US290744A - Glass mirror - Google Patents
Glass mirror Download PDFInfo
- Publication number
- US290744A US290744A US290744DA US290744A US 290744 A US290744 A US 290744A US 290744D A US290744D A US 290744DA US 290744 A US290744 A US 290744A
- Authority
- US
- United States
- Prior art keywords
- silver
- glass
- wax
- coating
- glass mirror
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011521 glass Substances 0.000 title description 22
- BQCADISMDOOEFD-UHFFFAOYSA-N silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 30
- 229910052709 silver Inorganic materials 0.000 description 30
- 239000004332 silver Substances 0.000 description 30
- 239000011248 coating agent Substances 0.000 description 22
- 238000000576 coating method Methods 0.000 description 22
- 239000000126 substance Substances 0.000 description 20
- 239000001993 wax Substances 0.000 description 20
- 229910052751 metal Inorganic materials 0.000 description 14
- 239000002184 metal Substances 0.000 description 14
- 239000010408 film Substances 0.000 description 12
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 239000003973 paint Substances 0.000 description 8
- 239000002966 varnish Substances 0.000 description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000010409 thin film Substances 0.000 description 6
- 239000005864 Sulphur Substances 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 4
- 239000011888 foil Substances 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 206010022114 Injury Diseases 0.000 description 2
- 240000003936 Plumbago auriculata Species 0.000 description 2
- 235000013871 bee wax Nutrition 0.000 description 2
- 239000012166 beeswax Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000005357 flat glass Substances 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 230000000266 injurious Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000012184 mineral wax Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000001590 oxidative Effects 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N tin hydride Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 239000012178 vegetable wax Substances 0.000 description 2
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31714—Next to natural gum, natural oil, rosin, lac or wax
Definitions
- the silver deposited on the surface of sheets or plates of glass for the purpose of making mirrors, is very apt to suffer injury by mechanical abrasion, and also by oxidation from the access of the atmosphere.
- the first of these is that the contact of the two metals causes a galvanic action to be established,which in process of time causes the silver to be so acted uponas to destroythe smoothness of its surface, and thus render it useless as a mirror; and the other is that, owing to the different degrees of expansibility by heat of copper and silver, the continuity of surface of the silver is broken up by the formation of minute cracks, with a like in jurious effect on the mirror.
- the method of protecting the silvered surfaces of mirrors which we have invented is designed to obviate these defects by coating the outer surface of the silver, after it has been deposited upon the glass, with a thin film of wax, paint, varnish, or similar substance, and then applying an exterior coating of metal, by which means we not only protect the silver deposited on the glass from being Application filed August 18, 1883. (No model.)
- the glass having been first coated with silver by. any of the methods used for that purpose, a thin film of wax, varnish, paint, or similar substance is applied, the manner of its application depending on the substance used. For this purpose it is desirable to use a. sub stance which contains as little oxygen as possible. Beeswax or any of the vegetable or mineral waxes may be employed, in which case the plate-glass may be heated in any convenient mannerto a sufficient degree to melt the wax, which is then gently rubbed over the surface of the silver until it is uniformly coated therewith.
- any suitable paint or varnish may be used, or the viscous residuum of the distillation of petroleum, which, if reduced to a sufficient degree of consistency, is
- a thin leaf of metallic foil is placed evenly on the surface of the plate, over the film of wax or other substance, and is pressed down closely by means of a roller, brush, or otherwise, so as to form a close union between the foil and the film of wax or other substance, and to exclude all bubbles of air.
- the outer or metallic coating may be applied by first coating the surface of the wax, &c. with plumbago, and then depositing a film of copper, tin, or other metal by means of the electrotype process in the well-known method 5 or, if preferred, the metallic coating may be applied by means of foilsuch as tin-foil-0r of paper coated with silver or other metal, in which case we prefer to apply the metallic surface of the paper to the surface of the inner coating.
- silvered glass mirrors having on the silvercd surface an inner coating of wax or other similar sub- 10 stance impervious to the atmosphere and an outer coating of metal, substantially as de scribed.
Description
(No Model.)
J. M. GONROY & F. E. YOUNGS.
. GLASS MIRROR; No. 290,744. Patented Dec. 25, 1883.
WFLEESR Y [qveqlnaa M 5;, ym J jy y" silver in contact with the glass.
STATES PATENT rrrcn.
JOHN M. CONR-OY AND FRED E. YOUNGS, OF ALLEGHENY, PENNSYLVANIA.
GLASS MIRROR.
SPECIFICATION forming part of Letters PatentNo. 290,744, dated December 25, 1883.
To all whom it may concern.-
Be it known that we, JOHN M. CONROY and FRED E. YoUNGs, of the city of Allegheny, in the county of Allegheny and State of Penn sylvania, have invented a new and useful Improvement in Glass Mirrors; and we do hereby declare the following to be a full, clear, and exact description thereof.
