US3073002A - Non-distorting polypropylene fibers - Google Patents

Non-distorting polypropylene fibers Download PDF

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US3073002A
US3073002A US17779A US1777960A US3073002A US 3073002 A US3073002 A US 3073002A US 17779 A US17779 A US 17779A US 1777960 A US1777960 A US 1777960A US 3073002 A US3073002 A US 3073002A
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filaments
fibers
isotactic polypropylene
fiber
heat
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US17779A
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Plummer C Munt
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E B & A C Whiting
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E B & A C Whiting
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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
    • D01F6/06—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/91—Product with molecular orientation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber

Definitions

  • Another object of this invention is to provide oriented filaments of isotactic polypropylene which are resistant to distortion caused by'heating such filaments to temperatures within the range of 100 F. to about 320 F.
  • a further object of this invention is to provide a process for rendering oriented filaments of isotactic polypropyleneresistant to heat distortion at a predetermined temperature within the range of 100 F. to about 320 F.
  • Still another object of this invention is to provide a process for rendering oriented filaments of isotactic polypropylene resistant to heat distortion at any predetermined temperature in the range of from 160-320 F.
  • a still further object of this invention is to provide a process for render ing oriented filaments of isotactic polypropylene resistant to heat distortion at high temperatures, which. filaments are obtained by stretch orienting melt extruded isotactic polypropylene and cold quenching the filaments before and after stretching.
  • each fiber is maintainedin a'straight line during which treatment the fiber is maintained in a relaxed condition, i.e.,'not under tension.
  • This may be accomplished by running a filament through an oven main- I tained at a temperature such that the fiber will be heated to a temperature within the range of 100 F. to about 320 F.
  • the speed of the take up reel must be adjusted so that the fiber will be in a relaxed condition, i.e., not under tension, while in the oven. It is preferred, however, to heat.
  • the isotactic polypropylene from which oriented filaments are produced preparatory to being treated in acin accordance with this invention, which bowing is the v cordance with this invention are high molecular weight (i.e., above about 45,000), solid polymers which exhibit a crystalline X-ray diffraction and pattern. These polymers have a density between 0.90 and 0,94 and a melting point above about 320 F.
  • the preferred isotactic polypropylene polymers have a melt index of from about28 grams/ten minutes to about 30 grams/ten minutes under a load of 10 kilograms at a temperature of 250 C., the melt index being determined by the standard ASTM procedure.
  • Isotactic polypropylene polymers may be prepared by methods now well known in the art, such as the proceedescribed by G. Natta in the Journal of Polymer e, volume XVI, pages 143 to 154 (1955), and in disclosures of these references are hereby incorporated herein.
  • a bundle of fibers in a suitable wrapper such as paper or a plasticsheet material including cellulose acetate, polyvinyl chloride, or other common wrapping materials of this type which will provide lateral constraint for all of the fibers in thebundle, thereby maintaining the longitudinal axis of each,of the filaments in-the bundle in a straight line and in arelaxed or tension-free state.
  • the bundle of filaments may contain any number of fibers and the fibers in a single bundle may be of'the same diameter or of varying diameters so long as the longitudinal axis of each fiber is maintained in a straight line.
  • the filaments in the bundle should be of the same length
  • the bundle of fibers may be heat treated in any standard heating oven which is adapted to be maintained at a constant temperature within the range of 100 F. to about 320 F. and preferably between about 160 F. and 320 F.
  • the bundle is left in the oven until each fiber in the bundle reaches the temperature of the oven.
  • heating time is not a factor in the practice of this invention.
  • the critical factor is that every fiber must be heated to the selected temperature up to which the treated filament is tovbe resistant to distortion by heat.
  • the filaments may be cooled in any desired manner; such as, for example, by quenching in. a liquid non-solvent for isotactic polypropylene (e.g., water) or by allowing the fibers to return to room temperature naturally.
