating-engine, from six to ten pounds of the soluble salt of the alkaline earth, and I prefer to employ for this purpose barium chloride, and alter being thoroughly mixed with the size in the beating-engine I add, either in a dry state or in solution, a sulphate or a sulphite. I prefer to employ sulpl'iateofalumina in a proportion of about four pounds to every six pounds of the salt of the alkaline earth employed, and, after being thoroughly mixed, I add a small quantity of a caustic alkali in solution-such as soda hydrate-in a proportion of about one-half pound to every six pounds of baryta chloride employed; or, instead of employing a caustic alkali, I can employ an alkaline sulphate, in which case I prefer to use the ammonia sulphate.
No. 11.--lnstead o't precipitating the glue in the beating-engine,I may precipitate it, but not with such good results, before it is incorporated with the tibrous pulp in the beating-engine by any of the above-named processes, or with bichromate of potash in'conjunction with any other astringent metallic acid salt, such as the sulphate of alumina or zinc. In this case I can add the precipitating agent separately to the dissolved glue in any suitable apparatus, or I can mix the precipitating solution together with the pulp.
No. 12.Instead of precipitating the glue in the pulp, or previous to its introduction into the beating-engine, I may, in the case of paper or boards, which are made in thin layers upon adrum,mixthe chemical agents with the size in such a manner that the size becomes very thick without precipitating. I prefer for this purpose an alkaline ehromate and an acid salt of aluminafor instance, chromate of potash and sulphate of alumina. I mix asolution of the two salts until the mixture becomes turbidthat is, until the mixed solution is almost neutral, the acid, however, supervening. Of this mixture I add about one gallon toevery four gallons of size in solution, stirring well. I then introduce the thickened size into a conical-shaped box fitted with a steampipe, for the purpose of keeping the size iluid. The box is placed above the drum of the paper-machine, extending its whole length with the narrow end downward. The box is open at the bottom, the aperture being cove-red by a roller which rests upon the drum and revolves with the same, giving oif the glue taken from the box to the layer ofthe pulp upon the drum. Flaps attached to the box at each side of the roller are drawn together or opened by means of screws, and thus by opening or pressing on the roller regulate or stop the flow of size from the box The glue in material made in this manner being homogencous,snch material does not require the treatment with heat, as hereinafterdescribed. Of course the abovedescribed process may be varied or blended according to circumstances, and although to the best of my experience they are the most applicable, I do not strictly confine myselfto them. Taking, for instance, process N o. 2, I could substitute, but not with such good results, sulphate of zinc alone or with other astringent acid saltsin the place of the sulphate of ammonia. Instead of adding the chemical agents separately to the size, I may in some instances add all the chemicals together and precipitate with the mixed solution. Thus in the case of chromate of potash and sulphate of alumina I can mix a solution of each salt together until the mixture becomes turbid, and I then add this mixed solution to the size in the beatingengine until all-the size is precipitated, which may be ascertained in all cases by filtering some of the liquid from the pulp into a glass and testing it with some of the precipitating soluunder Nos. 6 ,and 11. produce a Colorless or tion employed. If the liquid remains clear upon, the addition of some of the precipitating solution, all the size is precipitated; but if it becomes cloudy more of the precipitating solution must be added. Instead of employing chromate of potash, very fair results are obtained by employing an acid salt of zinc and alumina in combination, and adding to a so lution composed of equal parts of these'salts acaustic alkali until the mixture is very turbid but still of an acid reaction. I would employ for this purpose the sulphate of zinc and of alumina and the soda hydrate. Although the precipitated glue is in an insoluble or very difticultly soluble condition in the fibrous pulp, it retains in most cases its strong adhesive property, and I make use of this for the purpose of rendering the material manufactured perfectly homogeneous and very strong,as required for the various purposes described.
