US2908652A

US2908652A - Process and apparatus for defoaming liquids

Info

Publication number: US2908652A
Application number: US528377A
Authority: US
Inventors: Forrester Gilbert
Original assignee: Individual
Current assignee: Individual
Priority date: 1955-08-15
Filing date: 1955-08-15
Publication date: 1959-10-13
Anticipated expiration: 1976-10-13
Also published as: GB813856A; DE1178041B

Description

Oct. 13, 1959 I G. FORRESTER 2,908,652

PROCESS AND APPARATUS FOR DEFOAMING LIQUIDS 'Filed Aug. 15, 1955 INVENTOR PW W*BJJUJL ATTORNEYS United States Patent PROCESS AND APPARATUS FOR DEFOAMING LIQUIDS Gilbert Forrester, Falmouth, Maine Application August 15, 1955, Serial No. 528,377

6 Claims. (Cl. 252-321) As is well known foam is a problem in many situations such as in the art of paper coating. In this art coating compositions commonly are used consisting esesntially of water, pigment and adhesive. The adhesives customarily used e.g. casein and starch act as protective colloids or foam stabilizers so that it is practically impossible to make a paper coating composition of this type which is entirely free of foam or entrapped air or gas bubbles.

Foam increases the apparent viscosity of liquids and aifects their flow characteristics so that they do not pump or spread as well as foam-free liquids. The foam or bubbles present in the drying layer of coating composition on paper causes foam pits, craters and holes and seriously affects the quality of the coated paper product.

So-called foam killers or anti-foam agents are almost universally used in paper coating compositions and do serve greatly to decrease the quantity of foam but do not completely eliminate it. Besides anti-foam agents add appreciably to the cost and their use sometimes gives rise to other defects in the coated paper such as so-called oilspots or fish-eyes.

An object of the present invention is to provide relatively simple and inexpensive means for de-airing or defoaming liquids of the type of said paper coating compositions i.e. any liquid which is sufficiently fluid to be pumpable.

A further object of the'invention is to provide a defoarning apparatus which is sufficiently effective that the use of defoaming agents may be obviated, or the amount thereof required may be reduced or the results obtained with their use may be improved.

It has been found in the practice of the invention that paper coating compositions of the type referred to, are rendered substantially bubble-free so that they flow smoothly and spread well. The resulting dried coatings are free of pits' or holes and it even appears that the coated paper product has better folding properties than similar coated paper made in the usual way without the use of the defoaming apparatus of the present invention. The. invention will be described below with reference to the accompanying drawings which show an illustrative embodiment of the invention.

In the accompanying drawings:

Fig. 1 is a vertical section with parts appearing in elevation of the defoaming tank with associated equipment for supplying and withdrawing the liquid to be defoamed and for creating a reduced pressure on the liquid, and

Fig. 2 is a section on the line 2-2 of Fig. 1.

In illustrating the invention in the accompanying drawings conventional means for varying the flow of liquid and maintaining the liquid level in the apparatus and for regulating the vacuum applied are omitted. I have found that liquid level detecting means of the stationary probe type capable of sensing the electrical capacity of the adjacent liquid is most satisfactory.

Referring to the drawings 1 is a vertically disposed cylindrical tank of suitable size or capacity e.g. 1 to 1.5 feet diameter and of suitable height e.g. 4 to 6 feet. The

height generally should be several times the diameter e.g. 3 to 6 or more but operative limits of the ratio of height to diameter have not been determined and are not thought to be critical.

The tank 1 is provided with a flat cover 2 providing a gas tight closure and secured to the tank in any suitable way such as by means of the flanges 3, 3 and bolts (not shown). The cover 1 is provided with an opening for the valved pipe 4 through which liquid to be defoamed is introduced into the tank 1, a second opening for the pipe 5 through which air is exhausted from the tank 1 and a third opening through which the rotatable shaft 6 extends. A stufling box and bearings (not shown) are carried on the cover 2 for rotatably supporting the upper end of the shaft 6 and the shaft is provided with means which is conventionally illustrated by the pulley 7 and belt 8 for rotating it.

The pipe 4 discharges against the splash plate 9. This is not essential but is useful for breaking up the stream of liquid and gives improved operation.