  • a liquid non-solvent for isotactic polypropylene e.g., water
  • the filaments become resistant to distortion by heat ing at the particular temperature at which the filaments are heat treated so that they may be subsequently heated up' to that temperature without becoming distorted. Therefore, if the filaments are heat treated in accordance with this invention, for example, at 290 F., they become resistant to distortion when heated to this temperature;
  • EXAMPLEI A bundle of melt extruded, stretch oriented isotactic polypropylene fibers, each fiber having a diameter of 14 mil and a length of 3 inches, was securely wrapped in paper .by conventional wrapping techniques so as to maintain the longitudinal axis of each fiber in a straight line.
  • the bundle was 2 inches in diameter and contained about 1000 fibers.
  • the package of fibers was placed in a heat- I ing oven maintained at aconstant temperature of 310 F.
  • every fiber in the bundle was heatedto the temperature of the oven, i.e., to 310 F.
  • the bundle was then removed from the oven and allowedv to cool to room temperature.
  • the abrasion test was conducted by allowing a filament about 1 inch long and held securely in a fixed position by an arm perpendicular to the face of a small rotating sand paper covered drum, to contact said rotating drum for five minutes. The filament was measured before and after the abrasion treatment and the length of the filament which waslost by abrasion thereby determined. Eight tests were run on both heat treated and non-heat treated fibers and the average percent of loss by abrasion of each series reported. As can be seen from the table, the fibers treated in accordance with this invention are about 16 percent more abrasion resistant than the non-treated fibers.
  • the elongation tests were made on a standard Scott tester.
  • the heat treated fiber showed significantly less elongation than the untreated fiber.
  • the regain test was conducted by anchoring one. end of a 3 /2 inch "filament in a position perpendicular to a base line, bending the filament to a angle so that it is horizontal to the base line, immediately releasing the filament and measuring in degrees the size of the arc circumscribed by the released filament. This are was the amount of regain possessed by the filament after having been deflected by 90 from its original position. The percent of regain was determined by dividing the amount of regain by 90 and multiplying-by 100. As shown in the table, the filament treated in accordance with this invention possesses surprisingly greater regain characteristics than the untreated filament.
  • both the treated and the untreated filaments were tested for stiffness on a standard laboratory Gurley stiffness tester. It was found that the untreated fiber was 30 percent stiffer than was the treated fiber. 1
  • EXAMPLE 2 the oven and allowed to cool at room temperature.
  • the I fibers could subsequently be heated to F. without distorting.
  • the fibers thus treated were non-distorting at temperatures below 160 EXAMPLE 4
  • the process as described inv Example 2 was repeated with the sole exception that the bundle was heated to 250 F.
  • the fibers could subsequently be heated up to 250 F. without distorting.
  • Example 2 The process as set out in Example 2 was repeated except that the bundle was heated at 320 F. for 3 hours. The fibers thus treated could be heated up to 320 F. without distorting.
  • the foregoing examples demonstrate the improvement in resistance to heat distortion imparted to brush filaments of isotactic polypropylene which have been heat treated according to this invention. It has been demonstrated that the heat treatment may be carried out at temperatures below the melting point of the fiber, preferably about F. below the' fiber melting point. Within the range of temperatures at which the filaments may be treated, which range is preferably 160-320 F., a brush filament of isotactic polypropylene may be heated to any predetermined temperature which is dictated by the degree of heat to which the treated filament is to be subjected. It has also been shown that the treatment of isotactic polypropylene filaments according to this invention has other efleets upon the filaments.
  • oriented fibers of isotactic polypropylene treated in accordance with this invention have greater abrasion resistance, less stiffness and elongation and greater regain than do the untreated fibers.
  • High abrasion resistance is very important in many uses of fibers such as when used as bristles in brushes since bristles with high abrasion resistance wear much longer than those with low abrasion resistance.
  • Bristles of low stiffness are desired in many uses such as, for example, in shaving brushes. Good regain characteristics are desirable in bristles and, when the filaments are used in making a fabric, improve resistance to wrinkling.
  • novel filaments of oriented isotactic polypropylene produced in accordance with this invention have many desirable characteristics which have hereto- :iore been lacking in oriented isotactic polypropylene filapropylene while the longitudinal axis of the fiber is maintained in a straight line by means of lateral constraint and in a relaxed condition to a temperature within the range of F. to about 320 F.
