US2912794A - Electron tube - Google Patents

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US2912794A
US2912794A US625139A US62513956A US2912794A US 2912794 A US2912794 A US 2912794A US 625139 A US625139 A US 625139A US 62513956 A US62513956 A US 62513956A US 2912794 A US2912794 A US 2912794A
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glass
disc
tube
tubes
discs
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US625139A
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Jr Joseph S Harvey
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GTE Sylvania Inc
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Sylvania Electric Products Inc
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J21/00Vacuum tubes
    • H01J21/36Tubes with flat electrodes, e.g. disc electrode
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/02Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing by fusing glass directly to metal
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T403/00Joints and connections
    • Y10T403/44Three or more members connected at single locus
    • Y10T403/447Mutually contacting
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T403/00Joints and connections
    • Y10T403/47Molded joint
    • Y10T403/477Fusion bond, e.g., weld, etc.

Definitions

  • a stem is prepared which includes a press of glass through which a plurality of lead wires are sealed. Elements which constitute the operating electrodes of the tube, or the filament of the lamp, are welded to the ends of these lead wires. The opposite ends of the lead wires extend through the press. The entire stem is sealed into a bulb and the bulb is evacuated to provide the vacuum necessary for operation. If a gas fill is desired, the gas fill is introduced after evacuation of air in the bulb and the atmosphere is then sealed out. Occasionally, where voltage considerations or need for isolation of leads exists, one or more leads are led out through the wall of the bulb at points removed from the stem.
  • planar tube To reduce capacity in these tubes, a disc is used to connect the Working elements of the tube through the glass to external potential sources. It has also proven possible with these structures to further minimize capacity and electron transit time by bringing the various elements of the tube into very close relationship within the tube because of the superior strength and rigidity of support provided. Inv this fashion successful high frequency operation has been achieved.
  • the microwave tubes have included one or more discs of metal against which cylinders of glass are sealed.
  • Material such as a wellknown alloy of iron, nickel and cobalt known as Kovar has been used for some of the metal discs and the glass which is sealed to the Kovar has a coefficient of expansion which closely matches that of the Kovar.
  • copper has been used and in some cases, the copper has been silver-plated to provide an even higher Q.
  • the coefiicient of expansion of copper is quite different from that of any glass which can be successfully used therewith in an electron tube, successful construction of the tubes has depended upon the ability of the copper disc to give when the sealed assembly is heated or cooled and expansion or contraction takes place.
  • the copper disc is a thin sheet and is sandwiched between two cylinders of glass. In this fashion, thebutt seals are balanced; the glass cylinders normally being placed opposite each other on the disc.
  • Several techniques have been developed to enhance the structural strength of seals made in this fashion.
  • One of the techniques which has been developed is to oxidize the copper disc prior to sealing the glass thereto. It is believed thatthe oxide coating on the copper provides a sort of transition between the copper itself and the glass which is being sealed thereto.
  • Another object is to provide a discseal which retains the advantages of conventional butt-seals without the disadvantages normally encountered.
  • the present. invention is concerned with composite structures including a thin metal element having tubular glass sections sealed to opposite faces of the element. Apertures are provided in the metallic memher to permit the flow of molten glass through the metallicv member during the sealing operation. The apertures are so disposed that melting of the glass during the sealing process provides a glass-to-glass seal.
  • Fig. 1 is a view in front elevation of a completed tube made in accordance with the teaching of the present invention
  • Fig. 2 is a sectional viewof the cylindrical glass members and metallic discs after sealing
  • Fig. 3 is a view of one embodiment of an apertured metallic disc used in the tube
  • Fig. 4 is a view of an alternative form of the metallic disc.
  • Fig. 1 the invention is shown in connection with a disc-seal electron tube for purposes of illustration only. It includes a tubular glass envelope which is formed of three cylindrical glass sections between which are sandwiched two metal discs. These discs may be of various metals known to be suitable for use in making glass-tometal seals, but in the embodiment hereinafter described and illustrated in the accompanying drawing, the discs are of copper.
