US3072536A - Pre-shaving lotion and method - Google Patents
Pre-shaving lotion and method Download PDFInfo
- Publication number
- US3072536A US3072536A US804861A US80486159A US3072536A US 3072536 A US3072536 A US 3072536A US 804861 A US804861 A US 804861A US 80486159 A US80486159 A US 80486159A US 3072536 A US3072536 A US 3072536A
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- shaving
- weight
- polymer
- lotion
- percent
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q9/00—Preparations for removing hair or for aiding hair removal
- A61Q9/02—Shaving preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
Definitions
- the high-molecular-weight, water-soluble polymers employed in the invention include those polymers commonly designated as polyelectrolytes and obtained by vinyl polymerization of monoethylenically unsaturated compounds containing one or more water-solubilizing, carboxyl or carboxamide groups on the molecule.
- Representative polymers include homopolymers of acrylamide and acrylic acid and copolymers of said compounds with other suitable monomers such as methacrylic acid, methacrylamide and the like.
- Satisfactory polymers can also be prepared wherein one or more monomers having water solubilizing constituents as set forth above is copolymerized with not more than about 25 mole percent of another vinyl monomer free of water solubilizing groups, such as acrylonitrile, methacrylonitrile, vinyl chloride, vinylidene chloride, styrene, alkyl esters of acrylic or methacrylic acid and the like.
- another vinyl monomer free of water solubilizing groups such as acrylonitrile, methacrylonitrile, vinyl chloride, vinylidene chloride, styrene, alkyl esters of acrylic or methacrylic acid and the like.
- the essential factors for obtaining the desired improvement in lubricity are achieved when the polymer is water-soluble, contains a plurality of carboxyl and/or carboxamide groups and has a molecular weight of at least about 500,000.
- Preferred polymers are polyacrylamides and copolymers of acrylamide with not more than about 50 mole percent of acrylic acid or an ammonium or alkali metal acrylate.
- Polymeric compounds similar to the preferred copolymers of acrylamide and acrylates can also be obtained by partial hydrolysis of polyacrylamide with an alkali metal hydroxide.
- an aqueous solution containing a small amount of a high-molecular-weight, watersoluble polymer, as set forth above, is applied to the skin and spread to form a film over the area to be shaved. Thereafter shaving with a sharp razor may proceed without further preparation.
- the aqueous solution of high-molecularweight, water-soluble polymer is applied as set forth above and thereafter a shaving soap is applied in conventional fashion prior to the actual shaving operation. In either mode of operation, a high degree of lubricity is afiorded to. the skin and shaving proceeds smoothly and easily with a minimum of irritation.
- the amount of polymer to be employed in the presliaving lotion composition may vary'depending upon the particular polymer employed, the degree of lubricity desired and whether the lotion is employed alone or followed with a conventional shaving cream treatment.
- the amount of any particular polymer or copolymer required varies in inverse proportion to the molecular weight of said polymer or copolymer.
- a preshaving lotion containing about 0.5 percent by weight of a polymerv having a weight-average molecular weight of about 2,000,000 while 2 percent by weight or more of a polymer having a weight-average molecular weight of about 500,000 may be required for equivalent lubricity.
- the pre-shaving lotion composition should comprise an aqueous solution containing at least about 0.5 percent by weight of polymer and it isgenerally desirable that said solution contain from about 1" to about 4 percent by weight of a polymer.
- concentration of polymer is adjusted to provide a lotion composition having a moderately high viscosity so that it may be spread readily on the face without an excessive tendency to run or drip.
- the amount ofthe lotion compositionemployed will vary depending on the length and density of 'the beard and personal preferences. Good results have been obtained when from about 3 to 10 milliliters of lotion were spread evenly on the area to be shaved.
- Various other additaments may be incorporated in the pre-shaving lotion composition as desired.
- antiseptics or germicides such as halogenated methylenebisphenols or long chain quaternary ammonium compounds
- cooling agents such as menthol
- wetting agents may be incorporated in the composition in small amounts.
- a wetting agent such as an alkylaryl sulfonate or an alkylaryl polyoxyalkylene compound is incorporated in the composition in the amount of from about 0.01 to about 1 percent by weight to facilitate spreading of the lotion on oily skin.
