US2956910A - Removal of combustion chamber deposits - Google Patents
Removal of combustion chamber deposits Download PDFInfo
- Publication number
- US2956910A US2956910A US536020A US53602055A US2956910A US 2956910 A US2956910 A US 2956910A US 536020 A US536020 A US 536020A US 53602055 A US53602055 A US 53602055A US 2956910 A US2956910 A US 2956910A
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- US
- United States
- Prior art keywords
- deposits
- combustion
- engine
- solvent
- removal
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/032—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing oxygen-containing compounds
- C23G5/036—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing oxygen-containing compounds having also nitrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/06—Use of additives to fuels or fires for particular purposes for facilitating soot removal
Definitions
- the invention relates to the removal of carbonaceous deposits from the combustion chambers of internal combustion engines. More particularly, it relates to materials capable of dissolving such deposits and to an economical method for the removal of such deposits.
- combustion deposit solvents are of great value to the art since they afford a most convenient and economical way of keeping an engine free of deposits and, consequently, in top operating condition. Accordingly, it is the prime object of the present invention to provide a new combustion deposit solvent. Other and further objects will appear from the description of the invention.
- this invention pro vides a method for the removal of combustion deposits nited States PatcntO 2,956,910 Patented Oct. 18, 1960 from the metal surfaces of internal combustion engines which comprises applying N-methyl-Z-pyrrolidone to the adhered deposits and then removing the loosened deposits.
- a specific and preferred embodiment of the invention involves the contacting of the deposit-coated engine parts with the N-methyl-Z-pyrrolidone without dissembling the engine and then starting the engine to cause the loosened deposits to be removed and carried out through the exhaust. This particular embodiment of the invention is described more fully hereinbelow.
- N-methyl-Z-pyrrolidone as a combustion deposit solvent has been demonstrated by the following tests.
- a sample of a typical deposit taken from the combustion chambers of a road test car was first de-oiled by extraction with normal pentane.
- One gram of the deposit was then soaked in 25 cc. of the N-methyl-2- pyrrolidone for one hour at room temperature and then filtered.
- the undi-ssolved deposit was washed with 50 cc. of methanol, dried'and weighed. The per cent soluble in each of the solvents is shown below.
- the results of similar tests made on a material sold commercially as a combustion deposit solvent are also shown for comparison.
- Percent deposit is more than three times as strong a solvent for the combustion deposits as the commercial material.
- the utilization of the N-methyl-Z- pyrrolidone in accordance with the invention preferably involves bringing the solvent into contact with the depositcoated engine parts without dissembling the engine.
- a preferred procedure is as follows. A portion of the solvent, say 25 to cc., preferably about 50 cc., is either poured or sprayed into the combustion chamber through the spark plug hole.
- Another method of applying the N- methyl-Z-pyrrolidone is to slowly introduce a suitable amount into the carburetor air-intake while the engine is idling, the rate of addition of the last portion of the dose being increased so as to cause the engine to stall. In this way a good distribution of the solvent in the combustion chambers is assured.
- the solvent is introduced to the combustion chamber after the engine has been operated for a period of time so that the coated metal parts have become heated.
- the solvent may be preheated before introducing it to the combustion chamber.
- the solvent is allowed to act on the deposits for a suitable period of time, depending upon the severity of the deposit condition. In general, it has been found that from about 1 to about 6 hours is a sufiicient length of time to provide excellent results.
- the engine is then started up and the loosened carbon and other deposit particles are blown out through the exhaust.
- the solvent of the invention is particularly advantageous in providing for the removal of combustion deposits from the engine parts without dissembling the engine, it may also be used in cleaning the coated parts of a dissembled engine.
- the solvent may be applied to the coated parts by some suitable method, such as spraying, painting or immersion, and after allowing time for it to act on the deposits the loosened deposits may be wiped, brushed or blown off the metal surfaces.
- the parts may be heated by a flame, or otherwise, to accelerate the solvent action, if desired.
- N-methyl-Z-pyrrolidone provides excellent results when used alone, it has been found that its effectiveness is enhanced in certain instances by using it in combination with an organic type solvent.
- solvents as benzene, cresols, dichloroand tnichlorobenzenes; with ketones, such as methyl ethyl ketone; with esters, such as ethyl acetate; and with amides, such as formamide, dimethylfoirmamide, etc.
- solvent combinations may suitably comprise from about 25% to about 75% of the N-methyl-Z-pyrrolidone.