The silver deposited on the surface of sheets or plates of glass, for the purpose of making mirrors, is very apt to suffer injury by mechanical abrasion, and also by oxidation from the access of the atmosphere. In order to protect the silvered surface from being defaced by either of these causes, it has been suggested to coat the silvered surface of the glass with a thin film of copper deposited on the silver by the electrotype process; but this method, although affording a certain degree of protection, is liable to two serious objections, either of which renders it practically useless. The first of these is that the contact of the two metals causes a galvanic action to be established,which in process of time causes the silver to be so acted uponas to destroythe smoothness of its surface, and thus render it useless as a mirror; and the other is that, owing to the different degrees of expansibility by heat of copper and silver, the continuity of surface of the silver is broken up by the formation of minute cracks, with a like in jurious effect on the mirror. In both cases, also, the mirror becomes spotted and discollored, owing to the access of oxygen, and in some localities of sulphur, to the surface of the Another method which has been proposed is to coat the outer surface of the silver with a film or succession of films of varnish, paint, or like substances; but this is liable to the objection that these substances will gradually shrink and crack and expose the silver to the oxidizing effect of the atmosphere.
The method of protecting the silvered surfaces of mirrors which we have invented is designed to obviate these defects by coating the outer surface of the silver, after it has been deposited upon the glass, with a thin film of wax, paint, varnish, or similar substance, and then applying an exterior coating of metal, by which means we not only protect the silver deposited on the glass from being Application filed August 18, 1883. (No model.)
attacked by the oxygen and sulphur in the atmosphere, but also obviate the injurious effects resulting from the immediate contact with:
the silver of another metal.
In order to enable our invention to be used by others skilled in the art, we will proceed more fully to describe the method by which we carry it into effect.
The glass having been first coated with silver by. any of the methods used for that purpose, a thin film of wax, varnish, paint, or similar substance is applied, the manner of its application depending on the substance used. For this purpose it is desirable to use a. sub stance which contains as little oxygen as possible. Beeswax or any of the vegetable or mineral waxes may be employed, in which case the plate-glass may be heated in any convenient mannerto a sufficient degree to melt the wax, which is then gently rubbed over the surface of the silver until it is uniformly coated therewith.
In place of wax, any suitable paint or varnish may be used, or the viscous residuum of the distillation of petroleum, which, if reduced to a sufficient degree of consistency, is
desirable as being free from oxygen. Before the film thus applied becomes hard a thin leaf of metallic foil is placed evenly on the surface of the plate, over the film of wax or other substance, and is pressed down closely by means of a roller, brush, or otherwise, so as to form a close union between the foil and the film of wax or other substance, and to exclude all bubbles of air.
If the inner coating is made of wax or other substance which will become, when cold or dry, sufficiently hard to permit of it, the outer or metallic coating may be applied by first coating the surface of the wax, &c. with plumbago, and then depositing a film of copper, tin, or other metal by means of the electrotype process in the well-known method 5 or, if preferred, the metallic coating may be applied by means of foilsuch as tin-foil-0r of paper coated with silver or other metal, in which case we prefer to apply the metallic surface of the paper to the surface of the inner coating.
Having thus described our improvement, what we claim as our invention, and desire to secure by Letters Patent, is-
1. The method hereinbefore described of protecting the silvered surface of mirrors from abrasion and atmospheric action by applying to the exterior surface of the silver an inner coating of wax or other suitable substance and 5 an outer coating of metal, substantially as and for the purpose described.
2. As a new article of manufacture, silvered glass mirrors having on the silvercd surface an inner coating of wax or other similar sub- 10 stance impervious to the atmosphere and an outer coating of metal, substantially as de scribed.
In testimony whereof we have hereunto set our hands this 15th day of August, A.D.1883.
JOHN M. CONROY. FRED E. YOUNGS.
Witnesses:
THOMAS W. BAKEWELL, W. B. CoRWIN.
Publications (1)
Publication Number | Publication Date |
---|---|
US290744A true US290744A (en) | 1883-12-25 |
Family
ID=2359932
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US290744D Expired - Lifetime US290744A (en) | Glass mirror |
Country Status (1)
Country | Link |
---|---|
US (1) | US290744A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2468568A (en) * | 1945-09-27 | 1949-04-26 | Safetee Glass Company | Laminated mirror |
US2582786A (en) * | 1950-03-23 | 1952-01-15 | Seth G Malby | Mirror |
-
0
- US US290744D patent/US290744A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2468568A (en) * | 1945-09-27 | 1949-04-26 | Safetee Glass Company | Laminated mirror |
US2582786A (en) * | 1950-03-23 | 1952-01-15 | Seth G Malby | Mirror |
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