US2950867A - Pulse powder feed for detonation waves - Google Patents

Pulse powder feed for detonation waves Download PDF

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US2950867A
US2950867A US815434A US81543459A US2950867A US 2950867 A US2950867 A US 2950867A US 815434 A US815434 A US 815434A US 81543459 A US81543459 A US 81543459A US 2950867 A US2950867 A US 2950867A
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powder
detonation
comminuted
gas
barrel
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US815434A
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George P Hawley
Lewis M Cowden
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Union Carbide Corp
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Union Carbide Corp
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/0006Spraying by means of explosions
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C23C4/126Detonation spraying

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  • This pulse powder feed With this pulse powder feed less powder is wasted, and the position of the powder in the barrel of the gun at the time of the detonation is controlled, thus giving greater control over the coating process.
  • This pulse powder feed also makes possible the application of other coating materials with dilferent melting temperatures by changing the position of the powder in the barrel at the timeof the detonation. This changes both the length of time heat is applied to the particles and the velocity with which the particles strike the base metal.
  • Fig. 1 is a vertical sectional diagram of a modified form of apparatus according to, and for carrying out the method of, the present invention
  • Fig. 2 is a diagrammatic comparison of the effect of pulsing on the coating.
  • Fig. 3 is a vertical sectional diagram of the preferred form of method and apparatus for Supplying the pulsed powder to the system shown in Fig. 1.
  • a combustible gas such as acetylene is supplied through a pipe 10, and an oxidizing gas such as air is supplied through a pipe il, to a mixing chamber l2 where they form a detonatable gaseous charge mixture.
  • the chamber l2 also constitutes an ignition chamber, provided with a spark plug 15. Sparking of the plug ignites the charge, leading to the formation of a detonation wave which travels through a barrel 16 of the gun and out its open end.
  • the firing of the spark plug 15 is accomplished by a spark coil 17, battery 1'8, and cam operated switch 219.
  • the frequency of firing is regulated by a variable speed motor 20 which drives the cam of the switch 19.
  • a powder tube 2S is shown between the ignition chamber 12 and the open end of the gun barrel 16.
  • the powder is supplied from a powder hopper mounted in a housing 32 and provided with a hopper vibrator 33.
  • the hopper 30 delivers the powder through a partition 34 to a vibratory dispenser 35 in the lower chamber of the housing 32 which is supice 36.
  • the dispenser 35 delivers the powder through a spout 37 to the powder pulsing device.
  • the powder pulsing device consists of a small trough 38, the bottom of which is a sliding trap door 39.
  • the door 39 is actuated by an electric solenoid 40, which in turn is energized through a cam operated microswitch 42.
  • a cam 43 is mounted on the same shafts as cam 27 and the cam for switch 19.
  • an electric solenoid valve 45 is mounted in the powder tube between the housing 32 and the gun. This valve is actuated by a microswitch 46 operated by the same cam 43 as the microswitch 42.- Switch 46 is coordinated with the cam to close the valve 45 just prior to the spark, and to open it soon after the detonation has occurred.
  • the preferred method of operating a detonation gun is to purge the barrel with gas such as nitrogen after each detonation and prior to the introduction of the detonatable fuel-oxidant mixture for the next detonation.
  • the powder pulsing device 39 is thus timed to inject powder into tube 28 in such fashion that the powder arrives in the barrel 16 subsequent to the purging portion of the cycle and prior to the tiring of spark-plug 15. Any powder introduced subsequent to the ignition will not be desirably heated and propelled by the detonation wave and accompanying hot gases against a workpiece to form a coating. This powder will simply pass through the barrel along with the purge gas stream and be wasted.
  • Fig. 3 The preferred method and apparatus for pulse powder feed to a detonation gas is shown in Fig. 3.
  • the powder is entrained in a stream of carrier gas such as nitrogen and supplied at constant velocity through a tube 50.
  • a stream of nitrogen at substantially the same velocity is supplied through a parallel tube 52.
  • the entrance ends of these tubes are mounted pivotally and gas tightly in a housing 54 by means of a support 55.
  • the outlet ends of these tubes are carried by a connecting rod 56 reciprocably and gas tightly supported by a diaphragm 57 in the top of the housing 54.
  • the connecting rod 56 is actuated by a follower 58 engaging cam 59 driven by a belt 60 from the shaft of motor 20.
  • the cam 59 moves the connecting rod 56 at regular intervals.
  • the open ends of the tubes 50 and 52 alternately register with the inlet end ⁇ of the powder introduction pipe 28.
  • the flow of powder in substantially equal pulses into the gun barrel 116 is controlled in regularly spaced intervals.
  • the device is so timed that the powder flows into the gun barrel only during the time or a portion of the time when fuel gas is also flowing into the gun barrel.