  • a method for producing an isotactic polypropylene oriented filament which will not distort when heated to a predetermined temperature which comprises heating a bundle of oriented isotactic polypropylene filaments, in which the longitudinal axis of each filament is maintained in a straight line by means of lateral constraint and in a relaxed condition up to a temperature within the range of 100 F. to about 320 F. for a time suificient to allow each filament in the bundle to become heated to the same temperature and then allowing said filaments to cool.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Artificial Filaments (AREA)

Description

United States Patent ()fj e 3,073,002 NON-DISTORTING POLYPROPYLENE FIBERS Plummer C. Munt, Burlington, Vt., assignor to E. B. 8: A. C. Whiting Company No Drawing. Filed Mar. 28, 1960, Ser. No. 17,779 4 Claims. (CI. 28-72) This invention relates to oriented fibers of isotactic polypropylene which will not become distorted when heated and to a method of producing such heat resistant fibers or filaments.
Melt extruded, stretch oriented fibers of isotactic polypropylene have been reported, for instance in an article by V. Erlich appearing inModern Textiles Magazine, November 1958, pages 59 to 66; and in Paper No. 72, Propylene Industrial Fibers, by G. L. McIntyre et al., reported in Technical Papers, volume VI, presented at the Sixteenth Annual Technical Conferenceof the Society of Plastics Engineers, Inc., January 1960.-; -Such fibers havev high tensile strength, high melting point, good resiliency and many other desirable properties. However, isotactic polypropylene filaments have a marked tendency to distort or to bow when subjected to heat. The greater the amount of heat applied to these filaments, the greater the amount of such distortion. This is a distinct disadvantage in many fields, such as in the use of isotactic polypropylene fibers as brushfilaments or bristles.
Still another type of filament of isotactic polypropylene that is distorted by'hat, though '10 lesser degree than are the foregoing prior filaments, is disclosed in copending application Serial No. 800,840, filed March 20, 1959, by Plummer C. Munt. These unusual filaments are ob tained by aprocess for producing straight, non-curling oriented filaments of isotactic polypropylene described in that application which comprises melt extruding filaments of isotactic polypropylene, quenching the freshly extruded filaments in a liquid non-solvent bath for the filaments maintained at a temperature of from about 40 F. to about 60 F.; gradually heating the quenched filaments to their softening temperature, i.e., from about 260 F. to about 305 F., stretching the heat softened filaments from about six tovabout eleven times their original length, and quenching the filaments a second timeafter stretching in a liquid non-solvent bath for the filaments maintained, at a temperatureof at least as low as about 60 F. The
fiber thereby obtained represents a vast improvement over 7 prior art oriented fibers of isotactic polypropylene in that the tendency of such fibers to curl after orientation is overcome. However, even fibers produced according to that invention have a tendency to bow or flare slightly when the filaments are released'from their wrappings and exposed to heat. At temperatures below about 160 F., this bowing is detectable but it is not appreciable. At
temperatures above about 160 F. the amount of distor};
tion in filaments prepared in the above-describ'df' ma becomes significant and objectionable. At these h u temperatures, a filament of the foregoing type, whenly in a straight line on a flat surface, bows to such an extent a US. Patents 2,882,263; 2,874,153; and 2,913,442. The
that it cannot be satisfactorily used in a brush. When a brush with bristles made of such fibers is subjected to temperatures of about 160 F., or temperatures in excess of this temperature, such as are encountered when a brush is used in close proximity to industrial furnaces or to brush away waste material from the face of a die heated with super-heated steam, the bristles become distorted to the extent that'they are no longer perpendicular to the plane of the side or face of the brush from which the filaments project. The bristles become so badly bowed that the brush is rendered useless. The above-described bow ing ofpolypropylene filaments which has not been treated invention which, briefly, consists of heat treating at least one oriented filament of isotactic polypropylene while the Patented Jan. 15, 1963 result of heating the oriented filaments, is also referred to herein as, fiaring.". This bowing or flaring efiect is measurable by tests which are described hereinafter.