- Other additaments such as perfumes and nontoxic coloring agents can be added as desired.
- a polyacrylamide having a weight-average molecular weight of over 1,000,000 and having about 5 percent of its carboxamide groups by drolyzed to carboxyl groups was dissolved in water together with a commercial wetting agent (Triton X-l00, identified as an alkylaryl polyoxyethylene compound) to produce a solution containing 2 percent by weight of the polyacrylamide and about 0.1 percent by weight of wetting agent.
- Triton X-l00 identified as an alkylaryl polyoxyethylene compound
- pre-shaving lotions consisting of aqueous solutions of the indicated amounts of the following polymers (having molecular weights of over 500,000)
- Polymer Percent by weight Copolymer of equimolar proportions of acrylamide and sodium acrylate 1.0 Copolymer of 85 mole percent of acrylamide and 15 mole percent of methyl methacrylate 1.5 Copolymer of 60 mole percent acrylamide, 30 mole percent ammonium acrylate and mole percent of acrylonitrile 3.5
- a method of shaving which comprises the steps of applying to the face a film of an aqueous solution of a water-soluble, high-molecular-weight polymer, said polymer having a molecular weight of at least about 500,000
- a method according to claim 1 wherein the solution comprises from about 0.5 to about 4 percent by weight of the polymer and from about 0.01 to about 1 percent by weight of a wetting agent.
- a pre-shaving lotion composition for application to the skin prior to shaving with a razor which consists essentially of an aqueous solution containing from about 0.5 to about 4 percent by weight of a high-molecularweight, water-soluble polymer and from about 0.01 to about 1 percent by weight of a wetting agent, said polymer having a molecular weight of at least about 500,000 and being selected from the group consisting of polyacrylamide, co-polymers of acrylamide with up to about mole percent of acrylic acid, and the ammonium and alkali metal salts of such co-polymers.
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Description
United States Patent 3,072,536 PRE-SHAVING LOTION AND METHOD David J. Pye, Walnut Creek, Calif.,.assignor to The Dow Chemical. Company, Midland, Mich., a corporationof Delaware No Drawing; Filed-Apr. 8, 1959, Ser. No. 804,861" 4 Glaims. (GI. 167-85) This invention is concernedwith a pre-shaving lotion and with an improved method for shaving.
Ever since man decided that his facial hair should be periodically removed, therev has resulted more or less discomfort particularly forthose men with tough beards and/or tender skins. Numerous devices for removing hair, -as well as some chemical preparations, have been suggested, but the majorityof men still employ razors. When removing hair with a razor, it is customary to apply a soap or grease-composition to the face to facilitate the shaving operation. However, despite the numerous shaving creams and soaps which have been placed on the market over the years, many men still encounter difiiculty in" obtaining a clean, smooth face'without discomfort.
In accordance with the present invention, it has been discovered that the application of a pre-shaving lotion, embodying certain high-molecular-weight, water-soluble polymers, to the skin prior to shaving provides an excellent degree of lubricity to the skin so that the subsequent cutting operation with the razor proceeds more smoothly and with much less discomfort than in previously employed methods of shaving.
The high-molecular-weight, water-soluble polymers employed in the invention include those polymers commonly designated as polyelectrolytes and obtained by vinyl polymerization of monoethylenically unsaturated compounds containing one or more water-solubilizing, carboxyl or carboxamide groups on the molecule. Representative polymers include homopolymers of acrylamide and acrylic acid and copolymers of said compounds with other suitable monomers such as methacrylic acid, methacrylamide and the like. Satisfactory polymers can also be prepared wherein one or more monomers having water solubilizing constituents as set forth above is copolymerized with not more than about 25 mole percent of another vinyl monomer free of water solubilizing groups, such as acrylonitrile, methacrylonitrile, vinyl chloride, vinylidene chloride, styrene, alkyl esters of acrylic or methacrylic acid and the like. In any case, it appears that the essential factors for obtaining the desired improvement in lubricity are achieved when the polymer is water-soluble, contains a plurality of carboxyl and/or carboxamide groups and has a molecular weight of at least about 500,000. Preferred polymers are polyacrylamides and copolymers of acrylamide with not more than about 50 mole percent of acrylic acid or an ammonium or alkali metal acrylate. Polymeric compounds similar to the preferred copolymers of acrylamide and acrylates can also be obtained by partial hydrolysis of polyacrylamide with an alkali metal hydroxide.