  • the uppermost cylindrical glass section 11 is terminated in a tip 12.
  • the lower glass section 13 is sealed to a header 14 through which a tubular metallic member 15 passes.
  • the third cylindrical glass section 17 is sealed between the metallic discs 18 and 19.
  • Within the tubular metallic member 15 there is disposed a heater and a cathode. These are of minor importance in the present invention and are not shown.
  • the cathode is disposed at the extreme upper end within the tube 15 with its active surface facing upwardly.
  • a metallic disc 19 which is closely spaced from the cathode at the end of tubular member 15 serves as a grid in the structure.
  • the second metallic member 18 serves as an anode in the electron tube.
  • the resonant cavity into which the tube may be inserted is provided with axial openings.
  • the tube is plugged into one of the axial openings in such a manner that the tubular metallic member 15 passes out through the opposite axial opening, the disc 19 is engaged by resilient fingers, and the outwardly extending flange of disc 18 butts against the outer wall of the cavity.
  • a central opening is provided in disc 19 and this opening may, if desired, be screened by grid wires 25.
  • the central portion of anode disc 18 is depressed conically and the furthest extension of the conical portion is in close proximity to the grid disc 19.
  • Fig. 2 the tube shown in Fig. 1 is illustrated in an early stage of construction.
  • the metallic discs 18 and 19 may first be coated with an oxide by heating the discs to red heat in open air.
  • the three cylindrical sections of glass 11, 13 and 17 may be cut from a continuous run of tubing in order that they may have approximately the same internal and external diameters, although that is not necessary to the invention but only desirable in the interests of symmetry and balance of the seals to be made.
  • the three sections of glass with the copper discs sandwiched therebetween are assembled in axial alignment.
  • the entire assembly is then placed in an induction coil in such a fashion that either sequentially or simultaneously, the copper discs are heated by eddy currents induced in the copper discs by the induction coil.
  • the end surfaces of the glass cylinders which abut the copper discs begin to melt as the discs approach red heat. Either by reason of gravity or because of externally applied compression, the glass softens and flows laterally from the ends of the cylinders adjacent the heated discs over the surfaces of the discs.
  • the apertures as at 2 1 in disc 18 and at 23 in disc 19 permit molten glass to flow through the discs.
  • portions of glass cylindrical section 11 become joined to portions of glass cylindrical section 17.
  • portions of glass cylindrical section 13 become joined to portions of glass cylindrical section 17.
  • the glass hardens and a strong hermetic seal results.
  • the disc 18 as best shown in Fig. 3 includes a circular array of circular openings.
  • the diameter of the array and the diameters of the respective openings are chosen so that the openings lie completely within the area of the completed glass-to-metal seal. With reasonably well matched tubing on both sides of the disc, no possibility of leakage through the disc into the tube is possible.
  • the array of openings in disc 19 is similar to the array provided in disc 18.
  • a disc is shown having openings 21' which are substantially reniform in shape and arrayed circularly.
  • the minor dimensions of the openings are chosen so that the bond between the metal disc and the glass sections completely surrounds each of the openings.
  • Either openings of the type shown in Fig. 3 or those shown in Fig. 4 may be used in discs 18 or 19. Combinations of the two types of openings may also be used. Other openings of various shapes may also be used, the only requirements being that sufiicient metal be left in the discs for proper electrical properties as is explained below. It may be clearly seen that a glass-to-glass bond exists for a considerable portion of the seal between adjacent ends of the glass tubing, when any of the embodiments shown or suggested is utilized.
  • any resonant cavity in microwave practice would have substantially continuous metallic surfaces.
