US2962574A - Semiconductor assembling apparatus - Google Patents

Semiconductor assembling apparatus Download PDF

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US2962574A
US2962574A US752308A US75230858A US2962574A US 2962574 A US2962574 A US 2962574A US 752308 A US752308 A US 752308A US 75230858 A US75230858 A US 75230858A US 2962574 A US2962574 A US 2962574A
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holder
envelope
ring
glass
portions
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US752308A
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Wendell C Brooke
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Texas Instruments Inc
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Texas Instruments Inc
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005Apparatus not specifically provided for elsewhere
    • H01L21/67011Apparatus for manufacture or treatment
    • H01L21/67126Apparatus for sealing, encapsulating, glassing, decapsulating or the like
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/02Containers; Seals
    • H01L23/04Containers; Seals characterised by the shape of the container or parts, e.g. caps, walls
    • H01L23/041Containers; Seals characterised by the shape of the container or parts, e.g. caps, walls the container being a hollow construction having no base used as a mounting for the semiconductor body
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L24/00Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
    • H01L24/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto

Definitions

  • This invention relates to improvements in semiconductor assembling apparatus and more specifically relates to a separable holder for holding a contact element and a semiconductor element and correctly positioning these elements relative to one another and to an apparatus for sealing the elements together.
  • a graphite ring as the heat concentrating member within the field of the induction coil.
  • Graphite is especially suitable for this purpose as it is highly conductive and will not adhere to the fused glass.
  • the use of a graphite ring poses problems when it is subjected to air during use. Graphite quickly deteriorates from oxidation under these circumstances and, hence, the ring physically decays in a short time to the point where it is no longer usable.
  • the deterioration of the graphite ring sometimes referred to as flaking, has caused temperature control problems because it produces a decreased size of the radiating heating means with a proportional reduction of heat delivered.
  • the present invention overcomes this difiiculty by substantially reducing the flaking of the graphite ring thereby permitting the graphite ring to be much smaller and closer to the glass envelope. Hence, the heat delivered ICC is much more localized and the semiconductor wafer is not adversely affected. Stability in the time setting for the application of RF energy is also achieved.
  • This invention provides a means for prolonging the sealing life of the heating ring by providing a novel enclosing holder therefor. It was discovered that by enclosing the graphite ring within a holder, the ring will last through approximately two and a half times as many heating cycles as a ring which is not so enclosed.
  • a further object of this invention is to provide a separable holder having mating portions which provide a reference for positioning of the whisker and semiconductor element of a diode.
  • Figure 1 is a sectional elevation view of the holder of this invention shown assembled.
  • Figure 2 is an exploded view partially in section of the semiconductor elements before they are assembled and sealed by the apparatus of Figure 1.
  • the improved apparatus for assembling and sealing the diodes comprises a holder generally indicated by reference numeral 10 which is separable into an upper portion 12 and a lower portion 14.
  • the portion 12 is adapted to hold lead 16, the assembly consisting of contact element 26, and glass bead 20, while the portion 14 is adapted to hold a subassembly indicated at 23 and consisting of lead 18, semiconductor element 24 mounted on a molybdenum plug 25 which has previously been sealed within an envelope 22 as shown in Figure 2.
  • the contact element or whisker 26 of the diode is connected to the end of a lead 16 on which is located a glass bead 20.
  • the assembly including the semiconductor element 24 includes glass tube 22 surrounding the semiconductor element 24 and a lead 18 attached to the plug 25.
  • the envelope is illustrated and described as being made of glass as a matter of convenience, but other equivalent materials may be substituted for the glass.
  • the end of whisker 26 is correctly positioned by the holder of this invention in engagement with the top of the semiconductor element 24.
  • the upper portion 12 of the holder 10 includes a mating section 28 having a tapered mating surface 30 and a threaded bore 31 into which is threaded a tube 32 constructed preferably of brass since it is noncorrosive and easy to machine. However, copper or steel may also be used.
  • the tube 32 and the element 28 preferably have aligned axial holes 34 and 36 therein to allow the lead wire 16 of the contact element to extend therethrough.