In carrying out the invention, an aqueous solution containing a small amount of a high-molecular-weight, watersoluble polymer, as set forth above, is applied to the skin and spread to form a film over the area to be shaved. Thereafter shaving with a sharp razor may proceed without further preparation. In a further mode of carrying out the invention, the aqueous solution of high-molecularweight, water-soluble polymer is applied as set forth above and thereafter a shaving soap is applied in conventional fashion prior to the actual shaving operation. In either mode of operation, a high degree of lubricity is afiorded to. the skin and shaving proceeds smoothly and easily with a minimum of irritation.
The amount of polymer to be employed in the presliaving lotion composition'may vary'depending upon the particular polymer employed, the degree of lubricity desired and whether the lotion is employed alone or followed with a conventional shaving cream treatment. In general, the amount of any particular polymer or copolymer required varies in inverse proportion to the molecular weight of said polymer or copolymer. Thus, for example, satisfactory results may be obtained with a preshaving lotion containing about 0.5 percent by weight of a polymerv having a weight-average molecular weight of about 2,000,000 while 2 percent by weight or more of a polymer having a weight-average molecular weight of about 500,000 may be required for equivalent lubricity. In general, the pre-shaving lotion composition should comprise an aqueous solution containing at least about 0.5 percent by weight of polymer and it isgenerally desirable that said solution contain from about 1" to about 4 percent by weight of a polymer. The concentration of polymer is adjusted to provide a lotion composition having a moderately high viscosity so that it may be spread readily on the face without an excessive tendency to run or drip. The amount ofthe lotion compositionemployed will vary depending on the length and density of 'the beard and personal preferences. Good results have been obtained when from about 3 to 10 milliliters of lotion were spread evenly on the area to be shaved.
Various other additaments may be incorporated in the pre-shaving lotion composition as desired. Thus, for example, antiseptics or germicides, such as halogenated methylenebisphenols or long chain quaternary ammonium compounds, cooling agents, such as menthol, and wetting agents may be incorporated in the composition in small amounts. In a preferred composition, a wetting agent such as an alkylaryl sulfonate or an alkylaryl polyoxyalkylene compound is incorporated in the composition in the amount of from about 0.01 to about 1 percent by weight to facilitate spreading of the lotion on oily skin. Other additaments such as perfumes and nontoxic coloring agents can be added as desired.
In a representative operation, a polyacrylamide having a weight-average molecular weight of over 1,000,000 and having about 5 percent of its carboxamide groups by drolyzed to carboxyl groups was dissolved in water together with a commercial wetting agent (Triton X-l00, identified as an alkylaryl polyoxyethylene compound) to produce a solution containing 2 percent by weight of the polyacrylamide and about 0.1 percent by weight of wetting agent. The resulting composition was viscous and spread readily when applied to the skin. Portions of this composition were distributed to a panel of men who applied the material to the face prior to shaving. In several cases, the shaving operation was completed with a safety razor with no further treatment of the face after application of the pro-shave lotion. A majority of the men applied a conventional aerosol or brush-type shaving soap over the pre-shaving lotion and then proceeded to shave with a razor as usual. In a few cases, after the application of the pre-shave lotion, a lather was worked up on the face using a brush and ordinary bar hand soap prior to shaving. In all cases, the panel reported improved smoothness and ease of shaving with a minimum of dragging, nicking and irritation as compared to shaving with a conventional shaving soap without the pre-shaving lotion.
Similarly, improved ease of shaving is obtained by applying pre-shaving lotions consisting of aqueous solutions of the indicated amounts of the following polymers (having molecular weights of over 500,000)
Polymer: Percent by weight Copolymer of equimolar proportions of acrylamide and sodium acrylate 1.0 Copolymer of 85 mole percent of acrylamide and 15 mole percent of methyl methacrylate 1.5 Copolymer of 60 mole percent acrylamide, 30 mole percent ammonium acrylate and mole percent of acrylonitrile 3.5
I claim:
1. A method of shaving which comprises the steps of applying to the face a film of an aqueous solution of a water-soluble, high-molecular-weight polymer, said polymer having a molecular weight of at least about 500,000
and being selected from the group consisting of polyacrylamide, co-polymers of acrylamide with up to about 50 mole percent of acrylic acid, and the ammonium and alkali metal salts of such co-polyrners, and thereafter shaving with a razor.