It is, therefore, the principal object of this invention to provide oriented filaments of isotactic polypropylene which will not become distorted when subjected to heat.
Another object of this invention is to provide oriented filaments of isotactic polypropylene which are resistant to distortion caused by'heating such filaments to temperatures within the range of 100 F. to about 320 F. A further object of this invention is to provide a process for rendering oriented filaments of isotactic polypropyleneresistant to heat distortion at a predetermined temperature within the range of 100 F. to about 320 F. Still another object of this invention is to provide a process for rendering oriented filaments of isotactic polypropylene resistant to heat distortion at any predetermined temperature in the range of from 160-320 F. A still further object of this invention is to provide a process for render ing oriented filaments of isotactic polypropylene resistant to heat distortion at high temperatures, which. filaments are obtained by stretch orienting melt extruded isotactic polypropylene and cold quenching the filaments before and after stretching.
The above-enume ated objects are accomplished by this longitudinal axis of each fiber is maintainedin a'straight line during which treatment the fiber is maintained in a relaxed condition, i.e.,'not under tension. This may be accomplished by running a filament through an oven main- I tained at a temperature such that the fiber will be heated to a temperature within the range of 100 F. to about 320 F. The speed of the take up reel must be adjusted so that the fiber will be in a relaxed condition, i.e., not under tension, while in the oven. It is preferred, however, to heat. treat a bundle or package of fibers in which the fibers are all maintained in a relaxed condition, i.e., free of tension, and with their longitudinal axes maintained in a straight line by means of lateral constraint until every fiber in the bundle has reached anydesired temperature in the range of 160 F. up to 320 F.
The isotactic polypropylene from which oriented filaments are produced preparatory to being treated in acin accordance with this invention, which bowing is the v cordance with this invention are high molecular weight (i.e., above about 45,000), solid polymers which exhibit a crystalline X-ray diffraction and pattern. These polymers have a density between 0.90 and 0,94 and a melting point above about 320 F. The preferred isotactic polypropylene polymershave a melt index of from about28 grams/ten minutes to about 30 grams/ten minutes under a load of 10 kilograms at a temperature of 250 C., the melt index being determined by the standard ASTM procedure.
Isotactic polypropylene polymers may be prepared by methods now well known in the art, such as the procedescribed by G. Natta in the Journal of Polymer e, volume XVI, pages 143 to 154 (1955), and in disclosures of these references are hereby incorporated herein.
application are hereby incorporated by reference into and made a part ofthis disclosure.
In preparing the oriented filaments of isotactic polypropylene for'theheat-treatment, it is preferred to wrap a bundle of fibers in a suitable wrapper such as paper or a plasticsheet material including cellulose acetate, polyvinyl chloride, or other common wrapping materials of this type which will provide lateral constraint for all of the fibers in thebundle, thereby maintaining the longitudinal axis of each,of the filaments in-the bundle in a straight line and in arelaxed or tension-free state. The bundle of filaments may contain any number of fibers and the fibers in a single bundle may be of'the same diameter or of varying diameters so long as the longitudinal axis of each fiber is maintained in a straight line.
The filaments in the bundle should be of the same length;
since, if they are of varying lengths, the ends of the longer fiberswill be free to curl during the heat treatment. To 7 avoid the necessity of later classifying the fibers into filaments of uniform sizes, it is preferred that all the fibers in one bundle be of the same dimension.
The bundle of fibers may be heat treated in any standard heating oven which is adapted to be maintained at a constant temperature within the range of 100 F. to about 320 F. and preferably between about 160 F. and 320 F. The bundle is left in the oven until each fiber in the bundle reaches the temperature of the oven. By this heat soaking technique, the fibers near the surface of the bundle do not reach a temperature in excess of the temperature selected for the treatment. Therefore, heating timeis not a factor in the practice of this invention. The critical factor is that every fiber must be heated to the selected temperature up to which the treated filament is tovbe resistant to distortion by heat.
