US3072256A - Process for concentrating ores - Google Patents
Process for concentrating ores Download PDFInfo
- Publication number
- US3072256A US3072256A US842201A US84220159A US3072256A US 3072256 A US3072256 A US 3072256A US 842201 A US842201 A US 842201A US 84220159 A US84220159 A US 84220159A US 3072256 A US3072256 A US 3072256A
- Authority
- US
- United States
- Prior art keywords
- percent
- weight
- ore
- zinc
- pulp
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 16
- -1 STEAROYL-HYDROXYETHYLAMIDE SULFATE Chemical compound 0.000 claims description 18
- 229920001296 polysiloxane Polymers 0.000 claims description 13
- 239000007900 aqueous suspension Substances 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- JQJCSZOEVBFDKO-UHFFFAOYSA-N lead zinc Chemical compound [Zn].[Pb] JQJCSZOEVBFDKO-UHFFFAOYSA-N 0.000 claims description 8
- 238000007664 blowing Methods 0.000 claims description 7
- JZHWFOSUPCOWBJ-UHFFFAOYSA-N [dimethyl(octadecyl)silyl]oxy-dimethyl-trimethylsilyloxysilane Chemical compound CCCCCCCCCCCCCCCCCC[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C JZHWFOSUPCOWBJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000011701 zinc Substances 0.000 description 49
- 229910052725 zinc Inorganic materials 0.000 description 22
- 239000012141 concentrate Substances 0.000 description 20
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 11
- 238000005188 flotation Methods 0.000 description 11
- 239000007864 aqueous solution Substances 0.000 description 10
- 229910052745 lead Inorganic materials 0.000 description 10
- 239000000839 emulsion Substances 0.000 description 9
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 229910052949 galena Inorganic materials 0.000 description 7
- XCAUINMIESBTBL-UHFFFAOYSA-N lead(ii) sulfide Chemical compound [Pb]=S XCAUINMIESBTBL-UHFFFAOYSA-N 0.000 description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- 239000003995 emulsifying agent Substances 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 4
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 4
- 229910052950 sphalerite Inorganic materials 0.000 description 4
- 239000012991 xanthate Substances 0.000 description 4
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 4
- 239000011686 zinc sulphate Substances 0.000 description 4
- 235000009529 zinc sulphate Nutrition 0.000 description 4
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 125000005210 alkyl ammonium group Chemical group 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 150000002897 organic nitrogen compounds Chemical class 0.000 description 2
- NNFCIKHAZHQZJG-UHFFFAOYSA-N potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 150000004763 sulfides Chemical class 0.000 description 2
- 239000001117 sulphuric acid Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- 239000006004 Quartz sand Substances 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 229940125773 compound 10 Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000009291 froth flotation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- ZLVXBBHTMQJRSX-VMGNSXQWSA-N jdtic Chemical compound C1([C@]2(C)CCN(C[C@@H]2C)C[C@H](C(C)C)NC(=O)[C@@H]2NCC3=CC(O)=CC=C3C2)=CC=CC(O)=C1 ZLVXBBHTMQJRSX-VMGNSXQWSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052914 metal silicate Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
- JCBJVAJGLKENNC-UHFFFAOYSA-M potassium ethyl xanthate Chemical compound [K+].CCOC([S-])=S JCBJVAJGLKENNC-UHFFFAOYSA-M 0.000 description 1
- ZTHBGWDIOJXYNC-UHFFFAOYSA-M potassium;hexoxymethanedithioate Chemical compound [K+].CCCCCCOC([S-])=S ZTHBGWDIOJXYNC-UHFFFAOYSA-M 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/016—Macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/0046—Organic compounds containing silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
Definitions
- the invention relates to a froth flotation process for the separation of mineral raw materials, particularly sulphidic ores, for example, for the separate concentration of galena and sphalerite.
- the invention provides a flotation process for the selective separation of sulphidic ores with the use of conventional frothing agents such as terpene alcohols or those based on pine oil, and organopolysiloxanes as collectors, characterised by using the collector in the form of an emulsion of liquid organopolysiloxanes or solid organopolysiloxanes dissolved in a water-immiscible liquid, and using as emulsifier for this emulsion a surface-active nitrogen-containing organic compound.
- conventional frothing agents such as terpene alcohols or those based on pine oil
- organopolysiloxanes as collectors, characterised by using the collector in the form of an emulsion of liquid organopolysiloxanes or solid organopolysiloxanes dissolved in a water-immiscible liquid, and using as emulsifier for this emulsion a surface-active nitrogen-containing organic compound.