- the method of removing combustion deposits from the metal parts of an internal combustion engine which comprises heating the deposit-coated parts, contacting the deposits with N-methyl-Z-pyrrolidone and then removing the loosened deposits.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Liquid Carbonaceous Fuels (AREA)
Description
REMOVAL OF COMBUSTION DEPOSITS John J. Giammaria, Woodbury, NJ., assignor to Socony Mobil Oil Company Inc.,a corporation of New York No Drawing. Filed Sept. 22, 1955, Ser. No. 536,020
3 Claims. (Cl. 134-22) The invention relates to the removal of carbonaceous deposits from the combustion chambers of internal combustion engines. More particularly, it relates to materials capable of dissolving such deposits and to an economical method for the removal of such deposits.
It is well known that solid deposits, consisting principally of carbon and other products of combustion of the fuel mixture and lubricating oil, such as lead salts, formed from tetraethyl lead which is commonly used as an antiknock agent in gasoline, adhere to the interior parts, such as the combustion chambers, pistons, cylinder heads and valves, of internal combustion engines. The harmful effects of these deposits have been recognized for some time. One harmful effect is the increase in octane requirement of an engine caused by the build-up of these deposits. Another is pre-ignition which is caused primarily by glowing deposit particles which ignite the fuel charge before the normal spark. These harmful effects are reflected in rough engine operation and power loss. This is particularly true in the case of the newer, high compression type engines. Other detrimental effects of these deposits are that they lower the efficiency of heat transfer from the combustion chambers to the cooling jacket and reduce the capacity of the engine to take in a full charge of air and fuel. Also, the accumulation of such deposits has been found to shorten the working life of the exhaust valves. Accordingly, some easy means of accomplishing the removal of these deposits has been sought. Such means have been provided in the prior art through the development of certain liquid materials which exert a solvent action on the combustion deposits, but which have no harmful effect on the metal parts. By the employment of such materials, which are known in the art as combustion deposit solvents, the removal of the deposits may be accomplished without dissembling the engine. Thus, by introducing the solvent into the combustion chamber and allowing it time to act on the surface deposits, the deposits are effectively loosened. The engine is then started up and the loosened deposits are blown out through the exhaust. It will be appreciated then that combustion deposit solvents are of great value to the art since they afford a most convenient and economical way of keeping an engine free of deposits and, consequently, in top operating condition. Accordingly, it is the prime object of the present invention to provide a new combustion deposit solvent. Other and further objects will appear from the description of the invention.
In accordance with the invention, it has now been found that N-methyl-2-pyrrolidone,
is a highly effective combustion deposit solvent. Accordingly, it is seen that, broadly stated, this invention pro vides a method for the removal of combustion deposits nited States PatcntO 2,956,910 Patented Oct. 18, 1960 from the metal surfaces of internal combustion engines which comprises applying N-methyl-Z-pyrrolidone to the adhered deposits and then removing the loosened deposits. A specific and preferred embodiment of the invention, however, involves the contacting of the deposit-coated engine parts with the N-methyl-Z-pyrrolidone without dissembling the engine and then starting the engine to cause the loosened deposits to be removed and carried out through the exhaust. This particular embodiment of the invention is described more fully hereinbelow.
The ability of the N-methyl-Z-pyrrolidone as a combustion deposit solvent has been demonstrated by the following tests. A sample of a typical deposit taken from the combustion chambers of a road test car was first de-oiled by extraction with normal pentane. One gram of the deposit was then soaked in 25 cc. of the N-methyl-2- pyrrolidone for one hour at room temperature and then filtered. The undi-ssolved deposit was washed with 50 cc. of methanol, dried'and weighed. The per cent soluble in each of the solvents is shown below. The results of similar tests made on a material sold commercially as a combustion deposit solvent are also shown for comparison.
Percent deposit is more than three times as strong a solvent for the combustion deposits as the commercial material.
As aforementioned, the utilization of the N-methyl-Z- pyrrolidone in accordance with the invention preferably involves bringing the solvent into contact with the depositcoated engine parts without dissembling the engine. A preferred procedure is as follows. A portion of the solvent, say 25 to cc., preferably about 50 cc., is either poured or sprayed into the combustion chamber through the spark plug hole. Another method of applying the N- methyl-Z-pyrrolidone is to slowly introduce a suitable amount into the carburetor air-intake while the engine is idling, the rate of addition of the last portion of the dose being increased so as to cause the engine to stall. In this way a good distribution of the solvent in the combustion chambers is assured. Preferably, the solvent is introduced to the combustion chamber after the engine has been operated for a period of time so that the coated metal parts have become heated. Also, the solvent may be preheated before introducing it to the combustion chamber.