  • the continuing powder llow is collected in the hopper bottom of the housing 54.
  • the fraction of the operating cycle during which the powder enters the gun barrel is called the length of the pulse.
  • This pulse length is conveniently expressed in degrees of operating carn angle, the 'total angle from one ignition to the next being 360.
  • Fuel gas is usually introduced to the barrel for 270 of the operating cycle and the powder pulse is introduced during the fuel injection portion of the cycle. It has been found that the powder pulse length should be a maximum of 200 or 5%, of the operating cycle. It has also been found that the length of the powder pulse tends to increase as it passes through the powder tube 2S. This powder feed tube must therefore be of relatively short length in order to maintain the desired pulse lengths.
  • EXAMPLE Detonatz'on gun plating employing powder pulsing A powder pulsing feed apparatus of the type shown in Fig. 3 was operated in the following manner. Finely divided (mostly to 40 microns particle size) cast tungsten carbide composition containing, apart from the tungsten, about 9% cobalt and 4% carbon, was fed at a rate of about 8% lbs. per hour into a nitrogen gas stream of 0.2 c.f.m. and then passed continuously into powder tube 5i). Nitrogen gas at 0.4 e.f.m. was also passed continuously into tube 52. Tubes 50 and 52 were alternately passed into axial alignment with feed tube 28 connected to a detonation gun so as te provide about four powder feed pulses per second.
  • the powder which owed through tube 50 during the non-plating part of the cycle was collected and amounted to 40% of the total powder dispensed. This raised the eiciency of the resulting plating operation by 40%.
  • the accompanying detonation gun was operated at acetylene and oxygen feed rates of about 2% cfm. each. The ignition rate of the gun was about four times per second.
  • a smooth, dense, adherent layer of tungsten carbide composition about 0.06 inch thick was deposited at a rate of about one square inch per minute on a steel surface placed about three inches from the open end of the gun.
  • a method for utilizing detonation waves to act upon a comminuted solid material which comprises introducing a detonatable mixture Iof combustible gas and oxidizing gas to an elongated confined path having an open end; introducing a comminuted solid material to the detonatable mixture in said barrel, igniting said detonatable mixture to produce ⁇ a detonation therein and thereby transmit to said comminuted material some of the energy of said detonation to eject said comminuted material at high velocity from the open end of said path; and repeating these process steps in cyclical operation; the improvement which comprises introducing the comminuted solid material under pressure to the detonatable mixture in a controlled pulse timed with the cycle of operation, such comminuted material pulse being completely introduced prior to ignition of such detonatable mixture, whereby less comminuted material is Wasted and greater control over the process is obtained.
  • a method for utilizing detonation Waves to act upon a comminuted solid material which comprises introducing ⁇ a detonatable mixture of combustible gas and oxidizing gas to an elongated comined path having an open end; introducing a comminuted solid material under pressure to the detonatable 4mixture in said path; igniting said detonatable mixture to produce a detonation therein and thereby transmit to said comminuted material some of the energy of said detonation to eject said comminuted material at high velocity from the open end of said path; and repeating these process steps in cyclical operation; the improvement which comprises introducing the comminuted solid material by Ia.
  • a method for utilizing detonation waves to act upon a comminuted solid material which comprises introducing a detonatable mixture of combustible gas and oxidizing gas to an elongated confined path having an open end; introducing a comminuted solid material to the detonatable mixture in said path; igniting said detonatable mixture to produce a detonation therein and thereby transmit to said comminuted material some of the energy of said detonation to eject said comminuted material at high Velocity from the ⁇ open end of said path; purging the barrel of combustion gases with a stream of inert gas; and then repeating these process steps in cyclical operation; the improvement which comprises introducing the comminuted solid material by a stream of nitrogen gas under pressure to the detonatable mixture in a controlled pulse timed with the cycle or" operation, such comminuted material pulse being completely introduced subsequent to the purging portion of the previous cycle and prior to the ignition of the de
  • a method for intermittently utilizing detonation waves to act upon a comminuted solid material which comprises introducing a detonatable mixture of combustible gas and oxidizing gas to a detonation zone in an elongated cylindrical path having an open end; introducing a comminuted solid material to the detonatable mixture in said barrel; -igniting said detonatable mixture to produce a detonation therein and thereby transmit to said comminuted material some of the energy of said detonation to eject said comminuted material at high velocity from the open end of said path; and repeating these process steps in cyclical operation; the improvement which comprises introducing the comminuted solid material to the detonatable mixture contained within a detonation zone in a controlled pulse timed with the cycle of operation, such comminuted material pulse being formed and completely introduced prior to ignition of the detonatable mixture by passing a pressurized stream of said comminuted material entrained
  • Apparatus for supplying comminuted solid material in controlled pulses to an elongated barrel for utilizing detonation waves to act upon the comminuted material which comprises in combination an inlet conduit to the detonation barrel; av iirst conduit for supplying purge gas to the inlet conduit; a second conduit for supplying comminuted solid material suspended in a carrier gas to the inlet conduit; and means connected to the first and second conduits for alternately registering these conduits with the inlet conduit so as to produce alternate controlled pulses of purge gas and suspended comminuted solid material in the inlet conduit, such pulses being in timed sequential relation to the operating cycle of the detonation device.