- organopolysiloxanes have proved to be those which contain on an average at least one alkyl radical with more than two carbon atoms per 4 Si-atoms, and among those again the organopolysiloxanes containing 3-10 siloxane units in an unbranched open chain.
- a hydrocarbosiloxane may be used consisting of linear unbranched chains of more than 2 and less than 11 siloxane units per molecule wherein 75% of the hydrocarbon radicals of the hydrocarbosiloxane are methyl and are radicals having more than 2 carbon atoms.
- an octahydrocarbotrisiloxane may be used having one hydrocarbon radical of more than 2 carbon atoms, the other hydrocarbon radicals being methyl, such as an octaalkyltrisiloxane which has one alkyl radical of more than 2 carbon atoms, the other alkyl radicals being methyl. More specifically, octadecyl-(heptamethyl)-trisiloxane has been used with effective results.
- the emulsion applied according to the invention contains between 0.5 and 2 percent by weight of the nitrogencontaining emulsifier and expediently about percent by weight of organosiloxane; an amount of between 2 and g., preferably between 7 and 30 g. of this emulsion is added to the pulp per 1000 kg. of raw ore.
- emulsifiers which may be used in accordance with the invention are, quaternary alkyl ammonium salts, such as dodecyl-(dimethyl)-benzyl-ammonium chloride, and acylhydroxyalkylamide sulphates, such as especially the sodium salt of stearoyl-hydroxyethylamide sulphate CH .CO.NH.C H .OSO Na
- quaternary alkyl ammonium salts such as dodecyl-(dimethyl)-benzyl-ammonium chloride
- acylhydroxyalkylamide sulphates such as especially the sodium salt of stearoyl-hydroxyethylamide sulphate CH .CO.NH.C H .OSO Na
- osuol-nn were emulsified with 12 g. of the sodium salt of stearoyl hydroxyethylamide sulphate in 588 g. of water.
- the loss i.e. the residue remaining in the flotation cell was 763 g. with a content of 0.1 percent by weight of Pb and 0.3 percent by weight of Zn.
- the lead content of the raw ore was thus floated out after 5 minutes to 89% in the form of 52 g. of lead concentrates, the metal content of which amounting to 43 percent by weight of Pb and 12 percent by Weight of Zn, and the Zn content of the raw ore upon flotation of the residual pulp for minutes to 91% in the form of 185 g. of Zinc concentrates with a metal content of 47 percent by weight of Zn and 1 percent by weight of Pb.
- a zinc concentrate of 27 g. with a content of 1 percent by weight of Pb and 56 percent by weight of Zn, equal to 0.9% Pb and 16% Zn of the total contained in the raw ore was then extracted in the course of 2 minutes.
- a second concentrate was extracted, namely 87 g. containing 1 percent by weight of Pb and 53 percent by weight of Zn (3% Pb and 47% Zn of the total used).
- Zinc concentrate 19 g.; 3%/W. Pb,'25%/w. Zn
- Zinc concentrate g.; 3%/w. Pb, 3%/W. Zn
- Zinc concentrate 38 g.; 1%/w. Pb, 0.5%/w. Zn
- the lead content of the raw ore was floated out after a flotation period of 10 minutes to 86% in the form of 100 g. of lead concentrate the metal content of which amounted to 29 percent by weight Pb and 10 percent by weight Zn, and th zinc content of the raw ore after flotation-of the remaining pulp for 21 minutes to 90% in the form of 236 g. of zinc concentrates with a metal content of together 37 percent by weight Zn and 2 percent by weight Pb.
- the comparison teaches that by the process according to the invention a substantially higher concentration of the ores is attained in a shorter flotation period. if in each case the proportions of the metals in the concentrates obtained are compared with the ratio in the raw ore the process according to the invention results in a calculated factor of 13 for the lead concentration and a factor of 12 for the zinc concentration; in the experiment using xanthate instead of polysiloxane the respective factors were only 9 for lead and 8 for zinc.
- Process according to claim 1 which comprises adding to the pulp zinc sulphate in an amount between 300 and 600 g. per 1000 kg. of raw ore prior to the extraction of the lead ore.
- a process for the concentration of sulfidic ores by blowing air into an aqueous suspension of the ore in the presence of a frothing agent and a hydrocarbopolysiloxane which comprises adding to said aqueous suspension of the ore (1) a linear alkylpolysiloxane of more than two and less than 11 siloxane units per molecule, 75% of the alkyl radicals of said alkylpolysiloxane being methyl and 25% of said alkyl radicals having more than 2 carbon atoms, and (2) a surface-active organic nitrogen compound selected from the group consisting of allryi ammonium salts and acyl-hydroxyalkyl amide sulphates.