After the heat treatment, the filaments may be cooled in any desired manner; such as, for example, by quenching in. a liquid non-solvent for isotactic polypropylene (e.g., water) or by allowing the fibers to return to room temperature naturally. I
By the practice'of this invention, it has been .found that the filaments become resistant to distortion by heat ing at the particular temperature at which the filaments are heat treated so that they may be subsequently heated up' to that temperature without becoming distorted. Therefore, if the filaments are heat treated in accordance with this invention, for example, at 290 F., they become resistant to distortion when heated to this temperature;
. and, therefore, may subsequently be'heated up to 290 F.
without becoming distorted. If, however, the filaments are subjected to temperatures in excess of the temperature at which they were heat treated, they will become distorted. 1 1
The'following examples illustrate this invention and constitute the best mode contemplated of carrying out this invention: EXAMPLEI A bundle of melt extruded, stretch oriented isotactic polypropylene fibers, each fiber having a diameter of 14 mil and a length of 3 inches, was securely wrapped in paper .by conventional wrapping techniques so as to maintain the longitudinal axis of each fiber in a straight line. The bundle was 2 inches in diameter and contained about 1000 fibers. The package of fibers was placed in a heat- I ing oven maintained at aconstant temperature of 310 F.
and left there for 3 hours. During this time, every fiber in the bundle was heatedto the temperature of the oven, i.e., to 310 F. The bundle was then removed from the oven and allowedv to cool to room temperature.
- The treated filaments were tested for heat distortion to demonstrate the advantage of this invention. In addition, the effect of the heat treatment on the fibers with respect to abrasion resistance, regain and elongation was noted and measured. For the purpose of this comparison, an untreated melt extruded, stretch oriented isotactic polypropylene fiber having exactly the same dimensions -as' the heat treated fiber was also tested. The. results are set outinthe followingftable:
In making the test for the amount of distortion at 275 F., one end of a two inch filament was inserted in a block and the block was placed in an oven preheated to 275 F. The longitudinal axis of the fiber was perpendicular to the base of the block and the bottom of the oven. The size of the angle by which the fiber deviated from the perpendicular after 20 minutes in the oven was measured and reported as the amount of distortion. The results set out in the above table show the remarkable advantages obtained by the practice of this invention, the previously heat treated fiber having undergone no distortion while the untreated fiber distorted from a vertical to a horizontal position.
The manner in which the other tests were conducted is explained hereinafter. The abrasion test was conducted by allowing a filament about 1 inch long and held securely in a fixed position by an arm perpendicular to the face of a small rotating sand paper covered drum, to contact said rotating drum for five minutes. The filament was measured before and after the abrasion treatment and the length of the filament which waslost by abrasion thereby determined. Eight tests were run on both heat treated and non-heat treated fibers and the average percent of loss by abrasion of each series reported. As can be seen from the table, the fibers treated in accordance with this invention are about 16 percent more abrasion resistant than the non-treated fibers.
The elongation tests were made on a standard Scott tester. The heat treated fiber showed significantly less elongation than the untreated fiber.
The regain test was conducted by anchoring one. end of a 3 /2 inch "filament in a position perpendicular to a base line, bending the filament to a angle so that it is horizontal to the base line, immediately releasing the filament and measuring in degrees the size of the arc circumscribed by the released filament. This are was the amount of regain possessed by the filament after having been deflected by 90 from its original position. The percent of regain was determined by dividing the amount of regain by 90 and multiplying-by 100. As shown in the table, the filament treated in accordance with this invention possesses surprisingly greater regain characteristics than the untreated filament.
In addition to the above tests, both the treated and the untreated filaments were tested for stiffness on a standard laboratory Gurley stiffness tester. It was found that the untreated fiber was 30 percent stiffer than was the treated fiber. 1
EXAMPLE 2 the oven and allowed to cool at room temperature. The I fibers could subsequently be heated to F. without distorting.
EXAMPLE 3 The process set out in Example 2 was repeated with the sole exception that the bundle was heated to F.