The solvent is allowed to act on the deposits for a suitable period of time, depending upon the severity of the deposit condition. In general, it has been found that from about 1 to about 6 hours is a sufiicient length of time to provide excellent results. The engine is then started up and the loosened carbon and other deposit particles are blown out through the exhaust.
It will be appreciated that, although the solvent of the invention is particularly advantageous in providing for the removal of combustion deposits from the engine parts without dissembling the engine, it may also be used in cleaning the coated parts of a dissembled engine. Thus, the solvent may be applied to the coated parts by some suitable method, such as spraying, painting or immersion, and after allowing time for it to act on the deposits the loosened deposits may be wiped, brushed or blown off the metal surfaces. The parts may be heated by a flame, or otherwise, to accelerate the solvent action, if desired.
Although generally speaking the N-methyl-Z-pyrrolidone provides excellent results when used alone, it has been found that its effectiveness is enhanced in certain instances by using it in combination with an organic type solvent. Thus, it has been found highly effective when used with such solvents as benzene, cresols, dichloroand tnichlorobenzenes; with ketones, such as methyl ethyl ketone; with esters, such as ethyl acetate; and with amides, such as formamide, dimethylfoirmamide, etc. Such solvent combinations may suitably comprise from about 25% to about 75% of the N-methyl-Z-pyrrolidone.
Having now fully described the invention, what is claimed is:
1. The method of removing combustion deposits from the metal parts of an internal combustion engine which comprises applying N-methyl-Z-pyrrolidone to the deposits and then removing the loosened deposits.
2. The method of removing combustion deposits from the metal parts of an internal combustion engine which comprises heating the deposit-coated parts, contacting the deposits with N-methyl-Z-pyrrolidone and then removing the loosened deposits.
3. The method of removing combustion deposits from the combustion chamber of an internal combustion engine which comprises contacting deposits with N-methyl-Z-pyrrolidone and then removing the loosened deposits.
References Cited in the file of this patent UNITED STATES PATENTS 1,833,429 Lovell et a1 Nov. 24, 1931 1,908,705 Jaeger May 16, 1933 1,914,509 Jaeger June 20, 1933 1,924,722 Lovell et a1 Aug. 29, 1933 1,941,689 Jaeger Jan. 2, 1934 2,281,598 Pruttonv May 5, 1942 2,509,197 Borus et al. May 30, 1950 2,599,649 Lorenz June 10, 1952 2,704,733 'Pearsall Mar. 22, 1955 2,753,381 Nelson July 3, 1956 OTHER REFERENCES Walker, Jr., Applied Chem. (London), vol. 2, pp. 470- 481 (1952).
Claims (1)
1. THE METHOD OF REMOVING COMBUSTION DEPOSITS FROM THE METAL PARTS OF AN INTERNAL COMBUSTION ENGINE WHICH COMPRISES APPLYING N-METHYL-2-PYRROLIDONE TO THE DEPOSITS AND THEN REMOVING THE LOOSENED DEPOSITS.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US536020A US2956910A (en) | 1955-09-22 | 1955-09-22 | Removal of combustion chamber deposits |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US536020A US2956910A (en) | 1955-09-22 | 1955-09-22 | Removal of combustion chamber deposits |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2956910A true US2956910A (en) | 1960-10-18 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US536020A Expired - Lifetime US2956910A (en) | 1955-09-22 | 1955-09-22 | Removal of combustion chamber deposits |
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| Country | Link |
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| US (1) | US2956910A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4033784A (en) * | 1975-08-25 | 1977-07-05 | Halliburton Company | Method for dissolving asphaltic material |
| DE2732064A1 (en) * | 1977-07-15 | 1979-05-31 | Goldschmidt Ag Th | Cleaning film for removing cured phenolic resin residues - from press platens and moulds, contains methyl-pyrrolidone and nonionic wetting agent |
| US4376069A (en) * | 1979-10-15 | 1983-03-08 | Life Industries Corporation | Hydrotropic cleaner and deoxidizer |
| US4666529A (en) * | 1985-11-21 | 1987-05-19 | Shell Oil Company | Method for reducing combustion chamber deposits from an internal combustion engine |
| EP0487255A1 (en) * | 1990-11-22 | 1992-05-27 | The British Petroleum Company P.L.C. | Composition and process for inhibiting and removing carbonaceous deposits |