  • the apertures in the discs constitute interruptions of the continuity, but the interruptions are slight in a radial direction. No significant operational difficulties are encountered because of the dispostion and size of the apertures. More important, the inherent structural Weakness of the metal-to-glass butt seals of the prior art is avoided because, in fact, the seals are no longer entirely seals of this nature. On the contrary, for a considerable distance about the periphery of the tube, a glass-to-glass seal is provided.
  • a circular copper disc having a plurality of relatively closely spaced like openings therethrough arranged in a circle coaxially with said disc and confined within the area of said disc, and at least a first and a second section of glass tubing each having a diameter approximately equal to the diameter of said circle and each having a wall thickness greater than the dimension of said openings measured along a radius of said disc in axial alignment with said disc integrally joined to each other by a glass-to-glass bond through said openings, the wall thickness of said first and second sections of glass tubing being sufficiently greater than the radial dimension of said openings as to be also respectively sealed to opposite surfaces of said disc with a glass-to-metal bond in a continuous annular area within which said openings are confined.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Joining Of Glass To Other Materials (AREA)

Description

Nov. 17, 1959 J. 5. HARVEY, JR
ELECTRON TUBE Filed Nov. 29, 1956 Fig. 2
A I I I I! I I z r I /z 1 z 1 I I I 4. I I K Fig. l
INVENTOR. JOSEPH S. HARVEY, JR.
ATTORNEYS United States Patent O ELECTRON TUBE Joseph S. Harvey, Jr., Medfield, Mass, assignor, by mesne assignments, to Sylvania Electric Products Inc., Wilnuugton, Del., a corporation of Delaware Application November 29, 1956, Serial No. 625,139
1 Claim. (Cl. 49-925) This invention relates in general to glass-to-metal seals and in particular, to electron tubeshaving such seals.
Conventional electron tubes have long been made in a manner closely resembling that used in the manufacture of incandescent lamps. Although additional electrodes not found in lamps are usually incorporated in electron tubes, the techniques for introducing electric potentials into the bulb have been and are quite similar. Normally, a stem is prepared which includes a press of glass through which a plurality of lead wires are sealed. Elements which constitute the operating electrodes of the tube, or the filament of the lamp, are welded to the ends of these lead wires. The opposite ends of the lead wires extend through the press. The entire stem is sealed into a bulb and the bulb is evacuated to provide the vacuum necessary for operation. If a gas fill is desired, the gas fill is introduced after evacuation of air in the bulb and the atmosphere is then sealed out. Occasionally, where voltage considerations or need for isolation of leads exists, one or more leads are led out through the wall of the bulb at points removed from the stem.
As the electronic art developed, there arose a necessity for diiferent types of structures of electron tubes. The primary factor giving rise to this necessity was the increasing use of electron tubes at higher frequencies. At such frequencies it became impossible to use aconventional press because the capacities existing between lead wires and electron transit time between electrodes became of significance in successful operation of the tube. In other words, the inherent capacities between leads, although small, were great enough to bypass input signals, from input circuit to output circuit. Similarly, electron transit times approached the period of the signals being generated or applied. Forall practical purposes, conventional tubes were abandoned for high frequency applications.
Perhaps the earliest structural expedient designed to avoid the difiiculties arising from excess capacity existing between leads, wasthe so-called planar tube. To reduce capacity in these tubes, a disc is used to connect the Working elements of the tube through the glass to external potential sources. It has also proven possible with these structures to further minimize capacity and electron transit time by bringing the various elements of the tube into very close relationship within the tube because of the superior strength and rigidity of support provided. Inv this fashion successful high frequency operation has been achieved.
In more recent years, with the increasing use of microwave devices, it has become necessary to utilize resonant cavities as tank circuits. Some tubes developed for this type of operation have had their own built-in resonant cavities. However, incorporation of cavities into the tubes themselves is not the most economical approach to the problem. Obviously, a tube failure due to a burned-out heater or other simple fault means discarding the entire tube, resonant cavity included. For this and other reasons of convenience in building microwave equipment, tubes have been developed to fit into resonant cavities, the tubes being'so designed that their elements actually form a continuation of the cavity when the tube is assembled therein. One of the simpler devices designed for incorporation into a resonant cavity, is'the transmit re- 2,912,794 Patented Nov. 17, 1959 ceive switch tube for radar equipment. Other tubes such asvelocity-modulation oscillators of the Klystron type, pencil tubes, rocket tubes, and lighthouse tubes are also usually incorporated in resonant cavities.