The fibers thus treated were non-distorting at temperatures below 160 EXAMPLE 4 The process as described inv Example 2 was repeated with the sole exception that the bundle was heated to 250 F. The fibers could subsequently be heated up to 250 F. without distorting.
EXAMPLE The process as set out in Example 2 was repeated except that the bundle was heated at 320 F. for 3 hours. The fibers thus treated could be heated up to 320 F. without distorting.
The foregoing examples demonstrate the improvement in resistance to heat distortion imparted to brush filaments of isotactic polypropylene which have been heat treated according to this invention. It has been demonstrated that the heat treatment may be carried out at temperatures below the melting point of the fiber, preferably about F. below the' fiber melting point. Within the range of temperatures at which the filaments may be treated, which range is preferably 160-320 F., a brush filament of isotactic polypropylene may be heated to any predetermined temperature which is dictated by the degree of heat to which the treated filament is to be subiected. It has also been shown that the treatment of isotactic polypropylene filaments according to this invention has other efleets upon the filaments. For example, it has been found that oriented fibers of isotactic polypropylene treated in accordance with this invention have greater abrasion resistance, less stiffness and elongation and greater regain than do the untreated fibers. High abrasion resistance is very important in many uses of fibers such as when used as bristles in brushes since bristles with high abrasion resistance wear much longer than those with low abrasion resistance.
Bristles of low stiffness are desired in many uses such as, for example, in shaving brushes. Good regain characteristics are desirable in bristles and, when the filaments are used in making a fabric, improve resistance to wrinkling.
Thus, the novel filaments of oriented isotactic polypropylene produced in accordance with this invention have many desirable characteristics which have hereto- :iore been lacking in oriented isotactic polypropylene filapropylene while the longitudinal axis of the fiber is maintained in a straight line by means of lateral constraint and in a relaxed condition to a temperature within the range of F. to about 320 F.
2. A method for producing an isotactic polypropylene oriented filament which will not distort when heated to a predetermined temperature which comprises heating a bundle of oriented isotactic polypropylene filaments, in which the longitudinal axis of each filament is maintained in a straight line by means of lateral constraint and in a relaxed condition up to a temperature within the range of 100 F. to about 320 F. for a time suificient to allow each filament in the bundle to become heated to the same temperature and then allowing said filaments to cool.
3. A method as set forth in claim 2 wherein the bundle is heated at a predetermined temperature in the range of from about F. to about 320 F.
4. A filament produced by the method of claim 1.
References Cited in the file of this patent UNITED STATES PATENTS 2,325,060 Ingersoll July 27, 1943 2,420,565 Ruge'ley et al. May 13, 1947 2,421,334 Kline et al. May 27, 1947 2,421,336 Kline et al May 27, 1947 2,715,763 Marley Aug. 23, 1955 FOREIGN PATENTS 1,163,710 France Apr. 28, 1958 1,184,613 France Feb. 9, 1959 1,185,793 France Feb. 16, 1959 813,891 Great Britain May 27, 1959

Claims (1)

1. A METHOD FOR PRODUCING AN ISOTACTIC POLYPROPYLENE ORIENTED FIBER WHICH WILL NOT DISTORT WHEN HEATED WHICH COMPRISES HEATING AN ORIENTED FIBER OF ISOTACTIC POLYPROPYLENE WHILE THE LONGITUDINAL AXIS OF THE FIBER IS MAINTAINED IN A STRAIGHT LINE BY MEANS OF LATERAL CONSTRAINT AND IN A RELAXED CONDITION TO A TEMPERATURE WITHIN THE RANGE OF 100*F. TO ABOUT 320*F.