  • Apparatus for supplying comminuted solid material in controlled pulses to a barrel for utilizing detonation waves to act upon the comminuted material which comprises in combination a comminuted material collecting chamber with an outlet for removing comminuted material therefrom; an inlet conduit to the detonation barrel, Such inlet conduit gas-tightly communicating with the chamber; a iirst conduit gas-tightly passing into the chamber for supplying purge gas to the inlet conduit; a second conduit gas-tightly passing into the chamber for Supplying comminuted solid material suspended in a carrie-r gas to the inlet conduit; and means gas-tightly passing into the chamber and connected to the first and second conduits ⁇ for -alternately registering these conduits with the'inlet conduit so as to produce alternate controlled pulses of purge gas and suspended comminuted solid material in the inlet conduit while the chamber collects 4the unused comminuted material, such pulses being in timed sequential relation to the operating cycle of the
  • Apparatus for supplying comminuted solid material in controlled pulses to a barrel for utilizing detonation Waves to act upon the comminuted material which comprises in combination a comminuted material collecting chamber with an outlet for removing comminuted material therefrom; an inlet conduit to the detonation barrel, such inlet conduit gas-tightly communicating with the chamber; a irst conduit gas-tightly passing into the chamber for supplying purge gas to the inlet conduit; a second conduit gas-tightly passing into the chamber for supplying comminuted solid material suspended in a carrier gas to the inlet conduit; and reciprocating means gastightly passing into the chamber and connected to the irst and second conduits for alternately registering these conduits with the inlet conduit so as to produce alternate controlled pulses of purge gas and suspended comminuted solid material in the inlet conduit while the chamber collects the unused comminuted material, such pulses being in timed sequential relation to the operating cycle of the detonation barrel.
  • Apparatus lfor supplying comminuted solid material in controlled pulses to a barrel for utilizing detonation waves to act upon the comminuted material which comprises in combination a comminuted material collecting chamber with an outlet for removing comminuted material therefrom; an inlet conduit to the detonation barrel, such inlet conduit gas-tightly communicating with the chamber; a lirst conduit passing into the chamber for supplying purge gas to the inlet conduit; a second conduit passing into the chamber for supplying comminuted solid material suspended in a carrier gas to the inlet conduit, such iirst and second conduits being parallel and pivotally and gas-tightly supported at the chamber wall; and a cam-operated reciprocating connecting rod gastightly passing into the chamber vand connected to the rst and second conduits for alternately registering these conduits with the inlet conduit so as to produce alternate controlled pulses of purge gas and suspended comminuted solid material in the inlet conduit, while the chamber collects the
  • a method for utilizing detonation waves to act upon a comminuted solid body which comprises introducing a detonatable mixture of combustible gas and oxidizing gas to a detonation zone in an elongated cylindrical path havingA an open end, introducing a comminuted solid material to the detonatable mixture in said barrel, igniting said detonatable mixture to produce a detonation therein and thereby transmit to said cornminuted material some of the energy of said detonation to eject said comminuted material at high velocity from the open end of said elongated cylindrical path, and repeating these process steps in cyclical operation, the improvement which comprises continuous and uniform feed and delivery of powder in inert gas through an inlet conduit at constant velocity to storage, intermittent and equal delivery of powder to said cylindrical path when said inlet conduit is in register therewith, this occurring after purging and before detonation, but only during fuel delivery, delivering purging nitrogen through another inlet conduit with alternate registration of the

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Description

Aug. 30, 1960 G. P. HAWLEY ET AL 2,950,857
PULSE POWDER FEED FR DETONATION WAVES 2 Sheets-Sheet l Filed May 25, 1959 A0255@ .Sorhv lNvENToRS GE P.HAWLEY IS M.COWDEN GEO L E w I MMM/JJM ATTORNEY Aug. 30, 1960 G. P. HAWLEY ET AL 2,950,367
PULSE POWDER FEED FOR DETONATION WAVES Filed May 25, 1959 2 Sheets-Sheet 2 VMI' 55u- N3 5U k Powder -4 P LEWIS M COWDEN ATTO R N EY PULSE POWDER FEED FOR DETONATIGN WAVES I George l?. Hawley, South Charleston, W. Va., and Lewis M. Cowden, indianapolis, lud., assignors to Union Carbide Corporation, a corporation of New York ined May 2s, 1959, ser. No. 815,434
9 claims. (c1. 239-13) This invention relates to pulse powder feed for detonation waves, and constitutes an improvement upon the subject of Poorman et al. Patent No. 2,714,563, the entire disclosure of which by this reference is hereby incorporated into this application.