  • This wire 16 of the contact element is held by a suitable magnet 38 which is slidably mounted within the tube 32.
  • a plunger or weight 4! or any other suitable biasing means may be utilizedto assure that the magnet 38 is at the bottom of the tubular element 32 when the device is to be sealed. This assures the proper pressure being applied to element 26.
  • the lower portion 14 of the holder 1t has a mating element 42 with a tapered surface 44 adapted to mate with tapered surface 3t) of the upper portion 12 of the holder and correctly positions the bottom and top portions 12 and 14 of the holder with respect to each other.
  • the mating elements 28 and 42 are preferably constructed of boron nitride or any other suitable material capable of withstanding ahigh thermal shock in the order of 2009 C. or more.
  • Another suitable material for the mating elements 28 and 42 is a material known under the trademark of Diamonite which is made by Diamonite Products- Manufacturing Co. of Canton, Ohio, a Division of United States Ceramic Tile Co.
  • Another suitable material for the mating elements is Mylar which is a highly durable polyethylene terephthalate resin and which is a registered trademark of E. I. Du Pont de Nemours & Company of Wilmington, Delaware. Still another material which may be used for the mating surfaces is an alumina oxide ceramic material sold .by American Lava Corporation of Chattanooga, Tennessee. All of these materials are characterized by the property of withstanding high thermal shock.
  • the mating element 42 is threadedly attached to a body element 46 which has a flange 48 thereon. Also threadedly attached within a bore in the upper end of body element 46 is an induction ring holder 54.
  • This holder is generally tubular in shape and has an upper portion shaped to support an induction ring 56.
  • This ring is preferably constructed of graphite although any conductive material that would concentrate the radio-frequency electrical energy and transfer the same to the glass without adhering thereto may be used.
  • a tubular support 58 constructed of brass, copper or like material possessing high thermal conductivity is axially positioned within the body member 46 and has a threaded plug as on the lower end thereof for cooperating with a threaded bore 62 in the body element 46.
  • the tube 58 may be adjusted to position it axially with respect to the body.
  • the glass tube of the semiconductor element of the diode is supported on the top of this tube as shown in Figure l.
  • the lower end of the body element -46 may have a threaded portion 64 on the periphery thereof for suitable cooperation in any desired type of support means.
  • a coil 65 connected to a suitable source of radio-frequency electrical energy is adapted to be positioned as shown in Figure 1 adjacent the graphite ring 56 and surrounding the holder.
  • the coil 65 may be supported on body 66, and the flange 48 of the body member 36 may be utilized to position the holder 10 and the ring 56 carried therein with reference to the stationary coil after the holder has been assembled as shown in Figure 1.
  • the lead wire 16 of the contact element is positioned within the upper portion 12 of the separable holder 18 and is held therein by the magnet 38.
  • the subassembly 23 is positioned within the lower portion of the holder 14 while the portions of the holder 10 are separated.
  • the holder portions 12 and 14 are then assembled and the mating surfaces 44 and 30 will correctly position the glass head 26 within the top of the glass tube 22 with the whisker 26 in contact with the semiconductor element 24.
  • the graphite ring 56 will be adjacent the area of the envelope to be sealed, i.e., the top of glass tube 22 and theglass bead 20. if it is desired to move the glass 4 tube 22 this may be accomplished by adjusting the nut 69 within the threaded bore 62.
  • the plunger '40 insures that the magnet 33 is resting against the bottom of the tube 32. Any suitable jig or clamping fixture may be used to insure that the holder portions are securely assembled.
  • the holder is positioned such that the induction coil 65 surrounds the holder adjacent the induction ring 56. This may be accomplished by positioning the holder until top surface of flange 48 abuts a suitable mating surface on body 66.