2. A method according to claim 1 wherein the polymer is employed in the amount of from about 0.5 to 4 percent by weight of the aqueous solution.
3. A method according to claim 1 wherein the solution comprises from about 0.5 to about 4 percent by weight of the polymer and from about 0.01 to about 1 percent by weight of a wetting agent.
4. A pre-shaving lotion composition for application to the skin prior to shaving with a razor which consists essentially of an aqueous solution containing from about 0.5 to about 4 percent by weight of a high-molecularweight, water-soluble polymer and from about 0.01 to about 1 percent by weight of a wetting agent, said polymer having a molecular weight of at least about 500,000 and being selected from the group consisting of polyacrylamide, co-polymers of acrylamide with up to about mole percent of acrylic acid, and the ammonium and alkali metal salts of such co-polymers.
References Cited in the file of this patent UNITED STATES PATENTS 2,227,321 Robson Dec. 31, 1940 2,326,078 Trommsdorlf Aug. 3, 1943 2,754,291 Pollack July 10, 1956 2,798,047 Touey et al July 2, 1957 2,831,841 Jones Apr. 22, 1958 FOREIGN PATENTS 62,708 Netherlands Mar. 15, 1949 703,238 Germany Mar. 4, 1941 731,361 Germany Feb. 8, 1943 796,319 Great Britain June 11, 1958 873,891 Germany Apr. 20, 1953 880,046 Germany July 8, 1949 OTHER REFERENCES Schwartz et al.: Surface Active Agents and Detergents, vol. 11, p. 409, 1958, Interscience Pub.
J. Soc. of Cosmetic Chemists, 8:4, July 1957, pp. 196-211.
Sagarin: Cosmetics Sci. and Tech, Interscience Pub., New York, 1957, pp. 433, 434.
Claims (1)
1. A METHOD OF SHAVING WHICH COMPRISES THE STEPS OF APPLYING TO THE FACE A FILM OF AN AQUEOUS SOLUTION OF A WATER-SOLUBLE, HIGH-MOLECULAR-WEIGHT POLYMER, SAID POLYMER HAVING A MOLECULAR WEIGHT OF AT LEAST ABOUT 500,000 AND HAVING SELECTED FROM THE GROUP CONSISTING OF POLYACRYLAMIDE, C0-POLYMERS OF ACRYLAMIDE WITH UP TO ABOUT 50 MOLE PERCENT OF ACRYLIC ACID, AND THE AMMONIUM AND ALKALI METAL SALTS OF SUCH CO-POLYMERS, AND THEREAFTER SHAVING WITH A RAZOR.