For the purpose of merely sizing paper in the ordinary sense the usual treatment which paper receives in the course of manufacture is sufficient; but for special purposes I proceed as follows: In order to render the particles of glue contained in the fibrous material adhesive, I heat the sheet or board directly or soon after it leaves themachinethat is,while fresh and wetto about 180 to 220 Fahreu heit in any convenient manner. I may eX- pose the material for this purpose on heat-ed surfaces or place itin heated chambers fitted with suitable shelves. When the material is thoroughly heated throughout, I subject it topressure between felts or other porous fabrics for the purpose of expelling the water and al lowing the particles of glue to unite with each other. The pressure is brought to bear very gradually upon the material, so'as to allow the water to pass out without disturbing the felt ing of the fibers. The material is allowed to remain in thepress until no more water escapes, and it isthcn hung up and dried in suitable rooms,which may be slightly warmed forthe purpose of causing a dry atmosphere. The processes described under Nos. 1, 2, 3, 4, 5, 6, 7, 9, andthe corresponding processes under Nos. 6 and 11 are adaptable to this method of rendering the material homogeneous. The omission of the ammonia chloride as mentioned does not hinder the materiat from becoming adhesive. Glue treated by the processes Nos. 8 and 10 does not become adhesive by heat, but in drying the particles of glue set to a solid mass. Therefore material made by processes Nos. 8 and 10 need not to be subjected to heat, but it is well to subject it to a moderate pressure; also in cases where I precipitate with a salt of an alkaline earth instead of with a salt of an alkaline metal. For instance, if I substitute hydrate of lime for sulphate of ammonia in process No. 1, the material produced is not affected, and such material need not be subjected to heat,but merely to pressure. The processes under Nos. 1, 7, 8, 9, and 10, and the corresponding processes almost colorless sizing, and-these are therefore adapted where a white material is to be produced and for sizing white papers in general. Of these the processes No. land the corresponding processes under Nos. 6 and 11 produce the strongest sizing, and are adaptable for purposes accordingly, such as parch- Material manufactured to take the place of horn is subjected to an extra pressure after it is dry. Forthis purpose I heat the material,
when perfectly dry, to about 200 to 240 Fahrenheit, and I then place it between metal plates and into a hydraulic press and subject it to pressure of one hundred and sixty tons or more, and I have the material under full pressure for three hours or upward. Such material, when finished, can be bent to any shape,when heated,like natural horn. With all the processes described the glue is rendered more or less insoluble,- but with the exception of Nos. 7 and 8, and in cases where hydrate of lime has been employed for precipitating the glue, it absorbs, when placed in water, a certain amount of the same, without, however, losing its strength.
No. 7 produces a sizing which, when dry, is perfectly foreign to water or damp, and is therefore applicable for all kinds of building purposes, being especially adapted for such purposes, as this process renders the material almost fire-proof. It is also useful for a great number of purposes where wood, bone, stone,
850., are employed. 7
For the purpose of imparting great softness to the material, such as is required for most leather purposes, I subject it to a bath of glyc'erine diluted with from three to five times its bulk of water. It is of course understood that the material is subjected to this bath when it is finished and dry. Itis allowed to remain in the bath until saturated, and it is then again dried in any convenient manner. The material produced by such processes as Nos.
7 and 8 is not adaptable for this purpose, as
will be naturally understood, being quite unaffected by moisture; also, material which has been heated and pressed for making substitutes for horn is not adapted for this purpose.
Material manufactured to take the place of.
leather after the processes described maybe curried in a similar manner as natural leather.
Instead of heating and pressing the material as described for the purpose of rendering it homogeneous, I sometimes omit these operations, and merely dry the material as it comes, from the machine. Such material is porous and slightly spongy, and may, if re-.
quired, be saturated with oils or fats by im. mersion in oils or fat, or by rubbing these with the material.
For the purpose of sizing with starch or flour I suspend the starch or fiour L). water, and I add a solution of a caustic alkali until the mixture becomes transparent and gelatinous, and I add of this dissolved starch or fiour the requisite quantity to the fibrous pulp in the beating engine. Instead of dissolving the starch with a caustic alkali, it may be dissolved by boiling.