The main object of the present invention is to provide method and apparatus for conveying powdered coating material from a dispenser to the barrel of the detonation gun in the form of pulses timed with the cycle of operation.
With this pulse powder feed less powder is wasted, and the position of the powder in the barrel of the gun at the time of the detonation is controlled, thus giving greater control over the coating process. This pulse powder feed also makes possible the application of other coating materials with dilferent melting temperatures by changing the position of the powder in the barrel at the timeof the detonation. This changes both the length of time heat is applied to the particles and the velocity with which the particles strike the base metal. A
The accurate metering and injection of powder in substantially equal pulses at the same point in each successive cycle eliminates some variables encountered in the detonation gun process and results in greater control over the process.
In the drawings:
Fig. 1 is a vertical sectional diagram of a modified form of apparatus according to, and for carrying out the method of, the present invention;
Fig. 2 is a diagrammatic comparison of the effect of pulsing on the coating; and
Fig. 3 is a vertical sectional diagram of the preferred form of method and apparatus for Supplying the pulsed powder to the system shown in Fig. 1.
As shown in Fig. 1, a combustible gas such as acetylene is supplied through a pipe 10, and an oxidizing gas such as air is supplied through a pipe il, to a mixing chamber l2 where they form a detonatable gaseous charge mixture. The chamber l2 also constitutes an ignition chamber, provided with a spark plug 15. Sparking of the plug ignites the charge, leading to the formation of a detonation wave which travels through a barrel 16 of the gun and out its open end. The firing of the spark plug 15 is accomplished by a spark coil 17, battery 1'8, and cam operated switch 219. The frequency of firing is regulated by a variable speed motor 20 which drives the cam of the switch 19.
To provide positive closure between the ignition chamber and the gas supply, poppet valves are operated by the motor 20 and cam 27 to obtain the desired frequency of opening and closing the valves. A powder tube 2S is shown between the ignition chamber 12 and the open end of the gun barrel 16. The powder is supplied from a powder hopper mounted in a housing 32 and provided with a hopper vibrator 33. The hopper 30 delivers the powder through a partition 34 to a vibratory dispenser 35 in the lower chamber of the housing 32 which is supice 36. The dispenser 35 delivers the powder through a spout 37 to the powder pulsing device.
The powder pulsing device consists of a small trough 38, the bottom of which is a sliding trap door 39. The door 39 is actuated by an electric solenoid 40, which in turn is energized through a cam operated microswitch 42.
For operating this switch, a cam 43 is mounted on the same shafts as cam 27 and the cam for switch 19. Once each cycle the trap door l39 slides open and closed, dropplied with an inert gas such as nitrogen through an inlet ping the powder that has collected into the powder cone 44, which delivers it into the powder tube 28, where it is carried to the open barrel by the carrier gas.
In this form of powder pulsing apparatus, rather violent pressure attained in the detonation gun at time of ignition can travel back through the powder feed tube and blow the powder from the puiser, thus destroying all effects gained by the pulse.
To prevent the back surge from reaching the dispenser, an electric solenoid valve 45 is mounted in the powder tube between the housing 32 and the gun. This valve is actuated by a microswitch 46 operated by the same cam 43 as the microswitch 42.- Switch 46 is coordinated with the cam to close the valve 45 just prior to the spark, and to open it soon after the detonation has occurred.
As disclosed in the above-mentioned Patent 2,714,563, the preferred method of operating a detonation gun is to purge the barrel with gas such as nitrogen after each detonation and prior to the introduction of the detonatable fuel-oxidant mixture for the next detonation. The powder pulsing device 39 is thus timed to inject powder into tube 28 in such fashion that the powder arrives in the barrel 16 subsequent to the purging portion of the cycle and prior to the tiring of spark-plug 15. Any powder introduced subsequent to the ignition will not be desirably heated and propelled by the detonation wave and accompanying hot gases against a workpiece to form a coating. This powder will simply pass through the barrel along with the purge gas stream and be wasted.
The preferred method and apparatus for pulse powder feed to a detonation gas is shown in Fig. 3. The powder is entrained in a stream of carrier gas such as nitrogen and supplied at constant velocity through a tube 50. A stream of nitrogen at substantially the same velocity is supplied through a parallel tube 52. The entrance ends of these tubes are mounted pivotally and gas tightly in a housing 54 by means of a support 55. The outlet ends of these tubes are carried by a connecting rod 56 reciprocably and gas tightly supported by a diaphragm 57 in the top of the housing 54. The connecting rod 56 is actuated by a follower 58 engaging cam 59 driven by a belt 60 from the shaft of motor 20.