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US804861A US3072536A (en) | 1959-04-08 | 1959-04-08 | Pre-shaving lotion and method |
Applications Claiming Priority (1)
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US804861A US3072536A (en) | 1959-04-08 | 1959-04-08 | Pre-shaving lotion and method |
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US3072536A true US3072536A (en) | 1963-01-08 |
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US804861A Expired - Lifetime US3072536A (en) | 1959-04-08 | 1959-04-08 | Pre-shaving lotion and method |
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Cited By (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3314857A (en) * | 1964-07-29 | 1967-04-18 | Clairol Inc | Shaving assistant composition |
US3449255A (en) * | 1966-02-18 | 1969-06-10 | Dow Chemical Co | Method for decreasing friction in mopping |
US3777597A (en) * | 1970-04-29 | 1973-12-11 | Pharmachem Corp | Method of shaving employing an aqueous solution of dextran |
US3811349A (en) * | 1971-05-13 | 1974-05-21 | J Jennings | Method of shaving |
US3965908A (en) * | 1975-01-02 | 1976-06-29 | Posthuma Albert E | Synthetic physiological mucus |
US4232003A (en) * | 1975-11-26 | 1980-11-04 | Posthuma Albert E | Synthetic physiological mucus |
US5019377A (en) * | 1987-12-11 | 1991-05-28 | The Procter & Gamble Company | Low glass transistion temperature adhesive copolymers for use in hair styling products |
US5104642A (en) * | 1990-04-06 | 1992-04-14 | The Procter & Gamble Company | Hair styling compositions containing particular hair styling polymers and non-aqueous solvents |
US5120531A (en) * | 1990-04-06 | 1992-06-09 | The Procter & Gamble Company | Hair styling conditioners |
US5120532A (en) * | 1990-04-06 | 1992-06-09 | The Procter & Gamble Company | Hair styling shampoos |
US6342211B1 (en) * | 1999-06-09 | 2002-01-29 | Ronald S. Ace | Differential lubricants |
EP2246041A1 (en) * | 2009-04-27 | 2010-11-03 | The Gillette Company | Shaving regimen |
WO2012058502A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Razor cartridge with elongated recess |
WO2012058216A2 (en) | 2010-10-27 | 2012-05-03 | The Gillette Company | Composition dispensing device comprising a non-foaming hydrating composition |
WO2012058504A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Cartridge biasing applicator for a hair removal device |
WO2012058506A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Applicator for liquid dispensing hair removal device |
WO2012058507A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Handle for a liquid dispensing hair removal device |
WO2012058501A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Razor with cartridge retention cover |
WO2012058505A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Applicator with a baffle for a hair removal device |
WO2012058500A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Liquid dispensing razor |
WO2012058214A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Applicator with a baffle for a hair removal device |
WO2012058498A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Razor with removable care bottle |
WO2012058503A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Personal care bottle |
WO2012058499A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Pump for a liquid dispensing hair removal device |
WO2013025886A1 (en) | 2011-08-16 | 2013-02-21 | The Gillette Company | Shave preparations comprising an anti-irritation agent |
WO2013025772A2 (en) | 2011-08-16 | 2013-02-21 | The Gillette Company | Composition dispensing device comprising a moisturizing composition |
WO2015066486A1 (en) | 2013-11-01 | 2015-05-07 | The Gillette Company | Shave care composition for a liquid dispensing razor |
Citations (11)
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US2227321A (en) * | 1939-12-14 | 1940-12-31 | Arthur D Robson | Preparation for applying to the hair and skin preparatory to dry-shaving |
DE703238C (en) * | 1938-03-24 | 1941-03-04 | I G Farbenindustrie Akt Ges | Lubricants and lubricants |
DE731361C (en) * | 1940-12-23 | 1943-02-08 | Ig Farbenindustrie Ag | Rodent control pastes |
US2326078A (en) * | 1938-12-07 | 1943-08-03 | Rohm & Haas | Process of polymerizing methacrylic acid |
DE873891C (en) * | 1944-07-27 | 1953-04-20 | Basf Ag | Cosmetic preparations |
DE880046C (en) * | 1950-12-05 | 1953-06-18 | Hoechst Ag | Process for the production of bismuth preparations |
US2754291A (en) * | 1951-08-09 | 1956-07-10 | Maxwell A Pollack | Polyamino acids |
US2798047A (en) * | 1953-02-11 | 1957-07-02 | Eastman Kodak Co | Detergent compositions for laundering textile fabrics, containing a copolymer of a lower nu-alkyl acrylamide and vinyl alcohol |
US2831841A (en) * | 1956-03-19 | 1958-04-22 | Dow Chemical Co | Treatment of acrylamide polymers |