  • An apparatus for assembling a semiconductor element and a contact element in proper engaging relationship and for enclosing same in an envelope comprising a holder having a pair of separable portions, one of said portions adapted to hold a semiconductor element and part of an envelope and the other of said portions adapted to hold a contact element and the remaining part of he envelope, said portions provided with mating surfaces such that when assembled they will position the semiconductor element and contact element in proper engaging relationship and said portions will be engaged to enclose substantially the semiconductor element, contact element and envelope, an electrical coil adapted to supply high frequency electrical energy to said holder positioned around said holder adjacent the area of the joint between the envelope parts to be fused, and a heating member carried by one of said elements of said holder in a position adjacent the area of the joint between the envelope parts to be fused, said heating member being totally enclosed within said holder when the elements of said holder are assembled to accomplish the sealing operation.
  • heating member is a ring constructed of graphite.
  • a device as defined in claim 4 wherein the holder portion adapted to hold the semiconductor element includes an adjustable support therein for adjustably positioning the semiconductor element within the holder portion.
  • a holder for holding the elements of a semiconductor diode and the parts of an encapsulating envelope and correctly positioning same in proper engagement said holder comprising a pair of holder portions, said holder portions having mating elements such that when the elements of the diode and the parts of the envelope are held therein and the holder portions are assembled, the elements and parts will be positioned in proper engagement and the holder portions will be engaged to enclose substantially the diode and encapsulating envelope, and an annular heating member positioned within the holder adjacent the parts of the envelope at the area thereof to be fused, said annular member being constructed of a material adapted to be heated by induced RF currents and to transfer its heat to the envelope thereby sealing said envelope.
  • annular member is constructed of graphite and said mating e1ements of said holder portions are constructed of boron nitride and further wherein a magnet holding device is located in one of said holder portions.
  • annular member is constructed of graphite and said mating elements of said holder portions are constructed of Mylar and further wherein a magnet holding device is located in one of said holder portions.
  • annular member is constructed of graphite and said mating elements of said holder portions are constructed of an alumina oxide ceramic material and further wherein a magnet holding device is located in one of said holder portions.

Description

Nov. 29 1960 w. c. BROOKE SEMICONDUCTOR ASSEMBLING APPARATUS Filed July 31, 1958 a m w z z 2 a 4 w M m if ill- 3 4 I 7/// H a w w M a z k 6 4 I 2 z 3M7 ATTORNEYS United States Patent SEMICONDUCTOR ASSEMBLING APPARATUS Wendell C. Brooke, Dallas, Tex., assignor to Texas Instruments Incorporated, Dallas, Tex., a corporation of Delaware Filed July 31, 1958, Ser. No. 752,308
Claims. (Cl. 219-9.5)
This invention relates to improvements in semiconductor assembling apparatus and more specifically relates to a separable holder for holding a contact element and a semiconductor element and correctly positioning these elements relative to one another and to an apparatus for sealing the elements together.
In the manufacture of diodes and other semiconductor translators, it is common to mount one of the pair of elements, usually a semiconductor wafer, within a tubular glass envelope and locate a glass bead on the other element, usually the point contact element. The whisker element is adapted to fit within the end of the tubular glass member. It is usually the practice then to heat seal the edges of the bead within the tube by fusing after the elements have been assembled in proper relationship. This heating is customarily accomplished by indirect means, such as high frequency induction devices, although resistance heating is sometimes used. For RF heating, it is known to provide a conductive member adjacent the area of the glass envelope that is to be sealed. This member is heated to a high temperature by currents induced therein by the induction coil and transfers its heat to the glass envelope essentially by conduction to seal the bead within the glass envelope and thereby hermetically seal the semiconductor device.
In one known device for assembling semiconductors as described above, there is provided a graphite ring as the heat concentrating member within the field of the induction coil. Graphite is especially suitable for this purpose as it is highly conductive and will not adhere to the fused glass. The use of a graphite ring poses problems when it is subjected to air during use. Graphite quickly deteriorates from oxidation under these circumstances and, hence, the ring physically decays in a short time to the point where it is no longer usable. Moreover, the deterioration of the graphite ring, sometimes referred to as flaking, has caused temperature control problems because it produces a decreased size of the radiating heating means with a proportional reduction of heat delivered. This necessitates a change in the time the RF energy is applied on nearly each diode assembly made. The present manner of coping with this problem is to increase both the size of the graphite ring and the distance between the graphite ring and the glass envelope. Thus, a decrease in the physical size by flaking will not produce as large a percentage change in the heat delivered to the glass envelope as when the graphite ring more closely surrounds the glass envelope. Thus greater stability is achieved in the time setting for applying the RF energy. However, in order to do this, the graphite ring must be larger and the amount of heat delivered therefrom must be greater. Thus, the problem of protecting the semiconductor wafer is much greater because the heating is not so well localized.