The cam 59 moves the connecting rod 56 at regular intervals. The open ends of the tubes 50 and 52 alternately register with the inlet end `of the powder introduction pipe 28. Thus the flow of powder in substantially equal pulses into the gun barrel 116 is controlled in regularly spaced intervals. The device is so timed that the powder flows into the gun barrel only during the time or a portion of the time when fuel gas is also flowing into the gun barrel. When the barrel is being purged with nitrogen, the continuing powder llow is collected in the hopper bottom of the housing 54.
The fraction of the operating cycle during which the powder enters the gun barrel is called the length of the pulse. This pulse length is conveniently expressed in degrees of operating carn angle, the 'total angle from one ignition to the next being 360. Fuel gas is usually introduced to the barrel for 270 of the operating cycle and the powder pulse is introduced during the fuel injection portion of the cycle. It has been found that the powder pulse length should be a maximum of 200 or 5%, of the operating cycle. It has also been found that the length of the powder pulse tends to increase as it passes through the powder tube 2S. This powder feed tube must therefore be of relatively short length in order to maintain the desired pulse lengths.
EXAMPLE Detonatz'on gun plating employing powder pulsing A powder pulsing feed apparatus of the type shown in Fig. 3 was operated in the following manner. Finely divided (mostly to 40 microns particle size) cast tungsten carbide composition containing, apart from the tungsten, about 9% cobalt and 4% carbon, was fed at a rate of about 8% lbs. per hour into a nitrogen gas stream of 0.2 c.f.m. and then passed continuously into powder tube 5i). Nitrogen gas at 0.4 e.f.m. was also passed continuously into tube 52. Tubes 50 and 52 were alternately passed into axial alignment with feed tube 28 connected to a detonation gun so as te provide about four powder feed pulses per second. The powder which owed through tube 50 during the non-plating part of the cycle was collected and amounted to 40% of the total powder dispensed. This raised the eiciency of the resulting plating operation by 40%. The accompanying detonation gun was operated at acetylene and oxygen feed rates of about 2% cfm. each. The ignition rate of the gun was about four times per second. A smooth, dense, adherent layer of tungsten carbide composition about 0.06 inch thick Was deposited at a rate of about one square inch per minute on a steel surface placed about three inches from the open end of the gun.
This application is a continuation in part of application Serial No. 602,582, tile-d August 7, 1956, now abandoned.
What is claimed is:
l. In a method for utilizing detonation waves to act upon a comminuted solid material which comprises introducing a detonatable mixture Iof combustible gas and oxidizing gas to an elongated confined path having an open end; introducing a comminuted solid material to the detonatable mixture in said barrel, igniting said detonatable mixture to produce `a detonation therein and thereby transmit to said comminuted material some of the energy of said detonation to eject said comminuted material at high velocity from the open end of said path; and repeating these process steps in cyclical operation; the improvement which comprises introducing the comminuted solid material under pressure to the detonatable mixture in a controlled pulse timed with the cycle of operation, such comminuted material pulse being completely introduced prior to ignition of such detonatable mixture, whereby less comminuted material is Wasted and greater control over the process is obtained.
2. In a method for utilizing detonation Waves to act upon a comminuted solid material which comprises introducing `a detonatable mixture of combustible gas and oxidizing gas to an elongated comined path having an open end; introducing a comminuted solid material under pressure to the detonatable 4mixture in said path; igniting said detonatable mixture to produce a detonation therein and thereby transmit to said comminuted material some of the energy of said detonation to eject said comminuted material at high velocity from the open end of said path; and repeating these process steps in cyclical operation; the improvement which comprises introducing the comminuted solid material by Ia. stream of inert carrier gas to the detonatable mixture under pressure in a controlled pulse timed with the cycle of operation, such comminuted material pulse being completely introduced prior to ignition of such detonatable mixture and continuing for a maximum of 5/9 of the total operating cycle, whereby less comminuted material is wasted and greater control over the process is obtained.
3. ln a method for utilizing detonation waves to act upon a comminuted solid material which comprises introducing a detonatable mixture of combustible gas and oxidizing gas to an elongated confined path having an open end; introducing a comminuted solid material to the detonatable mixture in said path; igniting said detonatable mixture to produce a detonation therein and thereby transmit to said comminuted material some of the energy of said detonation to eject said comminuted material at high Velocity from the `open end of said path; purging the barrel of combustion gases with a stream of inert gas; and then repeating these process steps in cyclical operation; the improvement which comprises introducing the comminuted solid material by a stream of nitrogen gas under pressure to the detonatable mixture in a controlled pulse timed with the cycle or" operation, such comminuted material pulse being completely introduced subsequent to the purging portion of the previous cycle and prior to the ignition of the detonatable mixture, whereby less comminuted material is wasted and greater control over the process is obtained.