In common with the planar tubes, the microwave tubes have included one or more discs of metal against which cylinders of glass are sealed. Material such as a wellknown alloy of iron, nickel and cobalt known as Kovar has been used for some of the metal discs and the glass which is sealed to the Kovar has a coefficient of expansion which closely matches that of the Kovar. In other tubes where, for example, the requirements for a high Q have demanded it, copper has been used and in some cases, the copper has been silver-plated to provide an even higher Q. Because the coefiicient of expansion of copper is quite different from that of any glass which can be successfully used therewith in an electron tube, successful construction of the tubes has depended upon the ability of the copper disc to give when the sealed assembly is heated or cooled and expansion or contraction takes place. In the usual structure, the copper disc is a thin sheet and is sandwiched between two cylinders of glass. In this fashion, thebutt seals are balanced; the glass cylinders normally being placed opposite each other on the disc. Several techniques have been developed to enhance the structural strength of seals made in this fashion. One of the techniques which has been developed is to oxidize the copper disc prior to sealing the glass thereto. It is believed thatthe oxide coating on the copper provides a sort of transition between the copper itself and the glass which is being sealed thereto. Inasmuch as the copper oxide adheres tenaciously to the copper, and also is dissolved 'to a certain extent in the glass, a successful seal has resulted. In addition, it has been the practice to form ripples or flanges in the copper disc to add to its structural strength and resistance to distortion. Despite these precautions, however, there has been-some difiiculty with seals which break apart especially when they are subjected to sharp changes in ambient temperature. The point of rupture of the seal is usually at the junction of the oxide and the copper, and the inherent physical weakness of such butt seals even when they are balanced by similar seals on the opposite side of the metal is thus exemplified.
Therefore, it is an object of the present invention to improve g'lass-to-metal seals.
It is another object of the present invention to provide electron tubes of superior physical construction.
It is another object of the present invention to provide disc-seal electron tubes which are not subject to failure over wide ranges of ambient temperature.
Still, another object is to provide a discseal which retains the advantages of conventional butt-seals without the disadvantages normally encountered.
In general, the present. invention is concerned with composite structures including a thin metal element having tubular glass sections sealed to opposite faces of the element. Apertures are provided in the metallic memher to permit the flow of molten glass through the metallicv member during the sealing operation. The apertures are so disposed that melting of the glass during the sealing process provides a glass-to-glass seal. For a better understanding of the present invention, together with other and further. advantages, features. and objects, reference should be made to the accompanying drawing of a preferred embodiment thereof wherein:
Fig. 1 is a view in front elevation of a completed tube made in accordance with the teaching of the present invention,
Fig. 2 is a sectional viewof the cylindrical glass members and metallic discs after sealing Fig. 3 is a view of one embodiment of an apertured metallic disc used in the tube, and
Fig. 4 is a view of an alternative form of the metallic disc.
In Fig. 1 the invention is shown in connection with a disc-seal electron tube for purposes of illustration only. It includes a tubular glass envelope which is formed of three cylindrical glass sections between which are sandwiched two metal discs. These discs may be of various metals known to be suitable for use in making glass-tometal seals, but in the embodiment hereinafter described and illustrated in the accompanying drawing, the discs are of copper. The uppermost cylindrical glass section 11 is terminated in a tip 12. The lower glass section 13 is sealed to a header 14 through which a tubular metallic member 15 passes. The third cylindrical glass section 17 is sealed between the metallic discs 18 and 19. Within the tubular metallic member 15 there is disposed a heater and a cathode. These are of minor importance in the present invention and are not shown. However, the cathode is disposed at the extreme upper end within the tube 15 with its active surface facing upwardly. A metallic disc 19 which is closely spaced from the cathode at the end of tubular member 15 serves as a grid in the structure. The second metallic member 18 serves as an anode in the electron tube.