The present invention overcomes this difiiculty by substantially reducing the flaking of the graphite ring thereby permitting the graphite ring to be much smaller and closer to the glass envelope. Hence, the heat delivered ICC is much more localized and the semiconductor wafer is not adversely affected. Stability in the time setting for the application of RF energy is also achieved.
This invention provides a means for prolonging the sealing life of the heating ring by providing a novel enclosing holder therefor. It was discovered that by enclosing the graphite ring within a holder, the ring will last through approximately two and a half times as many heating cycles as a ring which is not so enclosed.
Accordingly, it is a principal object of this invention to provide a separate holder for assembling semiconductors having an induction-heated heating ring, completely enclosed when the holder is assembled, for heating and fusing the glass areas of the envelope and bead to be joined.
A further object of this invention is to provide a separable holder having mating portions which provide a reference for positioning of the whisker and semiconductor element of a diode.
It is another object of this invention to provide an improved separable holder to aid in assembling and sealing a sem'conductor assembly to produce a glass encapsulated semiconductive device wherein the holder has improved means for holding both the semiconductor element and the contact element.
It is an additional object of this invention to provide a separable holder having a surface which may be used as a reference point to position the holder correctly with respect to a high frequency induction coil and thus positlon an enclosed graphite ring directly adjacent the coil.
Other objects and advantages of this invention will be apparent from the following detailed description taken in connection with the accompanying drawing which discloses, by way of example, the principle of this invention and the best mode which has been contemplated of applying that principle.
In the drawing:
Figure 1 is a sectional elevation view of the holder of this invention shown assembled; and
Figure 2 is an exploded view partially in section of the semiconductor elements before they are assembled and sealed by the apparatus of Figure 1.
Referring to the drawing, the improved apparatus for assembling and sealing the diodes comprises a holder generally indicated by reference numeral 10 which is separable into an upper portion 12 and a lower portion 14. The portion 12 is adapted to hold lead 16, the assembly consisting of contact element 26, and glass bead 20, while the portion 14 is adapted to hold a subassembly indicated at 23 and consisting of lead 18, semiconductor element 24 mounted on a molybdenum plug 25 which has previously been sealed within an envelope 22 as shown in Figure 2.
Also shown in Figure 2, the contact element or whisker 26 of the diode is connected to the end of a lead 16 on which is located a glass bead 20. The assembly including the semiconductor element 24 includes glass tube 22 surrounding the semiconductor element 24 and a lead 18 attached to the plug 25. The envelope is illustrated and described as being made of glass as a matter of convenience, but other equivalent materials may be substituted for the glass. The end of whisker 26 is correctly positioned by the holder of this invention in engagement with the top of the semiconductor element 24.
The upper portion 12 of the holder 10 includes a mating section 28 having a tapered mating surface 30 and a threaded bore 31 into which is threaded a tube 32 constructed preferably of brass since it is noncorrosive and easy to machine. However, copper or steel may also be used. The tube 32 and the element 28 preferably have aligned axial holes 34 and 36 therein to allow the lead wire 16 of the contact element to extend therethrough. This wire 16 of the contact element is held by a suitable magnet 38 which is slidably mounted within the tube 32. A plunger or weight 4! or any other suitable biasing means may be utilizedto assure that the magnet 38 is at the bottom of the tubular element 32 when the device is to be sealed. This assures the proper pressure being applied to element 26.