- aqueous suspension of the ore in the presence of a frothing agent and a hydrocarbopolysiloxane the step which comprises adding to said aqueous suspension of the ore (1) an octahydroc'arbotrisiloxane having one hydrocarbon radical of more than 2 carbon atoms, the other hydrocarbon radicals being methyl, and (2) a compound selected from the group consisting of dodecyl-(dimethyl)-benzyl ammonium chloride and the stearoyl hydroxyethylamide sulfates.
- step 5 which comprises adding to said aqueous suspension of the ore (1) a linear alkylpolysiloxane of more than 2 and less than 11 siloxane units per molecule, one of said siloxane units per each 4 thereof having one alkyl radical of more than 2 carbon atoms, all
- alkyl radicals being methyl
- a surfactant selected from the group consisting of quarternary ammonium salts and acyl-hydroxya1kylamide sulfates.
- step 6 which comprises adding to said aqueous suspension of the ore (1) an octaalkyltrisiloxane having one alkyl radical of more than 2 carbon atoms,
- step 7 which comprises adding to said aqueous suspension of the ore octadecyl- (heptamethyl)-trisiloxane and a stearoyl-hydroxyethylamide sulfate.
Landscapes
- Manufacture And Refinement Of Metals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
amazes Patented Jan. 8, 1983 3,072,256 PROCESS FER CONCENTRATENG QPJES August Giitte, Aachen, Walter Noll, Levcrknsemflayerwerk, Hans Horst Steinbach, Aachen, and Albrecht Zappel, Bergisch-Neukirchen, Germany, assignors to Farhenfabriken Bayer Aktiengesellschaft, Levcrlrusen,
Germany, a corporation of Germany No Drawing. Fiicd Sept. 25, 1959, Scr. No. 842,201
Claims priority, application Germany Get. 1, 1950 7 Claims. (61. 209-167) The invention relates to a froth flotation process for the separation of mineral raw materials, particularly sulphidic ores, for example, for the separate concentration of galena and sphalerite.
It has already been proposed to add alkyl polysiloxanes as flotation oil to an aqueous suspension of galena and quartz containing dissolved a froth-stabilizing component and to produce the galena in a froth layer separately from the depositing quartz sand by blowing in air. An industrially applicable process according to this suggestion and especially a process by which the sulphides of several metals may be separated from one another has not yet become known. Xanthates have hitherto preferably been used as so-called collectors in the flotation of sulphides.
The invention provides a flotation process for the selective separation of sulphidic ores with the use of conventional frothing agents such as terpene alcohols or those based on pine oil, and organopolysiloxanes as collectors, characterised by using the collector in the form of an emulsion of liquid organopolysiloxanes or solid organopolysiloxanes dissolved in a water-immiscible liquid, and using as emulsifier for this emulsion a surface-active nitrogen-containing organic compound. Especially advantageous organopolysiloxanes have proved to be those which contain on an average at least one alkyl radical with more than two carbon atoms per 4 Si-atoms, and among those again the organopolysiloxanes containing 3-10 siloxane units in an unbranched open chain. In this connection, a hydrocarbosiloxane may be used consisting of linear unbranched chains of more than 2 and less than 11 siloxane units per molecule wherein 75% of the hydrocarbon radicals of the hydrocarbosiloxane are methyl and are radicals having more than 2 carbon atoms. Besides, for example, an octahydrocarbotrisiloxane may be used having one hydrocarbon radical of more than 2 carbon atoms, the other hydrocarbon radicals being methyl, such as an octaalkyltrisiloxane which has one alkyl radical of more than 2 carbon atoms, the other alkyl radicals being methyl. More specifically, octadecyl-(heptamethyl)-trisiloxane has been used with effective results. It is not necessary to produce the emulsion serving as collector prior to its addition to the suspension; it is also suflicient to add directly the siloxane liquid and the emulsifier to the pulp and to effect the emulsification and the froth production in the pulp.
It has further been found that it is advantageous to carry out the flotation of sulphidic lead-zinc ores in such a manner that the galena is initially floated out from an alkaline pulp, preferably at pH values between 8 and 10 and then sphalerite after acidificaiotn of the pulp to pH values of about 4 and after the addition of copper sulphate, preferably in amounts between 50 and 250 g. per 1000 kg. of raw ore to be concentrated. For a better depression of the sphalerite during the flotation of galena it is advantageous to add to the pulp before the beginning zinc sulphate in an amount between 300 and 600 g. per 1000 kg. of raw ore of the pulp.