| US5324363A (en) * | 1992-07-20 | 1994-06-28 | Exxon Research And Engineering Company | Method for carbonaceous deposit removal and for reducing engine octane requirement using an aqueous base |
| US5340488A (en) * | 1989-11-15 | 1994-08-23 | Petro Chemical Products, Inc. | Composition for cleaning an internal combustion engine |
| US5698045A (en) * | 1995-04-13 | 1997-12-16 | Basf Corporation | Method of cleaning polymer residues with NMP |
| US5752990A (en) * | 1996-03-29 | 1998-05-19 | Exxon Research And Engineering Company | Composition and method for reducing combustion chamber deposits, intake valve deposits or both in spark ignition internal combustion engines |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1833429A (en) * | 1929-08-28 | 1931-11-24 | Gen Motors Res Corp | Method and means for removing carbon deposits |
| US1908705A (en) * | 1931-07-23 | 1933-05-16 | Selden Co | Motor fuel |
| US1914509A (en) * | 1931-07-24 | 1933-06-20 | Selden Co | Motor fuel |
| US1924722A (en) * | 1929-08-28 | 1933-08-29 | Gen Motors Res Corp | Method and means for removing carbon deposits |
| US1941689A (en) * | 1931-07-20 | 1934-01-02 | Selden Co | Motor fuel |
| US2281598A (en) * | 1939-03-17 | 1942-05-05 | Lubri Zol Corp | Solvent and fuel containing same |
| US2509197A (en) * | 1948-01-16 | 1950-05-30 | Shell Dev | Carbon remover and metal surface cleaning composition |
| US2599649A (en) * | 1950-08-31 | 1952-06-10 | Lorenz Lothar | Acetylene solution |
| US2704733A (en) * | 1955-03-22 | Process for removing deposits from | ||
| US2753381A (en) * | 1953-12-18 | 1956-07-03 | Phillips Petroleum Co | Nu-acyl pyrrolidines as selective solvents |
-
1955
- 1955-09-22 US US536020A patent/US2956910A/en not_active Expired - Lifetime
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2704733A (en) * | 1955-03-22 | Process for removing deposits from | ||
| US1833429A (en) * | 1929-08-28 | 1931-11-24 | Gen Motors Res Corp | Method and means for removing carbon deposits |
| US1924722A (en) * | 1929-08-28 | 1933-08-29 | Gen Motors Res Corp | Method and means for removing carbon deposits |
| US1941689A (en) * | 1931-07-20 | 1934-01-02 | Selden Co | Motor fuel |
| US1908705A (en) * | 1931-07-23 | 1933-05-16 | Selden Co | Motor fuel |
| US1914509A (en) * | 1931-07-24 | 1933-06-20 | Selden Co | Motor fuel |
| US2281598A (en) * | 1939-03-17 | 1942-05-05 | Lubri Zol Corp | Solvent and fuel containing same |
| US2509197A (en) * | 1948-01-16 | 1950-05-30 | Shell Dev | Carbon remover and metal surface cleaning composition |
| US2599649A (en) * | 1950-08-31 | 1952-06-10 | Lorenz Lothar | Acetylene solution |
| US2753381A (en) * | 1953-12-18 | 1956-07-03 | Phillips Petroleum Co | Nu-acyl pyrrolidines as selective solvents |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4033784A (en) * | 1975-08-25 | 1977-07-05 | Halliburton Company | Method for dissolving asphaltic material |
| US4108681A (en) * | 1975-08-25 | 1978-08-22 | Halliburton Company | Method for dissolving asphaltic material |
| DE2732064A1 (en) * | 1977-07-15 | 1979-05-31 | Goldschmidt Ag Th | Cleaning film for removing cured phenolic resin residues - from press platens and moulds, contains methyl-pyrrolidone and nonionic wetting agent |
| US4376069A (en) * | 1979-10-15 | 1983-03-08 | Life Industries Corporation | Hydrotropic cleaner and deoxidizer |
| US4666529A (en) * | 1985-11-21 | 1987-05-19 | Shell Oil Company | Method for reducing combustion chamber deposits from an internal combustion engine |
| US5340488A (en) * | 1989-11-15 | 1994-08-23 | Petro Chemical Products, Inc. | Composition for cleaning an internal combustion engine |
| EP0487255A1 (en) * | 1990-11-22 | 1992-05-27 | The British Petroleum Company P.L.C. | Composition and process for inhibiting and removing carbonaceous deposits |
| US5324363A (en) * | 1992-07-20 | 1994-06-28 | Exxon Research And Engineering Company | Method for carbonaceous deposit removal and for reducing engine octane requirement using an aqueous base |
| US5698045A (en) * | 1995-04-13 | 1997-12-16 | Basf Corporation | Method of cleaning polymer residues with NMP |
| US5752990A (en) * | 1996-03-29 | 1998-05-19 | Exxon Research And Engineering Company | Composition and method for reducing combustion chamber deposits, intake valve deposits or both in spark ignition internal combustion engines |
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