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US3152380A (en) * 1961-05-05 1964-10-13 Du Pont Process for treating polypropylene fibers
US3272687A (en) * 1964-07-22 1966-09-13 Eastman Kodak Co Vapor permeable non-woven fibrous element
US3323190A (en) * 1963-06-12 1967-06-06 Hercules Inc Elastic polypropylene yarn and process for its preparation
US3445561A (en) * 1962-06-25 1969-05-20 Bayer Ag Process for producing polycarbonate films and product thereof
US3607616A (en) * 1968-11-22 1971-09-21 Eastman Kodak Co Laminated amorphous and crystalline polypropylene sheeting
US3716446A (en) * 1971-01-21 1973-02-13 Johnson & Johnson Privacy cubicle curtain cloth
US4208457A (en) * 1979-05-04 1980-06-17 Conwed Corporation Plastic netting for load unitization
US5478646A (en) * 1989-08-25 1995-12-26 Mitsui Toatsu Chemicals, Inc. Polypropylene fiber and a preparation process thereof
US5763080A (en) * 1994-05-24 1998-06-09 Exxon Chemical Co. Fibers and fabrics incorporating lower melting propylene polymers

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US2420565A (en) * 1943-02-20 1947-05-13 Carbide & Carbon Chem Corp Synthetic textile articles
US2421334A (en) * 1944-04-26 1947-05-27 Ind Rayon Corp Method of treating twisted filamentary materials
US2421336A (en) * 1944-04-26 1947-05-27 Ind Rayon Corp Method of treating twisted filamentary materials
US2715763A (en) * 1950-06-27 1955-08-23 American Viscose Corp Synthetic textile fiber
FR1163710A (en) * 1955-12-31 1958-09-30 Hoechst Ag Process for obtaining plastic yarns with a low shrinkage rate
GB813891A (en) * 1956-07-17 1959-05-27 Montedison Spa Process and apparatus for improving the dimensional stability of fibres obtained from crystallizable propylene high polymers
FR1185793A (en) * 1956-11-08 1959-08-05 Montedison Spa Improvements to pile fabrics

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2325060A (en) * 1942-02-25 1943-07-27 Du Pont Nonshrinking yarn
US2420565A (en) * 1943-02-20 1947-05-13 Carbide & Carbon Chem Corp Synthetic textile articles
US2421334A (en) * 1944-04-26 1947-05-27 Ind Rayon Corp Method of treating twisted filamentary materials
US2421336A (en) * 1944-04-26 1947-05-27 Ind Rayon Corp Method of treating twisted filamentary materials
US2715763A (en) * 1950-06-27 1955-08-23 American Viscose Corp Synthetic textile fiber
FR1163710A (en) * 1955-12-31 1958-09-30 Hoechst Ag Process for obtaining plastic yarns with a low shrinkage rate
GB813891A (en) * 1956-07-17 1959-05-27 Montedison Spa Process and apparatus for improving the dimensional stability of fibres obtained from crystallizable propylene high polymers
FR1184613A (en) * 1956-07-17 1959-07-23 Montedison Spa Method and apparatus for improving the dimensional stability of fibers obtained from high crystallizable polymers of propylene
FR1185793A (en) * 1956-11-08 1959-08-05 Montedison Spa Improvements to pile fabrics

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3152380A (en) * 1961-05-05 1964-10-13 Du Pont Process for treating polypropylene fibers
US3445561A (en) * 1962-06-25 1969-05-20 Bayer Ag Process for producing polycarbonate films and product thereof
US3323190A (en) * 1963-06-12 1967-06-06 Hercules Inc Elastic polypropylene yarn and process for its preparation
US3272687A (en) * 1964-07-22 1966-09-13 Eastman Kodak Co Vapor permeable non-woven fibrous element
US3607616A (en) * 1968-11-22 1971-09-21 Eastman Kodak Co Laminated amorphous and crystalline polypropylene sheeting
US3716446A (en) * 1971-01-21 1973-02-13 Johnson & Johnson Privacy cubicle curtain cloth
US4208457A (en) * 1979-05-04 1980-06-17 Conwed Corporation Plastic netting for load unitization
US5478646A (en) * 1989-08-25 1995-12-26 Mitsui Toatsu Chemicals, Inc. Polypropylene fiber and a preparation process thereof
US5763080A (en) * 1994-05-24 1998-06-09 Exxon Chemical Co. Fibers and fabrics incorporating lower melting propylene polymers

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