The emulsion applied according to the invention contains between 0.5 and 2 percent by weight of the nitrogencontaining emulsifier and expediently about percent by weight of organosiloxane; an amount of between 2 and g., preferably between 7 and 30 g. of this emulsion is added to the pulp per 1000 kg. of raw ore. As emulsifiers which may be used in accordance with the invention are, quaternary alkyl ammonium salts, such as dodecyl-(dimethyl)-benzyl-ammonium chloride, and acylhydroxyalkylamide sulphates, such as especially the sodium salt of stearoyl-hydroxyethylamide sulphate CH .CO.NH.C H .OSO Na The following example of operation demonstrates the advantages of the process according to the invention compared with an analogous process in which Xanthates are used as collector.
Example For producing the collector component according to the invention, 400 g. of polysiloxane of the formula osnonm H3CSi(CH2)i1.OH
osuol-nn were emulsified with 12 g. of the sodium salt of stearoyl hydroxyethylamide sulphate in 588 g. of water.
1 kg. of a West German lead-zinc ore having a grain size below 0.1 mm. containing 2.5 percent by weight of Pb and 9.5 percent by weight of Zn was placed in a 2.5 litre experimental flotation cell. To this there were added 10 cc. of an aqueous solution of sodium meta silicate containing 3.5 percent by weight of Na SiO 3 cc. of an aqueous solution of zinc sulphate containing 10 percent by weight of ZnSO 10 mg. of the aforedescribed polysiloxane emulsion 1 drop (34 mg.) of a commercial synthetic terpene alcohol 272 cc. of a saturated aqueous caustic lime solution (1.18
g. CaO per litre) After making up with water to 2.5 litres, air was beaten into the resultant pulp, the pH-value being 9.4. The froth layer thus formed on the surface of the pulp, rich in galena, was extracted for 2 minutes; it yielded the first concentrate of 31 g. with a content of 60 percent by weight of Pb and 10 percent by weight of Zn, equal to 74% Pb and 3% Zn of the total of the raw ore used. After a further 3 minutes a second concentrate was eX- tracted, i.e. 21 g. with 18 percent by weight of Pb and 16 percentby weight of Zn (15% Pb and 3% Zn of the total used).
Then, there were added to the pulp:
10 cc. of 2 N sulphuric acid 1 cc. of an aqueous solution of copper sulphate containing 10 percent by weight of CuSO 10 mg. of the aforedescribed polysiloxane emulsion 1 drop of terpene alcohol as above and another 10 cc. of 2 N sulphuric acid A Zn concentrate of 126 g. with a content of 0.6 percent by weight of Pb and 53 percent by weight of Zn equal to 3% Pb and 70% Zn of the raw ore used were then extracted from the aerated pulp for 2 minutes. A second zinc concentrate was extracted during the following 3 minutes, namely 59 g. with 2 percent by weight of Pb and 33 percent by weight of Zn (4% Pb and 21% Zn of the total used).
The loss, i.e. the residue remaining in the flotation cell was 763 g. with a content of 0.1 percent by weight of Pb and 0.3 percent by weight of Zn.
The lead content of the raw ore was thus floated out after 5 minutes to 89% in the form of 52 g. of lead concentrates, the metal content of which amounting to 43 percent by weight of Pb and 12 percent by Weight of Zn, and the Zn content of the raw ore upon flotation of the residual pulp for minutes to 91% in the form of 185 g. of Zinc concentrates with a metal content of 47 percent by weight of Zn and 1 percent by weight of Pb.