The lower portion 14 of the holder 1t has a mating element 42 with a tapered surface 44 adapted to mate with tapered surface 3t) of the upper portion 12 of the holder and correctly positions the bottom and top portions 12 and 14 of the holder with respect to each other. The mating elements 28 and 42 are preferably constructed of boron nitride or any other suitable material capable of withstanding ahigh thermal shock in the order of 2009 C. or more. Another suitable material for the mating elements 28 and 42 is a material known under the trademark of Diamonite which is made by Diamonite Products- Manufacturing Co. of Canton, Ohio, a Division of United States Ceramic Tile Co. Another suitable material for the mating elements is Mylar which is a highly durable polyethylene terephthalate resin and which is a registered trademark of E. I. Du Pont de Nemours & Company of Wilmington, Delaware. Still another material which may be used for the mating surfaces is an alumina oxide ceramic material sold .by American Lava Corporation of Chattanooga, Tennessee. All of these materials are characterized by the property of withstanding high thermal shock.
The mating element 42 is threadedly attached to a body element 46 which has a flange 48 thereon. Also threadedly attached within a bore in the upper end of body element 46 is an induction ring holder 54. This holder is generally tubular in shape and has an upper portion shaped to support an induction ring 56. This ring is preferably constructed of graphite although any conductive material that would concentrate the radio-frequency electrical energy and transfer the same to the glass without adhering thereto may be used. A tubular support 58 constructed of brass, copper or like material possessing high thermal conductivity is axially positioned within the body member 46 and has a threaded plug as on the lower end thereof for cooperating with a threaded bore 62 in the body element 46. By this means the tube 58 may be adjusted to position it axially with respect to the body. The glass tube of the semiconductor element of the diode is supported on the top of this tube as shown in Figure l. The lower end of the body element -46 may have a threaded portion 64 on the periphery thereof for suitable cooperation in any desired type of support means.
A coil 65 connected to a suitable source of radio-frequency electrical energy is adapted to be positioned as shown in Figure 1 adjacent the graphite ring 56 and surrounding the holder. The coil 65 may be supported on body 66, and the flange 48 of the body member 36 may be utilized to position the holder 10 and the ring 56 carried therein with reference to the stationary coil after the holder has been assembled as shown in Figure 1.
It is believed that the operation of the device wili be apparent from the foregoing description, however, a brief summary of the operation will now be given. W.th the members 12 and 14 separated, the lead wire 16 of the contact element is positioned within the upper portion 12 of the separable holder 18 and is held therein by the magnet 38. The subassembly 23 is positioned within the lower portion of the holder 14 while the portions of the holder 10 are separated. The holder portions 12 and 14 are then assembled and the mating surfaces 44 and 30 will correctly position the glass head 26 within the top of the glass tube 22 with the whisker 26 in contact with the semiconductor element 24. As shown in Figure 1, the graphite ring 56 will be adjacent the area of the envelope to be sealed, i.e., the top of glass tube 22 and theglass bead 20. if it is desired to move the glass 4 tube 22 this may be accomplished by adjusting the nut 69 within the threaded bore 62. The plunger '40 insures that the magnet 33 is resting against the bottom of the tube 32. Any suitable jig or clamping fixture may be used to insure that the holder portions are securely assembled. The holder is positioned such that the induction coil 65 surrounds the holder adjacent the induction ring 56. This may be accomplished by positioning the holder until top surface of flange 48 abuts a suitable mating surface on body 66.
After the holder has been correctly positioned, R.F. energy is applied to the coil 65 and this in turn heats the graphite ring by induction heating. The graphite ring becomes heated to a temperature of 20002500 C. and transfers its heat to the glass without sealing itself thereto. Furthermore, the envelope is only heated to a fusing temperature in the sealing region and the heat generated will not adversely affect the semiconductormaterial which is remote from the sealing region. The unusual result obtainable with the above disclosed holder isthat by enclosing the heat concentrating ring within the holder and excluding air flow around the graphite ring, the average life of the ring has been extended from approximately 40 seals per ring .to around sealing operations per ring. Also the holder may be automatically loaded with the subassembly parts of the diode shown in Figure 2 thereby permitting mass production of the diodes.