The bottom of tank 1 is closed by the funnel-shaped bottom 10 which is secured to the tank in any suitable way as by means of the flanges 11, 11 and bolts (not shown). The funnel 10 consists of the upper conical portion 12 and the lower cylindrical portion 13 which is closed at its lower end by the plug 14 which also serves to provide the bearing for the lower end of the shaft 6. The lower end of the cylindrical portion 13 of the funnel 10 is connected to the discharge pipe 15 for the de-aerated or defoamed liquid, the movement of which is assisted by the pump 16. Pipe 5 is connected to the gas pump 17 for creating vacuum in the tank 1.

The wall of the tank 1 carries inwardly extending, spaced apart stationary blades 18, secured at their outer ends in any suitable way to the tank wall.

Blades 18 may be positioned in a variety of arrangements around the wall of the tank i.e. they may be scattered at random or arranged in a curved row extending lengthwise and around the wall of the tank or in any other pattern so long as they permit the introduction and withdrawal of the shaft 6 with its blade 19 and the rotation of said shaft and blades and provide a scissoring action between themselves and the rotating blades. Each blade 18 presents a vertically disposed flat surface and is so positioned vertically as to provide a clearance preferably of 0.10 to 0.5 inch for medium to low viscosity liquids and up to about 0.75 inch for high viscosity liquids between its edges and the edges of the rotatable blades 19. It is noted however that a blade clearance of 0.20 to 0.25 inch is capable of handling liquids within the viscosity range from that of water up to the highest viscosity that the pumps will handle. More power is of course required for the more viscous liquids. As illustrated the blades 18 are mounted in two opposite vertical rows. Each blade suitably has a width (vertical dimension) of about 1 to 1.5 inches, is of suitable thickness for strength and rigidity and its inner end is spaced a suitable distance from the shaft 6, say 0.5 inch. The blades 19 are similar to the blades 18 and extend outwardly from the shaft 6 to a suitable clearance from the wall of the tank 1, say 0.5 inch. Blades 19 also may be distributed around the shaft 6 in a variety of arrangements similarly to the blades 18. As illustrated they are arranged in two opposite vertical rows. In order to avoid sudden peaks. of hydraulic resistance as the rotating blades 19 pass the stationary blades 18 one or the other or both are positioned at an angle to the plane through the axis of the tank so that they will pass each other with a scissoring action. As illustrated the blades 19 extend outwardly in parallel planes tangent to the shaft 6 so that their outer ends trail behind their inner ends as the blades rotate counter clockwise as viewed in Fig. 2 and the blades 18 extend inwardly from the wall of the tank 1 in parallel 'planes tangent to the shaft 6. Thus the inner ends of the rotor blades will precede the outer ends thereof in passing the stator blades. Either the blades 18 may extend radially from the wall of the tank 1 toward the axis thereof or the blades 19 may extend radially from the shaft 6 outwardly toward the tank wall provided that the other set of blades is arranged non-radially to give the described scissoring action.

Mounted on the lower end of the shaft .6 within the cylindrical portion 13 of the funnel 10 is the helical auger type blade 20. This blade fits fairly closely within the cylindrical extension 13 (clearance of about 0.25' inch) and serves to move any heavy material or lumps toward the outlet pipe 15 to pump 16.

Above the helix on the shaft 6, within the conical portion 12 of the funnel 10 the shaft 6 carries the two blades 21. These blades are arranged with their lower edges close to the surface of the portion 12 of the funnel 10 and with their end edges close to the cylindrical side wall of the tank 1 so as to prevent any substantial accumulation of solids on these surfaces. These blades 21 are set at an angle to the radius from the axis to the side wall of the tank 1 so that their outer ends lead with respect to their inner ends as they rotate and material scraped from the surface of the conical portion 12 is moved inwardly and downwardly toward the helix 20.

In operation of the apparatus described above, the liquid level in the tank 1 is maintained preferably at a short distance, say 10 inches, below the top rotor blades. The blades are rotated at a suitable rate such as from 120 to 150 revolutions per minute. The vacuum in the tank 1 is maintained at a suitable value say 26 to 28 inches of mercury. The rate of flow of the liquid to be de-aerated through the tank 1 may vary within a Wide range and may be very rapid since de-aeration appears to be practically instantaneous. The rate of flow is limited only by the capacity of the pipes and valves to convey the liquid, the ability of the vacuum pump to maintain the vacuum in the tank and the ability of the apparatus to dispose of foam which appears on the surface of the body of liquid in the tank 1. This foam is beaten down by breaking the walls of the foam bubbles while they are in an expanded condition due to entry into the reduced pressure in tank 1, through the action of the exposed rotating blades 19. The foam must not be permitted to overflow from the tank 1 into the vacuum pump 17. The level of the liquid pool in tank 1 is maintained at a height such that the added height of the yet unbroken foam is below the level of the uppermost rotating blades 19.