For comparison, an experimental flotation was carried out according to the known art using xanthates as follows:
To the same amount of 1 kg. of West German lead-zinc ore having a grain size of below 0.1 mm. and containing 3.3 percent by weight of Pb and 9.8 percent by weight of Zn in the same cell as above there were added 3 cc. of an aqueous solution of sodium metal silicate conta-ining 3.5 percent by weight of Na SiO 2.5 cc. of an aqueous solution of sodium carbonate containing percent by weight of Na CO 20 cc. of an aqueous solution of potassium cyanide containing 1 percent by weight of KCN 4.5 cc. of an aqueous solution of zinc sulphate containing 10 percent by weight of ZnSO 10 drop (0.65 cc.) of an aqueous solution of potassium ethyl xanthate containing 10 percent by weight of C H .OCS.SK
1 drop (34 mg.) of terpene alcohol as above The mixture was made up with water, and air beaten in as described above. The resultant froth cover was withdrawn for 1 minute and yielded a first concentrate of 38 g. with a content of 55 percent by weight of Pb and 9 percent by weight of Zn equal to 63% of Pb and 3% of Zn of the total contained in the raw ore. During a further 3 minutes a second concentrate was withdrawn, namely 33 g. containing 20 percent by weight of Pb and 11 percent by weight of Zn (20% Pb and 4% Zn of the total used). In the course of 3 minutes each there was withdrawn a third and fourth concentrate:
(3) 20 g. containing 4 percent by weight of Pb and 9 percent by weight of Zn (2% of the total Pb and 2% of the total Zn) 9 g. containing 3 percent by weight of Pb and 8 percent by Weight of Zn (0.8% of the total Pb and 0.7% of the total Zn) After stopping the aeration there were added to the pulp:
5 cc. of an aqueous solution of copper sulphate containing 10 percent by weight of CuSOL,
11 drops (0.46 cc.) of an aqueous solution of potassium hexylxanthate containing 10 percent by weight of CH .(CH .O.CS.SK
From the re-aerated pulp a zinc concentrate of 27 g. with a content of 1 percent by weight of Pb and 56 percent by weight of Zn, equal to 0.9% Pb and 16% Zn of the total contained in the raw ore was then extracted in the course of 2 minutes. During the following 3 minutes a second concentrate was extracted, namely 87 g. containing 1 percent by weight of Pb and 53 percent by weight of Zn (3% Pb and 47% Zn of the total used).
A further drop of the aforesaid terpene alcohol was then added and, thereupon, a third zinc concentrate of 50 g. was extracted after 3 minutes containing 2 percent by weight Pb and 43 percent by weight of Zn, that is to say 3% of the total Pb and 22% of the total Zn. In the course of 3 minutes each there were extracted a fourth and fifth concentrate and, finally, a sixth concentrate during 7 minutes:
(4) Zinc concentrate, 19 g.; 3%/W. Pb,'25%/w. Zn
2% Pb of the total 5% Zn of the total (5) Zinc concentrate, g.; 3%/w. Pb, 3%/W. Zn
1% Pb of the total 0.4% Zn of the total 4 (6) Zinc concentrate, 38 g.; 1%/w. Pb, 0.5%/w. Zn
2% Pb of the total 0.2% Zn of the total The loss amounted to 664 g. containing 0.1 percent by weight Pb and 0.05 percent by weight Zn.
In this case the lead content of the raw ore was floated out after a flotation period of 10 minutes to 86% in the form of 100 g. of lead concentrate the metal content of which amounted to 29 percent by weight Pb and 10 percent by weight Zn, and th zinc content of the raw ore after flotation-of the remaining pulp for 21 minutes to 90% in the form of 236 g. of zinc concentrates with a metal content of together 37 percent by weight Zn and 2 percent by weight Pb.
The comparison teaches that by the process according to the invention a substantially higher concentration of the ores is attained in a shorter flotation period. if in each case the proportions of the metals in the concentrates obtained are compared with the ratio in the raw ore the process according to the invention results in a calculated factor of 13 for the lead concentration and a factor of 12 for the zinc concentration; in the experiment using xanthate instead of polysiloxane the respective factors were only 9 for lead and 8 for zinc.
We claim:
1. In a process for the concentration of sulphidic leadzinc ores with the use of conventional frothing agents and organo-polysiloxanes as collectors by using the collector in the form of an emulsion of a member selected from the group consisting of liquid hydrocarbopolysiloxanes and solid hydrocarbopolysiloxanes dissolved in a water-immiscible liquid, and using as emulsifier for this emulsion a surface-active organic nitrogen compound selected from the group consisting of alkyl ammonium salts and acyl-hydroxyalkylamide sulphates, the improvement which comprises initially floating out galena from an alkaline pulp, at pH values between 8 and 10, and, then sphalerite after acidification of the pulp, to a pH value of about 4 and after the addition of copper sulphate, in amounts between 50 and 250 g. per 1000 kg. of raw ore to be concentrated.
2. Process according to claim 1 which comprises adding to the pulp zinc sulphate in an amount between 300 and 600 g. per 1000 kg. of raw ore prior to the extraction of the lead ore.
3. In a process for the concentration of sulfidic ores by blowing air into an aqueous suspension of the ore in the presence of a frothing agent and a hydrocarbopolysiloxane the step which comprises adding to said aqueous suspension of the ore (1) a linear alkylpolysiloxane of more than two and less than 11 siloxane units per molecule, 75% of the alkyl radicals of said alkylpolysiloxane being methyl and 25% of said alkyl radicals having more than 2 carbon atoms, and (2) a surface-active organic nitrogen compound selected from the group consisting of allryi ammonium salts and acyl-hydroxyalkyl amide sulphates.