The embodiment of the invention disclosed above is for the purposes of illustration only. It will be understood that the invention is susceptible to'modifications, substitutions, and changes in form and details by one skilled in the art without departing from the spirit of the invention. Therefore, this invention is limited only by the scope of the appended claims wherein applicant is entitled to a reasonable range of equivalents.
What is claimed is:
1. An apparatus for assembling a semiconductor element and a contact element in proper engaging relationship and for enclosing same in an envelope, comprising a holder having a pair of separable portions, one of said portions adapted to hold a semiconductor element and part of an envelope and the other of said portions adapted to hold a contact element and the remaining part of he envelope, said portions provided with mating surfaces such that when assembled they will position the semiconductor element and contact element in proper engaging relationship and said portions will be engaged to enclose substantially the semiconductor element, contact element and envelope, an electrical coil adapted to supply high frequency electrical energy to said holder positioned around said holder adjacent the area of the joint between the envelope parts to be fused, and a heating member carried by one of said elements of said holder in a position adjacent the area of the joint between the envelope parts to be fused, said heating member being totally enclosed within said holder when the elements of said holder are assembled to accomplish the sealing operation.
2. An apparatus as defined in claim 1 wherein said heating member is a ring constructed of graphite.
3. A device as defined in claim 1 wherein the mating surfaces of said holder portions are tapered.
4. A device as defined in claim 3 wherein the holder portion adapted to hold the contact element carries a mag net for holding said element.
5. A device as defined in claim 4 wherein the holder portion adapted to hold the semiconductor element includes an adjustable support therein for adjustably positioning the semiconductor element within the holder portion.
6. A holder for holding the elements of a semiconductor diode and the parts of an encapsulating envelope and correctly positioning same in proper engagement, said holder comprising a pair of holder portions, said holder portions having mating elements such that when the elements of the diode and the parts of the envelope are held therein and the holder portions are assembled, the elements and parts will be positioned in proper engagement and the holder portions will be engaged to enclose substantially the diode and encapsulating envelope, and an annular heating member positioned within the holder adjacent the parts of the envelope at the area thereof to be fused, said annular member being constructed of a material adapted to be heated by induced RF currents and to transfer its heat to the envelope thereby sealing said envelope.
7. A device as defined in claim 6 wherein said holder has a reference surface for correctly positioning an RF induction coil adjacent the annular member.
8. A device as defined in claim 7 wherein said annular member is constructed of graphite and said mating e1ements of said holder portions are constructed of boron nitride and further wherein a magnet holding device is located in one of said holder portions.
9. A device as defined in claim 7 wherein said annular member is constructed of graphite and said mating elements of said holder portions are constructed of Mylar and further wherein a magnet holding device is located in one of said holder portions.
10. A device as defined in claim 7 wherein said annular member is constructed of graphite and said mating elements of said holder portions are constructed of an alumina oxide ceramic material and further wherein a magnet holding device is located in one of said holder portions.
Gates Jan. 29, 1957 Wade et -al. Aug. 20, 1957
US752308A 1958-07-31 1958-07-31 Semiconductor assembling apparatus Expired - Lifetime US2962574A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3070683A (en) * 1960-01-27 1962-12-25 Joseph J Moro-Lin Cementing of semiconductor device components
US3093719A (en) * 1961-04-07 1963-06-11 Texas Instruments Inc Method of forming clean iron-lead telluride high temperature pressure contacts

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2779134A (en) * 1952-01-03 1957-01-29 Sylvania Electric Prod Semiconductor assembling apparatus
US2803732A (en) * 1952-01-17 1957-08-20 Sylvania Electric Prod High-speed r. f. sealing

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2779134A (en) * 1952-01-03 1957-01-29 Sylvania Electric Prod Semiconductor assembling apparatus
US2803732A (en) * 1952-01-17 1957-08-20 Sylvania Electric Prod High-speed r. f. sealing

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3070683A (en) * 1960-01-27 1962-12-25 Joseph J Moro-Lin Cementing of semiconductor device components
US3093719A (en) * 1961-04-07 1963-06-11 Texas Instruments Inc Method of forming clean iron-lead telluride high temperature pressure contacts

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