The resonant cavity into which the tube may be inserted is provided with axial openings. The tube is plugged into one of the axial openings in such a manner that the tubular metallic member 15 passes out through the opposite axial opening, the disc 19 is engaged by resilient fingers, and the outwardly extending flange of disc 18 butts against the outer wall of the cavity. As shown in Fig. 2, a central opening is provided in disc 19 and this opening may, if desired, be screened by grid wires 25. The central portion of anode disc 18 is depressed conically and the furthest extension of the conical portion is in close proximity to the grid disc 19.
In Fig. 2, the tube shown in Fig. 1 is illustrated in an early stage of construction. The metallic discs 18 and 19 may first be coated with an oxide by heating the discs to red heat in open air. The three cylindrical sections of glass 11, 13 and 17 may be cut from a continuous run of tubing in order that they may have approximately the same internal and external diameters, although that is not necessary to the invention but only desirable in the interests of symmetry and balance of the seals to be made.
The three sections of glass with the copper discs sandwiched therebetween are assembled in axial alignment. The entire assembly is then placed in an induction coil in such a fashion that either sequentially or simultaneously, the copper discs are heated by eddy currents induced in the copper discs by the induction coil. The end surfaces of the glass cylinders which abut the copper discs begin to melt as the discs approach red heat. Either by reason of gravity or because of externally applied compression, the glass softens and flows laterally from the ends of the cylinders adjacent the heated discs over the surfaces of the discs. The apertures as at 2 1 in disc 18 and at 23 in disc 19 permit molten glass to flow through the discs. Thus, portions of glass cylindrical section 11 become joined to portions of glass cylindrical section 17. In similar fashion, portions of glass cylindrical section 13 become joined to portions of glass cylindrical section 17. Upon cooling of the assembly, the glass hardens and a strong hermetic seal results.
The disc 18 as best shown in Fig. 3 includes a circular array of circular openings. The diameter of the array and the diameters of the respective openings are chosen so that the openings lie completely within the area of the completed glass-to-metal seal. With reasonably well matched tubing on both sides of the disc, no possibility of leakage through the disc into the tube is possible.
4 The array of openings in disc 19 is similar to the array provided in disc 18.
In Fig. 4, a disc is shown having openings 21' which are substantially reniform in shape and arrayed circularly. Here also, the minor dimensions of the openings are chosen so that the bond between the metal disc and the glass sections completely surrounds each of the openings.
Either openings of the type shown in Fig. 3 or those shown in Fig. 4 may be used in discs 18 or 19. Combinations of the two types of openings may also be used. Other openings of various shapes may also be used, the only requirements being that sufiicient metal be left in the discs for proper electrical properties as is explained below. It may be clearly seen that a glass-to-glass bond exists for a considerable portion of the seal between adjacent ends of the glass tubing, when any of the embodiments shown or suggested is utilized.
Ideally, any resonant cavity in microwave practice would have substantially continuous metallic surfaces. In tubes incorporating the present invention, the apertures in the discs constitute interruptions of the continuity, but the interruptions are slight in a radial direction. No significant operational difficulties are encountered because of the dispostion and size of the apertures. More important, the inherent structural Weakness of the metal-to-glass butt seals of the prior art is avoided because, in fact, the seals are no longer entirely seals of this nature. On the contrary, for a considerable distance about the periphery of the tube, a glass-to-glass seal is provided.