4. In a proces for the concentration of sulfidic ores by blowing air into an aqueous suspension of the ore in the presence of a frothing agent and a hydrocarbopolysiloxane the step which comprises adding to said aqueous suspension of the ore (1) an octahydroc'arbotrisiloxane having one hydrocarbon radical of more than 2 carbon atoms, the other hydrocarbon radicals being methyl, and (2) a compound selected from the group consisting of dodecyl-(dimethyl)-benzyl ammonium chloride and the stearoyl hydroxyethylamide sulfates.
5. In a process for the selective concentration of sulfidic lead-zinc ores by blowing air into an aqueous suspension of the ore in the presence of a frothing agent and an alkylpolysiloxane, the step which comprises adding to said aqueous suspension of the ore (1) a linear alkylpolysiloxane of more than 2 and less than 11 siloxane units per molecule, one of said siloxane units per each 4 thereof having one alkyl radical of more than 2 carbon atoms, all
remaining alkyl radicals being methyl, and (2) a surfactant selected from the group consisting of quarternary ammonium salts and acyl-hydroxya1kylamide sulfates.
6. In a process for the selective concentration of sulfidic lead-zinc ores by blowing air into an aqueous suspension of the ore in the presence of a frothing agent and an alkylpolysiloxane, the step which comprises adding to said aqueous suspension of the ore (1) an octaalkyltrisiloxane having one alkyl radical of more than 2 carbon atoms,
the other alkyl radicals being methyl, and (2) a compound 10 selected from the group consisting of dodecyl-(dimethyD- benzyl-ammoniurn chloride and the stearoyl-hydroxyethylamide sulfates.
7. In a process for the selective concentration of sulfidic lead-zinc ores by blowing air into an aqueous suspension of the ore in the presence of a irothing agent and an alkyal-polysiloxane, the step which comprises adding to said aqueous suspension of the ore octadecyl- (heptamethyl)-trisiloxane and a stearoyl-hydroxyethylamide sulfate.
References Cited in the file of this patent UNITED STATES PATENTS 2594,612 Bates Apr. 29, 1952 2,891,920 Hyde June 23, 1959 2,957,576 Henderson Oct. 25, 1960 FOREIGN PATENTS 495,948 Canada Sept. 4, .953
Claims (1)
- 7. IN A PROCESS FOR THE SELECTIVE CONCENTRATION OF SULFIDIC LEAD-ZINC ORES BY BLOWING AIR INTO AN AQUEOUS SUSPENSION OF THE ORE IN THE PRESENCE OF A FROTHING AGENT AND AN ALKYAL-POLYSILOXANE, THE STEP WHICH COMPRISES ADDING TO SAID AQUEOUS SESPENSION OF THE ORE OCTADECYL(HEPTAMETHYL)-TRISILOXANE AND A STEAROYL-HYDROXYETHYLAMIDE SULFATE.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF26701A DE1156724B (en) | 1958-10-01 | 1958-10-01 | Flotation process for sulphidic ores |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3072256A true US3072256A (en) | 1963-01-08 |
Family
ID=7092123
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US842201A Expired - Lifetime US3072256A (en) | 1958-10-01 | 1959-09-25 | Process for concentrating ores |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3072256A (en) |
| CY (1) | CY241A (en) |
| DE (1) | DE1156724B (en) |
| FR (1) | FR1238551A (en) |
| GB (1) | GB881818A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4102781A (en) * | 1976-01-30 | 1978-07-25 | The International Nickel Company, Inc. | Flotation process |
| US4526680A (en) * | 1984-05-30 | 1985-07-02 | Dow Corning Corporation | Silicone glycol collectors in the beneficiation of fine coal by froth flotation |
| US4532032A (en) * | 1984-05-30 | 1985-07-30 | Dow Corning Corporation | Polyorganosiloxane collectors in the beneficiation of fine coal by froth flotation |
| US4908125A (en) * | 1987-07-07 | 1990-03-13 | Henkel Kommanditgesellschaft Auf Aktien | Froth flotation process for the recovery of minerals and a collector composition for use therein |
| US5544760A (en) * | 1994-10-20 | 1996-08-13 | Benn; Freddy W. | Flotation of lead sulfides using rapeseed oil |
| US20050167340A1 (en) * | 2000-05-16 | 2005-08-04 | Roe-Hoan Yoon | Methods of increasing flotation rate |