4. ln a method for intermittently utilizing detonation waves to act upon a comminuted solid material which comprises introducing a detonatable mixture of combustible gas and oxidizing gas to a detonation zone in an elongated cylindrical path having an open end; introducing a comminuted solid material to the detonatable mixture in said barrel; -igniting said detonatable mixture to produce a detonation therein and thereby transmit to said comminuted material some of the energy of said detonation to eject said comminuted material at high velocity from the open end of said path; and repeating these process steps in cyclical operation; the improvement which comprises introducing the comminuted solid material to the detonatable mixture contained within a detonation zone in a controlled pulse timed with the cycle of operation, such comminuted material pulse being formed and completely introduced prior to ignition of the detonatable mixture by passing a pressurized stream of said comminuted material entrained in an inert gas axially into said cylindrical path containing a detonatable mixture and then periodically `and controllably deilecting the comminuted material stream for collection of the unused comminuted material subsequent to the ignition of the detonatable mixture while continuing to introduce inert gas into said detonation zone.
5. Apparatus for supplying comminuted solid material in controlled pulses to an elongated barrel for utilizing detonation waves to act upon the comminuted material, which comprises in combination an inlet conduit to the detonation barrel; av iirst conduit for supplying purge gas to the inlet conduit; a second conduit for supplying comminuted solid material suspended in a carrier gas to the inlet conduit; and means connected to the first and second conduits for alternately registering these conduits with the inlet conduit so as to produce alternate controlled pulses of purge gas and suspended comminuted solid material in the inlet conduit, such pulses being in timed sequential relation to the operating cycle of the detonation device.
6. Apparatus for supplying comminuted solid material in controlled pulses to a barrel for utilizing detonation waves to act upon the comminuted material, which comprises in combination a comminuted material collecting chamber with an outlet for removing comminuted material therefrom; an inlet conduit to the detonation barrel, Such inlet conduit gas-tightly communicating with the chamber; a iirst conduit gas-tightly passing into the chamber for supplying purge gas to the inlet conduit; a second conduit gas-tightly passing into the chamber for Supplying comminuted solid material suspended in a carrie-r gas to the inlet conduit; and means gas-tightly passing into the chamber and connected to the first and second conduits `for -alternately registering these conduits with the'inlet conduit so as to produce alternate controlled pulses of purge gas and suspended comminuted solid material in the inlet conduit while the chamber collects 4the unused comminuted material, such pulses being in timed sequential relation to the operating cycle of the detonation barrel.
7. Apparatus for supplying comminuted solid material in controlled pulses to a barrel for utilizing detonation Waves to act upon the comminuted material, which comprises in combination a comminuted material collecting chamber with an outlet for removing comminuted material therefrom; an inlet conduit to the detonation barrel, such inlet conduit gas-tightly communicating with the chamber; a irst conduit gas-tightly passing into the chamber for supplying purge gas to the inlet conduit; a second conduit gas-tightly passing into the chamber for supplying comminuted solid material suspended in a carrier gas to the inlet conduit; and reciprocating means gastightly passing into the chamber and connected to the irst and second conduits for alternately registering these conduits with the inlet conduit so as to produce alternate controlled pulses of purge gas and suspended comminuted solid material in the inlet conduit while the chamber collects the unused comminuted material, such pulses being in timed sequential relation to the operating cycle of the detonation barrel.
8. Apparatus lfor supplying comminuted solid material in controlled pulses to a barrel for utilizing detonation waves to act upon the comminuted material, which comprises in combination a comminuted material collecting chamber with an outlet for removing comminuted material therefrom; an inlet conduit to the detonation barrel, such inlet conduit gas-tightly communicating with the chamber; a lirst conduit passing into the chamber for supplying purge gas to the inlet conduit; a second conduit passing into the chamber for supplying comminuted solid material suspended in a carrier gas to the inlet conduit, such iirst and second conduits being parallel and pivotally and gas-tightly supported at the chamber wall; and a cam-operated reciprocating connecting rod gastightly passing into the chamber vand connected to the rst and second conduits for alternately registering these conduits with the inlet conduit so as to produce alternate controlled pulses of purge gas and suspended comminuted solid material in the inlet conduit, while the chamber collects the unused comminuted material, such pulses being in timed sequential relation to the operating cycle of the detonation barrel.