GB796319A (en) * | 1953-11-05 | 1958-06-11 | Ciba Ltd | Aerosol spray hair fixatives and process for their manufacture |
-
1959
- 1959-04-08 US US804861A patent/US3072536A/en not_active Expired - Lifetime
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
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NL62708C (en) * | ||||
DE703238C (en) * | 1938-03-24 | 1941-03-04 | I G Farbenindustrie Akt Ges | Lubricants and lubricants |
US2326078A (en) * | 1938-12-07 | 1943-08-03 | Rohm & Haas | Process of polymerizing methacrylic acid |
US2227321A (en) * | 1939-12-14 | 1940-12-31 | Arthur D Robson | Preparation for applying to the hair and skin preparatory to dry-shaving |
DE731361C (en) * | 1940-12-23 | 1943-02-08 | Ig Farbenindustrie Ag | Rodent control pastes |
DE873891C (en) * | 1944-07-27 | 1953-04-20 | Basf Ag | Cosmetic preparations |
DE880046C (en) * | 1950-12-05 | 1953-06-18 | Hoechst Ag | Process for the production of bismuth preparations |
US2754291A (en) * | 1951-08-09 | 1956-07-10 | Maxwell A Pollack | Polyamino acids |
US2798047A (en) * | 1953-02-11 | 1957-07-02 | Eastman Kodak Co | Detergent compositions for laundering textile fabrics, containing a copolymer of a lower nu-alkyl acrylamide and vinyl alcohol |
GB796319A (en) * | 1953-11-05 | 1958-06-11 | Ciba Ltd | Aerosol spray hair fixatives and process for their manufacture |
US2831841A (en) * | 1956-03-19 | 1958-04-22 | Dow Chemical Co | Treatment of acrylamide polymers |
Cited By (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3314857A (en) * | 1964-07-29 | 1967-04-18 | Clairol Inc | Shaving assistant composition |
US3449255A (en) * | 1966-02-18 | 1969-06-10 | Dow Chemical Co | Method for decreasing friction in mopping |
US3777597A (en) * | 1970-04-29 | 1973-12-11 | Pharmachem Corp | Method of shaving employing an aqueous solution of dextran |
US3811349A (en) * | 1971-05-13 | 1974-05-21 | J Jennings | Method of shaving |
US3965908A (en) * | 1975-01-02 | 1976-06-29 | Posthuma Albert E | Synthetic physiological mucus |
US4232003A (en) * | 1975-11-26 | 1980-11-04 | Posthuma Albert E | Synthetic physiological mucus |
US5019377A (en) * | 1987-12-11 | 1991-05-28 | The Procter & Gamble Company | Low glass transistion temperature adhesive copolymers for use in hair styling products |
US5104642A (en) * | 1990-04-06 | 1992-04-14 | The Procter & Gamble Company | Hair styling compositions containing particular hair styling polymers and non-aqueous solvents |
US5120531A (en) * | 1990-04-06 | 1992-06-09 | The Procter & Gamble Company | Hair styling conditioners |
US5120532A (en) * | 1990-04-06 | 1992-06-09 | The Procter & Gamble Company | Hair styling shampoos |
US6342211B1 (en) * | 1999-06-09 | 2002-01-29 | Ronald S. Ace | Differential lubricants |
EP2246041A1 (en) * | 2009-04-27 | 2010-11-03 | The Gillette Company | Shaving regimen |
WO2010126757A1 (en) * | 2009-04-27 | 2010-11-04 | The Gillette Company | Shaving regimen |
WO2012058216A2 (en) | 2010-10-27 | 2012-05-03 | The Gillette Company | Composition dispensing device comprising a non-foaming hydrating composition |
WO2012058500A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Liquid dispensing razor |
WO2012058502A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Razor cartridge with elongated recess |
WO2012058506A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Applicator for liquid dispensing hair removal device |
WO2012058507A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Handle for a liquid dispensing hair removal device |
WO2012058501A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Razor with cartridge retention cover |
WO2012058505A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Applicator with a baffle for a hair removal device |
WO2012058504A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Cartridge biasing applicator for a hair removal device |
WO2012058214A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Applicator with a baffle for a hair removal device |
WO2012058499A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Pump for a liquid dispensing hair removal device |
WO2012058503A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Personal care bottle |
WO2012058498A1 (en) | 2010-10-28 | 2012-05-03 | The Gillette Company | Razor with removable care bottle |
WO2013025886A1 (en) | 2011-08-16 | 2013-02-21 | The Gillette Company | Shave preparations comprising an anti-irritation agent |
WO2013025772A2 (en) | 2011-08-16 | 2013-02-21 | The Gillette Company | Composition dispensing device comprising a moisturizing composition |
WO2015066486A1 (en) | 2013-11-01 | 2015-05-07 | The Gillette Company | Shave care composition for a liquid dispensing razor |
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