| US8007754B2 (en) | 2005-02-04 | 2011-08-30 | Mineral And Coal Technologies, Inc. | Separation of diamond from gangue minerals |
| CN103861740A (en) * | 2014-03-25 | 2014-06-18 | 中南大学 | Method for flotation separation of copper sulfide and lead concentrate processed through pre-oxidation |
| WO2018111975A1 (en) * | 2016-12-14 | 2018-06-21 | Ecolab USA, Inc. | Functionalized silicones for froth flotation |
| CN109174459A (en) * | 2018-09-10 | 2019-01-11 | 北京矿冶科技集团有限公司 | The beneficiation method of high sulfur-lead-zinc ore under a kind of hot environment |
| CN113477410A (en) * | 2021-08-11 | 2021-10-08 | 彝良驰宏矿业有限公司 | Combined inhibitor for flotation separation of lead-zinc sulfide ore and application thereof |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104084313B (en) * | 2014-06-24 | 2018-06-26 | 云南科力新材料股份有限公司 | A kind of flotation collector and frother and preparation method thereof |
| CN112619902A (en) * | 2020-11-26 | 2021-04-09 | 江西理工大学 | Efficient combined collecting agent for galena and preparation method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2594612A (en) * | 1949-11-01 | 1952-04-29 | California Research Corp | Recovery of zinc values by selective flotation of sulfide ores |
| CA495948A (en) * | 1953-09-08 | Hudson Bay Mining And Smelting Co. Limited | Selective flotation of zinc | |
| US2891920A (en) * | 1955-01-26 | 1959-06-23 | Dow Corning | Polymerization of organopolysiloxanes in aqueous emulsion |
| US2957576A (en) * | 1958-03-07 | 1960-10-25 | Anaconda Co | Recovery of molybdenite by flotation |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE5812C (en) * | G. SlGL, Maschinenfabrikant in Berlin, Chausseestrafse 28 | Innovations in the construction of iron girders, ceilings and walls | ||
| DE683678C (en) * | 1938-05-19 | 1939-11-11 | I G Farbenindustrie Akt Ges | Process for swimming pool treatment with additives that are poorly soluble or insoluble in water |
| US2564546A (en) * | 1947-07-23 | 1951-08-14 | Carl H Scheu | Method of separating ores by treatment with a gaseous polyhalosilane |
-
1958
- 1958-10-01 DE DEF26701A patent/DE1156724B/en active Pending
-
1959
- 1959-09-23 GB GB32433/59A patent/GB881818A/en not_active Expired
- 1959-09-25 FR FR806001A patent/FR1238551A/en not_active Expired
- 1959-09-25 US US842201A patent/US3072256A/en not_active Expired - Lifetime
-
1962
- 1962-03-24 CY CY24162A patent/CY241A/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA495948A (en) * | 1953-09-08 | Hudson Bay Mining And Smelting Co. Limited | Selective flotation of zinc | |
| US2594612A (en) * | 1949-11-01 | 1952-04-29 | California Research Corp | Recovery of zinc values by selective flotation of sulfide ores |
| US2891920A (en) * | 1955-01-26 | 1959-06-23 | Dow Corning | Polymerization of organopolysiloxanes in aqueous emulsion |
| US2957576A (en) * | 1958-03-07 | 1960-10-25 | Anaconda Co | Recovery of molybdenite by flotation |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4102781A (en) * | 1976-01-30 | 1978-07-25 | The International Nickel Company, Inc. | Flotation process |
| US4526680A (en) * | 1984-05-30 | 1985-07-02 | Dow Corning Corporation | Silicone glycol collectors in the beneficiation of fine coal by froth flotation |
| US4532032A (en) * | 1984-05-30 | 1985-07-30 | Dow Corning Corporation | Polyorganosiloxane collectors in the beneficiation of fine coal by froth flotation |
| EP0163480A2 (en) * | 1984-05-30 | 1985-12-04 | Dow Corning Corporation | Silicone glycol collectors in the beneficiation of fine coal by froth flotation |
| EP0164237A2 (en) * | 1984-05-30 | 1985-12-11 | Dow Corning Corporation | Polyorganosiloxane collectors in the beneficiation of fine coal by froth flotation |
| EP0164237A3 (en) * | 1984-05-30 | 1988-01-07 | Dow Corning Corporation | Polyorganosiloxane collectors in the beneficiation of fine coal by froth flotation |
| EP0163480A3 (en) * | 1984-05-30 | 1988-01-07 | Dow Corning Corporation | Silicone glycol collectors in the beneficiation of fine coal by froth flotation |