Although the present invention has been described with reference to an electron tube, it is obvious that the technique of providing openings through a metal element to opposite sides of which a glass member is to be sealed, is applicable in many areas. Numerous examples from the electronic art could be cited, and those skilled in the art of fabricating other apparatus and devices which include both metal and glass parts will also appreciate the advantages of the present invention. Hence, the invention should not be limited in any sense to the details shown, but only by the spirit and scope of the appended claim.
What is claimed is:
In an electron tube of the planar electrode type, a circular copper disc having a plurality of relatively closely spaced like openings therethrough arranged in a circle coaxially with said disc and confined within the area of said disc, and at least a first and a second section of glass tubing each having a diameter approximately equal to the diameter of said circle and each having a wall thickness greater than the dimension of said openings measured along a radius of said disc in axial alignment with said disc integrally joined to each other by a glass-to-glass bond through said openings, the wall thickness of said first and second sections of glass tubing being sufficiently greater than the radial dimension of said openings as to be also respectively sealed to opposite surfaces of said disc with a glass-to-metal bond in a continuous annular area within which said openings are confined.
References Cited in the file of this patent UNITED STATES PATENTS 1,579,626 Banta Apr. 6, 1926 2,197,511 Scharfragel Apr. 16, 1940 2,483,940 Scott Oct. 4, 1949 2,486,065 Saucet Oct. 25, 1949 2,575,448 Haas Nov. 20, 1951 2,553,749 Clark et al. May 22, 1951 2,656,404 Walsh Oct. 23, 1953 2,676,196 Marsden Apr. 20, 1954 FOREIGN PATENTS 696,106 Germany Sept. 11, 1940
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3107757A (en) * 1958-11-05 1963-10-22 Gen Electric Co Ltd Glass-to-metal seals

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1579626A (en) * 1923-11-19 1926-04-06 Western Electric Co Sealing leading-in conductor
US2197511A (en) * 1938-02-21 1940-04-16 Lorenz C Ag Vacuum tube device
DE696106C (en) * 1939-04-27 1940-09-11 Carl Schnuerle Process for the production of glass bottles with mouth caps
US2483940A (en) * 1943-03-03 1949-10-04 Gen Electric Method of making lead-in seals
US2486065A (en) * 1944-04-24 1949-10-25 Radio Electr Soc Fr Lead-in structure for vacuum tubes
US2553749A (en) * 1948-05-05 1951-05-22 Bell Telephone Labor Inc Sealing fixture for the manufacture of electron discharge devices
US2575448A (en) * 1945-08-22 1951-11-20 Sylvania Electric Prod Electron discharge device
US2656404A (en) * 1950-12-01 1953-10-20 Bell Telephone Labor Inc Laminated ring lead-in for electron discharge devices
US2676196A (en) * 1953-02-27 1954-04-20 Phillips Petroleum Co Electrical transducing element

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1579626A (en) * 1923-11-19 1926-04-06 Western Electric Co Sealing leading-in conductor
US2197511A (en) * 1938-02-21 1940-04-16 Lorenz C Ag Vacuum tube device
DE696106C (en) * 1939-04-27 1940-09-11 Carl Schnuerle Process for the production of glass bottles with mouth caps
US2483940A (en) * 1943-03-03 1949-10-04 Gen Electric Method of making lead-in seals
US2486065A (en) * 1944-04-24 1949-10-25 Radio Electr Soc Fr Lead-in structure for vacuum tubes
US2575448A (en) * 1945-08-22 1951-11-20 Sylvania Electric Prod Electron discharge device
US2553749A (en) * 1948-05-05 1951-05-22 Bell Telephone Labor Inc Sealing fixture for the manufacture of electron discharge devices
US2656404A (en) * 1950-12-01 1953-10-20 Bell Telephone Labor Inc Laminated ring lead-in for electron discharge devices
US2676196A (en) * 1953-02-27 1954-04-20 Phillips Petroleum Co Electrical transducing element

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3107757A (en) * 1958-11-05 1963-10-22 Gen Electric Co Ltd Glass-to-metal seals

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