9. ln a method for utilizing detonation waves to act upon a comminuted solid body which comprises introducing a detonatable mixture of combustible gas and oxidizing gas to a detonation zone in an elongated cylindrical path havingA an open end, introducing a comminuted solid material to the detonatable mixture in said barrel, igniting said detonatable mixture to produce a detonation therein and thereby transmit to said cornminuted material some of the energy of said detonation to eject said comminuted material at high velocity from the open end of said elongated cylindrical path, and repeating these process steps in cyclical operation, the improvement which comprises continuous and uniform feed and delivery of powder in inert gas through an inlet conduit at constant velocity to storage, intermittent and equal delivery of powder to said cylindrical path when said inlet conduit is in register therewith, this occurring after purging and before detonation, but only during fuel delivery, delivering purging nitrogen through another inlet conduit with alternate registration of the exit thereof, thus phasing the nitrogen feed, preventing back surge of powder through said other inlet conduit by disregistration thereof during a detonation and storage of the powder during periods of non-registration of the powder tube.
References Cited in the le of this patent UNITED STATES PATENTS 2,389,702 Ullmer Nov. 27, 1945 2,714,563 Poorman et al. Aug. 2, 1955 2,774,625 Hawley et al. Dec. 18, 1956 2,861,900 Smith et al. Nov. 25, 1958 FOREIGN PATENTS 199,962 Austria Oct. 10, 1958
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Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3231002A (en) * 1962-01-11 1966-01-25 Thiokol Chemical Corp Pulsed chamber pressurization system
US3361353A (en) * 1965-10-20 1968-01-02 Mitchell W. Millman Method and apparatus for injection of liquid fuels
DE2356616A1 (en) * 1972-11-17 1974-05-22 Union Carbide Corp ABRASION RESISTANT BEARING MATERIAL AND METHOD FOR ITS MANUFACTURING
US3915381A (en) * 1971-11-15 1975-10-28 Southwest Res Inst Method and apparatus for applying particulate coating material to a work piece
US4004735A (en) * 1974-06-12 1977-12-25 Zverev Anatoly Apparatus for detonating application of coatings
FR2452995A1 (en) * 1979-02-06 1980-10-31 Dudko Daniil METHOD OF APPLYING A POWDER COATING USING THE ENERGY OF AN EXPLOSION
DE3331216A1 (en) * 1983-08-30 1985-03-14 Castolin Gmbh, 6239 Kriftel DEVICE FOR THERMAL SPRAYING OF FOLDING WELDING MATERIALS
US4519840A (en) * 1983-10-28 1985-05-28 Union Carbide Corporation High strength, wear and corrosion resistant coatings
EP0143343A1 (en) * 1983-10-28 1985-06-05 Union Carbide Corporation Wear and corrosion resistant coatings and method for producing the same
EP0143344A1 (en) * 1983-10-28 1985-06-05 Union Carbide Corporation Wear and corrosion resistant coatings applied at high deposition rates
US4526618A (en) * 1983-10-18 1985-07-02 Union Carbide Corporation Abrasion resistant coating composition
US4568019A (en) * 1984-02-24 1986-02-04 Browning James A Internal burner type flame spray method and apparatus having material introduction into an overexpanded gas stream
US4588606A (en) * 1983-10-18 1986-05-13 Union Carbide Corporation Abrasion resistant coating and method for producing the same
US4626476A (en) * 1983-10-28 1986-12-02 Union Carbide Corporation Wear and corrosion resistant coatings applied at high deposition rates
US4626477A (en) * 1983-10-28 1986-12-02 Union Carbide Corporation Wear and corrosion resistant coatings and method for producing the same
US4687135A (en) * 1986-05-09 1987-08-18 Institut Problem Materialovedenia Akademii Nauk Ukrainskoi Ssr Detonation-gas apparatus for applying coatings
US4781145A (en) * 1985-07-26 1988-11-01 Amlinsky Roman A Detonation deposition apparatus
US4788077A (en) * 1987-06-22 1988-11-29 Union Carbide Corporation Thermal spray coating having improved addherence, low residual stress and improved resistance to spalling and methods for producing same
US5328763A (en) * 1993-02-03 1994-07-12 Kennametal Inc. Spray powder for hardfacing and part with hardfacing
US5405085A (en) * 1993-01-21 1995-04-11 White; Randall R. Tuneable high velocity thermal spray gun
US5445325A (en) * 1993-01-21 1995-08-29 White; Randall R. Tuneable high velocity thermal spray gun
US5520334A (en) * 1993-01-21 1996-05-28 White; Randall R. Air and fuel mixing chamber for a tuneable high velocity thermal spray gun
US5716422A (en) * 1996-03-25 1998-02-10 Wilson Greatbatch Ltd. Thermal spray deposited electrode component and method of manufacture