| US4908125A (en) * | 1987-07-07 | 1990-03-13 | Henkel Kommanditgesellschaft Auf Aktien | Froth flotation process for the recovery of minerals and a collector composition for use therein |
| US5122289A (en) * | 1987-07-07 | 1992-06-16 | Henkel Kommanditgesellschaft Auf Aktien | Collector composition for use in a froth flotation process for the recovery of minerals |
| US5544760A (en) * | 1994-10-20 | 1996-08-13 | Benn; Freddy W. | Flotation of lead sulfides using rapeseed oil |
| US20050167340A1 (en) * | 2000-05-16 | 2005-08-04 | Roe-Hoan Yoon | Methods of increasing flotation rate |
| US8007754B2 (en) | 2005-02-04 | 2011-08-30 | Mineral And Coal Technologies, Inc. | Separation of diamond from gangue minerals |
| CN103861740A (en) * | 2014-03-25 | 2014-06-18 | 中南大学 | Method for flotation separation of copper sulfide and lead concentrate processed through pre-oxidation |
| CN103861740B (en) * | 2014-03-25 | 2016-02-24 | 中南大学 | The method of FLOTATION SEPARATION after the pre-oxidation of a kind of copper sulfide lead concentrate |
| WO2018111975A1 (en) * | 2016-12-14 | 2018-06-21 | Ecolab USA, Inc. | Functionalized silicones for froth flotation |
| CN110022983A (en) * | 2016-12-14 | 2019-07-16 | 埃科莱布美国股份有限公司 | Functionalized siloxanes for froth flotation |
| US11014097B2 (en) | 2016-12-14 | 2021-05-25 | Ecolab Usa Inc. | Functionalized silicones for froth flotation |
| CN110022983B (en) * | 2016-12-14 | 2022-03-01 | 埃科莱布美国股份有限公司 | Functionalized siloxanes for froth flotation |
| CN109174459A (en) * | 2018-09-10 | 2019-01-11 | 北京矿冶科技集团有限公司 | The beneficiation method of high sulfur-lead-zinc ore under a kind of hot environment |
| CN109174459B (en) * | 2018-09-10 | 2020-09-04 | 北京矿冶科技集团有限公司 | Beneficiation method for high-sulfur lead-zinc ore in high-temperature environment |
| CN113477410A (en) * | 2021-08-11 | 2021-10-08 | 彝良驰宏矿业有限公司 | Combined inhibitor for flotation separation of lead-zinc sulfide ore and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1238551A (en) | 1960-08-12 |
| GB881818A (en) | 1961-11-08 |
| DE1156724B (en) | 1963-11-07 |
| CY241A (en) | 1962-03-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3072256A (en) | Process for concentrating ores | |
| AU2007284003B2 (en) | Collectors and flotation methods | |
| Sun et al. | Separation of sulfide lead-zinc-silver ore under low alkalinity condition | |
| CN110548592B (en) | Beneficiation method for improving comprehensive recovery index of complex low-grade molybdenum multi-metal ore | |
| US5049612A (en) | Depressant for flotation separation of polymetallic sulphidic ores | |
| US4877517A (en) | Depressant for flotation separation of polymetallic sulphidic ores | |
| CN106944247A (en) | A kind of beneficiation method of low-grade vulcanized lead zinc ore | |
| US2125337A (en) | Flotation reagents and method of use | |
| US1893517A (en) | Separation of minerals by flotation | |
| US2011176A (en) | Ore concentration | |
| US3827557A (en) | Method of copper sulfide ore flotation | |
| US20110020198A1 (en) | Process for recovering copper sulphide from copper bearing ores by froth flotation | |
| CN114100863B (en) | Application of alpha-enol ketone in lead sulfide mineral flotation | |
| FI71884B (en) | MALMFLOTATION MED KOMBINERADE KOLLEKTORER | |
| CN114146821B (en) | Zinc combined collecting agent and flotation method | |
| US4159943A (en) | Froth flotation of ores using hydrocarbyl bicarbonates | |
| US4341626A (en) | Process for the flotation of sulfide minerals employing alkylaryl hydrocarbon compounds | |
| AU2020407504B2 (en) | Arsenic removal from lead concentrate by ozone treatment and reverse flotation | |
| RU2504438C1 (en) | Method of flotation separation of black jack and copper mineral from iron sulphide | |
| CA2116276C (en) | Flotation processes | |
| FI59538B (en) | SAETT ATT ANRIKA SULFIDISK NICKELMALM | |
| CN113600345A (en) | Method for floating pyrite inhibited by lime in acid-free and ammonium-free manner | |
| EP0193630B1 (en) | Ore flotation with combined collectors | |
| JPH0371181B2 (en) | ||
| WO2014208504A1 (en) | Production method for low-sulfur iron ore |