The separation of the bubbles from the liquid in the form of a foam is effected very rapidly by flotation, as the bubbles expand upon entry into the evacuated tank 1. This separation serves to maintain the bubbles in the path of the rotating blades 19, where they are sheared and ruptured. The pool consists of substantially bubble-free liquid. With the blade arrangements described, the rate of rupture of the bubbles is very rapid, regardless of wide variations in viscosity and tenacity encountered in paper coating compositions, and the rate of treatment of liquid is limited only by the relative volume of foam entrained in a volume of untreated liquid, in that the foam layer must be maintained within the limits described above. With paper coating compositions which vary considerably in viscosity and in the tenacity of their foams, it has been found that the rate of movement of the liquid through a tank having a total capacity of about 30 gallons varies from about 15 gallons to about 35 gallons per minute.

I claim:

1. Apparatus for defoaming liquids comprising a vertically disposed cylindrical tank, means for supplying liquid to said tank, means for withdrawing liquid from said tank, means for maintaining a vacuum in said tank, a set of stationary blades carried by the wall of said tank and extending inwardly, a shaft extending axially of said tank, means for rotating said shaft, a set of blades extending outwardly from said shaft toward the wall of said tank and automatic means for maintaining the level of liquid in said tank at a substantial distance below the uppermost blades carried by said wall and said shaft, at least one of said sets of blades being positioned at an angle to the plane through the axis of said tank so that they will pass each other with a scissoring action.

2. Apparatus as defined in claim 1 in which the stationary blades are positioned in at least one plane tangent to said shaft.

3. Apparatus as defined in claim 1 in which the blades carried by said shaft extend in at least one plane tangent to said shaft.

4. Apparatus as defined in claim 1 in which said tank has a conical bottom and said shaft carries blades which are positioned to move close to the surface of said conical bottom and extend outwardly from said shaft at an angle such that the outer end of each blade precedes its inner end as the blade rotates.

5. Apparatus as defined in claim 1 in which the tank has a conical bottom with a cylindrical downward extension and the shaft carries blades and a screw which cooperate respectively with said conical bottom and said cylindrical extension to move material out of the tank as the shaft rotates.

6. Process of defoaming a liquid which comprises continuously feeding a liquid containing bubbles of gas into the top of a closed chamber, continuously withdrawing liquid from said chamber adjacent to the bottom thereof, regulating the relative rates of supply and withdrawal of liquid into and out of said chamber so as to maintain a substantially constant level of liquid therein, maintaining a vacuum in said chamber, and continuously subjecting both the body of liquid in said chamber and the layer of foam which collects on the upper surface thereof to a shearing action between relatively moving solid surfaces.

References Cited in the file of this patent UNITED STATES PATENTS

Claims

6. PROCESS OF DEFOAMING A LIQUID WHICH COMPRISES CONTINOUSLY FEEDING A LIQUID CONTAINING BUBBLES OF GAS INTO THE TOP OF A CLOSED CHAMBER, CONTINUOUSLY WITHDRAWING LIQUID FROM SAID CHAMBER ADJACENT TO THE BOTTOM THEREOF, REGULATING THE RELATIVE RATES OF SUPPLY AND WITHDRAWAL OF LIQUID INTO AND OUT OF SAID CHAMBER SO AS TO MAINTAIN A SUBSTANTIALLY CONSTANT LEVEL OF LIQUID THEREIN, MAINTAINING A VUCUUM IN SAID CHAMBER, AND CONTINOUSLY SUBJECTING BOTH THE BODY OF LIQUID IN SAID CHAMBER AND THE LAYER OF FOAM WHICH COLLECTS ON THE UPPER SURFACE THEREOF TO A SHEARING ACTION BETWEEN RELATIVELY MOVING SOLID SURFACES.