US6455108B1 (en) 1998-02-09 2002-09-24 Wilson Greatbatch Ltd. Method for preparation of a thermal spray coated substrate for use in an electrical energy storage device
CN103305785A (en) * 2012-03-06 2013-09-18 兰州理工大学 Pressure sensitive adhesive carrier powder continuous electro-explosive spraying device

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US2389702A (en) * 1943-04-01 1945-11-27 Haynes Stellite Co Apparatus for treating metal articles
US2714563A (en) * 1952-03-07 1955-08-02 Union Carbide & Carbon Corp Method and apparatus utilizing detonation waves for spraying and other purposes
US2774625A (en) * 1954-10-21 1956-12-18 Union Carbide & Carbon Corp Apparatus utilizing detonation waves for spraying powders
US2861900A (en) * 1955-05-02 1958-11-25 Union Carbide Corp Jet plating of high melting point materials
AT199962B (en) * 1956-08-07 1958-10-10 Union Carbide Corp Detonation device

Cited By (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3231002A (en) * 1962-01-11 1966-01-25 Thiokol Chemical Corp Pulsed chamber pressurization system
US3361353A (en) * 1965-10-20 1968-01-02 Mitchell W. Millman Method and apparatus for injection of liquid fuels
US3915381A (en) * 1971-11-15 1975-10-28 Southwest Res Inst Method and apparatus for applying particulate coating material to a work piece
DE2356616A1 (en) * 1972-11-17 1974-05-22 Union Carbide Corp ABRASION RESISTANT BEARING MATERIAL AND METHOD FOR ITS MANUFACTURING
US4004735A (en) * 1974-06-12 1977-12-25 Zverev Anatoly Apparatus for detonating application of coatings
FR2452995A1 (en) * 1979-02-06 1980-10-31 Dudko Daniil METHOD OF APPLYING A POWDER COATING USING THE ENERGY OF AN EXPLOSION
US4258091A (en) * 1979-02-06 1981-03-24 Dudko Daniil A Method for coating
DE3331216A1 (en) * 1983-08-30 1985-03-14 Castolin Gmbh, 6239 Kriftel DEVICE FOR THERMAL SPRAYING OF FOLDING WELDING MATERIALS
US4711627A (en) * 1983-08-30 1987-12-08 Castolin S.A. Device for the thermal spray application of fusible materials
US4588606A (en) * 1983-10-18 1986-05-13 Union Carbide Corporation Abrasion resistant coating and method for producing the same
US4526618A (en) * 1983-10-18 1985-07-02 Union Carbide Corporation Abrasion resistant coating composition
US4519840A (en) * 1983-10-28 1985-05-28 Union Carbide Corporation High strength, wear and corrosion resistant coatings
EP0143342A1 (en) * 1983-10-28 1985-06-05 Union Carbide Corporation High strength, wear and corrosion resistant coatings and method for producing the same
EP0143343A1 (en) * 1983-10-28 1985-06-05 Union Carbide Corporation Wear and corrosion resistant coatings and method for producing the same
EP0143344A1 (en) * 1983-10-28 1985-06-05 Union Carbide Corporation Wear and corrosion resistant coatings applied at high deposition rates
US4626476A (en) * 1983-10-28 1986-12-02 Union Carbide Corporation Wear and corrosion resistant coatings applied at high deposition rates
US4626477A (en) * 1983-10-28 1986-12-02 Union Carbide Corporation Wear and corrosion resistant coatings and method for producing the same
US4568019A (en) * 1984-02-24 1986-02-04 Browning James A Internal burner type flame spray method and apparatus having material introduction into an overexpanded gas stream
US4781145A (en) * 1985-07-26 1988-11-01 Amlinsky Roman A Detonation deposition apparatus
US4687135A (en) * 1986-05-09 1987-08-18 Institut Problem Materialovedenia Akademii Nauk Ukrainskoi Ssr Detonation-gas apparatus for applying coatings
US4788077A (en) * 1987-06-22 1988-11-29 Union Carbide Corporation Thermal spray coating having improved addherence, low residual stress and improved resistance to spalling and methods for producing same
US5405085A (en) * 1993-01-21 1995-04-11 White; Randall R. Tuneable high velocity thermal spray gun
US5445325A (en) * 1993-01-21 1995-08-29 White; Randall R. Tuneable high velocity thermal spray gun
US5520334A (en) * 1993-01-21 1996-05-28 White; Randall R. Air and fuel mixing chamber for a tuneable high velocity thermal spray gun
US5328763A (en) * 1993-02-03 1994-07-12 Kennametal Inc. Spray powder for hardfacing and part with hardfacing
US5716422A (en) * 1996-03-25 1998-02-10 Wilson Greatbatch Ltd. Thermal spray deposited electrode component and method of manufacture
US6455108B1 (en) 1998-02-09 2002-09-24 Wilson Greatbatch Ltd. Method for preparation of a thermal spray coated substrate for use in an electrical energy storage device
CN103305785B (en) * 2012-03-06 2015-04-22 兰州理工大学 Pressure sensitive adhesive carrier powder continuous electro-explosive spraying device
CN103305785A (en) * 2012-03-06 2013-09-18 兰州理工大学 Pressure sensitive adhesive carrier powder continuous electro-explosive spraying device

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