For ordinary sizing purposes, the practical paper-maker will be able to adjust the proportion of starch or flour to his requirements. For special purposes rather more will be required than for ordinary sizing. Thus,if the material is to be employed for some purposes where wood and bone are used, a good average proportion is about ten pounds of dry starch or flour for every hundred-weight of dry pulp.
Instead of dissolving the starch or flour before its introduction into the beating-engine, I may mix it in a dry state with the pulp in the beating engine, and when thoroughly mixed with the fibrous pulp I add about five pounds of caustic soda in solution for every ten pounds of starch or fiour, and I proceed as follows: I add to the starch or flour and the pulp in the beating-engine about twenty pounds of a solution of silicate of soda or other alkaline silicate for every ten pounds ofstarch or fiour'employed, and I then add a solution of a salt of an alkaline earth-such as calcium or barium chloride or magnesia sulphate--until no more precipitate will form; or, instead of an alkaline earth, I may employ a salt of chlorine-by preference ammonia chloride for the purpose of precipitation. For purposes where a stronger sizing is required I precipitate with an acid metallic salt, omitting the silica. I prefer to employ the chloride of zinc or the sulphate of copper, a solution of either of which salts I add to the starch or flour and pulp in the beating-engine until no more precipitate will form. I may also precipitate with very good results with an acid solution of silica prepared with hydrochloric acid, as hereinbefore described. If the processes are employed for sizing paper in the ordinary sense, the paper is finished off in the usual manner; but for special purposes, when the material is to be employed for some of the purposes named, I subject it to a very gradual pressure while it is still in a wet statethat is, soon after it leaves the machineand I then dry it by exposing it in any suitable rooms in the same manner as the glue-sized material. Still better results are obtained by partially drying the material before subjecting it to any pressure, and when about onehalf or three-fourths dry to subject it to a strong pressure between soft porous material, allowing it to remain under full pressure for three hours or upward.
In employing copper sulphate heat may be used to facilitate the adhesion of the particles of starch in the same way as described under the animal-sizing process. The copper sulphate colors the starch or flour a bright green or blue. The other processes produce almost a colorless sizing.
I claim 1. An improved process or method for treating fibrous material, which consists in precipitating glue, starch, or flour in the fibrous pulp, and then treating the materials in the manner described, so as to render them more or less waterproof without injuring their binding property, for the purposes specified.
2. The improved process or method herein described for treating fibrous materials, consisting in applying dissolved glue to fibrous pulp, then adding one or more astringent inetallic salts or non-metallic elements, and then adding a caustic alkali or alkaline earth or a salt of the latter, for the purposes described.
3. The improved process or method herein described for treating fibrous materials, consisting in applying dissolvedv glue to fibrous pulp, then adding one or more astringent metallic salts or non-metallic elements, then adding a caustic alkali or alkaline earth, or a salt of the latter, and then pressing and drying the pulp, for the purposes set forth.
4. The method of incorporating animal glue with fibrous material by precipitating the glue with the pulp in amixing apparatus, then adding one or more astringent metallic salts and one or more salts of an alkali or alkaline earth, as described.
In testimony whereof I have hereto set my hand this 30th day of November, 1883.
CHARLES I/VEYGANG.
Witnesses:
P. COLLINGWOOD, 155 Fenchurch 821, London, Merchants Clerk.
J. ED. BEESLEY, 2 Popes Head Alley, Ooi'nht'll, London, Gentn.
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US307607A true US307607A (en) | 1884-11-04 |
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US307607D Expired - Lifetime US307607A (en) | Chaeles weygang |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2899352A (en) * | 1959-08-11 | Manufacture of structural board from | ||
US3197360A (en) * | 1963-04-02 | 1965-07-27 | Int Paper Canada | Internal strengthening of insulating board with cereal flour |
-
0
- US US307607D patent/US307607A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2899352A (en) * | 1959-08-11 | Manufacture of structural board from | ||
US3197360A (en) * | 1963-04-02 | 1965-07-27 | Int Paper Canada | Internal strengthening of insulating board with cereal flour |
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